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USGS2011

Accuracy of flowmeters measuring horizontal groundwater flow in an unconsolidated aquifer simulator.

Borehole flowmeters that measure horizontal flow velocity and direction of groundwater flow are being increasingly applied to a wide variety of environmental problems. This study was carried out to evaluate the measurement accuracy of several types of flowmeters in an unconsolidated aquifer simulator. Flowmeter response to hydraulic gradient, aquifer properties, and well-screen construction was measured during 2003 and 2005 at the U.S. Geological Survey Hydrologic Instrumentation Facility in Bay St. Louis, Mississippi. The flowmeters tested included a commercially available heat-pulse flowmeter, an acoustic Doppler flowmeter, a scanning colloidal borescope flowmeter, and a fluid-conductivity logging system. Results of the study indicated that at least one flowmeter was capable of measuring borehole flow velocity and direction in most simulated conditions. The mean error in direction measurements ranged from 15.1 degrees to 23.5 degrees and the directional accuracy of all tested flowmeters improved with increasing hydraulic gradient. The range of Darcy velocities examined in this study ranged 4.3 to 155 ft/d. For many plots comparing the simulated and measured Darcy velocity, the squared correlation coefficient (r 2 ) exceeded 0.92. The accuracy of velocity measurements varied with well construction and velocity magnitude. The use of horizontal flowmeters in environmental studies appears promising but applications may require more than one type of flowmeter to span the range of conditions encountered in the field. Interpreting flowmeter data from field settings may be complicated by geologic heterogeneity, preferential flow, vertical flow, constricted screen openings, and nonoptimal screen orientation.

Ground Water Monitoring and Remediation↗

USGS1978

Uranium-isotope variations in groundwaters of the Floridan aquifer and Boulder Zone of south Florida

Water samples from four wells from the main Floridan aquifer (300-400 m below mean sea level) in southeast Florida exhibit 234 U 233 U activity ratios that are significantly lower than the secular equilibrium value of 1.00. Such anomalous values have been observed previously only in waters from sedimentary aquifers in the near-surface oxidizing environments. These four wells differ from six others, all producing from the same general horizon, in being located in cavernous highly transmissive zones. We hypothesize that the low activity ratios are indicative of a relic circulation pattern whereby water from the surface aquifer was channelled to lower levels when sea level was much lower. At a deeper cavernous level, known as the Boulder Zone (800-1,000 m below mean sea level), the U isotopes, along with other chemical constituents, show progressive changes with increasing distance from an inferred flow source in the Straits of Florida. This tends to support the hypothesized landward flow (though with a more northerly component) of cold seawater in the extensively transmissive Boulder Zone.

Florida↗

USGS2024

Predicting redox conditions in groundwater at a national scale using random forest classification

Redox conditions in groundwater may markedly affect the fate and transport of nutrients, volatile organic compounds, and trace metals, with significant implications for human health. While many local assessments of redox conditions have been made, the spatial variability of redox reaction rates makes the determination of redox conditions at regional or national scales problematic. In this study, redox conditions in groundwater were predicted for the contiguous United States using random forest classification by relating measured water quality data from over 30,000 wells to natural and anthropogenic factors. The model correctly predicted the oxic/suboxic classification for 78 and 79% of the samples in the out-of-bag and hold-out data sets, respectively. Variables describing geology, hydrology, soil properties, and hydrologic position were among the most important factors affecting the likelihood of oxic conditions in groundwater. Important model variables tended to relate to aquifer recharge, groundwater travel time, or prevalence of electron donors, which are key drivers of redox conditions in groundwater. Partial dependence plots suggested that the likelihood of oxic conditions in groundwater decreased sharply as streams were approached and gradually as the depth below the water table increased. The probability of oxic groundwater increased as base flow index values increased, likely due to the prevalence of well-drained soils and geologic materials in high base flow index areas. The likelihood of oxic conditions increased as topographic wetness index (TWI) values decreased. High topographic wetness index values occur in areas with a propensity for standing water and overland flow, conditions that limit the delivery of dissolved oxygen to groundwater by recharge; higher TWI values also tend to occur in discharge areas, which may contain groundwater with long travel times. A second model was developed to predict the probability of elevated manganese (Mn) concentrations in groundwater (i.e., ≥50 μg/L). The Mn model relied on many of the same variables as the oxic/suboxic model and may be used to identify areas where Mn-reducing conditions occur and where there is an increased risk to domestic water supplies due to high Mn concentrations. Model predictions of redox conditions in groundwater produced in this study may help identify regions of the country with elevated groundwater vulnerability and stream vulnerability to groundwater-derived contaminants.

contiguous United States↗

USGS2026

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas↗

USGS2006

Research approach to teaching groundwater biodegradation in karst aquifers

TSU in partnership with the USGS has conducted extensive research regarding biode??gradation of contaminants in karst aquifers. This research resulted in the development of a numerical approach to modeling biodegradation of contaminants in karst aquifers that is taught to environmental engineering students in several steps. First, environmental engineering students are taught chemical-reaction engineering principles relating to a wide variety of environmental fate and transport issues. Second, as part of TSU's engineering course curriculum, students use a non-ideal flow laboratory reactor system and run a tracer study to establish residence time distribution (RTD). Next, the students couple that formula to a first-order biodegradation rate and predict the removal of a biodegradable contaminant as a function of residence time. Following this, students are shown data collected from karst bedrock wells that suggest that karst aquifers are analogous to non-ideal flow reactors. The students are challenged to develop rates of biodegradation through lab studies and use their results to predict biodegradaton at an actual contaminated karst site. Field studies are also conducted to determine the accuracy of the students' predictions. This academic approach teaches biodegradation processes, rate-kinetic processes, hydraulic processes and numerical principles. The students are able to experience how chemical engineering principles can be applied to other situations, such as, modeling biodegradation of contaminants in karst aquifers. This paper provides background on the chemical engineering principles and karst issues used in the research-enhanced curriculum. ?? American Society for Engineering Education, 2006.

Conference Paper↗

USGS1994

Geochemical interactions between constituents in acidic groundwater and alluvium in an aquifer near Globe, Arizona

Acidic water from a copper-mining area has contaminated an alluvial aquifer and stream near Globe, Arizona. The most contaminated groundwater has a pH of 3.3, and contains about 100 mmol/1 SO 4 , 50 mmol/1 Fe, 11 mmol/1 Al and 3 mmol/1 Cu. Reactions between alluvium and acidic groundwater were first evaluated in laboratory column experiments. A geochemical model was developed and used in the equilibrium speciation program, MINTEQA2, to simulate breakthrough curves for different constituents from the column. The geochemical model was then used to simulate the measured changes in concentration of aqueous constituents along a flow path in the aquifer. The pH was predominantly controlled by reaction with carbonate minerals. Where carbonates had been dissolved, adsorption of H + by iron oxides was used to simulate pH. Acidic groundwater contained little or no dissolved oxygen, and most aqueous Fe was present as Fe(II). In the anoxic core of the plume, Fe(II) was oxidized by MnO 2 to Fe(III), which then precipitated as Fe(OH) 3 . Attenuation of aqueous Cu, Co, Mn, Ni and Zn was a function of pH and could be quantitatively modeled with the diffuse-layer, surface complexation model in MINTEQA2. Aluminum precipitated as amorphous Al(OH) 3 at pH < 4.7 and as AlOHSO 4 at pH < 4.7. Aqueous Ca and SO 4 were close to equilibrium with gypsum. After the alluvium in the column had reached equilibrium with acidic groundwater, uncontaminated groundwater was eluted through the column to evaluate the effect of reactants on groundwater remediation. The concentration of Fe, Mn, Cu, Co, Ni and Zn rapidly decreased to the detection limits within a few pore volumes. All of the gypsum that had precipitated initially redissolved, resulting in elevated Ca and SO 4 concentrations for about 5 pore volumes. Aluminum and pH exhibited the most potential for continued adverse effects on groundwater quality. As H + desorbed from Fe(OH) 3 , pH remained below 4.5 for more than 20 pore volumes, resulting in dissolution of AlOHSO 4 and elevated aqueous Al.

Applied Geochemistry↗

USGS2019

Groundwater quality of a public supply aquifer in proximity to oil development, Fruitvale Oil Field, Bakersfield, California

Due to concerns over the effects of oil production activities on groundwater quality in California, chemical, isotopic, dissolved gas and age-dating tracers were analyzed in samples collected from public-supply wells and produced-water sites in the Fruitvale oil field (FVOF). A combination of newly collected and historical data was used to determine whether oil formation fluids have mixed with groundwater used for public supply and what the potential pathways for the migration of oil formation fluids into groundwater may be. Stable isotopes of water (δ 2 H and δ 18 O) and age dating ( 3 H, 3 He trit , SF 6 and 14 C) tracers in groundwater samples were consistent with the Kern River being the main source of recharge to aquifers. The distribution of major ion concentrations and pH with distance from the Kern River indicate that natural processes were the primary controls on groundwater salinity. Two of 14 groundwater samples had δ 13 C-DIC values (−2.4 to +1.9 per mil) consistent with mixtures of <1 to about 9 percent oil-field water. Concentrations of TDS in groundwater samples were generally much lower (129–1,200 milligrams per liter (mg/l), median 216 mg/l) than produced water samples (586–24,930 mg/l, median 2,717 mg/l), suggesting that any mixing of oil-field water with groundwater has not significantly affected groundwater salinity. Trace concentrations of thermogenic methane were detected in three groundwater samples that did not have dissolved inorganic or isotopic indicators consistent with mixing of oil-field water, suggesting that stray gases may have migrated from the subsurface via preferential pathways such as leaky well bores into groundwater aquifers. Low concentrations of petroleum hydrocarbons were detected in samples that also contained anthropogenic VOCs and components of post- and pre-1950s recharge, indicating that petroleum hydrocarbons could have come from subsurface and/or surface sources. Overall, the results of this study indicated that groundwater currently used for public supply in the FVOF was of good quality with little, if any, effects from oil production activities. This may be due in part to the relatively rapid flushing of the aquifer system by recharge from the Kern River.

California↗

USGS2022

Over a third of groundwater in USA public-supply aquifers is Anthropocene-age and susceptible to surface contamination

The distribution of groundwater age is useful for evaluating the susceptibility and sustainability of groundwater resources. Here, we compute the aquifer-scale cumulative distribution function to characterize the age distribution for 21 Principal Aquifers that account for ~80% of public-supply pumping in the United States. The aquifer-scale cumulative distribution function for each Principal Aquifer was derived from an ensemble of modeled age distributions (~60 samples per aquifer) based on multiple tracers: tritium, tritiogenic helium-3, sulfur hexafluoride, chlorofluorocarbons, carbon-14, and radiogenic helium-4. Nationally, the groundwater is 38% Anthropocene (since 1953), 34% Holocene (75 – 11,800 years ago), and 28% Pleistocene (>11,800 years ago). The Anthropocene fraction ranges from <5 to 100%, indicating a wide range in susceptibility to land-surface contamination. The Pleistocene fraction of groundwater exceeds 50% in 7 eastern aquifers that are predominately confined. The Holocene fraction of groundwater exceeds 50% in 5 western aquifers that are predominately unconfined. The sustainability of pumping from these Principal Aquifers depends on rates of recharge and release of groundwater stored in fine-grained layers.

Nature Communications Earth & Environment↗

USGS2021

Critical aquifer overdraft accelerates degradation of groundwater quality in California’s Central Valley during drought

Drought-induced pumpage has precipitated dramatic groundwater-level declines in California’s Central Valley over the past 30 years, but the impacts of aquifer overdraft on water quality are poorly understood. This study coupled over 160,000 measurements of nitrate from ∼6,000 public-supply wells with a 30-year reconstruction of groundwater levels throughout the Central Valley to evaluate dynamic relations between aquifer exploitation and resource quality. We find that long-term rates of groundwater-level decline and water-quality degradation in critically overdrafted basins accelerate by respective factors of 2–3 and 3–5 during drought, followed by brief reversals during wetter periods. Episodic water-quality degradation can occur during drought where increased pumpage draws shallow, contaminated groundwater down to depth zones tapped by long-screened production wells. These data show, for the first time, a direct linkage between climate-mediated aquifer pumpage and groundwater quality on a regional scale.

California↗

USGS1993

Estimating net drawdown resulting from episodic withdrawals at six well fields in the coastal plain physiographic province of Virginia

The groundwater-flow system of the Virginia Coastal Plain consists of areally extensive and interconnected aquifers. Large, regionally coalescing cones of depression that are caused by large withdrawals of water are found in these aquifers. Local groundwater systems are affected by regional pumping, because of the interactions within the system of aquifers. Accordingly, these local systems are affected by regional groundwater flow and by spatial and temporal differences in withdrawals by various users. A geographic- information system was used to refine a regional groundwater-flow model around selected withdrawal centers. A method was developed in which drawdown maps that were simulated by the regional groundwater-flow model and the principle of superposition could be used to estimate drawdown at local sites. The method was applied to create drawdown maps in the Brightseat/Upper Potomac Aquifer for periods of 3, 6, 9, and 12 months for Chesapeake, Newport News, Norfolk, Portsmouth, Suffolk, and Virginia Beach, Virginia. Withdrawal rates were supplied by the individual localities and remained constant for each simulation period. This provides an efficient method by which the individual local groundwater users can determine the amount of drawdown produced by their wells in a groundwater system that is a water source for multiple users and that is affected by regional-flow systems.

Water-Resources Investigations Report↗

USGS2023

Per- and polyfluoroalkyl substances in groundwater from the Great Miami buried-valley aquifer, southwestern Ohio, 2019–20

Groundwater samples were collected during 2019 and 2020 from 23 wells in the Great Miami buried-valley aquifer (GM-BVA) in southwestern Ohio by the U.S. Geological Survey, in cooperation with the Miami Conservancy District, Dayton, Ohio, to determine concentrations of selected per- and polyfluoroalkyl substances (PFAS). The GM-BVA is a glacial outwash and alluvial fill aquifer that is the sole source of water supply for much of the region. Wells had total depths that ranged from 21 to 101 feet below land surface, and groundwater levels that ranged from 1.39 to 52.15 feet below land surface before sampling in 2019. Groundwater and related quality-control samples were sequentially collected from 22 of the 23 wells and analyzed for 24 different PFAS by 2 methods that used proprietary isotope-dilution based adaptations of U.S. Environmental Protection Agency (EPA) method 537.1, termed methods 1 and 2. Method 2 had smaller reporting limits (RL) for 22 of 24 PFAS analyzed and smaller detection limits (DLs) for all 24 PFAS analyzed compared with method 1, which made method 2 more sensitive to detect PFAS. Concentrations of perfluorooctanesulfonate (PFOS) in a groundwater (GW)-method 2 sample from well CL–275 of 1.9 nanograms per liter (ng/L) and perfluorooctanoate (PFOA) in a GW-method 2 sample from well BU–1106 of 2.1 ng/L were greater than their EPA interim health advisory guidances for drinking water (as of June 2022) by about 9,500 and 52,500 percent, respectively. The EPA interim health advisory guidances for PFOS (0.02 ng/L) and PFOA (0.004 ng/L) were also 65 and 215 times less, respectively, than the smallest method 2 DLs for PFOS (1.3 ng/L) and PFOA (0.86 ng/L). Other PFAS were either not detected in GM-BVA groundwater samples or were detected in concentrations less than Ohio action levels or Federal health-risk-based guidance. The most detected PFAS in groundwater was perfluorobutanesulfonate (PFBS), which had concentrations in samples from eight wells that ranged from 1.0 to 8.0 ng/L or from 0.05 to 0.4 percent of its EPA health advisory of 2,000 ng/L for drinking water. The similarity of PFBS (7.8 ng/L), perfluoropentanesulfonate (PFPeS; 8.1 ng/L), and perfluorohexanesulfonate (PFHxS; 14 ng/L) concentrations yielded from the GW-method 1 sample from well CL–275 on July 9, 2019, to those of PFBS (8.0 ng/L), PFPeS (7.8 ng/L), and PFHxS (16 ng/L) from the paired GW-method 2 sample demonstrated the capability of both methods to reproduce PFAS concentrations that were greater than their respective DLs. Non-detection of these PFAS in follow-up GW-method 1 and sequential replicate (Rep–GW-method 1) samples from CL–275 on April 21, 2020, indicated that the 2019 results represented a transient detection in groundwater. Eleven of twenty-three wells sampled in 2019 had from 1 to 4 PFAS detected in one or more groundwater samples or in a paired replicate sample: PFBS in 8 wells and 9 samples; PFHxS in 4 wells and 5 samples; and PFPeS, PFOS, perfluorobutanoate, perfluoropentanoate, PFOA, and perfluorooctanesulfonamide in 1 well and 1 sample each. More PFAS were detected in GW-method 2 samples than GW-method 1 samples because method 2 had smaller RLs and DLs. Results indicate benefits from the analysis of paired samples, sequential replicate samples, and other quality-control samples using analytical methods with sensitive RLs and DLs to verify PFAS concentrations in groundwater. Groundwater-age estimates indicate that water produced from all sampled wells had infiltrated to the water table within the 1947–present (2022) period of PFAS use or environmental presence. Eight wells with detectable PFBS in groundwater from 2019 samples also had groundwater-recharge dates that ranged from 1991 to 2016. Those ages coincided with the possible environmental presence of PFBS as a PFAS byproduct or use as an alternative to PFOS after about 2002. Two wells that had detections of PFHxS in 2019 groundwater samples also had post-2000 groundwater-recharge dates that coincided with the period of use of PFHxS as an alternative to PFOS. Six of nine wells with more than 66-percent of urban land use that was within 0.3 miles of each well, as of 2012, also had 1 to 4 PFAS detected in one of their groundwater samples. Seven of nine wells that produced groundwater in 2019 with an oxic redox category also had one or more PFAS detected in a sample.

Ohio↗

USGS2018

Relations between total phosphorus and orthophosphorus concentrations and rainfall, surface-water discharge, and groundwater levels in Big Cypress Seminole Indian Reservation, Florida, 2014–16

The Seminole Tribe of Florida (the Tribe) is partnering with the U.S. Environmental Protection Agency to develop a numeric phosphorus criterion for the 52,000-acre Big Cypress Seminole Indian Reservation (BCSIR), which is located downgradient of the Everglades Agricultural Area, and of other public and private lands, in southeastern Hendry County and northwestern Broward County in southern Florida. The U.S. Geological Survey (USGS), in cooperation with the Tribe, used water-quality data collected between October 2014 and September 2016 by the Tribe and the South Florida Water Management District (SFWMD), along with data from rainfall gages, surface-water stage and discharge gages, and groundwater monitoring wells, to (1) examine the relations between local hydrology and measured total phosphorus (TP) and orthophosphorus (OP) concentrations and (2) identify explanatory variables for TP concentrations. Of particular concern were conditions when TP exceeded 10 parts per billion (ppb) (0.01 milligram per liter [mg/L]) given that the State of Florida and the Miccosukee Tribe of Indians Alligator Alley Reservation (located downstream of the BCSIR) have adopted a 10-ppb maximum TP criterion for surface waters. From October 2014 to September 2016, the Tribe collected 47–52 samples at each of nine water-quality sites for analysis of TP and OP, except at one site where 28 samples were collected. For all sites sampled, concentrations of TP (as phosphorus [P]) ranged from less than 0.002 mg/L (2 ppb) to a maximum of nearly 0.50 mg/L (500 ppb), whereas concentrations of OP (as P), the reactive form of inorganic phosphorus readily absorbed by plants and (or) abiotically absorbed, ranged from less than 0.003 mg/L (3 ppb) to a maximum of 0.24 mg/L (240 ppb). The median and interquartile ranges of concentrations of TP and OP in the samples collected in 2014–16 by the Tribe were similar to the median and interquartile ranges of concentrations in samples collected by the SFWMD at nearby sites during the same period. Differences in concentrations can likely be explained by differences in sample collection methods, sampling locations, sample collection time, and the hydrology during sampling or by the number of samples collected. A major limitation of this study was the short duration of sample collection, which covers a limited range of hydrologic conditions within the BCSIR. The effect of surface-water and groundwater hydrologic conditions on TP and OP concentrations was assessed by using rainfall data and surface-water stage and discharge records. The highest TP and OP concentrations occurred during peak surface-water flows in the canals following long dry periods. Concentrations of TP and OP increased internal to the BCSIR in the western half of the BCSIR during wet periods, but increased concentrations tended to lag behind rainfall events, likely because control structures upstream of sampling sites do not release flows until the water levels in the canals reach predetermined levels. This pattern may indicate that bed sediments in the canals contain high concentrations of phosphorus that becomes resuspended during high flows or that phosphorus salts that had accumulated on dry land during dry periods are carried into the canals by runoff. The largest TP spikes usually occurred at the beginning of high-flow events, but then quickly tapered off even when flows remained high. Groundwater flows were assessed in the BCSIR by using groundwater level observations from two preexisting USGS monitoring well clusters, each characterized by a shallow well installed in the surficial aquifer system and a deeper well installed in the intermediate aquifer system. Groundwater levels were evaluated with respect to surface-water levels and discharge in the BCSIR during the period of surface-water sampling. During dry conditions water levels in canals were often higher than groundwater levels in the surficial aquifer, indicating the potential for surface water to recharge the surficial aquifer. During wetter conditions, this trend reversed, and there was potential for shallow groundwater discharge into the canals. From October 2014 to September 2016, concentrations of TP tended to decrease as surface-water inflows moved across the BCSIR from north to south. In both the western and eastern halves of the reservation, the mean concentration of TP was lower in the surface-water outflows from the BCSIR than in the inflows. The mean concentration of TP in the inflows to the western reservation was 0.04 mg/L (40 ppb), whereas the mean concentration of TP in the outflows was 0.03 mg/L (30 ppb). In the eastern reservation, the mean concentration of TP in the inflows was 0.07 mg/L (70 ppb), whereas the mean concentration of TP in the outflows was 0.04 mg/L (40 ppb). TP and OP concentrations were evaluated relative to other water-quality parameters, including turbidity, suspended solids, nitrate plus nitrite, dissolved oxygen, pH, and specific conductance, to determine if any relations existed between TP and other variables. Weak relations were indicated for turbidity and suspended solids at two sites, which indicates that there may be a relation of increased TP to mobilization of sediment.

Florida↗

USGS2018

Groundwater quality in the shallow aquifers of the Madera–Chowchilla and Kings subbasins, San Joaquin Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Program’s Priority Basin Project assesses the quality of groundwater resources used for drinking-water supply and increases public access to groundwater-quality information. Many households and small communities in the Madera– Chowchilla and Kings subbasins of the San Joaquin Valley rely on private domestic wells for their drinking-water supplies.

California↗

USGS2015

Groundwater recharge assessment at local and episodic scale in a soil mantled perched karst aquifer in southern Italy

Groundwater recharge assessment of karst aquifers, at various spatial and temporal scales, is a major scientific topic of current importance, since these aquifers play an essential role for both socio-economic development and fluvial ecosystems. In this study, groundwater recharge was estimated at local and episodic scales in a representative perched karst aquifer in a region of southern Italy with a Mediterranean climate. The research utilized measurements of precipitation, air temperature, soil water content, and water-table depth, obtained in 2008 at the Acqua della Madonna test area (Terminio Mount karst aquifer, Campania region). At this location the aquifer is overlain by ash-fall pyroclastic soils. The Episodic Master Recession (EMR) method, an improved version of the Water Table Fluctuation (WTF) method, was applied to estimate the amount of recharge generated episodically by individual rainfall events. The method also quantifies the amount of precipitation generating each recharge episode, thus permitting calculation of the Recharge to the Precipitation Ratio (RPR) on a storm-by-storm basis. Depending on the seasonally varying air temperature, evapotranspiration, and precipitation patterns, calculated values of RPR varied between 35% and 97% among the individual episodes. A multiple linear correlation of the RPR with both the average intensity of recharging rainfall events and the antecedent soil water content was calculated. Given the relatively easy measurability of precipitation and soil water content, such an empirical model would have great hydrogeological and practical utility. It would facilitate short-term forecasting of recharge in karst aquifers of the Mediterranean region and other aquifers with similar hydrogeological characteristics. By establishing relationships between the RPR and climate-dependent variables such as average storm intensity, it would facilitate prediction of climate-change effects on groundwater recharge. The EMR methodology could further be applied to other aquifers for evaluating the relationship of recharge to various hydrometeorological and hydrogeological processes.

Journal of Hydrology↗

USGS2015

Conceptual and numerical models of groundwater flow in the Ogallala and Arikaree aquifers, Pine Ridge Indian Reservation area, South Dakota, water years 1980-2009

The Ogallala and Arikaree aquifers are the largest sources of groundwater on the Pine Ridge Indian Reservation and are used extensively for irrigation and public and domestic water supplies. To assess the potential for decreased water levels and discharge to streams in the Pine Ridge Indian Reservation, conceptual and numerical models of groundwater flow in the Ogallala and Arikaree aquifers in southwestern South Dakota were developed by the U.S. Geological Survey in cooperation with the Oglala Sioux Tribe. The study area includes most of the Pine Ridge Reservation in Jackson and Shannon Counties and Indian trust lands in Bennett County in southwestern South Dakota. The High Plains aquifer, which includes the Ogallala and Arikaree aquifers, generally is less developed in South Dakota compared with other areas underlain by this aquifer; therefore, water levels in the High Plains aquifer in South Dakota generally fluctuated by less than 5 feet (ft) from 1980 to 1999. Despite minimal water-level changes in the High Plains aquifer in South Dakota, extensive withdrawals of groundwater for irrigation have caused water-level declines in many areas and increased concerns about the long-term sustainability of the aquifer; therefore, continued or increased withdrawals from the aquifer or prolonged drought may have the potential to affect water levels within the aquifer and discharge to important streams in the area. The Ogallala and Arikaree aquifers generally consist of poorly consolidated claystones, siltstones, sandstones, and shale deposited in fluvial and lacustrine environments. Saturated thicknesses ranged from 10 to 314 ft for the Ogllala aquifer and from 10 to 862 ft for the Arikaree aquifer. Previous hydraulic conductivity estimates ranged from less than 1 to 180 feet per day (ft/d) for the Ogallala aquifer and from less than 1 to 13 ft/d for the Arikaree aquifer. Recharge to the Ogallala and Arikaree aquifers is from precipitation on the outcrop areas, and discharge occurs through evapotranspiration, discharge to streams, and well withdrawals. Evapotranspiration generally occurs in topographically low areas along streams, and maximum evapotranspiration occurs when the water level is at the land surface. The generalized groundwater-flow direction is to the northeast with local flow towards streams. Precipitation for water years 1980–2009 ranged from about 11 to 39 inches per year (in/yr) and averaged about 19 in/yr. Estimated mean recharge for water years 1980–2009 was about 17.3 percent of precipitation for the Ogallala aquifer and 7.9 percent of precipitation for the Arikaree aquifer. The estimated mean maximum evapotranspiration for water years 1980–2009 was about 35 in/yr. Estimated mean base flow for gaged streams was about 0.06 cubic foot per second (ft 3 /s) per square mile of drainage area. Estimated mean total water use for water years 1980–2009 was 5.4 ft 3 /s from the Ogallala aquifer and 7.1 ft 3 /s from the Arikaree aquifer. A two-layer numerical groundwater-flow model was constructed using MODFLOW–NWT with a uniformly spaced grid consisting of 166 rows and 288 columns with cells 1,640 ft on a side. The numerical model of the Ogallala and Arikaree aquifers was used to simulate steady-state and transient conditions for water years 1980–2009. Model calibration was accomplished using the Parameter ESTimation (PEST) program that adjusted individual model input parameters and assessed the difference between estimated and model-simulated values of hydraulic head and base flow. Aquifer boundaries were no-flow on the northern and western sides and constant-head on the southern and eastern sides. The mean arithmetic difference was 1.4 ft between the 731 simulated and observed hydraulic heads in the Ogallala aquifer and 9.8 ft between the 2,754 simulated and observed hydraulic heads in the Arikaree aquifer. Simulated mean discharge from the Ogallala and Arikaree aquifers to selected stream reaches was 92.1 ft 3 /s compared to estimated discharge of 88.7 ft 3 /s. Calibrated recharge for the transient simulation averaged 3.3 in/yr for the Ogallala aquifer and 1.1 in/yr for the Arikaree aquifer. The mean maximum potential evapotranspiration rate was 35.4 in/yr. Streambed conductance for perennial stream reaches averaged 530 feet squared per day. Horizontal hydraulic conductivity averaged 27 ft/d for the Ogallala aquifer and 1.0 ft/d for the Arikaree aquifer. The vertical hydraulic conductivity averaged 1.4 ft/d for the Ogallala aquifer and 0.004 ft/d for the Arikaree aquifer. Specific yield for the Ogallala aquifer was 0.15 (dimensionless) and averaged 0.02 for the Arikaree aquifer. Specific storage for the Arikaree aquifer was 1.7x10 -6 per foot. Simulated steady-state model inflow and outflow was 459 ft 3 /s. The percentages of inflows were 17 percent from constant-head boundaries, 9 percent from streams, and 74 percent from recharge. Percentages of outflow were 8 percent to constant-head boundaries, 1 percent to wells, 31 percent to streams, and 59 percent to evapotranspiration. Simulated net inflow from the Ogallala aquifer to the Arikaree aquifer ranged from about 22 ft 3 /s in dry years to about 37 ft 3 /s in wet years. Two hypothetical future stress scenarios were simulated using input from the 30-year calibrated simulation of water years 1980–2009. The first hypothetical scenario represented an increase in groundwater withdrawals from 50 hypothetical production wells completed in the Arikaree aquifer. At the end of the 30-year hypothetical increased pumping simulation, water levels declined as much as 66 ft in the Arikaree aquifer, decreased discharge to streams accounted for about 26 percent (2.6 ft 3 /s) of increased withdrawals, and decreased evapotranspiration accounted for about 53 (5.3 ft 3 /s) percent of increased withdrawals. The second hypothetical scenario represented a 30-year period of decreased recharge (drought) by decreasing recharge 0.2 inch (24 ft 3 /s) for each water year. At the end of the hypothetical drought simulation, water levels declined as much as 10.9 ft in the Arikaree aquifer, decreased discharge to streams accounted for about 23 percent (5.5 ft 3 /s) of decreased recharge, and decreased evapotranspiration accounted for about 72 percent (17.3 ft 3 /s) of decreased recharge. The numerical model is a tool that could be used to better understand the flow system of the Ogallala and Arikaree aquifers, to approximate hydraulic heads in the aquifer, and to estimate discharge to rivers, springs, and seeps in the Pine Ridge Reservation area in Bennett, Jackson, and Shannon Counties. The model also is useful to help assess the response of the aquifer to additional stress, including potential increased well withdrawals and potential drought conditions.

South Dakota↗

USGS2014

Simulation of groundwater flow in the Edwards-Trinity and related aquifers in the Pecos County region, Texas

The Edwards-Trinity aquifer is a vital groundwater resource for agricultural, industrial, and public supply uses in the Pecos County region of western Texas. The U.S. Geological Survey completed a comprehensive, integrated analysis of available hydrogeologic data to develop a numerical groundwater-flow model of the Edwards-Trinity and related aquifers in the study area in parts of Brewster, Jeff Davis, Pecos, and Reeves Counties. The active model area covers about 3,400 square miles of the Pecos County region of Texas west of the Pecos River, and its boundaries were defined to include the saturated areas of the Edwards-Trinity aquifer. The model is a five-layer representation of the Pecos Valley, Edwards-Trinity, Dockum, and Rustler aquifers. The Pecos Valley aquifer is referred to as the alluvial layer, and the Edwards-Trinity aquifer is divided into layers representing the Edwards part of the Edwards-Trinity aquifer and the Trinity part of the Edwards-Trinity aquifer, respectively. The calibration period of the simulation extends from 1940 to 2010. Simulated hydraulic heads generally were in good agreement with observed values; 1,684 out of 2,860 (59 percent) of the simulated values were within 25 feet of the observed value. The average root mean square error value of hydraulic head for the Edwards-Trinity aquifer was 34.2 feet, which was approximately 4 percent of the average total observed change in groundwater-level altitude (groundwater level). Simulated spring flow representing Comanche Springs exhibits a pattern similar to observed spring flow. Independent geochemical modeling corroborates results of simulated groundwater flow that indicates groundwater in the Edwards-Trinity aquifer in the Leon-Belding and Fort Stockton areas is a mixture of recharge from the Barilla and Davis Mountains and groundwater that has upwelled from the Rustler aquifer. The model was used to simulate groundwater-level altitudes resulting from prolonged pumping to evaluate sustainability of current and projected water-use demands. Each of three scenarios utilized a continuation of the calibrated model. Scenario 1 extended recent (2008) irrigation and nonirrigation pumping values for a 30-year period from 2010 to 2040. Projected groundwater-level changes in and around the Fort Stockton area under scenario 1 change little from current conditions, indicating that the groundwater system is near equilibrium with respect to recent (2008) pumping stress. Projected groundwater-level declines in the eastern part of the model area ranging from 5.0 to 15.0 feet are likely the result of nonequilibrium conditions associated with recent increases in pumping after a prolonged water-level recovery period of little or no pumping. Projected groundwater-level declines (from 15.0 to 31.0 feet) occurred in localized areas by the end of scenario 1 in the Leon-Belding area. Scenario 2 evaluated the effects of extended recent (2008) pumping rates as assigned in scenario 1 with year-round maximum permitted pumping rates in the Belding area. Results of scenario 2 are similar in water-level decline and extent as those of scenario 1. The extent of the projected groundwater-level decline in the range from 5.0 to 15.0 feet in the Leon-Belding irrigation area expanded slightly (about a 2-percent increase) from that of scenario 1. Maximum projected groundwater-level declines in the Leon-Belding irrigation area were approximately 31.3 feet in small isolated areas. Scenario 3 evaluated the effects of periodic increases in pumping rates over the 30-year extended period. Results of scenario 3 are similar to those of scenario 2 in terms of the areas of groundwater-level decline; however, the maximum projected groundwater-level decline increased to approximately 34.5 feet in the Leon-Belding area, and the extent of the decline was larger in area (about a 17-percent increase) than that of scenario 2. Additionally, the area of projected groundwater-level declines in the eastern part of the model area increased from that of scenario 2—two individual areas of decline coalesced into one larger area. The localized nature of the projected groundwater-level declines is a reflection of the high degree of fractured control on storage and hydraulic conductivity in the Edwards-Trinity aquifer. Additionally, the finding that simulated spring flow is highly dependent on the transient nature of hydraulic heads in the underlying aquifer indicates the importance of adequately understanding and characterizing the entire groundwater system.

Texas↗

USGS2009

Characteristics of Southern California coastal aquifer systems

Most groundwater produced within coastal Southern California occurs within three main types of siliciclastic basins: (1) deep (>600 m), elongate basins of the Transverse Ranges Physiographic Province, where basin axes and related fluvial systems strike parallel to tectonic structure, (2) deep (>6000 m), broad basins of the Los Angeles and Orange County coastal plains in the northern part of the Peninsular Ranges Physiographic Province, where fluvial systems cut across tectonic structure at high angles, and (3) shallow (75-350 m), relatively narrow fluvial valleys of the generally mountainous southern part of the Peninsular Ranges Physiographic Province in San Diego County. Groundwater pumped for agricultural, industrial, municipal, and private use from coastal aquifers within these basins increased with population growth since the mid-1850s. Despite a significant influx of imported water into the region in recent times, groundwater, although reduced as a component of total consumption, still constitutes a significant component of water supply. Historically, overdraft from the aquifers has caused land surface subsidence, flow between water basins with related migration of groundwater contaminants, as well as seawater intrusion into many shallow coastal aquifers. Although these effects have impacted water quality, most basins, particularly those with deeper aquifer systems, meet or exceed state and national primary and secondary drinking water standards. Municipalities, academicians, and local water and governmental agencies have studied the stratigraphy of these basins intensely since the early 1900s with the goals of understanding and better managing the important groundwater resource. Lack of a coordinated effort, due in part to jurisdictional issues, combined with the application of lithostratigraphic correlation techniques (based primarily on well cuttings coupled with limited borehole geophysics) have produced an often confusing, and occasionally conflicting, litany of names for the various formations, lithofacies, and aquifer systems identified within these basins. Despite these nomenclatural problems, available data show that most basins contain similar sequences of deposits and share similar geologic histories dominated by glacio-eustatic sea-level fluctuations, and overprinted by syndepositional and postdepositional tectonic deformation. Impermeable, indurated mid-Tertiary units typically form the base of each siliciclastic groundwater basin. These units are overlain by stacked sequences of Pliocene to Holocene interbedded marine, paralic, fluvial, and alluvial sediment (weakly indurated, folded, and fractured) that commonly contain the historically named "80-foot sand," "200-foot sand," and "400-foot gravel" in the upper part of the section. An unconformity, cut during the latest Pleistocene lowstand (?? 18 O stage 2; ca. 18 ka), forms a major sequence boundary that separates these units from the overlying Holocene fluvial sands and gravels. Unconfined aquifers occur in amalgamated coarse facies near the bounding mountains (forebay area). These units are inferred to become lithologically more complex toward the center of the basins and coast line, where interbedded permeable and low-permeability alluvial, fluvial, paralic, and marine facies contain confined aquifers (pressure area). Coastal bounding faults limit intrabasin and/or interbasin flow in parts of many basins. ?? 2009 Geological Society of America.

Special Paper of the Geological Society of America↗

USGS2014

A multiphased approach to groundwater investigations for the Edwards-Trinity and related aquifers in the Pecos County region, Texas

The Edwards-Trinity aquifer is a vital groundwater resource for agricultural, industrial, and public supply uses in the Pecos County region of western Texas. Resource managers would like to understand the future availability of water in the Edwards-Trinity aquifer in the Pecos County region and the effects of the possible increase or temporal redistribution of groundwater withdrawals. To provide resource managers with that information, the U.S. Geological Survey (USGS), in cooperation with the Middle Pecos Groundwater Conservation District, Pecos County, City of Fort Stockton, Brewster County, and Pecos County Water Control and Improvement District No. 1, completed a three-phase study of the Edwards-Trinity and related aquifers in parts of Brewster, Jeff Davis, Pecos, and Reeves Counties. The first phase was to collect groundwater, surface-water, geochemical, geophysical, and geologic data in the study area and develop a geodatabase of historical and collected data. Data compiled in the first phase of the study were used to develop the conceptual model in the second phase of the study. The third phase of the study involved the development and calibration of a numerical groundwater-flow model of the Edwards-Trinity aquifer to simulate groundwater conditions based on various groundwater-withdrawal scenarios. Analysis of well, geophysical, geochemical, and hydrologic data contributed to the development of the conceptual model in phase 1. Lithologic information obtained from well reports and geophysical data was used to describe the hydrostratigraphy and structural features of the groundwater-flow system, and aquifer-test data were used to estimate aquifer hydraulic properties. Geochemical data were used to evaluate groundwater-flow paths, water-rock interaction, aquifer interaction, and the mixing of water from different sources in phase 2. Groundwater-level data also were used to evaluate aquifer interaction, as well as to develop a potentiometric-surface map, delineate regional groundwater divides, and describe regional groundwater-flow paths. During phase 3, the data collected and compiled along with the conceptual information in the study area were incorporated into a numerical groundwater-flow model to evaluate the sustainability of recent (2008) and projected water-use demands on groundwater resources in the study area.

Texas↗