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Effect of on-site wastewater disposal on quality of ground water and base flow: A pilot study in Chester County, southeastern Pennsylvania, 2005

On-site wastewater disposal has the potential to introduce contaminants into ground water and subsequently, by ground-water discharge, to streams. A pilot study was conducted during 2005 by the U.S. Geological Survey in cooperation with the Chester County Health Department and the Chester County Water Resources Authority to determine if wastewater components, including inorganic constituents and selected organic wastewater compounds, such as detergents, considered to be emerging contaminants, were present in ground water and stream base flow in areas with on-site wastewater disposal. The study area was a small watershed (about 7.1 square miles) of mixed land use drained by Broad Run in central Chester County, Pa. The area is underlain by fractured metamorphic rocks that form aquifers recharged by precipitation. Surface- and ground-water sampling was done in areas with and without on-site wastewater disposal for comparison, including a relatively densely populated village with cesspools and septic systems, a residential area with septic systems, a residential area served by sewers, and agricultural land. Samples were collected in May-June and September 2005 from eight headwater stream sites under base-flow conditions and in June 2005 from eight wells and two springs. Samples were analyzed for major ions, nutrients, boron, bacteria, and a suite of organic wastewater compounds. Several emerging contaminant wastewater compounds, including detergent components, insect repellents, and flame retardants, were detected in base-flow and ground-water samples. Stream base-flow samples generally contained more compounds and higher concentrations of those compounds than did ground-water samples, and of the ground-water samples, samples from springs contained more compounds and higher concentrations than samples from wells. Concentrations of nitrate, chloride, and boron (inorganic constituents associated with wastewater) generally were all elevated in base-flow and ground-water samples in areas with relatively high densities of on-site wastewater disposal (septic systems or cesspools) compared to other areas sampled. Results of this pilot study should be considered preliminary because of limited data.

Pennsylvania

Assessment of groundwater availability in the Northern Atlantic Coastal Plain aquifer system From Long Island, New York, to North Carolina

Executive Summary The U.S. Geological Survey began a multiyear regional assessment of groundwater availability in the Northern Atlantic Coastal Plain (NACP) aquifer system in 2010 as part of its ongoing regional assessments of groundwater availability of the principal aquifers of the Nation. The goals of this national assessment are to document effects of human activities on water levels and groundwater storage, explore climate variability effects on the regional water budget, and provide consistent and integrated information that is useful to those who use and manage the groundwater resource. As part of this nationwide assessment, the USGS evaluated available groundwater resources within the NACP aquifer system from Long Island, New York, to northeastern North Carolina. The northern Atlantic Coastal Plain physiographic province depends heavily on groundwater to meet agricultural, industrial, and municipal needs. The groundwater assessment of the NACP aquifer system included an evaluation of how water use has changed over time; this evaluation primarily used groundwater budgets and development of a numerical modeling tool to assess system responses to stresses from future human uses and climate trends. This assessment focused on multiple spatial and temporal scales to examine changes in groundwater pumping, storage, and water levels. The regional scale provides a broad view of the sources and demands on the system with time. The sub-regional scale provides an evaluation of the differing response of the aquifer system across geographic areas allowing for closer examination of the interaction between different aquifers and confining units and the changes in these interactions under pumping and recharge conditions in 2013 and hydrologic stresses as much as 45 years in the future. By focusing on multiple scales, water-resource managers may utilize this study to understand system response to changes as they affect the system as a whole. The NACP aquifer system extends from Long Island to northeastern North Carolina, and includes aquifers primarily within New York, New Jersey, Delaware, Maryland, Virginia, and North Carolina. The seaward-dipping sedimentary wedge that underlies the northern Atlantic Coastal Plain physiographic province forms a complex groundwater system. Although the NACP aquifer system is recognized by the U.S. Geological Survey as one of the smallest of the 66 principal aquifer systems in the Nation, it ranks 13th overall in terms of total groundwater withdrawals and is 7th in population served. Despite abundant precipitation [about 45 inches per year (in/yr)], the supply of fresh surface water in this region is limited because many of the surface waters in this area are brackish estuaries, contributing to why many communities in the northern Atlantic Coastal Plain physiographic province rely heavily on groundwater to meet their water needs. Increases in population and changes in land use during the past 100 years have resulted in diverse increased demands for freshwater throughout the northern Atlantic Coastal Plain physiographic province with groundwater serving as a vital source of drinking water for the nearly 20 million people who live in the region. Total groundwater withdrawal in 2013 was estimated to be about 1,300 million gallons per day (Mgal/d) and accounts for about 40 percent of the drinking water supply with the densely populated areas tending to have the highest rates of withdrawals and, therefore, being most susceptible to effects from these withdrawals over time. Water levels in many of the confined aquifers are decreasing by as much as 2 feet per year (ft/yr) in response to extensive development and subsequent increased withdrawals throughout the region. Total water-level decreases (drawdowns) are more than 100 feet (ft) in some aquifers from their predevelopment (before 1900) levels. These drawdowns extend across state lines and under the Chesapeake and Delaware Bays, creating the potential for interstate aquifer management issues. Regional water-resources managers in the northern Atlantic Coastal Plain physiographic province face challenges beyond competing local domestic, industrial, agricultural, and environmental demands for water. Large changes in regional water use have made the State-level management of aquifer resources more difficult because of hydrologic effects that extend beyond State boundaries. The northern Atlantic Coastal Plain physiographic province is underlain by a wedge of unconsolidated to partially consolidated sediments that are typically thousands of feet thick along the coastline with a maximum thickness of about 10,000 ft near the edge of the continental shelf. The NACP aquifer system consists of nine confined aquifers and nine confining units capped by an unconfined surficial aquifer that is bounded laterally from the west by the contact between Coastal Plain sediments and the upland Piedmont bedrock. This aquifer system extends to the east to the limit of the Continental Shelf, however, the boundary between fresh and saline groundwater is considered to be much closer to the shoreline and varies vertically by aquifer. Precipitation over the region for average conditions from 2005 to 2009 is about 61,800 Mgal/d, but about 70 percent of it is lost to evapotranspiration resulting in an inflow of about 19,600 Mgal/d entering the groundwater system as aquifer recharge. Most of this recharge enters the aquifer system and flows through the shallow unconfined aquifer and either discharges to streams or directly to coastal waters without reaching the deep, confined aquifer system. In addition to recharge from precipitation, other sources of water include the return of wastewater from domestic septic systems of about 240 Mgal/d, about 60 Mgal/d of water released from storage in the confined system, and about 30 Mgal/d of lateral inflow at the boundary between freshwater and saltwater in response to pumping for conditions in 2013. The outflow needed to balance the inflows was subdivided between streamflow, discharge to tidal portions of streams, and coastal discharge. The hydrologic budget developed for current [2013] conditions determined that 93 percent of the total outflow was to surface waters with about 70 percent divided evenly between streamflow and shallow coastal discharge and 23 percent as discharge to tidal waters. The remaining 7 percent of the total outflow components include withdrawals from both the surficial and confined aquifers of the groundwater system. The groundwater availability assessment of the NACP aquifer system highlights the importance of analyses at both the regional and local scales to understand how changes in land use, water use, and climate have affected groundwater resources and how these resources may change in the future. The investigation included assessments of the regional changes in water levels and budgets across State lines, the importance of considering storage change in the confining units, the response of the aquifer system to a continuation of current [2013] hydrologic stresses into the future, and the potential effects of climate change and sea-level rise on the aquifer system. The Potomac aquifer group includes two of the most widely used aquifers in the NACP aquifer system, the Potomac-Patapsco and Potomac-Patuxent regional aquifers, providing about 24 percent of the total groundwater used in the region. Withdrawals from large pumping centers in this deep, confined aquifer group have resulted in substantial decreases in water-levels across state lines, particularly between southern Virginia and northeastern North Carolina as well as between southern New Jersey and northern Delaware where water levels in the Potomac-Patapsco aquifer have decreased by as much as 200 ft and 50 ft, respectively from predevelopment to current [2013] conditions. This response in water levels also is reflected in changes in water budgets where, for example, about 20 percent of the total response to pumping in Virginia is met by inducing flow from adjacent States. Understanding and quantifying these hydrologic effects that extend beyond State boundaries is critical for the State- and regional-level management of aquifer resources. The cumulative storage loss from the intervening confining units throughout the entire NACP aquifer system was about 35 percent of the total storage loss from predevelopment to current [2013] conditions. In geographic areas such as Delmarva Peninsula, Maryland, and New Jersey, the water released from storage in the confining units makes up the majority of the total storage release from the groundwater system and is becoming proportionally more important over time as the surficial aquifer approaches equilibrium with respect to pumping and recharge stresses as of 2013. Storage loss from the confining units is of particular concern because, unlike in the sands that comprise the confined aquifers, water removed from the clayey confining unit sediments cannot be replenished as these units gradually compress. This non-recoverable storage loss, if great enough, can result in land subsidence where these units are thick and the release from storage is relatively large and contributes to increased concerns for sea-level rise in areas such as the lower portion of the Chesapeake Bay. Groundwater usage increased dramatically in the NACP aquifer system during post-World War II era from the mid-1940s to early the 1980s, with withdrawals increasing from about 400 Mgal/d to more than 1,300 Mgal/d. Although groundwater withdrawals have been relatively constant since the early 1980s, about half of the total groundwater withdrawn from the NACP aquifer system since 1900 was withdrawn in the past 30 years. An analysis of the response of the groundwater system to a continuation of the current [2013] pumping for an additional 30 years into the future shows that the flow system continues to adjust in terms of changes in water budget components, water levels, and the boundary between freshwater and saltwater as it approaches equilibrium. The largest change in water budget components is the reduction in the amount of water released from storage. Across the entire NACP aquifer system, the reduction of storage release from 7 to 4 percent of the total water budget change is accounted for by reductions in groundwater discharge to streams and coastal waters. Locally, a similar response is calculated for each of the geographic areas except for Virginia where the amount of water released from storage accounts for about 25 percent of the total change in water budget. This finding suggests that the groundwater flow system in Virginia is not approaching equilibrium under the current [2013] stresses and, therefore, water levels will continue to decrease even if the pumping remains constant. An analysis of the change in water levels in the Potomac-Patapsco aquifer as pumping is continued 30 years into the future reveals that the largest decreases in water levels throughout the NACP aquifer system will occur in the southern Virginia and northeastern North Carolina parts of the study area. It is these areas that also see the greatest potential for increased lateral movement of saline groundwater in the deep, confined portion of the groundwater flow system in response to a continuation of the current [2013] pumping rates. The potential effects of long-term climate change and variability on the hydrologic system and availability of water resources in the NACP aquifer system continue to be of serious societal concern. These concerns include the effects of changes in aquifer recharge and in sea-level rise on the groundwater flow system. An assessment of the potential effects of a prolonged drought during current [2013] pumping conditions indicated that the reductions in recharge associated with droughts, including additional irrigation withdrawals required to meet increased crop water demand, have the greatest effects on water levels and streamflows in the surficial aquifer, and changes in water levels in the confined aquifers primarily resulted from the increased withdrawals associated with increased irrigation pumping; this response was most apparent in the Delmarva Peninsula. These results suggest that water levels may not be susceptible to the effects of droughts in the confined aquifers of the NACP aquifer system not used for irrigation, unlike in the unconfined surficial aquifer. A second analysis also was conducted to assess the effects of sea-level rise on the groundwater system throughout the northern Atlantic Coastal Plain physiographic province because recent analyses of the relative rates of sea-level rise along the Atlantic coast indicate that the Mid-Atlantic region represents a hot spot with anomalously higher rates of sea-level rise than observed elsewhere in the United States. Groundwater levels rose from 0 to 3 ft in response to a 3-ft simulated change in sea-level position, with the largest response occurring along the shoreline and away from non-tidal streams. About 37 percent (or 10,000 square miles) of the area of the northern Atlantic Coastal Plain physiographic province may experience about a 0.5-ft or more increase in water levels with the 3-ft increase in sea-level position, whereas about 18 percent (almost 5,000 square miles) of land of the northern Atlantic Coastal Plain physiographic province may experience a 2-ft or more increase in water levels with the 3-ft increase in sea-level position. These increases in the water table are of particular concern in low-lying areas where the unsaturated (vadose) zone is already thin, thus creating concerns for groundwater inundation of subsurface infrastructure, such as basements, septic systems, and subway systems. This increase in the water table also will likely alter the distribution of groundwater discharge to surface-water bodies thus increasing groundwater flow to streams that would have otherwise discharged directly to coastal waters. Throughout the NACP aquifer system, this redistribution of groundwater discharge results in an additional 2 percent of base flow in streams. Although the increases in groundwater discharge to streams (and corresponding decreases in discharge to coastal waters) calculated for the entire NACP aquifer system and its geographic areas represent only a small increase compared with current [2013] conditions, this redistribution of groundwater discharge from the coast to streams locally can alter the delivery of freshwater input to coastal receiving waters and have ecohydrological implications on the sensitive ecosystems which rely on a balance of groundwater discharge and surface-water flow.

Delaware, Maryland, New Jersey, New York, North Ca

Microbiological and chemical quality of ground water used as a source of public supply in southern Missouri — Phase II, April–July, 1998

The protection of public health through quality public ground-water systems is the responsibility of the U. S. Environmental Protection Agency and the State of Missouri, through the Missouri Department of Natural Resources, Public Drinking Water Program. Approximately 95 percent of the public-water supplies in Missouri use ground water as their source of drinking water through more than 3,700 public wells. Karst terrain, intensive agricultural operations, extensive numbers of on-site sewage systems, and poor well construction can lead to chemical and microbiological contamination of the contributing aquifers. Sitespecific studies and routine regulatory monitoring have produced information on the overall quality and potability of the State's public-drinking-water supplies, but little is known about the presence of viruses. The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, sampled 109 public-water supplies to characterize the physical, chemical, bacterial, and viral conditions in southern Missouri. During April to July 1998, these wells were sampled for nutrients, total organic carbon, optical brighteners, indicator bacteria, enteric viruses, and ribonucleic acid and somatic coli phages. These constituents indicate possible surface contamination of the sampled aquifer. Selection of the wells to be sampled depended on the age of the well (pre-1970), land use, geohydrology, and well construction. None of the physical or chemical constituents measured or analyzed exceeded Missouri's Drinking Water Standards set by the Public Drinking Water Program of the Missouri Department of Natural Resources. The majority of ammonia plus organic nitrogen, nitrite, and phosphorus concentrations were below the laboratory's minimum reporting levels. There were a greater number of detects above the minimum reporting level with respect to the nitrite plus nitrate, ammonia, orthophosphate, and total organic carbon concentrations. Analyses included comparing and contrasting the data by grouping according to well age and construction, karst type, geohydrology, soil type, and land use. There was little variation in well construction between selected wells. The results indicated several groupings of similar and dissimilar concentrations, most expected because of hydrological, physical, or land use differences. Dissolved oxygen values indicated distinct variation in the different groupings. There were significant differences in dissolved oxygen values between the secondary and non-karst areas, the Ozark confined and Ozark unconfined geohydrologic groups, and between agricultural and other land uses. In groupings by soil and geohydrology, the Missouri bootheel region differed with respect to ammonia, total organic carbon, and phosphorus when compared with the other groups. Less than 10 percent of the wells sampled tested positive for bacterial contamination. E. coli was the most frequently detected bacterium. The public wells at Monett and West Plains, Missouri, had plates with colonies too numerous to count for all three indicator bacteria. Further analyses by rRNA (ribosomal RiboNucleic Acid) hybridization techniques detennined that much of the bacteria present were from ruminant and human sources. No enteric viruses were detected in the 109 samples. Both ribonucleic acid and somatic coliphage were detected at two wells. One additional well had ribonucleic acid coliphage and another had somatic coliphage for a total of four wells with coliphage selects.

Missouri

Water-use information for California

This pamphlet reports on the availability of water use information to and for the state of California, through the development of the State Water-Use Data System (SWUDS). SWUDS is currently organized into 12 water use categories: Agricultural non-irrigation; Commercial; Domestic; Industrial; Irrigation; Mining; Power generation--fossil fuel, geothermal, hydroelectric , nuclear; Sewage treatment; and Water supply. The information needs of this system include type of water use (by category); name of water user; location of water use (latitude/longitude, county, and hydrologic unit--drainage basin); sources of water supply and return (fresh, saline, or reclaimed surface or groundwater); volume of water withdrawn, delivered, consumed, released, and returned; and period of water use (month, year). (Lantz-PTT)

Open-File Report

Internal surface water flows

Introduction The South Florida Ecosystem Restoration Program is an intergovernmental effort to reestablish and maintain the ecosystem of south Florida. One element of the restoration effort is the development of a firm scientific basis for resource decision making.The U.S. Geological Survey (USGS) provides scientitic information as part of the South Florida Ecosystem Restoration Program. The USGS began its own project, called the South Florida Ecosystem Project in fiscal year 1995 for the purpose of gathering hydrologic, cartographic, and geologic data that relate to the mainland of south Florida, Florida Bay, and the Florida Keys and Reef ecosystems. Historical changes in water-management practices to accommodate a large and rapidly growing urban population along the Atlantic coast, as well as intensive agricultural activities, have resulted in a highly managed hydrologic system with canals, levees, and pumping stations. These structures have altered the hydology of the Everglades ecosystem on both coastal and interior lands. Surface-water flows in a direction south of Lake Okeechobee have been regulated by an extensive canal network, begun in the 1940's, to provide for drainage, flood control, saltwater intrusion control, agricultural requirements, and various environmental needs. Much of the development and subsequent monitoring of canal and river discharge south of Lake Okeechobee has traditionally emphasized the eastern coastal areas of Florida. Recently, more emphasis has been placed on providing a more accurate water budget for internal canal flows.

Florida

Geospatial data resampling and resolution effects on watershed modeling: A case study using the agricultural non-point source pollution model

Researchers have been coupling geographic information systems (GIS) data handling and processing capability to watershed and waterquality models for many years. This capability is suited for the development of databases appropriate for water modeling. However, it is rare for GIS to provide direct inputs to the models. To demonstrate the logical procedure of coupling GIS for model parameter extraction, we selected the Agricultural Non-Point Source (AGNPS) pollution model. Investigators can generate data layers at various resolutions and resample to pixel sizes to support models at particular scales. We developed databases of elevation, land cover, and soils at various resolutions in four watersheds. The ability to use multiresolution databases for the generation of model parameters is problematic for grid-based models. We used database development procedures and observed the effects of resolution and resampling on GIS input datasets and parameters generated from those inputs for AGNPS. Results indicate that elevation values at specific points compare favorably between 3- and 30-m raster datasets. Categorical data analysis indicates that land cover classes vary significantly. Derived parameters parallel the results of the base GIS datasets. Analysis of data resampled from 30-m to 60-, 120-, 210-, 240-, 480-, 960-, and 1920-m pixels indicates a general degradation of both elevation and land cover correlations as resolution decreases. Initial evaluation of model output values for soluble nitrogen and phosphorous indicates similar degradation with resolution. ?? Springer-Verlag 2004.

Journal of Geographical Systems

Generalized potentiometric maps of the Fort Union, Hell Creek, and Fox Hills aquifers within the Standing Rock Reservation

Generalized potentiometric surfaces of the Fort Union, Hell Creek, and Fox Hills aquifers were constructed to assess the groundwater resources of the Standing Rock Reservation. Additionally, this information can provide water managers with tools and data to effectively manage water resources in the future. Previous studies that mapped the geology and hydrogeology of the area at differing scales were used to confirm in which aquifer the study wells were completed. Water-level data from wells are provided by the U.S. Geological Survey Groundwater System Inventory database, the South Dakota Department of Agriculture and Natural Resources, and the North Dakota Department of Water Resources. Hydrographs were constructed for five selected observation wells to evaluate historical water-level fluctuations and trends. Hydrographs for the Hell Creek aquifer showed a flat trend with a rise in 2020. Hydrographs for the deeper Fox Hills aquifer showed that water levels fluctuated in response to climatic conditions and demonstrated an increasing trend in water-level elevations starting in 2010. Hydrographs were not constructed for any wells completed in the Fort Union Formation because none of the wells had continuous long-term measurements. Generalized potentiometric surfaces, constructed from interpolating water-level elevations, gave insight into groundwater flow directions. Groundwater in the Fort Union aquifer likely flows radially outward from the northwest part of the study area to the northeast and south-southeast parts. Groundwater in the Hell Creek aquifer generally flows from higher elevations in the northwest towards lower areas, where surface-water tributaries have incised into the aquifer. Groundwater in the Fox Hills aquifer likely flows from higher elevations in the west, southwest, and central parts of the study area towards the valleys of the Grand River and Missouri River. Most wells used for constructing potentiometric maps had only one recorded water-level measurement from drillers at the time of well construction. These measurements are often subject to error because the well is still recovering and because of spatial limitations of data availability. Also, because single water-level measurements were recorded at different points in time, additional uncertainty is introduced by fluctuating climatic conditions effect on water levels. Potentiometric map interpretation limitations are a result of areas with sparse data. Limitations also arise from potentiometric surfaces generalizing a complex and dynamic hydrogeologic system; however, the generalized potentiometric surface maps can be used to assist water managers and can help prioritize locations for future monitoring in areas with high uncertainty from sparse existing data.

North Dakota, South Dakota

From deposition to erosion: Spatial and temporal variability of sediment sources, storage, and transport in a small agricultural watershed

The spatial and temporal variability of sediment sources, storage, and transport were investigated in a small agricultural watershed draining the Coast Ranges and Sacramento Valley in central California. Results of field, laboratory, and historical data analysis in the Willow Slough fluvial system document changes that transformed a transport-limited depositional system to an effective erosion and transport system, despite a large sediment supply. These changes were caused by a combination of factors: (i) an increase in transport capacity, and (ii) hydrologic alteration. Alteration of the riparian zone and drainage network pattern during the past ~ 150 years included a twofold increase in straightened channel segments along with a baselevel change from excavation that increased slope, and increased sediment transport capacity by ~ 7%. Hydrologic alteration from irrigation water contributions also increased transport capacity, by extending the period with potential for sediment transport and erosion by ~ 6 months/year. Field measurements document Quaternary Alluvium as a modern source of fine sediment with grain size distributions characterized by 5 to 40% fine material. About 60% of an upland and 30% of a lowland study reach incised into this deposit exhibit bank erosion. During this study, the wet 2006 and relatively dry 2007 water years exhibited a range of total annual suspended sediment load spanning two orders of magnitude: ~ 108,500 kg/km 2 /year during 2006 and 5,950 kg/km 2 /year during 2007, only 5% of that during the previous year. Regional implications of this work are illustrated by the potential for a small tributary such as Willow Slough to contribute sediment – whereas large dams limit sediment supply from larger tributaries – to the Sacramento River and San Francisco Bay Delta and Estuary. This work is relevant to lowland agricultural river–floodplain systems globally in efforts to restore aquatic and riparian functions and where water quality management includes reducing fine sediment contributions that can couple with other pollutants.

California

Characterization of Ground-Water Quality, Upper Republican Natural Resources District, Nebraska, 1998-2001

Nearly all rural inhabitants and livestock in the Upper Republican Natural Resources District (URNRD) in southwestern Nebraska use ground water that can be affected by elevated nitrate concentrations. The development of ground-water irrigation in this area has increased the vulnerability of ground water to the introduction of fertilizers and other agricultural chemicals. In 1998, the U.S. Geological Survey, in cooperation with the Upper Republican Natural Resources District, began a study to characterize the quality of ground water in the Upper Republican Natural Resources District area with respect to physical properties and concentrations of major ions, coliform bacteria, nitrate, and pesticides, and to assess the presence of nitrogen concentrations in the unsaturated zone. At selected well sites, the ground-water characterization also included tritium and nitrogen-isotope analyses to provide information about the approximate age of the ground water and potential sources of nitrogen detected in ground-water samples, respectively. In 1998, ground-water samples were collected from 101 randomly selected domestic-well sites. Of the 101 samples collected, 26 tested positive for total coliform bacteria, exceeding the U.S. Environmental Protection Agency's Maximum Contaminant Level (MCL) of zero colonies. In 1999, ground-water samples were collected from 31 of the 101 well sites, and 16 tested positive for coliform bacteria. Nitrates were detected in ground water from all domestic-well samples and from all but four of the irrigation-well samples collected from 1998 to 2001. Eight percent of the domestic-well samples and 3 percent of the irrigation-well samples had nitrate concentrations exceeding the U.S. Environmental Protection Agency's MCL for drinking water of 10 milligrams per liter. Areas with nitrate concentrations exceeding 6 milligrams per liter, the URNRD's ground-water management-plan action level, were found predominantly in north-central Chase, western and south-central Dundy, and south-central Perkins Counties. Generally, these concentrations were detected in samples from wells located in upland areas with permeable soils and a high percentage of cropland. In 1999, 31 of the ground-water samples collected from irrigation wells were analyzed for pesticides, and 14 samples (45 percent) had detectable concentrations of at least one pesticide compound. In 2000, all of the 23 irrigation-well samples analyzed had one or more pesticides present at detectable concentrations. In 2001, 12 of 26 domestic-well samples (46 percent) had detectable concentrations. Although the analytical method used during the study was changed to increase the number of pesticides included in the analyses, the pesticides detected in the ground-water samples from domestic and irrigation wells were limited to the commonly used herbicide compounds acetochlor, alachlor, atrazine, metolachlor, prometon, propachlor, propazine, trifluralin, and the atrazine degradation product deethylatrazine. Of the compounds detected, only atrazine (3.0 micrograms per liter) and alachlor (2.0 micrograms per liter) have MCLs established by the U.S. Environmental Protection Agency. None of the ground-water samples from the URNRD study area had concentrations that exceeded either MCL. Tritium age-dating analyses indicate water from about one-third of the sites entered the ground-water system prior to 1952. Because the increase in agricultural practices occurred during the 1950s and 1960s, it can be assumed that this water was not influenced by agricultural practices. Nitrogen-isotope speciation analyses for samples from three irrigation wells indicated that the source of nitrates in the ground water probably is synthetic fertilizer; however, the source at most irrigation wells probably is either naturally occurring or a mixture of water from various anthropogenic sources (such as synthetic fertilizer and animal waste).

Scientific Investigations Report

Hydrogeologic characterization of the San Antonio Creek Valley watershed, Santa Barbara County, California

The San Antonio Creek Valley watershed (SACVW) is located in western Santa Barbara County, about 15 miles south of Santa Maria and 55 miles north of Santa Barbara, California. The SACVW is about 135 square miles and encompasses the San Antonio Creek Valley groundwater basin; the SACVW is separated from adjacent groundwater basins by the Casmalia and Solomon Hills to the north, and the Purisima Hills to the south. At the western, downstream part of the valley, uplifted, consolidated rocks cause groundwater to discharge at land surface at Barka Slough. Since the late 1800s, groundwater has been the primary source of water for agricultural, military, municipal, and domestic uses. Groundwater withdrawal by pumping exceeded the amount of water replenishing the aquifer system during water years 1948–2018, causing groundwater-level declines of more than 150 feet in parts of the valley and reducing base flow at Barka Slough. Reliance on groundwater for agricultural water use (primarily for the irrigation and frost protection of vineyards, and fruit and berry crops) continues to strain the sustainability of the groundwater system. Through a cooperative agreement, the Santa Barbara County Water Agency and Vandenberg Space Force Base invited the U.S. Geological Survey to address declines in groundwater levels, develop a better understanding of the hydrogeologic system, and provide tools to help evaluate and manage the effects of future development of the San Antonio Creek Valley groundwater basin within the encompassing San Antonio Creek Valley watershed (SACVW). The objectives of this study were to (1) refine the hydrogeologic framework of the San Antonio Creek Valley watershed, (2) quantify the hydrologic budget of the valley, and (3) develop hydrologic modeling tools to evaluate and aid in managing the groundwater resource. This report focuses on the first and second objectives to construct a hydrogeologic framework and characterize the historical and present-day hydrologic conditions of the SACVW during water years 1948–2018. As part of the second objective, work included quantifying the hydrologic budget and evaluating the hydrogeologic system using a combination of existing data and geologic and hydrologic data collected for this study. The groundwater-flow system in the SACVW consists of five hydrogeologic units. These separate water-bearing units were identified based on hydrogeologic properties, such as sediment grain size, vertical-head differences in multiple-depth, monitoring-well sites, long-term groundwater level responses to pumping and climate, and the chemical character of groundwater and groundwater age in the mostly semi-consolidated to unconsolidated basin-fill sediments. The hydrogeologic units that comprise the different aquifers vary in their lithologic composition. The upper and lower aquifers (upper Paso Robles Formation, and lower Paso Robles Formation and Careaga Sandstone, respectively) are relatively coarse grained and are comprised of sand, gravel, and clay; the middle confining unit (the middle Paso Robles Formation) is relatively fine grained and is comprised of primarily clay, silt, and sand. The Pezzoni-Casmalia and Los Alamos faults, which are inferred to transect the SACVW between the western and eastern areas of the valley floor, do not appear to substantially affect the groundwater system. Present-day recharge to the study area occurs primarily as infiltration from precipitation and streams in the upland areas of the Casmalia Hills and Solomon Hills, and along the main channel of San Antonio Creek. Reported estimates of annual natural recharge during water years 1948–2018 generally ranged from about 5,000 acre-feet to more than about 30,000 acre-feet. Stable and radioactive isotopes show that groundwater from the lower aquifer is old and probably was recharged as infiltration from precipitation and streams in the eastern upland areas of the Solomon Hills; however, the infiltration and recharge from these sources probably does not occur under present-day climatic conditions. Anthropogenic recharge, from sources such as return flow from agricultural irrigation, municipal water systems, and wastewater effluent, was estimated to range from about 600 acre-feet in 1948 to about 6,600 acre-feet in 2018. The average annual amount of groundwater removed from the SACVW by pumping during 1948–2018 was estimated to be about 17,200 acre-feet per year, increasing from about 3,000 acre-feet in 1948 to about 32,600 acre-feet in 2018. Estimates of annual pumpage generally exceeded estimates of annual recharge beginning in the mid-1970s and continuing through 2018. The predominant direction of groundwater flow under historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek to the discharge area in Barka Slough, and from the northern uplands in the Casmalia Hills south to San Antonio Creek. Pumpage since the early 1900s and the subsequent groundwater-level declines have substantially reduced the amount of natural groundwater discharge at Barka Slough. Estimates of base flow to San Antonio Creek at the western, downstream extent of the SACVW have varied over time in response to changes in groundwater pumpage and climate; however, there was an overall decline in base flow during water years 1956–2018, decreasing from an average of about 1,700 acre-feet per year during 1956–69, to about 300 acre-feet per year during 2016–18. The long-term extraction of groundwater correlates with a decrease in groundwater levels by more than about 150 feet since the early 1940s in the eastern part of the basin near Los Alamos, and as much as about 50 feet in the upland areas and in the western part of the basin. At Barka Slough, groundwater levels have declined below land surface in some places, altering native riparian vegetation in and around the slough. Surface-water quality in the SACVW varied depending on location and the time of year the samples were collected and on the amount of annual precipitation Most groundwater in the SACVW was calcium-bicarbonate-type water with total dissolved-solids concentrations of about 500–800 milligrams per liter generally representing water naturally recharged as infiltration from precipitation and streams. Total dissolved-solids concentrations in some wells ranged from 800 to 8,000 milligrams per liter, suggesting mixing of naturally recharged infiltrated water with water associated with oil-bearing geologic formations, agricultural products, or the evaporation of shallow groundwater. Concentrations of total dissolved solids and the chemical constituents chloride, nitrate plus nitrite (as nitrogen), calcium, and magnesium at selected wells generally increased during water years 1980–2018; increasing concentrations of these constituents may be associated with the expansion of agriculture in the watershed over time and the corresponding increase in the use of nitrates and calcium- and magnesium-based fertilizers and soil additives in modern agricultural practices. The predominant direction of groundwater flow during historical and present-day conditions was from the eastern uplands in the Solomon Hills to the west along San Antonio Creek toward Barka Slough, and from the western uplands in the Casmalia Hills south to San Antonio Creek. The age of groundwater in the SACVW was evaluated using radioactive isotopes, and the flow of groundwater within the SACVW was evaluated using radioactive and stable isotopes. Modern groundwater (recharged after 1952) was generally found adjacent to San Antonio Creek and its tributaries in wells with perforated depths that averaged about 270 feet below land surface. Pre-modern groundwater (recharged before 1952) was found in wells that had average perforation depths of about 540 ft below land surface. Pre-modern groundwater identified in wells in the eastern upland area is interpreted to have had long, slow travel times to the western part of the SACVW where it was eventually discharged as base flow at Barka Slough or extracted as groundwater pumpage.

California

Tracking the fate of nitrate through pulse-flow wetlands: A mesocosm scale 15N enrichment tracer study

Quantitative information about the fate of applied nitrate (NO 3 -N) in pulse-flow constructed wetlands is essential for designing wetland treatment systems and assessing their nitrogen removal services for agricultural and stormwater applications. Although many studies have documented NO 3 -N losses in wetlands, controlled experiments indicating the relative importance of different processes and N sinks are scarce. In the current study, 15 NO 3 -N isotope enrichment tracer experiments were conducted in wetland mesocosms of two different wetland soil types at two realistic agricultural NO 3 -N source loads. The 15 N label was traced from the source NO 3 -N into plant biomass, soil (including organic matter and ammonium), and N-gas constituents over 7–10 day study periods. All sinks responded positively to higher NO 3 -N loading. Plant uptake exceeded denitrification 2–3 fold in the low NO 3 -N loading experiments, while both fates were nearly equivalent in the high loading experiments. One to two years later, soils largely retained the assimilated tracer N, whereas plants had lost much of it. Results demonstrated that plant and microbial assimilation in the soil (temporary N sinks) can exceed denitrification (permanent N loss) in pulse-flow environments and must be considered by wetland designers and managers for optimizing nitrogen removal potential.

Ecological Engineering

PHT3D-UZF: A reactive transport model for variably-saturated porous media

A modified version of the MODFLOW/MT3DMS-based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably-saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D-UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated-zone flow (UZF1) package. A volume-averaged approach similar to the method used in UZF-MT3DMS was adopted. The PHREEQC-based computation of chemical processes within PHT3D-UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional-scale applications, UZF1 simulates downward-only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably-saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns.

Ground Water

Mapping the global threat of land subsidence

Subsidence, the lowering of Earth's land surface, is a potentially destructive hazard that can be caused by a wide range of natural or anthropogenic triggers but mainly results from solid or fluid mobilization underground. Subsidence due to groundwater depletion ( 1 ) is a slow and gradual process that develops on large time scales (months to years), producing progressive loss of land elevation (centimeters to decimeters per year) typically over very large areas (tens to thousands of square kilometers) and variably affects urban and agricultural areas worldwide. Subsidence permanently reduces aquifer-system storage capacity, causes earth fissures, damages buildings and civil infrastructure, and increases flood susceptibility and risk. During the next decades, global population and economic growth will continue to increase groundwater demand and accompanying groundwater depletion ( 2 ) and, when exacerbated by droughts ( 3 ), will probably increase land subsidence occurrence and related damages or impacts. To raise awareness and inform decision-making, we evaluate potential global subsidence due to groundwater depletion, a key first step toward formulating effective land-subsidence policies that are lacking in most countries worldwide.

Science

Nature reserves: Do they capture the full range of America's biological diversity?

Less than 6% of the coterminous United States is in nature reserves. Assessment of the occurrence of nature reserves across ranges of elevation and soil productivity classes indicates that nature reserves are most frequently found at higher elevations and on less productive soils. The distribution of plants and animals suggests that the greatest number of species is found at lower elevations. A preliminary assessment of the occurrence of mapped land cover types indicates that ???60% of mapped cover types have <10% of their area in nature reserves Land ownership patterns show that areas of lower elevation and more productive soils are most often privately owned and already extensively converted to urban and agricultural uses. Thus any effort to establish a system of nature reserves that captures the full geographical and ecological range of cover types and species must fully engage the private sector.

Ecological Applications

The promise of precise borehole gravimetry in petroleum exploration and exploitation

This report provides comprehensive information on the geology, geohydrology, and mineral resources of Boone and Winnebago Counties for use in resource-based land-use planning and development. Data on the composition, thickness, and regional distribution of glacial drift and bedrock materials were used to construct maps of: geologic materials to a depth of 20 ft; bedrock topography; drift thickness; major terrains; and glacial drift aquifers. Because contamination of aquifers is a serious concern in some areas of the two counties, a major focus of this study is on interpreting data critical to the selection of suitable areas for municipal waste disposal and prevention of contamination from existing municipal landfills and septic systems. Interpretive maps accompanying the text: (1) rate geological sequences on their capacity to protect aquifers and surface water from contamination by land burial of municipal wastes, septic system disposal, and surface spreading of wastes and agricultural chemicals; (2) geologic sequences on their suitability for general construction; and (3) delineate resources of sand, gravel, peat, and dolomite. Areas in which aquifer contamination from waste disposal and other land-use practices is most likely to occur are those in which sand and gravel and/or permeable creviced bedrock are at or near the surface. Areas having the lowest contamination potential are underlain by thick (20 ft or more) deposits of fine-grained glacial till. Areas most favorable for general construction are well-drained locations in major river valleys and terrace outwash plains; areas least favorable for construction are scattered throughout both counties on poorly drained land having low bearing capacities and on uplands and slopes in northwestern Winnebago County where the drift is thin over the bedrock. Extensive deposits of sand and gravel occur in the major bedrock valleys. Dolomite deposits underlie all the uplands of Winnebago County and most of Boone County, but extraction costs are prohibitive where overburden is thick. High-grade dolomite with relatively thin overburden is found in eastern Winnebago County and southwestern Boone County. (Author 's abstract)

Circular

Potentiometric Surfaces in the Springfield Plateau and Ozark Aquifers of Northwestern Arkansas, Southeastern Kansas, Southwestern Missouri, and Northeastern Oklahoma, 2006

The Springfield Plateau and Ozark aquifers are important sources of ground water in the Ozark Plateaus aquifer system. Water from these aquifers is used for agricultural, domestic, industrial, and municipal water sources. Changing water use over time in these aquifers presents a need for updated potentiometric-surface maps of the Springfield Plateau and Ozark aquifers. The Springfield Plateau aquifer consists of water-bearing Mississippian-age limestone and chert. The Ozark aquifer consists of Late Cambrian to Middle Devonian age water-bearing rocks consisting of dolostone, limestone, and sandstone. Both aquifers are complex with areally varying lithologies, discrete hydrologic units, varying permeabilities, and secondary permeabilities related to fractures and karst features. During the spring of 2006, ground-water levels were measured in 285 wells. These data, and water levels from selected lakes, rivers, and springs, were used to create potentiometric-surface maps for the Springfield Plateau and Ozark aquifers. Linear kriging was used initially to construct the water-level contours on the maps; the contours were subsequently modified using hydrologic judgment. The potentiometric-surface maps presented in this report represent ground-water conditions during the spring of 2006. During the spring of 2006, the region received less than average rainfall. Dry conditions prior to the spring of 2006 could have contributed to the observed water levels as well. The potentiometric-surface map of the Springfield Plateau aquifer shows a maximum measured water-level altitude within the study area of about 1,450 feet at a spring in Barry County, Missouri, and a minimum measured water-level altitude of 579 feet at a well in Ottawa County, Oklahoma. Cones of depression occur in Dade, Lawrence and Newton Counties in Missouri and Delaware and Ottawa Counties in Oklahoma. These cones of depression are associated with private wells. Ground water in the Springfield Plateau aquifer generally flows to the west in the study area, and to surface features (lakes, rivers, and springs) particularly in the south and east of the study area where the Springfield Plateau aquifer is closest to land surface. The potentiometric-surface map of the Ozark aquifer indicates a maximum measured water-level altitude of 1,303 feet in the study area at a well in Washington County, Arkansas, and a minimum measured water-level altitude of 390 feet in Ottawa County, Oklahoma. The water in the Ozark aquifer generally flows to the northwest in the northern part of the study area and to the west in the remaining study area. Cones of depression occur in Barry, Barton, Cedar, Jasper, Lawrence, McDonald, Newton, and Vernon Counties in Missouri, Cherokee and Crawford Counties in Kansas, and Craig and Ottawa Counties in Oklahoma. These cones of depression are associated with municipal supply wells. The flow directions, based on both potentiometric-surface maps, generally agree with flow directions indicated by previous studies.

Scientific Investigations Report

National water summary 1986: Hydrologic events and ground-water quality

Ground water is one of the most important natural resources of the United States and degradation of its quality could have a major effect on the welfare of the Nation. Currently (1985), ground water is the source of drinking water for 53 percent of the Nation's population and for more than 97 percent of its rural population. It is the source of about 40 percent of the Nation's public water supply, 33 percent of water for irrigation, and 17 percent of freshwater for selfsupplied industries. Ground water also is the source of about 40 percent of the average annual streamflow in the United States, although during long periods of little or no precipitation, ground-water discharges provide nearly all of the base streamflow. This hydraulic connection between aquifers and streams implies that if a persistent pollutant gets into an aquifer, it eventually could discharge into a stream. Information presented in the 1986 National Water Summary clearly shows that the United States has very large amounts of potable ground water available for use. Although naturally occurring constituents, such as nitrate, and human-induced substances, such as synthetic organic chemicals, frequently are detected in ground water, their concentrations usually do not exceed existing Federal or State standards or guidelines for maximum concentrations in drinking water. Troublesome contamination of ground water falls into two basic categories related to the source or sources of the contamination. Locally, high concentrations of a variety of toxic metals, organic chemicals, and petroleum products have been detected in ground water associated with point sources such as wastedisposal sites, storage-tank leaks, and hazardous chemical spills. These types of local problems commonly occur in densely populated urban areas and industrialized areas. Larger, multicounty areas also have been identified where contamination frequently is found in shallow wells. These areas generally are associated with broad-scale, or nonpoint, sources of contamination such as agricultural activities or highdensity domestic waste disposal (septic systems) in urban centers. At present, only a very small percentage of the total volume of potable ground water in the United States is contaminated from both point and nonpoint sources; however, available data, especially data about the occurrence of synthetic organic and toxic substances, generally are inadequate to determine the full extent of ground-water contamination in the Nation's aquifers or to define trends in groundwater quality. Most information about the occurrence of these substances has come from the study of individual sites or areas where contamination had already been detected or suspected. Management and protection of ground water present a major challenge to the Nation. Current and projected costs of detection and cleanup of existing ground-water contamination are staggering and, even so, complete removal of pollutants from ground water in the vicinity of some waste sites might not be technically feasible. At all levels of government, the task of protecting the resource for its most beneficial uses is difficult and controversial. Despite increasing awareness that some of the Nation's ground water is contaminated with a variety of toxic metals, synthetic organic chemicals, radionuclides, pesticides, and other contaminants that might present a long-term risk to human health, public policy towards ground-water protection is still in the formative stages. Despite increasing efforts devoted to ground-water protection by State and Federal regulatory and resource-management agencies, the extent of ground-water contamination is likely to appear to increase over the next few years because more agencies will be searching for evidence of contamination, and they will be using increasingly sensitive analytical procedures. Increased technology and expanded monitoring activities probably will detect the effects of past contamination and land uses on water quality. The significant time lag between a waterquality change in one part of an aquifer system and the effects of that change at a downgradient site, such as a well, results from the generally slow movement of ground water. This lag between cause and observed effect needs to be considered in evaluating the effectiveness of current and future ground-water policies and remedial measures. Conclusive answers to questions about the location, extent, and severity of ground-water contamination, and about trends in ground-water quality, must await further collection and analysis of data from the Nation's aquifers. Generalizations, however, can be made, and the 1986 National Water Summary, which describes the natural quality of ground-water resources in each State and the major contamination problems that have been identified as of 1986, provides a national perspective of the ground-water-quality situation. The 1986 National Water Summary follows the format of previous volumes. It contains three parts, and the contents of each of these parts are highlighted below.

Water Supply Paper

Vegetation community response to tidal marsh restoration of a large river estuary

Estuaries are biologically productive and diverse ecosystems that provide ecosystem services including protection of inland areas from flooding, filtering freshwater outflows, and providing habitats for fish and wildlife. Alteration of historic habitats, including diking for agriculture, has decreased the function of many estuarine systems, and recent conservation efforts have been directed at restoring these degraded areas to reestablish their natural resource function. The Nisqually Delta in southern Puget Sound is an estuary that has been highly modified by restricting tidal flow, and recent restoration of the delta contributed to one of the largest tidal salt marsh restorations in the Pacific Northwest. We correlated the response of nine major tidal marsh species to salinities at different elevation zones. Our results indicated that wetland species richness was not related to soil pore-water salinity (R2 = 0.03), but were stratified into different elevation zones (R2 = 0.47). Thus, restoration that fosters a wide range of elevations will provide the most diverse plant habitat, and potentially, the greatest resilience to environmental change.

Washington