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At least 271 records · Page 15Linked to original sources

Trace element abundances in major minerals of Late Permian coals from southwestern Guizhou province, China

Fourteen samples of minerals were separated by handpicking from Late Permian coals in southwestern Guizhou province, China. These 14 minerals were nodular pyrite, massive recrystallized pyrite, pyrite deposited from low-temperature hydrothermal fluid and from ground water; clay minerals; and calcite deposited from low-temperature hydrothermal fluid and from ground water. The mineralogy, elemental composition, and distribution of 33 elements in these samples were studied by optical microscopy, scanning electron microscope equipped with energy-dispersive X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), cold-vapor atomic absorption spectrometry (CV-AAS), atomic fluorescence spectrometry (AFS), inductively coupled-plasma mass spectrometry (ICP-MS), and ion-selective electrode (ISE). The results show that various minerals in coal contain variable amounts of trace elements. Clay minerals have high concentrations of Ba, Be, Cs, F, Ga, Nb, Rb, Th, U, and Zr. Quartz has little contribution to the concentration of trace elements in bulk coal. Arsenic, Mn, and Sr are in high concentrations in calcite. Pyrite has high concentrations of As, Cd, Hg, Mo, Sb, Se, Tl, and Zn. Different genetic types of calcite in coal can accumulate different trace elements; for example Ba, Co, Cr, Hg, Ni, Rb, Sn, Sr, and Zn are in higher concentrations in calcite deposited from low-temperature hydrothermal fluid than in that deposited from ground water. Furthermore, the concentrations of some trace elements are quite variable in pyrite; different genetic types of pyrites (Py-A, B, C, D) have different concentrations of trace elements, and the concentrations of trace elements are also different in pyrite of low-temperature hydrothermal origin collected from different locations. The study shows that elemental concentration is rather uniform in a pyrite vein. There are many micron and submicron mosaic pyrites in a pyrite vein, which is enriched in some trace elements, such as As and Mo. The content of trace element in pyrite vein depends upon the content of mosaic pyrite and of trace elements in it. Many environmentally sensitive trace elements are mainly contained in the minerals in coal, and hence the physical coal cleaning techniques can remove minerals from coal and decrease the emissions of potentially hazardous trace elements. ?? 2002 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology

National Park Service Vegetation Inventory Program, Cuyahoga Valley National Park, Ohio

The National Park Service (NPS) Vegetation Inventory Program (VIP) is an effort to classify, describe, and map existing vegetation of national park units for the NPS Natural Resource Inventory and Monitoring (I&M) Program. The NPS VIP is managed by the NPS Biological Resources Management Division and provides baseline vegetation information to the NPS Natural Resource I&M Program. The U.S. Geological Survey (USGS) Vegetation Characterization Program lends a cooperative role in the NPS VIP. The USGS Upper Midwest Environmental Sciences Center, NatureServe, and NPS Cuyahoga Valley National Park (CUVA) have completed vegetation classification and mapping of CUVA. Mappers, ecologists, and botanists collaborated to identify and describe vegetation types within the National Vegetation Classification Standard (NVCS) and to determine how best to map them by using aerial imagery. The team collected data from 221 vegetation plots within CUVA to develop detailed descriptions of vegetation types. Data from 50 verification sites were also collected to test both the key to vegetation types and the application of vegetation types to a sample set of map polygons. Furthermore, data from 647 accuracy assessment (AA) sites were collected (of which 643 were used to test accuracy of the vegetation map layer). These data sets led to the identification of 45 vegetation types at the association level in the NVCS at CUVA. A total of 44 map classes were developed to map the vegetation and general land cover of CUVA, including the following: 29 map classes represent natural/semi-natural vegetation types in the NVCS, 12 map classes represent cultural vegetation (agricultural and developed) in the NVCS, and 3 map classes represent non-vegetation features (open-water bodies). Features were interpreted from viewing color-infrared digital aerial imagery dated October 2010 (during peak leaf-phenology change of trees) via digital onscreen three-dimensional stereoscopic workflow systems in geographic information systems (GIS). The interpreted data were digitally and spatially referenced, thus making the spatial database layers usable in GIS. Polygon units were mapped to either a 0.5 ha or 0.25 ha minimum mapping unit, depending on vegetation type. A geodatabase containing various feature-class layers and tables shows the locations of vegetation types and general land cover (vegetation map), vegetation plot samples, verification sites, AA sites, project boundary extent, and aerial photographic centers. The feature-class layer and relate tables for the CUVA vegetation map provides 4,640 polygons of detailed attribute data covering 13,288.4 ha, with an average polygon size of 2.9 ha. Summary reports generated from the vegetation map layer show map classes representing natural/semi-natural types in the NVCS apply to 4,151 polygons (89.4% of polygons) and cover 11,225.0 ha (84.5%) of the map extent. Of these polygons, the map layer shows CUVA to be 74.4% forest (9,888.8 ha), 2.5% shrubland (329.7 ha), and 7.6% herbaceous vegetation cover (1,006.5 ha). Map classes representing cultural types in the NVCS apply to 435 polygons (9.4% of polygons) and cover 1,825.7 ha (13.7%) of the map extent. Map classes representing non-NVCS units (open water) apply to 54 polygons (1.2% of polygons) and cover 237.7 ha (1.8%) of the map extent. A thematic AA study was conducted of map classes representing natural/semi-natural types in the NVCS. Results present an overall accuracy of 80.7% (kappa index of 79.5%) based on data from 643 of the 647 AA sites. Most individual map-class themes exceed the NPS VIP standard of 80% with a 90% confidence interval. The CUVA vegetation mapping project delivers many geospatial and vegetation data products in hardcopy and/or digital formats. These products consist of an in-depth project report discussing methods and results, which include descriptions and a dichotomous key to vegetation types, map classification and map-class descriptions, and a contingency table showing AA results. The suite of products also includes a database of vegetation plots, verification sites, and AA sites; digital pictures of field sites; field data sheets; aerial photographic imagery; hardcopy and digital maps; and a geodatabase of vegetation types and land cover (map layer), fieldwork locations (vegetation plots, verification sites, and AA sites), aerial photographic index, project boundary, and metadata. All geospatial products are projected in Universal Transverse Mercator, Zone 17, by using the North American Datum of 1983. Information on the NPS VIP and completed park mapping projects are located on the Internet at <http://science.nature.nps.gov/im/inventory/veg> and <http://www.usgs.gov/core_science_systems/csas/vip/index.html>.

Natural Resource Technical Report

Geochemical evolution of groundwater in the Mud Lake area, eastern Idaho, USA

Groundwater with elevated dissolved-solids concentrations&mdash;containing large concentrations of chloride, sodium, sulfate, and calcium&mdash;is present in the Mud Lake area of Eastern Idaho. The source of these solutes is unknown; however, an understanding of the geochemical sources and processes controlling their presence in groundwater in the Mud Lake area is needed to better understand the geochemical sources and processes controlling the water quality of groundwater at the Idaho National Laboratory. The geochemical sources and processes controlling the water quality of groundwater in the Mud Lake area were determined by investigating the geology, hydrology, land use, and groundwater geochemistry in the Mud Lake area, proposing sources for solutes, and testing the proposed sources through geochemical modeling with PHREEQC. Modeling indicated that sources of water to the eastern Snake River Plain aquifer were groundwater from the Beaverhead Mountains and the Camas Creek drainage basin; surface water from Medicine Lodge and Camas Creeks, Mud Lake, and irrigation water; and upward flow of geothermal water from beneath the aquifer. Mixing of groundwater with surface water or other groundwater occurred throughout the aquifer. Carbonate reactions, silicate weathering, and dissolution of evaporite minerals and fertilizer explain most of the changes in chemistry in the aquifer. Redox reactions, cation exchange, and evaporation were locally important. The source of large concentrations of chloride, sodium, sulfate, and calcium was evaporite deposits in the unsaturated zone associated with Pleistocene Lake Terreton. Large amounts of chloride, sodium, sulfate, and calcium are added to groundwater from irrigation water infiltrating through lake bed sediments containing evaporite deposits and the resultant dissolution of gypsum, halite, sylvite, and bischofite.

Idaho

Using geochemistry to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: Part 2

Montezuma Well is a unique natural spring located in a sinkhole surrounded by travertine. Montezuma Well is managed by the National Park Service, and groundwater development in the area is a potential threat to the water source for Montezuma Well. This research was undertaken to better understand the sources of groundwater to Montezuma Well. Strontium isotopes ( 87 Sr/ 86 Sr) indicate that groundwater in the recharge area has flowed through surficial basalts with subsequent contact with the underlying Permian aged sandstones and the deeper, karstic, Mississippian Redwall Limestone. The distinctive geochemistry in Montezuma Well and nearby Soda Springs (higher concentrations of alkalinity, As, B, Cl, and Li) is coincident with added carbon dioxide and mantle-sourced He. The geochemistry and isotopic data from Montezuma Well and Soda Springs allow for the separation of groundwater samples into four categories: (1) upgradient, (2) deep groundwater with carbon dioxide, (3) shallow Verde Formation, and (4) mixing zone. δ 18 O and δD values, along with noble gas recharge elevation data, indicate that the higher elevation areas to the north and east of Montezuma Well are the groundwater recharge zones for Montezuma Well and most of the groundwater in this portion of the Verde Valley. Adjusted groundwater age dating using likely 14 C and δ 13 C sources indicate an age for Montezuma Well and Soda Springs groundwaters at 5,400–13,300 years, while shallow groundwater in the Verde Formation appears to be older (18,900). Based on water chemistry and isotopic evidence, groundwater flow to Montezuma Well is consistent with a hydrogeologic framework that indicates groundwater flow by (1) recharge in higher elevation basalts to the north and east of Montezuma Well, (2) movement through the upgradient Permian and Mississippian units, especially the Redwall Limestone, and (3) contact with a basalt dike/fracture system that provides a mechanism for groundwater to flow to the surface. While the exact nature of the groundwater flow connections is still uncertain, the available data indicate that flow to Montezuma Well may be more susceptible to future groundwater development in the Redwall Limestone than from any other geologic unit. Overall, the shallow groundwater in the surrounding Verde Formation appears to be largely disconnected from deeper groundwater flowing to Montezuma Well.

Arizona

Nationwide reconnaissance of contaminants of emerging concern in source and treated drinking waters of the United States: Pharmaceuticals

Mobile and persistent chemicals that are present in urban wastewater, such as pharmaceuticals, may survive on-site ormunicipal wastewater treatment and post-discharge environmental processes. These pharmaceuticals have the potential to reach surface and groundwaters, essential drinking-water sources. A joint, two-phase U.S. Geological Survey-U.S. Environmental Protection Agency study examined source and treated waters from 25 drinking-water treatment plants from across the United States. Treatment plants that had probable wastewater inputs to their source waters were selected to assess the prevalence of pharmaceuticals in such source waters, and to identify which pharmaceuticals persist through drinking-water treatment. All samples were analyzed for 24 pharmaceuticals in Phase I and for 118 in Phase II. In Phase I, 11 pharmaceuticals were detected in all source-water samples, with amaximumof nine pharmaceuticals detected in any one sample. The median number of pharmaceuticals for all 25 samples was five. Quantifiable pharmaceutical detections were fewer, with a maximum of five pharmaceuticals in any one sample and a median for all samples of two. In Phase II, 47 different pharmaceuticals were detected in all source-water samples, with a maximum of 41 pharmaceuticals detected in any one sample. The median number of pharmaceuticals for all 25 samples was eight. For 37 quantifiable pharmaceuticals in Phase II, median concentrations in source water were below 113 ng/L.

Science of the Total Environment

Regional controls on geomorphology, hydrology, and ecosystem integrity in the Orinoco Delta, Venezuela

Interacting river discharge, tidal oscillation, and tropical rainfall across the 22,000 km2 Orinoco delta plain support diverse fresh and brackish water ecosystems. To develop environmental baseline information for this largely unpopulated region, we evaluate major coastal plain, shallow marine, and river systems of northeastern South America, which serves to identify principal sources and controls of water and sediment flow into, through, and out of the Orinoco Delta. The regional analysis includes a summary of the geology, hydrodynamics, sediment dynamics, and geomorphic characteristics of the Orinoco drainage basin, river, and delta system. Because the Amazon River is a major source of sediment deposited along the Orinoco coast, we summarize Amazon water and sediment input to the northeastern South American littoral zone. We investigate sediment dynamics and geomorphology of the Guiana coast, where marine processes and Holocene history are similar to the Orinoco coast. Major factors controlling Orinoco Delta water and sediment dynamics include the pronounced annual flood discharge; the uneven distribution of water and sediment discharge across the delta plain; discharge of large volumes of water with low sediment concentrations through the Rio Grande and Araguao distributaries; water and sediment dynamics associated with the Guayana littoral current along the northeastern South American coast; inflow of large volumes of Amazon sediment to the Orinoco coast; development of a fresh water plume seaward of Boca Grande; disruption of the Guayana Current by Trinidad, Boca de Serpientes, and Gulf of Paria; and the constriction at Boca de Serpientes. ?? 2002 Elsevier Science B.V. All rights reserved.

Geomorphology

Polychlorinated dibenzo-p-dioxin and dibenzofuran concentration profiles in sediment and fish tissue of the Willamette Basin, Oregon

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) are highly hydrophobic compounds that have been implicated as carcinogens and, more recently, as estrogen disrupters. An occurrence and distribution study of these compounds in the Willamette Basin, Oregon, was conducted by the U.S. Geological Survey as part of the National Water-Quality Assessment Program. Bed sediment was collected from 22 sites; fish tissue was collected from eight sites. PCDD/F were found to be ubiquitous in Willamette Basin sediment. A distinct homolog profile, dominated by octachlorodibenzo-p-dioxin, was observed in sediment throughout the basin. The PCDD homolog profile was consistent at all sites, regardless of total PCDD/F concentration, presence of point sources, subbasin size, geographic location or land use. Principal components analysis revealed a gradient among the homolog profiles that showed increasing dominance of highly chlorinated congeners where human and industrial activity increased. Tissue and bed sediment obtained from the same site did not have similar PCDD/F concentrations or homolog profiles. Fish tissue showed enrichment in less chlorinated congeners and congeners with chlorine substitutions in the 2, 3, 7 and 8 positions.

Environmental Science & Technology

Predicting aquatic habitat connectivity across watershed boundaries: Implications for interbasin spread of nonindigenous aquatic species.

Understanding habitat connectivity is critical for managing nonindigenous aquatic species (NAS) spread. Dams and watershed boundaries can be impassable to NAS during typical conditions but may become temporarily passable during flooding. The goal of our project was to develop an approach for identifying locations of aquatic connectivity at a fine spatial scale along watershed boundaries using readily available data. To develop this approach, we focused on the potential for range expansion of invasive fish in the United States via possible cross-boundary habitat connections. First, we developed an index using metrics of elevation, watershed size, and geology at regular points along a watershed boundary to stratify points by likelihood of connectivity during high precipitation (>20 mm of precipitation in a 3-day period). We then used a subset of points across a gradient of connectivity likelihoods to gather Landsat-derived observed surface water data and developed a statistical model to predict surface water presence from landscape characteristics. We applied the model throughout the entire watershed boundary to identify locations of hydrologic connectivity during high-water events. The presence of surface water on watershed boundaries was predicted by the interactions between watershed boundary point elevation relative to the minimum adjacent HUC-12 elevations and watershed boundary point elevation relative to neighboring point elevations (marginal R 2 = 0.94). Our approach can be used to identify potential areas of surface water connectivity between watersheds quickly and easily at a fine spatial scale using readily available, remotely sensed data that can inform conservation and management actions across disciplines.

North Dakota, South Dakota

An evaluation of selenium concentrations in water, sediment, invertebrates, and fish from the Solomon River Basin

The Solomon River Basin is located in north-central Kansas in an area underlain by marine geologic shales. Selenium is an indigenous constituent of these shales and is readily leached into the surrounding groundwater. Portions of the Basin are irrigated primarily through the pumping of selenium-contaminated groundwater from wells onto fields in agricultural production. Water, sediment, macroinvertebrates, and fish were collected from various sites in the Basin in 1998 and analyzed for selenium. Selenium concentrations were analyzed spatially and temporally and compared to reported selenium toxic effect thresholds for specific ecosystem components: water, sediments, food-chain organisms, and wholebody fish. A selenium aquatic hazard assessment for the Basin was determined based on protocol established by Lemly. Throughout the Basin, water, macroinvertebrate, and whole fish samples exceeded levels suspected of causing reproductive impairment in fish. Population structures of several fish species implied that successful reproduction was occurring; however, the influence of immigration of fish from low-selenium habitats could not be discounted. Site-specific fish reproduction studies are needed to determine the true impact of selenium on fishery resources in the Basin. ?? Springer Science+Business Media B.V. 2007.

Environmental Monitoring and Assessment

Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States

Ungulate migration in a changing climate—An initial assessment of climate impacts, management priorities, and science needs

Executive Summary Migratory behavior among ungulates in the Western United States occurs in response to changing forage quality and quantity, weather patterns, and predation risk. As snow melts and vegetation green-up begins in late spring and early summer, many migratory ungulates leave their winter range and move to higher elevation summer ranges to access high-quality forage and areas with vegetative cover for protection during fawning. Ungulates remain on these ranges until the fall when increasing snowfall and decreasing temperatures trigger them to migrate back to their lower elevation winter ranges. While researchers have begun to assess the effects of physical barriers such as roads and energy infrastructure on migration, less attention has been paid to understanding how changing climate conditions might affect ungulate movements and range habitats. Does earlier spring green-up make ungulates leave their winter ranges sooner? Do persistent drought conditions reduce the carrying capacity of seasonal range habitats or lead to shifts in migration pathways? These and other questions remain largely unanswered but could have cascading effects on ungulate population dynamics and migratory behavior. In February 2018, the Secretary of the Interior signed Department of the Interior Secretarial Order 3362 (SO3362), “Improving Habitat Quality in Western Big-Game Winter Range and Migration Corridors.” The order, which focuses on elk, mule deer, and pronghorn in 11 Western States, directs the Bureau of Land Management (BLM), the U.S. Fish and Wildlife Service (FWS), the National Park Service (NPS), and the U.S. Geological Survey (USGS) to partner with State wildlife agencies on their priorities and objectives for identifying and conserving ungulate migration corridors and winter-range habitat. The USGS Climate Adaptation Science Centers (CASCs) were established to help managers of the Nation’s fish, wildlife, waters, and lands understand the effects of climate change and adapt to changing conditions. To support the recent Department of the Interior (DOI) emphasis on ungulate migration corridors and winter-range habitat, this report assesses current information on how climate change could affect elk, mule deer, and pronghorn migration. The report synthesizes the drivers of migration, outlines what is known about how climate change might affect these drivers, and summarizes management priorities and science needs related to ungulate migration corridors and range habitat. A review of the literature on ungulate migration shows that the core drivers of spring migration are the timing of spring green-up and snowmelt, and the core driver of fall migration is winter severity. After exploring what is known about how these drivers affect or could be affected by climate change, several pathways through which ungulate migration could be altered were identified: (1) ungulates alter migration timing to better track plant phenology or in response to changes in winter conditions; (2) ungulates change their migration route or distance traveled during migration to accommodate changes in environmental conditions; and (3) ungulate populations that are currently migratory may begin to demonstrate interannual variability in whether they migrate, depending on environmental conditions and density-dependence, and may remain resident for sets of consecutive years. Through discussions with managers, physical barriers to movement such as roads and fences were identified as a core concern. In addition, the primary research needs of States are the acquisition and analysis of data on ungulate movements, to refine delineation of winter range, summer range, and corridors, and to support a better understanding of how ungulates use these habitats. When it comes to understanding climate effects, managers were more concerned with understanding the vulnerability of winter- and summer-range habitats than the vulnerability of migration corridors because of the influence of summer and winter forage on ungulate condition and reproductive success. Managers were also concerned about how forage quality and quantity might change because of stressors such as drought, wildfire, and invasive species and how they might need to alter habitat-treatment strategies as a result. More baseline data are needed before effective projections of ungulate migration, at a West-wide scale under climate change, can be made. These data needs include (1) more clearly defined corridors and seasonal range habitats; (2) a comprehensive understanding of the ecological drivers of migration across ungulate species and populations; and (3) the identification of environmental thresholds for key variables that influence migration, above which ungulates alter migratory behavior. The CASCs have several opportunities to play a role in addressing these needs. The CASCs could initiate projects to identify past and potential future changes and trends in key variables known to affect ungulate migration, such as plant phenology, forage quality, or winter severity. However, it would be difficult to use this information to determine what those trends mean for ungulate migration due to the lack of knowledge about environmental thresholds for ungulates. Additional projects would be required to compare multiple years of movement data with key variables to define thresholds. Once available, information on environmental thresholds could be integrated with projections of key variables to forecast the likelihood that the migration routes or the distance traveled could change—another area in which the CASCs could contribute. A more immediate role for the CASCs would be to carry out synthesis projects. One such project could summarize the “state of the science” on the drivers of ungulate migration. Although there are dozens of population- and location-specific studies on this topic, collating this information could help highlight trends in migration drivers that span species and geographies: a necessary first step toward determining the extent to which migration drivers could be affected by climate change. A second project could focus on what is known about how climate variability and change affect ungulate life-histories, population dynamics, and migration in the Western United States. The goal of this effort could be to identify knowledge clusters and information gaps that require further investigation. Together, these synthesized products could focus future scientific activities on the most pressing issues of ungulate migration and climate change in the Western United States.

Arizona, California, Colorado, Idaho, Montana, New

Natural and anthropogenic influences on benthic cyanobacteria in streams of the northeastern United States

Benthic cyanobacteria are widespread in streams and rivers and have the potential to release toxins. In large numbers, these microorganisms and their toxins present a risk to human health. Cyanobacterial abundance in stream biofilms is typically related to single or a limited set of environmental factors, mainly light availability, water temperature, and nutrient concentrations. However, these factors may act synergistically with watershed characteristics and other stressors, such as anthropogenic pollutants, to affect cyanobacteria. We investigated the influence of multiple regional and local variables on the abundance of benthic cyanobacterial genera in streams using all subsets generalized additive modeling. We examined watershed factors (topography, geology, and climate) alongside in-stream factors (geomorphology, hydrology, pH, specific conductance, nutrients, organic contaminants, and dissolved metals) from 76 sites along an urban gradient in the northeast United States. Each genus responded to a distinct combination of environmental variables, demonstrating strong intergeneric variation in environmental selection of realized niches. Four of the 7 potentially toxigenic genera that we modeled were positively influenced by water temperature or nutrients. Nonetheless, watershed characteristics, streamflow, and/or other water quality pollutants were equally or more influential for the potentially toxigenic genera. Additionally, the relationships between cyanobacterial abundance and environmental factors varied in shape and direction across many genera. In particular, with increasing concentrations of herbicides, polychlorinated biphenyls, or metals, the abundance of roughly half of the affected genera decreased, while the others increased. These results likely demonstrate novel toxic effects of the pollutants on cyanobacterial genera in the environment, while indicating that unmeasured biotic interactions may lead to positive responses for other genera. Our results emphasize the need to consider variables beyond those that are most frequently measured or implicated (e.g., water temperature and nutrients) to more fully understand the environmental conditions that influence the distributions and abundance of potentially harmful cyanobacteria.

Connecticut, Massachusetts, New Hampshire. New Yor

Earth science and public health: Proceedings of the Second National Conference on USGS Health-Related Research

The mission of the U.S. Geological Survey (USGS) is to serve the Nation by providing reliable scientific information to describe and understand the earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life. As the Nation?s largest water, earth, and biological science and civilian mapping agency, the USGS can play a significant role in providing scientific knowledge and information that will improve our understanding of the relations of environment and wildlife to human health and disease. USGS human health-related research is unique in the Federal government because it brings together a broad spectrum of natural science expertise and information, including extensive data collection and monitoring on varied landscapes and ecosystems across the Nation. USGS can provide a great service to the public health community by synthesizing the scientific information and knowledge on our natural and living resources that influence human health, and by bringing this science to the public health community in a manner that is most useful. Partnerships with health scientists and managers are essential to the success of these efforts. USGS scientists already are working closely with the public health community to pursue rigorous inquiries into the connections between natural science and public health. Partnering agencies include the Armed Forces Institute of Pathology, Agency for Toxic Substances Disease Registry, Centers for Disease Control and Prevention, U.S. Environmental Protection Agency, Food and Drug Administration, Mine Safety and Health Administration, National Cancer Institute, National Institute of Allergy and Infectious Disease, National Institute of Environmental Health Sciences, National Institute for Occupational Safety and Health, U.S. Public Health Service, and the U.S. Army Medical Research Institute of Infectious Diseases. Collaborations between public health scientists and earth scientists can lead to improved solutions for existing and emerging environmental health problems. This report summarizes the presentations and discussions held at the Second National Conference on USGS Health-Related Research, held at the USGS national headquarters in Reston, Virginia. The report presents 68 abstracts of technical presentations made at the conference and summaries of six topical breakout sessions. The abstracts cover a broad range of issues and demonstrate connections between human health and the quality and condition of our environment and wildlife. The summaries of the topical breakout sessions present ideas for advancing interdisciplinary science in areas of earth science and human health.

Scientific Investigations Report

Effects of culverts on habitat connectivity in streams—A science synthesis to inform National Environmental Policy Act analyses

The U.S. Geological Survey is working with Federal land management agencies to develop a series of science syntheses to support environmental effects analyses that agencies conduct to comply with the National Environmental Policy Act (NEPA). This report synthesizes science information about the potential effects of culverts on stream connectivity and subsequent effects on fish. We conducted a structured search of published scientific literature to find information about (1) culvert design, installation, and degradation; (2) methods for analyzing culvert condition and quantifying stream connectivity; and (3) the effects of changes to stream connectivity on freshwater fish. We follow the organization first established in U.S. Geological Survey Scientific Investigations Report 2023-5114, in which the report sections align with standard elements of NEPA analyses. We found that, while the effects of dams on stream biota are well documented, smaller barriers at road crossings, like culverts, are prevalent and collectively have a substantial effect on habitat connectivity. Individual culverts differ in the degree to which they impede the movement of aquatic organisms, and we documented methods to assess and estimate the permeability of a culvert, or the ability of aquatic organisms to pass through it. Finally, we outlined methods for using culvert location and permeability information to quantify connectivity in a watershed based on the Dendritic Connectivity Index. Studies have shown that channel constriction, perched outlets, and extreme flow velocities are some of the characteristics of culverts that may hinder aquatic organism passage. Culverts can serve as daily and seasonal barriers to fish, disrupting access to habitat and essential resources like cold water or overwintering refuges. Reduced connectivity can have population-level effects, leading to lower fish species richness and abundance in affected watersheds. Public land managers can use this report by incorporating it by reference in NEPA documentation, as supplemental information, or as a general reference for literature about the effects of culverts on stream connectivity and freshwater fish.

Scientific Investigations Report

Comparison of Surface Flow Features from Lidar-Derived Digital Elevation Models with Historical Elevation and Hydrography Data for Minnehaha County, South Dakota

The U.S. Geological Survey (USGS) has taken the lead in the creation of a valuable remote sensing product by incorporating digital elevation models (DEMs) derived from Light Detection and Ranging (lidar) into the National Elevation Dataset (NED), the elevation layer of 'The National Map'. High-resolution lidar-derived DEMs provide the accuracy needed to systematically quantify and fully integrate surface flow including flow direction, flow accumulation, sinks, slope, and a dense drainage network. In 2008, 1-meter resolution lidar data were acquired in Minnehaha County, South Dakota. The acquisition was a collaborative effort between Minnehaha County, the city of Sioux Falls, and the USGS Earth Resources Observation and Science (EROS) Center. With the newly acquired lidar data, USGS scientists generated high-resolution DEMs and surface flow features. This report compares lidar-derived surface flow features in Minnehaha County to 30- and 10-meter elevation data previously incorporated in the NED and ancillary hydrography datasets. Surface flow features generated from lidar-derived DEMs are consistently integrated with elevation and are important in understanding surface-water movement to better detect surface-water runoff, flood inundation, and erosion. Many topographic and hydrologic applications will benefit from the increased availability of accurate, high-quality, and high-resolution surface-water data. The remotely sensed data provide topographic information and data integration capabilities needed for meeting current and future human and environmental needs.

Scientific Investigations Report

The National Geochemical Survey: Database and documentation

The USGS, in collaboration with other federal and state government agencies, industry, and academia, is conducting the National Geochemical Survey (NGS) to produce a body of geochemical data for the United States based primarily on stream sediments, analyzed using a consistent set of methods. These data will compose a complete, national-scale geochemical coverage of the US, and will enable construction of geochemical maps, refine estimates of baseline concentrations of chemical elements in the sampled media, and provide context for a wide variety of studies in the geological and environmental sciences. The goal of the NGS is to analyze at least one stream-sediment sample in every 289 km2 area by a single set of analytical methods across the entire nation, with other solid sample media substituted where necessary. The NGS incorporates geochemical data from a variety of sources, including existing analyses in USGS databases, reanalyses of samples in USGS archives, and analyses of newly collected samples. At the present time, the NGS includes data covering ~71% of the land area of the US, including samples in all 50 states. This version of the online report provides complete access to NGS data, describes the history of the project, the methodology used, and presents preliminary geochemical maps for all analyzed elements. Future editions of this and other related reports will include the results of analysis of variance studies, as well as interpretive products related to the NGS data.

Open-File Report

An innovative carbonate coprecipitation process for the removal of zinc and manganese from mining impacted waters

Although mine drainage is usually thought of as acidic, there are many cases where the water is of neutral pH, but still contains metal species that can be harmful to human or aquatic animal health, such as manganese (Mn) and zinc (Zn). Typical treatment of mine drainage waters involves pH adjustment, but this often results in excessive sludge formation and removal of nontoxic species such as magnesium and calcium. Theoretical consideration of the stability of metal carbonate species suggests that the target metals could be removed from solution by coprecipitation with calcium carbonate. The U.S. Geological Survey has developed a limestone-based process for remediation of acid mine drainage that increases calcium carbonate saturation. This treatment could then be coupled with carbonate coprecipitation as an innovative method for removal of toxic metals from circumneutral mine drainage waters. The new process was termed the carbonate coprecipitation (CCP) process. The CCP process was tested at the laboratory scale using a synthetic mine water containing 50 mg/L each of Mn and Zn. Best results showed over 95% removal of both Mn and Zn in less than 2 h of contact in a limestone channel. The process was then tested on a sample of water from the Palmerton zinc superfund site, near Palmerton, Pennsylvania, containing over 300 mg/L Zn and 60 mg/L Mn. Treatment of this water resulted in removal of over 95% of the Zn and 40% of the Mn in the limestone channel configuration. Because of the potential economic advantages of the CCP process, further research is recommended for refinement of the process for the Palmerton water and for application to other mining impacted waters as well. ?? Mary Ann Liebert, Inc.

Environmental Engineering Science

National Park Service Vegetation Mapping Inventory Program: Appalachian National Scenic Trail vegetation mapping project

The National Park Service (NPS) Vegetation Mapping Inventory (VMI) Program classifies, describes, and maps existing vegetation of national park units for the NPS Natural Resource Inventory and Monitoring (I&M) Program. The NPS VMI Program is managed by the NPS I&M Division and provides baseline vegetation information to the NPS Natural Resource I&M Program. The U.S. Geological Survey Upper Midwest Environmental Sciences Center, NatureServe, NPS Northeast Temperate Network, and NPS Appalachian National Scenic Trail (APPA) have completed vegetation classification and mapping of APPA for the NPS VMI Program. Mappers, ecologists, and botanists collaborated to affirm vegetation types within the U.S. National Vegetation Classification (USNVC) of APPA and to determine how best to map the vegetation types by using aerial imagery. Analyses of data from 1,618 vegetation plots were used to describe USNVC associations of APPA. Data from 289 verification sites were collected to test the field key to vegetation associations and the application of vegetation associations to a sample set of map polygons. Data from 269 validation sites were collected to assess vegetation mapping prior to submitting the vegetation map for accuracy assessment (AA). Data from 3,265 AA sites were collected, of which 3,204 were used to test accuracy of the vegetation map layer. The collective of these datasets affirmed 280 USNVC associations for the APPA vegetation mapping project. To map the vegetation and land cover of APPA, 169 map classes were developed. The 169 map classes consist of 150 that represent natural (including ruderal) vegetation types in the USNVC, 11 that represent cultural (agricultural and developed) vegetation types in the USNVC, 5 that represent natural landscapes with catastrophic disturbance or some other modification to natural vegetation preventing accurate classification in the USNVC, and 3 that represent nonvegetated water (non-USNVC). Features were interpreted from viewing 4-band digital aerial imagery using digital onscreen three-dimensional stereoscopic workflow systems in geographic information systems (GIS). (Digital aerial imagery was collected each fall during 2009–11 to capture leaf-phenology change of hardwood trees across the latitudinal range of APPA.) The interpreted data were digitally and spatially referenced, thus making the spatial-database layers usable in GIS. Polygon units were mapped to either a 0.5-hectare (ha) or 0.25-ha minimum mapping unit, depending on vegetation type or scenario; however, polygon units were mapped to 0.1 ha for alpine vegetation. A geodatabase containing various feature-class layers and tables provide locations and support data to USNVC vegetation types (vegetation map layer), vegetation plots, verification sites, validation sites, AA sites, project boundary extent and zones, and aerial image centers and flight lines. The feature-class layer and related tables of the vegetation map layer provide 30,395 polygons of detailed attribute data covering 110,919.7 ha, with an average polygon size of 3.6 ha; the vegetation map coincides closely with the administrative boundary for APPA. Summary reports generated from the vegetation map layer of the map classes representing USNVC natural (including ruderal) vegetation types apply to 28,242 polygons (92.9% of polygons) and cover 106,413.0 ha (95.9%) of the map extent for APPA. The map layer indicates APPA to be 92.4% forest and woodland (102,480.8 ha), 1.7% shrubland (1866.3 ha), and 1.8% herbaceous cover (2,065.9 ha). Map classes representing park-special vegetation (undefined in the USNVC) apply to 58 polygons (0.2% of polygons) and cover 404.3 ha (0.4%) of the map extent. Map classes representing USNVC cultural types apply to 1,777 polygons (5.8% of polygons) and cover 2,516.3 ha (2.3%) of the map extent. Map classes representing nonvegetated water (non-USNVC) apply to 332 polygons (1.1% of polygons) and cover 1,586.2 ha (1.4%) of the map extent.

Appalachian National Scenic Trail