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At least 271 records · Page 15Linked to original sources

Analysis of saltwater upconing beneath a pumping well

Aquifer systems that contain freshwater and saltwater are usually stratified, with the more dense saltwater underlying the freshwater. A groundwater well discharging from the freshwater zone causes the saltwater to move upwards towards the well. This phenomenon is known as saltwater upconing. Two methods of analysis, the sharp-interface method and the fluid-density-dependent solute-transport method, are used to simulate saltwater upconing. Numerical experiments including comparisons of the two methods indicate: (1) for low to moderate pumpages the 50% isochlor and sharp interface correlate well; (2) the well can discharge significant concentrations of saltwater, even though a stable cone (according to the sharp-interface method) exists below the well screen; (3) an almost linear relationship exists between the well discharge rate and the concentration of the discharge at low pumping rates that maintain a stable cone; and (4) upconing is sensitive to transverse dispersivity, whereas it is insensitive to longitudinal dispersivity. A simulation of upconing at Test Site No. 4, Truro, Cape Cod, Massachusetts, indicates that the appropriate field value of transverse dispersivity is very small. This supports the validity of the sharp-interface assumption for analyzing the behavior of systems with thin saltwater-freshwater transition zones.

Journal of Hydrology

Controls on rind thickness on basaltic andesite clasts weathering in Guadeloupe

A clast of low porosity basaltic andesite collected from the B horizon of a soil developed on a late Quaternary volcaniclastic debris flow in the Bras David watershed on Basse-Terre Island, Guadeloupe, exhibits weathering like that observed in many weathered clasts of similar composition in other tropical locations. Specifically, elemental profiles measured across the core-rind interface document that primary minerals and glass weather to Fe oxyhydroxides, gibbsite and minor kaolinite in the rind. The earliest reaction identified in the core is oxidation of Fe in pyroxene but the earliest reaction that creates significant porosity is plagioclase dissolution. Elemental loss varies in the order Ca???Na>K???Mg>Si>Al>Fe???P??Ti, consistent with the relative reactivity of phases in the clast from plagioclase???pyroxene???glass>apatite>ilmenite. The rind surrounds a core of unaltered material that is more spherical than the original clast. The distance from the core-rind boundary to a visually prominent rind layer, L, was measured as a proxy for the rind thickness at 36 locations on a slab cut vertically through the nominal center of the clast. This distance averaged 24.4??3.1mm. Maximum and minimum values for L, 35.8 and 20.6mm, were observed where curvature of the core-rind boundary is greatest (0.12mm-1) and smallest (0.018mm-1) respectively. Extrapolating from other rinds in other locations, the rate of rind formation is estimated to vary by a factor of about 2 (from ~4 to 7??10-14ms-1) from low to high curvature. The observation of a higher rate of rind formation for a higher curvature interface is consistent with a diffusion-limited model for weathering rind formation. The diffusion-limited model predicts that, like rind thickness, values of the thickness of the reaction front (h) for a given reaction, defined as the zone over which a parent mineral such as plagioclase completely weathers to rind material, should also increase with curvature. Values of h were quantified as a function of interface curvature using bulk chemical analysis (500<h<2000??m). Values of h were also quantified by measuring loss of matrix glass and increase in porosity as a function of curvature. In contrast to rind thickness, h shows no consistent increase with curvature. This contradiction is attributed to the mm-scale roughness of the interface which is related to phenocryst grain size. Therefore, the overall rind formation rate is strongly affected by curvature measured at the scale of the clast, while mineral reaction rates documented by reaction front thickness are strongly affected by curvature at the scale of phenocrysts. Similarly, the weathering advance rate (ms-1) for the entire Bras David watershed can be extrapolated from the clast weathering rate if roughness at the watershed scale equals values of approximately 400-800. ?? 2010 Elsevier B.V.

Chemical Geology

The presence of silicate melt may enhance rates of cation diffusion in olivine

Olivine is commonly used as a ‘crystal clock’ to extract timescales relevant to pre-eruptive perturbations within mafic magmatic systems. Diffusion chronometry applications require accurate calibrations for the rates at which Fe-Mg or other commonly measured elements like Ni, Mn, and Ca diffuse through the crystal lattice. In the past, these rates have been mainly characterized using solid-solid diffusion couple experiments involving olivine single crystals, thin films, or powder sources. Despite the presence of melt surrounding olivine in natural magmatic systems, very few experiments involving magma have been performed, largely because controlling interface reactions is difficult. For this study, we carried out olivine-melt diffusion experiments as a test of the diffusion chronometry method, and to determine whether the presence of melt influences the calculated timescales. To approximate a natural system, we incorporated small natural Kīlauea and San Carlos olivine seeds within a natural Kīlauea basalt and tracked diffusive re-equilibration through time. To better control interface reactions, after some equilibration period at an initial superliquidus temperature of 1290 °C, the runs were rapidly cooled to form a rim and left to dwell at various final temperatures (1200, 1220, 1240, 1255 °C) for 6–84 h. Concentration gradients for Fe-Mg, Mn, Ni, Ca were measured, and the step-wise nature of the core-rim transition was ascertained using slow diffusing elements like P or Al. When these gradients are modeled using published diffusivities, the timescales retrieved are typically 10 times longer than the actual experiment durations. Thus, measured diffusivities are an order of magnitude faster than those previously obtained in olivine-solid source experiments, but they are in excellent agreement with the only two other melt-olivine datasets. We explore reasons for why melt-bearing olivine diffusion experiments tend to yield faster rates. The possible effects of (1) growth during diffusion, (2) diffusion during any initial dissolution step, and (3) extended tube or planar defects at the interface on calculated diffusivities are all considered but found to be inconsequential. Instead, we argue that additional point defects (vacancies) are likely created at the interface by higher concentrations in elements like Al or H in the basalt melt compared to other solid couple diffusant sources. Future applications of diffusion chronometry in olivine may require a complete re-evaluation of published diffusivities using melt-bearing experimental configurations.

Earth and Planetary Science Letters

Characterizing the diverse hydrogeology underlying rivers and estuaries using new floating transient electromagnetic methodology

The hydrogeology below large surface water features such as rivers and estuaries is universally under-informed at the long reach to basin scales (tens of km+). This challenge inhibits the accurate modeling of fresh/saline groundwater interfaces and groundwater/surface water exchange patterns at management-relevant spatial extents. Here we introduce a towed, floating transient electromagnetic (TEM) system (i.e. FloaTEM) for rapid (up to 15 km/h) high resolution electrical mapping of the subsurface below large water bodies to depths often a factor of 10 greater than other towed instruments. The novel FloaTEM system is demonstrated at a range of diverse 4th through 6th-order riverine settings across the United States including 1) the Farmington River, near Hartford, Connecticut; 2) the Upper Delaware River near Barryville, New York; 3) the Tallahatchie River near Shellmound, Mississippi; and, 4) the Eel River estuary, on Cape Cod, near Falmouth, Massachusetts. Airborne frequency-domain electromagnetic and land-based towed TEM data are also compared at the Tallahatchie River site, and streambed geologic scenarios are explored with forward modeling. A range of geologic structures and pore water salinity interfaces were identified. Process-based interpretation of the case study data indicated FloaTEM can resolve varied sediment-water interface materials, such as the accumulation of fines at the bottom of a reservoir and permeable sand/gravel riverbed sediments that focus groundwater discharge. Bedrock layers were mapped at several sites, and aquifer confining units were defined at comparable resolution to airborne methods. Terrestrial fresh groundwater discharge with flowpaths extending hundreds of meters from shore was also imaged below the Eel River estuary, improving on previous hydrogeological characterizations of that nutrient-rich coastal exchange zone. In summary, the novel FloaTEM system fills a critical gap in our ability to characterize the hydrogeology below surface water features and will support more accurate prediction of groundwater/surface water exchange dynamics and fresh-saline groundwater interfaces.

Science of the Total Environment

Time-dependent pore filling

Capillarity traps fluids in porous media during immiscible fluid displacement. Most field situations involve relatively long time scales, such as hydrocarbon migration into reservoirs, resource recovery, nonaqueous phase liquid remediation, geological CO 2 storage, and sediment‐atmosphere interactions. Yet laboratory studies and numerical simulations of capillary phenomena rarely consider the impact of time on these processes. We use time‐lapse microphotography to record the evolution of saturation in air‐ or hydrocarbon‐filled capillary tubes submerged in water to investigate long‐term pore filling phenomena beyond imbibition. Microphotographic sequences capture a lively pore filling history where various concurrent physical phenomena coexist. Dissolution and diffusion play a central role. Observations indicate preferential transport of the wetting liquid along corners, vapor condensation, capillary flow induced by asymmetrical interfaces, and interface pinning that defines the diffusion length. Other processes include internal snap‐offs, fluid redistribution, and changes in wettability as fluids dissolve into each other. Overall, the rate of pore filling is diffusion‐controlled for a given interfacial configuration; diffusive transport takes place at a constant rate for pinned interfaces and is proportional to the square root of time for free interfaces where the diffusion length increases with time.

Water Resources Research

Spectral element modelling of fault-plane reflections arising from fluid pressure distributions

The presence of fault-plane reflections in seismic images, besides indicating the locations of faults, offers a possible source of information on the properties of these poorly understood zones. To better understand the physical mechanism giving rise to fault-plane reflections in compacting sedimentary basins, we numerically model the full elastic wavefield via the spectral element method (SEM) for several different fault models. Using well log data from the South Eugene Island field, offshore Louisiana, we derive empirical relationships between the elastic parameters (e.g. P-wave velocity and density) and the effective-stress along both normal compaction and unloading paths. These empirical relationships guide the numerical modelling and allow the investigation of how differences in fluid pressure modify the elastic wavefield. We choose to simulate the elastic wave equation via SEM since irregular model geometries can be accommodated and slip boundary conditions at an interface, such as a fault or fracture, are implemented naturally. The method we employ for including a slip interface retains the desirable qualities of SEM in that it is explicit in time and, therefore, does not require the inversion of a large matrix. We performa complete numerical study by forward modelling seismic shot gathers over a faulted earth model using SEM followed by seismic processing of the simulated data. With this procedure, we construct post-stack time-migrated images of the kind that are routinely interpreted in the seismic exploration industry. We dip filter the seismic images to highlight the fault-plane reflections prior to making amplitude maps along the fault plane. With these amplitude maps, we compare the reflectivity from the different fault models to diagnose which physical mechanism contributes most to observed fault reflectivity. To lend physical meaning to the properties of a locally weak fault zone characterized as a slip interface, we propose an equivalent-layer model under the assumption of weak scattering. This allows us to use the empirical relationships between density, velocity and effective stress from the South Eugene Island field to relate a slip interface to an amount of excess pore-pressure in a fault zone. ?? 2007 The Authors Journal compilation ?? 2007 RAS.

Geophysical Journal International

The 2023 Alaska National Seismic Hazard Model

US Geological Survey (USGS) National Seismic Hazard Models (NSHMs) are used extensively for seismic design regulations in the United States and earthquake scenario development, as well as risk assessment and mitigation for both buildings and infrastructure. This 2023 update of the long-term, time-independent Alaska NSHM includes substantial changes to both the earthquake rupture forecast (ERF) and ground motion models (GMMs). The ERF includes numerous additions to the finite-fault model, considers two deformation models, and introduces updated declustering and smoothing algorithms in the gridded background seismicity model. For the Alaska–Aleutian subduction zone, megathrust earthquakes occur on an updated structural and segmentation model, and the moment magnitude (M) 8+ rupture and rate model include a logic tree branch that considers slip rates derived from geodetic models of interface coupling. The megathrust model considers multiple models of down-dip width, and magnitudes are computed using newly developed scaling relations. For subduction intraslab events and subduction interface events with M < 7, the 2023 update uses a smoothed seismicity model with rupture depths derived from Slab2. The 2023 model updates GMMs in all tectonic settings using the recently published Next Generation Attenuation Subduction (NGA-Sub) GMMs for subduction interface and intraslab events, and the NGA-West2 GMMs for active crustal settings. Collectively, additions and updates to the Alaska NSHM result in hazard increases across most of south-central Alaska relative to the previous model, published in 2007. These changes are primarily due to the adoption of updated rate models for the large-magnitude interface events and the NGA-Sub GMMs that have much higher aleatory variability (sigma), consistent with global observations, and that include models of epistemic uncertainty.

Alaska

A new model for tabular-type uranium deposits

Tabular-type uranium deposits occur as tabular, originally subhorizontal bodies entirely within reduced fluvial sandstones of Late Silurian age or younger. This paper proposes that belts of tabular-type uranium deposits formed in areas of mixed local and regional ground-water discharge shortly after deposition of the host sediments. The general characteristics of tabular-type uranium deposits, especially the most studied deposits, those in the Uravan mineral belt, Henry basin, and Grants uranium region, indicate that their essential feature was the formation at a density-stratified ground-water interface in areas of local and regional ground-water discharge. Reconstruction of the paleohydrogeology is the key to understanding the formation of these deposits. Gravity-driven ground water recharged in major highlands and discharged in lowlands at major concave changes in paleotopographic slope. Shallow local and deep regional ground-water systems were characterized by dilute and saline water, respectively. Typically, underlying marine rocks, especially evaporites, provided the solutes to the deep regional ground water. A density-stabilized interface existed at the ground-water divide between local and regional flow systems. Tabular-type uranium deposits formed where these divides or interfaces intersected pockets of reduction where organic matter accumulated. The precipitation of humate and uranium at an interface accounts for the tabular shape and the tendency of deposits to rise stratigraphically into the basin. Geologic ground-water controls that favor discharge, such as the pinch-out of major aquifers, are also favorable for uranium ore. The combination of topographic and geologic features that both cause discharge is most favorable for ore deposition.

Economic Geology

A graphical modeling tool for evaluating nitrogen loading to and nitrate transport in ground water in the mid-Snake region, south-central Idaho

A flow and transport model was created with a graphical user interface to simplify the evaluation of nitrogen loading and nitrate transport in the mid-Snake region in south-central Idaho. This model and interface package, the Snake River Nitrate Scenario Simulator, uses the U.S. Geological Survey's MODFLOW 2000 and MOC3D models. The interface, which is enabled for use with geographic information systems (GIS), was created using ESRI's royalty-free MapObjects LT software. The interface lets users view initial nitrogen-loading conditions (representing conditions as of 1998), alter the nitrogen loading within selected zones by specifying a multiplication factor and applying it to the initial condition, run the flow and transport model, and view a graphical representation of the modeling results. The flow and transport model of the Snake River Nitrate Scenario Simulator was created by rediscretizing and recalibrating a clipped portion of an existing regional flow model. The new subregional model was recalibrated with newly available water-level data and spring and ground-water nitrate concentration data for the study area. An updated nitrogen input GIS layer controls the application of nitrogen to the flow and transport model. Users can alter the nitrogen application to the flow and transport model by altering the nitrogen load in predefined spatial zones contained within similar political, hydrologic, and size-constrained boundaries.

Scientific Investigations Report

Simulation of Variable-Density Ground-Water Flow and Saltwater Intrusion beneath Manhasset Neck, Nassau County, New York, 1905-2005

The coastal-aquifer system of Manhasset Neck, Nassau County, New York, has been stressed by pumping, which has led to saltwater intrusion and the abandonment of one public-supply well in 1944. Measurements of chloride concentrations and water levels in 2004 from the deep, confined aquifers indicate active saltwater intrusion in response to public-supply pumping. A numerical model capable of simulating three-dimensional variable-density ground-water flow and solute transport in heterogeneous, anisotropic aquifers was developed using the U.S. Geological Survey finite-element, variable-density, solute-transport simulator SUTRA, to investigate the extent of saltwater intrusion beneath Manhasset Neck. The model is composed of eight layers representing the hydrogeologic system beneath Manhasset Neck. Four modifications to the area?s previously described hydrogeologic framework were made in the model (1) the bedrock-surface altitude at well N12191 was corrected from a previously reported value, (2) part of the extent of the Raritan confining unit was shifted, (3) part of the extent of the North Shore confining unit was shifted, and (4) a clay layer in the upper glacial aquifer was added in the central and southern parts of the Manhasset Neck peninsula. Ground-water flow and the location of the freshwater-saltwater interface were simulated for three conditions (time periods) (1) a steady-state (predevelopment) simulation of no pumping prior to about 1905, (2) a 40-year transient simulation based on 1939 pumpage representing the 1905-1944 period of gradual saltwater intrusion, and (3) a 60-year transient simulation based on 1995 pumpage representing the 1945-2005 period of stabilized withdrawals. The 1939 pumpage rate (12.1 million gallons per day (Mgal/d)) applied to the 1905-1944 transient simulation caused modeled average water-level declines of 2 and 4 feet (ft) in the shallow and deep aquifer systems from predevelopment conditions, respectively, a net decrease of 5.2 Mgal/d in freshwater discharge to offshore areas and a net increase of 6.9 Mgal/d of freshwater entering the model from the eastern, western, and southern lateral boundaries. The 1995 pumpage rate (43.3 Mgal/d) applied to the 1945-2005 transient simulation caused modeled average water-level declines of 5 and 8 ft in the shallow and deep aquifer systems from predevelopment conditions, respectively, a net decrease of 13.2 Mgal/d in freshwater discharge to offshore areas and a net increase of 30.1 Mgal/d of freshwater entering the model from the eastern, western, and southern lateral boundaries. The simulated decrease in freshwater discharge to the offshore areas caused saltwater intrusion in two parts of the deep aquifer system under Manhasset Neck. Saline ground water simulated in a third part of the deep aquifer system under Manhasset Neck was due to the absence of the North Shore confining unit near Sands Point. Simulated chloride concentrations greater than 250 milligrams per liter (mg/L) were used to represent the freshwater-saltwater interface, and the movement of this concentration was evaluated for transient simulations. The decrease in the 1905-1944 simulated freshwater discharge to the offshore areas caused the freshwater-saltwater interface in the deep aquifer system to advance landward more than 1,700 ft from its steady-state position in the vicinity of Baxter Estates Village, Long Island, New York. The decrease in the 1945-2005 simulated freshwater discharge to the offshore areas caused a different area of the freshwater-saltwater interface in the deep aquifer system to advance more than 600 ft from its steady-state position approximately 1 mile south of the Baxter Estates Village. However, the 1945-2005 transient simulation underestimates the concentration and extent of saltwater intrusion determined from water-quality samples collected from wells N12508 and N12793, where measured chloride concentrations increased from 625 and 18 mg/L in 1997 t

Scientific Investigations Report

Water movement through the unsaturated zone of the High Plains Aquifer in the Central Platte Natural Resources District, Nebraska, 2008-12

Uncertainty about the effects of land use and climate on water movement in the unsaturated zone and on groundwater recharge rates can lead to uncertainty in water budgets used for groundwater-flow models. To better understand these effects, a cooperative study between the U.S. Geological Survey and the Central Platte Natural Resources District was initiated in 2007 to determine field-based estimates of recharge rates in selected land-use areas of the Central Platte Natural Resources District in Nebraska. Measured total water potential and unsaturated-zone profiles of tritium, chloride, nitrate as nitrogen, and bromide, along with groundwater-age dates, were used to evaluate water movement in the unsaturated zone and groundwater recharge rates in the central Platte River study area. Eight study sites represented an east-west precipitation contrast across the study area—four beneath groundwater-irrigated cropland (sites 2, 5, and 6 were irrigated corn and site 7 was irrigated alfalfa/corn rotation), three beneath rangeland (sites 1, 4, and 8), and one beneath nonirrigated cropland, or dryland (site 3). Measurements of transient vertical gradients in total water potential indicated that periodic wetting fronts reached greater mean maximum depths beneath the irrigated sites than beneath the rangeland sites, in part, because of the presence of greater and constant antecedent moisture. Beneath the rangeland sites, greater temporal variation in antecedent moisture and total water potential existed and was, in part, likely a result of local precipitation and evapotranspiration. Moreover, greater variability was noticed in the total water potential profiles beneath the western sites than the corresponding eastern sites, which was attributed to less mean annual precipitation in the west. The depth of the peak post-bomb tritium concentration or the interface between the pre-bomb/post-bomb tritium, along with a tritium mass balance, within sampled soil profiles were used to estimate water fluxes in the unsaturated zone at three of the eight study sites: site 2 (irrigated), site 3 (dryland), and site 8 (rangeland). Estimates for recharge were about 68 millimeters per year [(mm/yr), post-bomb peak], 133 to 159 mm/yr (tritium interface), and 137 mm/yr (mass balance) at site 2 (irrigated); about 63 mm/yr (tritium interface) and 12 mm/yr (mass balance) at site 3 (dryland); and about 53 mm/yr (tritium interface) and 10 mm/yr (mass balance) at site 8 (rangeland). Recharge values from the mass balance at site 2 were more than an order of magnitude greater than recharge values at site 3, suggesting irrigation is an important control on water movement through the unsaturated zone. For the remaining five sites, the post-bomb tritium had flushed through the system and recharge was considered modern (within 10 years of sampling). The chloride mass-balance method was used to determine water fluxes below the root zone (less than 2 meters below land surface) at the rangeland sites: sites 1, 4, and 8. At these rangeland sites, water fluxes ranged from 1.8 to 96 mm/yr at site 1, 1.1 to 9.6 mm/yr at site 4, and 1.1 to 68 mm/yr at site 8, with mean rates of 21, 4.3, and 13 mm/yr, respectively. Site 1 had a greater mean water flux, which was consistent with the greater precipitation in the east than at site 8 in the west. Chloride mass balance was not calculated at the irrigated and dryland sites because of uncertainty about additional sources of chloride. Concentrations of nitrate as nitrogen in pore water in the unsaturated zone were larger beneath the irrigated and dryland (agricultural) sites compared with the rangeland sites. The larger concentrations at the agricultural sites are consistent with the application of nitrogen fertilizer at the agricultural sites and no substantial accumulation at the rangeland sites. The shape of the nitrate as nitrogen and chloride concentration profiles at site 1 (rangeland) indicate a reasonably larger and more consistent water flux in the UZ than beneath the other two rangeland sites (sites 4 or 8). Excluding site 7, the general shape of the nitrate as nitrogen profiles was similar beneath the agricultural sites and supports the estimates of water movement and recharge rates determined from the tritium and chloride methods. Movement of bromide through the unsaturated zone indicated greater water fluxes are found beneath irrigated lands than beneath rangeland. Bromide profiles in the unsaturated zone, determined from center of mass and peak displacement methods, document water fluxes ranged from 58 to 394 mm/yr beneath irrigated sites and 9 to 201 mm/yr beneath rangeland sites. Water-flux estimates from the potassium bromide tests at most sites did not represent overall recharge rates because the bromide remained primarily in the root zone. Apparent groundwater age was used to determine the groundwater residence time at the eight sites and to estimate recharge rates. Groundwater ages in the study area ranged from old water (defined here as groundwater that was recharged more than 50 years ago) to modern (defined here as groundwater that has recharged within the past 10 years). Groundwater ages indicated that the shallow monitoring wells generally had younger residence times, whereas the deeper monitoring wells generally had the older residence times. Groundwater dates from the shallowest monitoring wells were used to determine recharge rates at the water table. These rates generally were similar to recharge rates determined from tritium and chloride mass-balance methods. Groundwater recharge rates generally increased with well depth, and the deeper monitoring wells likely do not represent local recharge conditions but recharge from a regional flow system that receives recharge from distant sources. Overall, these data generally indicate that water movement within the unsaturated zone primarily is affected by spatial contrasts in mean annual precipitation and by the land use or land cover. The eight unsaturated-zone sites each generated unique, valuable datasets that likely will improve the understanding of water movement and recharge rates in the central Platte River valley.

Nebraska

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts

Determination of infiltration and percolation rates along a reach of the Santa Fe River near La Bajada, New Mexico

Two methods, one a surface-water method and the second a ground-water method, were used to determine infiltration and percolation rates along a 2.5-kilometer reach of the Santa Fe River near La Bajada, New Mexico. The surface-water method uses streamflow measurements and their differences along a stream reach, streamflow-loss rates, stream surface area, and evaporation rates to determine infiltration rates. The ground-water method uses heat as a tracer to monitor percolation through shallow streambed sediments. Data collection began in October 1996 and continued through December 1997. During that period the stream reach was instrumented with three streamflow gages, and temperature profiles were monitored from the stream-sediment interface to about 3 meters below the streambed at four sites along the reach. Infiltration is the downward flow of water through the stream- sediment interface. Infiltration rates ranged from 92 to 267 millimeters per day for an intense measurement period during June 26- 28, 1997, and from 69 to 256 millimeters per day during September 27-October 6, 1997. Investigators calculated infiltration rates from streamflow loss, stream surface-area measurements, and evaporation-rate estimates. Infiltration rates may be affected by unmeasured irrigation-return flow in the study reach. Although the amount of irrigation-return flow was none to very small, it may result in underestimation of infiltration rates. The infiltration portion of streamflow loss was much greater than the evaporation portion. Infiltration accounted for about 92 to 98 percent of streamflow loss. Evaporation-rate estimates ranged from 3.4 to 7.6 millimeters per day based on pan-evaporation data collected at Cochiti Dam, New Mexico, and accounted for about 2 to 8 percent of streamflow loss. Percolation is the movement of water through saturated or unsaturated sediments below the stream-sediment interface. Percolation rates ranged from 40 to 109 millimeters per day during June 26-28, 1997. Percolation rates were not calculated for the September 27-October 6, 1997, period because a late summer flood removed the temperature sensors from the streambed. Investigators used a heat-and-water flow model, VS2DH (variably saturated, two- dimensional heat), to calculate near-surface streambed infiltration and percolation rates from temperatures measured in the stream and streambed. Near the stream-sediment interface, infiltration and percolation rates are comparable. Comparison of infiltration and percolation rates showed that infiltration rates were greater than percolation rates. The method used to calculate infiltration rates accounted for net loss or gain over the entire stream reach, whereas the method used to calculate percolation was dependent on point measurements and, as applied in this study, neglected the nonvertical component of heat and water fluxes. In general, using the ground-water method was less labor intensive than making a series of streamflow measurements and relied on temperature, an easily measured property. The ground-water method also eliminated the difficulty of measuring or estimating evaporation from the water surface and was therefore more direct. Both methods are difficult to use during periods of flood flow. The ground-water method has problems with the thermocouple-wire temperature sensors washing out during flood events. The surface- water method often cannot be used because of safety concerns for personnel making wading streamflow measurements.

New Mexico

Challenges and opportunities developing mathematical models of shared pathogens of domestic and wild animals

Diseases that affect both wild and domestic animals can be particularly difficult to prevent, predict, mitigate, and control. Such multi-host diseases can have devastating economic impacts on domestic animal producers and can present significant challenges to wildlife populations, particularly for populations of conservation concern. Few mathematical models exist that capture the complexities of pathogens, yet development of such models would allow us to estimate and compare the potential effectiveness of management actions for mitigating or suppressing disease in wildlife and/or livestock host populations. We conducted a workshop in March 2014 to identify the challenges associated with developing models of pathogen transmission across the wildlife-livestock interface. The development of mathematical models of pathogen transmission at this interface is hampered by the difficulties associated with describing the host-pathogen systems including: 1) the identity of wildlife hosts, their distributions, and movement patterns, 2) the pathogen transmission pathways between wildlife and domestic animals, 3) the effects of the disease and concomitant mitigation efforts on wild and domestic animal populations, and 4) barriers to communication between sectors. To promote the development of mathematical models of transmission at this interface, we recommend further integration of modern quantitative techniques and improvement of communication among wildlife biologists, mathematical modelers, veterinary medicine professionals, producers, and other stakeholders concerned with the consequences of pathogen transmission at this important, yet poorly understood, interface.

Veterinary Sciences

Tectonic tremor observations across Alaska

Tectonic tremor is a semicontinuous, low-frequency seismic signal associated with stable fault motion at major plate boundaries worldwide. In subduction zones, tremor often coincides with geodetic transients that indicate discrete slow slip on the subducting plate interface. Because tremor epicenters offer better spatial and temporal resolution than geodetic inversions of slip, detecting tremor can provide important constraints on plate interface properties, coupling, and dynamics. But in Alaska, challenges abound. The geographic scale of the Alaska–Aleutian subduction zone, the limited land available for instruments in the Aleutian Islands, and the messy nature of the tremor signal itself inhibit efforts to uniformly catalog tremor. Here, I present an overview of such efforts and what can and cannot be inferred from where tremor has been observed. Reliable tremor observations are confined to south-central Alaska in conjunction with the subducting Yakutat microplate, and one section of the eastern Aleutian Islands near Unalaska, with scant evidence of tremor elsewhere. Unique fault interface conditions may explain why tremor is limited to these regions, but most null results are not robust, and the limited observations preclude any large-scale interpretations.

Alaska

Peat porewater chloride concentration profiles in the Everglades during wet/dry cycles from January 1996 to June 1998: Field measurements and theoretical analysis

Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles.

Hydrological Processes

Water table rise sustains carbon release from soils in wetland-dominated landscapes: An intact soil core study

Wetland-dominated landscapes influence carbon cycling through their potential to act as both carbon sinks and sources. Wetlands in low-relief landscapes have dynamic terrestrial-aquatic interfaces that change seasonally with variable surface water and groundwater levels. However, few studies have directly quantified dissolved organic matter (DOM) release and greenhouse gas (CO 2 , CH 4 ) fluxes from wetland soils along terrestrial-aquatic interfaces as they are seasonally re-saturated by groundwater. To estimate groundwater-mediated soil DOM and gas fluxes, we performed laboratory simulations of vertical groundwater rise on intact soil cores collected from four Delmarva bay wetlands located in the Mid-Atlantic United States. At each wetland, one core was collected from within the wetland basin and the other from the transitional zone at the basin edge. Cores were re-saturated with groundwater over 15 days and then kept fully saturated for an additional 25 days. Source groundwater, soil porewater, and exfiltrated surface water samples were collected and analyzed for pH, ORP, DOM concentration, and DOM optical indices. In both the wetland and transition zone cores, porewater DOM concentrations increased over the wet up and were sustained during prolonged saturation. Optical indices shifted from recently produced, microbial-like signatures towards aromatic, terrestrial-like signatures. Fluxes of CO 2 decreased as the duration of soil saturation increased and soil cores switched from CH 4 sinks to sources upon full soil core saturation. Results indicate that groundwater rise sustains carbon mobilization from soils in wetland-dominated landscapes, emphasizing the need to understand how climate-driven changes to groundwater dynamics may affect carbon fluxes along terrestrial-aquatic interfaces.

Delaware, Maryland

Crisis crowdsourcing framework: designing strategic configurations of crowdsourcing for the emergency management domain

Crowdsourcing is not a new practice but it is a concept that has gained significant attention during recent disasters. Drawing from previous work in the crisis informatics, disaster sociology, and computer-supported cooperative work (CSCW) literature, the paper first explains recent conceptualizations of crowdsourcing and how crowdsourcing is a way of leveraging disaster convergence. The CSCW concept of &ldquo;articulation work&rdquo; is introduced as an interpretive frame for extracting the salient dimensions of &ldquo;crisis crowdsourcing.&rdquo; Then, a series of vignettes are presented to illustrate the evolution of crisis crowdsourcing that spontaneously emerged after the 2010 Haiti earthquake and evolved to more established forms of public engagement during crises. The best practices extracted from the vignettes clarified the efforts to formalize crisis crowdsourcing through the development of innovative interfaces designed to support the articulation work needed to facilitate spontaneous volunteer efforts. Extracting these best practices led to the development of a conceptual framework that unpacks the key dimensions of crisis crowdsourcing. The Crisis Crowdsourcing Framework is a systematic, problem-driven approach to determining the why, who, what, when, where, and how aspects of a crowdsourcing system. The framework also draws attention to the social, technological, organizational, and policy (STOP) interfaces that need to be designed to manage the articulation work involved with reducing the complexity of coordinating across these key dimensions. An example of how to apply the framework to design a crowdsourcing system is offered with with a discussion on the implications for applying this framework as well as the limitations of this framework. Innovation is occurring at the social, technological, organizational, and policy interfaces enabling crowdsourcing to be operationalized and integrated into official products and services.

Computer Supported Cooperative Work