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At least 253 records · Page 14Linked to original sources

lowaphyllum (rugose coral) from the Upper Devonian of Arizona

The rugose coral genus lowaphyllum is uncommon but widely distributed in rocks of Devonian age. It is here reported for the first time from western North America (Late Devonian). lowaphyllum is also known from the late Middle and Late Devonian of Eastern North America, but the lack of Early and early Middle Devonian species anywhere in North America leaves open the question of derivation of these forms and their relationship to Early Devonian species in Europe and Australia.

Arizona

Inventory of land use and land cover of the Puget Sound region using Landsat digital data

Landsat multispectral scanner digital data from four bands were analyzed using computers to produce land use and land cover information of the Puget Sound region, Wash., for use by agencies in that area. The data were first geographically registered to map coordinates. This registration enabled samples of known land cover types to be digitized from the maps. Samples of the same land cover were grouped together and then subdivided by cluster analysis into spectrally similar classes. Spectral categories were associated with specific land cover classes and used to determine spectral signatures for classification of the entire region. Reclustering and reclassification techniques were developed and then employed to minimize certain classification errors. The classified data were displayed in color using a film recorder. This color image was enlarged photographically to a 1:100000 scale to match new base maps of the region. Although the result resembles a conventional polygonal land use and land cover map, certain image-like qualities remain and yield additional information about the landscape.

Washington

Application of four input-output models for nutrients in Lake Okeechobee, Florida

R. A. Vollenweider's (1975) nonconservative model described concentrations of nitrogen and phosphorus for 1969-70 in Lake Okeechobee, Fla., better than the models of F. Biffi in 1963, R. H. Rainey in 1967, and R. Piontelli and V. Tonolli in 1964. Vollenweider's model predicted concentrations of 1.4 milligrams per liter of total nitrogen and 0.09 mg/L of total phosphorus in the lake. The concentration of nitrogen could be approximated with conservation models but phosphorus required a nonconservative model. Unless variations in input concentrations and flow rate of the tributaries are modeled, only short-term predictions of lake concentrations can be made because of variations in inflow concentrations and because of the short time required (400 days) for the lake to be flushed by its inflow.

Florida

Reconnaissance for microbial activity in the Magothy aquifer, Bay Park, New York, four years after artificial recharge

Tertiary-treated sewage effluent was injected into the Magothy aquifer at Bay Park, Long Island, N.Y., between 1968 and 1973. In 1977, the microbial flora in water samples from the injection well and from three nearby wells were surveyed. Differences in the composition of the microbial flora among the four wells were found. A bacterial community dominated by facultative and obligate anaerobes, including two Clostridium species and methanogenic bacteria, was found at a well 6.1 m from the injection well. By contrast, except for isolation of Clostridium sphenoides from a well 30 m away, only obligate aerobes and facultative anaerobes were found in water from the injection well and the 30 m well. Only a small number of obligate aerobes were found in samples from a well 61 m away. These results suggest that nutrients in the recharge water formed an organically enriched zone to at least a distance of 6.1 m from the point of injection but not as far as 61 m. Extensive pumping at the end of the injection program apparently removed exogeneous nutrients near the injection well.

New York

Simulation of flow from an aquifer to a partially penetrating trench

Construction of the Tennessee-Tombigbee Waterway in northeast Mississippi will involve dewatering as much as 46 m of an unconfined aquifer near the Tennessee Valley divide. Dewatering by trenching is one of the proposed methods. Methods of calculating effects of dewatering by trenching have been heretofore limited to situations where ideal conditions such as isotropic aquifers and fully penetrating trenches occur. In order to study the effects of trenching on the water table in the more complicated hydrologic system in northeast Mississippi, a two-dimensional cross-sectional digital model was developed from an existing two-dimensional digital model. To make the solutions obtained from the model applicable to any aquifer thickness or other hydrologic condition, a technique for nondimensional simulation was developed. With these techniques, nondimensional water-surface profiles were generated for given stages of trench penetration of the aquifer and for different ratios of anisotropy.

Mississippi

A method for adjusting values of Manning's roughness coefficient for flooded urban areas

A method is presented for adjusting values of Manning's roughness coefficient for flooded urban areas on the basis of the density of buildings on a flood plain and verified roughness coefficients for natural conditions. An urban roughness coefficient can be calculated to emulate the water-surface profiles to within 0.06 meter for depths of flow less than 0.6 meter and plus or minus 10 percent for depths between 0.6 and 2 meters.

Journal of Research of the U.S. Geological Survey

Periphyton and phytoplankton in the Sacramento River, California, May 1972 to April 1973

Periphyton and phytoplankton samples were collected monthly at five sites in the Sacramento River between May 1972 and April 1973. Periphyton were analyzed for species identification and biomass, and phytoplankton were analyzed for species identification and concentrations. The results were used to assess biological water-quality conditions in the river and to compare phytoplankton types and concentrations at three sites with those in 1960-61. Diatoms were the dominant group in both numbers and types of periphyton and phytoplankton. The number of genera and frequency of occurrence of periphyton increased downstream. The periphyton biomass decreased downstream and with succeeding monthly sampling periods. The highest productivity was at site B, below Red Bluff, probably because the Red Bluff Diversion Dam provides optimum conditions for periphyton growth. The decreasing productivity downstream is probably a function of higher sediment concentrations. The periphyton biomass ranged from 0.00 to 0.56 grams per square meter per day throughout the study period. Phytoplankton concentrations and diversity increased downstream. The highest phytoplankton concentration was 980 organisms per milliliter at site D, above Knights Landing, in September. The diversity indices ranged from 0.95 to 3.88 for all sites throughout the study period. Fewer phytoplankton genera were collected in 1972-73 than in 1960-61, but the generic composition was similar. Total phytoplankton concentrations were nearly always higher in 1960-61 than in 1972-73. Green algal concentrations were significantly higher ( p <0.05) at site C and diatoms were significantly higher at all three sites in 1960-61. Blue-green algal concentrations were higher in 1972-73, but differences between the two time intervals were not significant.

California

Feasibility and technology for making remote measurements of solutes in water

An indepth evaluation of the available technology in the field of laser-Raman spectroscopy indicates that a TV-type detector, a single monochromator with a holographic grating, an entrance slit filter blocking the Rayleigh light, and a pulsed laser coupled to signal averaging electronics is the best combination of commercial equipment that is presently available for building a remote water-quality sensor. The resultant sensor would be capable of measuring oxyanions in water at concentrations from 10 to 50 milligrams per liter at distances from ground level to 30 meters above the sample. The main interferences would be ambient light, bioluminescence, and natural fluorescence, all of which are minimized when taking advantage of the signal generating and readout capability contained in this equipment package.

Journal of Research of the U.S. Geological Survey

Chemical structure of humic acids - Part 1, a generalized structural model

A new model is proposed for the structure of humic acids. In this model humic acid is pictured as being made up of a hierarchy of structural elements. At the lowest level in this hierarchy are simple phenolic, quinoid, and benzene carboxylic acid groups. These groups are bonded covalently into small particles. Particles of similar chemical structure are linked together by weak bonds to form "homogeneous" aggregates. Two or more different types of aggregates may be linked together to form mixed aggregates. Complexes of humic acid and clay minerals are also formed.

Journal of Research of the U.S. Geological Survey

Chemical structure of humic acids - Part 2, the molecular aggregation of some humic acid fractions in N, N-dimethylformamide

Humic acid fractions form molecular aggregates in solution. In previous studies we have shown by small angle X-ray scattering that the size of these aggregates is a function of pH. In this study we have found that the size of the aggregates of two humic acid fractions in water and buffers and in dimethylformamide solutions can be changed by oxidation with molecular oxygen and air. These results cast new light on the bonding mechanisms that cause aggregation of the humic acid particles in solution. We have interpreted the changes in aggregation sizes as being brought about by changes in intermolecular and intramolecular hydrogen bonding of the humic particles. Solvation of the humic molecules by dimethylformamide interferes with some of the hydrogen bonding reactions between proton donor and acceptor groups on the same humic acid molecules or on different molecules.

Journal of Research of the U.S. Geological Survey

Thallium contents of 16 USGS standard rocks

Thallium was determined in 16 USGS standard rocks by atomic absorption spectroscopy in which a heated graphite atomizer was used after extraction as thallium iodide into amyl acetate. Four subsamples from four bottles of each standard sample, except G-1 and W-1, were analyzed in random order, and the average thallium contents in parts per million (as Tl) were AGV-1, 0.41; GSP-1, 1.63; G-2, 1.08; BCR-1, 0.35; SDC-1, 0.80; MAG-1, 0.79; BHVO-1, 0.049; SCO-1, 0.79; SGR-1, 0.34; QLO-1, 0.23; RGM-1, 1.07 ; STM-1, 0.30; DTS-1, <0.005; and PCC-1, <0.005. The analysis of variance showed that all samples may be considered homogeneous at F 0.975 and only GSP-1 may be considered heterogeneous at F 0.95 . The Tl contents of G-1 and W-1 are 1.0 and 0.12 ppm, respectively.

Journal of Research of the U.S. Geological Survey

An improved ion-selective electrode method for the rapid determination of fluorine in rocks and soil

An improved method based on an ion-selective electrode technique for the analysis of fluorine in rocks and soils is presented. Analyses are made by using a sodium carbonate-potassium carbonate fusion and a citric acid dissolution of the fuseate. Prior to determining the fluorine concentration by a standard-addition procedure, sodium citrate buffer is added to the solution. The proposed method yields fluorine values in agreement with known values for standard rocks. Values of this method are also presented for six geochemical exploration rock-and-soil reference samples and compared to those from other ion-selective electrode techniques. Fifty samples can be analyzed in 1 person-day. The sensitivity of the method is 100 parts per million, and samples containing up to 45 percent fluorine have been successfully analyzed.

Journal of Research of the U.S. Geological Survey

Preparation of pyrite-coated sand grains for research on roll-type uranium deposits

Ordinary quartz sand grains can be coated with pyrite for use in laboratory experiments on the genetic geochemistry of roll-type uranium deposits. The sand is first added to a ferric chloride solution. The slow addition of sodium hydroxide to the mixture gives the sand grains an iron oxide coating. This coating is then converted to pyrite by reaction with hydrogen sulfide, thus yielding a product suitable for experimental use.

Journal of Research of the U.S. Geological Survey

A thermostatic water bath for experimental studies in aqueous solutions

A temperature-controlled water bath for the study of ion-pairing equilibria and mineral solubility in aqueous solutions below 100&deg;C is described. The bath is similar to a previously described system (P. B. Hostetler and C. L. Christ, 1968, U.S. Geol. Survey Prof. Paper 600-D, p. D217-D221) but incorporates several significant improvements. Included among these are a more efficient stirring mechanism, a potentially larger solid-to-solution ratio, and improved equilibration of the gas phase with the solution.

Journal of Research of the U.S. Geological Survey

Pressure corrections for fluid-inclusion homogenization temperatures based on the volumetric properties of the system NaCl-H 2 O

A series of pressure correction diagrams for 1-, 5-, 10-, 15-, 20-, and 25-percent NaCl solutions has been generated from the volumetric data for NaCl by R. W. Potter II and D. L. Brown in 1975. The diagrams cover the temperature range from 20&deg; to 400&deg; C at pressures up to 200 megapascals (2000 bars). These data can be used to correct fluid-inclusion homogenization temperatures for pressures greater than the liquid-vapor pressure-temperature curve.

Journal of Research of the U.S. Geological Survey

Exploration geochemical studies of some sandstone copper-uranium deposits, Bradford, Columbia, and Lycoming Counties, Pa

Semi-quantitative spectrographic analyses of mineralized and unmineralized sandstone, siltstone, and claystone from the Catskill Formation of Devonian age in Bradford, Columbia, and Lycoming Counties, Pa., suggest that copper, silver, and uranium are the principal metallic elements concentrated in the mineralized rock. Lead, mercury, and molybdenum may be concentrated slightly in mineralized rock but values are too low to be of use in exploration. The deposits are too small to make large anomalies in stream sediments except in drainage basins of less than a few acres. However, if a large deposit were exposed to weathering, it would probably be detectable by stream sediment sampling. Analyses of oxalic acid leachates of the minus 80-mesh fraction of the stream-sediment samples gave more useful values than analyses of the minus 80-mesh samples in separating drainage basins that have copper deposits from those that have no known copper deposits.

Pennsylvania

Rare earths, thorium, and other minor elements in sphene from some plutonic rocks in west-central Alaska

Sphene is an abundant accessory mineral in some abnormally radioactive plutonic rocks in west-central Alaska. Seven samples of sphene from four different areas in west-central Alaska contained from 20350 to 39180 parts per million total rare earths and 390 to 2000 ppm thorium. The lanthanide content in six of the seven sphenes is chiefly the light rare earths and is similar to that of crustal abundance; a seventh sphene from the Darby Mountains, however, contains above average amounts of the heavy rare earths. A comparison of the lanthanide distribution in sphene from several areas indicates that the structure of sphene will accommodate whatever lanthanides are available when the mineral crystallizes. The amount of thorium and rare earths in sphene is also affected by the presence of other accessory minerals. Sphene in rocks containing either allanite or zircon has a lower thorium content than in rocks that do not contain allanite or zircon. Sphene, because of its abundance, may contain the greater part of the rare earths and thorium in some of the plutonic rocks of west-central Alaska.

Alaska

Occurrence of bloedite and related minerals in marine shale of Diablo and Temblor Ranges, California

Bloedite, epsomite, and related minerals occur in small amounts throughout the arid eastern foothills of the Diablo and Temblor Ranges, as efflorescences on siliceous shale and as deposits around small springs and a brine pond. These minerals ultimately are products of weathering of underlying organic shale, and they are reminders that the chemistry of weathering of reduced organic shale is largely a reversal of the chemistry of its early diagenesis.

California