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Evidence for major input of riverine organic matter into the ocean

The changes in the structure of XAD-8 isolated dissolved organic matter (DOM) samples along a river (Penobscot River) to estuary (Penobscot Bay) to ocean (across the Gulf of Maine) transect and from the Pacific Ocean were investigated using selective and two dimensional (2D) nuclear magnetic resonance (NMR) spectroscopy coupled with elemental and carbon isotope analysis. The results provide important insights into the nature of relatively stable structures in the river-to-ocean continuum and the enigma of the fate of terrestrial DOM in the marine system. First, lignin and carboxyl-rich alicyclic molecules (CRAMs), which are indistinguishable from mass spectrometry, were clearly differentiated with NMR spectroscopy. NMR unambiguously showed that CRAMs persisted along the river-to-ocean transect and in the Pacific Ocean, while lignin residues dramatically decreased in abundance from the river to the coastal ocean and the Pacific Ocean. The results challenge a previous conclusion that lignin-derived compounds are refractory and can accumulate in the coastal ocean. The loss of terrestrial plant-derived aromatic compounds such as lignin and tannin residues throughout the sequence of riverine, coastal, and open ocean DOM extracts could also partially explain the decreasing organic carbon recovery by XAD-8 isolation and the change in carbon stable isotope composition from riverine DOM (δ 13 C −27.6‰) to ocean DOM (δ 13 C −23.0‰) extracts. The observation, from advanced NMR, of similar CRAM molecules in XAD-8 isolated DOM samples from the Penobscot River to the Penobscot Bay and from the ocean refutes a previous conclusion that XAD-isolated DOM samples from seawater and river are distinctly different. The alicyclic structural features of CRAMs and their presence as the major structural units in DOM extracts from the Penobscot River to Gulf of Maine transect, together with the deduced old 14 C age of CRAMs in the ocean, imply that terrestrial CRAMs may persist on timescales long enough to be transported into the ocean.

Organic Geochemistry

Petroleum geology and resources of northeastern Mexico

Petroleum deposits (primarily gas) in northeastern Mexico occur in two main basins, the Tertiary Burgos basin and the Mesozoic Sabinas basin. About 90 gas fields are present in the Burgos basin, which has undergone active exploration for the past 30-40 years. Production in this basin is from Oligocene and Eocene nearshore marine and deltaic sandstone reservoirs. Most of the fields are small to medium in size on faulted anticlinal or domal structures, some of which may be related to deep-seated salt intrusion. Cumulative production from these fields is about 4 trillion cubic feet gas and 100 million barrels condensate and oil. Since 1975, about 10 gas fields, some with large production rates, have been discovered in Cretaceous carbonate and Jurassic sandstone reservoirs in the Sabinas basin and adjacent Burro-Picachos platform areas. The Sabinas basin, which is in the early stages of exploration and development, may have potential for very large gas reserves. The Sabinas basin is oriented northwesterly with a large number of elongate northwest- or west-trending asymmetric and overturned Laramide anticlines, most of which-are faulted. Some of the structures may be related to movement of Jurassic salt or gypsum. Lower Cretaceous and in some cases Jurassic rocks are exposed in the centers of the larger anticlines, and Upper Cretaceous rocks are exposed in much of the remainder of the basin. A thick section of Upper Cretaceous clastic rocks is partly exposed in tightly folded and thrust-faulted structures of the west-east oriented, deeply subsided Parras basin, which lies south of the Sabinas basin and north of the Sierra Madre Oriental fold and thrust belt south and west of Monterrey. The sedimentary cover of Cretaceous and Jurassic rocks in the Sabinas and Parras basins ranges from about 1,550 m (5,000 ft) to 9,000 m (30,000 ft) in thickness. Upper Jurassic rocks are composed of carbonate and dark organic shaly or sandy beds underlain by an unknown thickness of Late Jurassic and older redbed clastics and evaporites, including halite. Lower Cretaceous rocks are mainly platform carbonate and fine clastic beds with some evaporites (gypsum or anhydrite) deposited in two main rudist reef-bearing carbonate cycles. Upper Cretaceous rocks are mainly continental and marine clastic beds related to early development of the Laramide orogeny. This Upper Cretaceous sequence contains a marine shale and deltaic clastic complex as much as 6,000 m (20,000 ft) or more thick in the Parras basin, which grades northward and eastward to open marine, fine clastic beds. The Burgos basin, which is an extension of the Rio Grande embayment of the western Gulf of Mexico basin province, contains an eastward-thickening wedge of Tertiary continental and marine clastics. These beds are about 1,550 to 3,000 m (5,000-10,000 ft) thick in the outcrop belt on the west side of the basin and thicken to more than 16,000 m (50,000 ft) near the Gulf Coast.

Circular

Impact origin of the Avak Structure, Arctic Alaska, and genesis of the Barrow gas fields

Geophysical and subsurface geologic data suggest that the Avak structure, which underlies the Arctic Coastal Plain 12 km southeast of Barrow, Alaska, is a hypervelocity meteorite or comet impact structure. The structure is a roughly circular area of uplifted, chaotically deformed Upper Triassic to Lower Cretaceous sedimentary rocks 8 km in diameter that is bounded by a ring of anastomosing, inwardly dipping, listric normal faults 12 km in diameter. A zone of gently outward-dipping sedimentary country rocks forms a discontinuous ring of "rim anticlines" within the peripheral ring of normal faults. Beyond these anticlines, the sedimentary rocks are almost flat-lying. Basement consists of strongly deformed Ordovician and Silurian argillite. Density and acoustic impedance con rasts between the argillite and the overlying strata produce gravity and seismic-reflection signatures that define a ring of anticlines around the disturbed zone and a structural high surrounded by an annular structural low at its center. In the adjacent Barrow gas fields, the tops of the informally named Neocomian "pebble shale" unit and the gas-producing Lower Jurassic Barrow sand (local usage) lie at average subsea depths of 488 m and 670 m, respectively. In the Avak 1 well, drilled on the central high, the pebble shale and the Barrow sand lie near the surface, documenting more than 500 m of relative uplift at the high. The cores in this well have steep dips (30-90 degrees), mixed breccia with Franklinian argillite clasts 10 and 90 m above basement, quartz grains with shock mosaicism and multiple sets of shock lamellae, oriented concussion fractures in sand-size quartz grains, and shatter cones resembling those found in the peripheral zones of well-documented impact structures. In addition, above-background levels o fractured quartz grains in Barrow sand were found as far as 19 km beyond the rim of the Avak structure. Data concerning the age of the Avak structure are not definitive. If submarine landslide deposits in the upper part of the Aptian and Albian Torok Formation, in the subsurface 200 km to the east, were triggered by the Avak event, then the Avak meteorite struck a submerged marine shelf about 100 + or - 5 Ma. However, the impact features found at Avak (shatter cones, concussion fractures, shock lamellae and shock mosaicism in quartz grains, and widespread cataclasis) characterize the distal zones of meteorite impact structures. Fused rocks, plastic deformation, and shock-metamorphic minerals found in more proximal zones of impact structures are apparently missing. These observations, and the lack of Avak ejecta in cuttings and cores from the Torok Formation and Nanushuk Group (Albian to middle Cenomanian) in surrounding test wells, indicate that the impact event postdated these beds. In this case, the Avak meteorite struck a Late Cretaceous or Tertiary marine shelf or coastal plain between the Cenomanian (ca. 95 Ma), and deposition of the basal beds of the overlying late Pliocene and Quaternary Gubik Formation (ca. 3 Ma).

Alaska

Benthic habitats and offshore geological resources of Kaloko-Honokohau National Historical Park, Hawai‘i

Kaloko-Honokōhau National Historical Park (KAHO) is one of three National Park lands located along the western coast of the Island of Hawai‘i and the only one to include submerged lands and marine resources within its official boundaries. The park was established in 1978 and is 1,160 acres in size, including 596 acres of marine area. The submerged lands are currently managed by the State of Hawaii, Department of Land and Natural Resources, Division of Aquatic Resources (DLNR-DAR). Marine resources located within KAHO include coral reef and habitat for many marine animals, including the green sea turtle and a variety of fish and invertebrates. In addition, many archeological, cultural, and recreational resources are located within the marine realm of the park. Potential threats and stressors to the modern marine environment include ground-water and surface-water contamination, invasive plants and algae, fishing pressure and use of monofilament gill nets (which can ensnare marine life or become tangled on reefs and be left behind as fishing debris), and visitor use impacts, such as scuba diving and snorkeling. Illegal dumping, oil releases, boat groundings, and other physical damage to reef resources are potential threats from users of the nearby harbor. Special issues of concern for the park include establishing baseline conditions of the offshore resources before the development of adjacent coastal lands. Until this study, only a general knowledge of the distribution of benthic habitats and the characteristics of the offshore region of Kaloko-Honokōhau National Historical Park was available. In 2003, a collaborative project between the U.S. Geological Survey (USGS) Coastal and Marine Geology Program and the National Park Service (NPS) was initiated to develop detailed benthic-habitat classification maps for the marine lands within and adjacent to the park. The intent of this project is to provide baseline maps and a Geographic Information System (GIS) database and description of the biological and geological resources of these marine lands in order to facilitate the management, interpretation, and understanding of park resources. A benthic-habitat classification map was created for the park using existing color aerial photography, Scanning Hydrographic Operational Airborne Lidar Survey (SHOALS) bathymetric data, georeferenced underwater video, and still photography. Individual habitat polygons were classified using five basic attributes: (1) major structure or substrate, (2) dominant structure, (3) major biologic cover on the substrate, (4) percentage of major biological cover, and (5) geographic zone. Additional information regarding geology, morphology, and coral species were also noted. Marine resources located within KAHO include coral reef and habitat for many marine animals, including the green sea turtle and a variety of fish and invertebrates. In addition, many archeological, cultural, and recreational resources are located within the marine realm of the park. Potential threats and stressors to the modern marine environment include ground-water and surface-water contamination, invasive plants and algae, fishing pressure and use of monofilament gill nets (which can ensnare marine life or become tangled on reefs and be left behind as fishing debris), and visitor use impacts, such as scuba diving and snorkeling. Illegal dumping, oil releases, boat groundings, and other physical damage to reef resources are potential threats from users of the nearby harbor. Special issues of concern for the park include establishing baseline conditions of the offshore resources before the development of adjacent coastal lands. Until this study, only a general knowledge of the distribution of benthic habitats and the characteristics of the offshore region of Kaloko-Honokōhau National Historical Park was available. In 2003, a collaborative project between the U.S. Geological Survey (USGS) Coastal and Marine Geology Program and the National Park Service (NPS) was initiated to develop detailed benthic-habitat classification maps for the marine lands within and adjacent to the park. The intent of this project is to provide baseline maps and a Geographic Information System (GIS) database and description of the biological and geological resources of these marine lands in order to facilitate the management, interpretation, and understanding of park resources. A benthic-habitat classification map was created for the park using existing color aerial photography, Scanning Hydrographic Operational Airborne Lidar Survey (SHOALS) bathymetric data, georeferenced underwater video, and still photography. Individual habitat polygons were classified using five basic attributes: (1) major structure or substrate, (2) dominant structure, (3) major biologic cover on the substrate, (4) percentage of major biological cover, and (5) geographic zone. Additional information regarding geology, morphology, and coral species were also noted.

Hawai'i

Formation of vertical columnar seismic structures and seafloor depressions by groundwater discharge in the drowned Miami Terrace platform and overlying deep-water carbonates, southeastern Florida

The presence of vertical cross-formational fluid migration passageways within sedimentary basins can profoundly impact aquifer and reservoir fluid-flow and their identification is fundamental to informing management of subsurface fluid resources (groundwater, oil, gas). In an onshore and offshore southeastern part of Florida, 2D/3D seismic-reflection and bathymetry data document ∼153 vertical columnar structures composed of reflection disruptions up to 790 m in the height and averaging 360 m in diameter, and ∼219 subcircular to circular seafloor depressions up to 1334 m wide. Our study focuses on these features found within the offshore shallow-marine carbonate Miami Terrace platform, which drowned approximately at the end of the middle Miocene, and within overlying Plio-Quaternary deep-water carbonate slope and drift deposits. Most columnar structures are rooted in stratiform aquifers of the Miami Terrace platform and associated with faults or fault intersections produced by Eocene and circa late Miocene tectonics. The columns commonly terminate within the platform or as subcircular depressions along an amalgamated karstic and drowning unconformity at the platform top. The columns typically stretch upwards from a zone of deep karst cavity collapse through the Miami Terrace platform with upward decreasing sag on internal reflections. Following drowning and Plio-Quaternary partial burial of the Miami Terrace platform by deep-water deposits, the subcircular depressions and faults along the platform top were points of origin for a second phase of column growth upward into the deep-water deposits. The continuation of deep platform cavity collapse and column evolution produced pockmarks along paleo-seafloors within the deep-water deposits and at the present-day sea floor. The Plio-Quaternary pockmarks formed at water depths too deep to suggest an origin related to meteoric karst above or near sea level, but rather their formation is suggested to be related to cyclic sea level falls that drove increased groundwater head and density gradients, and seafloor discharge of offshore freshened groundwater sourced from the underlying platform. Plausibly, mixing of freshened groundwater and seawater at the seafloor discharge sites drove dissolution of the host deep-water deposits, which together with erosion by groundwater venting and current scouring formed the pockmarks. Seaward of the Plio-Quaternary seafloor pockmarks, at the late-middle Miocene upper slope of the Miami Terrace platform and along the regional karst/drowning unconformity is a slope-parallel band of ∼189 densely distributed subcircular seafloor depressions with diameters up to 1334 m at water depths up to ∼660 m. It is plausible that along the upper slope, faults and fractures produced by gravity-driven slope instability and possibly tectonics formed a dense network of fluid passageways that promoted upward artesian freshened groundwater flow to sites of discharge where mixing with seawater generated limestone dissolution and the depressions. But tectonic uplift may have forced emersion and initial meteoric sinkhole formation circa late Miocene with later enhancement by freshened groundwater discharge and bottom current erosion.

Florida

Photographs of the Upper Pleistocene section at Sankaty Head cliff, Nantucket Island, Massachusetts

The pre-Sangamonian and Wisconsinan glacial drift units and Sangamonian marine beds exposed tin the Sankaty Head cliff (fig. 1) constitute a unique and important upper Pleistocene stratigraphic section in southern New England. Many workers have studied the section over the past 130 years, paying most attention to the fossiliferous Sankaty Sand. The earliest study was by Desor and Cabot (1849) followed by Verrill (1875), Cushman (1904), Wilson (1906), and Gustavson (1976). Currently the section at the cliff is exposed as a result of erosion during a severe winter storm in 1978. The exposure allowed a detailed study of the selection and the results of the study are included in this report and three others (Oldale and others 1981; Oldale, 1981; and Oldale and others, in press). The last report discusses the stratigraphy, structure, absolute age, and paleontology of the deposits at Sankaty Head. The southern part of the Sankaty Head cliff, where the most complete marine section is, has been stable and obscured by dense vegetation over many of the past 130 years. In the future, the cliff face could again become stabilized and overgrown, or continued erosion could destroy some of the beds now exposed. These photographs provide a record of the cliff face, beds, and structures looked in 1979. Finally, the Sankaty Head section is realtively remote, and these photographs together with a geologic profile of the cliff shown by Oldale and others (1981) may substitute for field trips to the site, albeit a somewhat less satisfying experience.

Massachusetts

Role of a large marine protected area for conserving landscape attributes of sand habitats on Georges Bank (NW Atlantic)

Mobile fishing gear reduces seafloor habitat complexity through the removal of structure-building fauna, e.g. emergent organisms that create pits and burrows, as well as by smoothing of sedimentary bedforms (e.g. sand ripples). In this study, we compared the relative abundance of microhabitat features (the scale at which individual fish associate with seafloor habitat) inside and outside of a large fishery closed area (6917 km 2 ) on Georges Bank. Starting in late 1994, the closed area excluded all bottom tending fishing gear capable of capturing demersal fishes. A total of 32 stations were selected inside and outside of the closed area in sand habitats. Video and still photographic transects were conducted at each station using the Seabed Observation and Sampling System (SEABOSS). Seven common (i.e. featureless sand, rippled sand, sand with emergent fauna, bare gravelly sand, gravelly sand with attached-erect fauna, whole shell, shell fragment) and 2 rare (sponges, biogenic depressions) microhabitat types were compared separately. Results showed significant differences in the relative abundance of the shell fragment and sponge microhabitat types between fished and unfished areas. The lack of differences for the other microhabitats may indicate that the level of fishing activity in the area is matched by the system's ability to recover.

Georges Bank

Characterization of the biological, physical, and chemical properties of a toxic thin layer in a temperate marine system

The distribution of plankton in the ocean is patchy across a wide range of spatial and temporal scales. One type of oceanographic feature that exemplifies this patchiness is a ‘thin layer’. Thin layers are subsurface aggregations of plankton that range in vertical thickness from centimeters to a few meters, which may extend horizontally for kilometers and persist for days. We undertook a field campaign to characterize the biological, physical, and chemical properties of thin layers in Monterey Bay, California (USA), an area where these features can be persistent. The particle aggregates (marine snow) sampled in the study had several quantifiable properties indicating how the layer was formed and how its structure was maintained. Particles were more elongated above the layer, and then changed orientation angle and increased in size within the layer, suggesting passive accumulation of particles along a physical gradient. The shift in particle aggregate orientation angle near the pycnocline suggests that shear may also have played a role in generating the thin layer. Pseudo-nitzschia spp. were the most abundant phytoplankton within the thin layer. Further, both dissolved and particulate domoic acid were highest within the thin layer. We suggest that phosphate stress is responsible for the formation of Pseudo-nitzschia spp. aggregates. This stress together with increased nitrogen in the layer may lead to increased bloom toxicity in the subsurface blooms of Pseudo-nitzschia spp. Several zooplankton groups were observed to aggregate above and below the layer. With the knowledge that harmful algal bloom events can occur in subsurface thin layers, modified sampling methods to monitor for these hidden incubators could greatly improve the efficacy of early-warning systems designed to detect harmful algal blooms in coastal waters.

Marine Ecology Progress Series (MEPS)

Origin of the Nubian and similar sandstones

The Nubian Sandstone and similar sandstone bodies exposed across much of northern Africa and adjoining parts of Asia are characteristically formed of clean sand that is conspicuously cross stratified throughout. Such sandstone, here called Nubian-type sandstone, ranges from Cambrian through Cretaceous in age and its genesis has been interpreted in many ways. Studies of its primary structures, and of the direction of sand transport, based on statistical measurements of foreset dip directions, have contributed new data on its genesis. By far the most common structure in Nubian-type sandstone is a medium-scale planar-type cross stratification in which sets of evenly dipping cross beds are bounded by essentially flat-lying top and bottom surfaces to form tabular bodies. Other less numerous but typical structures are large-scale, truncated-wedge cross strata, trough-type cross strata, intraformational recumbent folds, small-scale ripple laminae, and dipping sets of tabular-planar cross beds. An analysis of these structures suggests that in the typical Nubian Sandstone of Cretaceous age eolian deposits are not represented and normal marine types probably also are lacking; flood plain, pond or lagoon, and other continental and marginal environments are indicated. In the Carboniferous rocks of Sinai Peninsula some beach sandstone and possibly some eolian, in addition to the types described, form part of the sequence. Direction of sand transport, as determined from cross-bed dips, was northerly in the Cretaceous Nubian of Libya, Sudan, and Egypt; easterly in the Jurassic Adigrat of Ethiopia; westerly in the Carboniferous of Sinai; northwesterly in the early Paleozoic of Jordan.

Geologische Rundschau

Acoustic measurements and modeling of sub-bottom layers on the summit of the Atlantis II Seamount

Sub-bottom profiler images taken from the summit plateau of the Atlantis II Seamount reveal distinct seabed stratigraphy, including marine sediment, limestone, and basalt layers. Acoustic reflection data also show arrivals reflecting from this sub-bottom structure. A wavenumber integration model with elastic geoacoustic properties is able to reproduce the arrival pattern of seabed reflections and particularly the phase inversion of the sub-bottom return. The reflection model suggests that the limestone layer is eroded with high porosity and possesses a lower compressional velocity than a well-cemented layer. The model results also highlight the necessity of incorporating elastic effects for realistic geoacoustic characterization.

JASA Express Letters

Mechanical and chemical compaction in fine-grained shallow-water limestones

Artificial compaction of in-situ cores of sediments resulted in: 1) reduction of sediment thickness by 50 percent and more; 2) reduction of initial porosities of 65 to 75 percent to 35 to 45 percent; 3) creation of megascopic textures almost identical to many ancient lime mud- and wackestone; 4) creation of organic, wispy "stylolite-like" layers; 5) chemical compaction, evidenced by thin sections showing quartz grains piercing mollusc shells without causing fractures and SEM evidence of solutional interfitting of 1 to 4-mu m-size aragonitic carbonate grains; 6) obliteration of pellets and birdseye or fenestral voids in those sediments where early cementation was lacking; obliteration of identifiable marine grasses and vertical "root" tube voids; 8) mashing of sediment-filled circular burrows to produce ellipsoidal structures. Significant mechanical compaction resulted from pressures simulating less than 1,000 ft of burial. Increasing loads to more than 10,000 ft did not significantly increase compaction. Chemical compaction was detected only in cores compacted to pressures greater than 10,000 ft of burial. These experiments suggest that chemical compaction would begin at much shallower depths given geologic time. Experiments that caused chemical compaction lend support to the hypothesis that cement required to produce a low-porosity/low-permeability fine-grained limestone is derived internally. Dissolution, ion diffusion, and reprecipitation are the most likely processes for creating significant thicknesses of dense limestones. Continuation of chemical compaction after significant porosity reduction necessitates expulsion of connate fluids, possibly including hydrocarbons.--Modified journal abstract.

Journal of Sedimentary Petrology

The southern Washington Cascades conductor: A previously unrecognized thick sedimentary sequence?

Geophysical studies in the southern Washington Cascades have outlined a possible, previously unrecognized sequence of sedimentary rocks. These postulated sedimentary units are interpreted to correspond to at least the upper section of a low-resistivity (high-conductivity) assemblage of rocks at depths of 1-10 km and with thicknesses up to 15 km that called the southern Washington Cascades conductor. Structure on the upper surface of this conductive assemblage correlates in some places with anticlines that bring Tertiary marine rocks near the surface. The geometry of the conductive rocks consists of a east-dipping, low-angle wedge that thickens to the north and with an undulating upper surface corresponding to the anticlines. Geothermal fluids may be a contributing factor to low resistivities in the deeper parts of the conductive section. -from Authors

Washington

Map showing distribution of small-scale deformation structures in a part of the upper coastal plain of South Carolina and adjacent Georgia

As a contribution to the assessment of neotectonics in the area of the Upper Coastal Plain of South Carolina, field traverses were made between Columbia, S.C., and Augusta, Ga., in 1975 and early 1976 in order to locate and describe small-scale deformation structures within exposed Coastal Plain rocks. The study covered most of the area between the Fall Line (northwest margin of the Coastal Plain) and the Orangeburg (Citronelle) escarpment (fig. 1). Fieldwork was done principally by vehicle along roads, but also included railroad cuts and excavation sites, such as quarries and landfills. Natural exposures are rare and provided no examples of deformation structures for this study. The geologic units exposed in the area are chiefly clastic sediments deposited in nearshore marine to continental environments. They include semi-consolidated sand, silt, clay, and rare thin impure limestone beds of Late Cretaceous to Eocene age (fig. 2). These sedimentary beds generally have a gentle regional dip to the southeast (Faye and Prowell, 1982, p. 6).

Georgia, South Carolina

Near-field receiving-water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in south San Francisco Bay, California—2020

Trace-metal concentrations in sediment and in the clam Limecola petalum (World Register of Marine Species, 2020; formerly reported as Macoma balthica and M. petalum ), clam reproductive activity, and benthic macroinvertebrate community structure were investigated in a mudflat 1 kilometer (km) south of the discharge of the Palo Alto Regional Water Quality Control Plant (PARWQCP) in south San Francisco Bay, California. This report includes the data collected by the U.S. Geological Survey (USGS) for January 2020–December 2020 (Cain and others, 2022). These data append to long-term datasets extending back to 1974. A major focus of the report is an integrated description of the 2020 data within the context of the longer, multidecadal dataset. This dataset supports the City of Palo Alto’s Near-Field Receiving- Water Monitoring Program, initiated in 1994. Silver and copper contamination substantially decreased at the site in the 1980s following the implementation by PARWQCP of advanced wastewater-treatment and source-control measures. Since the 1990s, concentrations of these elements in surface sediments have continued to decrease, although more slowly. For example, from 1994 to 2020, the minimum annual mean silver concentration—0.20 milligram per kilogram (mg/kg)—was observed in multiple years. In 2020, silver concentrations ranged from 0.18 to 0.28 mg/kg. These concentrations are 2 to 3 times higher than the regional background concentration. Presently (2020), sediment-copper concentrations appear to be near the regional background level. Over the same period (1994–2020), sedimentary iron and zinc exhibited modest decreases. Sedimentary aluminum, chromium, mercury, nickel, and selenium have not exhibited any trend. Since 1994, silver and copper concentrations in L. petalum have varied seasonally, apparently in response to a combination of site-specific metal exposures and cyclic growth and reproduction, as reported previously. Seasonal patterns for other elements, including chromium, mercury, nickel, selenium, and zinc, generally were similar in timing and magnitude as those for silver and copper. Downward trends in the silver and zinc concentrations in L. petalum during 1994–2020 were evident and appeared to be related to the general physiological condition of the clam, indicated by a condition index. Biological effects of elevated silver and copper contamination at the Palo Alto site have been interpreted from data collected during and after the recession of these contaminants. Concentrations of both elements in the soft tissues of L. petalum decreased with sedimentary copper and silver. This pattern was associated with changes in the reproductive activity of L. petalum , as well as the structure of the benthic invertebrate community. Reproductive activity of L. petalum increased as metal concentrations in L. petalum decreased (Hornberger and others, 2000), and presently is stable with almost all animals initiating reproduction in the fall and spawning the following spring. Analyses of the benthic community structure indicate that the infaunal invertebrate community has shifted from one dominated by several opportunistic species when silver and copper exposures were highest to one in which the species abundance is more evenly distributed, a pattern that indicates a more stable community that is subjected to fewer stressors. Importantly, this long-term change is unrelated to other metals and other measured environmental factors, including salinity and sediment composition. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes have shown a continual decrease in dominance coincident with the decrease in metals. Both species had short-lived rebounds in abundance in 2008, 2009, and 2010 and showed signs of increasing abundance in 2020. Heteromastus filiformis (a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying its eggs on or in the sediment) showed a concurrent increase in dominance and, in the last several years before 2008, showed a stable population. H. filiformis abundance increased slightly from 2011 to 2012 and returned to pre-2011 numbers in 2020. The reproductive mode of most species that were present in 2020 was indicative of species that were capable of movement either as pelagic larvae or as mobile adults. Although oviparous species were lower in number in this group, the authors hypothesize that these species will return slowly as more species move back into the area. The use of functional ecology was highlighted in the 2020 benthic community data, which showed that the animals that have now returned to the mudflat are those that can respond successfully to a physical, nontoxic disturbance. Today, community data show a mix of species that consume the sediment, or filter feed, those that have pelagic larvae that must survive landing on the sediment, and those that brood their young. The long-term recovery observed after the 1970s can be ascribed to the decrease in sediment pollutants.

California

The Cerrillos Uplift, the La Bajada Constriction, and Hydrogeologic Framework of the Santo Domingo Basin, Rio Grande Rift, New Mexico

The geologic, geophysical, and hydrogeologic properties of the La Bajada constriction and Santo Domingo Basin, northern New Mexico, result from tectonic and volcanic processes of the late Tertiary and Quaternary Rio Grande rift. An integrated geologic and geophysical assessment in the La Bajada constriction allows development of a geologic framework that can provide input for regional ground-water flow models. These models then can provide better estimates of future water supplies in a region that largely subsists on aquifers in Rio Grande rift basins. The combination of surface geologic investigations (stratigraphic and structural studies; chapters A, B, C, and E), airborne geophysics (aeromagnetic and time-domain electromagnetic surveys; chapters D and F), ground geophysical measurements (gravity and magnetotelluric surveys; chapters D and F), and data from the few wells in the area (chapter G) provides new constraints on the hydrogeologic framework of this area. Summary results of our investigations are synthesized in chapter G. Through-going aquifers consisting of ancestral Rio Grande axial-river sand and gravel and of coarse western-piedmont gravel form the predominant ground-water pathways through the partly buried structural trough defining the La Bajada constriction between Española and Santo Domingo Basins. Thick, clay-rich Cretaceous marine shales of low hydraulic conductivity form a pervasive regional confining unit within the Cerrillos uplift on the southeast flank of the constriction. Numerous, dominantly north-northwest-striking, intrabasin faults that project part way across the La Bajada constriction create a matrix of laterally and vertically variable hydrogeologic compartments that locally partition and deflect ground-water flow parallel to faults.

New Mexico

Quaternary geology of the Kenai Lowland and glacial history of the Cook Inlet region, Alaska

The Kenai Lowland is part of the Cook Inlet Lowland physiographic subprovince that borders Cook Inlet, a major marine reentrant along the Pacific Ocean coastline of south-central Alaska. The Cook Inlet Lowland occupies a structural trough underlain by rocks of Tertiary age and mantled by Quaternary deposits of varying thicknesses. The bordering high alpine mountains—the Aleutian and Alaska Ranges to the northwest and north and the Talkeetna, Chugach, and Kenai Mountains to the northeast and southeast—are underlain by rocks of Mesozoic and older ages.

Professional Paper

Energy-rich mesopelagic fishes revealed as a critical prey resource for a deep-diving predator using quantitative fatty acid signature analysis

Understanding the diet of deep-diving predators can provide essential insight to the trophic structure of the mesopelagic ecosystem. Comprehensive population-level diet estimates are exceptionally difficult to obtain for elusive marine predators due to the logistical challenges involved in observing their feeding behavior and collecting samples for traditional stomach content or fecal analyses. We used quantitative fatty acid signature analysis (QFASA) to estimate the diet composition of a wide-ranging mesopelagic predator, the northern elephant seal ( Mirounga angustirostris ), across five years. To implement QFASA, we first compiled a library of prey fatty acid (FA) profiles from the mesopelagic eastern North Pacific. Given the scarcity of a priori diet data for northern elephant seals, our prey library was necessarily large to encompass the range of potential prey in their foraging habitat. However, statistical constraints limit the number of prey species that can be included in the prey library to the number of dietary FAs in the analysis. Exceeding that limit could produce non-unique diet estimates (i.e., multiple diet estimates fit the data equally well). Consequently, we developed a novel ad-hoc method to identify which prey were unlikely to contribute to diet and could, therefore, be excluded from the final QFASA model. The model results suggest that seals predominantly consumed small mesopelagic fishes, including myctophids (lanternfishes) and bathylagids (deep sea smelts), while non-migrating mesopelagic squids comprised a third of their diet, substantially less than suggested by previous studies. Our results revealed that mesopelagic fishes, particularly energy-rich myctophids, were a critical prey resource, refuting the long-held view that elephant seals are squid specialists.

Frontiers in Marine Science

Suspected microbial-induced sedimentary structures (MISS) in Furongian (Upper Cambrian; Jiangshanian, Sunwaptan) strata of the Upper Mississippi Valley

The Furongian (Upper Cambrian; Jiangshanian and Sunwaptan) Tunnel City Group (Lone Rock Formation and Mazomanie Formation), exposed in Wisconsin and Minnesota, represents a shallow-marine clastic environment during a time of exceptionally high sea level. Lithofacies from shoreface to transitional-offshore settings document deposition in a wave- and storm-dominated sea. Flooding of the cratonic interior was associated with formation of a condensed section and the extensive development of microbial mats. Biolamination, mat fragments, wrinkle structures, and syneresis cracks are preserved in various sandstone facies of the Lone Rock Formation, as is evidence for the cohesive behavior of sand. These microbial-induced sedimentary structures (MISS) provide unique signals of biological–physical processes that physical structures alone cannot mimic. The MISS are associated with a trilobite extinction event in the Steptoean–Sunwaptan boundary interval. This may support recent claims that Phanerozoic microbial mats were opportunistic disaster forms that flourished during periods of faunal turnover. Further investigation of stratigraphic, taphonomic, and other potential biases, however, is needed to fully test this hypothesis.

Minnesota;Wisconsin