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Use case development for earth monitoring, analysis, and prediction (EarthMAP)—A road map for future integrated predictive science at the U.S. Geological Survey

Executive Summary The U.S. Geological Survey (USGS) 21st-century science strategy 2020–30 promotes a bureau-wide strategy to develop and deliver an integrated, predictive science capability that works at the scales and timelines needed to inform societally relevant resource management and protection and public safety and environmental health decisions (U.S. Geological Survey, 2021). This is the overarching goal of the USGS Earth Monitoring, Analysis, and Prediction (EarthMAP) vision, which consists of three components: (1) integrated data and information, (2) integrated predictive science, and (3) actionable information—all designed and delivered to respond to user needs. To launch this vision and help shape the design and implementation of integrated predictive science, the USGS Regional Offices each developed a set of use cases (hereafter Use Cases)—short descriptions of potential science applications that could clearly address high priority decision-making needs of our stakeholders and that align with an integrated science focus. Use Cases are not actionable science planning documents, nor stand-alone scholarly works, but should be considered as innovative, next-generation science ideas that can be considered as potential components of science plans still under development. The goal of Use Case development was to (1) identify and characterize existing USGS scientific capacities and expertise that can support science goals and products, (2) identify opportunities to leverage current capacities for next-generation science, and (3) foster engagement across the entire Bureau to further refine the USGS strategy for EarthMAP and integrated predictive science. The Use Case development effort documented in this report was coordinated by the Use Case Development Team (UCDT), consisting of representatives from each region. The UCDT undertook five tasks: (1) develop a unified approach to engage bureau scientists consistently across all regions in aspirational thinking about what can be accomplished; (2) work with the regions and their Science Centers to generate an initial set of Use Cases, authored directly by scientists; (3) characterize, summarize, and document the initial set of Use Case submissions from authors to illuminate bureau-level demand for integrated science; (4) compare existing and needed capacities from the Use Case descriptions with preliminary results of the EarthMAP Capacity Assessment (Keisman and others, 2021); and (5) describe lessons learned from the Use Case development process and provide recommendations to inform future efforts to generate integrated science activities. This report outlines the approach the UCDT developed to solicit Use Cases from the regions and summarizes the high-level qualitative findings from this first-round effort. The UCDT received 36 Use Cases from the regions and identified potential points of convergence and commonalities considered useful in making connections among the participating scientists. The Southwest (SW) Region and the Rocky Mountain (RM) Region asked scientists to give special consideration to Use Cases with applicability to the Colorado River Basin, and seven of the Use Cases specifically named that geographic area as a focus. Coastal hazards and coastal resilience were identified in Use Cases from the Alaska (AK), Northeast (NE), and Southeast (SE) Regions. Aspects of wildfire and post-wildfire response were part of Uses Cases from AK, RM, and SW Regions. The greatest convergence of Use Case themes was related to conservation of public lands and waters, which is a powerful linkage lending strength to future collaborative efforts. The most common type of stakeholder decisions that would be informed by the Use Case science applications were related to adaptation, mitigation, and response (for example, how to increase the resilience of coastal communities to climate-related stressors and how to prevent or respond to harmful algal blooms). Other common types of decisions included water and land management decisions (including operational water management decisions such as reservoir operations and land use planning in the sagebrush biome), decisions about how to manage and conserve habitats and species, and risk management decisions (such as managing the post-wildfire flood risks). These decision types are not exclusive because many Use Cases cross categories. Use Case authors identified existing and needed science and technology capabilities required for Use Case implementation, which were then aligned to capabilities assessed in the EarthMAP Capacity Assessment (Keisman and others, 2021). Strong alignment was found for data and information integration approaches, modeling and prediction approaches, and capabilities related to delivery of actionable information. A majority of Use Cases indicated insufficient current capacity for needed data collection methods, data integration, and modeling and prediction approaches, whereas only 25 percent indicated insufficient capacity for actionable information delivery. Overall, many Use Case capacity demand gaps could potentially be met by existing bureau-wide capacity. In addition, nearly half of the Use Cases could potentially be implemented within 3 years if funding, capabilities, and personnel impediments were removed and science priorities were realigned. Several challenges emerged during the Use Case development process. The first challenge was developing an approach that was flexible enough to accommodate regional differences in planning and implementation, while also ensuring enough guidance to promote meaningful summary analyses. The UCDT encountered a strong demand for continuous communication and education to improve overall understanding of the integrated predictive science strategy. Another challenge was managing expectations about EarthMAP activities as a design effort that was not aligned to an immediate funding opportunity. Connecting the Use Cases to stakeholder needs without the opportunity for direct stakeholder engagement was also challenging. The last notable challenge was in obtaining consistent interpretation and characterization of the qualitative data housed in the narrative descriptions of Use Cases, written in different styles. Overall, the 36 Use Cases can serve as components of a road map for advancing integrated monitoring and predictive science throughout the USGS by revealing opportunities to (1) encourage cross-region initiatives that address shared interests in common themes by integrating similar Use Cases and through direct involvement of stakeholders in identifying needs and designing effective responses, (2) leverage the Use Cases to target investments that are aligned with the Bureau and Department of the Interior (DOI) priorities, (3) connect Use Cases and the results of the companion EarthMAP Capacity Assessment (Keisman and others, 2021) to identify potential priorities for capacity building investments, and (4) raise awareness of common integrated and interdisciplinary science interests within and across the regions through Use Case and Capacity Assessment summary outreach activities.

Open-File Report

Groundwater quality data in 15 GAMA study units: results from the 2006–10 Initial sampling and the 2009–13 resampling of wells, California GAMA Priority Basin Project

The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). From May 2004 to March 2012, the GAMA-PBP collected samples from more than 2,300 wells in 35 study units across the State. Selected wells in each study unit were sampled again approximately 3 years after initial sampling as part of an assessment of temporal trends in water quality by the GAMA-PBP. This triennial (every 3 years) trend sampling of GAMA-PBP study units concluded in December 2013. Fifteen of the study units, initially sampled between January 2006 and June 2010 and sampled a second time between April 2009 and April 2013 to assess temporal trends, are the subject of this report. The initial sampling was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies in the 15 study units. In these study units, 730 wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the areas assessed (grid wells, also called “status wells”). Approximately 3 years after the initial sampling, 93 of the previously sampled status wells (approximately 10 percent in each study unit) were randomly selected for trend sampling (“trend wells”). The 15 study units sampled for trends were distributed among 4 hydrogeologic provinces: Central Valley, Basin and Range, Desert, and Transverse and selected Peninsular Ranges. The total number of status wells sampled, along with those sampled again for trends, varied by study unit. In the Central Valley hydrogeologic province, the numbers of status wells and trend wells in each study unit were as follows: Kern County subbasin study unit—47 status wells, 5 trend wells Central Eastside San Joaquin Basin study unit—58 status wells, 6 trend wells Middle Sacramento Valley study unit—71 status wells, 8 trend wells Northern Sacramento Valley study unit—43 status wells, 4 trend wells Madera–Chowchilla study unit—30 status wells, 4 trend wells Western San Joaquin Valley study unit—39 status wells, 4 trend wells. The Basin and Range hydrogeologic province had only one study unit: Owens and Indian Wells Valleys study unit—53 status wells, 6 trend wells. In the Desert hydrogeologic province, the numbers of wells were as follows: Coachella Valley study unit—19 status wells 4 trend wells Colorado River study unit—20 status wells, 3 trend wells Antelope Valley study unit—56 status wells, 6 trend wells Mojave study unit—52 status wells, 7 trend wells Borrego Valley, Central Desert and Low-Use Basins of the Mojave and Sonoran Deserts study unit—49 status wells, 6 trend wells. In the Transverse and Selected Peninsular Ranges hydrogeologic province, the numbers of wells were as follows: Coastal Los Angeles Basin study unit—61 status wells, 8 trend wells Upper Santa Ana Watershed study unit—90 status wells, 16 trend wells Santa Clara River Valley study unit—42 status wells, 6 trend wells. The groundwater samples were analyzed for a number of synthetic organic constituents (volatile organic compounds, pesticides, and pesticide degradates), constituents of special interest (perchlorate, N -nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements). Naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) also were measured to help identify processes affecting groundwater quality and the sources and ages of the sampled groundwater. More than 200 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, or samples for matrix spikes) were collected at 34 percent of the trend wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. On the basis of detections in laboratory and field blanks in samples from GAMA-PBP study units, including the study units presented here, some groundwater results were adjusted in this report. Differences between replicate samples were mostly within acceptable ranges, indicating acceptably low variability in analytical results. Median matrix-spike recoveries were within the acceptable range (70 to 130 percent) for 189 of the 224 compounds for which matrix spikes were analyzed (84 percent). This study did not attempt to evaluate the quality of water delivered to consumers. After withdrawal, groundwater used for drinking water typically is treated, disinfected, and blended with other waters to attain acceptable water quality. The benchmarks used in this report apply to treated water that is served to the consumer, not to untreated groundwater. To provide some context for the results, however, concentrations of constituents measured in these groundwater samples were compared with benchmarks established by the U.S. Environmental Protection Agency and California Department of Public Health. Comparisons between data collected for this study and benchmarks for drinking-water quality are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most constituents that were detected in groundwater samples from the trend wells were found at concentrations less than drinking-water benchmarks. Two volatile organic compounds (VOCs)—tetrachloroethene and trichloroethene—were detected in samples from one or more wells at concentrations greater than their health-based benchmarks, and three VOCs—chloroform, tetrachloroethene, and trichloroethene—were detected in at least 10 percent of the trend-well samples from the initial sampling period and the later trend sampling period. No pesticides were detected at concentrations near or greater than their health-based benchmarks. Three pesticide constituents—atrazine, deethylatrazine, and simazine—were detected in more than 10 percent of the trend-well samples in both sampling periods. Perchlorate, a constituent of special interest, was detected at a concentration greater than its health-based benchmark in samples from one trend well in the initial sampling and trend sampling periods, and in an additional trend well sample only in the trend sampling period. Most detections of nutrients, major and minor ions, and trace elements in samples from trend wells were less than health-based benchmarks in both sampling periods. Exceptions included nitrate, fluoride, arsenic, boron, molybdenum, strontium, and uranium; these were all detected at concentrations greater than their health-based benchmarks in at least one well sample in both sampling periods. Lead and vanadium were detected above their health-based benchmarks in one sample each collected in the initial sampling period only. The isotopic ratios of oxygen and hydrogen in water and the activities of tritium and carbon-14 generally changed little between sampling periods.

California

Geology and underground waters of the Arkansas Valley in eastern Colorado

In the valley of Arkansas River in southeastern Colorado there is an area of considerable extent in which artesian flows are available. During the last ten years numerous wells have been sunk to develop this important resource and, in most cases in the lower lands, abundant water supplies have been obtained. The principal water-bearing bed is the "Dakota" formation, which consists of two sheets of porous sandstone separated by a small body of clay and overlain in the greater portion of the area by a mass of impervious shales. The sandstones receive their waters from, rainfall and from the sinking of streams along the foothills of the Rocky Mountains and on some of the higher slopes south of the Arkansas Valley. In the passage of this sandstone underground, the waters which it contains are held down by the overlying shales, but, as some of the sandstone outcrops are at relatively low levels to the east only a moderate head or pressure is sustained. On account of this low head, artesian flows are available only in the lower lands, and one of the principal objects of this investigation has been the determination of the area in which flows are to be expected. The "Dakota" sandstone and associated formations do not lie level, or even slope regularly to the east, but are flexed into low arches and shallow troughs of considerable complexity of configuration. Accordingly, in investigating this source of water supply, it has been necessary to ascertain the structure and distribution of the various formations in order to indicate the variations in depth to the water-bearing stratum. The principal results of these investigations are set forth: (1) In the geologic map (Pl. VI), which shows the distribution of the formations on the surface; (2) in the map, Pl. XXV, which shows the depth to the water-bearing horizon, the area in which flows are expected, the head of the underground waters, and other features, and (3) in the cross sections (Pls. VII and XXIII), which show the principal underground features. The investigation has been in progress for several years and is an extension of the preliminary examination of the region by G. K. Gilbert in 1894 and 1895. For the western portion of the area the maps and texts of the Pueblo, Elmoro, Walsenburg, Spanish Peaks, and Pikes Peak folios have been utilized as far as practicable. For the central and eastern portions the larger features of the geology have been specially mapped, and considerable detailed mapping has been done in the region south and southeast of Canyon and Colorado Springs. In the field work I have been assisted by Mr. C. A. Fisher, who has examined in detail the Nepesta quadrangle and contributed numerous other data. Dr. W. S. Tangier Smith and Messrs. C. E. Sicbenthal and W. T. Lee have made observations in certain areas. Much valuable information respecting wells has been furnished by Mr. William Archer, of the Atchison, Topeka and Santa Fe Railway Company, and Mr. C. H. McVay, well driller at Rocky Ford.

Colorado

Status and understanding of groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit, 2017—California GAMA Priority Basin Project

Groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit (SacMetro-DSA) was studied from August to November 2017 as part of the second phase of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in parts of Amador, Placer, Sacramento, and Sutter Counties, and the extent of the study unit was defined by the location of three California Department of Water Resources groundwater subbasins: the North American, the South American, and the Cosumnes. The SacMetro-DSA focused on groundwater resources used for domestic drinking-water supply, which generally correspond to shallower parts of aquifer systems than those of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included two components: (1) a status assessment, which characterized the status of the quality of the groundwater resources used for domestic supply and (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources. The first component of this study—the status assessment—was based on water-quality data collected from 49 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2017. The samples were analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that had concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, groundwater age, and geochemical and hydrologic conditions of the domestic-supply aquifer and related these data to constituents identified in the status assessment for further evaluation. In the SacMetro-DSA study unit, arsenic was the only inorganic constituent detected above health-based benchmarks and was detected in 10 percent of the domestic-supply aquifer system. Inorganic constituents were detected above the non-health-based California State Water Resources Control Board—Division of Drinking Water secondary maximum contaminant levels (SMCL-CA) in 16 percent of the system. The inorganic constituents detected above the SMCL-CA were chloride, iron, manganese, and total dissolved solids (TDS). Organic constituents (volatile organic compounds and pesticides) with health-based benchmarks were not detected above health-based benchmarks; however, chloroform was detected at concentrations higher than 10 percent of the health-based benchmark (80 micrograms per liter) in 2 percent of the domestic-supply aquifer system. Of the 310 organic constituents analyzed, 16 constituents were detected; however, only bentazon and chloroform had detection frequencies greater than 10 percent. Inorganic constituents with health-based benchmarks that were evaluated in the understanding assessment included arsenic and hexavalent chromium. Arsenic and hexavalent chromium are natural constituents of aquifer sediments in the study unit and did not appear to be influenced by anthropogenic processes; rather, the presence of arsenic and hexavalent chromium appeared to be related to geochemical conditions controlled by oxidation–reduction reactions in the aquifer system. Naturally occurring inorganic constituents with SMCL-CAs evaluated in the understanding assessment were the trace elements iron and manganese, the major ion chloride, and TDS. Like arsenic and hexavalent chromium, the presence of iron and manganese was most strongly related to geochemical conditions in the aquifer system, specifically reducing conditions, which were most common near the western edge of the study unit close to the Sacramento River. Concentrations of chloride and TDS are indicators of salinity and were correlated with variables related to well location and included redox, agricultural land use, and elevation. Chloride and TDS were positively correlated to reducing conditions, and agricultural land use was negatively correlated to elevation and well depth. Observed correlations among variables were likely driven by the characteristics of the western part of the study unit, such as its higher proportion of agricultural land use and its relatively low elevation. A large portion of the western edge of the study unit is located in the center of the Sacramento Valley, defined by the location of the Sacramento River. The special-interest constituent perchlorate, also included in the understanding assessment, has natural and anthropogenic sources. Perchlorate was detected frequently and at moderate relative concentrations. In some areas of the study unit, concentrations of perchlorate were higher than what might be expected in nature; therefore, anthropogenic introduction of perchlorate or anthropogenically induced migration of native perchlorate could be occurring.

California

Establishing links between streamflow and ecological integrity in the Sudbury River (Northeastern U.S.)

With increased pressure from a growing human population, managers are challenged to understand how novel disturbances (e.g., climate change, increased water withdrawals, urbanization) may affect natural resources. The Sudbury River is a National Wild and Scenic River located in suburban Boston, Massachusetts (Northeastern US) with myriad impairments (e.g., mainstem impoundments, withdrawals, and urbanization) that is under increasing pressure from hydrologic alteration. We sampled fish, mussel, and macroinvertebrate assemblages in the Sudbury River and used species traits to investigate potential effects of past and future flow alteration on biota. Analysis of 33 years of stream gage data indicates continued hydrologic alteration of the Sudbury River, likely related to increased urbanization and water withdrawals over that time. These changes include a roughly 200% increase in rise rates of flows, an approximate 65% decrease in 1-day minimum flows, and a trend towards increasing high flow pulse counts. Biotic sampling in summer of 2014 demonstrated that the Sudbury River is now dominated by generalist species. Of five mussel species sampled, all are generalists in their habitat requirements. Though one mussel species of special concern was sampled, the most abundant species collected were the widespread Eastern elliptio (58%) and Eastern lampmussel (40%). We used the target fish community (TFC) model to assess the degree to which the fish assemblage deviated from that expected for a river with similar zoogeographic and physical features. Overall, the current community has a 22.7% similarity to the TFC. Of the four fluvial specialist species present in the TFC, only fallfish was sampled in our study. While the TFC showed that the historical assemblage was likely dominated by fluvial specialist and fluvial dependent species, the current assemblage is overwhelmingly dominated by macrohabitat generalists (90.6% of fishes sampled). These results are consistent with other studies that show shifts in assemblages from fluvial specialists to habitat generalists with hydrologic alteration. If the current trends continue, it is likely that biotic assemblages will experience increasing pressure from hydrologic alteration. While hydrologic alteration is likely impacting biotic assemblages in the Sudbury River, other factors such as high temperatures, low dissolved oxygen, high nutrients, low availability of high-quality habitat, and poor habitat connectivity may also be negatively impacting biotic assemblages. Comparisons to other rivers and a complete longitudinal habitat survey could help to identify availability of unique habitats and representativeness of this study. While this study suggests impacts of flow on biota, future studies with quantitative, habitat-specific sampling during different flow levels could help to directly identify links between hydrologic alteration and biotic impairment in the Sudbury River.

Massachussetts

Ground-water quality data in the Southern Sierra study unit, 2006— Results from the California GAMA program

Ground-water quality in the approximately 1,800 square-mile Southern Sierra study unit (SOSA) was investigated in June 2006 as part of the Statewide Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Southern Sierra study was designed to provide a spatially unbiased assessment of raw ground-water quality within SOSA, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from fifty wells in Kern and Tulare Counties. Thirty-five of the wells were selected using a randomized grid-based method to provide statistical representation of the study area, and fifteen were selected to evaluate changes in water chemistry along ground-water flow paths. The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, pharmaceutical compounds, and wastewater-indicator compounds], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3-trichloropropane (1,2,3-TCP)], naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen and oxygen in water], and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected for approximately one-eighth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information resulted in censoring of less than 0.2 percent of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs and pesticides were detected in less than one-third of the grid wells, and all detections in samples from SOSA wells were below health-based thresholds. All detections of trace elements and nutrients in samples from SOSA wells were below health-based thresholds, with the exception of four detections of arsenic that were above the USEPA maximum contaminant level (MCL-US) and one detection of boron that was above the CDPH notification level (NL-CA). All detections of radioactive constituents were below health-based thresholds, although four samples had activities of radon-222 above the proposed MCL-US. Most of the samples from SOSA wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. A few samples contained iron, manganese, or total dissolved solids at concentrations above the SMCL-CA thresholds.

California

Ground-water quality data in the Central Sierra study unit, 2006— Results from the California GAMA Program

Ground-water quality in the approximately 950 square kilometer (370 square mile) Central Sierra study unit (CENSIE) was investigated in May 2006 as part of the Priority Basin Assessment project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). This study was designed to provide a spatially unbiased assessment of the quality of raw ground water used for drinking-water supplies within CENSIE, and to facilitate statistically consistent comparisons of ground-water quality throughout California. Samples were collected from thirty wells in Madera County. Twenty-seven of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and three were selected to aid in evaluation of specific water-quality issues (understanding wells). Ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], gasoline oxygenates and degradates, pesticides and pesticide degradates), constituents of special interest (N-nitrosodimethylamine, perchlorate, and 1,2,3-trichloropropane), naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon], and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. In total, over 250 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-sixth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Results from field blanks indicated contamination was not a noticeable source of bias in the data for ground-water samples. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most constituents. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), and thresholds established for aesthetic concerns (Secondary Maximum Contaminant Levels, SMCL-CA) by CDPH. Therefore, any comparisons of the results of this study to drinking-water standards only is for illustrative purposes and is not indicative of compliance or non-compliance to those standards. Most constituents that were detected in ground-water samples were found at concentrations below drinking-water standards or thresholds. Six constituents? fluoride, arsenic, molybdenum, uranium, gross-alpha radioactivity, and radon-222?were detected at concentrations higher than thresholds set for health-based regulatory purposes. Three additional constituents?pH, iron and manganese?were detected at concentrations above thresholds set for aesthetic concerns. Volatile organic compounds (VOCs) and pesticides, were detected in less than one-third of the samples and generally at less than one one-hundredth of a health-based threshold.

California

Ground-water quality data in the Owens and Indian Wells Valleys study unit, 2006: Results from the California GAMA Program

Ground-water quality in the approximately 1,630 square-mile Owens and Indian Wells Valleys study unit (OWENS) was investigated in September-December 2006 as part of the Priority Basin Project of Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board (SWRCB). The Owens and Indian Wells Valleys study was designed to provide a spatially unbiased assessment of raw ground-water quality within OWENS study unit, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 74 wells in Inyo, Kern, Mono, and San Bernardino Counties. Fifty-three of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 21 wells were selected to evaluate changes in water chemistry in areas of interest (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater- indicator compounds], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3- trichloropropane (1,2,3-TCP)], naturally occurring inorganic constituents [nutrients, major and minor ions, and trace elements], radioactive constituents, and microbial indicators. Naturally occurring isotopes [tritium, and carbon-14, and stable isotopes of hydrogen and oxygen in water], and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. This study evaluated the quality of raw ground water in the aquifer in the OWENS study unit and did not attempt to evaluate the quality of treated water delivered to consumers. Water supplied to consumers typically is treated after withdrawal from the ground, disinfected, and blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and non-regulatory thresholds established for aesthetic concerns (secondary maximum contamination levels, SMCL-CA) by CDPH. VOCs and pesticides were detected in samples from less than one-third of the grid wells; all detections were below health-based thresholds, and most were less than one-one hundredth of threshold values. All detections of perchlorate and nutrients in samples from OWENS were below health-based thresholds. Most detections of trace elements in ground-water samples from OWENS wells were below health-based thresholds. In samples from the 53 grid wells, three constituents were detected at concentrations above USEPA maximum contaminant levels: arsenic in 5 samples, uranium in 4 samples, and fluoride in 1 sample. Two constituents were detected at concentrations above CDPH notification levels (boron in 9 samples and vanadium in 1 sample), and two were above USEPA lifetime health advisory levels (molybdenum in 3 samples and strontium in 1 sample). Most of the samples from OWENS wells had concentrations of major elements, TDS, and trace elements below the non-enforceable standards set for aesthetic concerns. Samples from nine grid wells had concentrations of manganese, iron, or TDS above the SMCL-CAs.

California

Ground-water quality data in the coastal Los Angeles Basin study unit, 2006: Results from the California GAMA Program

Ground-water quality in the approximately 860 square-mile Coastal Los Angeles Basin study unit (CLAB) was investigated from June to November of 2006 as part of the Statewide Basin Assessment Project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment was developed in response to the Ground-Water Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Coastal Los Angeles Basin study was designed to provide a spatially unbiased assessment of raw ground-water quality within CLAB, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 69 wells in Los Angeles and Orange Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (?grid wells?). Fourteen additional wells were selected to evaluate changes in ground-water chemistry or to gain a greater understanding of the ground-water quality within a specific portion of the Coastal Los Angeles Basin study unit ('understanding wells'). Ground-water samples were analyzed for: a large number of synthetic organic constituents [volatile organic compounds (VOCs), gasoline oxygenates and their degradates, pesticides, polar pesticides, and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicators]; constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), 1,4-dioxane, and 1,2,3-trichloropropane (1,2,3-TCP)]; inorganic constituents that can occur naturally [nutrients, major and minor ions, and trace elements]; radioactive constituents [gross-alpha and gross-beta radiation, radium isotopes, and radon-222]; and microbial indicators. Naturally occurring isotopes [stable isotopic ratios of hydrogen and oxygen, and activities of tritium and carbon-14] and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. Quality-control samples (blanks, replicates, and samples for matrix spikes) were collected at approximately one-fourth of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a significant source of bias. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most compounds. Assessment of the quality-control information resulted in applying ?V? codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds are applied to the treated drinking water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA), California Department of Public Health (CDPH, formerly California Department of Health Services [CADHS]) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only, and are not indicative of compliance or non-compliance with those thresholds. VOCs were detected in alm

California

Ground-Water Quality Data in the Upper Santa Ana Watershed Study Unit, November 2006-March 2007: Results from the California GAMA Program

Ground-water quality in the approximately 1,000-square-mile Upper Santa Ana Watershed study unit (USAW) was investigated from November 2006 through March 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Upper Santa Ana Watershed study was designed to provide a spatially unbiased assessment of raw ground-water quality within USAW, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 99 wells in Riverside and San Bernardino Counties. Ninety of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Nine wells were selected to provide additional understanding of specific water-quality issues identified within the basin (understanding wells). The ground-water samples were analyzed for a large number of organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], 1,4-dioxane, and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) and dissolved noble gases also were measured to help identify sources and ages of the sampled ground water. Dissolved gases, and isotopes of nitrogen gas and of dissolved nitrate also were measured in order to investigate the sources and occurrence of nitrate in the study unit. In total, nearly 400 constituents and water-quality indicators were investigated for this study. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Volatile organic compounds (VOCs) were detected in more than 80 percent of USAW grid wells. Most VOCs detected were at concentrations far less than thresholds established for drinking water to protect human health; however, six wells had VOC concentrations above health-based thresholds. Twenty-four of the 85 VOCs investigated were detected in the study unit;11 were detected in more than 10 percent of the wells. The VOCs detected above health-based thresholds in at least one well were dibromochloropropane (DBCP), tetrachloroethene (PCE), trichloroethene (TCE), carbon tetrachloride, and 1,1-dichoroethene. Pesticide compounds were detected in more than 75 percent of the grid wells. However, of the 134 different pesticide compounds investigated, 13 were detected at concentrations greater than their respective long-term method detection limits, and only 7 compounds (all herbicides or herbicide degradates) were detected in more than 10 percent of the wells. No pesticide compound was detected above its health-based threshold, although thresholds exist for fewer than half of the pesticide compounds investigat

Data Series

Arsenic and selenium in soils and shallow ground water in the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas of the Garrison Diversion Unit, North Dakota

The Garrison Diversion Unit project was authorized as part of the Pick-Sloan Missouri River Basin program to divert water from Lake Sakakawea to irrigation areas in North Dakota. A special Garrison Commission was created to evaluate an environmental concern that return flow from the irrigation areas might contain metals in toxic concentrations. This report summarizes the results of detailed investigations of the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas. A total of 223 soil samples were collected from the irrigation areas and analyzed for elemental composition. Water extractions were done on 40 of the 223 soil samples using a 1:5 soil-to-water extraction method, and the solution from the extraction was analyzed for elemental composition. A total of 52 ground-water samples were collected and analyzed for inorganic constituents and organic carbon. Average arsenic concentrations in the entire soil column ranged from 1.0 milligram per kilogram in the Harvey Pumping irrigation area to 70 milligrams per kilogram in the New Rockford irrigation area. Average selenium concentrations ranged from less than 0.1 milligram per kilogram in the Turtle Lake, New Rockford, Harvey Pumping, and Lincoln Valley irrigation areas to 6.0 milligrams per kilogram in the Turtle Lake irrigation area. In the Turtle Lake irrigation area, average arsenic and selenium concentrations generally increased with depth through the topsoil, oxidized soil, and transition soil but decreased in the reduced soil at the bottom of the sampled horizons. Average arsenic concentrations in the New Rockford irrigation area follow the same pattern as in the Turtle Lake irrigation area, but selenium concentrations do not show a clear pattern of variation with depth. In the Harvey Pumping and Lincoln Valley irrigation areas, arsenic and selenium concentrations do not appear to vary systematically with depth. No correlation is shown between the concentrations in soils and soil extracts, indicating that, based on conditions of laboratory soil-water extraction experiments, trace-element concentrations in soils are not good predictors of trace-element concentrations in irrigation return flow. Arsenic concentrations in the aquifers ranged from less than 1 microgram per liter to 27 micrograms per liter. Arsenic concentrations generally were larger in the deep part of the aquifers underlying the Turtle Lake and New Rockford irrigation areas than in the shallow part of the aquifers. In the shallow part of the aquifers, where oxidizing conditions prevail, arsenic is strongly adsorbed to soil particles. In the deep part of the aquifers, where reducing conditions prevail, arsenic is more mobile. Selenium concentrations in the aquifers ranged from less than 1 microgram per liter to 4 micrograms per liter. Little difference existed between the selenium concentrations in the shallow part of the aquifers underlying the irrigation areas and the concentrations in the deep part of the aquifers.

Water-Resources Investigations Report

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report

Ground-Water Quality Data in the Coachella Valley Study Unit, 2007: Results from the California GAMA Program

Ground-water quality in the approximately 820 square-mile Coachella Valley Study Unit (COA) was investigated during February and March 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground water used for public-water supplies within the Coachella Valley, and to facilitate statistically consistent comparisons of ground-water quality throughout California. Samples were collected from 35 wells in Riverside County. Nineteen of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Sixteen additional wells were sampled to evaluate changes in water chemistry along selected ground-water flow paths, examine land use effects on ground-water quality, and to collect water-quality data in areas where little exists. These wells were referred to as 'understanding wells'. The ground-water samples were analyzed for a large number of organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (uranium, tritium, carbon-14, and stable isotopes of hydrogen, oxygen, and boron), and dissolved noble gases (the last in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled ground water. A quality-control sample (blank, replicate, or matrix spike) was collected at approximately one quarter of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information resulted in V-coding less than 0.1 percent of the data collected. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is supplied to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and thresholds established for aesthetic purposes (secondary maximum contaminant levels, SMCL-CA) by CDPH. Most constituents detected in ground-water samples were at concentrations below drinking-water thresholds. Volatile organic compounds, pesticides, and pesticide degradates were detected in less than one-third of the grid well samples collected. All VOC and pesticide concentrations measured were below health-based thresholds. Potential waste-water indicators were detected in less than half of the wells sampled, and no detections were above health-based thresholds. Perchlorate was detected in seven grid wells; concentrations from two wells were above the CDPH maximum contaminant level (MCL-CA). Most detections of trace elements in samples collected from COA Study Unit wells were below water-quality thresholds. Exceptions include five samples of arsenic that were above the USEPA maximum contaminant level (MCL-US), two detections of boron above the CDPH notification level (NL-CA), and two detections of mol

Data Series

Geology and ground-water resources of Galveston County, Texas

Galveston County, on the Texas gulf coast, is underlain by alternating beds of sand and clay. These sand and clay strata crop out in belts that roughly parallel the coastline and dip gently southeastward at an angle gre? +,er than the slope of the land, thereby creating artesian aquifers. The formations that yield potable water to wells are the Lissie formation, the "Alta Loma" sand and other sands of the Beaumont clay, and beach and dune sands of Recent aie. Most of the potable water is obtained on the mainland of Galveston County. The water from most wells on Galveston Island is highly mineralized. Before 1948, water for all public use and nearly all industrial use was derived from wells. Most ground water now used in the county is pumped from areas around Alta Loma and Texas City. The average daily pumpage in these areas increased from 6 million gallons in 1938 to 17.8 million gallons in 1940 and reached a peak of about 34 million gallons in 1945. Between 1945 and 1948 the rate of pumpage was nearly constant, but in 1948 surface water was diverted from the Brazos River to supply some of the Texas City industries and, as a result, the use of ground water was reduced about 30 percent. Water levels declined in county wells as the pumpage increased during the years prior to 1948. Since water from the Brazos River has been utilized the levels have risen in many wells and tended to become constant in others. Subsidence of the land in a large part of the county, particularly in the Texas City area, is attributed to the excessive withdrawal of ground water. Salt-water encroachment has been a problem in the county for many years. Salt water was present in the lower part of the "Alta Loma" sand in the Alta Loma and Texas City areas and throughout that sand on Galveston Island when the first wells were drilled. Encroachment from either below or downdip took place with the lowering of artesian pressure in the aquifer in the vicinity of Alta Loma and Texas City. Pumping tests reveal that the average coefficient of transmissibility of the "Alta Loma" sand is 102,000 at Alta Loma and 153,000 at Texas City. The coefficients- of transmissibility of sands in the upper part of the Beaumont clay around Texas City average 27,300. Surface water from the Brazos River, used for the irrigation of rice since 1942, was made available in 1948 to industries in Texas City as a substitute for ground water. The water from the Brazos River is variable in quality, but probably can be utilized on a somewhat larger scale than at present. Much additional ground water could be obtained from both the "Alta Loma" sand and the upper part of the Beaumont clay, especially in the northern and western parts of the county. Before large developments of supplies are planned, however, these areas should be explored by test drilling. The problems of well spacing and pumping rates should be thoroughly studied in order to determine the maximum development permitted by the ground-water supply. Current observations should be continued with special emphasis on the progress of salt-water encroachment.

Water Supply Paper

Ground-water resources: Cumberland County, New Jersey

Cumberland County is located in the Atlantic Coastal Plain physiographic province along the northeastern shore of Delaware Bay in Southwestern New Jersey. An average annual hydrologic budget was computed for Cumberland County. Water gains are: precipitation, 1,050 mgd (million gallons per day); surface-water inflow, 142 mgd; ground-water inflow negligible. Water losses are: evapotranspiration, 685 mgd; surface-water outflow, 370 mgd; ground-water outflow, 137 mgd. Unconsolidated and semiconsolidated Coastal Plain sediments, 2,500 to 4,500 feet thick, and ranging in age from Cretaceous to Holocene, consist of layers of clay, silt, sand and gravel. Aquifers composed mainly of sand and gravel occur in the Potomac Group and Raritan and Magothy Formations, the Wenonah Formation and Mount Laurel Sand, the Piney Point Formation, and the Kirkwood Formation and Cohansey Sand. Aquifers in the Potomac-Raritan-Magothy sequence contain saline water and are not currently utilized in Cumberland County. However, they may be utilized in the future for underground storage of fresh water, or possibly other uses when more is known about this aquifer system. The aquifer in the Wenonah Formation and Mount Laurel Sand is not presently utilized in Cumberland County. It is probably suitable for future development, however of wells yielding as much as 300 gpm (gallons per minute) of good quality water in the northern part of the county. The Piney Point Formation is tapped in Cumberland County by only a few wells; each of these generally yield less than 100 gpm. Additional small supplies can be developed from this aquifer. Water from this aquifer requires little or no treatment for domestic use. Two principal aquifers occur in the Kirkwood Formation and Cohansey Sand: (1) the lower Kirkwood aquifer and (2) the Cohansey-Kirkwood aquifer. Most wells tapping the lower Kirkwood aquifer yield less than 50 gpm but are capable of yielding as much as 400 gpm. Wells in the lower Kirkwood range in depth from 200 to 370 feet. The Cohansey-Kirkwood aquifer is the shallowest and most important source of ground-water in the county but is highly susceptible to surface contamination. This aquifer is highly permeable; analysis of data from two pumping tests indicates permeabilities of 1,200 and 2,700 gpm per square foot. It generally yields large supplies of water (300 to 1,200 gpm) to wells from depths of less than 180 feet. Water in the Cohansey-Kirkwood aquifer is characterized by 1mv dissolved-solids content (63 mg/l, median), low hardness (21 mg/l, median), and low pH values (5.5 pH units, median). Water use in Cumberland County varies and is highly seasonal, mainly because of increasing requirements for irrigation and the food processing industries in the county. In 1964 seasonal use ranged from 27 mgd in March to 145 mgd in August. This is much higher than withdrawals in neighboring Salem and Cape May Counties. In 1964 withdrawals in Cumberland County averaged about 51 mgd; almost all of this, 49.4 mgd, was from ground-water supplies. The total annual water use in 1964 according to type of use was: for public supply, 10.6 mgd; for industrial uses, 19.0 mgd; irrigation, 15.4 mgd; suburban, rural, residential, institutional, farm, and commercial, 5.9 mgd.

New Jersey

Ground-water quality data in the San Fernando-San Gabriel study unit, 2005— Results from the California GAMA program

Ground-water quality in the approximately 460 square mile San Fernando-San Gabriel study unit (SFSG) was investigated between May and July 2005 as part of the Priority Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The San Fernando-San Gabriel study was designed to provide a spatially unbiased assessment of raw ground-water quality within SFSG, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 52 wells in Los Angeles County. Thirty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and seventeen wells were selected to aid in the evaluation of specific water-quality issues or changes in water chemistry along a historic ground-water flow path (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), 1,2,3-trichloropropane (1,2,3-TCP), and 1,4-dioxane], naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately one-fifth (11 of 52) of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control results showed that the data had very little bias or variability and resulted in censoring of less than 0.7 percent (32 of 4,484 measurements) of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in more than 90 percent (33 of 35) of grid wells. For all wells sampled for SFSG, nearly all VOC detections were below health-based thresholds, and most were less than one-tenth of the threshold values. Samples from seven wells had at least one detection of PCE, TCE, tetrachloromethane, NDMA, or 1,2,3-TCP at or above a health-based threshold. Pesticides were detected in about 90 percent (31 of 35) grid wells and all detections in samples from SFSG wells were below health-based thresholds. Major ions, trace elements, and nutrients in samples from 17 SFSG wells were all below health-based thresholds, with the exception of one detection of nitrate that was above the USEPA maximum contaminant level (MCL-US). With the exception of 14 samples having radon-222 above the proposed MCL-US, radioactive constituents were below health-based thresholds for 16 of the SFSG wells sampled. Total dissolved solids in 6 of the 24 SFSG wells that were sampled ha

California

Springs of California

In 1903 the United States Geological Survey began an investigation of the underground water of California, generally with financial cooperation on the part of the State. Since that year ten papers on the underground water of the State have been issued by the Survey, each representing an investigation that has been completed. The field work which is to serve as the basis for two additional papers has also been done and the reports are in preparation. Investigations have been begun in two other areas in the State and their results will eventually be assembled and published. Since a period soon after the inception of the California work those responsible for its conduct have realized the desirability of a special study of the springs, particularly those which yield mineral waters and which are utilized to a greater or less extent by citizens of the State and by tourists as recreation and health resorts. It did not become practicable to begin this work until the summer of 1908, when Mr. G. A. Waring, who had assisted in some of the earlier California studies and had investigated for the Survey certain areas in southern Oregon and Washington, was assigned to the task of collecting and assembling the necessary data. California, with an area of 158,000 square miles, is the second largest State in the Union. It exhibits wide geographic diversity, since it includes the lowest area in the United States Death Valley, 276 feet below sea level and the highest Mount Whitney, 14,501 feet above the sea; and accompanying this geographic diversity there is a corresponding range in scenic effects, climate, and vegetation. The records obtained at meteorological stations in the Salton Sink indicate a maximum temperature of 130° in the shade, the highest of record within the continental United States. It is probable that minimum temperatures on the higher peaks, like Mount Whitney and Mount Shasta, approach the minimum within our boundaries. Rainfall records in the most arid sections of the southern deserts of the State represent the extreme of aridity in the United States, with averages of less than 3 inches per annum and periods of 12 months or more with only traces of rain, whereas the precipitation in northwestern California is very heavy, an annual average of close to 100 inches being recorded at a few stations in Mendocino and Del Norte counties. The immensity of the area of the State has made the collection of the field data required for the report a task of considerable magnitude, though its diversity has added greatly to the interest of the work. In the original plan it was estimated that two years of field studies would prove sufficient. Mr. Waring succeeded in visiting the more important localities during this period, although some of his examinations were, of necessity, rather cursory. In midsummer, 1910, after the completion of the field work and the assembling of the greater portion of his data in manuscript form he was called by the Government of Brazil to take charge of general water supply investigations in the northeastern arid portion of that South American republic. The task of reviewing, editing, and supplementing in some respects, the results of his studies was thus unavoidably left to others. This task was rendered light by the systematic form in which Mr. Waring's material was left. It was a matter of regret to Mr. Waring, as it has been to those associated with him, that the financial limitations which controlled his work made it impracticable to procure the large number of new analyses which are particularly important in a paper of this type, in which waters of unusual chemical characteristics are discussed. Such analyses as are available have been assembled from all possible sources and combined with those which were prepared especially in connection with this investigation. The result, although it is in some respects unsatisfactory, furnishes a basis for a general view of the characteristics of the spring waters and serves to permit, their classification in a general way. Mr. Herman Stabler has reviewed the chemical data and rearranged and interpreted the available analyses. It is hoped that the report, setting forth as it does the results of impartial observations upon one of the important present and more important prospective resources of the State, will prove of value to its citizens as well as to its visitors, and that the assembled material will not be without interest to physicians, chemists, geologists, and teachers who may have especial need for the information contained in the volume.

California

Ground-water quality data in the Southern Sacramento Valley, California, 2005 — Results from the California GAMA Program

Ground-water quality in the approximately 2,100 square-mile Southern Sacramento Valley study unit (SSACV) was investigated from March to June 2005 as part of the Statewide Basin Assessment Project of Ground-Water Ambient Monitoring and Assessment (GAMA) Program. This study was designed to provide a spatially unbiased assessment of raw ground-water quality within SSACV, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 83 wells in Placer, Sacramento, Solano, Sutter, and Yolo Counties. Sixty-seven of the wells were selected using a randomized grid-based method to provide statistical representation of the study area. Sixteen of the wells were sampled to evaluate changes in water chemistry along ground-water flow paths. Four additional samples were collected at one of the wells to evaluate water-quality changes with depth. The GAMA Statewide Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The ground-water samples were analyzed for a large number of man-made organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and wastewater-indicator constituents), constituents of special interest (perchlorate, N -nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, matrix spikes) were collected at ten percent of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control data resulted in censoring of less than 0.03 percent of the analyses of ground-water samples. This study did not evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Health Services (CADHS) (Maximum Contaminant Levels [MCLs], notification levels [NLs], or lifetime health advisories [HA-Ls]) and thresholds established for aesthetic concerns (Secondary Maximum Contaminant Levels [SMCLs]). All wells were sampled for organic constituents and selected general water quality parameters; subsets of wells were sampled for inorganic constituents, nutrients, and radioactive constituents. Volatile organic compounds were detected in 49 out of 83 wells sampled and pesticides were detected in 34 out of 82 wells; all detections were below health-based thresholds, with the exception of 1 detection of 1,2,3-trichloropropane above a NL. Of the 43 wells sampled for trace elements, 27 had no detections of a trace element above a health-based threshold and 16 had at least one detection above. Of the 18 trace elements with health-based thresholds, 3 (arsenic, barium, and boron) were detected at concentrations higher an MCL. Of the 43 wells sampled for nitrate, only 1 well had a detection above the MCL. Twenty wells were sampled for radioactive constituents; only 1 (radon-222) was measured at activities higher than the proposed MCL. Radon-222 was detected below the threshold in 7 wells and above the threshold in 13 wells. SMCLs have been established for nine constituents or parameters analyzed in SSACV. Six were measured at levels higher than an SMCL: chloride, iron, manganese, pH, specific conductance, and total dissolved solids. Chloride, iron, manganese, pH, and total dissolved solids were measured in 43 wells: 27 wells had no measurements above a threshold and 16 wells had a measurement above a threshold. Specific conductance was measured in 83 wells. In 68 wells, specific conductance was measured lower than the threshold and in 15 wells it was measured above the threshold.

California