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Geology and beryl deposits of the Peerless pegmatite, Pennington County, South Dakota

The Peerless pegmatite, half a mile south of Keystone, Pennington County, S. Dak., has been a large source of scrap mica and beryl. Feldspar, amblygonite, tantalite-columbite, and cassiterite also have been recovered. The pegmatite is intrusive into Precambrian quartz-mica schist. Much of the schist contains staurolite and chlorite. Staurolite has been partly altered to mica, quartz, and chlorite, especially near pegmatite contacts. The pegmatite is generally discordant with the schist, but in many places secondary schistosity has been developed parallel to the contact. Tourmaline and muscovite, presumably introduced by pegmatitic solutions, are characteristic of the wall rock near discordant contacts. At the surface the pegmatite is tadpole-shaped and is 580 feet long and 360 feet wide. In cross-section the pegmatite has an anticlinal form that suggests control of the intrusion by fractures bearing N. 30°W. and dipping 45°NE. and SW. Dike-like apophyses extending from the main pegmatite have various attitudes. The Peerless pegmatite is a complex pegmatite consisting of seven zones, two replacement units, and two types of fracture-fillings. These are: Zone 1, quartz-muscovite-plagioclase pegmatite (border zone); Zone 2, albite-quartz-muscovite pegmatite (wall zone); Zone 3, cleavelandite-quartz-muscovite pegmatite (first intermediate zone); Zone 4, perthite-cleavelandite-quartz pegmatite (second intermediate zone); Zone 5, clevelandite-quartz pegmatite (third intermediate zone); Zones 6a and b, quartz-microcline pegmatite and quartz pegmatite (fourth intermediate zone); Zone 7, lithia mica-cleavelandite pegmatite (core); lithia mica-cleavelandite-quartz replacement unit; muscovite-cleavelandite replacement unit; quartz fracture-fillings; and tourmaline-quartz fracture-fillings. Zones 1 and 2 consist of alternating layers of different texture and mineralogy that are parallel to the contact. The layers contain differing proportions of quartz, plagioclase, muscovite, perthite, and accessory minerals. Sugary albite-quartz aggregates are important constituents of some layers. Layers of similar composition may occur two, three, or perhaps more times. The overall mineralogic composition of Zones 1 and 2 is similar to the composition of wall zones in many other Black Hills pegmatite, Zones 3 to 7 are in the normal sequence of zones in Black Hills pegmatites. The structural, textural, and mineralogic data confirm previously published evidence from other Black Hills pegmatites that indicates crystallization of a magma-like fluid from the wall inward. Repetition of layers in Zones 1 and 2 indicates changes in composition of the fluid at the crystallizing face. These changes may have been caused by addition of new material from below, by loss of material to the wall rocks, or by failure of convection to maintain equilibrium throughout the fluid in the pegmatite chamber. Zone 3 to 7 are in the normal sequence of zoned pegmatites that indicates crystallization from a restricted or nearly closed system. The lithia mica-cleavelandite replacement unit, which extends outward from the core, shows that in, the very late stages of crystallization a pneumatolytic or hydrothermal fluid escaped outward and replaced previously crystallized pegmatite. Accessory minerals of the pegmatite include tourmaline, beryl, apatite, amblygonite (variety, montebrasite), lithia mica, cassiterite, tantalite-columbite, garnet, spodumene, svanbergite, loellingite (?), vivianite (?), triploidite (?), dahllite, and vari-colored phosphate minerals of the lithiophilitetriphylite group and their alteration products. The chemical composition of the pegmatite has been determined by estimating the mineral, constitution of the various units and by calculating the tonnage of these units by use of successive geologic sections. The principal constituents are: SiO 2 (77.0 percent), Al 2 O 3 (13.7 percent), Na 2 O (5.0 percent), and K 2 O (1.7 percent). Chemical composition has also been determined for four subdivisions of the pegmatite: (A) Zones 1 and 2, (B) Zones 3 and 4, (C) Zone 5, and (D) Zones 6 and 7 and the replacement units. The content of Si0 2 increases and the content of Al 2 O 3 decreases from the outer pan of the pegmatite inward. Na 2 O forms only 0.4 percent of the inner subdivision (D), but 4 .7 to 6.5 percent of the other subdivisions. K 2 O forms 4.0 percent of subdivision (B), but only 0.7 to 1.3 percent of the other subdivisions. Zone 3, the principal minable unit, contains 1. 7 percent beryl and 28 percent scrap mica. Beryl also constitutes more than 1 percent of parts of the wall zone, especially albite-rich layers of the inner part of the unit in the upper part of the pegmatite. Beryl is a less important constituent of other units of the pegmatite. Potash feldspar is mined chiefly from Zone 4. Clevelandite that can be hand-cobbed and sold as soda-feldspar occurs in Zones 3, 4, and 5. Amblygomlte forms between 0.5 and 1.0 percent of Zone 5. Reserves of beryl, scrap mica, potash feldspar, and amblygonite are one to six times past production.

South Dakota

Radioactive deposits in California

Reconnaissance examination by Government geologists of many areas, mine properties, and prospects in California during the period between 1948 and 1953 has confirmed the presence of radioactive materials in place at more than 40 localities. Abnormal radioactivity at these localities is due to concentrations of primary and secondary uranium minerals, to radon gas, radium (?), and to thorium minerals. Of the known occurrences only three were thought to contain uranium oxide (uranitite or pitchblende), 4 contained uranium-bearing columbate, tantalate, or titanate minerals, 12 contained secondary uranium minerals, such as autunite, carnotite, and torbernite, one contained radon gas, 7 contained thorium minerals, and, at the remaining 16 localities, the source of the anomalous radiation was not positively determined. The occurrences in which uranium oxide has been tentatively identified include the Rathgeb mine (Calaveras County), the Yerih group of claims (San Bernardino County), and the Rainbow claim (Madera County). Occurrences of secondary uranium minerals are largely confined to the arid desert regions of south-eastern California including deposits in San Bernardino, Kern, Inyo, and Imperial Counties. Uranium-bearing columbate, tantalate, or titanate minerals have been reported from pegmatite and granitic rock in southeastern and eastern California. Thorium minerals have been found in vein deposits in eastern San Bernardino County and from pegmatites and granitic rocks in various parts of southeastern California; placer concentrations of thorium minerals are known from nearly all areas in the State that are underlain, in part, by plutonic crystalline rocks. The primary uranium minerals occur principally as minute accessory crystals in pegmatite or granitic rock, or with base-metal sulfide minerals in veins. Thorium minerals also occur as accessory crystals in pegmatite or granitic rock, in placer deposits derived from such rock, and, at Mountain Pass, in veins containing rare earths. Secondary uranium minerals have been found as fracture coatings and as disseminations in various types of wall rock, although they are largely confined to areas of Tertiary volcanic rocks. Probably the uranium in the uraniferous deposits in California is related genetically to felsic crystalline rocks and felsic volcanic rocks; the present distribution of the secondary uranium minerals has been controlled, in part, by circulating ground waters and probably, in part, by magmatic waters related to the Tertiary volcanic activity. The thorium minerals are genetically related to the intrusion of pegmatite and plutonic crystalline rocks. None of the known deposits of radioactive minerals in California contain marketable reserves of uranium or thorium ore under economic conditions existing in 1952. With a favorable local market small lots of uranium ore may be available in the following places: the Rosamund prospect, the Rafferty and Chilson properties, the Lucky Star claim, and the Yerih group. The commercial production of thorium minerals will be possible, in the near future, only if these minerals can be recovered cheaply as a byproduct either from the mining of rare earths minerals at Mountain Pass or as a byproduct of placer mining for gold.

California

Geology, of the High Climb Pegmatite, Custer County, South Dakota

The High Climb pegmatite, Custer County, S. Dak., belongs to the series of pegmatitic and granitic rocks that characterize the Harney Peak region of the southern Black Hills. It intrudes pre-Cambrian metamorphic rocks consisting chiefly of quartz-mica schist. The country rock has been altered to a tourmaline-rich schist along part of the pegmatite contact. The structure of the pegmatite, in general is concordant with the westward-dipping schistosity of the country rock, but locally the pegmatite is crosscutting. The main part of the pegmatite is an irregularly shaped pipe that plunges 45° N. 40° W., parallel to the average plunge of rolls in the foot wall. A small northern extension of the pegmatite has a lenticular shape and crosscuts the schist at a low angle. Rolls in this part of the pegmatite have an average plunge of 28° N. 25° W. One large, north-trending crestal roll divides the outcrop of the northern segment of the pegmatite into two parts. The pegmatite has a well- defined internal structure consisting of five zones. A fine-grained wall zone, consisting of albite-quartz pegmatite, and a medium-grained first intermediate zone, consisting of albite-quartz-muscovite pegmatite, form incomplete concentric shells. Perthite-quartz-albite pegmatite (second intermediate zone) forms a hood-shaped unit between the outer units and the third intermediate zone along the crest and hanging-wall of the pegmatite. A concentric shell of quartz-cleavelandite pegmatite (third intermediate zone) surrounds a lenticular core of quartz pegmatite that contains altered spodumene, in addition -to the five zones, a fracture-filling unit of quartz-perthite-muscovite-albite-pegmatite and a possible sixth zone (or replacement unit?) of very fine-grained muscovite pegmatite were recognized. The essential minerals of the pegmatite include microcline-perthite, quartz, albite, and muscovite. Accessory minerals include tourmaline, beryl, amblygonite (variety, montebrasite), apatite, columbite-tantalite, loellingite, altered spodumene, numerous unidentified dark-colored phosphate minerals, a manganese-bearing carbonate, garnet, and chalcopyrite. An explanation of the origin of the pegmatite requires fractional crystallization and incomplete reaction in a restricted system. The concentric zonal structure and the general increase in grain size from the wall zone to the core suggest that the pegmatite units crystallized in order from the walls inward, without any true replacement stages. Industrial minerals that have been produced at the High Climb pegmatite are beryl, amblygonite, potash feldspar, columbite-tantalite, scrap mica, and sheet mica.

South Dakota

Origin of the Chattanooga shale

Tonight I will try to present to you the chief facts we have observed that have a bearing on the old problem of how the black shales originated. Some of the ideas have been used before, and some are new. Some of those that have been used before, have been used to support arguments for both shallow and deep water, yet I shall use them again and try to show why our use of them in support of shallow water is justified, and the other fellow's use of them in support of deep water is not justified. These conclusions are strictly our own. Early in our studies we gave serious consideration to deep-water possibilities, but always we ran into such highly improbable circumstances and implications that we were forced to abandon them. The shallow-water theory seems to encounter no such formidable obstacles. We know of no facts that are incompatible with a shallow-water theory; we think that all known facts lend themselves to such an explanation; and we believe that a shallow-water explanation of these black shales is the simpler and sounder of the alternatives.

Trace Elements Investigations

Uranium-bearing coal and carbonaceous shale in La Ventana Mesa area, Sandoval County, New Mexico

Uranium-bearing coal, carboanceous shale, and carboaceous sandstone of Upper Cretaceous age occur on and adjacent to La Ventana Mesa, Sandoval County, New Mexico. The geologic features of the uranium deposits are described and a hypothesis for the origin and control of the uranium deposits are described and a hypothesis for the origin and control of the uranium deposits is given. On the basis of recent sampling and analyses the uranium content in coal is found to be as much as 0.62 percent, whereas the coal ash has a uranium content that is as much as 1.34 percent.

New Mexico