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Map showing geology, oil and gas fields, and geologic provinces of the Caribbean Region

This CD-ROM compilation contains a map and associated spatial data showing surface geology, faults, oil and gas field centerpoints, and geologic provinces of the Caribbean region, draped over a shaded relief image of topography and bathymetry. The map is provided in the Environmental Systems Research Institute, Inc. (ESRI) ArcMap and ArcReader GIS formats, as well as in Adobe Acrobat Portable Document Format (PDF). On this CD-ROM, ESRI ArcReader and Adobe Acrobat Reader software provide a way to view and interact with the maps. The organization and user-friendly navigation of this CD-ROM ensure easy access to its maps and data by using the links on the right side of each page. A link to the USGS World Energy Project website is also provided to access the latest information, updates, and interactive maps, as they relate to this and other world energy products. In addition, system requirements, permission, and contact information can be found in the readme section of this product. Navigation of this product can be fully utilized with most web browsers (Internet Explorer 6.0/Netscape Navigator 7.1 or later recommended). Note: an Internet connection is necessary to view USGS website links, World Energy website, and the Caribbean Internet Map Service.

Open-File Report

Exxon Valdez oil spill long-term herring research and monitoring program final report

This study includes annual field surveys of Ichthyophonus, viral hemorrhagic septicemia virus, and erythrocytic necrosis virus in adult and juvenile Pacific herring (Clupea pallasii) in Prince William Sound, Alaska and several reference populations in Alaska, British Columbia, and Washington. Results from controlled experimental studies with Ichthyophonus indicated that: • Pacific herring could become infected after repeated feedings on simulated infected offal, • Gross external signs of ichthyophoniasis can persist for extended periods without causing direct host mortality, • A novel tool (chromogenic in situ hybridization) was developed to confirm the presence of Ichthyophonus in histological sections, • A circulating stage of Ichthyophonus was detected in the blood of infected hosts, • Ichthyophonus remains viable in a fish carcass for up to 4 weeks and remains infectious for at least 5 days post mortem, • Six distinct genetic types of Ichthyophonus were identified in different hosts throughout the world, • Tissue explant culture was confirmed to be more sensitive than qPCR for detecting low - intensity Ichthyophonus infections directly from fish tissues. Results from controlled experimental studies with viral hemorrhagic septicemia virus indicated that: • Cooler temperatures are more conducive to viral hemorrhagic septicemia epizootics in Pacific herring, • A blocking ELISA was developed to detect fish antibodies to viral hemorrhagic septicemia virus, • A more sensitive plaque neutralization test was optimized to detect herring neutralizing antibodies to viral hemorrhagic septicemia virus, • The relative susceptibility of Pacific herring to other viral hemorrhagic septicemia virus genotypes was assessed, experimental spill-over, amplification, and spill-back was demonstrated between Atlantic salmon (Salmo salar) and Pacific herring, • The efficacy of homologous and heterologous DNA vaccines against viral hemorrhagic septicemia virus was demonstrated in Pacific herring. Controlled experimental studies with erythrocytic necrosis virus resulted in the development of a conventional PCR technique that is capable of the virus in the blood and the development of a quantitative PCR technique that is capable of detecting the virus in any herring tissues.

Report

U.S. Geological Survey—Energy and Wildlife Research Annual Report for 2016

Recent growth and development of renewable energy and unconventional oil and gas extraction are rapidly diversifying the energy supply of the United States. Yet, as our Nation works to advance energy security and conserve wildlife, some conflicts have surfaced. To address these challenges, the U.S. Geological Survey (USGS) is conducting innovative research and developing workable solutions to reduce the impacts of energy production on wildlife. USGS scientists collaborate on many studies with scientists from other Federal, State, and local government agencies; Tribal nations; academic research institutions; and nongovernmental and private organizations. The mix of fuels used for electricity generation is evolving. Solar, natural gas, and wind energy made up most electricity generation additions in 2015 and 2016. The United States now leads the world in natural gas production, with new record highs for each year from 2011 through 2015. More than 48,000 wind turbines now contribute to power grids in most States, providing about 5 percent of U.S. end-use electricity demand in an average year. The number of utility-scale solar-energy projects is growing rapidly with solar energy projected to contribute to the largest electricity generation addition in 2016. A substantial number of large energy projects have been constructed on undeveloped public lands, and more are anticipated at an increasing rate, creating new stress to wildlife. Direct impacts include collisions with wind turbines and structures at solar facilities and loss of habitat which may negatively affect sensitive species. Recent estimates suggest 250,000 to 500,000 birds die each year at wind turbine facilities. Bat fatality rates at wind turbine facilities are less certain, but may average several hundred thousand per year throughout North America. Because new projects may be located in or near sensitive wildlife habitats, ecological science plays a key role in helping to guide project siting and operational decisions.

Open-File Report

Identifying and filling critical knowledge gaps can optimize financial viability of blue carbon projects in tidal wetlands

One of the world’s largest “blue carbon” ecosystems, Louisiana’s tidal wetlands on the US Gulf of Mexico coast, is rapidly being lost. Louisiana’s strong legal, regulatory, and monitoring framework, developed for one of the world’s largest tidal wetland systems, provides an opportunity for a programmatic approach to blue carbon accreditation to support restoration of these ecologically and economically important tidal wetlands. Louisiana’s coastal wetlands span ∼1.4 million ha and accumulate 5.5–7.3 Tg yr −1 of blue carbon (organic carbon), ∼6%–8% of tidal marsh blue carbon accumulation globally. Louisiana has a favorable governance framework to advance blue carbon accreditation, due to centralized restoration planning, long term coastal monitoring, and strong legal and regulatory frameworks around carbon. Additional restoration efforts, planned through Louisiana’s Coastal Master Plan, over 50 years are projected to create, or avoid loss of, up to 81,000 ha of wetland. Current restoration funding, primarily from Deepwater Horizon oil spill settlements, will be fully committed by the early 2030s and additional funding sources are required. Existing accreditation methodologies have not been successfully applied to coastal Louisiana’s ecosystem restoration approaches or herbaceous tidal wetland types. Achieving financial viability for accreditation of these restoration and wetland types will require expanded application of existing blue carbon crediting methodologies. It will also require expanded approaches for predicting the future landscape without restoration, such as numerical modeling, to be validated. Additional methodologies (and/or standards) would have many common elements with those currently available but may be beneficial, depending on the goals and needs of both the state of Louisiana and potential purchasers of Louisiana tidal wetland carbon credits. This study identified twenty targeted needs that will address data and knowledge gaps to maximize financial viability of blue carbon accreditation for Louisiana’s tidal wetlands. Knowledge needs were identified in five categories: legislative and policy, accreditation methodologies and standards, soil carbon flux, methane flux, and lateral carbon flux. Due to the large spatial scale and diversity of tidal wetlands, it is expected that progress in coastal Louisiana has high potential to be generalized to similar wetland ecosystems across the northern Gulf of Mexico and globally.

Louisiana

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology

The Pre-Messinian Total Petroleum System of the Provence Basin, Western Mediterranean Sea

The Provence Basin is in that portion of the western Mediterranean Sea that is deeper than 2 kilometers. The basin lies essentially beyond the outer continental shelf, between the countries of France, Italy, and Algeria, the Balearic Islands, and the islands of Sardinia and Corsica. It encompasses nearly 300,000 square kilometers and includes the Rhone River submarine fan on the continental slope of southern France. It is province 4068 in the World Energy study. A single, hypothetical, total petroleum system (TPS), the Pre-Messinian TPS (406801), was described for the Provence Basin. The designation hypothetical is used because there is no hydrocarbon production from the basin. The Provence Basin is a deep-water Tertiary rift basin in which the geothermal gradients vary regionally. The Red Sea Basin shares a similar geologic and thermal history with the rifted western Mediterranean Sea and was used as an analog to better understand the genesis of the Provence Basin and as a guide to estimating possible undiscovered amounts of hydrocarbons. For this assessment the basin was given a potential, at the mean, for undiscovered resources of 51 trillion cubic feet (1.4 trillion cubic meters) gas, 0.42 billion barrels oil, and 2.23 million barrels natural gas liquids.

Bulletin

Updated methodology for nuclear magnetic resonance characterization of shales

Unconventional petroleum resources, particularly in shales, are expected to play an increasingly important role in the world’s energy portfolio in the coming years. Nuclear magnetic resonance (NMR), particularly at low-field, provides important information in the evaluation of shale resources. Most of the low-field NMR analyses performed on shale samples rely heavily on standard T 1 and T 2 measurements. We present a new approach using solid echoes in the measurement of T 1 and T 1 –T 2 correlations that addresses some of the challenges encountered when making NMR measurements on shale samples compared to conventional reservoir rocks. Combining these techniques with standard T 1 and T 2 measurements provides a more complete assessment of the hydrogen-bearing constituents (e.g., bitumen, kerogen, clay-bound water) in shale samples. These methods are applied to immature and pyrolyzed oil shale samples to examine the solid and highly viscous organic phases present during the petroleum generation process. The solid echo measurements produce additional signal in the oil shale samples compared to the standard methodologies, indicating the presence of components undergoing homonuclear dipolar coupling. The results presented here include the first low-field NMR measurements performed on kerogen as well as detailed NMR analysis of highly viscous thermally generated bitumen present in pyrolyzed oil shale.

Journal of Magnetic Resonance

New U.S. Geological Survey method for the assessment of reserve growth

Reserve growth is defined as the estimated increases in quantities of crude oil, natural gas, and natural gas liquids that have the potential to be added to remaining reserves in discovered accumulations through extension, revision, improved recovery efficiency, and additions of new pools or reservoirs. A new U.S. Geological Survey method was developed to assess the reserve-growth potential of technically recoverable crude oil and natural gas to be added to reserves under proven technology currently in practice within the trend or play, or which reasonably can be extrapolated from geologically similar trends or plays. This method currently is in use to assess potential additions to reserves in discovered fields of the United States. The new approach involves (1) individual analysis of selected large accumulations that contribute most to reserve growth, and (2) conventional statistical modeling of reserve growth in remaining accumulations. This report will focus on the individual accumulation analysis. In the past, the U.S. Geological Survey estimated reserve growth by statistical methods using historical recoverable-quantity data. Those statistical methods were based on growth rates averaged by the number of years since accumulation discovery. Accumulations in mature petroleum provinces with volumetrically significant reserve growth, however, bias statistical models of the data; therefore, accumulations with significant reserve growth are best analyzed separately from those with less significant reserve growth. Large (greater than 500 million barrels) and older (with respect to year of discovery) oil accumulations increase in size at greater rates late in their development history in contrast to more recently discovered accumulations that achieve most growth early in their development history. Such differences greatly affect the statistical methods commonly used to forecast reserve growth. The individual accumulation-analysis method involves estimating the in-place petroleum quantity and its uncertainty, as well as the estimated (forecasted) recoverability and its respective uncertainty. These variables are assigned probabilistic distributions and are combined statistically to provide probabilistic estimates of ultimate recoverable quantities. Cumulative production and remaining reserves are then subtracted from the estimated ultimate recoverable quantities to provide potential reserve growth. In practice, results of the two methods are aggregated to various scales, the highest of which includes an entire country or the world total. The aggregated results are reported along with the statistically appropriate uncertainties.

Scientific Investigations Report

Sediments, structural framework, petroleum potential, environmental conditions, and operational considerations of the United States North Atlantic Outer Continental Shelf

The area designated for possible oil and gas lease sale as modified from BLM memorandum 3310 #42 (722) and referred to therein as the North Atlantic Outer Continental Shelf (OCS) contains about 58,300 sq km of shelf beneath water depths of less than 200 m and lies chiefly within the Georges Bank basin. The oldest sediments drilled or dredged on the bordering Continental Slope are sandstone, clay, and silt of Upper Cretaceous age. In Upper Cretaceous exposures, on Marthas Vineyard and nearby New England islands, the predominant lithology appears to be clay. About 125 km northeast of the eastern tip of Georges Bank, the Shell B-93 well penetrated clays and silts of Upper and Lower Cretaceous age above dense Jurassic carbonate rocks which overlie a basement of lower Paleozoic slate, schist, quartzite, and granite. Structurally, the Georges Bank basin is a westerly trending trough which opens to the west-southwest. Post-Paleozoic sediments are more than 8 km thick in parts of the basin. Major structural features appear to be directly related to basement structures. Local anticlines, probably caused by differential compaction over basement flexures and horst blocks or by later uplift along basement faults are reflected principally in Lower Cretaceous and older sediments, though some of these features continue upward to within 0.7 of a second (about 650 m) of the seafloor. Tertiary deposits in the Georges Bank basin are probably up to a kilometre thick and are made up of poorly consolidated sand, silt, and clay. The Cretaceous section is inferred to be up to 3.5 km thick and to be mainly clastics -- shale, siltstone, calcareous shale, changing to limestone in the lowest part of the system. Jurassic rocks in the deepest part of the basin appear to be about 3.6 to 4.0 km thick and probably consist mainly of dense carbonates. Potential source rocks in the Georges Bank basin may include organic-rich Cretaceous shale and carbonaceous Jurassic limestone. By analogy with the Scotian Shelf, Cretaceous sandstones are considered to be potential reservoir rocks. Local zones of porous dolomite are believed to be present in carbonate rocks of Jurassic age and should not be overlooked as potential reservoirs. Structural highs related to draping and differential compaction over basement blocks could be important potential petroleum traps. Additional traps may include reef structures near the shelf edge, updip pinchouts, and stratigraphic traps in both clastic and carbonate sediment. A statistical mean for the undiscovered recoverable petroleum resources is calculated to be 0.9 billion barrels of oil and 4.2 trillion cubic feet of gas. At the 5 percent probability level (1 in 20 chance) the undiscovered recoverable petroleum resources are calculated to be 2.4 billion barrels of oil and 12.5 trillion cubic feet of gas. These undiscovered recoverable petroleum resources are those quantities of oil and gas that may be reasonably expected to exist in favorable settings, but which have not yet been identified by drilling. Such estimates, therefore, carry a high degree of uncertainty. Environmental studies of Georges Bank indicated a low-moderate risk from petroleum development. However, the risk estimate is based on very limited data. Drift bottle returns used to infer oil spill trajectories show about a 2% overall recovery rate. Meteorologic data comes mainly from nearby land areas and from ships attempting to avoid storms. Seismicity on Georges Bank is low. This may reflect, in large part, the difficulty of land-based stations in recording earthquakes far from the coast. Direct data on the engineering properties of shallow buried sediment comes mainly from two Texas Tower surveys of limited areas on Georges Shoal and Nantucket Shoals made in the early 1950's. The 17 holes (most less than 30 m deep) reveal some silty layers below loose sand and much lateral variability in sediment type over short distances. The technology for exploration at the required water depths (20 m - 200 m) is available. Mobil drilling units are in great demand around the world and will have to be brought in from other areas along with skilled manpower. Our highest estimates indicate 50 platforms, 800 producing wells, 1,100 km of pipeline, and 5 onshore terminals may be needed. The time frame for production, using our high estimates (5% probability) for the undiscovered recoverable resources, could include 4-5 years for significant development, 6-7 years until production commences, and 18 years until peak production.

Open-File Report

Evaluation of the lithium resource in the Smackover Formation brines of southern Arkansas using machine learning

Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithium concentration data to train a random forest machine-learning model using geologic, geochemical, and temperature explanatory variables and create a map of predicted lithium concentrations in Smackover Formation brines across southern Arkansas. Using these predicted lithium maps with reservoir parameters and geologic information, we calculated that there are 5.1 to 19 million tons of lithium in Smackover Formation brines in southern Arkansas, which represents 35 to 136% of the current US lithium resource estimate. Based on these calculations, in 2022, 5000 tons of dissolved lithium were brought to the surface within brines as waste streams of the oil, gas, and bromine industries.

Arkansas

Modeling effects of crop production, energy development and conservation-grassland loss on avian habitat

Birds are essential components of most ecosystems and provide many services valued by society. However, many populations have undergone striking declines as their habitats have been lost or degraded by human activities. Terrestrial grasslands are vital habitat for birds in the North American Prairie Pothole Region (PPR), but grassland conversion and fragmentation from agriculture and energy-production activities have destroyed or degraded millions of hectares. Conservation grasslands can provide alternate habitat. In the United States, the Conservation Reserve Program (CRP) is the largest program maintaining conservation grasslands on agricultural lands, but conservation grasslands in the PPR have declined by over 1 million ha since the program’s zenith in 2007. We used an ecosystem-services model (InVEST) parameterized for the PPR to quantify grassland-bird habitat remaining in 2014 and to assess the degradation status of the remaining grassland-bird habitat as influenced by crop and energy (i.e., oil, natural gas, and wind) production. We compared our resultant habitat-quality ratings to grassland-bird abundance data from the North American Breeding Bird Survey to confirm that ratings were related to grassland-bird abundance. Of the grassland-bird habitat remaining in 2014, about 19% was degraded by crop production that occurred within 0.1 km of grassland habitats, whereas energy production degraded an additional 16%. We further quantified the changes in availability of grassland-bird habitat under various land-cover scenarios representing incremental losses (10%, 25%, 50%, 75%, and 100%) of CRP grasslands from 2014 levels. Our model identified 1 million ha (9%) of remaining grassland-bird habitat in the PPR that would be lost or degraded if all CRP conservation grasslands were returned to crop production. Grassland regions world-wide face similar challenges in maintaining avian habitat in the face of increasing commodity and energy production to sate the food and energy needs of a growing world population. Identifying ways to model the impacts of the tradeoff between food and energy production and wildlife production is an important step in creating solutions.

Prairie Pothole Region

Production of mineral commodities and geospatial map of the mineral industries and related infrastructure of China

As part of the U.S. Geological Survey’s (USGS) mission to distribute global mineral information and analyze supply chains, this study provides a comprehensive review of the global significance of China’s mineral production and capacity in 2023. Of 77 mineral commodities in the USGS dataset, China produced 74 and was the world’s first-ranked producer for 39 of the 74. Compared to the high share of global mineral production, including up to 98 percent of global gallium production, the country’s share of global mineral reserves was relatively small, ranging from 20 percent (zinc ore) to 52 percent (tungsten ore). China’s imports of metal ores, slag, and ash accounted for 64 percent of global imports of such commodities by value. The country’s exports of base metals and articles of base metal accounted for 17 percent of the global exports. To help nongeographic information system users assess the spatial distribution of mineral mines, processing facilities, and ports for trades in China, this study created a geospatial (also called “georeferenced”) portable document format (GeoPDF) map. In addition, the GeoPDF contains mineral resource tracts (such as antimony, copper, potash, coal, and oil and gas), exploration sites, and energy infrastructure based on the preexisting USGS data.

Open-File Report

Distribution of organic carbon and petroleum source rock potential of Cretaceous and lower Tertiary carbonates, south Florida basin: Preliminary results

Analyses of 134 core samples from the South Florida Basin show that the carbonates of Comanchean age are relatively richer in average organic carbon (0.41 percent) than those of Coahuilan age (0.28 percent), Gulfian age (0.18 percent) and Paleocene age (0.20 percent). They are also nearly twice as rich as the average world, wide carbonate (average 0.24 percent). The majority of carbonates have organic carbons less than 0.30 percent but the presence of many relatively organic rich beds composed of highly bituminous, argillaceous, highly stylolitic, and algal-bearing limestones and dolomites accounts for the higher percentage of organic carbon in some of the stratigraphic units. Carbonate rocks that contain greater than 0.4 percent organic carbon and that might be considered as possible petroleum sources were noted in almost each subdivision of the Coahuilan and Comanchean Series but particularly the units of Fredericksburg 'B', Trinity 'A', Trinity 'F', and Upper Sunniland. Possible source rocks have been ascribed by others to the Lower Sunniland, but lack of sufficient samples precluded any firm assessment in this initial report. In the shallower section of the basin, organic-rich carbonates containing as much as 3.2 percent organic carbon were observed in the lowermost part of the Gulfian Series and carbonate rocks with oil staining or 'dead' and 'live oil' were noted by others in the uppermost Gulfian and upper Cedar Keys Formation. It is questionable whether these shallower rocks are of sufficient thermal maturity to have generated commercial oil. The South Florida basin is still sparsely drilled and produces only from the Sunniland Limestone at an average depth of 11,500 feet (3500 m). Because the Sunniland contains good reservoir rocks and apparently adequate source rocks, and because the success rate of new oil field discoveries has increased in recent years, the chances of finding additional oil reserves in the Sunniland are promising. Furthermore, the presence of possible source rocks in many of the other stratigraphic units, in particular, the Fredericksburg, should give further impetus to exploring for other productive horizons.

Florida

Regional Fluid Flow and Basin Modeling in Northern Alaska

The foothills of the Brooks Range contain an enormous accumulation of zinc (Zn) in the form of zinc sulfide and barium (Ba) in the form of barite in Carboniferous shale, chert, and mudstone. Most of the resources and reserves of Zn occur in the Red Dog deposit and others in the Red Dog district; these resources and reserves surpass those of most deposits worldwide in terms of size and grade. In addition to zinc and lead sulfides (which contain silver, Ag) and barite, correlative strata host phosphate deposits. Furthermore, prolific hydrocarbon source rocks of Carboniferous and Triassic to Early Jurassic age generated considerable amounts of petroleum that may have contributed to the world-class petroleum resources of the North Slope. Deposits of Zn-Pb-Ag or barite as large as those in the Brooks Range are very rare on a global basis and, accordingly, multiple coincident favorable factors must be invoked to explain their origins. To improve our understanding of these factors and to contribute to more effective assessments of resources in sedimentary basins of northern Alaska and throughout the world, the Mineral Resources Program and the Energy Resources Program of the U.S. Geological Survey (USGS) initiated a project that was aimed at understanding the petroleum maturation and mineralization history of parts of the Brooks Range that were previously poorly characterized. The project, titled “Regional Fluid Flow and Basin Modeling in Northern Alaska,” was undertaken in collaboration with industry, academia, and other government agencies. This Circular contains papers that describe the results of the recently completed project. The studies that are highlighted in these papers have led to a better understanding of the following: The complex sedimentary facies relationships and depositional settings and the geochemistry of the sedimentary rocks that host the deposits (sections 2 and 3). The factors responsible for formation of the barite and zinc deposits (sections 4 and 5). The geochemical indicators or exploration tools that might be used to locate other large deposits of similar character in the Red Dog district and elsewhere (section 6). The isotopic compositions of barite and sulfide deposits (sections 7 and 8) The distribution and nature of phosphate and metalliferous oil shale localities (sections 9 and 10). The architecture, kinematics, and timing of the complex thrust systems that disrupted and redistributed the Carboniferous and younger rocks; these studies are necessary in order to make a realistic palinspastic reconstruction of the basin (sections 11 and 12). The nature and extent of the petroleum system sourced from Mississippian rocks (section 13).

Circular

Petroleum systems succeed play basis in Appalachian basin resource estimate

The US Geological Survey (USGS) periodically conducts subjective probabilistic assessments of the technically recoverable undiscovered hydrocarbon resources of the US and of the world. In addition, the USGS prepares forecasts of that portion of the technically recoverable resources that may be economic under specified conditions of supply, demand, and price. Depending on priorities, regional hydrocarbon assessments of the US are revised every 5 to 10 years. These assessments of undiscovered hydrocarbons supplement the data on hydrocarbon reserves that are reported annually by the US Department of Energy, Energy Information Administration. In between assessments, USGS assessment geologists conduct research and compile geologic and production data that may be used to improve future assessments. This new information commonly effects changes in the way the USGS defines "plays" or "assessment units" from assessment to assessment. Furthermore, USGS assessment methodology is in a constant state of evolution and changes to some degree from assessment to assessment.

Oil & Gas Journal

Stratigraphic sections of the Phosphoria formation in Idaho, 1947-48, Part I

The Permian Phosphoria formation of the western states contains one of the world's largest reserves of phosphate. Although previous investigations (see especially Mansfield, 1927), including reconnaissance geologic mapping and sampling, established the location of most of the important deposits and their quality of scattered localities, they were not sufficiently detailed to permit a comparison of the merits of individual deposits or an appraisal of the reserves of phosphate rock that might be available under present economic conditions. Because the growing importance of the western phosphate deposits requires a better, more detailed understanding of their distribution and quality, the Geological Survey began in 1947 a comprehensive investigation, including (1) reconnaissance geologic mapping, mostly in Montana, of areas in which the Phosphoria formation could occur but where it had not previously been looked for or found; (2) geologic mapping, mostly in Montana, at a scale no smaller than 1:62,500, of several areas known to contain the Phosphoria formation but not previously mapped except in reconnaissance fashion; (3) geologic and topographic mapping, at a scale of 1:12,000, of some of the richest, thickest, and most accessible deposits; (4) measuring, describing, and sampling all beds of the phosphatic and shaly parts, and in some places the full thickness, of the Phosphoria formation and its stratigraphic equivalents at one or two localities per township over the entire field; (5) chemical and spectrographic analysis of the samples for phosphate, fluorine, minor metals, oil, and rock-forming constituents; and (6) petrologic and geochemical studies of the rocks and minerals of the formation. These studies are designed to define the regional and local geologic structures in which the phosphate bed lie, to provide a basis for the estimation of reserves of the inferred class over the entire region, and to determine the origin of the rocks and the elements contained in them. The data collected are not of the detail required to plan actual mining operations, but it is hoped they will guide industry in the selection of individual deposits worthy of further exploration. Most of the field work contemplated as a part of this investigation is now completed. Although the data will not be compiled or published in final form for some years to come, segments of the data, accompanied by little or no interpretation, will be published as preliminary maps or reports as they are assembled. The present report is the first of a series presenting in abbreviated form the description and analyses of the beds measured and sampled at various localities in southeastern Idaho (pl. 1). Companion reports presenting segments of the data from Montana, Wyoming, and Utah (Swanson and others, 1952, and McKelvey and others, 1952a and 1952b) are being released at the same time as this report, and others are in preparation.

Idaho

Hydrogeology, ground-water movement, and subsurface storage in the Floridan aquifer system in southern Florida

The Floridan aquifer system of southern Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the aquifer system in southern Florida generally is at depths ranging from 500 to 1,000 feet, and the average thickness is about 3,000 feet. It is divided into three general hydrogeologic units: (1) the Upper Floridan aquifer, (2) the middle confining unit, and (3) the Lower Floridan aquifer. The Upper Floridan aquifer contains brackish ground water, and the Lower Floridan aquifer contains salty ground water that compares chemically to modern seawater. Zones of high permeability are present in the Upper and Lower Floridan aquifers. A thick, cavernous dolostone in the Lower Floridan aquifer, called the Boulder Zone, is one of the most permeable carbonate units in the world (transmissivity of about 2.5 x 107 feet squared per day). Ground-water movement in the Upper Floridan aquifer is generally southward from the area of highest head in central Florida, eastward to the Straits of Florida, and westward to the Gulf of Mexico. Distributions of natural isotopes of carbon and uranium generally confirm hydraulic gradients in the Lower Floridan aquifer. Groundwater movement in the Lower Floridan aquifer is inland from the Straits of Florida. The concentration gradients of the carbon and uranium isotopes indicate that the source of cold saltwater in the Lower Floridan aquifer is seawater that has entered through the karat features on the submarine Miami Terrace near Fort Lauderdale. The relative ages of the saltwater suggest that the rate of inland movement is related in part to rising sea level during the Holocene transgression. Isotope, temperature, and salinity anomalies in waters from the Upper Floridan aquifer of southern Florida suggest upwelling of saltwater from the Lower Floridan aquifer. The results of the study support the hypothesis of circulating relatively modern seawater and cast doubt on the theory that the saltwater in the Floridan aquifer system probably is connate or unflushed seawater from high stands of sea level. The principal use of the Floridan aquifer system in southern Florida is for subsurface storage of liquid waste. The Boulder Zone of the Lower Floridan aquifer is extensively used as a receptacle for injected treated municipal wastewater, oil field brine, and, to a lesser extent, industrial wastewater. Pilot studies indicate a potential for cyclic storage of freshwater in the Upper Floridan aquifer in southern Florida.

Florida

Northern Great Plains

In the Northern Great Plains, the timing and quantity of both precipitation and runoff have important consequences for water supplies, agricultural activities, and energy production. Overall, climate projections suggest that the number of heavy precipitation events (events with greater than 1 inch per day of rainfall) is projected to increase. Moving forward, the magnitude of year-to-year variability overshadows the small projected average decrease in streamflow. Changes in extreme events are likely to overwhelm average changes in both the eastern and western regions of the Northern Great Plains. Major flooding across the basin in 2011 was followed by severe drought in 2012, representing new and unprecedented variability that is likely to become more common in a warmer world. The Northern Great Plains region plays a critical role in national food security. Among other anticipated changes, projected warmer and generally wetter conditions with elevated atmospheric carbon dioxide concentrations are expected to increase the abundance and competitive ability of weeds and invasive species, increase livestock production and efficiency of production, and result in longer growing seasons at mid- and high latitudes. Net primary productivity, including crop yields and forage production, is also likely to increase, although an increasing number of extreme temperature events during critical pollination and grain fill periods is likely to reduce crop yields. Ecosystems across the Northern Great Plains provide recreational opportunities and other valuable goods and services that are ingrained in the region’s cultures. Higher temperatures, reduced snow cover, and more variable precipitation will make it increasingly challenging to manage the region’s valuable wetlands, rivers, and snow-dependent ecosystems. In the mountains of western Wyoming and western Montana, the fraction of total water in precipitation that falls as snow is expected to decline by 25% to 40% by 2100 under a higher scenario (RCP8.5), which would negatively affect the region’s winter recreation industry. At lower-elevation areas of the Northern Great Plains, climate-induced land-use changes in agriculture can have cascading effects on closely entwined natural ecosystems, such as wetlands, and the diverse species and recreational opportunities they support. Energy resources in the Northern Great Plains include abundant crude oil, natural gas, coal, wind, and stored water, and to a lesser extent, corn-based ethanol, solar energy, and uranium. The infrastructure associated with the extraction, distribution, and energy produced from these resources is vulnerable to the impacts of climate change. Railroads and pipelines are vulnerable to damage or disruption from increasing heavy precipitation events and associated flooding and erosion. Declining water availability in the summer would likely increase costs for oil production operations, which require freshwater resources. These cost increases will either lead to lower production or be passed on to consumers. Finally, higher maximum temperatures, longer and more severe heat waves, and higher overnight lows are expected to increase electricity demand for cooling in the summer, further stressing the power grid. Indigenous peoples in the region are observing changes to climate, many of which are impacting livelihoods as well as traditional subsistence and wild foods, wildlife, plants and water for ceremonies, medicines, and health and well-being. Because some tribes and Indigenous peoples are among those in the region with the highest rates of poverty and unemployment, and because many are still directly reliant on natural resources, they are among the most at risk to climate change (e.g., Gamble et al. 2016, Cozzetto et al. 2013, Espey et al. 2014, Wong et al. 2014, Kornfeld 2016, Paul and Caplins 2016, Maynard 2014, USGCRP 2017)

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