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Evaluation of field and laboratory research on scour at bridge piers in the United States

The Federal Highway Administration sponsored a laboratory research at Colorado State University and field data collection with the US Geological Survey, to evaluate the effects of bed material on the depth of scour. Correction factors are compared to include the effect of bed material in the HEC-18 equation. The HEC-18 equation tends to overpredict the observed scour for streams with coarse bed material. The field-based correction factor K4 causes underprediction associated with data collected from other countries.

Conference Paper

Automated identification of stream-channel geomorphic features from high‑resolution digital elevation models in West Tennessee watersheds

High-resolution digital elevation models (DEMs) derived from light detection and ranging (lidar) enable investigations of stream-channel geomorphology with much greater precision than previously possible. The U.S. Geological Survey has developed the DEM Geomorphology Toolbox, containing seven tools to automate the identification of sites of geomorphic instability that may represent sediment sources and sinks in stream-channel networks. These tools can be used to modify input DEMs on the basis of known locations of stormwater infrastructure, derive flow networks at user-specified resolutions, and identify possible sites of geomorphic instability including steep banks, abrupt changes in channel slope, or areas of rough terrain. Field verification of tool outputs identified several tool limitations but also demonstrated their overall usefulness in highlighting likely sediment sources and sinks within channel networks. In particular, spatial clusters of outputs from multiple tools can be used to prioritize field efforts to assess and restore eroding stream reaches.

Tennessee

Investigation of pier scour in coarse-bed streams in Montana, 2001 through 2007

A primary goal of ongoing field research of bridge scour is improvement of scour-prediction equations so that pier-scour depth is predicted accurately-an important element of hydraulic analysis and design of highway bridges that cross streams, rivers, and other waterways. Scour depth for piers in streambeds with a mixture of sand, gravel, cobbles, and boulders (coarse-bed streams, which are common in Montana) generally is less than the scour depth in finer-grained (sandy) streambeds under similar conditions. That difference is attributed to an armor layer of coarser material. Pier-scour data from the U.S. Geological Survey were used in this study to develop a bed-material correction factor, which was incorporated into the Federal Highway Administration's recommended equation for computing pier scour. This report describes results of a study of pier scour in coarse-bed streams at 59 bridge sites during 2001-2007 in the mountain and foothill regions of western Montana. Respective drainage areas ranged from about 3 square miles (mi 2 ) to almost 20,000 mi 2 . Data collected and analyzed for this study included 103 pier-scour measurements; the report further describes data collection, shows expansion of the national coarse pier-scour database, discusses use of the new data in evaluation of relative accuracy of various predictive equations, and demonstrates how differences in size and gradation between surface bed material and shallow-subsurface bed material might relate to pier scour. Nearly all measurements were made under clear-water conditions with no incoming sediment supply to the bridge opening. Half of the measurements showed approach velocities that equaled or surpassed the critical velocity for incipient motion of bed material, possibly indicating that measurements were made very near the threshold between clear-water and live-bed scour, where maximum scour was shown in laboratory studies. Data collected in this study were compared to selected pier-scour data from the nationwide Bridge Scour Data Management System (BSDMS), to show the effect of bed-material size and gradation on scour depth. Unsteady field flow conditions and armoring by coarser material reduced scour relative to the clear-water/sandy-bed laboratory results at steady flow. The new correction factor and the standard scour equation produced the most accurate estimates of scour depth in armored, coarse-bed conditions. Maximum relative scour occurred at similar velocity across variations in bed material and gradation. Pier scour decreased with increased variation in particle size and gradation.

Montana

Connecting diverse disciplines to improve understanding of surface water-groundwater interactions

Laura K. Lautz is a premier mentor, collaborator, and researcher at the intersection of natural hydrologic systems and humans. Her research has shifted the paradigm around measuring and understanding the impacts of surface water and groundwater interactions across spatial and temporal scales. She has done this by testing and refining new methods and by collaborating with, training, supporting, and mentoring diverse scientists. Here, we review her research across five themes, summarizing the prior status of the field, what Lautz contributed, as well as new directions in the field inspired by her work. Lautz’s research expanded our understanding of the impacts of stream restoration on surface water-groundwater interactions, where she tested new field methods and showed that restoration structures increase hyporheic exchange, locally altering biogeochemical function of the streambed. She refined novel methods for measuring surface water-groundwater exchanges and worked to make these methods easily accessible through freely available software. Her research group greatly expanded the use of heat as a quantitative tracer of hydrologic processes via the well-used VFLUX and HFLUX programs. Her research evaluated the impacts of surface water-groundwater interactions in urban streams, showing the substantial fluxes of nutrients and chloride that can move through those exchanges and the potential for groundwater to help buffer contamination. To assess groundwater impacts on streamflow below tropical glaciers, she used a wide range of field methods to reveal the sensitivity of these systems to climate change. Finally, she built tools to quantify natural brine contamination of drinking water wells in areas that may later be subject to high-volume hydraulic fracturing, creating a needed ‘pre-fracking’ dataset. Through this process, she identified multiple sources of salinity that are already reaching wells in these systems. Overall, this research has been done with a focus on mentoring and training the next generation of hydrologists, including work to specifically train for careers beyond academia, and facilitating early career scientists to realize their innate potentials. With former trainees in careers across industry, government, and academia, Dr. Laura K. Lautz is now working to build cross-disciplinary research at even larger scales, across federal research units, guaranteeing that an even larger impact on hydrology is still to come.

Journal of Hydrology X

Reconnaissance sediment budget for selected watersheds of West Maui, Hawai‘i

Episodic runoff brings suspended sediment to the nearshore waters of West Maui, Hawaiʻi. Even small rainfalls create visible plumes over a few hours. We used mapping, field experiments, and analysis of recent (July 19–20, 2014) and historic rainfall to estimate sources of land-based pollution for two watersheds in West Maui: Honolua, and Honokōwai. Former agricultural fields and some unimproved roads are plausible sources for polluted runoff, but have saturated hydraulic conductivities greater than the 10–15 millimeters per hour (mm/hr) rainfalls of July 2014. These fields and roads showed minor evidence for storm runoff, and could not have contributed substantially to July 2014 plume generation. Since 1978, rain at intensities capable of causing runoff from former agricultural fields sustained for 1–2 hours is also rare; such intensities have 2–5 year recurrence rates in the north, and greater than 25 year recurrence rates to the south near Lahaina. Streambanks now eroding into historic terraces of sands, silts, and clays are a more plausible source. Although past large storms contributed to sediment loading, annual plume generation is now caused by smaller rainfalls eroding these near-stream legacy deposits. Treatments of former agricultural fields, roads, and reserve forests are consequently not likely to measurably affect sediment pollution from smaller, more frequent storms. Increased runoff from the development of West Maui has the potential to exacerbate sediment plumes from such storms unless there is an effective strategy to reduce bank erosion. Uncertainties in the extent and erosion rate of historic terraces, however, limit our ability to plan mitigation.

Hawaii

In-situ sediment oxygen demand rates in Hammonton Creek, Hammonton, New Jersey, and Crosswicks Creek, near New Egypt, New Jersey, August-October 2009

Sediment oxygen demand rates were measured in Hammonton Creek, Hammonton, New Jersey, and Crosswicks Creek, near New Egypt, New Jersey, during August through October 2009. These rates were measured as part of an ongoing water-quality monitoring program being conducted in cooperation with the New Jersey Department of Environmental Protection. Oxygen depletion rates were measured using in-situ test chambers and a non-consumptive optical electrode sensing technique for measuring dissolved oxygen concentrations. Sediment oxygen demand rates were calculated on the basis of these field measured oxygen depletion rates and the temperature of the stream water at each site. Hammonton Creek originates at an impoundment, then flows through pine forest and agricultural fields, and receives discharge from a sewage-treatment plant. The streambed is predominantly sand and fine gravel with isolated pockets of organic-rich detritus. Sediment oxygen demand rates were calculated at four sites on Hammonton Creek and were found to range from -0.3 to -5.1 grams per square meter per day (g/m 2 /d), adjusted to 20 degrees Celsius. When deployed in pairs, the chambers produced similar values, indicating that the method was working as expected and yielding reproducible results. At one site where the chamber was deployed for more than 12 hours, dissolved oxygen was consumed linearly over the entire test period. Crosswicks Creek originates in a marshy woodland area and then flows through woodlots and pastures. The streambed is predominantly silt and clay with some bedrock exposures. Oxygen depletion rates were measured at three sites within the main channel of the creek, and the calculated sediment oxygen demand rates ranged from -0.33 to -2.5 g/m 2 /d, adjusted to 20 degrees Celsius. At one of these sites sediment oxygen demand was measured in both a center channel flowing area of a pond in the stream and in a stagnant non-flowing area along the shore of the pond where organic-rich bottom sediments had accumulated and lower dissolved oxygen concentration conditions existed in the water column. Dissolved oxygen concentrations in the center channel test chamber showed a constant slow decrease over the entire test period. Oxygen consumption in the test chamber at the near-shore location began rapidly and then slowed over time as oxygen became depleted in the chamber. Depending on the portion of the near-shore dissolved oxygen depletion curve used, calculated sediment oxygen demand rates ranged from as low as -0.03 g/m 2 /d to as high as -10 g/m 2 /d. The wide range of sediment oxygen demand rates indicates that care must be taken when extrapolating sediment oxygen demand rates between stream sites that have different bottom sediment types and different flow regimes.

New Jersey

Use of computer programs STLK1 and STWT1 for analysis of stream-aquifer hydraulic interaction

Quantifying the hydraulic interaction of aquifers and streams is important in the analysis of stream base fow, flood-wave effects, and contaminant transport between surface- and ground-water systems. This report describes the use of two computer programs, STLK1 and STWT1, to analyze the hydraulic interaction of streams with confined, leaky, and water-table aquifers during periods of stream-stage fuctuations and uniform, areal recharge. The computer programs are based on analytical solutions to the ground-water-flow equation in stream-aquifer settings and calculate ground-water levels, seepage rates across the stream-aquifer boundary, and bank storage that result from arbitrarily varying stream stage or recharge. Analysis of idealized, hypothetical stream-aquifer systems is used to show how aquifer type, aquifer boundaries, and aquifer and streambank hydraulic properties affect aquifer response to stresses. Published data from alluvial and stratifed-drift aquifers in Kentucky, Massachusetts, and Iowa are used to demonstrate application of the programs to field settings. Analytical models of these three stream-aquifer systems are developed on the basis of available hydrogeologic information. Stream-stage fluctuations and recharge are applied to the systems as hydraulic stresses. The models are calibrated by matching ground-water levels calculated with computer program STLK1 or STWT1 to measured ground-water levels. The analytical models are used to estimate hydraulic properties of the aquifer, aquitard, and streambank; to evaluate hydrologic conditions in the aquifer; and to estimate seepage rates and bank-storage volumes resulting from flood waves and recharge. Analysis of field examples demonstrates the accuracy and limitations of the analytical solutions and programs when applied to actual ground-water systems and the potential uses of the analytical methods as alternatives to numerical modeling for quantifying stream-aquifer interactions.

Water-Resources Investigations Report

Relations of dissolved-oxygen variability, selected field constituents, and metabolism estimates to land use and nutrients in high-gradient Boston Mountain streams, Arkansas

Continuous monitoring data can be extremely useful for assessing water quality conditions particularly for variables that exhibit dynamic diel swings such as dissolved oxygen. As a means of evaluating dissolved oxygen criteria used by the Arkansas Department of Environmental Quality (ADEQ) for assessing this stream class, we compared continuous dissolved oxygen (DO) data collected at five small- to moderate-sized (watersheds 10-100 mi 2 ), high-gradient streams in the Boston Mountains distributed across a land-use and nutrient condition gradient. The current DO criteria employed by ADEQ for Boston Mountains streams >10 mi2 consists of both an exceedance rate and a magnitude, in which, streams may be considered 'impaired' if greater than 10% of DO measurements during a period of record are < 6 mg/L. The 10% exceedance rate, however, is a commonly used “default” value that requires independent testing for different ecoregion stream classifications. Our findings for the five Boston Mountain streams fit a general pattern established for other aquatic systems (e.g. larger streams, low-gradient streams, and lakes) where increasing land-use intensity generally results in increased nutrient concentrations, which can lead to stream eutrophication and increased DO variability. DO concentrations were < 6 mg/L for fewer than 4% of measurements at the two sites identified “a priori” as least disturbed by nutrient and land-use indices, while concentrations at the three sites identified as moderately and most disturbed were < 6 mg/L for 20 to 33% of measurements. These findings demonstrate that the 10% exceedance rate currently employed by ADEQ was effective at identifying various degrees of DO impairment in Boston Mountain streams. Our analysis also demonstrated that continuous pH and specific conductance data and estimates of stream metabolism were helpful for associating DO variability to anthropogenic or natural origins. Considerations that were useful for examining these relationships and evaluating ADEQ’s DO criteria should be applicable to DO studies in other locations where stream and geologic characteristics are like those of the Boston Mountains.

Arkansas, Oklahoma

In-stream laser diffraction for measuring suspended sediment concentration and particle size distribution in rivers: Insights from field campaigns

This study evaluates the laser in situ scattering and transmissometry (LISST) instrument LISST-SL2, a laser diffraction instrument for suspended sediment sampling in rivers, with concurrent physical measurements of suspended sediment concentration (SSC) and particle size distribution (PSD) as well as velocity measurements by an acoustic Doppler current profiler (ADCP). We collected 136 LISST-SL2 samples along with 61 physical samples for SSC measurement, of which 24 physical samples included PSD measurement during 2018–2020 from 11 sites in Washington state and Virginia. An effective density is required to convert the measured volumetric SSC by the LISST-SL2 into a reported mass SSC, and by default the LISST-SL2 assumes a value of 2.65 g / mL . From our data set, we computed effective densities (mass SSC/volumetric SSC) that ranged from 0.5 to 5.4 g / mL , with a best-fit value of 2.05 g / mL . Additionally, the LISST-SL2 was not able to measure the finest sediment sizes in suspension, which affects the resulting PSD. Therefore, we propose some adjustments of the LISST-SL2 data with a supporting physical sample to account for these effective density and PSD issues. When doing so, we were able to reduce the root-mean square relative error (RMSRE) to 18% from 117% for SSC, and to 26% from 78% for PSD. LISST-SL2 velocities were generally higher than ADCP velocities with a 21% RMSRE. Our results and guidance will allow for more accurate sampling by the LISST-SL2, which has potential for studying spatial and temporal variation of suspended sediment characteristics in rivers.

Virginia, Washington

Elevated winter stream temperatures below wastewater treatment plants shift reproductive development of female Johnny Darter Etheostoma nigrum: A field and histologic approach

River water temperatures are increasing globally, particularly in urban systems. In winter, wastewater treatment plant (WWTP) effluent inputs are of particular concern because they increase water temperatures from near freezing to ~7–15 °C. Recent laboratory studies suggest that warm overwinter temperatures impact the reproductive timing of some fishes. To evaluate winter water temperature’s influence in the wild, we sampled Johnny Darter Etheostoma nigrum from three urban South Platte River tributaries in Colorado upstream and downstream of WWTP effluent discharge sites. Fish were collected weekly during the spring spawning season of 2021 and reproductive development was determined from histological analysis of the gonads. Winter water temperatures were approximately 5–10 °C greater ~300 m downstream of the WWTP effluent compared to upstream sites, and approximately 3 °C warmer at sampling sites ~5000 m downstream of the effluent discharge. Females collected downstream of WWTP effluent experienced accelerated reproductive development compared to upstream by 1–2 weeks. Water quality, including total estrogenicity, and spring water temperatures did not appear to explain varying reproductive development. It appears that small increases in winter water temperature influence the reproductive timing in E. nigrum . Further investigations into how shifts in reproductive timing influence other population dynamics are warranted.

Colorado

Use of the MODFLOW 6 water mover package to represent natural and managed hydrologic connections

The latest release of MODFLOW 6, the current core version of the MODFLOW groundwater modeling software, debuted a new package dubbed the “mover” (MVR). Using a generalized approach, MVR facilitates the transfer of water among any arbitrary combination of simulated features (i.e., pumping wells, stream, drains, lakes, etc.) within a MODFLOW 6 simulation. Four “rules” controlling the amount of water transferred from a providing feature to a receiving feature are currently available. In this way, MVR can represent natural connections between features, for example streams entering or exiting lakes, and perhaps more interestingly, it also can transfer water among simulated features to more accurately simulate water management. An example model representative of an agricultural setting demonstrates some of the available MVR connections. For example, an irrigation event that transfers surface water from an irrigation delivery ditch to multiple cropped areas demonstrates a “one-to-many” connection that is possible within MVR. Conversely, irrigation or precipitation runoff from multiple fields may be routed to a particular stream segment using “many-to-one” MVR connections. MVR supports many additional connection types, several of which are demonstrated by the included example problem.

Groundwater

An analytical framework for estimating aquatic species density from environmental DNA

Environmental DNA (eDNA) analysis of water samples is on the brink of becoming a standard monitoring method for aquatic species. This method has improved detection rates over conventional survey methods and thus has demonstrated effectiveness for estimation of site occupancy and species distribution. The frontier of eDNA applications, however, is to infer species density. Building upon previous studies, we present and assess a modeling approach that aims at inferring animal density from eDNA. The modeling combines eDNA and animal count data from a subset of sites to estimate species density (and associated uncertainties) at other sites where only eDNA data are available. As a proof of concept, we first perform a cross-validation study using experimental data on carp in mesocosms. In these data, fish densities are known without error, which allows us to test the performance of the method with known data. We then evaluate the model using field data from a study on a stream salamander species to assess the potential of this method to work in natural settings, where density can never be known with absolute certainty. Two alternative distributions (Normal and Negative Binomial) to model variability in eDNA concentration data are assessed. Assessment based on the proof of concept data (carp) revealed that the Negative Binomial model provided much more accurate estimates than the model based on a Normal distribution, likely because eDNA data tend to be overdispersed. Greater imprecision was found when we applied the method to the field data, but the Negative Binomial model still provided useful density estimates. We call for further model development in this direction, as well as further research targeted at sampling design optimization. It will be important to assess these approaches on a broad range of study systems.

Ecology and Evolution

Comparison of underwater video with electrofishing and dive‐counts for stream fish abundance estimation

Advances in video technology enable new strategies for stream fish research. We compared juvenile (age‐0) and adult (age 1+) Brook Trout Salvelinus fontinalis abundance estimates from underwater video with backpack electrofishing and dive‐count methods across a series of stream pools in Shenandoah National Park, Virginia ( n = 41). Video methods estimated greater mean abundance of adult trout than 1‐pass electrofishing but were not different than 3‐pass electrofishing or dive‐count methods in this regard. In contrast, videos underestimated abundance of juvenile trout, and we suggest this is because predator avoidance‐behaviors by juvenile trout limit their use of microhabitat locations visible to cameras. Integrated abundance estimates from 2 cameras increased correspondence to comparison methods relative to single cameras, demonstrating the importance of an expanded field of view for video sampling in streams. Geomorphic features helped explain method‐wise differences: more adult trout were estimated with video than 3‐pass electrofishing as riffle crest depth and boulder composition increased, indicating habitat associations with trout escapement from electrofishing. Our results demonstrated that video techniques can provide a robust alternative or supplement to traditional methods for estimating adult trout abundance in stream pools.

Virgiinia

Hydrogeology and ground-water flow in the carbonate rocks of the Little Lehigh Creek basin, Lehigh County, Pennsylvania

The Little Lehigh Creek basin is underlain mainly by a complex assemblage of highly-deformed Cambrian and Ordovician carbonate rocks. The Leithsville Formation, Allentown Dolomite, Beekmantown Group, and Jacksonburg Limestone act as a single hydrologic unit. Ground water moves through fractures and other secondary openings and generally is under water-table conditions. Median annual ground-water discharge (base flow) to Little Lehigh Creek near Allentown (station 01451500) during 1946-86 was 12.97 inches or 82 percent of streamflow. Average annual recharge for 1975-83 was 21.75 inches. Groundwater and surface-water divides do not coincide in the basin. Ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin in 1987 was 4 inches per year. A double-mass curve analysis of the relation of cumulative precipitation at Allentown to the flow of Schantz Spring for 1956-84 showed that cessation of quarry pumping and development of ground water for public supply in the Schantz Spring basin did not affect the flow of Schantz Spring. Ground-water flow in the Little Lehigh Creek basin was simulated using a finite-difference, two-dimensional computer model. The geologic units in the modeled area were simulated as a single water-table aquifer. The 134-squaremile area of carbonate rocks between the Lehigh River and Sacony Creek was modeled to include the natural hydrologic boundaries of the ground-water-flow system. The ground-water-flow model was calibrated under steady-state conditions using 1975-83 average recharge, evapotranspiration, and pumping rates. Each geologic unit was assigned a different hydraulic conductivity. Initial aquifer hydraulic conductivity was estimated from specific-capacity data. The average (1975-83) water budget for the Little Lehigh Creek basin was simulated. The simulated base flow from the carbonate rocks of the Little Lehigh Creek basin above gaging station 01451500 is 11.85 inches per year. The simulated ground-water underflow from the Little Lehigh Creek basin to the Cedar Creek basin is 4.04 inches per year. For steady-state calibration, the root-mean-squared difference between observed and simulated heads was 21.19 feet. The effects of increased ground-water development on base flow and underflow out of the Little Lehigh Creek basin for average and drought conditions were simulated by locating a hypothetical well field in different parts of the basin. Steady-state simulations were used to represent equilibrium conditions, which would be the maximum expected long-term effect. Increased ground-water development was simulated as hypothetical well fields pumping at the rate of 15, 25, and 45 million gallons per day in addition to existing ground-water withdrawals. Four hypothetical well fields were located near and away from Little Lehigh Creek in upstream and downstream areas. The effects of pumping a well field in different parts of the Little Lehigh Creek basin were compared. Pumping a well field located near the headwaters of Little Lehigh Creek and away from the stream would have greatest effect on inducing underflow from the Sacony Greek basin and the least effect on reducing base flow and underflow to the Ceda^r Creek basin. Pumping a well field located near the headwaters of Little Leh|igh Creek near the stream would have less impact on inducing underflow from|the Sacony Creek basin and a greater impact on reducing the base flow of Little Lehigh Creek because more of the pumpage would come from diverted base flow. Pumping a well field located in the downstream area of the Little Lehigh Creek basin away from the stream would have the greatest effect on the underflow to the Cedar Creek basin. Pumping a well field located in the downstream area of the Little Lehigh Creek basin near the stream would have the greatest effect on reducing the base flow of Little Lehigh Cteek. Model simulations show that groundwater withdrawals do not cause a proportional reduction in base flow. Under average conditions, ground-water withdrawals are equal to 48 to 70 percent of simulated base-flow reductions; under drought conditions, ground-water withdrawals are equal to 35 to 73 percent of simulated base-flow reductions. The hydraulic effects of pumping largely depend on well location. In the Little Lehigh basin, surface-water and ground-water divides do not coincide, and ground-water development, especially near surface-water divides, can cause ground-water divides to shift and induce ground-water underflow from adjacent basins. Large-scale ground-water pumping in a basin may not produce expected reductions of base flow in that basin because of shifts in the ground-water divide; however, such shifts can reduce base flow in adjacent surface-water basins.

Water-Resources Investigations Report

Chapter B. Physical, Chemical, and Biological Responses of Streams to Increasing Watershed Urbanization in the Piedmont Ecoregion of Georgia and Alabama, 2003

As part of the U.S. Geological Survey National Water-Quality Assessment Program?s effort to assess the physical, chemical, and biological responses of streams to urbanization, 30 wadable streams were sampled near Atlanta, Ga., during 2002?2003. Watersheds were selected to minimize natural factors such as geology, altitude, and climate while representing a range of urban development. A multimetric urban intensity index was calculated using watershed land use, land cover, infrastructure, and socioeconomic variables that are highly correlated with population density. The index was used to select sites along a gradient from low to high urban intensity. Response variables measured include stream hydrology and water temperature, instream habitat, field properties (pH, conductivity, dissolved oxygen, turbidity), nutrients, pesticides, suspended sediment, sulfate, chloride, Escherichia coli (E. coli) concentrations, and characterization of algal, invertebrate and fish communities. In addition, semipermeablemembrane devices (SPMDs)?passive samplers that concentrate hydrophobic organic contaminants such as polycyclicaromatic hydrocarbons (PAHs)?were used to evaluate water-quality conditions during the 4 weeks prior to biological sampling. Changes in physical, chemical, and biological conditions were evaluated using both nonparametric correlation analysis and nonmetric multidimensional scaling (MDS) ordinations and associated comparisons of dataset similarity matrices. Many of the commonly reported effects of watershed urbanization on streams were observed in this study, such as altered hydrology and increases in some chemical constituent levels. Analysis of water-chemistry data showed that specific conductance, chloride, sulfate, and pesticides increased as urbanization increased. Nutrient concentrations were not directly correlated to increases in development, but were inversely correlated to percent forest in the watershed. Analyses of SPMD-derived data showed that bioassays and certain chemical constituents such as pyrene and benzophenanthrene, both PAHs found in coal tar, were strongly correlated with measures of watershed urbanization. Hydrologic variability metrics indicated that as urban development increased, streams became flashier, with characteristic high flows having shorter duration. The hydrologic effects associated with urbanization were greatest during the fall and least apparent during the winter. No correlations were observed between increasing urbanization and stream temperature or changes in stream habitat. Algal, invertebrate, and fish communities exhibited statistically significant changes as watersheds became increasingly urban, with the strongest responses observed in the invertebrate community followed by fishes, then algal diatom communities. Invertebrate communities were the most responsive to increasing urbanization with Ephemeroptera, Plecoptera, and Tricoptera taxa, especially Plecoptera (stoneflies) responding negatively and most strongly to increasing urbanization. Invertebrate communities were influenced more significantly by water quality, although significant responses to altered hydrology also were noted. In terms of the fish community, the percentage of cyprinids present in the stream was the only Index of Biotic Integrity metric that responded negatively to increases in watershed urbanization. Fish community response to urbanization was intermediate relative to algae and invertebrates with respect to significant metric responses as well as the overall community response to increasing urbanization. Measures of hydrologic variability were the most influential environmental variables affecting the algal community. Although sites were originally chosen to represent a gradient of increasing urbanization, a cluster analysis performed on the component metrics of the urban index categorized sites into four distinct groups. Multivariate analysis based on nonmetric MDS and related analyses of data ma

Alabama, Georgia

Aqueous geochemical data from the analysis of stream-water samples collected in June and July 2006 — Taylor Mountains 1:250,000-scale quadrangle, Alaska

We report on the chemical analysis of water samples collected from the Taylor Mountains 1:250,000-scale quadrangle, Alaska. Parameters for which data are reported include pH, conductivity, water temperature, major cation and anion concentrations, trace-element concentrations, and dissolved organic-carbon concentrations. Samples were collected as part of a multiyear U.S. Geological Survey project entitled ?Geologic and Mineral Deposit Data for Alaskan Economic Development.? Data presented here are from samples collected in June and July 2006. The data are being released at this time with minimal interpretation. This is the third release of aqueous geochemical data from this project; aqueous geochemical data from samples collected in 2004 and 2005 were published previously. The data in this report augment but do not duplicate or supersede the previous data release. Site selection was based on a regional sampling strategy that focused on first- and second-order drainages. Water sample site selection was based on landscape parameters that included physiography, wetland extent, lithological changes, and a cursory field review of mineralogy from pan concentrates. Stream water in the Taylor Mountains quadrangle is dominated by bicarbonate (HCO3-), although in a few samples more than 50 percent of the anionic charge can be attributed to sulfate (SO42-). The major-cation chemistry ranges from Ca2+/Mg2+ dominated to a mix of Ca2+/Mg2+/Na++K+. Generally, good agreement was found between the major cations and anions in the duplicate samples. Many trace elements in these samples were at or near the analytical method detection limit, but good agreement was found between duplicate samples for elements with detectable concentrations. All field blank major-ion and trace-element concentrations were below detection.

Alaska

Aqueous geochemical data from the analysis of stream-water samples collected in June and July 2005 — Taylor Mountains 1:250,000 scale quadrangle, Alaska

We report on the chemical analysis of water samples collected from the Taylor Mountains 1:250,000-scale quadrangle. Parameters for which data are reported include pH, conductivity, water temperature, major cation and anion concentrations, trace-element concentrations, and dissolved organic-carbon concentrations. Samples were collected as part of a multiyear U.S. Geological Survey project "Geologic and Mineral Deposit Data for Alaskan Economic Development." Data presented here are from samples collected in June and July of 2005. The data are being released at this time with minimal interpretation. This is the second release of aqueous geochemical data from this project; 2004 aqueous geochemical data were published previously ( Wang and others, 2006 ). The data in this report augment but do not duplicate or supersede the previous data release. Site selection was based on a regional sampling strategy that focused on first- and second-order drainages. Water sample site selection was based on landscape parameters that included physiography, wetland extent, lithological changes, and a cursory field review of mineralogy from pan concentrates. Stream water in the Taylor Mountians quadrangle is dominated by bicarbonate (HCO 3- ), though in a few samples more than 50 percent of the anionic charge can be attributed to sulfate (SO 4 2- ). The major-cation chemistry ranges from Ca 2+ /Mg 2+ dominated to a mix of Ca 2+ /Mg 2+ /Na + +K + . In general, good agreement was found between the major cations and anions in the duplicate samples. Many trace elements in these samples were at or near the analytical method detection limit, but good agreement was found between duplicate samples for elements with detectable concentrations. With the exception of a total mercury concentration of 0.33 ng/L detected in a field blank, field blank major-ion and trace-elements concentrations were below detection.

Alaska

Influence of in-stream diel concentration cycles of dissolved trace metals on acute toxicity to one-year-old cutthroat trout (Oncorhynchus clarki lewisi)

Extrapolating results of laboratory bioassays to streams is difficult, because conditions such as temperature and dissolved metal concentrations can change substantially on diel time scales. Field bioassays conducted for 96 h in two mining‐affected streams compared the survival of hatchery‐raised, metal‐näive westslope cutthroat trout ( Oncorhynchus clarki lewisi ) exposed to dissolved (0.1‐μm filtration) metal concentrations that either exhibited the diel variation observed in streams or were controlled at a constant value. Cadmium and Zn concentrations in these streams increased each night by as much as 61 and 125%, respectively, and decreased a corresponding amount the next day, whereas Cu did not display a diel concentration cycle. In High Ore Creek (40 km south of Helena, MT, USA), survival (33%) after exposure to natural diel‐fluctuating Zn concentrations (range, 214–634 μg/L; mean, 428 μg/L) was significantly ( p = 0.008) higher than survival (14%) after exposure to a controlled, constant Zn concentration (422 μg/L). Similarly, in Dry Fork Belt Creek (70 km southeast of Great Falls, MT, USA), survival (75%) after exposure to diel‐fluctuating Zn concentrations (range, 266–522 μg/L; mean, 399 μg/L) was significantly ( p = 0.022) higher than survival (50%) in the constant‐concentration treatment (392 μg/L). Survival likely was greater in these diel treatments, both because the periods of lower metal concentrations provided some relief for the fish and because toxicity during periods of higher metal concentrations was lessened by the simultaneous occurrence each night of lower water temperatures, which reduce the rate of metal uptake. Based on the present study, current water‐quality criteria appear to be protective for streams with diel concentration cycles of Zn (and, perhaps, Cd) for the hydrologic conditions tested.

Environmental Toxicology and Chemistry