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USGS2013

Measuring the relative resilience of subarctic lakes to global change: redundancies of functions within and across temporal scales

1. Ecosystems at high altitudes and latitudes are expected to be particularly vulnerable to the effects of global change. We assessed the responses of littoral invertebrate communities to changing abiotic conditions in subarctic Swedish lakes with long-term data (1988–2010) and compared the responses of subarctic lakes with those of more southern, hemiboreal lakes. 2. We used a complex systems approach, based on multivariate time-series modelling, and identified dominant and distinct temporal frequencies in the data; that is, we tracked community change at distinct temporal scales. We determined the distribution of functional feeding groups of invertebrates within and across temporal scales. Within and cross-scale distributions of functions have been considered to confer resilience to ecosystems, despite changing environmental conditions. 3. Two patterns of temporal change within the invertebrate communities were identified that were consistent across the lakes. The first pattern was one of monotonic change associated with changing abiotic lake conditions. The second was one of showing fluctuation patterns largely unrelated to gradual environmental change. Thus, two dominant and distinct temporal frequencies (temporal scales) were present in all lakes analysed. 4. Although the contribution of individual feeding groups varied between subarctic and hemiboreal lakes, they shared overall similar functional attributes (richness, evenness, diversity) and redundancies of functions within and between the observed temporal scales. This highlights similar resilience characteristics in subarctic and hemiboreal lakes. 5. Synthesis and applications. The effects of global change can be particularly strong at a single scale in ecosystems. Over time, this can cause monotonic change in communities and eventually lead to a loss of important ecosystem services upon reaching a critical threshold. Dynamics at other spatial or temporal scales can be unrelated to environmental change. The relative ‘intactness’ of these scales that are unaffected by global change and the persistence of functions at those scales may safeguard the whole system from the potential loss of functions at the scale at which global change impacts can be substantial. Thus, an understanding of scale-specific processes provides managers with a realistic assessment of vulnerabilities and the relative resilience of ecosystems to environmental change. Explicit consideration of ‘intact’ and ‘affected’ scales in analyses of global change impacts provides opportunities to tailor more specific management plans.

Journal of Applied Ecology↗

USGS2008

Length variation in age-0 westslope cutthroat trout at multiple spatial scales

Phenotypic diversity provides ecological and evolutionary functions, stabilizing populations in variable environments. Although benefits of larger body size in juvenile fishes are well documented, size variation may have value as well. We explored the distribution of length and length variation in age-0 westslope cutthroat trout Oncorhynchus clarkii lewisi at three spatial scales: area (102 km2), stream (101 km2), and site (100 km2). In addition, we examined relationships between length variables (mean length and interquartile range of length) and instream (temperature and conductivity) and landscape (aspect, elevation, headwater distance, and valley width) variables that were expected to be associated with fish size. Conductivity was included as a surrogate for productivity. Most variation in mean length and interquartile range of fish length was found among areas (62.2% and 62.6%, respectively). Mean length also varied among streams and sites (21.9% and 15.8%, respectively). Similarly, interquartile range of fish length varied among streams and sites (19.1% and 18.3%, respectively). Both length variables were associated with temperature and elevation. Mean fish length was also associated with conductivity, but the association between interquartile length range and conductivity was weak. We conclude that the conservation of variation in phenotypic attributes, such as length, in westslope cutthroat trout may require conservation of viable populations across broad areas and across environmental gradients that are associated with growth. ?? Copyright by the American Fisheries Society 2008.

North American Journal of Fisheries Management↗

USGS2013

Selenium in irrigated agricultural areas of the western United States

Selenium was recognized as an important aquatic contaminant following the identification of widespread deformities in waterfowl at the agricultural drainage evaporation ponds of the Kesterson Reservoir (California) in 1983. Since then, California has been the focal point for global research and management of Se contamination. We analyzed the history and current developments in science, policy, and management of irrigation-induced Se contamination in California. In terms of management, we evaluated the effects of improvements in the design of local attenuation methods (drainage reuse and evaporation ponds) in conjunction with the development of programs for Se load reductions at the regional scale (namely the Grassland Bypass Project). In terms of policy, the USEPA is currently working on site-specific water quality criteria for the San Francisco Bay Delta that may be a landmark for future legislation on Se in natural water bodies. We provide a critical analysis of this approach and discuss challenges and opportunities in expanding it to other locations such as the Salton Sea. Management lessons learned in California and the novel policy approach may help prevent future events of Se contamination.

Journal of Environmental Quality↗

USGS2020

Effect of environmental factors on the movement of Rainbow Trout in the Deerfield Reservoir System

Spawning movements and the factors affecting those movements are often of interest to fisheries managers and biologists. The objective of this study was to examine the influence of environmental factors on the movements of an adfluvial Rainbow Trout Oncorhynchus mykiss population in the Black Hills, South Dakota. Three unique strains of hatchery-reared Rainbow Trout and resident Rainbow Trout were implanted with passive integrated transponder (PIT) tags and movements between Deerfield Reservoir and the Castle Creek tributary system were monitored from August, 2010-July, 2011. Initial adfluvial movements of Rainbow Trout were detected using a stationary PIT tag reader deployed near the mouth of Castle Creek. Multiple linear regressions were used to model the relationship between PIT tagged Rainbow Trout movement and water temperature, photoperiod, and discharge. Using Akaike’s information criterion (AIC) to compare models, discharge was the top supported model explaining variation in Rainbow Trout movement. Additionally, models containing temperature and photoperiod were also supported. Supported models only explained moderate levels of variation (<23%) in Rainbow Trout movement. Understanding how environmental variables affect the movement patterns of this unique population is essential in determining the proper management strategy for the Deerfield Reservoir system.

South Dakota↗

USGS2016

Influence of demography and environment on persistence in toad populations

Effective conservation of rare species requires an understanding of how potential threats affect population dynamics. Unfortunately, information about population demographics prior to threats (i.e., baseline data) is lacking for many species. Perturbations, caused by climate change, disease, or other stressors can lead to population declines and heightened conservation concerns. Boreal toads ( Anaxyrus boreas boreas ) have undergone rangewide declines due mostly to the amphibian chytrid fungus Batrachochytrium dendrobatidis (Bd), with only a few sizable populations remaining in the southern Rocky Mountains, USA, that are disease-free. Despite the apparent region-wide occurrence of Bd, our focal populations in central Colorado were disease free over a 14-year capture-mark-recapture study until the recent discovery of Bd at one of the sites. We used recapture data and the Pradel reverse-time model to assess the influence of environmental and site-specific conditions on survival and recruitment. We then forecast changes in the toad populations with 2 growth models; one using an average lambda value to initiate the projection, and one using the most recent value to capture potential effects of the incursion of disease into the system. Adult survival was consistently high at the 3 sites, whereas recruitment was more variable and markedly low at 1 site. We found that active season moisture, active season length, and breeding shallows were important factors in estimating recruitment. Population growth models indicated a slight increase at 1 site but decreasing trends at the 2 other sites, possibly influenced by low recruitment. Insight into declining species management can be gained from information on survival and recruitment and how site-specific environmental factors influence these demographic parameters. Our data are particularly useful because they provide baseline data on demographics in populations before a disease outbreak and enhance our ability to detect changes in population parameters potentially caused by the disease.

Journal of Wildlife Management↗

USGS2018

Determinants of Pseudogymnoascus destructans within bat hibernacula: Implications for surveillance and management of white-nose syndrome

Fungal diseases are an emerging global problem affecting human health, food security and biodiversity. Ability of many fungal pathogens to persist within environmental reservoirs can increase extinction risks for host species and presents challenges for disease control. Understanding factors that regulate pathogen spread and persistence in these reservoirs is critical for effective disease management. White-nose syndrome (WNS) is a disease of hibernating bats caused by Pseudogymnoascus destructans ( Pd ), a fungus that establishes persistent environmental reservoirs within bat hibernacula, which contribute to seasonal disease transmission dynamics in bats. However, host and environmental factors influencing distribution of Pd within these reservoirs are unknown. We used model selection on longitudinally collected field data to test multiple hypotheses describing presence–absence and abundance of Pd in environmental substrates and on bats within hibernacula at different stages of WNS. First detection of Pd in the environment lagged up to 1 year after first detection on bats within that hibernaculum. Once detected, the probability of detecting Pd within environmental samples from a hibernaculum increased over time and was higher in sediment compared to wall surfaces. Temperature had marginal effects on the distribution of Pd . For bats, prevalence and abundance of Pd were highest on Myotis lucifugus and on bats with visible signs of WNS. Synthesis and applications . Our results indicate that distribution of Pseudogymnoascus destructans ( Pd ) within a hibernaculum is driven primarily by bats with delayed establishment of environmental reservoirs. Thus, collection of samples from Myotis lucifugus , or from sediment if bats cannot be sampled, should be prioritized to improve detection probabilities for Pd surveillance. Long-term persistence of Pd in sediment suggests that disease management for white-nose syndrome should address risks of sustained transmission from environmental reservoirs.

Journal of Applied Ecology↗

USGS2011

Land use and climate influences on waterbirds in the Prairie Potholes

Aim We examined the influences of regional climate and land‐use variables on mallard ( Anas platyrhynchos ), blue‐winged teal ( Anas discors ), ruddy duck ( Oxyura jamaicensis ) and pied‐billed grebe ( Podilymbus podiceps ) abundances to inform conservation planning in the Prairie Pothole Region of the United States. Location The US portion of Bird Conservation Region 11 (US‐BCR11, the Prairie Potholes), which encompasses six states within the United States: Montana, North Dakota, South Dakota, Nebraska, Minnesota and Iowa. Methods We used data from the North American Breeding Bird Survey (NABBS), the National Land Cover Data Set, and the National Climatic Data Center to model the effects of environmental variables on waterbird abundance. We evaluated land‐use covariates at three logarithmically related spatial scales (1000, 10,000 and 100,000 ha), and constructed hierarchical spatial count models a priori using information from published habitat associations. Model fitting was performed using a hierarchical modelling approach within a Bayesian framework. Results Models with the same variables expressed at different scales were often in the best model subset, indicating that the influence of spatial scale was small. Both land‐use and climate variables contributed strongly to predicting waterbird abundance in US‐BCR11. The strongest positive influences on waterbird abundance were the percentage of wetland area across all three spatial scales, herbaceous vegetation and precipitation variables. Other variables that we included in our models did not appear to influence waterbirds in this study. Main conclusions Understanding the relationships of waterbird abundance to climate and land use may allow us to make predictions of future distribution and abundance as environmental factors change. Additionally, results from this study can suggest locations where conservation and management efforts should be focused.

Iowa, Minnesota, Montana, Nebraska, North Dakota, ↗

USGS2021

Clothianidin decomposition in Missouri wetland soils

Neonicotinoid pesticides can persist in soils for extended time periods; however, they also have a high potential to contaminate ground and surface waters. Studies have reported negative effects associated with neonicotinoids and nontarget taxa, including aquatic invertebrates, pollinating insect species, and insectivorous birds. This study evaluated factors associated with clothianidin (CTN) degradation and sorption in Missouri wetland soils to assess the potential for wetland soils to mitigate potential environmental risks associated with neonicotinoids. Solid-to-solution partition coefficients ( K d ) for CTN sorption to eight wetland soils were determined via single-point sorption experiments, and sorption isotherm experiments were conducted using the two most contrasting soils. Clothianidin degradation was determined under oxic and anoxic conditions over 60 d. Degradation data were fit to zero- and first-order kinetic decay models to determine CTN half-life ( t 0.5 ). Sorption results indicated CTN sorption to wetland soil was relatively weak (average K d , 3.58 L kg –1 ); thus, CTN has the potential to be mobile and bioavailable within wetland soils. However, incubation results showed anoxic conditions significantly increased CTN degradation rates in wetland soils (anoxic average t 0.5 , 27.2 d; oxic average t 0.5 , 149.1 d). A significant negative correlation was observed between anoxic half-life values and soil organic C content ( r 2 = .782; p = .046). Greater CTN degradation rates in wetland soils under anoxic conditions suggest that managing wetlands to facilitate anoxic conditions could mitigate CTN presence in the environment and reduce exposure to nontarget organisms.

Missouri↗

USGS2010

Determining sources of dissolved organic carbon and disinfection byproduct precursors to the McKenzie River, Oregon

This study was conducted to determine the main sources of dissolved organic carbon (DOC) and disinfection byproduct (DBP) precursors to the McKenzie River, Oregon (USA). Water samples collected from the mainstem, tributaries, and reservoir outflows were analyzed for DOC concentration and DBP formation potentials (trihalomethanes [THMFPs] and haloacetic acids [HAAFPs]). In addition, optical properties (absorbance and fluorescence) of dissolved organic matter (DOM) were measured to provide insight into DOM composition and assess whether optical properties are useful proxies for DOC and DBP precursor concentrations. Optical properties indicative of composition suggest that DOM in the McKenzie River mainstem was primarily allochthonous - derived from soils and plant material in the upstream watershed. Downstream tributaries had higher DOC concentrations than mainstem sites (1.6 ?? 0.4 vs. 0.7 ?? 0.3 mg L-1) but comprised <5% of mainstem flows and had minimal effect on overall DBP precursor loads. Water exiting two large upstream reservoirs also had higher DOC concentrations than the mainstem site upstream of the reservoirs, but optical data did not support in situ algal production as a source of the added DOC during the study. Results suggest that the first major rain event in the fall contributes DOM with high DBP precursor content. Although there was interference in the absorbance spectra in downstream tributary samples, fluorescence data were strongly correlated to DOC concentration (R 2 = 0.98), THMFP (R2 = 0.98), and HAAFP (R2 = 0.96). These results highlight the value of using optical measurements for identifying the concentration and sources of DBP precursors in watersheds, which will help drinking water utilities improve source water monitoring and management programs. Copyright ?? 2010 by the American Society of Agronomy.

Journal of Environmental Quality↗

USGS2023

Environmental correlates of walleye spawning movements in an Appalachian hydropower reservoir

Understanding walleye ( Sander vitreus ) spawning behavior is important for managing walleye fisheries, but such information is limited for Appalachian reservoirs. We assessed spawning movements and spawning locations for a reestablished walleye population in Cheat Lake, West Virginia. We tagged fifty-two walleye with acoustic telemetry transmitters to evaluate environmental correlates associated with pre-spawn movements and to deter- mine spawning locations. Using an information-theoretic approach, we compared candidate logistic regression models to determine which environmental variables best explained upstream movements to spawning areas. The two models with the most support both included additive effects of year and water temperature, with sex also included in the second of these models. Water temperature had a significant positive relationship with pre-spawn movements in each model. Other environmental covariates such as river discharge and water elevation were not significant predictors of upstream pre-spawn move- ments. Walleye made pre-spawn upstream movements in late winter/early spring to spawning areas in the headwaters of Cheat Lake during periods of el- evated water temperatures (75 % of movement events occurred at water temperatures >4.1 C) where spawning occurred in shallow (<1.5 m), rocky habitat. Male walleye generally made upstream pre-spawn movements earlier than females. Our results also suggested the timing of walleye spawning with respect to water-level fluctuations could influence reproductive success due to stranding of eggs or reducing suitable spawning habitat. Knowledge of pre-spawn movement patterns and spawning locations could aid management of this recovering population. Benefits to management may include the prediction of spawning timing and locations for broodstock surveys and influences of water-level fluctuations and other environmental stressors on spawning success.

Pennsylvania, West Virginia↗

USGS2014

Spatial variability and landscape controls of near-surface permafrost within the Alaskan Yukon River Basin

The distribution of permafrost is important to understand because of permafrost's influence on high-latitude ecosystem structure and functions. Moreover, near-surface (defined here as within 1 m of the Earth's surface) permafrost is particularly susceptible to a warming climate and is generally poorly mapped at regional scales. Subsequently, our objectives were to (1) develop the first-known binary and probabilistic maps of near-surface permafrost distributions at a 30 m resolution in the Alaskan Yukon River Basin by employing decision tree models, field measurements, and remotely sensed and mapped biophysical data; (2) evaluate the relative contribution of 39 biophysical variables used in the models; and (3) assess the landscape-scale factors controlling spatial variations in permafrost extent. Areas estimated to be present and absent of near-surface permafrost occupy approximately 46% and 45% of the Alaskan Yukon River Basin, respectively; masked areas (e.g., water and developed) account for the remaining 9% of the landscape. Strong predictors of near-surface permafrost include climatic indices, land cover, topography, and Landsat 7 Enhanced Thematic Mapper Plus spectral information. Our quantitative modeling approach enabled us to generate regional near-surface permafrost maps and provide essential information for resource managers and modelers to better understand near-surface permafrost distribution and how it relates to environmental factors and conditions.

Alaska↗

USGS1982

Some observations on the ecology and fish management of reservoirs in the United States

By 1980 there were 1,608 reservoirs (over 202 ha each) with a surface area of 4 million ha in the United States. Construction of new reservoirs has decreased in recent years because of the lack of suitable sites and the opposition of environmental interests. Reservoirs have characteristics of both lacustrine and riverine ecosystems. Reservoirs have been segmented into riverine, transitional and lacustrine zones for simulation modelling.Fish and plankton production increases rapidly after initial impoundment and then decreases and stabilizes at lower levels. Decreases in the number of fish species and in fish biomass following impoundment are caused by reduced quantity and quality of spawning and nursery habitat and decreased detrital input. Plankton populations can be followed downstream in a series of reservoirs and increases in abundance were associated with the inundation of vegetation or the introduction of nutrients.In addition to water level management, the most effective fish management programs have included introducing new fishes, developing vegetation or building structures on the reservoir bottom. Considerable progress has been made in predicting the effects of environmental parameters on fish production.

Montana, Nebraska, North Dakota, South Dakota↗

USGS2008

Differential exposure, duration, and sensitivity of unionoidean bivalve life stages to environmental contaminants

Freshwater mussels (superfamily Unionoidea) are in serious global decline and in urgent need of protection and conservation. The declines have been attributed to a wide array of human activities resulting in pollution and water-quality degradation, and habitat destruction and alteration. Linkages among poor water quality, pollutant sources, and mussel decline in rivers and streams have been associated with results of laboratory-based tests of specific pollutants. However, uncertainties remain about the relationship of laboratory data to actual contaminant exposure routes for various mussel species, life stages, and in the habitats occupied during these exposures. We evaluated the pathways of exposure to environmental pollutants for all 4 life stages (free glochidia, encysted glochidia, juveniles, adults) of unionoidean mussels and found that each life stage has both common and unique characteristics that contribute to observed differences in exposure and sensitivity. Free glochidia typically are exposed only briefly (e.g., seconds to days) through surface water, whereas adults sustain exposure over years to decades through surface water, pore water, sediment, and diet. Juveniles live largely burrowed in the sediment for the first 0 to 4 y of life. Thus, sediment, pore water, and diet are the predominant exposure routes for this life stage, but surface water also might contribute to exposure during certain periods and environmental conditions. The obligate parasitic stage (encysted glochidia stage) on a host fish might be exposed from surface water while partially encysted or from toxicants in host-fish tissue while fully encysted. Laboratory methods for testing for acute and chronic exposures in water have advanced, and toxicant-specific information has increased in recent years. However, additional research is needed to understand interactions of life history, habitat, and long-term exposure to contaminants through water, pore water, sediment, and diet so that the risks of environmental exposures can be properly assessed and managed. ?? 2008 by The North American Benthological Society.

Journal of the North American Benthological Societ↗

USGS1999

Oxidation and mobilization of selenium by nitrate in irrigation drainage

Selenium (Se) can be oxidized by nitrate (NO − 3 ) from irrigation on Cretaceous marine shale in western Colorado. Dissolved Se concentrations are positively correlated with dissolved NO − 3 concentrations in surface water and ground water samples from irrigated areas. Redox conditions dominate in the mobilization of Se in marine shale hydrogeologic settings; dissolved Se concentrations increase with increasing platinum-electrode potentials. Theoretical calculations for the oxidation of Se by NO − 3 and oxygen show favorable Gibbs free energies for the oxidation of Se by NO − 3 , indicating NO − 3 can act as an electron acceptor for the oxidation of Se. Laboratory batch experiments were performed by adding Mancos Shale samples to zero-dissolved-oxygen water containing 0, 5, 50, and 100 mg/L NO − 3 as N (mg N/L). Samples were incubated in airtight bottles at 25°C for 188 d; samples collected from the batch experiment bottles show increased Se concentrations over time with increased NO − 3 concentrations. Pseudo first-order rate constants for NO − 3 oxidation of Se ranged from 0.0007 to 0.0048/d for 0 to 100 mg N/L NO − 3 concentrations, respectively. Management of N fertilizer applications in Cretaceous shale settings might help to control the oxidation and mobilization of Se and other trace constituents into the environment.

Journal of Environmental Quality↗

USGS2025

Abundance of microplastics in a typical urban wetland in China: Association with occurrence and carbon storage

Microplastics (MPs) are gaining attention for their widespread presence and toxicity in ecosystems. However, their role as a carbon source in urban wetland carbon sinks is still unclear. In this study, the microplastic-carbon (MP-C) was firstly quantified based on the abundance and occurrence characteristics, including MP morphology, size and type in the Sanyang Wetland, a typical urban wetland of China. MP abundances ranged from 2.4 ± 0.6–14.9 ± 1.5 items/L in surface water and 6.6 ± 1.2 × 10 3 to 46.3 ± 5.9 × 10 3 items/kg in sediment. The predominant morphological characterization of MPs was fragments smaller than 200 μm in size, consisting of PP, PE, and PET, which suggests that the main source was domestic wastewater discharge nearby. Notably, in the Sanyang wetland, the contribution of MP-C to total organic carbon (TOC) was estimated to be 0.023 0.20 % in water and 0.026 0.28 % in sediment. With the continuous production of plastics globally, these values were predicted to increase to 0.12 0.71 % and 0.83 4.12 % by 2100, respectively. Although the estimations relied on simplified geometric assumptions for MP volume and theoretical carbon content, these approaches provide a reasonable basis for understanding MP-C dynamics in wetlands under current analytical constraints. The integration of MP-C characterization during environmental monitoring and management strategies would enhance our understanding of MP pollution's role in the carbon cycle.

Journal of Hazardous Materials↗

USGS2005

Seed storage conditions change the germination pattern of clonal growth plants in Mediterranean salt marshes

The effect of salinity level and extended exposure to different salinity and flooding conditions on germination patterns of three salt‐marsh clonal growth plants ( Juncus subulatus , Scirpus litoralis , and S. maritimus ) was studied. Seed exposure to extended flooding and saline conditions significantly affected the outcome of the germination process in a different, though predictable, way for each species, after favorable conditions for germination were restored. Tolerance of the germination process was related to the average salinity level measured during the growth/germination season at sites where established individuals of each species dominated the species cover. No relationship was found between salinity tolerance of the germination process and seed response to extended exposure to flooding and salinity conditions. The salinity response was significantly related to the conditions prevailing in the habitats of the respective species during the unfavorable (nongrowth/nongermination) season. Our results indicate that changes in salinity and hydrology while seeds are dormant affect the outcome of the seed‐bank response, even when conditions at germination are identical. Because these environmental‐history‐dependent responses differentially affect seed germination, seedling density, and probably sexual recruitment in the studied and related species, these influences should be considered for wetland restoration and management.

Doñana National Park↗

USGS2024

Contrasting migratory chronology and routes of Lesser Scaup: Implications of different migration strategies in a broadly distributed species

Migration allows birds to improve fitness by exploiting seasonal resource peaks and avoiding limitations. Migration strategies may differ among individuals within a species, but for all strategies, the benefit of increased fitness should outweigh the costs of migration. These costs can include increased mortality risk, time constraints in the annual cycle, and metabolic energy loss. We compared migratory chronology and routes of individuals from a broadly distributed species of waterfowl, the Lesser Scaup ( Aythya affinis ; hereafter Scaup), marked at the northern (66.51000° N, 145.98556° W) and southern (44.63778° N, 111.73694° W) extents of its breeding distribution in North America. Scaup breeding farther north in interior Alaska, USA migrated greater distances and had protracted migrations, especially in fall, compared to Scaup breeding farther south in southwest Montana, USA. During migration, Scaup breeding in Alaska used more staging and stopover areas compared to Scaup breeding in Montana. Scaup breeding in Alaska also spent less time at their breeding area and more time at their wintering areas compared to Scaup breeding in Montana. In addition, Scaup breeding in Alaska were largely absent from wintering areas in the Intermountain West that were used by Scaup breeding in Montana. These differences could have important effects on Scaup fitness and could contribute to differences in fecundity and recruitment observed across the Scaup’s broad latitudinal distribution. Understanding the fitness implications of intraspecific variation in migration strategies of broadly distributed species can assist resource managers by focusing conservation efforts on specific breeding populations, informing models of disease transmission, and improving projections of species’ responses to environmental change.

Journal of Field Ornithology↗

USGS2008

Land management impacts on dairy-derived dissolved organic carbon in ground water

Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L-1 in wells downgradient from wastewater ponds, 8 to 30 mg L-1 in corral wells, 5 to 12 mg L-1 in tile drains, and 4 to 15 mg L-1 in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 ??g L-1, well in excess of the maximum contaminant level of 80 ??g L-1 established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation (???4 to ???8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗