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1.13 – Emerging contaminants

Since the Industrial Revolution, a diversity of large-scale chemical innovations has impacted aquatic systems in urban environments. Beginning in the 1990s, there has been a growing scientific interest and public awareness of the effects of the chemicals used in domestic, commercial, industrial, and agricultural applications, referred to in this article as ‘emerging contaminants’ (ECs), on ecosystem and human health. The growing global population and its increasing demands on water supplies in conjunction with climate-induced changes in hydrologic regimes place stress on freshwater resources, resulting in a greater reliance on reuse of reclaimed municipal wastewater treatment plant (WWTP) effluents to meet human and environmental needs. WWTP effluents are a major source of ECs, and it is important to have an understanding of the chemical composition of the reclaimed water, because many ECs are biologically active and the effects of chronic exposure to low concentration complex mixtures are unknown. Several classes of ECs that have been shown to be widespread in the aquatic environment are discussed in this chapter, including surfactants, complexing agents, fragrances, antimicrobials, industrial chemicals, pharmaceuticals, natural and synthetic estrogens, and disinfection byproducts. All of these compounds are biologically active via a variety of modes of action, and can occur in aquatic systems at concentrations ranging from <0.001 to >100 μg l −1 .

Book chapter↗

Present weather and climate: evolving conditions

This chapter assesses weather and climate variability and trends in the Southwest, using observed climate and paleoclimate records. It analyzes the last 100 years of climate variability in comparison to the last 1,000 years, and links the important features of evolving climate conditions to river flow variability in four of the region&rsquo;s major drainage basins. The chapter closes with an assessment of the monitoring and scientific research needed to increase confidence in understanding when climate episodes, events, and phenomena are attributable to human-caused climate change.

Book chapter↗

Spatial Relation Predicates in Topographic Feature Semantics

Topographic data are designed and widely used for base maps of diverse applications, yet the power of these information sources largely relies on the interpretive skills of map readers and relational database expert users once the data are in map or geographic information system (GIS) form. Advances in geospatial semantic technology offer data model alternatives for explicating concepts and articulating complex data queries and statements. To understand and enrich the vocabulary of topographic feature properties for semantic technology, English language spatial relation predicates were analyzed in three standard topographic feature glossaries. The analytical approach drew from disciplinary concepts in geography, linguistics, and information science. Five major classes of spatial relation predicates were identified from the analysis; representations for most of these are not widely available. The classes are: part-whole (which are commonly modeled throughout semantic and linked-data networks), geometric, processes, human intention, and spatial prepositions. These are commonly found in the &lsquo;real world&rsquo; and support the environmental science basis for digital topographical mapping. The spatial relation concepts are based on sets of relation terms presented in this chapter, though these lists are not prescriptive or exhaustive. The results of this study make explicit the concepts forming a broad set of spatial relation expressions, which in turn form the basis for expanding the range of possible queries for topographical data analysis and mapping.

Book chapter↗

The geochemistry of pesticides

The mid-1970s marked a major turning point in human history, for it was at that moment that the ability of the Earth&rsquo;s ecosystems to absorb most of the biological impacts of human activities appears to have been exceeded by the magnitude of those impacts. This conclusion is based partly upon estimates of the rate of carbon dioxide emission during the combustion of fossil fuels, relative to the rate of its uptake by terrestrial ecosystems ( Loh, 2002 ). A very different threshold, however, had already been crossed several decades earlier with the birth of the modern chemical industry, which produced novel substances for which no such natural assimilative capacity existed. Among these new chemical compounds, none has posed a greater challenge to the planet&rsquo;s ecosystems than synthetic pesticides, compounds that have been intentionally released into the hydrologic system in vast quantities&mdash;several hundred million pounds of active ingredient (a.i.) per year in the United States alone ( Donaldson et al. , 2002 )&mdash;for many decades. To gauge the extent to which we are currently able to assess the environmental implications of this new development in the Earth&rsquo;s history, this chapter presents an overview of current understanding regarding the sources, transport, fate, and biological effects of pesticides, their transformation products, and selected adjuvants in the hydrologic system. (Adjuvants are the so-called inert ingredients included in commercial pesticide formulations to enhance the effectiveness of the active ingredients.)

Book chapter↗

Ostracoda and paleoceanography

This chapter contains sections titled: Introduction Brief Summary of Modern Ostracodes in the World's Oceans Paleoceanography Over 10 6 -10 7 Year Timescales Orbital Scale Climate Variability Millennial Scale Climate Centennial and Decadal Climate Trends Future Work

Geophysical Monograph↗

Soil formation: Chapter 6

Soil formation reflects the complex interaction of many factors, among the most important of which are (i) the nature of the soil parent material, (ii) regional climate, (iii) organisms, including humans, (iv) topography and (v) time. These processes operate in Earth's critical zone; the thin veneer of our planet where rock meets life. Understanding the operation of these soil-forming factors requires an interdisciplinary approach and is a necessary predicate to charactering soil processes and functions, mitigating soil degradation and adapting soil management to environmental change. In this chapter, we discuss how these soil-forming factors operate both singly and in concert in natural and human modified environments. We emphasize the role that soil organic matter plays in these processes to provide context for understanding the benefits that it bestows on humanity.

Book chapter↗

Seasonal movements among river reaches, migration strategies, and population structure of the divided Connecticut River shortnose sturgeon population: the effects of Holyoke Dam

Even after 155 years, each population segment seasonally migrates toward the other attempting to maintain the natural connection. Migration timing and style of pre-spawning and post-spawning males and females is discussed, as is homing. The impact of Holyoke Dam on population size and growth is characterized and turbine mortality of adult sturgeon passing through a Kaplan turbine at the dam is estimated. The chapter also identifies a behavioral dysfunction that results when migrations are blocked by a dam and are not completed at the correct stage of life. Many unknown effects of damming on other long-lived riverine fishes are likely captured in this 16-year study.

Conneticut, Massachusetts↗

Release strategies for rehabilitated sea otters

According to the U.S. Fish and Wildlife Services’ (USFWS) Response Plan for sea otters (USFWS, in preparation), in the event of an oil spill, the decision to release sea otters from rehabilitation centers following treatment will be linked to the decision on whether to capture sea otters for treatment . Assuming a scenario similar to the Exxon Valdez oil spill (EVOS), once the decision to capture sea otters is made, the ultimate goal is to return as many sea otters to the wild as possible, even though the rescue may not be expected to produce results significant at the population level. The decision by the USFWS to proceed with capture, rehabilitation, and release will be made on a case-by-case basis (USFWS, in preparation). Many factors will influence the decision. Perhaps the most important factors in deciding when and where to release sea otters are the location and availability of suitable release sites and verification that the otters are free of diseases that might be transmitted to the wild population. Alternative release strategies for sea otters will be contained in the sea otter response portion of the USFWS’s oil spill contingency plans for Alaska and California that are being developed as required by the Oil Pollution Act of 1990. Public review of these plans before they are implemented will help to reduce public concern about the survival of rehabilitated otters, their biological effect on the release area, and the potential introduction or spread of disease into the wild sea otter population. The objective of this chapter is to review alternative strategies for the disposition of rehabilitated sea otters. Our assumption is that returning as many animals to the wild as possible, whether it be for humanitarian or biological reasons, is the ultimate goal of this effort (Figure 10.1).

Book chapter↗

Fire and nonnative invasive plants in the central bioregion

The Central bioregion is a vast area, stretching from Canada to Mexico and from the eastern forests to the Rocky Mountains, dominated by grasslands and shrublands, but inclusive of riparian and other forests. This bioregion has been impacted by many human induced changes, particularly relating to agricultural practices, over the past 150 years. Also changed are fire regimes, first by native peoples who used fire for a variety of purposes and then by European settlers, who directly and indirectly contributed to a great reduction in the frequency of fire on the landscape. Perhaps of even greater importance has been the introduction of nonnative plant species, which have come to impact every community type to some degree. Nonnative plants have a wide array of impacts on native ecosystems and populations in the Central bioregion, and these impacts continue to mount and evolve. Many long-time invaders, such as smooth brome (Bromus inermis), and leafy spurge (Euphorbia esula), have already spread to large areas, and their ranges may still be expanding. Others, such as tamarisk or saltcedar (Tamarix spp.) and buffelgrass (Pennisetum ciliare), are rapidly spreading at the present time, while still others have likely not yet shown their full potential for expansion. In this volume, as well as in this chapter, our emphasis is on the interaction of nonnatives with fire, how it affects them and how they affect it. The ecosystems of the Central bioregion have been shaped by fire, including fires associated with natural ignitions and those deliberately set by humans. Both grasslands and shrublands in this bioregion experienced frequent and widespread fires during their evolution (Stewart 2002). Prescribed fire is now widely used to manage some areas for their natural characteristics. Thus, while changed in character, both by conditions that now limit wildfire occurrence and spread and by prescribed burning, the Central bioregion remains one with a high fire frequency (Wade and others 2000). Fire interactions with nonnative plants can have important impacts. In some cases, fire can be a means of reducing impacts of nonnative species (chapter 4). In other cases, fire may facilitate the establishment and spread of nonnatives (chapter 2). Some nonnative species can radically change the fire regime itself (chapter3). Because of the widespread use of prescribed fire in this bioregion, it is important to know how nonnative species interact with fire and whether there are means whereby these interactions can be controlled.

Great Plains↗

Imperiled mammalian fauna of aquatic ecosystems in the Southeast: A historical perspective

About 100 species of mammals are endemic to the southeastern United States, an area of diverse habitat types and high biodiversity. Many of these species are either formally considered aquatic or semi-aquatic, or they are otherwise closely associated with aquatic ecosystems. In the southeastern United States, greater than 80 percent of mammalian species are listed in some category of concern throughout all or at least a portion of their ranges (i.e., endangered, threatened, under review for possible listing as endangered or threatened, species of special concern, species deemed in need of management, etc.). Almost all of these species are imperiled because their populations have declined to dangerously low levels due to habitat loss, habitat degradation, or other human-related factors. Most imperiled mammal taxa can be categorized as belonging to one of two general groups: habitat generalists or habitat specialists. Typically, habitat generalists have become imperiled mainly due to human exploitation, while habitat specialists have suffered primarily from habitat loss or habitat degradation. The passage of the U.S. Endangered Species Act of 1973 resulted in an increased need for information concerning distribution and status of all native species. However, relatively little is known concerning the historical distribution and current status of many mammalian taxa, and this is particularly so for small non-game species. In this chapter we provide species accounts of mammals commonly associated with aquatic ecosystems that we consider to be imperiled in the southeastern United States. In these accounts we have included information which we feel is valuable toward best understanding the threats that challenge each considered taxon.

Book chapter↗

Cold-water corals of the world: Gulf of Mexico

The Gulf of Mexico is a semi-enclosed sea that borders the USA and Mexico and covers approximately 1.5 million square kilometers. The northern Gulf is topographically complex and is a rich source of oil and gas deposits, which has led to a great deal of research on benthic ecosystems from the coastal zone to the deep sea. While not fully explored, the distribution of cold seeps and deep corals in the northern Gulf is reasonably well described. The eastern Gulf has a moratorium on energy industry development and consequently less exploration and research has been conducted in this region; however, recent explorations have revealed deep scleractinian reefs on the west Florida slope and extensive octocoral gardens on the deep escarpment. The Gulf is a productive sea with lucrative fisheries in addition to oil and gas. Exploitation of natural resources and potential climate change impacts threaten vulnerable ecosystems in the Gulf, including those in the deep sea. This chapter describes the oceanography and geology of the Gulf of Mexico, presents the current state of the knowledge of cold-water coral distribution, physiology and ecology, and provides an assessment of the threats to these vulnerable ecosystems.

Book chapter↗

The medical geochemistry of dusts, soils, and other Earth materials: Chapter 7

A quick scan of newspapers, television, science magazines, or the internet on any given day has a fairly high likelihood of encountering stories (accompanied by headlines such as those above) regarding human health concerns linked to dusts, soils, or other Earth materials. Many such concerns have been recognized and studied for decades, but new concerns arise regularly.

Book chapter↗

Land use change and climate-smart agriculture in the Sahel

In the 1970s and 1980s, the Sahel experienced recurrent drought and famine. Farmers and their development partners reacted to this crisis by developing climate-smart agricultural practices and changes in land use, including water-harvesting techniques to restore degraded land to productivity. In several densely populated parts of the Sahel, farmers began to protect and manage woody species that regenerated naturally on their farmland. Farmer-managed natural regeneration (FMNR) is a foundational practice that produces multiple benefits, such as maintaining or improving soil fertility, which raises crop yields, and increasing the production of tree-based fodder, fruit, and firewood. In Niger’s Maradi and Zinder Regions alone, farmers have applied FMNR practices on 4.2 million hectares. The findings presented in this chapter suggest that the future of agriculture in the Sahel will be largely determined by whether low-income smallholder farmers will manage to improve soil fertility, which will depend on maintaining substantial densities of on-farm trees thus increasing tree cover.

Sahel Region↗

Serrasalmidae — Piranhas and Pacus

The family Serrasalmidae is a morphologically and ecologically diverse group of South American freshwater fishes consisting of 16 genera and about 91 valid species. This chapter is a summary of the current state of knowledge on serrasalmid taxonomy, species richness, and ecology, and provides an identification key to the genera and references to relevant literature for species-level identifications. Included is information on native and non-native populations.

Book chapter↗

Monitoring lightning and electrification in volcanic plumes

Detection of the electrical discharges and, more fundamentally, the electrification from volcanic plumes is an emerging capability for volcano monitoring. In addition to being able to detect an explosive eruption, such measurements also provide insight into volcanic processes. Volcanic lightning monitoring can be achieved through varying levels of complexity. At the lowest complexity, an observatory can use low-cost global lightning data sets for eruption detection and characterization, while at the highest complexity local lightning sensors can be installed to improve the level of observational detail and response times. This chapter provides background about volcanic lightning and plume electrification, information concerning the relevant instrumentation to detect lightning and electrified plumes, examples of how lightning can be used to understand eruptive processes, and a guide to implementing volcanic lightning detection into a monitoring scheme.

Book chapter↗

Freshwater to seawater transitions in migratory fishes

The transition from freshwater to seawater is integral to the life history of many fishes. Diverse migratory fishes express anadromous, catadromous, and amphidromous life histories, while others make incomplete transits between freshwater and seawater. The physiological mechanisms of osmoregulation are widely conserved among phylogenetically diverse species. Diadromous fishes moving between freshwater and seawater develop osmoregulatory mechanisms for different environmental salinities. Freshwater to seawater transition involves hormonally mediated changes in gill ionocytes and the transport proteins associated with hypoosmoregulation, increased seawater ingestion and water absorption in the intestine, and reduced urinary water losses. Fishes attain salinity tolerance through early development, gradual acclimation, or environmentally or developmentally cued adaptations. This chapter describes adaptations in diverse taxa and the effects of salinity on growth. Identifying common strategies in diadromous fishes moving between freshwater and seawater will reveal the ecological and physiological basis for maintaining homeostasis in different salinities, and inform efforts to conserve and manage migratory euryhaline fishes.

Book chapter↗

Hydrology and biogeochemistry linkages

This chapter provides an overview of the linkages between hydrology and biogeochemistry in terrestrial and aquatic systems. Selected topics include hydrological pathways on drainage basin slopes, mountain environments, within-river (or in-stream) processes, wetlands, groundwater (and groundwater–surface water interactions), and lakes. Beginning from catchment headwaters, This chapter introduces mechanisms delivering water from hillslopes to stream channels, highlighting the relative importance of biogeochemical processes along hydrological pathways. It considers processes affecting components of the water budget, including snow formation and ablation processes, and interactions with the soil below snow cover and during snowmelt. It presents the concept of nutrient spiraling and the importance of temperature and stream flow variability on biogeochemistry, as well as groundwater–surface water interactions through hyporheic and riparian zones. This chapter contrasts important processes in hydrologically isolated wetlands with those temporally connected to streams and rivers. It addresses stream and groundwater inputs, stratification, and within-lake processes, interactions with sediments, and a discussion about limiting nutrients. This chapter presents information about typical reactions controlled by hydrological pathways, lithology (mineralogy) and biota, the importance of residence time in biogeochemical evolution, and linkages between groundwater Acidic atmospheric deposition

Book chapter↗