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At least 217 records · Page 12Linked to original sources

USGS2014

Florfenicol residues in Rainbow Trout after oral dosing in recirculating and flow-through culture systems

Aquaflor is a feed premix for fish containing the broad spectrum antibacterial agent florfenicol (FFC) incorporated at a ratio of 50% (w/w). To enhance the effectiveness of FFC for salmonids infected with certain isolates of Flavobacterium psychrophilum causing coldwater disease, the FFC dose must be increased from the standard 10 mg·kg −1 body weight (BW)·d −1 for 10 consecutive days. A residue depletion study was conducted to determine whether FFC residues remaining in the fillet tissue after treating fish at an increased dose would be safe for human consumption. Groups of Rainbow Trout Oncorhynchus mykiss (total n = 144; weight range, 126–617 g) were treated with FFC at 20 mg·kg −1 BW·d −1 for 10 d in a flow-through system (FTS) and a recirculating aquaculture system (RAS) each with a water temperature of ∼13°C. The two-tank RAS included a nontreated tank containing 77 fish. Fish were taken from each tank (treated tank, n = 16; nontreated tank, n = 8) at 6, 12, 24, 48, 72, 120, 240, 360, and 480 h posttreatment. Florfenicol amine (FFA) concentrations (the FFC marker residue) in skin-on fillets from treated fish were greatest at 12 h posttreatment (11.58 μg/g) in the RAS and were greatest at 6 h posttreatment (11.09 μg/g) in the FTS. The half-lives for FFA in skin-on fillets from the RAS and FTS were 20.3 and 19.7 h, respectively. Assimilation of FFC residues in the fillets of nontreated fish sharing the RAS with FFC-treated fish was minimal. Florfenicol water concentrations peaked in the RAS-treated tank and nontreated tanks at 10 h (453 μg/L) and 11 h (442 μg/L) posttreatment, respectively. Monitoring of nitrite concentrations throughout the study indicated the nitrogen oxidation efficiency of the RAS biofilter was minimally impacted by the FFC treatment.

Journal of Aquatic Animal Health↗

USGS1987

A review of surface-water sediment fractions and their interactions with persistent manmade organic compounds

This paper reviews the suspended and surficial sediment fractions and their interactions with manmade organic compounds. The objective of this review is to isolate and describe those contaminant and sediment properties that contribute to the persistence of organic compounds in surface-water systems. Most persistent, nonionic organic contaminants, such as the chlorinated insecticides and polychlorinated biphenyls (PCBs), are characterized by low water solubilities and high octanol-water partition coefficients. Consequently, sorptive interactions are the primary transformation processes that control their environmental behavior. For nonionic organic compounds, sorption is primarily attributed to the partitioning of an organic contaminant between a water phase and an organic phase. Partitioning processes play a central role in the uptake and release of contaminants by sediment organic matter and in the bioconcentration of contaminants by aquatic organisms. Chemically isolated sediment fractions show that organic matter is the primary determinant of the sorptive capacity exhibited by sediment. Humic substances, as dissolved organic matter, contribute a number of functions to the processes cycling organic contaminants. They alter the rate of transformation of contaminants, enhance apparent water solubility, and increase the carrying capacity of the water column beyond the solubility limits of the contaminant. As a component of sediment particles, humic substances, through sorptive interactions, serve as vectors for the hydrodynamic transport of organic contaminants. The capabilities of the humic substances stem in part from their polyfunctional chemical composition and also from their ability to exist in solution as dissolved species, flocculated aggregates, surface coatings, and colloidal organomineral and organometal complexes. The transport properties of manmade organic compounds have been investigated by field studies and laboratory experiments that examine the sorption of contaminants by different sediment size fractions. Field studies indicate that organic contaminants tend to sorb more to fine-grained sediment, and this correlates significantly with sediment organic matter content. Laboratory experiments have extended the field studies to a wider spectrum of natural particulates and anthropogenic compounds. Quantitation of isotherm results allows the comparison of different sediment sorbents as well as the estimation of field partition coefficients from laboratory-measured sediment and contaminant properties. Detailed analyses made on the basis of particle-size classes show that all sediment fractions need to be considered in evaluating the fate and distribution of manmade organic compounds. This conclusion is based on observations from field studies and on the variety of natural organic sorbents that demonstrate sorptive capabilities in laboratory isotherm experiments.

Circular↗

USGS1972

Mass spectrometric analysis of organic compounds, water and volatile constituents in the atmosphere and surface of Mars: The Viking Mars Lander

An experiment centering around a mass spectrometer is described, which is aimed at the identification of organic substances present in the top 10 cm of the surface of Mars and an analysis of the atmosphere for major and minor constituents as well as isotopic abundances. In addition, an indication of the abundance of water in the surface and some information concerning the mineralogy can be obtained by monitoring the gases produced upon heating the soil sample. The organic material will simply be expelled by heating to 150°, 300°, and 500° into the carrier gas stream of a gas chromatograph interfaced to the mass spectrometer or by slowly heating the sample in direct communication with the spectrometer. It is planned to analyze a total of up to nine soil samples in order to study diurnal and seasonal variations. The system is designed to give useful data even for minor constituents if the total of organics should be as low as 5ppm. The spectrometer covers the mass range of 12–200 with adequate resolution. The results of these experiments, which are deliberately designed to cover a wide spectrum of possibilities independent of terrestrial models, are expected to produce a good picture of the planet's organic chemistry and its possible biological significance as well as allow conclusions regarding the history of the planet's atmosphere.

Icarus↗

USGS2013

Interactions between hyporheic flow produced by stream meanders, bars, and dunes

Stream channel morphology from grain-scale roughness to large meanders drives hyporheic exchange flow. In practice, it is difficult to model hyporheic flow over the wide spectrum of topographic features typically found in rivers. As a result, many studies only characterize isolated exchange processes at a single spatial scale. In this work, we simulated hyporheic flows induced by a range of geomorphic features including meanders, bars and dunes in sand bed streams. Twenty cases were examined with 5 degrees of river meandering. Each meandering river model was run initially without any small topographic features. Models were run again after superimposing only bars and then only dunes, and then run a final time after including all scales of topographic features. This allowed us to investigate the relative importance and interactions between flows induced by different scales of topography. We found that dunes typically contributed more to hyporheic exchange than bars and meanders. Furthermore, our simulations show that the volume of water exchanged and the distributions of hyporheic residence times resulting from various scales of topographic features are close to, but not linearly additive. These findings can potentially be used to develop scaling laws for hyporheic flow that can be widely applied in streams and rivers.

Water Resources Research↗

USGS2024

Quantifying form resistance is essential for estimating summer low and bankfull flow from stream survey channel morphology

Reliable estimates of low flow and flood discharge at ungaged locations are required for evaluating stream flow alteration, designing culverts and stream crossings, and interpreting regional surveys of habitat and biotic condition. Very few stream gaging stations are located on small, remote streams, which typically have complex channel morphology. Adequate gaging is also lacking on larger streams that are remote, smaller than those typically gaged, or have channel morphology not conducive to installation of gages. Complex channels typically contain large scale hydraulic roughness elements that dominate flow patterns (i.e., form roughness), making it difficult to measure channel cross-section area and water velocity, or to measure channel volume even where discharge is known. In channels with large channel form roughness, it is equally difficult to estimate discharge using commonly applied equations based on slope and channel dimensions or basin area. We employed a novel approach that explicitly accounts for hydraulic resistance from large wood and riffle-pool morphology (form roughness) in calculating low flow and bankfull discharge from stream and river physical habitat data collected from 4229 stream and river sites in the conterminous US (CONUS) sampled in 2008–9 and 2013–14 as part of the US Environmental Protection Agency's N ational R ivers and S treams A ssessment (NRSA). Hydraulic resistance derived from form roughness clearly dominated resistance derived from bed particles (particle resistance) during summer low flows in wadeable streams across the spectrum of channel slopes and substrate sizes smaller than boulders. Under bankfull conditions, the influence of form resistance relative to particle resistance was diminished, but form resistance still dominated except in large low gradient rivers lacking complex channels, and in streams or rivers with boulder-size bed particles. We validated our hydraulic resistance estimates by comparing measured discharges with calculated discharges that used those hydraulic resistance estimates along with measured NRSA channel morphology data. Morphology-based summer discharge (low flow) estimates and direct field measurements of discharge in 2333 wadeable CONUS streams showed reasonable agreement (median difference < 2.5×) for discharges ranging from 3.6 × 10 −5 to 123 m 3 /s and drainage areas of 0.12 to 171,000 km 2 . In a subset of 759 of NRSA's larger wadeable stream and non-wadeable river sites where nearby U.S. Geological Survey (USGS) gage data were available and adequate, our morphology-based summer discharge estimates agreed fairly well (median difference < 2.0×) with USGS 20-yr average August mean flows ranging from 0.003 to 16,000 m 3 /s. Similarly, morphology-based estimates of bankfull flow ranging from 0.3 to 100,000 m 3 /s agreed reasonably well with the 1.5-yr recurrence interval flood in these gaged sites (median deviation <2.2×). These findings demonstrate the importance of quantifying flow resistance from large-scale form roughness features in natural channels and provide a novel approach for estimating discharge from widely available survey data. This will allow examination of discharge and its ecological influence across the full range of stream and river sizes sampled by NRSA or other synoptic surveys where comprehensive measures of biota, physical habitat, and chemistry are also made. Although these morphology-based estimates exhibit some variability, they are adequate for examining regional patterns in discharge and flow alteration and their association with instream biota and anthropogenic disturbances, providing summer low and bankfull flow information where reliable estimates are lacking.

Geomorphology↗

USGS1994

Permeability-porosity relationships in sedimentary rocks

In many consolidated sandstone and carbonate formations, plots of core data show that the logarithm of permeability (k) is often linearly proportional to porosity (??). The slope, intercept, and degree of scatter of these log(k)-?? trends vary from formation to formation, and these variations are attributed to differences in initial grain size and sorting, diagenetic history, and compaction history. In unconsolidated sands, better sorting systematically increases both permeability and porosity. In sands and sandstones, an increase in gravel and coarse grain size content causes k to increase even while decreasing ??. Diagenetic minerals in the pore space of sandstones, such as cement and some clay types, tend to decrease log(k) proportionately as ?? decreases. Models to predict permeability from porosity and other measurable rock parameters fall into three classes based on either grain, surface area, or pore dimension considerations. (Models that directly incorporate well log measurements but have no particular theoretical underpinnings from a fourth class.) Grain-based models show permeability proportional to the square of grain size times porosity raised to (roughly) the fifth power, with grain sorting as an additional parameter. Surface-area models show permeability proportional to the inverse square of pore surface area times porosity raised to (roughly) the fourth power; measures of surface area include irreducible water saturation and nuclear magnetic resonance. Pore-dimension models show permeability proportional to the square of a pore dimension times porosity raised to a power of (roughly) two and produce curves of constant pore size that transgress the linear data trends on a log(k)-?? plot. The pore dimension is obtained from mercury injection measurements and is interpreted as the pore opening size of some interconnected fraction of the pore system. The linear log(k)-?? data trends cut the curves of constant pore size from the pore-dimension models, which shows that porosity reduction is always accompanied by a reduction in characteristic pore size. The high powers of porosity of the grain-based and surface-area models are required to compensate for the inclusion of the small end of the pore size spectrum.

Log Analyst↗

USGS2025

Patterns of water-extractable soil organic matter in the US Great Plains: Insights from the Haas Soil Archive

Novel approaches that are fast and sensitive are needed to evaluate soil change and integrate soil ecosystem properties. Carbon (C) and nitrogen (N) extracted from soil with water are associated with plant nutrients and microbial activity but information about change over time in the US Great Plains is sparse. We used cool (20°C) and hot (80°C) water extracts from historic (1947) and contemporary (2018) soil samples collected at Moccasin, MT; Akron, CO; and Big Spring, TX; to examine changes to labile C and N and optical properties after 71 years of dryland cropping. Concentrations of C and N extracted with cool water decreased between 1947 and 2018 in surface (0–15.2 cm) samples from Moccasin, by 52% and 35%, and Big Spring, by 37% and 32%, but remained unchanged at Akron. Conversely, net (hot−cool) extractable C did not change at Moccasin or Big Spring but increased at Akron by 26%. Net extractable N decreased at Moccasin by 22% but did not change elsewhere. Sequential principal component analysis and stepwise discriminant analysis identified three important optical properties. Values of SUVA 254 (where SUVA 254 is the specific ultraviolet absorbance at 254 nm) in extracts did not change at Moccasin between 1947 and 2018 but increased at Akron, indicating increased aromaticity. Conversely, SUVA 254 decreased at Big Spring. Values for Sag 350–400 (where Sag 350–400 is the slope from a nonlinear fit of an exponential function to the absorption spectrum over the wavelength range from 350 to 400 nm), inversely related to extract molecular weight and aromaticity, decreased at Moccasin but not elsewhere. The proportion of recalcitrant to labile compounds, C:T (where C:T is the ratio of fluorescence intensity from Peak C [ex340/em440] to Peak T [ex275/em340]), increased in extracts from all sites but especially at Akron. Together, these methods provided insights into soil change while conserving samples.

Colorado, Kansas, Montana, Nebraska, New Mexico, N↗

USGS1976

Gamma-ray spectrometer measurement of 238 U/ 235 U in uranium ore from a natural reactor at Oklo, Gabon

About 20 years ago, Kuroda theorized that a high-grade uranium deposit emplaced about 2x10 9 years ago could achieve criticality and sustain a nuclear chain reaction, given a sufficient thickness of high-grade ore and an appropriate water content. Such a natural reactor was found in 1972 at the Oklo deposit, Gabon. The ore contains as much as 60 percent uranium, but the isotopic abundance of 235 U is as little as 0.4 percent in contrast to the normal abundance of 0.7110 percent 235 U. A sample from the Oklo deposit containing about 0.51 atom percent 235 U (by mass spectrometer) was analyzed by a gamma-ray spectrometer system, using a high-purity planar germanium detector. The 235 U was determined from its daughter's ( 234 Th) 63.3 keV photopeak; the 235 U was determined from its 143.8 and 163.4 keV photopeaks. The ratios of these photopeaks were compared with that from a standard having normal uranium isotopic content; the resulting calculations give a 235 U abundance of 0.54 atom percent in the Oklo sample. The gamma-ray spectrum also contains lines from five other isotopes in the uranium series, which indicate the Oklo sample to be at or near secular equilibrium, as the time elapsed since the nuclear reaction ended was sufficient to permit the daughters to achieve equilibrium.

Journal of Research of the U.S. Geological Survey↗

USGS2001

Oxytetracycline depletion from skin-on fillet tissue of coho salmon fed oxytetracycline medicated feed in freshwater at temperatures less than 9°C

Oxytetracycline (OTC) is a broad spectrum antibacterial agent approved in the USA for treating certain bacterial diseases in salmonids cultured in freshwater at temperatures greater than or equal to 9°C. This study was conducted to provide the information necessary to expand the OTC label to include treatment of diseased salmonids cultured in freshwater at temperatures below 9°C. The study was designed to treat juvenile coho salmon ( Oncorhynchus kisutch ) with OTC-medicated feed and determine the depletion of OTC from the skin-on fillet tissue. Oxytetracycline depletion was evaluated in juvenile coho salmon (weight range, 13–62 g) fed OTC-medicated feed at a rate of 88.2 mg OTC/kg body weight/day for 10 days. Pairs of skin-on fillets were taken from individual fish on days 4 and 10 during the treatment phase and on days 1, 4, 8, 14, and 19 during the depletion phase. Water temperatures during the study period ranged from 4.1°C to 8.5°C. The OTC concentrations in medicated feed and skin-on fillets were determined with high-performance liquid chromatography methods. The maximum mean OTC concentration in fillet tissue was 932 ng/g, 1 day after the last treatment and decreased to 32 ng/g 19 days after the last treatment. The log-linear loss of OTC from the fillet tissue was biphasic with a terminal phase half-life of 4.9 days.

Aquaculture↗

USGS2019

Investigating lake-area dynamics across a permafrost-thaw spectrum using airborne electromagnetic surveys and remote sensing time-series data in Yukon Flats, Alaska

Lakes in boreal lowlands cycle carbon and supply an important source of freshwater for wildlife and migratory waterfowl. The abundance and distribution of these lakes are supported, in part, by permafrost distribution, which is subject to change. Relationships between permafrost thaw and lake dynamics remain poorly known in most boreal regions. Here, new airborne electromagnetic (AEM) data collected during June 2010 and February 2016 were used to constrain deep permafrost distribution. AEM data were coupled with Landsat-derived lake surface-area data from 1979 through 2011 to inform temporal lake behavior changes in the 35 500- km 2 Yukon Flats ecoregion of Alaska. Together, over 1500 km of AEM data, and roughly 30 years of Landsat data were used to explore processes that drive lake dynamics across a variety of permafrost thaw states not possible in studies conducted with satellite imagery or field measurements alone. Clustered time-series data identified lakes with similar temporal dynamics. Clusters possessed similarities in lake permanence (i.e. ephemeral versus perennial), subsurface permafrost distribution, and proximity to rivers and streams. Of the clustered lakes, ~66% are inferred to have at least intermittent connectivity with other surface-water features, ~19% are inferred to have shallow subsurface connectivity to other surface water features that served as a low-pass filter for hydroclimatic fluctuations, and ~15% appear to be isolated by surrounding permafrost (i.e. no connectivity). Integrated analysis of AEM and Landsat data reveals a progression from relatively synchronous lake dynamics among disconnected lakes in the most spatially continuous, thick permafrost to quite high spatiotemporal heterogeneity in lake behavior among variably-connected lakes in regions with notably less continuous permafrost. Variability can be explained by the preferential development of thawed permeable gravel pathways for lateral water redistribution in this area. The general spatial progression in permafrost thaw state and lake area behavior may be extended to the temporal dimension. However, extensive permafrost thaw, beyond what is currently observed, is expected to promote ubiquitous subsurface connectivity, eventually evolving to a state of increased lake synchronicity.

Alaska↗

USGS2013

Characterizing wave- and current- induced bottom shear stress: U.S. middle Atlantic continental shelf

Waves and currents create bottom shear stress, a force at the seabed that influences sediment texture distribution, micro-topography, habitat, and anthropogenic use. This paper presents a methodology for assessing the magnitude, variability, and driving mechanisms of bottom stress and resultant sediment mobility on regional scales using numerical model output. The analysis was applied to the Middle Atlantic Bight (MAB), off the U.S. East Coast, and identified a tidally-dominated shallow region with relatively high stress southeast of Massachusetts over Nantucket Shoals, where sediment mobility thresholds are exceeded over 50% of the time; a coastal band extending offshore to about 30 m water depth dominated by waves, where mobility occurs more than 20% of the time; and a quiescent low stress region southeast of Long Island, approximately coincident with an area of fine-grained sediments called the “Mud Patch”. The regional high in stress and mobility over Nantucket Shoals supports the hypothesis that fine grain sediment winnowed away in this region maintains the Mud Patch to the southwest. The analysis identified waves as the driving mechanism for stress throughout most of the MAB, excluding Nantucket Shoals and sheltered coastal bays where tides dominate; however, the relative dominance of low-frequency events varied regionally, and increased southward toward Cape Hatteras. The correlation between wave stress and local wind stress was lowest in the central MAB, indicating a relatively high contribution of swell to bottom stress in this area, rather than locally generated waves. Accurate prediction of the wave energy spectrum was critical to produce good estimates of bottom shear stress, which was sensitive to energy in the long period waves.

Continental Shelf Research↗

USGS1995

U.S. Geological Survey Subsidence Interest Group conference, Edwards Air Force Base, Antelope Valley, California, November 18-19, 1992; Abstracts and summary

Land subsidence, the loss of surface elevation as a result of the removal of subsurface support, affects every state in the United States. More than 17,000 mi 2 of land in the United States has been lowered by the various processes that produce land subsidence with annual costs from resulting flooding and structural damage that exceed $125 million. It is estimated that an additional $400 million is spent nationwide in attempts to control subsidence. Common causes of land subsidence include the removal of oil, gas, and water from underground reservoirs; dissolution of limestone aquifers (sinkholes); underground mining activities; drainage of organic soils; and hydrocompaction (the initial wetting of dry soils). Overdrafting of aquifers is the major cause of areally extensive land subsidence, and as ground-water pumping increases, land subsidence also will increase. Land subsidence and its effects on engineering structures have been recognized for centuries, but it was not until this century that the processes that produce land subsidence were identified and understood. In 1928, while working with field data from a test of the Dakota Sandstone aquifer, O.E. Meinzer of the U.S. Geological Survey recognized the compressibility of aquifers. Around the same time, Karl Terzaghi, a soil scientist working at Harvard University, developed the one-dimensional consolidation theory that provided a quantitative means of predicting soil compaction resulting from the drainage of compressible soils. Thus, with the recognition of the compressibility of aquifers (Meinzer), and the development of a quantitative means of predicting soil compaction as a consequence of the reduction of intergranular pore pressure (Terzaghi), the theory of aquifer-system compaction was formed. With the widespread availability of electric power in rural areas, and the advent of the deep turbine pump, ground-water withdrawals increased dramatically throughout the country in the 1940's and 1950's. Along with this unprecedented increase in pumpage, substantial amounts of land subsidence were observed in several areas of the United States, most notably in Arizona, California, and Texas. Beginning in 1955, under the direction of Joseph Poland, the Geological Survey began the "Mechanics of Aquifers Project," which focused largely on the processes that resulted in land subsidence due to the withdrawal of ground water. This research team gained international renown as they advanced the scientific understanding of aquifer mechanics and land-subsidence theory. The results of field studies by members of this research group not only verified the validity of the application of Terzaghi's consolidation theory to compressible aquifers, but they also provided definitions, methods of quantification, and confirmation of the interrelation among hydraulic head declines, aquifer-system compaction, and land subsidence. In addition to conducting pioneering research, this group also formed a "center of expertise," providing a focal point within the Geological Survey for the dissemination of technology and scientific understanding in aquifer mechanics. However, when the "Mechanics of Aquifers Project" was phased out in 1984, the focal point for technology transfer no longer existed. Interest among various state and local agencies in land subsidence has persisted, and the Geological Survey has continued to participate in a broad spectrum of cooperative and Federally funded projects in aquifer mechanics and land subsidence. These projects are designed to identify and monitor areas with the potential for land subsidence, to conduct basic research in the processes that control land subsidence and the development of earth fissures, as well as to develop new quantitative tools to predict aquifer-system deformation. In 1989 an ad hoc "Aquifer Mechanics and Subsidence Interest Group" (referred to herein as the "Subsidence Interest Group") was formed

California↗

USGS2002

Variability of suspended-sediment concentration at tidal to annual time scales in San Francisco Bay, USA

Singular spectrum analysis for time series with missing data (SSAM) was used to reconstruct components of a 6-yr time series of suspended-sediment concentration (SSC) from San Francisco Bay. Data were collected every 15 min and the time series contained missing values that primarily were due to sensor fouling. SSAM was applied in a sequential manner to calculate reconstructed components with time scales of variability that ranged from tidal to annual. Physical processes that controlled SSC and their contribution to the total variance of SSC were (1) diurnal, semidiurnal, and other higher frequency tidal constituents (24%), (2) semimonthly tidal cycles (21%), (3) monthly tidal cycles (19%), (4) semiannual tidal cycles (12%), and (5) annual pulses of sediment caused by freshwater inflow, deposition, and subsequent wind-wave resuspension (13%). Of the total variance 89% was explained and subtidal variability (65%) was greater than tidal variability (24%). Processes at subtidal time scales accounted for more variance of SSC than processes at tidal time scales because sediment accumulated in the water column and the supply of easily erodible bed sediment increased during periods of increased subtidal energy. This large range of time scales that each contained significant variability of SSC and associated contaminants can confound design of sampling programs and interpretation of resulting data.

Conference Paper↗

USGS2025

Shear surface undulations modulate clayey gouge strength and contribute to divergent landslide acceleration

Landslides display a spectrum of speeds for incompletely known reasons. Sliding occurs along slickensided undulatory shear surfaces within boundary shear gouge. Laboratory tests reveal that gouge shear strength generally decreases with finite cumulative displacement during relatively rapid failure and may increase or decrease with increasing shear rate; these behaviors can result in accelerating or decelerating landslide motion, which significantly affects consequent hazards. However, mechanisms responsible for such behaviors are poorly understood. We performed advanced ring shear strength testing that revealed such variable strength of a landslide near Oso, Washington, USA. We hypothesized that millimeter-scale undulations along shear surfaces caused the strength variability by imparting shear strength but while also modifying stresses that locally increase and decrease the typically considered particle-scale shear strength. We tested our hypotheses in the laboratory and with finite element soil deformation modeling. Lab results suggest that undulations contribute strength that decays with finite cumulative displacement. Modeling similarly reveals this, and that rapid shearing across undulations locally reduces effective normal stress by persistently elevating pore-water pressure and causing dilation. Consequent effects on strength differ by material with granular-rich, high-friction gouge losing strength and clay-rich, low-friction gouge losing little or gaining strength as shear rates increase. Ample testing by others reveals similar patterns. Hence, the propensity for gouge-controlled accelerating or decelerating failure may be estimated from simple index tests. Our findings on the effects of undulations reveal previously unknown mechanisms that may help to explain why some landslides reactivate catastrophically while others do not.

Washington↗

USGS2002

Structural analysis of geochemical samples by solid-state nuclear magnetic resonance spectrometry. Role of paramagnetic material

An examination of coals, coal tars, a fulvic acid, and soil fractions by solid-state 13C NMR spectrometry has demonstrated widely differing behavior regarding quantitative representation in the spectrum. Spin counting experiments on coal tars and the fulvic acid show that almost all the sample carbon is observed in both solution and solid-state NMR spectra. Similar experiments on two coals (a lignite and a bituminous coal) show that most (70-97%) of the carbon is observed; however, when the lignite is ion exchanged with 3% (w/w) Fe3+, the fraction of carbon observed drops to below 10%. In additional experiments signal intensity from soil samples is enhanced by a simple dithionite treatment. This is illustrated by 13C, 27Al, and 29Si solid-state NMR experiments on soil fractions.

Analytical Chemistry↗

USGS2024

Does the extent of glacial cover across watersheds and discharge periods affect dietary resource use of nearshore fishes in the Northern Gulf of Alaska?

Northern high-latitude glaciers impact nearshore marine ecosystems through the discharge of cold and fresh waters, including nutrients and organic matter. Fishes are important integrators of ecosystem processes and hold key positions in the transfer of energy to higher trophic positions in such systems. This study used a natural gradient in space and time, including watershed glacial cover (0–60%) of five adjacent estuaries and three sequential discharge periods (pre-peak, peak, post-peak) in the northern Gulf of Alaska (Kachemak Bay) to test whether differences in glacial cover of watersheds upstream of estuaries affect dietary resource use of nearshore fishes. Dietary resource use was assessed using stomach content and stable carbon and nitrogen isotope analyses to determine fish diet composition and trophic niche width. Crescent gunnel ( Pholis laeta ), a mostly sedentary species, was our focal species for comparisons across estuaries and discharge periods. Discharge period had a greater influence on diet composition and trophic niche width of crescent gunnels than watershed glacial coverage. Niche width of crescent gunnel was larger during the post-peak discharge period compared to pre-peak and peak periods, coincident with a shift in prey spectrum. However, watershed glacial cover was not a suitable predictor of niche width of crescent gunnel. Trophic resource use was also considered along this glacial cover gradient for two other fish species, Pacific staghorn sculpin ( Leptocottus armatus ) and starry flounder ( Platichthys stellatus ), but within the post-peak discharge period only. These species exploited a larger prey base compared to crescent gunnel, likely due to their greater mobility. Similar to crescent gunnel, there were no relationships in trophic niche width associated with watershed glacial coverage for these other species during the post-peak discharge period. Instead, trophic resource use of these three nearshore fish species was influenced by a more complex set of dynamic environmental variables (salinity, temperature, turbidity, and discharge), as well as static watershed characteristics, especially vegetation cover. Such drivers can act through changes in metabolic rates, modulating foraging strategies and trophic connectivity, as well as terrestrial nutrient delivery to support estuarine production. The environmental conditions associated with the glacially influenced estuaries during our study period (2020−2021) seemed within a range that allowed nearshore fishes to maintain energy pathways and prey bases across these estuaries, but it is unknown how these estuarine food webs may be influenced in years of extreme conditions such as during heat waves, droughts, or floods.

Alaska↗

USGS2011

Overview of the ARkStorm scenario

The U.S. Geological Survey, Multi Hazards Demonstration Project (MHDP) uses hazards science to improve resiliency of communities to natural disasters including earthquakes, tsunamis, wildfires, landslides, floods and coastal erosion. The project engages emergency planners, businesses, universities, government agencies, and others in preparing for major natural disasters. The project also helps to set research goals and provides decision-making information for loss reduction and improved resiliency. The first public product of the MHDP was the ShakeOut Earthquake Scenario published in May 2008. This detailed depiction of a hypothetical magnitude 7.8 earthquake on the San Andreas Fault in southern California served as the centerpiece of the largest earthquake drill in United States history, involving over 5,000 emergency responders and the participation of over 5.5 million citizens. This document summarizes the next major public project for MHDP, a winter storm scenario called ARkStorm (for Atmospheric River 1,000). Experts have designed a large, scientifically realistic meteorological event followed by an examination of the secondary hazards (for example, landslides and flooding), physical damages to the built environment, and social and economic consequences. The hypothetical storm depicted here would strike the U.S. West Coast and be similar to the intense California winter storms of 1861 and 1862 that left the central valley of California impassible. The storm is estimated to produce precipitation that in many places exceeds levels only experienced on average once every 500 to 1,000 years. Extensive flooding results. In many cases flooding overwhelms the state’s flood-protection system, which is typically designed to resist 100- to 200-year runoffs. The Central Valley experiences hypothetical flooding 300 miles long and 20 or more miles wide. Serious flooding also occurs in Orange County, Los Angeles County, San Diego, the San Francisco Bay area, and other coastal communities. Windspeeds in some places reach 125 miles per hour, hurricane-force winds. Across wider areas of the state, winds reach 60 miles per hour. Hundreds of landslides damage roads, highways, and homes. Property damage exceeds $ 300 billion, most from flooding. Demand surge (an increase in labor rates and other repair costs after major natural disasters) could increase property losses by 20 percent. Agricultural losses and other costs to repair lifelines, dewater (drain) flooded islands, and repair damage from landslides, brings the total direct property loss to nearly $ 400 billion, of which $ 20 to $ 30 billion would be recoverable through public and commercial insurance. Power, water, sewer, and other lifelines experience damage that takes weeks or months to restore. Flooding evacuation could involve 1.5 million residents in the inland region and delta counties. Business interruption costs reach $ 325 billion in addition to the $ 400 billion property repair costs, meaning that an ARkStorm could cost on the order of $ 725 billion, which is nearly 3 times the loss deemed to be realistic by the ShakeOut authors for a severe southern California earthquake, an event with roughly the same annual occurrence probability. The ARkStorm has several public policy implications: (1) An ARkStorm raises serious questions about the ability of existing federal, state, and local disaster planning to handle a disaster of this magnitude. (2) A core policy issue raised is whether to pay now to mitigate, or pay a lot more later for recovery. (3) Innovative financing solutions are likely to be needed to avoid fiscal crisis and adequately fund response and recovery costs from a similar, real, disaster. (4) Responders and government managers at all levels could be encouraged to conduct risk assessments, and devise the full spectrum of exercises, to exercise ability of their plans to address a similar event. (5) ARkStorm can be a reference point for application of Federal Emergency Management Agency (FEMA) and California Emergency Management Agency guidance connecting federal, state and local natural hazards mapping and mitigation planning under the National Flood Insurance Plan and Disaster Mitigation Act of 2000. (6) Common messages to educate the public about the risk of such an extreme disaster as the ARkStorm scenario could be developed and consistently communicated to facilitate policy formulation and transformation. These impacts were estimated by a team of 117 scientists, engineers, public-policy experts, insurance experts, and employees of the affected lifelines. In many aspects the ARkStorm produced new science, such as the model of coastal inundation. The products of the ARkStorm are intended for use by emergency planners, utility operators, policymakers, and others to inform preparedness plans and to enhance resiliency.

California↗

USGS1990

Paraquat Hazards to Fish, Wildlife, and Invertebrates: A Synoptic Review

Paraquat (1,1`dimethyl4,4`bipyridinium) are broad-spectrum contact plant killers and herbage desiccants that were introduced commercially during the past 25 years. Today, they rank among the most widely used herbicides globally and are frequently used in combination with other herbicides. The recommended paraquat field application rates for terrestrial weed control usually range between 0.28 and 1.12 kg/ha (0.25 and 1.0 lb/acre), and for aquatic weed control the range is 0.12.0 mg/l. Paraquat in surface soils generally photodecomposes in several weeks, but paraquat in subsurface soils and sediments may remain bound and biologically unavailablefor many years without significant degradation. Paraquat is not significantly accumulated by earthworms and other species of soil invertebrates and is usually excreted rapidly by higher animals; however, delayed toxic effects including death of birds and mammals are common. At concentrations below the recommended application rate, paraquat is embryotoxic to developing eggs of migratory waterfowl and adversely affects sensitive species of freshwater algae and macrophytes, larvae of crustaceans and frog tadpoles and carp. Sensitive species of birds are negatively affected at daily dose rates of 10 mg/kg body weight or when fed diets containing 20 mg/kg ration or drinking water containing 40 mg/l.

Contaminant Hazard Reviews↗