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Ground-water quality data in the middle Sacramento Valley study unit, 2006— Results from the California GAMA program

Ground-water quality in the approximately 3,340 mi 2 Middle Sacramento Valley study unit (MSACV) was investigated from June through September, 2006, as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) program. The GAMA Priority Basin Assessment project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Middle Sacramento Valley study was designed to provide a spatially unbiased assessment of raw ground-water quality within MSACV, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 108 wells in Butte, Colusa, Glenn, Sutter, Tehama, Yolo, and Yuba Counties. Seventy-one wells were selected using a randomized grid-based method to provide statistical representation of the study unit (grid wells), 15 wells were selected to evaluate changes in water chemistry along ground-water flow paths (flow-path wells), and 22 were shallow monitoring wells selected to assess the effects of rice agriculture, a major land use in the study unit, on ground-water chemistry (RICE wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], gasoline oxygenates and degradates, pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon), and dissolved noble gases also were measured to help identify the sources and ages of the sampled ground water. Quality-control samples (blanks, replicates, laboratory matrix spikes) were collected at approximately 10 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination was not a noticeable source of bias in the data for the ground-water samples. Differences between replicate samples were within acceptable ranges, indicating acceptably low variability. Matrix spike recoveries were within acceptable ranges for most constituents. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Comparisons between data collected for this study and drinking-water thresholds are for illustrative purposes only and are not indicative of compliance or noncompliance with regulatory thresholds. Most constituents that were detected in ground-water samples were found at concentrations below drinking-water thresholds. VOCs were detected in less than one-third and pesticides and pesticide degradates in just over one-half of the grid wells, and all detections of these constituents in samples from all wells of the MSACV study unit were below health-based thresholds. All detections of trace elements in samples from MSACV grid wells were below health-based thresholds, with the exceptions of arsenic and boron. Arsenic concentrations were above the USEPA maximum contaminant level (MCL-US) threshold in eight grid wells, and boron concentrations were above the CDPH notification level (NL-CA) in two grid wells. Arsenic was detected above the MCL-US in two flow-path wells. Arsenic, barium, boron, molybdenum, strontium, and vanadium were detected above health-based thresholds in a few of the RICE wells; these wells are not used to supply drinking water. All detections of radioactive constituents were below health-based thresholds, although six samples had activities of radon-222 above the lower proposed MCL-US threshold. Most of the samples from the MSACV wells had concentrations of major elements, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. Chloride and sulfate concentrations exceeded SMCL-CA thresholds in two and one grid well, respectively. Iron, manganese, and total dissolved solids concentrations were above the SMCL-CA thresholds in 1, 12, and 6 grid wells, respectively. Nitrate (nitrite plus nitrate, as dissolved nitrogen) concentrations from two grid wells were above the MCL-US threshold. There were no detections of microbial indicators in MSACV.

California

Shallow hydrogeologic framework of the Tully Valley mudboil area, Onondaga County, New York

Mudboils have been documented in the Tully Valley in southern Onondaga County, New York, since the late 1890s. Sediment-laden water from the mudboils flows into Onondaga Creek, which empties into Onondaga Lake at Syracuse 15 miles to the north. Turbidity from the mudboils has degraded the water quality of Onondaga Creek despite a series of mitigation efforts that began in the early 1990s. Turbidity mitigation actions presently (2025) being considered include creek relocation and offline sediment settling. In support of these proposed actions during 2021–23, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, U.S. Environmental Protection Agency, Onondaga Nation, Onondaga Environmental Institute, and Central New York Regional Planning and Development Board, collected and analyzed geologic, hydrologic, geophysical, and geotechnical data to characterize the shallow hydrogeology along four proposed creek-relocation paths and in the proposed offline settling basin area. The investigation indicated that the four proposed creek-relocation paths, two east of Onondaga Creek and two west of Onondaga Creek, are underlain by sediments including muck, alluvium, mudboil deposits, alluvial-fan sand and gravel, and lacustrine fines. The proposed excavations would penetrate partially to fully saturated conditions: generally, the water table is shallow near the creek and deep on the alluvial fans. The shallowest excavation, about 5 feet below land surface, would be near the creek and primarily in alluvium, and the deepest excavation, as much as 30 feet below land surface, would be in the alluvial-fan deposits. Brackish waters would be penetrated by proposed channel excavations on the eastern side of Onondaga Creek in an area downgradient from a potentially leaking historical salt-exploration borehole and near the main mudboil area. Excavation in these areas likely would provide a continuous source of brackish groundwater to the relocated creek. Proposed channel excavations of muck, soft to very soft lacustrine fines, and mudboil-type sediments in mudboil and suspected mudboil areas would pose an excavation and slope stability challenge and would have the greatest potential to create new mudboils. Proposed channel excavations below the water table on the Rattlesnake Gulf and Rainbow Creek alluvial fans would intercept groundwater and make the constructed streambank susceptible to seepage-induced slope instability. The substantial water-level fluctuation in the sediments of both alluvial fans would aggravate the stability condition. In addition, excavation on the Rattlesnake Gulf alluvial fan would have the potential to affect water-supply springs at the toe of the fan. The proposed offline settling basin area is in the northern part of the Rattlesnake Gulf alluvial fan. Natural and man-made diversions of Rattlesnake Gulf have resulted in saturated conditions in the general area of the proposed basin. The proposed offline settling basin would be excavated in, and berms would be constructed on, alluvial-fan deposits and lacustrine fines. In the proposed basin area, the alluvial deposits overlying the lacustrine fines are less than 10 feet thick. Excavation, berm construction, and loading of the saturated, soft to very soft lacustrine fines may be problematic and require soil strengthening.

New York

Variability in stream chemistry in relation to urban development and biological condition in seven metropolitan areas of the United States, 1999-2004

Beginning in 1999, the U.S. Geological Survey National Water Quality Assessment Program investigated the effects of urban development on stream ecosystems in nine metropolitan study areas across the United States. In seven of these study areas, stream-chemistry samples were collected every other month for 1 year at 6 to 10 sites. Within a study area, the sites collectively represented a gradient of urban development from minimally to highly developed watersheds, based on the percentage of urban land cover; depending on study area, the land cover before urban development was either forested or agricultural. The stream-chemistry factors measured in the samples were total nitrogen, total phosphorus, chloride, and pesticide toxicity. These data were used to characterize the stream-chemistry factors in four ways (hereafter referred to as characterizations)—seasonal high-flow value, seasonal low-flow value, the median value (representing a single integrated value of the factor over the year), and the standard deviation of values (representing the variation of the factor over the year). Aquatic macroinvertebrate communities were sampled at each site to infer the biological condition of the stream based on the relative sensitivity of the community to environmental stressors. A Spearman correlation analysis was used to evaluate relations between (1) urban development and each characterization of the stream-chemistry factors and (2) the biological condition of a stream and the different characterizations of chloride and pesticide toxicity. Overall, the study areas where the land cover before urban development was primarily forested had a greater number of moderate and strong relations compared with the study areas where the land cover before urban development was primarily agriculture; this was true when urban development was correlated with the stream-chemistry factors (except chloride) and when chloride and pesticide toxicity was correlated with the biological condition. Except for primarily phosphorus in two study areas, stream-chemistry factors generally increased with urban development, and among the different characterizations, the median value typically indicated the strongest relations. The variation in stream-chemistry factors throughout the year generally increased with urban development, indicating that water quality became less consistent as watersheds were developed. In study areas with high annual snow fall, the variation in chloride concentrations throughout the year was particularly strongly related to urban development, likely a result of road salt applications during the winter. The relations of the biological condition to chloride and pesticide toxicity were calculated irrespective of urban development, but the overall results indicated that the relations were still stronger in the study areas that had been forested before urban development. The weaker relations in the study areas that had been agricultural before urban development were likely the results of biological communities having been degraded from agricultural practices in the watersheds. Collectively, these results indicated that, compared with sampling a stream at a single point in time, sampling at regular intervals during a year may provide a more representative measure of water quality, especially in the areas of high urban development where water quality fluctuated more widely between samples. Furthermore, the use of "integrated" values of stream chemistry factors may be more appropriate when assessing relations to the biological condition of a stream because the taxa composition of a biological community typically reflects the water-quality conditions over time.

Scientific Investigations Report

Contaminants of emerging concern in the Great Lakes: Science to inform management practices for protecting the health and integrity of wildlife populations from adverse effects: GLRI action plan I, focus area 1, goal 5

Executive Summary: Under Action Plan I (2010-2014) of the Great Lakes Restoration Initiative (GLRI), Federal and Academic partners began an investigation of the presence and distribution of contaminants of emerging concern (CECs) in the Great Lakes and potential impacts on fish and wildlife. The term CECs is applied to a broad range of chemicals that are currently in use but for which we currently lack good understanding of whether fish, wildlife, or humans are being exposed and/or whether negative health or environmental effects are expected if exposure occurs. Pharmaceuticals, personal care products, flame retardants, many current use pesticides, and poly- and perfluorinated chemicals are some well-known groups of CECs, but there is no definitive or comprehensive list that can be used to support the management of CECs to reduce impacts on the Great Lakes ecosystem. Four overarching goals were identified for this collaborative investigation: 1. Evaluate the sources, occurrence, and distribution of CECs across the Great Lakes Basin. 2. Examine associations between the distribution of CECs and land-use patterns. 3. Review both scientific literature and field-generated data to determine the potential for CECs to cause adverse effects on Great Lakes fish and wildlife populations. 4. Develop efficient strategies to survey and/or monitor for threats that CECs may pose in order to take effective management actions before those threats evolve into large scale impacts on Great Lakes ecosystems or the services they provide. Achievement of these goals ensures progress towards Focus Area 1: Toxic Substances and Areas of Concern from GLRI Action Plan I, Goal 5: “ The health and integrity of wildlife populations and habitat are protected from adverse chemical and biological effects associated with the presence of toxic substances in the Great Lakes Basin ”. This large-scale research effort was comprised of individual and collaborative projects from multiple federal agencies and academic institutions, involving over 85 investigators, and overseen by the U.S. Environmental Protection Agency (EPA) Region 5, Great Lakes National Program Office. Partners include the United States Geological Survey, the National Oceanic and Atmospheric Administration, U.S. Fish and Wildlife Service, Saint Cloud State University, the U.S. EPA Office of Research and Development, and the U.S. Army Corps of Engineers. Key findings: 1. Contaminants of emerging concern were found throughout the monitored Great Lakes tributaries, but types and concentrations vary in association with regional land use. CECs were detected in nearly all samples collected. The type and concentration of the specific contaminants detected varied considerably among field sites and in association with land use type, such as urban, agricultural, wetland, 2 or forest. Contaminants were detected in the water column, sediment, and tissues of all species surveyed in the current work (mussels, aquatic insects, fish, and insect-eating birds). 2. There were over 20 contaminants for which CEC concentrations approached or exceeded those reported to cause toxicity in laboratory experiments. This was based on detection in water, sediments and or biota at one or more field sites. These contaminants represent compounds that warrant further investigation and monitoring with respect to potential impacts in certain areas of the Great Lakes basin. Based on the present investigation, compounds of greatest concern include: polycyclic aromatic hydrocarbons, associated with oil-based products and combustion of organic matter; atrazine, an herbicide; dichlorvos, an insecticide; and ibuprofen and venlafaxine, both pharmaceuticals. 3. Results suggest that mixtures of CECs presently found in most Great Lakes tributary locations surveyed may elicit subtle biological effects, but likely are not, alone, causing obvious detriment to current communities of fish and wildlife. CECs detected in the Great Lakes were associated with subtle biological effects like changes in gene expression, altered circulating glucose, etc. in both wild-caught and laboratory-reared organisms. These effects were generally not indicative of reproductive failure or mortality. However, the effects may have more serious implications when combined with other sources of stress like habitat degradation, changing climate conditions, and competition with invasive species. Due to limited historical data, it is unknown whether severe CEC-related impacts have already affected aquatic communities in waterbodies that have received long-term inputs of these contaminants. Likewise, under Action Plan I, biological effects were not necessarily evaluated at the sites where CEC concentrations exceeding laboratory toxicity thresholds were detected. As a result, strategic, ongoing surveillance and monitoring of CECs is warranted. This collaborative investigation resulted in new tools, approaches, and data that can be used to inform and support the management of CECs to reduce their impacts on Great Lakes natural resources. The following products of this research effort are available through https://communities.geoplatform.gov/glri/ or by contacting the investigators (see technical chapters found in Appendices A-F): 1. Database of CEC occurrence and concentrations in US tributary streams. The database includes CEC detections in water, sediment, and fish and wildlife tissues, and represents the most comprehensive survey of CECs in the Great Lakes Region. 2. Synopses of results and key findings. Integrated summaries of results, conclusions, and management implications of the CEC research are available through reports, topical fact sheets, and presentations. 3. Technical publications: This collaborative research effort has resulted in over 50 peer-reviewed publications, agency reports, and data releases that can be of use to resource managers, the scientific community, and members of the public. 4. Innovative tools. Innovative monitoring devices, sampling equipment, conceptual frameworks, and software applications were developed over the course of this 3 research. These tools are transferable to stakeholders via internet accessibility or via specifications, instructions, and demonstration detailed in technical publications. Hypotheses to guide CECs research under Action Plan II. Findings from 2010-2014 were used to guide further research in 2015-2018 for basin-wide surveillance of CECs and for sites warranting further study of potential biological impacts of CECs. Additional surveillance included both evaluation of additional classes of contaminants and expanded lists for chemical classes shown to be of greatest concern. Mixtures of some of the most frequently detected contaminants were also tested in laboratory studies to understand whether long term exposures to multiple contaminants may result in effects not evident from uncontrolled, short-term field experiments.

Great Lakes

Explainable machine learning improves interpretability in the predictive modeling of biological stream conditions in the Chesapeake Bay Watershed, USA

Anthropogenic alterations have resulted in widespread degradation of stream conditions. To aid in stream restoration and management, baseline estimates of conditions and improved explanation of factors driving their degradation are needed. We used random forests to model biological conditions using a benthic macroinvertebrate index of biotic integrity for small, non-tidal streams (upstream area ≤200 km 2 ) in the Chesapeake Bay watershed (CBW) of the mid-Atlantic coast of North America. We utilized several global and local model interpretation tools to improve average and site-specific model inferences, respectively. The model was used to predict condition for 95,867 individual catchments for eight periods (2001, 2004, 2006, 2008, 2011, 2013, 2016, 2019). Predicted conditions were classified as Poor, FairGood, or Uncertain to align with management needs and individual reach lengths and catchment areas were summed by condition class for the CBW for each period. Global permutation and local Shapley importance values indicated percent of forest, development, and agriculture in upstream catchments had strong impacts on predictions. Development and agriculture negatively influenced stream condition for model average (partial dependence [PD] and accumulated local effect [ALE] plots) and local (individual condition expectation and Shapley value plots) levels. Friedman's H-statistic indicated large overall interactions for these three land covers, and bivariate global plots (PD and ALE) supported interactions among agriculture and development. Total stream length and catchment area predicted in FairGood conditions decreased then increased over the 19-years (length/area: 66.6/65.4% in 2001, 66.3/65.2% in 2011, and 66.6/65.4% in 2019). Examination of individual catchment predictions between 2001 and 2019 showed those predicted to have the largest decreases in condition had large increases in development; whereas catchments predicted to exhibit the largest increases in condition showed moderate increases in forest cover. Use of global and local interpretative methods together with watershed-wide and individual catchment predictions support conservation practitioners that need to identify widespread and localized patterns, especially acknowledging that management actions typically take place at individual-reach scales.

Chesapeake Bay Watershed

Seed coating treatments alter emergence windows of native Intermountain West U.S. grasses under different regimes of water availability

Introduction Seed-based restoration is widely implemented to recover degraded lands but often fails. Seed enhancement technologies may improve outcomes by shifting emergence to target favorable climate windows and serving as a bet-hedging strategy against increasingly variable precipitation patterns. Objectives To test the potential benefit of these technologies, we applied seed coatings designed to accelerate or delay emergence to four native Intermountain West perennial grasses that are commonly used for restoration. Methods We subjected seeds to six different watering regimes in the greenhouse that represented variation in precipitation timing and amount and compared the emergence, growth, and biomass of coated and uncoated seedlings. Results Seed coating designed to accelerate germination strongly increased emergence in species with high dormancy requirements, while seed coating designed to delay germination decreased emergence in species with low dormancy by about half and postponed emergence by up to 15 days. These coatings altered emergence timing regardless of watering regime, suggesting that seed coating could expand emergence windows under variable precipitation regimes. Seedling growth and total biomass were less dependent on seed coating and were more driven by the average amount of soil moisture provisioned to the developing plant. While seed coating designed to accelerate germination increased the emergence of two grass species, growth decreased during late periods of water availability, suggesting a trade-off in seedling performance. Conclusions Our results show promise for seed coatings to shift windows of emergence, but further field testing could improve our understanding of their effects in restoration settings.

western United States

Concentrations of pesticides and pesticide degradates in the Croton River Watershed in southeastern New York, July-September 2000

Thirty-seven pesticides and (or) pesticide degradates were detected in baseflow samples collected from 47 stream sites in the Croton River Watershed (374 square miles) in southeastern New York in the summer of 2000. The Croton Reservoir provides about 10 percent of New York City's water supply. Maximum concentrations of most pesticides detected did not exceed 0.1 μg/L (micrograms per liter). This study, by the U.S. Geological Survey in cooperation with the New York State Department of Environmental Conservation, was conducted from July through September 2000 and entailed analysis of the samples for more than 150 pesticides and their degradates. Nine compounds were detected at a concentration greater than 0.10 μg/L; three of these were insecticides (diazinon, carbaryl, and imidacloprid), one was a fungicide (mycobutanil), and five were herbicides (simazine, 2,4-D, diuron, hexazinone, and 2,4-D methyl esther). Only two of these compounds (simazine and 2,4-D) were detected at a concentration exceeding 1 μg/L; the simazine concentration exceeded the New York State surface-water standard of 0.5 μg/L. Two insecticides (diazinon and azinphos-methyl) exceeded aquatic-life-protection standard in one sample each. Concentrations of three insecticides (chlorpyrifos, carbaryl, and malathion) were more than 50 percent of the aquatic-life-protection standards in one sample each. Total concentrations of insecticides and herbicides (the sum of the concentrations, whereby all concentrations below the detection limit were set to zero), and the concentrations of the herbicide prometon and the insecticide diazinon, were highest in samples from watersheds with population densities greater than 510 per square mile (21 sites); therefore, the presence of these compounds is attributable to urban, residential, and other developed land uses. The data obtained in this study are useful for making general comparisons among watersheds with differing land uses, but the concentrations represent baseflow conditions and, thus, are probably lower than the annual maximum concentrations in these streams. A July baseflow sample had total insecticide and fungicide concentrations of less than 0.03 μg/L, whereas a stormflow sample collected at the same site 2 weeks later had a corresponding concentration greater than 0.10 μg/L. Total herbicide concentrations for the July baseflow and stormflow samples were around 0.03 μg/L, but that for a stormflow sample collected at the same site 2 months later was greater than 20 μg/L.

Connecticut, New York

A conceptual framework for dryland aeolian sediment transport along the grassland–forest continuum: Effects of woody plant canopy cover and disturbance

Aeolian processes are of particular importance in dryland ecosystems where ground cover is inherently sparse because of limited precipitation. Dryland ecosystems include grassland, shrubland, savanna, woodland, and forest, and can be viewed collectively as a continuum of woody plant cover spanning from grasslands with no woody plant cover up to forests with nearly complete woody plant cover. Along this continuum, the spacing and shape of woody plants determine the spatial density of roughness elements, which directly affects aeolian sediment transport. Despite the extensiveness of dryland ecosystems, studies of aeolian sediment transport have generally focused on agricultural fields, deserts, or highly disturbed sites where rates of transport are likely to be greatest. Until recently, few measurements have been made of aeolian sediment transport over multiple wind events and across a variety of types of dryland ecosystems. To evaluate potential trends in aeolian sediment transport as a function of woody plant cover, estimates of aeolian sediment transport from recently published studies, in concert with rates from four additional locations (two grassland and two woodland sites), are reported here. The synthesis of these reports leads to the development of a new conceptual framework for aeolian sediment transport in dryland ecosystems along the grassland–forest continuum. The findings suggest that: (1) for relatively undisturbed ecosystems, shrublands have inherently greater aeolian sediment transport because of wake interference flow associated with intermediate levels of density and spacing of woody plants; and (2) for disturbed ecosystems, the upper bound for aeolian sediment transport decreases as a function of increasing amounts of woody plant cover because of the effects of the height and density of the canopy on airflow patterns and ground cover associated with woody plant cover. Consequently, aeolian sediment transport following disturbance spans the largest range of rates in grasslands and associated systems with no woody plants (e.g., agricultural fields), an intermediate range in shrublands, and a relatively small range in woodlands and forests. These trends are consistent with previous observations relating large rates of wind erosion to intermediate values for spatial density of roughness elements. The framework for aeolian sediment transport, which is also relevant to dust fluxes, wind erosion, and related aeolian processes, is applicable to a diverse suite of environmental challenges, including land degradation and desertification, dust storms, contaminant transport, and alterations of the hydrological cycle.

Geomorphology

The GFDL Earth System Model Version 4.1 (GFDL-ESM 4.1): Overall coupled model description and simulation characteristics

We describe the baseline coupled model configuration and simulation characteristics of GFDL's Earth System Model Version 4.1 (ESM4.1), which builds on component and coupled model developments at GFDL over 2013–2018 for coupled carbon-chemistry-climate simulation contributing to the sixth phase of the Coupled Model Intercomparison Project. In contrast with GFDL's CM4.0 development effort that focuses on ocean resolution for physical climate, ESM4.1 focuses on comprehensiveness of Earth system interactions. ESM4.1 features doubled horizontal resolution of both atmosphere (2° to 1°) and ocean (1° to 0.5°) relative to GFDL's previous-generation coupled ESM2-carbon and CM3-chemistry models. ESM4.1 brings together key representational advances in CM4.0 dynamics and physics along with those in aerosols and their precursor emissions, land ecosystem vegetation and canopy competition, and multiday fire; ocean ecological and biogeochemical interactions, comprehensive land-atmosphere-ocean cycling of CO 2 , dust and iron, and interactive ocean-atmosphere nitrogen cycling are described in detail across this volume of JAMES and presented here in terms of the overall coupling and resulting fidelity. ESM4.1 provides much improved fidelity in CO 2 and chemistry over ESM2 and CM3, captures most of CM4.0's baseline simulations characteristics, and notably improves on CM4.0 in (1) Southern Ocean mode and intermediate water ventilation, (2) Southern Ocean aerosols, and (3) reduced spurious ocean heat uptake. ESM4.1 has reduced transient and equilibrium climate sensitivity compared to CM4.0. Fidelity concerns include (1) moderate degradation in sea surface temperature biases, (2) degradation in aerosols in some regions, and (3) strong centennial scale climate modulation by Southern Ocean convection.

Journal of Advances in Modeling Earth Systems (JAM

Revolutionary land use change in the 21st century: Is (rangeland) science relevant?

Rapidly increasing demand for food, fiber, and fuel together with new technologies and the mobility of global capital are driving revolutionary changes in land use throughout the world. Efforts to increase land productivity include conversion of millions of hectares of rangelands to crop production, including many marginal lands with low resistance and resilience to degradation. Sustaining the productivity of these lands requires careful land use planning and innovative management systems. Historically, this responsibility has been left to agronomists and others with expertise in crop production. In this article, we argue that the revolutionary land use changes necessary to support national and global food security potentially make rangeland science more relevant now than ever. Maintaining and increasing relevance will require a revolutionary change in range science from a discipline that focuses on a particular land use or land cover to one that addresses the challenge of managing all lands that, at one time, were considered to be marginal for crop production. We propose four strategies to increase the relevance of rangeland science to global land management: 1) expand our awareness and understanding of local to global economic, social, and technological trends in order to anticipate and identify drivers and patterns of conversion; 2) emphasize empirical studies and modeling that anticipate the biophysical (ecosystem services) and societal consequences of large-scale changes in land cover and use; 3) significantly increase communication and collaboration with the disciplines and sectors of society currently responsible for managing the new land uses; and 4) develop and adopt a dynamic and flexible resilience-based land classification system and data-supported conceptual models (e.g., state-and-transition models) that represent all lands, regardless of use and the consequences of land conversion to various uses instead of changes in state or condition that are focused on a single land use.

Rangeland Ecology and Management

Hydrologic function of rapidly induced biocrusts

In dryland ecosystems, land degradation and erosion pose severe threats to ecosystem productivity and human wellbeing. Bio‐inoculation of degraded soils with native biological soil crusts ('biocrusts') is a promising yet relatively untested means to improve soil stability and hydrologic function (i.e. increase infiltration and reduce runoff). In a degraded semi‐arid grassland on the Colorado Plateau, we studied the establishment and hydrologic function (via simulated rainfall) of induced biocrusts grown with and without an organic soil stabilizer (psyllium, derived from Plantago sp. ) , after a period of four months. We found evidence of biocrust establishment, including significantly higher biocrust cover, chlorophyll a, and exopolysaccarides (EPS) in inoculated plots compared to controls. Plots inoculated with biocrust had higher runoff and sediment yields than controls during rainfall simulation. However, this effect was mitigated in plots where stabilizer was added, resulting in greater soil aggregate stability and higher levels of infiltration (reduced total runoff). The time to ponding was significantly greater than control for all inoculated plots, suggesting that induced biocrusts may be most effective at improving infiltration under low‐intensity, smaller precipitation events. Notably, the biocrusts in this study lacked the rough surface microtopography which is common in well‐developed biocrusts regionally and likely instrumental in slowing overland flow and increasing infiltration for larger rain events. These results highlight the temporal lag that may exist between apparent and functional restoration of biocrusts. In addition, the simultaneous additions of stabilizing amendments with biocrust inoculum may work collectively to achieve both short and long‐term restoration targets.

Ecohydrology

Assessing transportation infrastructure impacts on rangelands: test of a standard rangeland assessment protocol

Linear disturbances associated with on- and off-road vehicle use on rangelands has increased dramatically throughout the world in recent decades. This increase is due to a variety of factors including increased availability of all-terrain vehicles, infrastructure development (oil, gas, renewable energy, and ex-urban), and recreational activities. In addition to the direct impacts of road development, the presence and use of roads may alter resilience of adjoining areas through indirect effects such as altered site hydrologic and eolian processes, invasive seed dispersal, and sediment transport. There are few standardized methods for assessing impacts of transportation-related land-use activities on soils and vegetation in arid and semi-arid rangelands. Interpreting Indicators of Rangeland Health (IIRH) is an internationally accepted qualitative assessment that is applied widely to rangelands. We tested the sensitivity of IIRH to impacts of roads, trails, and pipelines on adjacent lands by surveying plots at three distances from these linear disturbances. We performed tests at 16 randomly selected sites in each of three ecosystems (Northern High Plains, Colorado Plateau, and Chihuahuan Desert) for a total of 208 evaluation plots. We also evaluated the repeatability of IIRH when applied to road-related disturbance gradients. Finally, we tested extent of correlations between IIRH plot attribute departure classes and trends in a suite of quantitative indicators. Results indicated that the IIRH technique is sensitive to direct and indirect impacts of transportation activities with greater departure from reference condition near disturbances than far from disturbances. Trends in degradation of ecological processes detected with qualitative assessments were highly correlated with quantitative data. Qualitative and quantitative assessments employed in this study can be used to assess impacts of transportation features at the plot scale. Through integration with remote sensing technologies, these methods could also potentially be used to assess cumulative impacts of transportation networks at the landscape scale.

Rangeland Ecology and Management

Identification of management thresholds of urban development in support of aquatic biodiversity conservation

Urbanization degrades stream ecosystems and causes loss of bodiversity. Using benthic macroinvertebrates as a surragate for overall aquatic diversity, we conducted a series of analytical approaches to derive management thresholds of urban development designed to link ecological responses to the primary management goal of protecting aquatic diversity in streams within the Delaware Water Gap National Recreation Area (USA). We were particularly interested in identifying urban thresholds that represent the early phases of biological impact to support cost-effect management and mitigation interventions. We used taxa-specific modeling approaches within a spatially-explicit framework to develop sensitive thresholds that anticipate and demark the onset of taxa loss and provide a foundation for investigating alternative mechanisms driving biological change. We identified an early-warning threshold of 1.5% urban development in the contributing watershed where 15% of the 107 taxa evaluated exhibited significant declines in abundance but prior to any evidence of extirpation, and an extirpation threshold of 6% urban development where nearly 3% of taxa are likely to be lost locally. These thresholds of urban development are substantially lower than response thresholds typically reported based upon traditional modeling approaches that rely on spatially-implicit summaries of land cover and univariate metrics or composite indices. An analysis of ecological and functional trait composition of taxa determined to be sensitive suggests that reduced storage of benthic organic matter caused by flashier hydrographs may be the primary mechanism driving biological changes observed at relatively low levels of urbanization. Although the extent to which stream communities respond to stressor gradients in a non-linear fashion continues to be debated, we show that threshold approaches can be applied in support of aquatic resource management irrespective of whether or not stress-response functions are non-linear.

New Jersey, Pennsylvania

Empirical evaluation of the conceptual model underpinning a regional aquatic long-term monitoring program using causal modelling

Conceptual models are an integral facet of long-term monitoring programs. Proposed linkages between drivers, stressors, and ecological indicators are identified within the conceptual model of most mandated programs. We empirically evaluate a conceptual model developed for a regional aquatic and riparian monitoring program using causal models (i.e., Bayesian path analysis). We assess whether data gathered for regional status and trend estimation can also provide insights on why a stream may deviate from reference conditions. We target the hypothesized causal pathways for how anthropogenic drivers of road density, percent grazing, and percent forest within a catchment affect instream biological condition. We found instream temperature and fine sediments in arid sites and only fine sediments in mesic sites accounted for a significant portion of the maximum possible variation explainable in biological condition among managed sites. However, the biological significance of the direct effects of anthropogenic drivers on instream temperature and fine sediments were minimal or not detected. Consequently, there was weak to no biological support for causal pathways related to anthropogenic drivers’ impact on biological condition. With weak biological and statistical effect sizes, ignoring environmental contextual variables and covariates that explain natural heterogeneity would have resulted in no evidence of human impacts on biological integrity in some instances. For programs targeting the effects of anthropogenic activities, it is imperative to identify both land use practices and mechanisms that have led to degraded conditions (i.e., moving beyond simple status and trend estimation). Our empirical evaluation of the conceptual model underpinning the long-term monitoring program provided an opportunity for learning and, consequently, we discuss survey design elements that require modification to achieve question driven monitoring, a necessary step in the practice of adaptive monitoring. We suspect our situation is not unique and many programs may suffer from the same inferential disconnect. Commonly, the survey design is optimized for robust estimates of regional status and trend detection and not necessarily to provide statistical inferences on the causal mechanisms outlined in the conceptual model, even though these relationships are typically used to justify and promote the long-term monitoring of a chosen ecological indicator. Our application demonstrates a process for empirical evaluation of conceptual models and exemplifies the need for such interim assessments in order for programs to evolve and persist.

California, Colorado, Idaho, Montana, Nevada, Oreg

The no-project alternative analysis: An early product of the Tahoe Decision Support System

We report on the development of a No-project alternative analysis (NPAA) or “business as usual” scenario with respect to a 20-year projection of 21 indicators of environmental and socioeconomic conditions in the Lake Tahoe Basin for the Tahoe Regional Planning Agency (TRPA). Our effort was inspired by earlier work that investigated the tradeoffs between an environmental and an economic objective. The NPAA study has implications for a longer term goal of building a Tahoe Decision Support System (TDSS) to assist the TRPA and other Basin agencies in assessing the outcomes of management strategies. The NPAA assumes no major deviations from current management practices or from recent environmental or societal trends and planned Environmental Improvement Program (EIP) projects. Quantitative “scenario generation” tools were constructed to simulate site-specific land uses, various population categories, and associated vehicle miles traveled. Projections of each indicator’s attainment status were made by building visual conceptual models of the relevant natural and social processes, extrapolating trends, and using available models, research, and expert opinion. We present results of the NPAA, projected indicator status, key factors affecting the indicators, indicator functionality, and knowledge gaps. One important result is that current management practices may slow the loss or degradation of environmental qualities but not halt or reverse it. Our analysis also predicts an increase in recreation and commuting into and within the basin, primarily in private vehicles. Private vehicles, which are a critical mechanism by which the Basin population affects the surrounding environment, are a key determinant of air-quality indicators, a source of particulate matter affecting Secchi depth, a source of noise, and a factor in recreational and scenic quality, largely owing to congestion. Key uncertainties in the NPAA include climate change, EIP project effectiveness, and external population, economic activity, and air pollution.

Lake Tahoe Basin

Can we avert an Amazon tipping point? The economic and environmental costs

The Amazon biome is being pushed by unsustainable economic drivers towards an ecological tipping point where restoration to its previous state may no longer be possible. This degradation is the result of self-reinforcing interactions between deforestation, climate change and fire. We assess the economic, natural capital and ecosystem services impacts and trade-offs of scenarios representing movement towards an Amazon tipping point and strategies to avert one using the Integrated Economic-Environmental Modeling (IEEM) Platform linked with spatial land use-land cover change and ecosystem services modeling (IEEM + ESM). Our approach provides the first approximation of the economic, natural capital and ecosystem services impacts of a tipping point, and evidence to build the economic case for strategies to avert it. For the five Amazon focal countries, namely, Brazil, Peru, Colombia, Bolivia and Ecuador, we find that a tipping point would create economic losses of US$256.6 billion in cumulative gross domestic product by 2050. Policies that would contribute to averting a tipping point, including strongly reducing deforestation, investing in intensifying agriculture in cleared lands, climate-adapted agriculture and improving fire management, would generate approximately US$339.3 billion in additional wealth and a return on investment of US$29.5 billion. Quantifying the costs, benefits and trade-offs of policies to avert a tipping point in a transparent and replicable manner can support the design of regional development strategies for the Amazon biome, build the business case for action and catalyze global cooperation and financing to enable policy implementation.

Amazon

Preface—Evaluating the response of critical zone processes to human impacts with sediment source fingerprinting

1) Background: Critical Zone Processes in the Anthropocene The Earth’s Critical Zone encompasses a suite of interconnected processes in the near-surface lithosphere, pedosphere, biosphere, atmosphere, and hydrosphere (Brantley et al., 2007; Lin, 2010) (Fig. 1). Processes and interactions both within and between these various Critical Zone components supports life-sustaining ecosystem services and resources that establish the foundation for humanity (NRC, 2001). This includes the formation production of fertile soils, flourishing vegetation, productive rivers, lakes and oceans, and our life-sustaining atmosphere (Gaillardet, 2014; Guo and Lin, 2016). Rapid population growth, land use intensification, and global environmental change are disturbing many of these fundamental Critical Zone processes. More than half of the Earth’s terrestrial surface is now impacted by anthropogenic activities (e.g., clearing, grazing, plowing, mining, and logging) (Hooke et al., 2012; Richter and Mobley, 2009). These changes are so widespread and pervasive that the great acceleration of socioeconomic development that occurred around 1950 (Fig. 2) has been recommended to delineate the dawn of the Anthropocene (Waters et al., 2016). Although the utility of adopting and delineating the Anthropocene as the current epoch is subject to debate (Crutzen, 2002; Ruddiman et al., 2015; Smith and Zeder, 2013), the concept effectively highlights both the nature and the extent of our global impact on Earth’s Critical Zone. Soil forming processes and ecosystem services provided by the pedosphere are central to the Critical Zone (Banwart et al., 2011; Lin, 2010). Many of these processes have been disturbed by the agricultural intensification that coincided with the great acceleration resulting in unsustainable land use practices now outpacing soil formation processes (Brantley et al., 2007). As agricultural landscapes now cover an area equivalent to what was scoured during the last glacial maximum (Amundson et al., 2007), the broad-scale intensification of anthropogenic activities has resulted in significant on- and off-site impacts. On-site, soil loss has resulted in decreases in soil fertility and agricultural yields (Ladha et al., 2009) threatening the ability to feed the world’s growing population (Brantley et al., 2007). Off-site, the excess delivery of particulate matter downstream is degrading riverine, lacustrine, and estuarine ecosystems (Bilotta and Brazier, 2008; Clark, 1985; Owens et al., 2005). The challenge, as noted by Brantley et al., (2007), is that despite our society having over 10,000 years of experience working with soils, our conceptual and quantitative models remain inadequate at predicting Critical Zone dynamics under current conditions. Notwithstanding growing pressure for improved environmental management, we still have a limited capacity to predict changes in the Critical Zone in response to anthropogenic activities owing to the multiple spatial and temporal scales at which these complex processes and feedbacks are manifest. As river basin systems are impacted by many of these processes, a deep understanding of soil-sediment continuum dynamics may provide a valuable framework for evaluating the disturbance response of Critical Zone processes. Understanding these processes may also provide land and resource managers with the information necessary to manage both the on-site and off-site effects of accelerated soil erosion.

Journal of Soils and Sediments

Groundwater-Quality Assessment, Pike County, Pennsylvania, 2007

Pike County, a 545 square-mile area in northeastern Pennsylvania, has experienced the largest relative population growth of any county in the state from 1990 to 2000 and its population is projected to grow substantially through 2025. This growing population may result in added dependence and stresses on water resources, including the potential to reduce the quantity and degrade the quality of groundwater and associated stream base flow with changing land use. Groundwater is the main source of drinking water in the county and is derived primarily from fractured-rock aquifers (shales, siltstones, and sandstones) and some unconsolidated glacial deposits that are recharged locally from precipitation. The principal land uses in the county as of 2005 were public, residential, agricultural, hunt club/private recreational, roads, and commercial. The public lands cover a third of the county and include national park, state park, and other state lands, much of which are forested. Individual on-site wells and wastewater disposal are common in many residential areas. In 2007, the U.S. Geological Survey, in cooperation with the Pike County Conservation District, began a study to provide current information on groundwater quality throughout the county that will be helpful for water-resource planning. The countywide reconnaissance assessment of groundwater quality documents current conditions with existing land uses and may serve as a baseline of groundwater quality for future comparison. Twenty wells were sampled in 2007 throughout Pike County to represent groundwater quality in the principal land uses (commercial, high-density and moderate-density residential with on-site wastewater disposal, residential in a sewered area, pre-development, and undeveloped) and geologic units (five fractured-rock aquifers and one glacial unconsolidated aquifer). Analyses selected for the groundwater samples were intended to identify naturally occurring constituents from the aquifer or constituents introduced by human activities that pose a health risk or otherwise were of concern in groundwater in the county. The analyses included major ions, nutrients, selected trace metals, volatile organic compounds (VOCs), selected organic wastewater compounds, gross alpha-particle and gross beta-particle activity, uranium, and radon-222. Analyses of the 20 samples were primarily for dissolved constituents, but six samples were analyzed for both dissolved and total metals. Results of the 2007 sampling indicated few water-quality problems, although concentrations of some constituents indicated influence of human activities on groundwater. No constituent analyzed exceeded any primary drinking-water standard or maximum contaminant level (MCL) established by the U.S. Environmental Protection Agency. Radon-222 levels were greater than, or equal to, the proposed MCL of 300 picocuries per liter (pCi/L) in water from 15 (75 percent) of the 20 wells. Radon-222 levels did not exceed the alternative MCL of 4,000 pCi/L in any groundwater sample. Radon-222 is naturally occurring, and the greatest concentrations (up to 2,650 pCi/L) were in water samples from wells in members of the Catskill Formation, a fractured-rock aquifer. The dissolved arsenic concentration of 3.9 micrograms per liter (ug/L) in one sample was greater than the health-advisory (HA) level of 2 ug/L but less than the MCL of 10 ug/L. Recommended or secondary maximum contaminant levels (SMCLs) were exceeded for pH, dissolved iron, and dissolved manganese. In six samples analyzed for dissolved and total concentrations of selected metals, total concentrations commonly were much greater than dissolved concentrations of iron, and to a lesser degree, for arsenic, lead, copper, and manganese. Concentrations of iron above the SMCL of 300 ug/L may be more widespread in the county for particulate iron than for dissolved iron. The total arsenic concentration in one of the six samples was greater than the HA level of

Scientific Investigations Report