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At least 235 records · Page 13Linked to original sources
USGS2014

Several methods of studying fluctuations of ground‐water levels

As a result of increased interest in ground‐water conditions in recent years, records of water‐levels in wells are now being collected in many places in the United States for the primary purpose of determining the relation of precipitation and other natural factors to fluctuations in water‐level. In the past, records of ground‐water levels have been collected chiefly in connection with intensive investigations in areas where the water‐levels were affected by artificial withdrawals and it has not been generally possible to correlate water‐level fluctuations closely with natural factors. It now appears probable that certain methods of studying water‐level fluctuations may be utilized advantageously in areas unaffected by heavy artificial withdrawals, but these methods generally do not yield satisfactory results in areas where there is considerable pumping or artesian flow. Three such methods are presented in this paper. The methods have not been given intensive study and their practical use is therefore not yet fully known. It is hoped that their application will be further investigated. Illustrations of the methods have been taken from records of ground‐water levels in the Platte River Valley, Nebraska, collected by the United States Geological Survey in cooperation with the Conservation and Survey Division of the University of Nebraska.

Eos, Transactions, American Geophysical Union↗
USGS2018

Position-specific 13C distributions within propane from experiments and natural gas samples

Site-specific carbon isotope measurements of organic compounds potentially recover information that is lost in a conventional, ‘bulk’ isotopic analysis. Such measurements are useful because isotopically fractionating processes may have distinct effects at different molecular sites, and thermodynamically equilibrated populations of molecules tend to concentrate heavy isotopes in one molecular site versus another. Most recent studies of site-specific 13 C in organics use specialized Nuclear Magnetic Resonance (NMR) techniques or complex chemical degradations prior to mass spectrometric measurements. Herein we present the first application of a new mass spectrometric technique that reconstructs the site-specific carbon isotope composition of propane based on measurements of the 13 C/ 12 C ratios of two or more fragment ions that sample different proportions of the terminal and central carbon sites. We apply this method to propane from laboratory experiments and natural gas samples to explore the relationships between site-specific carbon isotope composition, full-molecular δ 13 C, thermal maturity, and variation in organic matter precursors. Our goal is to advance the understanding of the sources and histories of short-chain alkanes within geologic systems. Our findings suggest that propane varies in its site-specific carbon isotope structure, which is correlated with increasing thermal maturity, first increasing in terminal position δ 13 C and then increasing in both center and terminal position δ 13 C. This pattern is observed in both experimental and natural samples, and is plausibly explained by a combination of site-specific, temperature-dependent isotope effects associated with conversion of different precursor molecules (kerogen, bitumen, and/or oil) to propane, differences in site-specific isotopic contents of those precursors, and possibly distillation of reactive components of those precursors with increasing maturity. We hypothesize that the largest changes in site-specific isotopic content of propane occur when bitumen and/or oil replace kerogen as the dominant precursors. If correct, this phenomenon could have significant utility for understanding gas generation in thermogenic petroleum systems.

Geochimica et Cosmochimica Acta↗
USGS1999

Techniques for restoration of disturbed coastal wetlands of the Great Lakes

A long history of human-induced degradation of Great Lakes wetlands has made restoration a necessity, but the practice of wetland restoration is relatively new, especially in large lake systems. Therefore, we compiled tested methods and developed additional potential methods based on scientific understanding of Great Lakes wetland ecosytems to providc an overview of approaches for restoration. We addressed this challenge by focusing on four general fields of science: hydrology, sedimentology, chemistry, and biology. Hydrologic remediation methods include restoring hydrologic connections between diked and hydrologically altered wetlands and the lakes, restoring water tables lowered by ditching, and restoring natural variation in lake levels of regulated lakes Superior and Ontario. Sedimentological remediation methods include management of sediment input from uplands, removal or proper management of dams on tributary rivers, and restoration of protective barrier beaches and sand spits. Chemical remediation methods include reducing or eliminating inputs of contaminants from point and non-pont sources, natural sediment remediation by biodegradation and chemical degradation, and active sediment remediation by removal or by in situ treatment Biological remediation methods include control of non-target organisms, enhancing populations of target organisms, and enhancing habitat for target organisms. Some of these method were used in three major restoration projects (Metzger Marsh on Lake Erie and Cootes Paradise and Oshawa Second Marsh on Lake Ontario), which are described as case studies to show practical applications of wetland restoration in the Great Lakes. Successful restoration techniques that do not require continued manipulation must be founded in the basic tenets of ecology and should mimic natural processes. Success is demonstrated by the sustainability, productivity, nutrient-retention ability, invasibility, and biotic interactions within a restored wetland.

Wetlands↗
USGS2015

Extraction of hydrocarbons from high-maturity Marcellus Shale using supercritical carbon dioxide

Shale is now commonly exploited as a hydrocarbon resource. Due to the high degree of geochemical and petrophysical heterogeneity both between shale reservoirs and within a single reservoir, there is a growing need to find more efficient methods of extracting petroleum compounds (crude oil, natural gas, bitumen) from potential source rocks. In this study, supercritical carbon dioxide (CO 2 ) was used to extract n -aliphatic hydrocarbons from ground samples of Marcellus shale. Samples were collected from vertically drilled wells in central and western Pennsylvania, USA, with total organic carbon (TOC) content ranging from 1.5 to 6.2 wt %. Extraction temperature and pressure conditions (80°C and 21.7 MPa, respectively) were chosen to represent approximate in situ reservoir conditions at sample depth (1920–2280 m). Hydrocarbon yield was evaluated as a function of sample matrix particle size (sieve size) over the following size ranges: 1000–500 μm, 250–125 μm, and 63–25 μm. Several methods of shale characterization including Rock-Eval II pyrolysis, organic petrography, Brunauer–Emmett–Teller surface area, and X-ray diffraction analyses were also performed to better understand potential controls on extraction yields. Despite high sample thermal maturity, results show that supercritical CO 2 can liberate diesel-range ( n -C 11 through n -C 21 ) n -aliphatic hydrocarbons. The total quantity of extracted, resolvable n -aliphatic hydrocarbons ranges from approximately 0.3 to 12 mg of hydrocarbon per gram of TOC. Sieve size does have an effect on extraction yield, with highest recovery from the 250–125 μm size fraction. However, the significance of this effect is limited, likely due to the low size ranges of the extracted shale particles. Additional trends in hydrocarbon yield are observed among all samples, regardless of sieve size: 1) yield increases as a function of specific surface area ( r 2 = 0.78); and 2) both yield and surface area increase with increasing TOC content ( r 2 = 0.97 and 0.86, respectively). Given that supercritical CO 2 is able to mobilize residual organic matter present in overmature shales, this study contributes to a better understanding of the extent and potential factors affecting the extraction process.

Pennsylvania↗
USGS2016

Methods for estimating peak-flow frequencies at ungaged sites in Montana based on data through water year 2011: Chapter F in Montana StreamStats

The U.S. Geological Survey (USGS), in cooperation with the Montana Department of Natural Resources and Conservation, completed a study to update methods for estimating peak-flow frequencies at ungaged sites in Montana based on peak-flow data at streamflow-gaging stations through water year 2011. The methods allow estimation of peak-flow frequencies (that is, peak-flow magnitudes, in cubic feet per second, associated with annual exceedance probabilities of 66.7, 50, 42.9, 20, 10, 4, 2, 1, 0.5, and 0.2 percent) at ungaged sites. The annual exceedance probabilities correspond to 1.5-, 2-, 2.33-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year recurrence intervals, respectively. Regional regression analysis is a primary focus of Chapter F of this Scientific Investigations Report, and regression equations for estimating peak-flow frequencies at ungaged sites in eight hydrologic regions in Montana are presented. The regression equations are based on analysis of peak-flow frequencies and basin characteristics at 537 streamflow-gaging stations in or near Montana and were developed using generalized least squares regression or weighted least squares regression. All of the data used in calculating basin characteristics that were included as explanatory variables in the regression equations were developed for and are available through the USGS StreamStats application (http://water.usgs.gov/osw/streamstats/) for Montana. StreamStats is a Web-based geographic information system application that was created by the USGS to provide users with access to an assortment of analytical tools that are useful for water-resource planning and management. The primary purpose of the Montana StreamStats application is to provide estimates of basin characteristics and streamflow characteristics for user-selected ungaged sites on Montana streams. The regional regression equations presented in this report chapter can be conveniently solved using the Montana StreamStats application. Selected results from this study were compared with results of previous studies. For most hydrologic regions, the regression equations reported for this study had lower mean standard errors of prediction (in percent) than the previously reported regression equations for Montana. The equations presented for this study are considered to be an improvement on the previously reported equations primarily because this study (1) included 13 more years of peak-flow data; (2) included 35 more streamflow-gaging stations than previous studies; (3) used a detailed geographic information system (GIS)-based definition of the regulation status of streamflow-gaging stations, which allowed better determination of the unregulated peak-flow records that are appropriate for use in the regional regression analysis; (4) included advancements in GIS and remote-sensing technologies, which allowed more convenient calculation of basin characteristics and investigation of many more candidate basin characteristics; and (5) included advancements in computational and analytical methods, which allowed more thorough and consistent data analysis. This report chapter also presents other methods for estimating peak-flow frequencies at ungaged sites. Two methods for estimating peak-flow frequencies at ungaged sites located on the same streams as streamflow-gaging stations are described. Additionally, envelope curves relating maximum recorded annual peak flows to contributing drainage area for each of the eight hydrologic regions in Montana are presented and compared to a national envelope curve. In addition to providing general information on characteristics of large peak flows, the regional envelope curves can be used to assess the reasonableness of peak-flow frequency estimates determined using the regression equations.

Montana↗
USGS2018

The use of remote camera trapping to study cheetahs

Remote camera trapping is an efficient noninvasive technique for monitoring rare and elusive species, such as cheetahs. The unique pelage pattern of cheetahs allows for identification of individuals from photographs, providing detection histories that are naturally suited for abundance estimation using capture–recapture methods. Furthermore, the spatial location of photographic detections allows for the use of spatial capture–recapture models, which provide estimates of density. In this chapter, we describe aspects of cheetah ecology that should be considered when designing camera trapping surveys (e.g., social structure, natural densities, and home range size) to estimate cheetah density and provide guidance for future camera trap sampling and analysis.

Book chapter↗
USGS2016

Developing population models with data from marked individuals

Population viability analysis (PVA) is a powerful tool for biodiversity assessments, but its use has been limited because of the requirements for fully specified population models such as demographic structure, density-dependence, environmental stochasticity, and specification of uncertainties. Developing a fully specified population model from commonly available data sources – notably, mark–recapture studies – remains complicated due to lack of practical methods for estimating fecundity, true survival (as opposed to apparent survival), natural temporal variability in both survival and fecundity, density-dependence in the demographic parameters, and uncertainty in model parameters. We present a general method that estimates all the key parameters required to specify a stochastic, matrix-based population model, constructed using a long-term mark–recapture dataset. Unlike standard mark–recapture analyses, our approach provides estimates of true survival rates and fecundities, their respective natural temporal variabilities, and density-dependence functions, making it possible to construct a population model for long-term projection of population dynamics. Furthermore, our method includes a formal quantification of parameter uncertainty for global (multivariate) sensitivity analysis. We apply this approach to 9 bird species and demonstrate the feasibility of using data from the Monitoring Avian Productivity and Survivorship (MAPS) program. Bias-correction factors for raw estimates of survival and fecundity derived from mark–recapture data (apparent survival and juvenile:adult ratio, respectively) were non-negligible, and corrected parameters were generally more biologically reasonable than their uncorrected counterparts. Our method allows the development of fully specified stochastic population models using a single, widely available data source, substantially reducing the barriers that have until now limited the widespread application of PVA. This method is expected to greatly enhance our understanding of the processes underlying population dynamics and our ability to analyze viability and project trends for species of conservation concern.

Biological Conservation↗
USGS2011

Using a semi-natural stream to produce young sturgeons for conservation stocking: Maintaining natural selection during spawning and rearing

Young sturgeons used for conservation stocking are presently produced using the same methods used for commercial culture. To determine if young sturgeons could be produced without relaxing natural selection factors, we developed a semi‐natural stream where we annually studied mating of wild shortnose sturgeon ( Acipenser brevirostrum ) observed movement of gametes released freely during spawning, and estimated the number of larvae produced by various densities of spawned eggs. The stream had a bottom area of 18.8 m 2 , a rubble–gravel bottom, and a mean bottom current at 0.6 depth during spawning of 48 cm s −1 (range, 17–126 cm s −1 ). Wild adults successfully spawned in the stream each year for 7 years (2002–2008). Some females and males were more successful during spawning than others, suggesting an unequal fitness during spawning among wild individuals, which is different than the controlled spawning fitness of individuals in hatcheries. Male and female gametes spawned naturally must connect quickly in the fast current or fail, a selection factor absent in hatcheries. The number of larvae produced was inversely related to spawned egg density m −2 ( R 2 = 0.65) and the maximum number of larvae produced was 8000–16 000 (425–851 larvae m −2 of bottom). Artificial spawning streams have the potential to contribute to sturgeon restoration.

Journal of Applied Ichthyology↗
USGS2000

Methodology for applying monitored natural attenuation to petroleum hydrocarbon-contaminated ground-water systems with examples from South Carolina

Natural attenuation processes such as dispersion, advection, and biogradation serve to decrease concentrations of disssolved contaminants as they are transported in all ground-water systems. However, the efficiency of these natural attenuation processes and the degree to which they help attain remediation goals, varies considerably from site to site. This report provides a methodology for quantifying various natural attenuation mechanisms. This methodology incorporates information on (1) concentrations of contaminants in space and/or time; (2) ambient reduction/oxidation (redox) conditions; (3) rates and directions of ground-water flow; (4) rates of contaminant biodegradation; and (5) demographic considerations, such as the presence of nearby receptor exposure points or property boundaries. This document outlines the hydrologic, geochemical, and biologic data needed to assess the efficiency of natural attenuation, provides a screening tool for making preliminary assessments, and provides examples of how to determine when natural attenuation can be a useful component of site remediation at leaking underground storage tank sites. At a site in the Piedmont Physiographic Province (Laurens, South Carolina), hydrologic and water-chemistry data indicate that the natural attenuation capacity for benzene is approximately 5 percent per foot of flowpath. As a result, benzene concentrations would decrease from about 28,000 micrograms per liter in ground water at the source area to less than 5 micrograms per liter 200 feet downgradient and prior to discharging to a stream. Because of this rapid attenuation, contaminants do not presently impact the stream downgradient of the site. In contrast, at a site in the coastal Plain Physiographic Province (Charleston, South Carolina), hydrologic and water-chemistry data indicate that, even thought the site has a substantial natural attenuation capacity, it may not be sufficient to fully protect a nearby point of ground-water discharge. These two sites illustrate how the efficiency of natural attenuation processes acting on petroleum hydrocarbons can be systematically evaluated using hydrologic, geochemical, and microbiologic methods. These methods, in turn, can be used to assess the role that the natural attenuation of petroleum hydrocarbons can play in achieving overall site remediation.

South Carolina↗
USGS2022

GSPy: A new toolbox and data standard for Geophysical Datasets

The diversity of geophysical methods and datatypes, as well as the isolated nature of various specialties (e.g., electromagnetic, seismic, potential fields) leads to a profusion of separate data file formats and documentation conventions. This can hinder cooperation and reduce the impact of datasets researchers have invested in heavily to collect and prepare. An open, portable, and well-supported community data standard could greatly improve the interoperability, transferability, and long-term archival of geophysical data. Airborne geophysical methods particularly need an open and accessible data standard, and they exemplify the complexity that is common in geophysical datasets where critical auxiliary information on the survey and system parameters are required to fully utilize and understand the data. Here, we propose a new Geophysical Standard, termed the GS convention, that leverages the well-established and widely used NetCDF file format and builds on the Climate and Forecasts (CF) metadata convention. We also present an accompanying open-source Python package, GSPy, to provide methods and workflows for building the GS-standardized NetCDF files, importing and exporting between common data formats, preparing input files for geophysical inversion software, and visualizing data and inverted models. By using the NetCDF format, handled through the Xarray Python package, and following the CF conventions, we standardize how metadata is recorded and directly stored with the data, from general survey and system information down to specific variable attributes. Utilizing the hierarchical nature of NetCDF, GS-formatted files are organized with a root Survey group that contains global metadata about the geophysical survey. Data are then organized into subgroups beneath Survey and are categorized as Tabular or Raster depending on the geometry and point of origin for the data. Lastly, the standard ensures consistency in constructing and tracking coordinate reference systems, which is vital for accurate portability and analysis. Development and adoption of a NetCDF-based data standard for geophysical surveys can greatly improve how these complex datasets are shared and utilized, making the data more accessible to a broader science community. The architecture of GSPy can be easily transferred to additional geophysical datatypes and methods in future releases.

Frontiers in Earth Science - Environmental Informa↗
USGS1981

E-field ratio telluric survey near the Big Maria Mountains, Riverside County, California

The U.S. Geological Survey (USGS) under the Wilderness Act (Public Law 88-577) and the Federal Land Policy and Management Act (Public Law 94-579) has the responsibility, along with the U.S. Bureau of Mines, to survey certain areas in order to determine their mineral resource potential. This report presents results of three electric-field ratio telluric traverses conducted as part of the Bureau of Land Management Wilderness Program in the Big Maria Mountains, Riverside County, Calif. The telluric traverses were run on the southwest side of the Big Maria Mountains in an attempt to define the location of major buried faults near the eroded front of the range. E-field ratio tellurics is a descriptive name applied to the electrical exploration technique used in this survey. The telluric method refers to the measurement of the earth's electric field generated by induction from natural electromagnetic waves arriving at the surface. The E-field ratio telluric method uses a receiving array of three electrodes spaced equidistant and inline. This array is, in effect, two colinear dipoles sharing a common electrode. The potential difference across each dipole is then proportional to the component of the telluric field in the direction of the array. This configuration permits the measurement of the ratio of the telluric field at each dipole in the direction of the dipole line, and hence the name. The traverse data is extended by moving the three-electrode array forward one dipole length so that the forward electrode becomes the center electrode for the next ratio measurement. Electric-field data so obtained are proportional to the square root of the apparent resistivity of the earth at the location of the dipoles. However, because the apparent resistivity can be a function of the dipole direction, it is important to know the orientation of the dipoles with respect to major structures. Because the resistivity of fluid-saturated earth materials is largely dependent on the porosity of the rocks, the salinity of the pore fluid, and the presence of clays or similar material where surface conduction is high, alluvial fill, argillite and similar rocks tend to have low resistivities whereas igneous or high-grade metamorphic rocks have high resistivities. Variation in the electrical properties along a traverse may then be used to infer lithologic or structural changes.

California↗
USGS2025

Initial responses of songbird communities to forest reclamation on legacy surface mines

Surface coal mining and subsequent reclamation efforts in the Appalachian Mountains, USA, transform the ecological characteristics of natural landscapes. The Forestry Reclamation Approach (FRA) is a mine reclamation method that emphasizes best management practices in forestry. FRA practices have demonstrated success in establishing native forests and accelerating natural succession on coal mines; however, no studies have empirically examined the effects of the FRA on bird communities. Our study aimed to assess the avian community composition within young forests reclaimed using the FRA after one decade of forest growth. Whereas traditional reclamation practices often support grassland avian guilds, we expected that the FRA would provide habitat for shrubland and young forest avian guilds. Moreover, we sought to determine whether FRA forests would contain known avian indicator species of the native forest land cover. In June 2022, we conducted point count surveys in high-elevation, red spruce-northern hardwood (RS-NH) forests in the Appalachian Mountains of eastern West Virginia, USA. Using Bayesian multispecies occupancy models, we assessed avian guild occupancy and species richness within two FRA forest age classes (2–5 years and 8–11 years). We also examined avian community composition within two older RS-NH reference age classes to predict the future avian composition within FRA forests if reclamation succeeds. We found that the FRA breeding bird community included all of the avian indicator species expected to inhabit a young RS-NH forest. These results suggest that after approximately one decade, legacy mines reclaimed using the FRA are progressing toward a native RS-NH forest that supports associated forest bird communities.

West Virginia↗
USGS2023

Method for identification of reservoir regulation within U.S. Geological Survey streamgage basins in the Central United States using a decadal dam impact metric

Researchers routinely study streamflow data to understand the effects of natural climate variability and anthropogenic climate change, and to develop methods for estimating streamflow at ungaged locations. These studies require streamflow data that are not modified or largely altered by other anthropogenic activities, such as reservoirs or diversions. This report discusses a method for identifying basins with reservoir regulation using a decadal impact metric that characterizes the degree of regulation of a given river reach. The method is applied to U.S. Geological Survey streamgage basins from eight States in the Central United States. Using this metric, 140 streamgages with known regulation effects (annual peak streamflow values qualified with a code 6) were evaluated for their impact metric values in decades with annual peak streamflow values qualified with code 6. Based on the distribution of median impact metric values at these regulated basins, a threshold value of 0.1 was identified as the value that when exceeded was the most characteristic of the regulated streamgage basins in the study area. Streamgage basins from nine States with peak streamflow values that were not qualified with code 6 were evaluated for impact metric values equal to or greater than the established threshold. About 13 percent of streamgages (136 of 1,017) had an impact metric equal to or greater than the identified regulated threshold at some point in their periods of record. The method discussed in this report, which has limitations owing to characteristics of the data underlying the dam impact metric, provides a regionally consistent approach to identifying regulated U.S. Geological Survey streamgage basins.

Iowa, Illinois, Michigan, Missouri, Montana, North↗
USGS2017

Earthquake source properties from instrumented laboratory stick-slip

Stick-slip experiments were performed to determine the influence of the testing apparatus on source properties, develop methods to relate stick-slip to natural earthquakes and examine the hypothesis of McGarr [2012] that the product of stiffness, k , and slip duration, Δ t , is scale-independent and the same order as for earthquakes. The experiments use the double-direct shear geometry, Sierra White granite at 2 MPa normal stress and a remote slip rate of 0.2 µm/sec. To determine apparatus effects, disc springs were added to the loading column to vary k . Duration, slip, slip rate, and stress drop decrease with increasing k , consistent with a spring-block slider model. However, neither for the data nor model is k Δ t constant; this results from varying stiffness at fixed scale. In contrast, additional analysis of laboratory stick-slip studies from a range of standard testing apparatuses is consistent with McGarr's hypothesis. k Δ t is scale-independent, similar to that of earthquakes, equivalent to the ratio of static stress drop to average slip velocity, and similar to the ratio of shear modulus to wavespeed of rock. These properties result from conducting experiments over a range of sample sizes, using rock samples with the same elastic properties as the Earth, and scale-independent design practices.

Book chapter↗
USGS1958

The next decade in geochemistry

The purpose, associations, functions; and activities of the Geochmical Society are reviewed briefly. Work on the Colorado Plateau uranium deposits is described as an example of what geochemical research, in conjunction with detailed field work, mineralogical studies, and related techniques can contribute to the understanding of a type of deposit. It is pointed out that not only have these studies given a great deal of information about the origin of the ores, but they have brought about directly a manifold increase in production and reserves of uranium in the United States. Indirectly, they aided the discovery of the tremendous deposits of the Blind River area in Ontario. It is suggested that similar broad cooperative attacks could not only yield comparable results with other types of mineral deposits, such as laterites and Mississippi Valley type lead-zinc deposits, but could also advance our knowledge and understanding of such diverse problems of geology and cosmology as the origin of granites, origin and geologic implications of meteorites (including tektites), origin and search for petroleum, and geochemical relations and interpretations of natural waters. For each of these problems methods of approach are outlined and for some of them, specific projects and correlative problems are mentioned. It is further suggested that the broad cooperative attack needed for most of these problems might be fostered most effectively by a programme comparable to that of the I.G.Y., even though for most types of geochemical research synoptic sampling and observations are not as important as they are for many projects in geophysics.

Geochimica et Cosmochimica Acta↗
USGS2024

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment↗
USGS1999

Double-disk solid-phase extraction--Simultaneous cleanup and trace enrichment of herbicides and metabolites from environmental samples

Phenylurea and triazine herbicides, including some metabolites, were isolated from water and soil extracts by solid-phase extraction using a layered system of two extraction disks, a method called double-disk solid-phase extraction. The first disk consisted of strong anion exchange (SAX) of 10-μm styrene divinylbenzene (SDB) particles embedded in Teflon, and the second disk was a C 18 disk of 10-μm particles also embedded in Teflon. A volume of 500 mL of water or aqueous soil extract is passed through the layered system with the SAX disk first. The purpose of the SAX disk is to remove the humic and fulvic acids from the water or aqueous soil extract by ion exchange through their carboxyl groups. Even during methanol elution of herbicides, the humic substances remain bound to the SAX disk with >85% retention. Elution with methanol results in more than 90% recovery of the herbicides from the layered extraction disks. Removal of the humic and fulvic acids results in greater sensitivity for diode array detection quantitation (0.05 μg/L for herbicides) by substantially reducing the absorbance of the humic peak on the LC chromatogram. The herbicides adsorb to the SAX disk either through hydrogen bonding to the anion-exchange sites or by hydrophobic interaction with the SDB surface of the anion-exchange disk. The method was tested for the analysis of natural water samples from the Mississippi Embayment, a cotton-growing area of the southeastern United States.

Analytical Chemistry↗
USGS2004

Granular avalanches across irregular three-dimensional terrain: 2. Experimental tests

Scaling considerations indicate that miniature experiments can be used to test models of granular avalanches in which the effects of intergranular fluid and cohesion are negligible. To test predictions of a granular avalanche model described in a companion paper, we performed bench top experiments involving avalanches of dry sand across irregular basal topography that mimicked the complexity of natural terrain. The experiments employed a novel method of laser-assisted cartography to map the three-dimensional morphology of rapidly moving avalanches, thereby providing high-resolution data for comparison with model output. Model input consisted of two material properties (angles of internal and basal Coulomb friction of the sand), which were measured in independent tests, and of initial and boundary conditions that characterized the geometry of the experimental apparatus. Experimental results demonstrate that the model accurately predicts not only the gross behavior but also many details of avalanche motion, from initiation to deposition. We attribute this accuracy to a mathematical and computational formulation that conserves mass and momentum in three-dimensional physical space and satisfies the Coulomb equation in three-dimensional stress space. Our results support the hypothesis that a Coulomb proportionality between shear and normal stresses applies in moderately rapid granular flows and that complicated constitutive postulates are unnecessary if momentum conservation is strictly enforced in continuum avalanche models. Furthermore, predictions of our Coulomb continuum model contrast with those of a Coulomb point mass model, illustrating the importance of multidimensional modeling and model testing.

Journal of Geophysical Research Earth Surface↗