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220 records · Page 12Linked to original sources

Sensitivity of benthic biota and toxicity of cadmium, cobalt, copper, nickel, lead, and zinc mixtures in Washington, United States, and British Columbia, Canada

Relative sensitivities and responses of juvenile white sturgeon ( Acipenser transmontanus ), Hyalella azteca , two families of mayfly (Ephemerellidae, Heptageniidae), one family of caddisfly (Brachycentridae), and a natural community of benthic macroinvertebrates (BMI) to multiple metals are predicted using previously collected laboratory and field samples and a metal mixture model. Biological responses in single metal exposures are used to parameterize toxicity functions, which include accumulations of hydrogen and selected metals on biological receptors, intrinsic potencies of hydrogen and metals, sensitivities of organisms, and times of exposure. The model then is used to predict responses in multiple metal laboratory exposures and field-collected porewater. The following sensitivity sequence in porewater was determined based on endpoints of survival or total abundance: juvenile white sturgeon greater than (>) Ephemerellidae family > Hyalella azteca > Heptageniidae family about equal to (~) benthic macroinvertebrate community > Brachycentridae family. The fraction of porewater samples that are predicted to have adverse impacts on benthic biota (20-percent or greater negative response) depends on organism sensitivities and metal toxicities, and ranges from 44 to 48 percent for juvenile white sturgeon, 23 to 26 percent for the Ephemerellidae family, 16 to 22 percent for Hyalella azteca , 5 to 8 percent for the Heptageniidae family and BMI community, and 0 percent for the caddisfly family. The most toxic porewater in the upper Columbia River Basin (UCR) is at the backwater bar site at Deadmans Eddy and China Bend. The model also indicates that the element responsible for the most toxic conditions in UCR porewater is copper for all organisms, except Hyalella azteca and the metal-insensitive Brachycentridae family. Copper and lead result in the most toxic conditions for Hyalella azteca . This approach and results can aid in assessing metal toxicity and its potential risk to aquatic biota in ecosystems impacted by historical mining activities.

British Columbia, Washington

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida

Potentially toxic elements in wild Agassiz’s desert tortoises: Tissue concentrations and association with disease

Background: Desert tortoise ( Gopherus agassizii ) populations have continued to decline due to infectious and other diseases, predation, and habitat alteration. The potential contribution of minerals and heavy metals to tortoise health and susceptibility to disease remains uncertain. Objective: The objective of this study was to evaluate the results of elemental analysis of trace minerals and macrominerals in scute keratin, kidney, and liver tissue from ill and dying desert tortoises salvaged for necropsy between 1993 and 2000. Methods: Salvaged tortoises were categorized by age (adult, juvenile), geographic location, and primary disease based on necropsy findings. A subset of tortoises that were injured or killed by vehicular trauma or predation but with no notable pathologic abnormalities were used as controls. A panel of 21 trace minerals and 6 macrominerals was analyzed in scute keratin, kidney, and liver tissue samples by inductively-coupled plasma spectrometry and atomic absorption spectrophotometry. Results: Necropsies were done on 46 tortoises, including 9 juveniles salvaged from 5 regions in the Colorado and Mojave deserts of California. Primary diseases were cutaneous dyskeratosis (n=9), infection/ inflammation (n=8), malnutrition (n=7), mycoplasmosis (n=5), and urolithiasis (n=3); 14 tortoises were classified as controls. Concentrations of elements differed significantly by tissue, age, desert region, and disease (P < 0.05). Tortoises with cutaneous dyskeratosis had significantly higher Se concentrations, primarily in keratin and liver, than tortoises with other diseases (P < 0.001). Juveniles were more likely than adults to have high Pb, Sn, and Zn levels (P < 0.05). All tortoises had detectable levels of more than one potentially toxic heavy metal, including As, Cd, Cr, Hg, Ni, Pb, Sn and V. Conclusions: Potentially toxic elements are frequently found in tissue from tortoises in desert regions of California, with significantly higher concentrations in diseased tortoises. Metal exposure from soils, mining, historic and ongoing military activities, and other human activities could increase susceptibility to disease in desert tortoises.

California

Framework for implementing damping scaling factors in U.S. Geological Survey National Seismic Hazard Models

Traditionally, probabilistic seismic hazard analysis (PSHA) has focused on calculating ground motion hazard curves for elastic, 5%-damped pseudo spectral accelerations, Sa(T,5%), which are used as the basis for engineering design parameters and targets for ground motion selection and modification. However, structures and geotechnical systems can exhibit a wide range of damping ratios both above and below the 5% level, depending on the construction material, structural system, nonstructural elements, or subsurface soil properties. When spectral parameters at such damping levels are required for certain applications, 5%-damped accelerations have traditionally been extracted from PSHA-based hazard curves and adjusted outside of the hazard integral using damping scaling factors (DSF) such as those from Newmark & Hall (1982). Recent advances in the development of more rigorous and comprehensive damping scaling models (e.g., Rezaeian et al., 2014; Rezaeian et al., 2021) have allowed for the modeling of means and standard deviations of DSFs as functions of earthquake source and path properties for crustal, intraslab, and subduction interface tectonic environments. These DSF models can be applied to ground motion model (GMM) estimates of Sa(T,5%) for a given earthquake rupture scenario to produce a corresponding mean and standard deviation Sa at a specified damping ratio β, Sa(T,β). In this study, the DSF models of Rezaeian et al. (2014) and Rezaeian et al. (2021) are implemented within the U.S. Geological Survey National Seismic Hazard Model (NSHM) PSHA framework to calculate probabilistic hazard curves for spectral accelerations at damping ratios from 0.5% to 30%. The DSF models are applied directly to the mean and standard deviation of Sa(T,5%) predictions from each GMM in the NSHM logic tree. Resulting hazard curves and uniform hazard and risk spectra for Sa(T,β) are presented for several geographic locations and compared with corresponding spectra estimated using current design practices by applying the same DSFs outside of the PSHA calculation. Key differences between the two methods for estimating Sa(T,β) are discussed, and potential strategies are presented for the implementation and usage of the hazard-consistent Sa(T,β) in building codes. Comparing the results to those from DSFs used in current design practices that are mainly based on Newmark & Hall (1982) is not explored in this study.

Conference Paper

2025 USGS National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands: Overview of model and hazard results

The U.S. Geological Survey recently updated the National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI). The first version of the PRVI NSHM was released in 2003, and therefore this 2025 update includes over 20 years of new geologic, geophysical, and engineering data, methods, and models. Updates follow similar efforts performed in the recent 2023 50-state NSHM. However, this is the first NSHM in which we: (1) apply an inversion methodology to subduction interface fault sources in the earthquake rupture forecast (ERF) model; (2) develop scaled backbone median ground-motion models and independent aleatory variability models that are applied in the ground-motion characterization (GMC) model; and (3) calculate epistemic uncertainty related to alternative scenarios in the ERF and GMC models for all grid points in the study region. Long-term time-independent mean hazard calculations were performed for peak ground acceleration and 5%-damped pseudospectral acceleration at 21 spectral periods from 0.01- to 10.0-s, for eight National Earthquake Hazards Reduction Program site conditions ranging from V S30 = 150 to 1500 m/s, and for 2%, 5%, and 10% in 50-year probabilities of exceedance (return periods of 2475, 975, and 475 years, respectively). Epistemic uncertainty, in the form of selected percentiles, is also provided for a suite of test sites and all grid points in the study region for limited periods, site conditions, and probabilities of exceedance. Selected results, including comparisons with the 2003 PRVI NSHM, are shown and discussed for selected periods, site conditions, and probabilities of exceedance. When comparing the 2025 PRVI NSHM with the 2003 PRVI NSHM, hazard is generally higher at shorter periods and lower at longer periods, as a result of updates in both ERF and GMC models. The 2025 PRVI NSHM is applicable for return periods greater than ∼475 or less than ∼10,000 years.

Puerto Rico, U.S. Virgin Islands

Regional characterization of coal resources in the U.S. Gulf Coast

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The U.S. Gulf Coast and the Williston basins are the two major lignite-bearing basins within the country. Recent REE and CM studies of the lignite in these basins have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of the U.S. Gulf Coast lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from 31,181 drill holes and other data points. The estimated total coal resource in the Gulf Coast is about 83 billion metric tons in the upper 90 m (~ 300 ft) of the subsurface. Texas accounted for 40 percent (32 billion metric tons) of the total resource, followed by Mississippi (24 %, 20 billion metric tons), Louisiana (14 %, 12 billion metric tons), Tennessee (10 %, 8.5 billion metric tons), and Arkansas (6 %, 5.1 billion metric tons). The remaining states each accounted for less than 5 percent of the total resource. Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known state-wide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast and Williston Basin resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses. Coal-power electric generation has sharply decreased in past decades and mining of these coals for CM and REE could provide additional co-products such as activated carbon and other uses such as fertilizer (soil enhancer).

EarthArXiv

Structural analysis of brittle-plastic shear zones in the Sangre de Cristo Range, southern Colorado USA: Superposition of Rio Grande rift extension on Laramide contraction

The Sangre de Cristo Range in southern Colorado exposes some of the deepest Cenozoic structural levels in the Rocky Mountain region, including mylonitic shear zones associated with both the Laramide orogeny and Rio Grande rift. We investigated the relation between Laramide contraction and Rio Grande rift extension with detailed geologic mapping, kinematic analysis, and geochronometry in a 50 km 2 area centered on the Independence Mine shear zone (IMSZ). The 15−100-m-thick IMSZ is one of several shallowly to moderately (∼45° ± 20°) W-SW−dipping brittle-plastic shear zones along the western flank of the range. These shear zones display microstructural evidence of initiation as top-NE contractional mylonite zones, consistent with regional Laramide kinematics, which have been pervasively overprinted by shear fabrics indicating top-SW extensional reactivation. Both top-NE and top-SW shear fabrics involve cataclasis and quartz dislocation creep, although top-SW shear is more commonly localized along phyllosilicate-lined shear bands. Shear zones are hosted predominately within Proterozoic gneiss, and contain abundant chlorite and white mica derived from alteration of hornblende and feldspar, which indicates that weakening driven by fluid reactions played an important role in localizing strain. Extensional overprinting appears to be most pervasive along more steeply dipping portions of shear zones and where secondary phyllosilicates form an interconnected weak phase, which suggests that reactivation was primarily controlled by geometry and rheological contrasts inherited from contraction. One top-SW shear zone adjacent to the IMSZ cuts a late Oligocene gabbro stock, and monazite grains synkinematic with top-SW shear in the IMSZ yielded late Oligocene to Early Miocene U-Th-Pb dates that correspond with initiation of the Rio Grande rift. Reactivation of weak reverse faults may represent an important structural control during initial extension in the middle crust, prior to slip along the high-angle Sangre de Cristo normal fault system.

Colorado

Geochemistry and radiogenic isotopes constrain the mantle source region of the Mountain Pass Intrusive Suite, California

The Mountain Pass carbonatite stock is the largest rare earth element (REE) deposit and only active REE mine in the United States. The carbonatite intrusion and spatially associated alkaline silicate intrusions constitute the Mountain Pass Intrusive Suite, which is located within the Mojave Province in California. Both the carbonatite and the alkaline silicate rocks are enriched in large ion lithophile elements and light REEs, and less enriched to depleted in high field strength elements, indicating the mantle source region was metasomatically enriched in incompatible trace elements. The cause of this metasomatic mantle enrichment and the genetic relationship between the carbonatite and the alkaline silicate stocks are poorly understood. In this study, major and trace element geochemical data and isotopic (Rb-Sr, Sm-Nd, and Lu-Hf) data are presented to constrain genesis of the Mountain Pass Intrusive Suite, from mantle source region to the intrusion of the stocks. Our geochemical data are consistent with derivation of the alkaline silicate and carbonatite melts through partial melting from a shared mantle source region rather than through liquid immiscibility or fractional crystallization and separation of a carbothermal fluid. Although the Rb-Sr isotopic system in the Mountain Pass Intrusive Suite is disturbed at the whole-rock scale, the isotopic systems for whole-rock Sm-Nd (εNd i = ‐2.2 ± 0.8) and zircon Lu-Hf (εHf i = 0.1 ± 1.1) are robust and support mantle derivation of the magmas. Geochemical modeling using experimentally derived partition coefficients was used to identify possible causes of enrichment in incompatible elements through metasomatism in the mantle source region. Modeling of metasomatism by melts derived by partial melting of deeply subducted carbonated sediments approximates observed Mountain Pass Intrusive Suite trace element chemistry. Scattered εHf i in inherited zircon (2.8 ± 2.6) is consistent with derivation from an arc-related environment with substantial crustal contamination. Paleotectonic studies in the Mojave Province indicate that regional subduction preceded emplacement of the Mountain Pass Intrusive Suite by ∼300 Ma. Melting of the Mountain Pass source region may have been caused by post-collisional thermal relaxation and extension.

California

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Deep-ocean macrofaunal assemblages on ferromanganese and phosphorite-rich substrates in the Southern California Borderland

Mineral-rich hardgrounds, such as ferromanganese (FeMn) crusts and phosphorites, occur on seamounts and continental margins, gaining attention for their resource potential due to their enrichment in valuable metals in some regions. This study focuses on the Southern California Borderland (SCB), an area characterized by uneven and heterogeneous topography featuring FeMn crusts, phosphorites, basalt, and sedimentary rocks that occur at varying depths and are exposed to a range of oxygen concentrations. Due to its heterogeneity, this region serves as an optimal setting for investigating the relationship between mineral-rich hardgrounds and benthic fauna. This study characterizes the density, diversity, and community composition of macrofauna (>300 μm) on hardgrounds as a function of substrate type and environment (depth and oxygen ranges). Rocks and their macrofauna were sampled quantitatively using remotely operated vehicles (ROVs) during expeditions in 2020 and 2021 at depths above, within, and below the oxygen minimum zone (OMZ). A total of 3,555 macrofauna individuals were counted and 416 different morphospecies (excluding encrusting bryozoans and hydrozoans) were identified from 82 rocks at depths between 231 and 2,688 m. Average density for SCB macrofauna was 11.08 ± 0.87 ind. 200 cm −2 and mean Shannon-Wiener diversity per rock (H′ [loge] ) was 2.22 ± 0.07. A relationship was found between substrate type and macrofaunal communities. Phosphorite rocks had the highest H′ of the four substrates compared on a per-rock basis. However, when samples were pooled by substrate, FeMn crusts had the highest H′ and rarefaction diversity. Of all the environmental variables examined, water depth explained the largest variance in macrofaunal community composition. Macrofaunal density and diversity values were similar at sites within and outside the OMZ. This study is the first to analyze the macrofaunal communities of mineral-rich hardgrounds in the SCB, which support deep-ocean biodiversity by acting as specialized substrates for macrofaunal communities. Understanding the intricate relationships between macrofaunal assemblages and mineral-rich substrates may inform effects from environmental disruptions associated with deep-seabed mining or climate change. The findings contribute baseline information useful for effective conservation and management of the SCB and will support scientists in monitoring changes in these communities due to environmental disturbance or human impact in the future.

California

Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida

Three-dimensional temperature maps of the Williston Basin, USA: Implications for deep hot sedimentary and enhanced geothermal resources

As part of U.S. Geological Survey's (USGS) efforts to identify and assess geothermal energy resources of the US, a three-dimensional (3D) geologic and thermal model has been constructed for the Williston Basin, USA. The geologic model consists of all sedimentary units above the Proterozoic and Archean crystalline rock (called basement herein), with a total sedimentary thickness of up to 5 km near the basin center. Twenty-nine geologic units were mapped from interpreted formation tops from 16,465 wells. A 3D temperature model was constructed to a depth of 7 km by constructing a 3D heat flow model for the sedimentary units, followed by estimating underlying temperature using a one-dimensional (1D) analytic solution for heat flow within the underlying crystalline basement. Using the sedimentary basin model, heat flow was simulated in 3D and was calibrated using three temperature datasets: 1) 24 high-confidence static temperature logs (equilibrium thermal profiles), 2) more than15,000 drill stem test (DST) measurements from >7,000 wells, and 3) more than 45,000 bottomhole temperature (BHT) measurements from >14,000 wells. The DST and BHT datasets provide broad spatial coverage, but are lower confidence, primarily because measurements were made prior to attaining thermal equilibrium. DST and BHT measurements were binned regionally to develop representative thermal profiles that generally agree with these lower quality data (hereafter called pseudowell temperature profiles). Layer properties (primarily thermal conductivity and compaction curves) were set to best estimate values, then the heat flow model was calibrated to fit pseudowell and static temperature logs primarily by adjusting basal heat flow to approximate the overall temperature profile. Minor adjustments to thermal conductivity allowed adjusting changes in slope at lithologic contacts. Resulting maps include 3D temperature and basal (bottom of sedimentary units) heat flow estimates, which are used as input for the temperature model of the basement. The crystalline basement temperature model uses an analytic 1D solution to the heat flow equation that requires estimates of heat flow and temperature at the upper boundary (i.e., the sediment/basement contact), radiogenic heat production within the crystalline basement, and reference thermal conductivity (i.e., uncorrected for temperature). Two regions of high heat flow are identified: 1) in western North Dakota along the North American Central Plains Conductivity Anomaly and 2) in eastern Montana near the Poplar dome. Within the sedimentary column in the center of the basin of the basin, an area of approximately 100,000 km2 is predicted to have moderate- to high-temperature geothermal resources (>90 °C) under the thickest sequences of sediments. Where thick insulation and high heat flow coincide, electric-grade resources can be less than 4 km deep. Assuming a maximum feasible drilling depth of 7 km, temperatures are predicted to be as high as 175 °C. The geologic model may be used to identify strata at sufficient temperatures that may have natural permeability or that may have conditions that favor development of enhanced/engineered geothermal systems resources.

Montana, North Dakota, South Dakota

Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA

Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.

California

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Hydrogeologic conceptualization of the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory, Edwards Air Force Base, Antelope Valley, California, 2017–21

Research and testing within the Air Force Research Laboratory at Edwards Air Force Base in the southwestern Mojave Desert has been conducted since the 1950s. This testing requires large quantities of groundwater for cooling and operations involving hazardous constituents that have entered the groundwater. To better understand the potential movement of contaminants through the groundwater system, the U.S. Geological Survey entered into a cooperative agreement with the U.S. Air Force Civil Engineer Center with the purpose of (1) gaining a more detailed understanding of the hydraulic connection between the unconsolidated basin-fill sediment and the underlying weathered and crystalline bedrock and (2) investigating faults and their potential effect on groundwater flow. This study was specific to the Arroyos subarea and Northeast Air Force Research Laboratory subarea of the Air Force Research Laboratory. The refined hydrogeologic characterization was derived by evaluating surface geologic maps, a regional gravity model, new subsurface geophysical surveys, lithology data from boreholes, and groundwater-level data. Refinement of the hydrogeologic characterization of the study area involved developing a map of basin-fill sediment thickness, estimating the geometry and depth to bedrock, determining the presence of weathered bedrock material, and identifying the location of faults and subsurface structures. The thickness of basin-fill sediment was derived from a regional gravity model. Basin-fill sediment ranges from less than 20 feet (ft) thick to about 150 ft thick and increases substantially toward a deep structural basin in the northwestern part of the study area. The top of bedrock estimated from the new surface geophysical surveys is generally deeper than the top of bedrock from the regional gravity model. These differences in interpreted bedrock tops indicate that there may be a zone of weathered bedrock in the subsurface, overlying crystalline bedrock. Additional subsurface data evaluating the geometry and thickness of weathered bedrock are necessary for a comprehensive evaluation of weathered bedrock in the study area. Previously unmapped extensions of the Leuhman Fault, Spring Fault Zone, and Boron Gate Fault were identified in the new surface geophysical surveys. Evaluation of groundwater flow between bedrock and basin-fill sediment, and the effects of faults on groundwater flow, was done using groundwater-level data from 2020. The groundwater table was in crystalline bedrock throughout most of the Arroyos and Northeast Air Force Research Laboratory subareas, with a few exceptions where it was in basin-fill sediment and weathered bedrock. Basin-fill sediment, and likely weathered bedrock, was partially saturated in parts of the study area where basin-fill sediment was as thick as 150 ft. Weathered bedrock material may be present near the Spring Fault Zone, and if so, was likely saturated in 2020. The groundwater-level data near and within Spring Fault Zone indicate that the Spring Fault Zone acts as a vertical-along-strike conduit for, and as an across-strike impediment to, groundwater flow. In addition, steep groundwater-level gradients in the southeastern part of the study area indicate that a subsurface structure affecting groundwater flow could be related to the Leuhman Fault. Sufficient groundwater-level data were not available to conclusively determine if the Arroyos, Rich, and Boron Gate Faults, and their inferred extensions from the geophysical surveys, affect the movement or direction of groundwater flow.

California

Lunar grid systems, coordinate systems, and map projections for the Artemis missions and lunar surface navigation

Foreward This document contains design specifications of a navigational standard for the Moon, including a Lunar Transverse Mercator system, a Lunar Polar Stereographic system, a Lunar Grid Reference System, and a unique coordinate structure, Artemis Condensed Coordinates, for Artemis mission navigation and lunar surface science. The National Aeronautics and Space Administration (NASA) Artemis campaign seeks to place humans on the Moon for the first time since the Apollo missions. Early Artemis missions are heavily focused on the lunar south pole, which promises to return valuable data on the Moon’s geologic record, amongst other mission objectives. Coordinate systems in use today for the lunar south pole provides crew members on the surface neither an efficient nor intuitive means to communicate their position and orientation. A novel grid coordinate system, the Lunar Grid Reference System, is proposed to address these concerns for use in real-time extravehicular activity operations on the lunar surface. The many stakeholders involved in the Artemis missions will need a common system to communicate position and orientation while astronauts are operating on the lunar surface. To that end, Artemis crew members will need that system to be efficient and intuitive to promote efficient extravehicular activity timelines and reduce confusion. In the context of this document, these characteristics are addressed on the design of lunar coordinate systems: Efficient.—The number of characters required to communicate a location within a desired precision level in both local and global contexts, and how many steps are required for a recipient or sender to interpret a location. Intuitive.—How well the system aligns with human perceptual abilities, and whether the system yields distances that have the same relationship to actual lunar surface distance in all directions from the point where a person is located. Technological systems are currently being investigated to supplement the crew members’ ability to locate and orient themselves and other assets on the lunar surface; however, it is unlikely that those systems will be fully operational for the first few landed missions. Even with future positional aids, crew members will still need an efficient and intuitive means to communicate position and orientation. In addition, if technological systems fail, the crews will require land navigation skills and have maps available, thus providing further motivation for a crew-centric coordinate system. The contents of this U.S. Geological Survey (USGS) document detail a comprehensive framework for standardizing lunar crewed surface navigation within NASA and outlines the protocols, methods, and designs necessary for achieving consistency and interoperability across relevant space mission teams and lunar surface navigators. Key components of this document include designs of map projections, projected coordinate reference systems (Lunar Transverse Mercator and Lunar Polar Stereographic systems), and a grid system (Lunar Grid Reference System and Artemis Condensed Coordinates) for the Moon. The work proposed in this document seeks to accomplish something similar to the National Geospatial-Intelligence Agency (NGA) document SIG 0012 (NGA, 2014a), but for using grid systems for the Moon. This report incorporates initial feedback and input from NASA’s Artemis Geospatial Data Team, NASA’s Flight Operations Directorate, National Geodetic Survey, USGS Astrogeology Science Center, and NGA and is intended to serve as a resource for all involved with the Artemis missions, as well as for engineers designing and operating lunar infrastructure.

Techniques and Methods