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Methyl tert-Butyl Ether (MTBE) in ground water, air, and precipitation at North Windham, Maine

Thirty-one monitoring wells in the Windham aquifer in North Windham, Maine, were sampled for methyl tert-butyl ether (MTBE) from July 1998 to May 1999. MTBE was detected in 35 percent of the wells sampled in the Windham aquifer. MTBE was detected in 64 percent of wells in the high-yielding part of the aquifer; these wells account for 82 percent of all wells with detectable MTBE. Land cover also was found to be associated with MTBE in the wells in the study area, with the urban and low-density residential areas having more MTBE than undeveloped areas. The median concentration in wells with detectable MTBE was 1.13 micrograms per liter. Air and precipitation samples were collected in North Windham along with ground-water samples. Air samples were collected every 10 days from December 1998 to July 1999 (20 samples). MTBE was present in all 20 air samples collected, at concentrations ranging from 0.03 ppbv (parts per billion by volume) to 1.0 ppbv. Before Maine opted out of the reformulated gasoline (RFG) program in the spring of 1999, median concentrations in air at the North Windham site were 0.25 ppbv. After Maine stopped using RFG, the median concentration in air dropped to 0.09 ppbv. No MTBE was detected in four samples of precipitation at North Windham. The lack of rainfall during the study period prevented the collection of an adequate number of samples, and technical difficulties negated the results of some of the analyses of the samples that were collected. Based on the equilibrium partitioning of MTBE from the air into rain, the hypothetical average concentration of MTBE in rainfall during months when recharge typically occurs (March-April and October-December) would be approximately 0.3 to 0.4 micrograms per liter during the time that RFG was being used in Maine. After the phaseout of RFG, the maximum average concentration of MTBE in rainfall during these months would be approximately 0.1 micrograms per liter. The distribution and concentrations of MTBE that were detected in ground water indicate that recharge from precipation containing MTBE is not a likely explanation for the occurrence of MTBE in the Windham aquifer.

Maine

Exploring spatial and temporal symptoms of the freshwater salinization syndrome in a rural to urban watershed

The freshwater salinization syndrome (FSS), a concomitant watershed-scale increase in salinity, alkalinity, and major-cation and trace-metal concentrations, over recent decades, has been described for major rivers draining extensive urban areas, yet few studies have evaluated temporal and spatial FSS variations, or causal factors, at the subwatershed scale in mixed-use landscapes. This study examines the potential influence of land-use practices and wastewater treatment plant (WWTP) effluent on the export of major ions and trace metals from the mixed-use East Branch Brandywine Creek watershed in southeastern Pennsylvania, during the 2019 water year. Separate analysis of baseflow and stormflow subsets revealed similar correlations among land-use characteristics and streamwater chemistry. Positive associations between percent impervious surface cover, which ranged from 1.26 % to 21.9 % for the 13 sites sampled, and concentrations of Ca 2+ , Mg 2+ , Na + , and Cl − are consistent with road-salt driven reverse cation exchange and weathering of the built environment. The relative volume of upstream WWTP was correlated with Cu and Zn, which may be derived in part from corroded water-conveyance infrastructure; chloride to sulfate mass ratios (CSMR) ranged from ~6.3 to ~7.7× the 0.5 threshold indicating serious corrosivity potential. Observed exceedances of U.S. Environmental Protection Agency Na + and Cl − drinking water and aquatic life criteria occurred in winter months. Finally, correlations between percent cultivated cropland and As and Pb concentrations may be explained by the persistence of agricultural pesticides that had been used historically. Study results contribute to the understanding of FSS solute origin, fate, and transport in mixed-use watersheds, particularly those in road salt-affected regions. Study results also emphasize the complexity of trace-metal source attribution and explore the potential for FSS solutes to affect human health, aquatic life, and infrastructure.

Pennsylvania

Impacts on groundwater recharge areas of megacity pumping: analysis of potential contamination of Kolkata, India, water supply

Water supply to the world's megacities is a problem of quantity and quality that will be a priority in the coming decades. Heavy pumping of groundwater beneath these urban centres, particularly in regions with low natural topographic gradients, such as deltas and floodplains, can fundamentally alter the hydrological system. These changes affect recharge area locations, which may shift closer to the city centre than before development, thereby increasing the potential for contamination. Hydrogeological simulation analysis allows evaluation of the impact on past, present and future pumping for the region of Kolkata, India, on recharge area locations in an aquifer that supplies water to over 13 million people. Relocated recharge areas are compared with known surface contamination sources, with a focus on sustainable management of this urban groundwater resource. The study highlights the impacts of pumping on water sources for long-term development of stressed city aquifers and for future water supply in deltaic and floodplain regions of the world.

West Bengal

Using a BACI design to assess stream ecology and chemistry response after wildfire

Wildfires can have complex effects on aquatic communities, which can be either beneficial or adverse depending on the setting. In California, USA, the size, frequency, and severity of wildfires has greatly increased over the last few decades. Understanding the effects of fire on aquatic ecosystem health and human land use has become increasingly important in managing the interface of the natural and urban landscape. In this study, we used a before–after control–impact (BACI) study design to test for differences in bed sediment chemistry, water chemistry, benthic algal biomass, and benthic macroinvertebrate communities between burned and unburned (control) watersheds, pre- and post-fire, using data collected before and after California’s 2017 Atlas, Nuns, and Tubbs wildfires. We found a treatment effect (burned vs control) on water chemistry, sediment trace-metal concentrations, algae, and community structure of benthic macroinvertebrates, but we found no evidence of an interaction between time period (pre- vs post-fire) and treatment. Both the difference in environmental factors between our control and burned sample sites and the proximity and degree of wildfire burn severity may have contributed to the results of this BACI study. Our results also highlight the importance of including control sites when assessing the effects of discrete disturbances, such as wildfire, to avoid spurious conclusions of disturbance effects that may be attributable to innate ecological variability.

Freshwater Science

Using crustal-scale refraction data of joint inversions of Rayleigh-wave dispersion curves and H/V spectral ratios for Atlantic Coastal Plain velocity structure, eastern U.S.

Shallow shear‐wave velocities ( ⁠⁠ V s ) sometimes are estimated from joint inversions of horizontal‐to‐vertical (H/V) spectral ratios and surface‐wave dispersion curves derived from ambient noise or small active sources. Here, we evaluate carrying out these inversions using Rayleigh‐wave dispersion curves computed from crustal‐scale P ‐wave seismic refraction data. We use data from the 2014–2015 Eastern North American Margin (ENAM) experiment in Virginia and North Carolina, but similar seismic refraction data sets have been acquired over sedimentary basins of interest for seismic hazard studies, including in major urban areas. The ENAM project deployed a pair of ∼215 km long, northwest–southeast linear arrays with ∼300 m receiver spacing to record 11 dynamite shots, and 80 continuously recording seismometers with 5–6 km spacing along the same arrays to record offshore airguns. The arrays crossed the onland portion of the Atlantic Coastal Plain sediments, which are a seaward‐thickening wedge of Cretaceous and younger sediments deposited mostly on crystalline bedrock. We compute Rayleigh‐wave dispersion curves from 3 to 9 km long portions of the receiver arrays on each side of the dynamite shots, and we compute ambient‐noise H/V ratios from the continuously recording seismometers. We use a genetic inversion algorithm in which forward velocity models in each “generation” are evaluated for misfits compared to the observed data, with subsequent generations constructed from the models with the smallest misfits. Velocities to depths of 500 m are defined well, as shown by a narrow range of velocities in the best‐fit models, by the consistency between multiple inversion runs at a site, and by forward modeling of site responses. The resulting velocity cross‐section of the Coastal Plain strata has seaward‐dipping contours in the thinner portions of the Coastal Plain but smaller dips in the deeper portions. We interpret these results as showing that velocity contours in the ACP strata are influenced by a combination of lithology and overburden pressure. Results demonstrate that existing seismic refraction data have the potential for determining detailed shallow shear‐wave velocity profiles.

eastern United States

Can hunting of translocated nuisance Canada geese reduce local conflicts?

Resident Canada geese (Branta canadensis) nest or reside in the temperate latitudes of North America. In past years, translocation-the capture and subsequent release of geese at distant locations-has been used to establish resident goose populations and to reduce nuisance problems. However, with new special hunting seasons designed to target resident Canada geese, we can now evaluate translocation as a management tool when hunting is allowed at release sites. We selected 2 study sites, representative of urban and suburban locations with nuisance resident geese, in central and western New York, USA. In June 2003, we translocated 80 neck-banded adult geese, 14 radiomarked adult females, and 83 juveniles 150 km east and southwest from urban and suburban problem sites in western New York to state-owned Wildlife Management Areas. At these same capture sites, we used 151 neck-banded adult geese, 12 radiomarked females, and 100 juveniles as controls to compare dispersal movements and harvest vulnerability to translocated geese. All observations (n = 45) of translocated radiomarked geese were <20 km from release sites, in areas where hunting was permitted. Only 25 of 538 observations (4.6%) of radiomarked geese at control sites were in areas open to hunting. The remainder of observations occurred at nonhunting locations within 10 km of control sites. More translocated adult geese (23.8%) were harvested than control geese (6.6%; ??2 = 72.98, P = 0.0009). More translocated juvenile geese were harvested (22.9%) than juvenile controls (5.0%; ??2 = 72.30, P = 0.0005). Only 7 (8.8%) translocated adult geese returned to the original capture sites during Canada goose hunting seasons. Translocation of adult and juvenile geese in family groups may alleviate nuisance problems at conflict sites through increased harvest, reducing the number of birds returning in subsequent years.

Wildlife Society Bulletin

Total Mercury, Methylmercury, and Carbon and Nitrogen Stable Isotope Data for Biota from Selected Streams in Oregon, Wisconsin, and Florida, 2002-04

The U.S. Geological Survey National Water-Quality Assessment Program conducted a multidisciplinary study to investigate the bioaccumulation of mercury from 2002 to 2004. Study areas were located in Oregon, Wisconsin, and Florida. Each study area included one urban site, and one or two nonurban sites that had the following attributes: high-percent wetland or low-percent wetland. Periphyton, macroinvertebrates, and forage fish were collected twice per year (during 2003 and 2004) to capture seasonality. Top predators, specifically largemouth bass (Micropterus salmoides), brown trout (Salmo trutta), and cutthroat trout (Oncorhynchus clarkii), were collected once per year (Oregon, Wisconsin, and Florida in 2003; Florida only in 2004). All biota were identified to the lowest possible taxonomic category and were analyzed for mercury and stable carbon and nitrogen isotopes. Periphyton and invertebrates were analyzed for total mercury and methylmercury; fish were analyzed for total mercury only. This report presents (1) methodology and data on mercury, methylmercury, stable isotopes, and (2) other ecologically relevant measurements in biological tissues of periphyton, invertebrates, forage fish, and predator fish.

Data Series

Uses of conventional aerial photography in urban areas - review and bibliography

This paper is divided into two parts. Part I presents a review of some of the past uses of aerial photography in urban areas. The empirical studies reviewed are divided into two broad categories depending on whether inventory compilation is by direct or indirect observation. Studies using inventory by direct observation are further divided into land-use studies and transportation studies. Part II identifies some problem areas for future research.

Open-File Report

National Water-Quality Assessment of the Trinity River Basin, Texas - Well and Water-Quality Data from the Outcrop of the Woodbine Aquifer in Urban Tarrant County, 1993

An urban land-use study of the shallow water-bearing zones of the Woodbine aquifer outcrop area began in 1993 as a part of the National Water-Quality Assessment Program for the Trinity River Basin. Thirty-eight wells located within predominantly commercial or residential settings were selected for this study. Water samples were collected from each well and analyzed for 186 waterquality constituents. A brief description of the study area and the Woodbine aquifer, a description of the installation and design of the wells used, and the water-quality data obtained from this study are included in this report. The well description includes the locations of the 38 wells used in the study, the well design of the 28 U.S. Geological Survey-installed wells, and the lithological logs. Laboratory analyses of water samples include major inorganic constituents, nutrients, trace elements, tritium, organic carbon, phenols, methyl blue active substance, pesticides, and volatile organic compounds. Field measurements (specific conductance, pH, water temperature, and dissolved oxygen concentration) were measured at each site.

Open-File Report

Regression equations for estimating flood flows for the 2-, 10-, 25-, 50-, 100-, and 500-Year recurrence intervals in Connecticut

Multiple linear-regression equations were developed to estimate the magnitudes of floods in Connecticut for recurrence intervals ranging from 2 to 500 years. The equations can be used for nonurban, unregulated stream sites in Connecticut with drainage areas ranging from about 2 to 715 square miles. Flood-frequency data and hydrologic characteristics from 70 streamflow-gaging stations and the upstream drainage basins were used to develop the equations. The hydrologic characteristics-drainage area, mean basin elevation, and 24-hour rainfall-are used in the equations to estimate the magnitude of floods. Average standard errors of prediction for the equations are 31.8, 32.7, 34.4, 35.9, 37.6 and 45.0 percent for the 2-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals, respectively. Simplified equations using only one hydrologic characteristic-drainage area-also were developed. The regression analysis is based on generalized least-squares regression techniques. Observed flows (log-Pearson Type III analysis of the annual maximum flows) from five streamflow-gaging stations in urban basins in Connecticut were compared to flows estimated from national three-parameter and seven-parameter urban regression equations. The comparison shows that the three- and seven- parameter equations used in conjunction with the new statewide equations generally provide reasonable estimates of flood flows for urban sites in Connecticut, although a national urban flood-frequency study indicated that the three-parameter equations significantly underestimated flood flows in many regions of the country. Verification of the accuracy of the three-parameter or seven-parameter national regression equations using new data from Connecticut stations was beyond the scope of this study. A technique for calculating flood flows at streamflow-gaging stations using a weighted average also is described. Two estimates of flood flows - one estimate based on the log-Pearson Type III analyses of the annual maximum flows at the gaging station, and the other estimate from the regression equation - are weighted together based on the years of record at the gaging station and the equivalent years of record value determined from the regression. Weighted averages of flood flows for the 2-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals are tabulated for the 70 streamflow-gaging stations used in the regression analysis. Generally, weighted averages give the most accurate estimate of flood flows at gaging stations. An evaluation of the Connecticut's streamflow-gaging network was performed to determine whether the spatial coverage and range of geographic and hydrologic conditions are adequately represented for transferring flood characteristics from gaged to ungaged sites. Fifty-one of 54 stations in the current (2004) network support one or more flood needs of federal, state, and local agencies. Twenty-five of 54 stations in the current network are considered high-priority stations by the U.S. Geological Survey because of their contribution to the longterm understanding of floods, and their application for regionalflood analysis. Enhancements to the network to improve overall effectiveness for regionalization can be made by increasing the spatial coverage of gaging stations, establishing stations in regions of the state that are not well-represented, and adding stations in basins with drainage area sizes not represented. Additionally, the usefulness of the network for characterizing floods can be maintained and improved by continuing operation at the current stations because flood flows can be more accurately estimated at stations with continuous, long-term record.

Connecticut

Ground-Water Flow Model for the Spokane Valley-Rathdrum Prairie Aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

This report presents a computer model of ground-water flow in the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in Spokane County, Washington, and Bonner and Kootenai Counties, Idaho. The aquifer is the sole source of drinking water for more than 500,000 residents in the area. In response to the concerns about the impacts of increased ground-water withdrawals resulting from recent and projected urban growth, a comprehensive study was initiated by the Idaho Department of Water Resources, the Washington Department of Ecology, and the U.S. Geological Survey to improve the understanding of ground-water flow in the aquifer and of the interaction between ground water and surface water. The ground-water flow model presented in this report is one component of this comprehensive study. The primary purpose of the model is to serve as a tool for analyzing aquifer inflows and outflows, simulating the effects of future changes in ground-water withdrawals from the aquifer, and evaluating aquifer management strategies. The scale of the model and the level of detail are intended for analysis of aquifer-wide water-supply issues. The SVRP aquifer model was developed by the Modeling Team formed within the comprehensive study. The Modeling Team consisted of staff and personnel working under contract with the Idaho Department of Water Resources, personnel working under contract with the Washington Department of Ecology, and staff of the U.S. Geological Survey. To arrive at a final model that has the endorsement of all team members, decisions on modeling approach, methodology, assumptions, and interpretations were reached by consensus. The ground-water flow model MODFLOW-2000 was used to simulate ground-water flow in the SVPR aquifer. The finite-difference model grid consists of 172 rows, 256 columns, and 3 layers. Ground-water flow was simulated from September 1990 through September 2005 using 181 stress periods of 1 month each. The areal extent of the model encompasses an area of approximately 326 square miles. For the most part, the model extent coincides with the 2005 revised extent of the Spokane Valley-Rathdrum Prairie aquifer as defined in a previous report. However, the model excludes Spirit and Hoodoo Valleys because of uncertainties about the ground-water flow directions in those valleys and the degree of hydraulic connection between the valleys and northern Rathdrum Prairie. The SVRP aquifer is considered to be a single hydrogeologic unit except in Hillyard Trough and the Little Spokane River Arm. In those areas, a continuous clay layer divides the aquifer into an upper, unconfined unit and a lower, confined unit. The model includes all known components of inflows to and outflows from the aquifer. Inflows to the SVRP aquifer include (1) recharge from precipitation, (2) inflows from tributary basins and adjacent uplands, (3) subsurface seepage and surface overflows from lakes that border the aquifer, (4) flow from losing segments of the Spokane River to the aquifer, (5) return percolation from irrigation, and (6) effluent from septic systems. Outflows from the SVRP aquifer include (1) ground-water withdrawals from wells, (2) flow from the aquifer to gaining segments of the Spokane River, (3) aquifer discharge to the Little Spokane River, and (4) subsurface outflow from the lower unit at the western limit of the model area near Long Lake. These inflow and outflow components are represented in the model by using MODFLOW-2000 packages. The parameter-estimation program PEST was used to calibrate the SVRP aquifer model. PEST implements a nonlinear least-squares regression method to estimate model parameters so that the differences between measured and simulated quantities are minimized with respect to an optimal criterion. Calibration data include 1,573 measurements of water levels and 313 measurements of streamflow gains and losses along segments of the Spokane and Little Spokane Rivers. Model parameters estimated during calib

Scientific Investigations Report

Ground-Water Quality and its Relation to Land Use on Oahu, Hawaii, 2000-01

Water quality in the main drinking-water source aquifers of Oahu was assessed by a one-time sampling of untreated ground water from 30 public-supply wells and 15 monitoring wells. The 384 square-mile study area, which includes urban Honolulu and large tracts of forested, agricultural, and suburban residential lands in central Oahu, accounts for 93 percent of the island's ground-water withdrawals. Organic compounds were detected in 73 percent of public-supply wells, but mostly at low concentrations below minimum reporting levels. Concentrations exceeded drinking-water standards in just a few cases: the solvent trichloroethene and the radionuclide radon-222 exceeded Federal standards in one public-supply well each, and the fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2,3-trichloropropane (TCP) exceeded State standards in three public-supply wells each. Solvents, fumigants, trihalomethanes, and herbicides were prevalent (detected in more than 30 percent of samples) but gasoline components and insecticides were detected in few wells. Most water samples contained complex mixtures of organic compounds: multiple solvents, fumigants, or herbicides, and in some cases compounds from two or all three of these classes. Characteristic suites of chemicals were associated with particular land uses and geographic locales. Solvents were associated with central Oahu urban-military lands whereas fumigants, herbicides, and fertilizer nutrients were associated with central Oahu agricultural lands. Somewhat unexpectedly, little contamination was detected in Honolulu where urban density is highest, most likely as a consequence of sound land-use planning, favorable aquifer structure, and less intensive application of chemicals (or of less mobile chemicals) over recharge zones in comparison to agricultural areas. For the most part, organic and nutrient contamination appear to reflect decades-old releases and former land use. Most ground-water ages were decades old, with recharge dates ranging from pre-1940 to the present, and with most dates falling within the 1950s to 1980s time span. Several widely detected compounds were discontinued as long ago as the 1970s but have yet to be flushed from the ground-water system. Although large tracts of land in central Oahu have been converted from agriculture to residential urban use since the 1950s, water quality in the converted areas still more closely reflects the former agricultural land. It appears to be too early to detect a distinct water-quality signature characteristic of the newer urban use, although several urban turfgrass herbicides in use for just 10 years or so were detected in monitoring wells and may represent early arrivals of urban contaminants at the water table.

Water-Resources Investigations Report

Analysis of different sensor performances in impervious surface mapping

The U.S. Geological Survey (USGS) has developed the National Land Cover Database (NLCD) to provide consistent land cover and land cover change products for the nation since 2001. As one of products in the NLCD, the percent impervious surface area (ISA), which was estimated with Landsat imagery, represents the fraction of human-made impervious area in a 30-m grid and has been used to quantify urban land cover types and extents for the United States. However, it is still a challenge to clearly determine urban land cover intensity and extents using remote sensing data with spatial and spectral resolutions similar to Landsat in part because of highly heterogeneous features of urban land cover. Most urban areas, especially in low intensity development areas, exhibit sub-pixel characteristics that mix impervious surface with other land covers (e.g., grass and trees) in the 30-m resolution satellite imagery. Furthermore, the influence of highly heterogeneous features in many urban areas and how they alter the spectral signature of urban landscapes has not yet been fully studied. Recent advances in remote sensing technology have provided multiple spectral and spatial resolution data from several satellites including WorldView (WV), Sentinel-2, and the Landsat Operational Land Imager (OLI). Remote sensing images having different spectral bands and high spatial resolution provide the potential to derive detailed information on the nature and properties of different surface materials on the urban ground. This study focuses on performance of mapping impervious surface using data collected from WorldView-3, Sentinel-2, and Landsat OLI. We compared ISA results estimated from these sensors and evaluated benefits and limitations of radiometric and spatial resolutions for mapping impervious surface in a study area on the Eastern corridor between Washington, D.C., and Baltimore, where developed impervious surface containing both residential housings, office buildings, and roads, in the United States. The impact of different band combinations in Sentinel-2 imagery on mapping urban impervious surface and urban land cover was also evaluated.

Conference Paper

Urban-Related Environmental Variables and Their Relation with Patterns in Biological Community Structure in the Fountain Creek Basin, Colorado, 2003-2005

In 2003, the U.S. Geological Survey, in cooperation with Colorado Springs City Engineering, began a study to evaluate the influence of urbanization on stream ecosystems. To accomplish this task, invertebrate, fish, stream discharge, habitat, water-chemistry, and land-use data were collected from 13 sites in the Fountain Creek basin from 2003 to 2005. The Hydrologic Index Tool was used to calculate hydrologic indices known to be related to urbanization. Response of stream hydrology to urbanization was evident among hydrologic variables that described stormflow. These indices included one measurement of high-flow magnitude, two measurements of high-flow frequency, and one measurement of stream flashiness. Habitat and selected nonstormflow water chemistry were characterized at each site. Land-use data were converted to estimates of impervious surface cover and used as the measure of urbanization annually. Correlation analysis (Spearman?s rho) was used to identify a suite of nonredundant streamflow, habitat, and water-chemistry variables that were strongly associated (rho > 0.6) with impervious surface cover but not strongly related to elevation (rho < 0.60). An exploratory multivariate analysis (BIO-ENV, PRIMER ver 6.1, Plymouth, UK) was used to create subsets of eight urban-related environmental variables that described patterns in biological community structure. The strongest and most parsimonious subset of variables describing patterns in invertebrate community structure included high flood pulse count, lower bank capacity, and nutrients. Several other combinations of environmental variables resulted in competing subsets, but these subsets always included the three variables found in the most parsimonious list. This study found that patterns in invertebrate community structure from 2003 to 2005 in the Fountain Creek basin were associated with a variety of environmental characteristics influenced by urbanization. These patterns were explained by a combination of hydrologic, habitat, and water-chemistry variables. Fish community structure showed weaker links between urban-related environmental variables and biological patterns. A conceptual model was developed that showed the influence of urban-related environmental variables and their relation to fish and invertebrate assemblages. This model should prove helpful in guiding future studies on the impacts of urbanization on aquatic systems. Long-term monitoring efforts may be needed in other drainages along the Front Range of Colorado to link urban-related variables to aquatic communities in transition zone streams.

Scientific Investigations Report

An initial abstraction and constant loss model, and methods for estimating unit hydrographs, peak streamflows, and flood volumes for urban basins in Missouri

Streamflow data, basin characteristics, and rainfall data from 39 streamflow-gaging stations for urban areas in and adjacent to Missouri were used by the U.S. Geological Survey in cooperation with the Metropolitan Sewer District of St. Louis to develop an initial abstraction and constant loss model (a time-distributed basin-loss model) and a gamma unit hydrograph (GUH) for urban areas in Missouri. Study-specific methods to determine peak streamflow and flood volume for a given rainfall event also were developed. Distinct basin characteristics were evaluated and selected for use on the basis of their theoretical relation to flow, results from previous studies, and the ability to reliably measure the basin characteristic using digital datasets and geographic information system (GIS) technology. The key basin characteristics determined or computed for each of the 39 basins upstream from the streamflow-gaging stations were drainage area, percent impervious area, main-channel slope based on the 10- and 85-percent length method, percentage of the basin area in storage (lakes, ponds, reservoirs, wetlands), the composite Natural Resources Conservation Service curve number estimated from a combination of the soil type data and land-use characteristics, and the streamflow variability index developed for the recently completed study of low-flow regression in Missouri. Characteristics of spatial and temporal rainfall distribution came from the next generation weather radar (NEXRAD) network. Procedures were developed for this study to convert the variable radar sweep rate into a 5-minute total rainfall hyetograph using data from the radar bin at the centroid of a given basin. Additional characteristics determined for each storm on the basin included the 5-day and 14-day antecedent rainfall, estimated from the mean of daily rainfall values from various rain gages in the area. The database of observed rainfall and runoff events for the 39 basins upstream from the streamflow-gaging stations was analyzed to compute the optimal storm-specific initial abstraction and constant loss values, as well as the time to peak, peak streamflow, and shape factor values of the GUH. The optimal storm-specific values were used to develop a regional regression equation for initial abstraction; conversely, the constant loss was estimated not by regression but from either a generalized or specific regional mean value. The optimal storm-specific values of GUH time to peak, GUH peak streamflow, and GUH shape factor were used to develop regression equations for the GUH. The regression equations for the GUH initially were tested alone, and then were combined with the appropriate regional regression equation for initial abstraction and both the generalized regional and specific regional mean constant loss values. For the GUH regression equations, the interquartile range was substantially smaller than the range spanned by the minimum and maximum values, which indicates most of the errors have much smaller variation, and the minimum and maximum values may be extreme outliers. The central tendency of the regressed errors for peak streamflow and runoff hydrograph volume were both approximately zero, which implies a generally unbiased estimation of these values. The mean and median of the regressed errors for time to peak streamflow were both small but greater than zero, which implies the GUH regression equations create a hydrograph that has a peak that is later in time than observed. Specifically, the regressed times indicate an offset of about 10 minutes, on average, from observed. The mean and median of the regressed errors for widths of the runoff hydrograph at 50 and 75 percent were less than zero, which implies the GUH tends to slightly underestimate these widths compared to the observed. The appropriate regional initial abstraction regression equation was combined with both the generalized and the specific regional mean constant loss values and the GUH regression equations. Both the generalized regional mean constant loss and specific regional mean constant loss forms of the basin-loss model worked equally well to model the observed runoff hydrograph based on the error analysis, and neither model seems to make a consistently better approximation. Both initial abstraction and constant loss models combined with the GUH regression equations were further validated using several storms available after the start of the project in early 2011 with similar but consistently higher error results. If these methods are used in an urban area in Missouri other than those examined in this study, advice to the user is given to consider using the generalized regional mean values. If these methods are used in an urban area that is a subbasin of one of the basins in this study, advice to the user is given to consider using the specific regional mean values. The rainfall-runoff pairs from the storm-specific GUH analysis were further analyzed against various basin and rainfall characteristics to develop equations to estimate the peak streamflow and flood volume based on a quantity of rainfall on the basin.

Missouri

Are streams in agricultural and urban areas contaminated by pesticides?

To answer this question, a study of pesticides in streams in a small agricultural area and a small urban area in Colorado was conducted in 1993 by the U.S. Geological Survey (USGS) as part of the National Water-Quality Assessment (NAWQA) program. The results indicate that pesticides are present in streams, and both agricultural and urban areas are probable sources of the contamination. In the agricultural area, 30 pesticides were detected and in the urban area, 26 pesticides were detected at least once during the thirteen month study. In the agricultural area, the herbicides alachlor (two samples) and cyanazine (four samples) and the insecticide diazinon (one sample) were the only pesticides that exceeded the U.S. Environmental Protection Agency's maximum contaminant levels (MCLs) or health advisory levels (HALs) for drinking water. No pesticides exceeded MCLs or HALs in the urban area.

Fact Sheet

Macroinvertebrate-based assessment of biological condition at selected sites in the Eagle River watershed, Colorado, 2000-07

The U.S. Geological Survey (USGS), in cooperation with the Colorado River Water Conservation District, Eagle County, Eagle River Water and Sanitation District, Upper Eagle Regional Water Authority, Colorado Department of Transportation, City of Aurora, Town of Eagle, Town of Gypsum, Town of Minturn, Town of Vail, Vail Resorts, Colorado Springs Utilities, Denver Water, and the U.S. Department of Agriculture Forest Service (FS), compiled macroinvertebrate (73 sites, 124 samples) data previously collected in the Eagle River watershed from selected USGS and FS studies, 2000-07. These data were analyzed to assess the biological condition (that is, biologically ?degraded? or ?good?) at selected sites in the Eagle River watershed and determine if site class (for example, urban or undeveloped) described biological condition. An independently developed predictive model was applied to calculate a site-specific measure of taxonomic completeness for macroinvertebrate communities, where taxonomic completeness was expressed as the ratio of observed (O) taxa to those expected (E) to occur at each site. Macroinvertebrate communities were considered degraded at sites were O/E values were less than 0.80, indicating that at least 20 percent of expected taxa were not observed. Sites were classified into one of four classes (undeveloped, adjacent road or highway or both, mixed, urban) using a combination of riparian land-cover characteristics, examination of topographic maps and aerial imagery, screening for exceedances in water-quality standards, and best professional judgment. Analysis of variance was used to determine if site class accounted for variability in mean macroinvertebrate O/E values. Finally, macroinvertebrate taxa observed more or less frequently than expected at urban sites were indentified. This study represents the first standardized assessment of biological condition of selected sites distributed across the Eagle River watershed. Of the 73 sites evaluated, just over half (55 percent) were considered in good biological condition (O/E greater than 0.80). The remaining sites were either consistently biologically degraded (30 percent; O/E less than 0.80) or varied annually between good and degraded condition (15 percent; O/E is less than or greater than 0.80). Sites primarily affected by urbanization were among the most severely degraded (lowest O/E values) when compared to other site classes. Although most urban sites were among the most severely degraded (lowest O/E values), a few sites had nearly intact macroinvertebrate communities (O/E near 1.0). Similar observations were noted among sites classified as mixed. Thirteen macroinvertebrate taxa were indentified that occurred more or less frequently than expected at urban sites. Additionally, six other taxa were impartial (tolerant) to the same conditions. Combined, these 19 taxa provide an opportunity to enhance the interpretation of future studies in the Eagle River watershed, but will require better insight into the responses of these taxa to specific stressors. Understanding the sources of variability affecting biological condition along with why some sites expected to be degraded, but showed otherwise, will have clear implications for mitigation efforts. Integrating results of this study with field and laboratory investigations will greatly enhance the ability to identify causal factors affecting biological condition at degraded sites, the logical next step. Information generated from such integrative studies will be imperative for well targeted mitigation efforts in the Eagle River watershed.

Scientific Investigations Report