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USGS2023

Water quality at Chaco Culture National Historical Park and the potential effects of hydrocarbon extraction

Study region Chaco Culture National Historical Park (CCNHP) is in the San Juan Basin of northwestern New Mexico, U.S.A. Its only water supply is in Gallup Sandstone aquifer, stratigraphically surrounded by layers long targeted for oil and natural gas extraction. Study focus To assess groundwater flow direction, age, mixing between aquifers, and whether hydrocarbons extraction may affect water quality, we completed a geochemical groundwater sampling campaign. Groundwater at 11 sites was analyzed for major ions, hydrocarbon associated volatile organic carbon (VOC) compounds, noble gases, and the isotope systems δ 2 H, δ 18 O, 87 Sr/ 86 Sr, δ 13 C, and 14 C. New hydrological insights for the region Results demonstrate that all sampled groundwaters are exceedingly old and geochemically evolved, with a median 14 C age of ∼41,000 years before present and a north flowing path. Three lines of evidence suggest mixing between aquifers through relatively impermeable shale units and mixing with hydrocarbons: 1) noble gases are fractionated likely through mixing with connate water expelled during hydrocarbon genesis; 2) several wells—including the park’s main supply well—contained trace amounts of hydrocarbon related VOC compounds; and 3) major ion analysis shows mixing trends between aquifers. We hypothesize that cross-aquifer mixing may be facilitated through the region’s numerous hydrocarbon related boreholes. Whether our findings are the result of oil and gas extraction or represent the natural state of the aquifers will require more research.

New Mexico↗

USGS1994

The effect of a confining unit on the geochemical evolution of ground water in the Upper Floridan aquifer system

In west-central Florida, sections of the Upper Floridan aquifer system range in character from confined to leaky to unconfined. The confining unit is the Hawthorn Formation, a clay-rich sequence. The presence or absence of the Hawthorn Formation affects the geochemical evolution of the ground water in the Upper Floridan aquifer system. Mass-balance and mass-transfer models suggest that, in unconfined areas, the geochemical reactions are dolomite dissolution, ion exchange (Mg for Na, K), sulfate reduction, calcite dissolution, and CO 2 exchange. In the areas in which the Hawthorn Formation is leaky, the evolution of the ground water is accounted for by ion exchange, sulfate reduction, calcite dissolution, and CO 2 exchange. In the confined areas, no ion exchange and only limited sulfate reduction occur, and the chemical character of the ground water is consistent with dolomite and gypsum dissolution, calcite precipitation, and CO 2 ingassing. The Hawthorn Formation acts both as a physical barrier to the transport of CO 2 and organic matter and as a source of ion-exchange sites, but the carbonate-mineral reactions are largely unaffected by the extent of confinement of the Upper Floridan aquifer.

Journal of Hydrology↗

USGS1981

Geological considerations in hazardous waste disposal

Present regulations assume that long-term isolation of hazardous wastes - including toxic chemical, biological, radioactive, flammable and explosive wastes - may be effected by disposal in landfills that have liners of very low hydraulic conductivity. In reality, total isolation of wastes in humid areas is not possible; some migration of leachate from wastes buried in the gound will always occur. Regulations should provide performance standards applicable on a site-by-site basis rather than rigid criteria for site selection and design. The performance standards should take into account several factors: (1) the categories, segregation, degradation and toxicity of the wastes; (2) the site hydrogeology, which governs the direction and rate of contaminant transport; (3) the attenuation of contaminants by geochemical interactions with geologic materials; and (4) the release rate of unattenuated pollutants to surface or groundwater. An adequate monitoring system is essential. The system should both test the extent to which the operation of the site meets performance standards and provide sufficient warning of pollution problems to allow implementation of remedial measures. In recent years there has been a trend away from numerous, small disposal sites toward fewer and larger sites. The size of a disposal site should be based on the attenuation capacity of the geologic material, which has a finite, though generally not well-defined, limit. For slowly degradable wastes, engineered sites with leachate-collection systems appear to be only a temporary solution since the leachate collected will also require final disposal.

Journal of Hydrology↗

USGS2018

The geochemistry of loess: Asian and North American deposits compared

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the bulk of loess deposits are found on both continents. Although loess has been considered to be representative of the average upper continental crust, there are regionally distinctive compositions of loess in both Asia and North America. Loess deposits in Asia from Yakutia, Tajikistan, and China have compositionally distinct major element compositions, due to varying abundances of silicate minerals, carbonate minerals, and clay minerals. In North America, loess in the Mississippi River valley, the Great Plains, and Alaska are also distinguishable with regard to major element composition that reflects highly diverse source sediments. Trace element geochemistry (Sc-Th-Zr and the rare earth elements) also shows regional diversity of loess bodies, in both Asia and North America. On both continents, most loess bodies show significant contributions from later-cycle, altered sedimentary rocks, as opposed to direct derivation from igneous rocks. Further, some loess bodies have detectable contributions from mafic igneous rocks as well as major contributions from average, upper-crustal, felsic rocks. Intercalated paleosols in loess sections show geochemical compositions that differ significantly from the underlying loess parent materials. Ratios of soluble-to-insoluble elements show depletions in paleosols due to chemical weathering losses of calcite, dolomite, plagioclase, mica, apatite, and smectite. In Asia and North America, the last interglacial paleosol is more weathered than equivalent modern soils, which could be due either to a climate that was warmer and more humid, a longer period of pedogenesis, or both. In Asia, early Pleistocene loess and paleosols are both more weathered than those from the middle and late Pleistocene, forming prior to a mid-Pleistocene aridification of Asia from uplift of the Tibetan Plateau. Understanding the geochemistry of loess and paleosols can tell us much about past atmospheric circulation, past temperature and moisture regimes, and even tectonic processes.

Journal of Asian Earth Sciences↗

USGS2007

Geochemical interpretations of groundwater flow systems

Interest in the geochemistry of groundwater is increasing owing to the great number of current projects involving underground liquid waste storage, artificial recharge of potable water, accidental contamination of groundwater bodies, sanitary landfills, and pollution monitoring. Geochemical techniques used to facilitate the understanding of a groundwater system range from extremely simple to those requiring sophisticated theories, equipment, and procedures. An interpretation of the simple trilinear diagram for samples collected from the Yucatan Peninsula of Mexico provided evidence that the fresh-water body was only a few tens of meters thick and was underlain everywhere by an extensive body of salt water. A geochemical technique that has been used effectively to identify the source of salt water in coastal aquifers is measurement of the carbon-14 concentrations. Carbon-14 has been used in a regional carbonate aquifer to determine the velocity of groundwater movement, rates of chemical reactions, and distribution of hydraulic conductivity. The application of principles of irreversible thermodynamics to groundwater systems provides a basis for constructing models which permit prediction, over both time and space, of changes in head distribution and chemical character of the water resulting from imposed stresses on the system. In essence, proper application of irreversible thermodynamics combines the potential theory of Hubbert with principles of reversible chemical thermodynamics, such as solution of carbonate minerals, to describe and explain controlling chemical reactions and processes of groundwater systems.

Florida, South Carolina↗

USGS1993

Geology, geochemistry, and geochronology of the central Giants Range batholith, northeastern Minnesota

The Giants Range batholith is a large composite granitoid body that intrudes deformed supracrustal rocks in the western part of the Wawa Subprovince of the Archean Superior Province. Peak fabric development in the supracrustal rocks coincides with D 2 deformation, the product of regional transpression across the southern Superior Province. U–Pb zircon ages on two phases of the Giants Range batholith bracket D 2 deformation to an interval between 2685 and 2669 Ma. Two well-exposed components of the central part of the Giants Range batholith are the pre- to syn-D 2 Britt granodiorite, which contains a linear D 2 metamorphic fabric, and the syn- to post-D 2 Shannon Lake granite, which cuts deformation fabrics in the Britt granodiorite and the supracrustal rocks. Geochemical discrimination plots imply emplacement of the Britt granodiorite in an arc environment and the Shannon Lake granite in a collision setting. Zircons yield U–Pb ages of 2681 ± 4 and 2685 ± 4 Ma for the Britt granodiorite and 2674 ± 5 and 2674 ± 27 Ma for the Shannon Lake granite. Timing of D 2 deformation near the Giants Range batholith corresponds well with similar rocks exposed along strike 170 km to the east near Shebandowan Lake, Ontario, where the end of D 2 deformation has been bracketed between 2692 and 2681 Ma. The slightly younger ages for D 2 deformation in Minnesota reflect later volcanic-arc development and associated plutonism than at Shebandowan Lake, possibly due to oblique convergence along a westward-migrating tectonic front.

Canadian Journal of Earth Sciences↗

USGS2008

Variability of geochemical properties in a microbially dominated coalbed gas system from the eastern margin of the Illinois Basin, USA

This study outlines gas characteristics along the southeastern margins of the Illinois Basin and evaluates regional versus local gas variations in Seelyville and Springfield coal beds. Our findings suggest that high permeability and shallow (100-250??m) depths of these Indiana coals allowed inoculation with methanogenic microbial consortia, thus leading to widespread microbial methane generation along the eastern marginal part of the Illinois Basin. Low maturity coals in the Illinois Basin with a vitrinite reflectance Ro ~ 0.6% contain significant amounts of coal gas (~ 3??m3/t, 96??scf/t) with ??? 97??vol.% microbial methane. The amount of coal gas can vary significantly within a coal seam both in a vertical seam section as well as laterally from location to location. Therefore sampling of an entire core section is required for accurate estimates of coal gas reserves. ?? 2008 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

USGS1989

Relation of salinity and selenium in shallow groundwater to hydrologic and geochemical processes, Western San Joaquin Valley, California

Salinity and selenium concentrations in shallow groundwater of the western San Joaquin Valley, California, are related to the geomorphology and hydrology of the alluvial fans. The highest salinity and selenium concentrations in shallow groundwater occur in alluvium deposited by ephemeral streams and at the margins of the major alluvial fans, where there were naturally saline, fine-grained soils. Low-to-moderate salinity and selenium concentrations in shallow groundwater are associated with upper and middle areas of the major alluvial fans deposited by intermittent streams. Areas with the most naturally saline soils have been irrigated in the last 40 years. These are now the areas of highest salinity and selenium concentrations in the shallow groundwater. Present-day (1986) groundwater salinity is spatially correlated with natural soil salinity in these areas. Isotopic data indicate that the highest salinity and selenium concentrations in groundwater present at low altitudes resulted from evaporative concentration when the water table was shallow.

California↗

USGS2012

Soil genesis on the island of Bermuda in the Quaternary: the importance of African dust transport and deposition

The origin of terra rossa, red or reddish-brown, clay-rich soils overlying high-purity carbonate substrates, has intrigued geologists and pedologists for decades. Terra rossa soils can form from accumulation of insoluble residues during dissolution of the host limestones, addition of volcanic ash, or addition of externally derived, long-range-transported (LRT) aeolian particles. We studied soils and paleosols on high-purity, carbonate aeolianites of Quaternary age on Bermuda, where terra rossa origins have been debated for more than a century. Potential soil parent materials on this island include sand-sized fragments of local volcanic bedrock, the LRT, fine-grained (<20 μm) component of distal loess from the lower Mississippi River Valley, and LRT dust from Africa. These parent materials can be characterized geochemically using trace elements that are immobile in the soil-forming environment. Results indicate that local volcanic bedrock on Bermuda has Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, La N /Yb N , Gd N /Yb N that can be distinguished from African dust and lower Mississippi River valley loess. Bermuda soils have Sc-Th-La, Cr-Ta-Nd, and Eu/Eu*, La N /Yb N , Gd N /Yb N that indicate derivation from a combination of LRT dust from Africa and local volcanic bedrock. Our results indicate that soils on islands in a very broad latitudinal belt of the western Atlantic margin have been influenced by African LRT dust inputs over much of the past –500 ka.

Journal of Geophysical Research↗

USGS1999

Diagenesis of lower Cretaceous pelagic carbonates, North Atlantic: Paleoceanographic signals obscured

The stable isotope and minor element geochemistry of Neocomian (Lower Cretaceous) pelagic carbonates of the North Atlantic Basin (Deep Sea Drilling Project Sites 105, 367, 387, 391, and 603) was examined to develop a diagenetic model for pelagic limestones. In particular, we hoped to test the fidelity of whole-rock geochemical records as paleoceanographic indicators for pelagic deposits of pre-Aptian age, in which individual microfossils are not available for analysis. Data indicate that in addition to depth of burial, rhythmic variations in primary carbonate content have strongly controlled diagenetic patterns and associated geochemical signatures in these Neocomian sequences. Samples become increasingly depleted in Sr and 18O with increasing CaCO3 content. Within individual sedimentary sections, substantial decreases in Sr/Ca ratios and ??18O values are evident over a range of 4 to 98% CaCO3. However, even over a relatively narrow range of 50 to 98% CaCO3 a 2.5%c variation in ??18O values and a change of a factor of 1.7 in Sr/Ca ratios are observed. Carbon isotope compositions do not vary as extensively with CaCO3 content, but carbonate-rich intervals tend to be relatively depleted in 13C. Petrographic analysis reveals that these geochemical patterns are related to the transfer of CaCO3 from carbonate-poor intervals (calcareous shales and marlstones) to adjacent carbonate-rich intervals (limestones) during burial compaction and pressure solution. This process results in the addition of diagenetic cement to carbonate-rich intervals to produce a bulk composition that is relatively depleted in Sr and 18O and, at the same time, enables the retention of more-or-less primary carbonate that is relatively enriched in Sr and 18O in adjacent carbonate-poor intervals. Thus, although cyclic variations in CaCO3 content are primary in the Neocomian sequences examined, measured variations in Sr/Ca ratios and ??18O values are not and, as such, do not provide reliable proxies for past variations in climate, oceanographic conditions, or global ice volume.

Journal of Foraminiferal Research↗

USGS2012

Use of ASTER and MODIS thermal infrared data to quantify heat flow and hydrothermal change at Yellowstone National Park

The overarching aim of this study was to use satellite thermal infrared (TIR) remote sensing to monitor geothermal activity within the Yellowstone geothermal area to meet the missions of both the U.S. Geological Survey and the Yellowstone National Park Geology Program. Specific goals were to: 1) address the challenges of monitoring the surface thermal characteristics of the > 10,000 spatially and temporally dynamic thermal features in the Park (including hot springs, pools, geysers, fumaroles, and mud pots) that are spread out over ~ 5000 km 2 , by using satellite TIR remote sensing tools (e.g., ASTER and MODIS), 2) to estimate the radiant geothermal heat flux (GHF) for Yellowstone's thermal areas, and 3) to identify normal, background thermal changes so that significant, abnormal changes can be recognized, should they ever occur (e.g., changes related to tectonic, hydrothermal, impending volcanic processes, or human activities, such as nearby geothermal development). ASTER TIR data (90-m pixels) were used to estimate the radiant GHF from all of Yellowstone's thermal features and update maps of thermal areas. MODIS TIR data (1-km pixels) were used to record background thermal radiance variations from March 2000 through December 2010 and establish thermal change detection limits. A lower limit for the radiant GHF estimated from ASTER TIR temperature data was established at ~ 2.0 GW, which is ~ 30–45% of the heat flux estimated through geochemical thermometry. Also, about 5 km 2 of thermal areas was added to the geodatabase of mapped thermal areas. A decade-long time-series of MODIS TIR radiance data was dominated by seasonal cycles. A background subtraction technique was used in an attempt to isolate variations due to geothermal changes. Several statistically significant perturbations were noted in the time-series from Norris Geyser Basin, however many of these did not correspond to documented thermal disturbances. This study provides concrete examples of the strengths and limitations of current satellite TIR monitoring of geothermal areas, highlighting some specific areas that can be improved. This work provides a framework for future satellite-based thermal monitoring at Yellowstone and other volcanic and geothermal systems.

Idaho, Montana, Oregon, Wyoming↗

USGS2018

The timing and origin of pre- and post-caldera volcanism associated with the Mesa Falls Tuff, Yellowstone Plateau volcanic field

We present new sanidine 40 Ar/ 39 Ar ages and paleomagnetic data for pre- and post-caldera rhyolites from the second volcanic cycle of the Yellowstone Plateau volcanic field, which culminated in the caldera-forming eruption of the Mesa Falls Tuff at ca. 1.3 Ma. These data allow for a detailed reconstruction of the eruptive history of the second volcanic cycle and provide new insights into the petrogenesis of rhyolite domes and flows erupted during this time period. 40 Ar/ 39 Ar age data for the biotite-bearing Bishop Mountain flow demonstrate that it erupted approximately 150 kyr prior to the Mesa Falls Tuff. Integrating 40 Ar/ 39 Ar ages and paleomagnetic data for the post-caldera Island Park rhyolite domes suggests that these five crystal-rich rhyolites erupted over a centuries-long time interval at 1.2905 ± 0.0020 Ma (2σ). The biotite-bearing Moonshine Mountain rhyolite dome was originally thought to be the downfaulted vent dome for the pre-caldera Bishop Mountain flow due to their similar petrographic and oxygen isotope characteristics, but new 40 Ar/ 39 Ar dating suggest that it erupted near contemporaneously with the Island Park rhyolite domes at 1.2931 ± 0.0018 Ma (2σ) and is a post-caldera eruption. Despite their similar eruption ages, the Island Park rhyolite domes and the Moonshine Mountain dome are chemically and petrographically distinct and are not derived from the same source. Integrating these new data with field relations and existing geochemical data, we present a petrogenetic model for the formation of the post-Mesa Falls Tuff rhyolites. Renewed influx of basaltic and/or silicic recharge magma into the crust at 1.2905 ± 0.0020 Ma led to [1] the formation of the Island Park rhyolite domes from the source region that earlier produced the Mesa Falls Tuff and [2] the formation of Moonshine Mountain dome from the source region that earlier produced the biotite-bearing Bishop Mountain flow. These magmas were stored in the crust for less than a few thousand years before being erupted contemporaneously along a 30 km long, structurally controlled vent zone related to extracaldera Basin and Range faults. These data highlight the rapidity with which magma can be generated and erupted over large distances at Yellowstone.

Idaho, Wyoming↗

USGS1977

Exploration geochemical studies of some sandstone copper-uranium deposits, Bradford, Columbia, and Lycoming Counties, Pa

Semi-quantitative spectrographic analyses of mineralized and unmineralized sandstone, siltstone, and claystone from the Catskill Formation of Devonian age in Bradford, Columbia, and Lycoming Counties, Pa., suggest that copper, silver, and uranium are the principal metallic elements concentrated in the mineralized rock. Lead, mercury, and molybdenum may be concentrated slightly in mineralized rock but values are too low to be of use in exploration. The deposits are too small to make large anomalies in stream sediments except in drainage basins of less than a few acres. However, if a large deposit were exposed to weathering, it would probably be detectable by stream sediment sampling. Analyses of oxalic acid leachates of the minus 80-mesh fraction of the stream-sediment samples gave more useful values than analyses of the minus 80-mesh samples in separating drainage basins that have copper deposits from those that have no known copper deposits.

Pennsylvania↗

USGS2020

Oil-source rock correlation studies in the unconventional Upper Cretaceous Tuscaloosa marine shale (TMS) petroleum system, Mississippi and Louisiana, USA

The U.S. Geological Survey assessed undiscovered unconventional hydrocarbon resources reservoired in the Upper Cretaceous Tuscaloosa marine shale (TMS) of southern Mississippi and adjacent Louisiana in 2018. As part of the assessment, oil-source rock correlations were examined in the TMS play area where operators produce light (38–45° API), sweet oil from horizontal, hydraulically-fractured wells in an overpressured ‘high-resistivity’ (>5 Ω-m) zone at the base of the TMS. Geochemical data from 39 oil samples and 17 source rock solvent extracts collected from the TMS play area indicate close correspondence for Tuscaloosa Group oils [from lower Tuscaloosa, middle Tuscaloosa (the TMS) and upper Tuscaloosa reservoirs] in thermal maturity (computed from MPI), SARA proportions, n- alkane distributions, isoprenoid and DBT/P ratios, monoaromatic steroids, and δ 13 C isotopic compositions (from whole oils, saturate and aromatic fractions). Other parameters (normal steranes, extended homohopanes, C 31 R/C 30 hopane, norhopane/hopane and tricyclic terpane ratios, gammacerane/hopane) show most oil samples have similar values, suggesting all Tuscaloosa Group oils are from a common mixed marine-terrigenous source rock. Tighter distributions for triaromatic steroid (TAS) and δ 13 C isotopic composition for conventional oils in lower and upper Tuscaloosa reservoirs may indicate charge occurred in a single or shorter pulse relative to TMS oils which show broader TAS and δ 13 C properties, possibly from their generation over an extended period of burial maturation. Dissimilarity in geochemical properties between lower Tuscaloosa source rock solvent extracts and Tuscaloosa Group oils indicates lower Tuscaloosa source rocks did not contribute significantly to conventional and unconventional Tuscaloosa Group hydrocarbon accumulations. Whereas, TMS solvent extracts are similar to Tuscaloosa Group oils, suggesting an oil-source rock correlation. Excluding the possibility for long-distance lateral migration from a similar source downdip (which is unnecessary given thermal maturity considerations), the observations indicate 1. the TMS is a self-sourced reservoir, 2. the TMS is the source of oils accumulated in nearby conventional Tuscaloosa Group reservoirs, and 3. thin organic-rich shales in the lower Tuscaloosa did not contribute substantially to any oil accumulations in the Tuscaloosa Group.

Louisiana, Mississippi↗

USGS1974

Upward migration of deep-well waste injection fluids in Floridan Aquifer, south Florida

Geochemical data from an industrial deep-well waste injection system southeast of Lake Okeechobee indicate a decrease in sulfate concentration concomitant with an increase in hydrogen sulfide concentration, a result of oxidation of injected organic waste by anaerobic bacteria. Subtle decreases in the sulfate-chloride ratio suggest that the waste migrated upward to a shallow monitor well about 27 mo after waste injection began and again within 15 mo of the resumption of waste injection after the injection well was deepened. The possibility of a hydraulic connection between the injection zone and overlying monitoring zone is implied. The decrease in the sulfate-chloride ratio appears to be a sensitive indicator of waste migration. Potential conflicts exist in the use of the Floridan aquifer for waste disposal and subsequent use as a natural resource.

Florida↗

USGS2024

Reexamining the Honolulu Volcanics: Hawai‘i's classic case of rejuvenation volcanism

Rejuvenated volcanism is a worldwide phenomenon occurring on many oceanic islands in all of the major ocean basins. This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g. 0.6–2 Myrs in Hawai'i). The Honolulu Volcanics (HV), the classic case of rejuvenated volcanism, involved monogenetic eruptions from at least 48 vent areas. Previous studies inferred these vents were aligned along 3 to 11 rifts oriented orthogonal to the propagation direction of the Hawaiian plume. HV basalts are known for having high MgO contents (greater than 10 wt %) and upper mantle xenoliths. Thus, HV magmas are assumed to be relatively primitive and to have ascended rapidly (less than 1 day) through the crust. However, new analyses of olivine cores in basalts from 24 HV vents are mostly too low in forsterite content (74–86 mol %) to be in equilibrium with mantle melts. Olivine and clinopyroxene in HV basalts commonly show reverse zoning indicating magma mixing prior to eruption. These results are inconsistent with the rapid ascent of HV magmas directly from their mantle source. Many of the HV magmas underwent storage (probably in the lower crust or uppermost mantle), crystal fractionation and magma mixing prior to eruption. New 40 Ar/ 39 Ar dates were determined for 11 HV lavas to evaluate their eruptive history. These ages, 80 to 685 ka, combined with our previous and other 40 Ar/ 39 Ar ages for HV lavas reveal long gaps (greater than 50 kyr) between some eruptions. Our comprehensive, whole-rock major and trace element database (63 XRF analyses, 57 ICPMS analyses) of basalts from 37 vents show remarkable compositional diversity with no obvious spatial pattern or temporal trends. The two most recent eruptive sequences have the greatest diversity (basanite and melilitite compositions). HV basanites show systematic trace element trends that may reflect mixing of multiple source components. The nephelinites and melilitites require a complex source history that may have involved residual accessory minerals during mantle melting and a metasomatic component that was not carbonatitic. The new ages and geochemical data show eruptions along most of the previously proposed rift systems were unrelated (except for the Koko Rift). Therefore, geodynamic models that relate HV volcanism to these rift systems are invalid. Lava volumes for two HV eruptions were estimated at 0.11 and 0.23 km 3 using surface mapping and water well data. Similar size, recent monogenetic eruptions in Auckland, New Zealand, were inferred to have lasted several months. Thus, if another HV eruption were to occur, which is possible given the long hiatus between eruptions, it would be extremely disruptive for the nearly 1 million residents of Honolulu. None of the existing geodynamic models fully explain the age duration, volumes and the locations of Hawai'i's rejuvenated volcanism. Thus, the cause of this secondary volcanism remains enigmatic.

Hawaii↗

USGS1996

Origin of Bermuda's clay-rich Quaternary paleosols and their paleoclimatic significance

Red clayey paleosols that are chiefly the product of aerosolic dust deposition are interbedded in the Quaternary carbonate formations of the Bermuda oceanic island system. These paleosols provide a basis for reconstructing Quaternary atmospheric circulation patterns in the northwestern Atlantic. Geochemical analyses were performed on representative paleosol samples to identify their parent dust source. Fine-grained fractions were analyzed by energy-dispersive X ray fluorescence to determine trace element (Zr, Y, La, Ti, and Nb) concentrations and to derive geochemical signatures based on immobile element ratios. These ratios were compared with geochemical signatures determined for three possible sources of airborne dust: (1) Great Plains loess, (2) Mississippi River Valley loess, and (3) Saharan dust. The Zr/Y and Zr/La ratios provided the clearest distinction between the hypothesized dust sources. The low ratios in the paleosol B horizons most closely resemble Saharan dust in the <2-μm size class fraction. Contributions from the two North American loessial source areas could not be clearly detected. Thus Bermuda paleosols have a predominantly Saharan aerosolic dust signature. Saharan dust deposition on Bermuda during successive Quaternary glacial periods is consistent with patterns of general circulation models, which indicate that during glacial maxima the northeast summer trade winds were stronger than at present and reached latitudes higher than 30°N despite lower-than-present sea surface temperatures in the North Atlantic.

Journal of Geophysical Research D: Atmospheres↗

USGS2026

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin↗