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At least 235 records · Page 13Linked to original sources

A sensitive and rapid method for the determination of trace amounts of selenium in geologic materials

A sensitive method for the determination of less than crustal abundance amounts of selenium has been developed that can be useful in the geochemical investigation of selenium. The sample is roasted with a flux of sodium carbonate, chloride, and chlorate and then digested in a mixture of nitric and phosphoric acids. The resulting solution is stabilised; the selenium is reacted with 2,3-diaminonaphthalene to form 4,5-benzopiazselenol, extracted with cyclohexane, and measured fluorometrically. The lower limit of selenium content of a sample that can be determined by this method is 0.04 p/m using a 0.5-g sample.

Journal of Research of the U.S. Geological Survey

Uncertainty in remote sensing of streams using noncontact radars

Accounting for freshwater resources and monitoring floods are vital functions for societies throughout the world. Remote-sensing methods offer great prospects to expand stream monitoring in developing countries and to smaller, headwater streams that are largely ungauged worldwide. This study evaluates the potential to estimate discharge using eight radar units that have been installed over streams in diverse hydrologic and hydraulic settings across the United States. The research highlights error characteristics associated with the measurements of stage using pulsed wave radars, mean channel velocity from continuous wave Doppler radars, and their combined use to estimate discharge at sites that were collocated with conventional streamgauges. Potential stage biases caused by the thermal expansion and contraction of supporting structures due to diurnal temperature changes were examined. A dry concrete, flume showed the temperature-dependent stage variations were no more than 2 cm. Surface velocity retrievals needed to be adjusted to represent the mean channel velocity when estimating discharge. Different approaches were evaluated and application of two different, depth-dependent adjustment factors was found to yield the most accurate estimates. This study found that it is possible to get accurate discharge estimates from noncontact radar measurements, providing cost-effective solutions for remote sensing of ungauged streams. Lastly, radar measurements of the raw variables (i.e., stage and surface velocity) can be used in an early alerting context to detect flash floods in ungauged streams.

Arizona, Colorado, Oklahoma, Texas

Flow of variably fluidized granular masses across three-dimensional terrain I. Coulomb mixture theory

Rock avalanches, debris flows, and related phenomena consist of grain-fluid mixtures that move across three-dimensional terrain. In all these phenomena the same basic forces, govern motion, but differing mixture compositions, initial conditions, and boundary conditions yield varied dynamics and deposits. To predict motion of diverse grain-fluid masses from initiation to deposition, we develop a depth-averaged, threedimensional mathematical model that accounts explicitly for solid- and fluid-phase forces and interactions. Model input consists of initial conditions, path topography, basal and internal friction angles of solid grains, viscosity of pore fluid, mixture density, and a mixture diffusivity that controls pore pressure dissipation. Because these properties are constrained by independent measurements, the model requires little or no calibration and yields readily testable predictions. In the limit of vanishing Coulomb friction due to persistent high fluid pressure the model equations describe motion of viscous floods, and in the limit of vanishing fluid stress they describe one-phase granular avalanches. Analysis of intermediate phenomena such as debris flows and pyroclastic flows requires use of the full mixture equations, which can simulate interaction of high-friction surge fronts with more-fluid debris that follows. Special numerical methods (described in the companion paper) are necessary to solve the full equations, but exact analytical solutions of simplified equations provide critical insight. An analytical solution for translational motion of a Coulomb mixture accelerating from rest and descending a uniform slope demonstrates that steady flow can occur only asymptotically. A solution for the asymptotic limit of steady flow in a rectangular channel explains why shear may be concentrated in narrow marginal bands that border a plug of translating debris. Solutions for static equilibrium of source areas describe conditions of incipient slope instability, and other static solutions show that nonuniform distributions of pore fluid pressure produce bluntly tapered vertical profiles at the margins of deposits. Simplified equations and solutions may apply in additional situations identified by a scaling analysis. Assessment of dimensionless scaling parameters also reveals that miniature laboratory experiments poorly simulate the dynamics of full-scale flows in which fluid effects are significant. Therefore large geophysical flows can exhibit dynamics not evident at laboratory scales.

Journal of Geophysical Research B: Solid Earth

Spectrofluorimetric procedure using 2,3-napthalenediamine for determining selenium in rocks

A spectrofluorimetric procedure using 2,3-naphthalenediamine is given for determining submicrogram and microgram quantities of selenium in mineralized rocks. Conditions for the satisfactory isolation and concentration of the selenium are investigated and tested on six USGS standard rocks of various types. Selenium contents of samples treated by an alkaline sinter and leach are compared with those obtained by acid decomposition and with published values determined by neutron-activation analyses. In pure solutions, 0.01 μg of selenium can be determined with a relative standard deviation of 25 percent, thus setting the determination limit at approximately 0.01 ppm Se in a 1.0-g sample. When the amount of selenium is ≥0.1 ppm, a relative standard deviation of 10 percent or less is obtained.

Journal of Research of the U.S. Geological Survey

Pneumonia in bighorn sheep: Risk and resilience

Infectious disease was an important driver of historic declines and extirpations of bighorn sheep (Ovis canadensis) in North America and continues to impede population restoration and management. Domestic sheep have long been linked to pneumonia outbreaks in bighorn sheep and this association has now been confirmed in 13 captive commingling experiments. However, ecological and etiological complexities still hinder our understanding and control of the disease. We provide an overview of the current state of knowledge about the biology and management of respiratory disease in bighorn sheep and propose strategies for moving forward. Epizootic pneumonia in bighorn sheep is polymicrobial. Mycoplasma ovipneumoniae, a bacterium host-specific to Caprinae and commonly carried by healthy domestic sheep and goats appears to be a necessary primary agent. All-age epizootics following introduction of M. ovipneumoniae along with other pathogens into bighorn sheep populations are usually severe (median mortality 47%) but fatality rates vary widely, from 15 – 100%. Disease severity may be influenced by the strain of M. ovipneumoniae, by secondary bacterial and viral pathogens, and by factors affecting transmission and host immunity. Once introduced, M. ovipneumoniae can persist in bighorn sheep populations for decades. Carrier dams transmit the pathogen to their susceptible lambs, triggering fatal pneumonia outbreaks in nursery groups, which limits recruitment and slows or prevents population recovery. The result is that demographic costs of pathogen persistence often outweigh the impacts of the initial invasion and die-off. There is currently no effective vaccine or antibiotic for domestic or wild sheep and to date, no management actions have been successful in reducing morbidity, mortality, or disease spread once pathogen invasion has occurred. Molecular-based strain typing suggests that spillover of M. ovipneumoniae into bighorn sheep populations from domestic small ruminants is ongoing, and that consequences of pathogen invasion are amplified by movements of infected bighorn sheep. Therefore, current disease management strategies focus on reducing risk of spillover from reservoir populations of domestic small ruminants and on limiting transmission among bighorn sheep. A broad array of approaches has been tried and more are needed to prevent pathogen introduction, induce disease fadeout in persistently infected populations, and promote population resilience across the diverse landscapes bighorn sheep inhabit. A comprehensive examination of disease dynamics across populations could help elucidate how disease fades out naturally and if population resilience can be increased in the face of infection. Cross-jurisdictional adaptive management experiments and transdisciplinary collaboration, including partnerships with members of the domestic sheep and goat community, are needed to facilitate innovation and speed progress towards sustainable solutions for managing pneumonia to protect and restore bighorn sheep populations.

California, Idaho, Nevada, Oregon, Utah, Washingto

Granular avalanches across irregular three-dimensional terrain: 1. Theory and computation

To establish a theoretical basis for predicting and interpreting the behavior of rapid mass movements on Earth's surface, we develop and test a new computational model for gravity-driven motion of granular avalanches across irregular, three-dimensional (3-D) terrain. The principles embodied in the model are simple and few: continuum mass and momentum conservation and intergranular stress generation governed by Coulomb friction. However, significant challenges result from the necessity of satisfying these principles when deforming avalanches interact with steep and highly variable 3-D terrain. We address these challenges in four ways. (1) We formulate depth-averaged governing equations that are referenced to a rectangular Cartesian coordinate system (with z vertical) and that account explicitly for the effect of nonzero vertical accelerations on depth-averaged mass and momentum fluxes and stress states. (2) We compute fluxes of mass and momentum across vertical cell boundaries using a high-resolution finite volume method and Roe-type Riemann solver. Our algorithm incorporates flux difference splitting, an entropy correction for the flux, and eigenvector decomposition to embed the effects of driving and resisting forces in Riemann solutions. (3) We use a finite element method and avalanche displacements predicted by Riemann solutions to compute Coulomb stresses conjugate to the displacements in 3-D stress space. (4) We test the model output against analytical solutions, a sand cone conceptual experiment, and (in a companion paper) data from detailed laboratory experiments. Model results illustrate a complex interplay of basal traction and internal stress, and they successfully predict not only the gross behavior but also many details of avalanche motion from initiation to deposition.

Journal of Geophysical Research Earth Surface

Sterilization of sea lampreys ( Petromyzon marinus ) by immersion in an aqueous solution of bisazir

Groups of sea lamprey ( Petromyzon marinus ) eggs fertilized by males previously immersed in an aqueous solution of p , p -bis(1-aziridinyl)- N -methylphosphinothioic amide (bisazir) at concentrations of 10–100 mg/L produced fewer normal, live prolarvae after 15–17 d of incubation than did groups of eggs fertilized by normal males. Mortality of embryos or prolarvae was nearly 100% in groups of eggs fertilized by males that had been immersed in a 50 mg/L solution of bisazir for 4 h or in a 100 mg/L solution for 2 h. The immersion technique appears to be an efficient method of sterilizing large numbers of male sea lampreys for use in a proposed sterile-male-release program. Key words : sea lamprey, Petromyzon marinus ; pest control, fish control, sterile-male technique, sterilization, chemosterilants, bisazir, Great Lakes

Canadian Journal of Fisheries and Aquatic Sciences

A guide to creating an effective big data management framework

Many agencies and organizations, such as the U.S. Geological Survey, handle massive geospatial datasets and their auxiliary data and are thus faced with challenges in storing data and ingesting it, transferring it between internal programs, and egressing it to external entities. As a result, these agencies and organizations may inadvertently devote unnecessary time and money to convey data without existing or outdated standards. This research aims to evaluate the components of data conveyance systems, such as transfer methods, tracking, and automation, to guide their improved performance. Specifically, organizations face the challenges of slow dispatch time and manual intervention when conveying data into, within, and from their systems. Conveyance often requires skilled workers when the system depends on physical media such as hard drives, particularly when terabyte transfers are required. In addition, incomplete or inconsistent metadata may necessitate manual intervention, process changes, or both. A proposed solution is organization-wide guidance for efficient data conveyance. That guidance involves systems analysis to outline a data management framework, which may include understanding the minimum requirements of data manifests, specification of transport mechanisms, and improving automation capabilities.

Journal of Big Data

Rapid determination of sulfur in rocks

Sulfur is determined turbidimetrically as barium sulfate after an aqua regia attack. The turbidity is formed in an ammoniacal solution from which R2O3 has been centrifuged. Reproducibility of turbidity is obtained by adding barium chloride as a solid rather than as a solution. Sulfur is determined in the range 0.01-4 percent within ±0.02 absolute, or approximately 5 percent of the amount present, whichever is larger. A 100-mg sample is used for sulfur concentrations of up to 0.50 percent S, a 20-mg sample for higher levels. A determination requires about 5 minutes.

Journal of Research of the U.S. Geological Survey

Ancient solution phenomena in the Madison Limestone (Mississippian) of north-central Wyoming

A karst topography was developed on the Madison Limestone of north-central Wyoming during the middle Meramecian early Chesterian time interval. Ancient karst features include enlarged joints, sinkholes, caves, and solution breccias that resulted from leaching of evaporitic beds in the upper 400 ft of the Madison bedrock. These features are predominantly phreatic rather than vadose. Most of the open spaces are fdled by sand and residual products reworked by the early Amsden sea, which transgressed the area during the Chesterian.

Wyoming

Groundwater flow and transport modeling

Deterministic, distributed-parameter, numerical simulation models for analyzing groundwater flow and transport problems have come to be used almost routinely during the past decade. A review of the theoretical basis and practical use of groundwater flow and solute transport models is used to illustrate the state-of-the-art. Because of errors and uncertainty in defining model parameters, models must be calibrated to obtain a best estimate of the parameters. For flow modeling, data generally are sufficient to allow calibration. For solute-transport modeling, lack of data not only limits calibration, but also causes uncertainty in process description. Where data are available, model reliability should be assessed on the basis of sensitivity tests and measures of goodness-of-fit. Some of these concepts are demonstrated by using two case histories.

Journal of Hydrology

Nitrate transport and transformation processes in unsaturated porous media

A series of experiments was conducted on two contrasting agricultural soils to observe the influence of soil texture, preferential flow, and plants on nitrate transport and denitrification under unsaturated conditions. Calcium nitrate fertilizer was applied to the surface of four large undisturbed soil cores (30 cm diameter by 40 cm height). Two of the cores were a structured clay obtained from central Missouri and two were an unstructured fine sand obtained from central Florida. The cores were irrigated daily and maintained at a matric potential of -20 kPa, representative of soil tension in the rooting zone of irrigated agricultural fields. Volumetric water content (θ), concentration of nitrate-N in the soil solution, and nitrous oxide flux at the surface, 10, 20, and 30 cm were monitored daily. Leaching loss of surface-applied N0 3 − -N was significant in both the sand and the clay. In unplanted sand cores, almost all of the applied nitrate was leached below 30 cm within 10 days. Gaseous N loss owing to denitrification was no greater than 2% of the nitrate-N applied to the unplanted sand cores and, in general, was less than 1 %. Although leaching was somewhat retarded in the clay cores, about 60% of the applied nitrate-N was leached from the unplanted clay soil in 5–6 weeks. Under unsaturated conditions, the clay had little to no tendency to denitrify despite the greater moisture content of the clay and retarded leaching of nitrate in the clay. The planted sand cores had surprisingly large gaseous N loss owing to denitrification, as much as 17% of the nitrate-N. Results from both the clay and sand experiments show that the dynamics of nitrate transport and transformation in unsaturated soils are affected by small, localized variations in the soil moisture content profile, the gaseous diffusion coefficient of the soil, the rate at which the nitrate pulse passes through the soil, the solubility of N 2 O and N 2 and the diffusion of the gasses through the soil solution, and development of a water content profile in the soil. Limited dentrification in the clay soil was due to a limited volume of soil available for infiltration after internal catchment and the development of denitrifying conditions resulting from the presence of an extensive macropore system.

Journal of Hydrology

Deformation in the White Mountain seismic gap, California-Nevada, 1972-1982

A 100×40 km trilateration network extending from Bishop, California, to near Hawthorne, Nevada, crosses the east end of the Long Valley caldera, site of renewed magma inflation in the 1979–1980 interval, and spans most of the White Mountain seismic gap. The network was surveyed in 1972, 1973, 1976, 1979, 1980, and 1982. The 1980 survey may be contaminated by a scale error. In addition, leveling surveys across the caldera have been run in 1932, 1957, 1975, 1980, 1982, and 1983. Interpretation of the deformation is complicated by the occurrence of the May 1980 Mammoth Lakes earthquake sequence (four earthquakes M L ≥6) at the south edge of the caldera as well as other moderate earthquakes within the White Mountain seismic gap. The vertical deformation is largely accounted for by 0.10‐ to 0.15‐km 3 expansion of a spherical magma chamber 8–10 km beneath the resurgent dome within the Long Valley caldera sometime between July 1979 and September 1980 with an additional expansion of perhaps 0.05 km 3 between September 1980 and July 1982. Some additional sources of deformation within the aftershock zone of the Mammoth Lakes earthquakes seem to be required to explain the horizontal deformation. We show that right‐lateral slip on vertical faults extending WNW from each of the three largest earthquakes in the Mammoth Lakes sequence provides the required additional deformation, but this solution is by no means unique. There are simply too few data to define the rather complex deformation that apparently occurred within the aftershock zone. There is little doubt, however, that inflation of a magma chamber beneath the resurgent dome within the Long Valley caldera was involved in the deformation.

California

Two-dimensional steady-state dispersion in a saturated porous medium

A previously developed analytical solution for two-dimensional dispersion is computed for various conditions. These results were then compared with solution of previously developed approximate models of transverse dispersion which were used to analyze experimentally derived concentration distribution. Comparison established that, whenever steady state was reached, the values of dispersion coefficient computed using the approximate expression agreed with values derived from exact expression and in addition allowed a quick computation of the parameter.

Journal of Research of the U.S. Geological Survey

An improved method of censusing deer in deciduous-coniferous forests

Aerial censusing has been used to determine densities of many large mammals, including deer ( Odocoileus virginianus ) in agricultural areas or deciduous forests (Saugstad 1942, Morse 1946, Petrides 1953, Sanderson 1953, Berner pers. comm.). However, observability of deer from the air remains a problem in northern coniferous forests. LeResche and Rausch (1974) determined that even with the much larger and more observable moose ( Alces alces ) during ideal snow conditions, experienced observers counted only 68% of a known number of animals; inexperienced observers counted 43%. Caughley (1974) and Caughley et al. (1976) suggested that the best solution to the problem of observability in aerial censuses is to measure the magnitude of the biases that exist, and correct estimates accordingly. This paper describes an attempt to measure observability bias in an aerial census of deer in deciduous coniferous habitat and to produce an accurate estimate of numbers.

Minnesota

Groundwater chemistry near an impoundment for produced water, Powder River Basin, Wyoming, USA

The Powder River Basin is one of the largest producers of coal-bed natural gas (CBNG) in the United States. An important environmental concern in the Basin is the fate of the large amounts of groundwater extracted during CBNG production. Most of this produced water is disposed of in unlined surface impoundments. A 6-year study of groundwater flow and water chemistry at one impoundment, Skewed Reservoir, has produced the most detailed data set for any impoundment in the Basin. Data were collected from a network of 21 observation wells and three suction lysimeters. A groundwater mound formed atop bedrock within initially unsaturated, unconsolidated deposits underlying the reservoir. Heterogeneity in physical and chemical properties of sediments resulted in complex groundwater flow paths and highly variable groundwater chemistry. Sulfate, bicarbonate, sodium, and magnesium were the dominant ions in all areas, but substantial variability existed in relative concentrations; pH varied from less than 3 to more than 9, and total dissolved solids concentrations ranged from less than 5000 to greater than 100,000 mg/L. Selenium was a useful tracer of reservoir water; selenium concentrations exceeded 300 μg/L in samples obtained from 18 of the 24 sampling points. Groundwater travel time from the reservoir to a nearby alluvial aquifer (a linear distance of 177 m) was calculated at 474 days on the basis of selenium concentrations. The produced water is not the primary source of solutes in the groundwater. Naturally occurring salts and minerals within the unsaturated zone, dissolved and mobilized by infiltrating impoundment water, account for most of the solute mass in groundwater. Gypsum dissolution, cation-exchange, and pyrite oxidation appear to be important reactions. The complex geochemistry and groundwater flow paths at the study site underscore the difficulty in assessing effects of surface impoundments on water resources within the Powder River Basin.

Wyoming

Pathogenicity of Bacillus thuringiensis variety kurstaki to Ixodes scapularis (Acari: Ixodidae)

Pathogenicity of the entomopathogenic bacterium Bacillus thuringiensis var. kurstaki de Barjac & Lemille was tested against the black-legged tick, Ixodes scapularis Say. Engorged larvae dipped in a solution of 108 spores per ml showed 96% mortality, 3 wk post-infection. The LC50 value for engorged larvae (concentration required to kill 50% of ticks) was 107 spores/ml. Bacillus thuringiensis shows considerable potential as a microbial control agent for the management of Ixodes scapularis .

Journal of Medical Entomology

The LTAR Grazing Land Common Experiment at the Jornada Experimental Range: Old genetics, new precision technologies, and adaptive value chains

Rangelands and the supply chains connected to them are central to the agrifood systems of the Southwestern United States. Local ranchers are simultaneously arid lands managers, herd managers, and marketing managers. To stay in business, they must constantly adapt to unpredictable forage resources and markets while conserving soils and vegetation resources for the long term. As climate warming and drying exacerbate the complexity and difficulty of day-to-day production, producers and policy-makers are seeking alternatives to “business as usual”. To meet this need, the LTAR-Jornada team has developed a package of strategies to help producers adapt to the local and inter-regional challenges. The package includes heritage cattle, precision ranching systems, and adaptive value chains. Five ranches across the Southwest have adopted different combinations of the strategies and are partnering to measure their benefits and drawbacks in real-world conditions. Opportunities for controlled experimentation differ among the ranches, so we use LTAR’s indicator system to assess and compare results. Even as we invest in co-producing knowledge about these three strategies, we recognize that progressive aridification and urbanization of Southwestern rangelands create challenges for which a single “silver bullet” agricultural innovation is unlikely to provide durable solutions. We are learning from our customers and stakeholders about ways to adjust the development of new options.

New Mexico