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A spatiotemporal deep learning approach for predicting daily air-water temperature signal coupling and identification of key watershed physical parameters in a montane watershed

Seasonal shifts from runoff to groundwater dominance influence daily headwater stream temperatures, especially where local groundwater input is strong. This input buffers temperature during hot periods, supporting cold-water habitats. Recent studies use air–water temperature signal metrics to identify zones of strong stream–groundwater connectivity. While Previous studies used air–water signal ratios as proxies for groundwater influence but were limited to specific sites and periods, without dynamic forecasting. This study is the first to forecast daily A r as a spatiotemporal signal using a Graph Convolutional Network–Long Short-Term Memory (GCN-LSTM) model. The model was trained using hydroclimate data (air temperature, precipitation, shortwave radiation, streamflow) and watershed physical features (e.g., sand content, slope). Results showed high predictive skill, achieving R 2 (NSE, RMSE) of 0.86 (0.73, 0.0004) for one-day-ahead to 0.52 (0.50, 0.0009) for seven-days ahead forecasts. Prior studies often have not explicitly incorporated spatial hydrogeologic drivers, but this model explicitly incorporates them to assess their impact on A r forecasting and stream-groundwater connectivity. Feature analysis identified mean sand, elevation, slope, clay, and TWI as key predictors of A r . Stronger groundwater signals appeared in hillslopes, elevations, and tributaries, highlighting watershed influence on streamflow. However, limitations include reliance on historical air–water temperature patterns for training and limited representation of extreme climate conditions. Despite these limitations, unlike previous studies relying on measured in-situ stream and air temperature, this study forecasts A r directly from climate and physiographic features after training, avoiding in-situ data requirements. Findings aiding predictions of stream ecosystem resilience.

New York

Detrital zircons and the magmatic history of Viti Levu, Fiji

We integrate the existing detrital zircon data from multiple modern river sediment samples on Viti Levu, Fiji, with the most current available geological and topographic mapping of the respective river drainage basins to compare detrital populations with potential bedrock sources. The temporal and spatial variations in zircon geochemistry supplement what is known from igneous rocks and confirm the petrological differences between plutonic and volcanic rocks from the Eocene to early Oligocene (Yavuna age, >30 Ma), middle Oligocene to middle Miocene (Wainimala age, 30–12.5 Ma), late Miocene (Colo age, 12.5–6.5 Ma) and latest Miocene (Namosi age, 6.5–5 Ma). The >30 Ma Yavuna-age zircons are restricted to areas that drain the previously mapped Yavuna Group. The 30–12.5 Ma zircons are found across central Viti Levu from west to east, and the 30–15 Ma zircons have distinctively low U/Yb and high Dy/Yb ratios. They are the best radiometric evidence of widespread early to middle Miocene arc magmatism in Fiji that was relatively U-poor. Peak deconvolution of the Colo age zircons from individual basins suggests the following ages for undated or poorly dated plutons from central Viti Levu. The large Mavuvu pluton is probably composed of multiple intrusions in the 12–10 Ma range, the Waiqa pluton is probably ca 10 Ma, and the Noikoro pluton is probably ca 9 Ma. There are zircons from unknown plutonic or volcanic sources between 8 and 7 Ma in western Viti Levu that have distinct Eu/Eu* ratios. We attribute the highest U/Yb ratios in some Colo age zircons to crustal anatexis. Namosi-age zircons are abundant in the Medrausucu Group and can be found scattered across Viti Levu.

Viti Levu

Upper Triassic igneous rocks of the southern Kenai Peninsula, Alaska – Prelude to Early Jurassic subduction along the western Wrangellia composite terrane margin

New U–Pb zircon geochronology identifies a latest Triassic (ca 214–201 Ma) igneous suite of tuff, hypabyssal dikes, and a pluton on the southern Kenai Peninsula, Alaska. The igneous suite was emplaced within Upper Triassic sedimentary rocks along the southern margin of Western Wrangellia, the western-most fragment of the Wrangellia composite terrane. The igneous rocks range from mafic (50.6% SiO 2 ) to felsic (78.3% SiO 2 ), characteristically have less than 1.55% K 2 O, and generally have low trace element abundances. The tonalitic and trondhjemitic magmas were largely sourced in mafic-rich lower crust and incompletely assimilated quartz and other mineral xenocrysts are common. Fractionation involving plagioclase and amphibole is indicated for some magmas and composite intrusions and igneous xenoliths indicate magma mixing was possible. Paleozoic and Precambrian inherited zircons and initial 87 Sr/ 86 Sr (0.704103–0.705609) and 143 Nd/ 144 Nd (0.512396–0.512777) ratios indicate that the Western Wrangellia crustal sources are heterogeneous and contain sialic components. The latest Triassic magmatism reflects processes that preceded Early Jurassic subduction along the Wrangellia composite terrane and Pacific Ocean plate boundary. These processes involved heating and melting of mantle lithosphere and lower crust as mantle instabilities accompanied the breaking of the plate boundary linkages. The Late Triassic transition to subduction along the Wrangellia composite terrane margin coincided with the transition to subduction cessation in the Late Triassic arcs of the western Intermontane terranes of Canada. The shift to subduction along the outboard Wrangellia composite terrane margin marks the beginning of the Pacific Ocean–Cordillera plate interactions that came to dominate the tectonic evolution of the northern Cordillera from the Early Jurassic to today.

Alaska

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio

Northern bobwhites select for native grasses on working grazing land

Northern bobwhite ( Colinus virginianus ; bobwhite) populations have experienced an 85% decline across most of its range since the 1960s. The most drastic decreases have been in the southeastern United States where biologists attribute the decline to widespread habitat loss, including conversion of native grasslands to tall fescue ( Lolium arundinaceum ) and other exotic cool-season grass (CSG) pasture and hayfields. Including agricultural lands in conservation programs could improve habitat conditions on a regional scale. One working-lands conservation strategy involves the use of native warm-season grasses (NWSGs) rather than cool-season exotic grasses as economically viable cattle forage. To evaluate this management practice for creating bobwhite habitat, we conducted a field study on a bobwhite population in eastern Kentucky, USA, where grazed NWSG and burned NWSG fields were adjacent to exotic grazed and exotic hayed CSG fields. Between April 2019 and October 2022, we used radio telemetry to track bobwhites to evaluate resource selection at second- and third-order scales. Bobwhites used traditionally managed CSGs less than would be expected by chance at the second-order scale in both breeding and non-breeding seasons. Bobwhite use of grazed NWSG and burned NWSG was greater than would be expected by chance at the second-order scale in both breeding and non-breeding seasons. Similarly, at the third-order scale, bobwhites used CSGs less than would be expected by chance, whereas NWSGs and woody stems were used more than by chance alone. Our study suggests that bobwhites select NWSGs at multiple spatial scales despite broad-scale availability of managed exotic CSGs. Under a working-lands framework, the integration of NWSGs into working lands could create bobwhite habitat in the southeastern United States, especially if woody stems are present.

Kentucky

Deformation by pressure solution and grain boundary sliding in a retrograde shear zone in southern New England, USA

Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by 40 Ar/ 39 Ar dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

Connecticut

Following the tug of the audience from complex to simplified hazards maps at Cascade Range volcanoes

Volcano-hazard maps are broadly recognized as important tools for forecasting and managing volcanic crises and for disseminating spatial information to authorities and people at risk. As scientists, we might presume that hazards maps can be developed at the time and with the methods of our discretion, yet the co-production of maps with stakeholder groups, who have programmatic needs of their own, can sway the timing, usability, and acceptance of map products. We examine two volcano hazard map-making efforts by staff at the U.S. Geological Survey. During the 1990s and early 2000s scientists developed a series of hazard assessments and maps with detailed zonations for volcanoes in Washington and Oregon. In 2009, the National Park Service expressed the need for simplified versions of the existing hazard maps for a high-profile visitor center exhibit. This request created an opportunity for scientists to rethink the objectives, scope, content, and map representations of hazards. The primary focus of this article is a discussion of processes used by scientists to distill the most critical information within the official parent maps into a series of simplified maps using criteria specified. We contextualize this project with information about development of the parent maps, public response to the simplified hazard maps, the value of user engagement in mapmaking, and with reference to the abundance of guidance available to the next generation of hazard-mapmakers. We argue that simplified versions of maps should be developed in tandem with any hazard maps that contain technical complexities, not as a replacement, but as a mechanism to broaden awareness of hazards. We found that when scientists endeavor to design vivid and easy-to-understand maps, people in many professions find uses for them within their organization’s information products, resulting in extensive distribution.

Washington

The petrogenesis of Þingmúli volcano, East Fjords, Iceland

In this work we revisit Þingmúli volcano (Þ = Th), a classic locality known as an example of a complete tholeiitic differentiation. Þingmúli is a ~ 9.5 Ma extinct central volcano located in the East Fjords of Iceland, in which the whole compositional spectrum from basalt to rhyolites have erupted. These volcanic products have been previously considered as petrogenetically related by an ideal fractionation trend, regardless any temporal relationship or volumetric considerations. Here we report new whole-rock geochemistry, mineral chemistry, isotope analyses, estimation of residence times of the different eruptive deposits, and an update of the original petrogenetic model. Our results highlight that an enriched source, likely spinel lherzolites, generated transitional-alkaline basaltic melts after 15–20% of partial melting at depths of 40–45 km. Many of these basaltic melts erupted at various stages of the volcano's history, while others remained longer in the volcanic plumbing system. These evolved by fractional crystallisation into basaltic andesite magmas with a residence time of ~5 years based on the crystal size distribution of the plagioclase population. Isotopic differences between the basalts/basaltic andesites ( 87 Sr/ 86 Sr ~ 0.7034; 143 Nd/ 144 Nd ~ 0.51315) and the erupted rhyolites ( 87 Sr/ 86 Sr ~ 0.7037; 143 Nd/ 144 Nd ~ 0.51304) indicate that the latter are not petrogenetically related to the former. Therefore, instead of a fractional crystallisation mechanism to generate the rhyolites, we propose the partial melting of ignimbrite layers located beneath the volcano. The broad range of trace element concentrations in andesites and dacites and their different isotopic values compared to the basalts strongly suggest that these magmas have been generated by magma mixing between basaltic and rhyolitic melts, similar to modern day Icelandic volcanoes such as Hekla. These results highlight the need to revisit previously studied Icelandic classic localities and reassess their traditionally proposed petrogenetic models.

Þingmúli volcano, East Fjords

Geologic models underpinning the 2024 U.S. Geological Survey assessment of undiscovered oil and gas resources in the Hosston and Travis Peak Formations of the onshore Gulf Coast region, U.S.A.

The Early Cretaceous (Berriasian–Hauterivian) Hosston Formation in Louisiana and eastward is time correlative to the Travis Peak Formation of Texas and southern Arkansas. The formation is a first-order clastic sequence with a regional carbonate transgressive surface as an upper contact. The Hosston and Travis Peak formations contain conventional natural gas and oil accumulations that have been produced for nearly a century. These mature reservoirs contain terrigenous fluvial-deltaic, shore-zone, and paralic deposits across the productive trend; organic-lean mudstone and siltstone lithologies are found outboard of the Lower Cretaceous shelf margin. Producing reservoirs exhibit normal pressure gradients from 0.43 to 0.55 psi/ft (9.7 to 12.4 kpa/m), depths from 4000 to over 20,000 ft (1220 to 6100 m), and temperatures from 150 to 385°F (65 to 196°C). Wells are primarily vertical completions. The number of new field wildcats has been declining since the late 1990s. This paper presents comprehensive geologic models, which include lithofacies maps, structure and isopach maps, burial history models, regional seismic interpretations, and events charts that underpin the recently completed U.S. Geological Survey assessment of undiscovered, technically recoverable hydrocarbons within the Hosston and Travis Peak formations. This study also provides geographic and stratigraphic distributions of Hosston–Travis Peak reservoir properties, including geopressure, reservoir temperature, porosity, permeability, API gravity, and gas-oil ratios. Results indicate estimated undiscovered, technically recoverable mean resources of 28 million barrels of oil and 35.8 trillion cubic ft of gas in conventional and continuous accumulations within the Lower Cretaceous Hosston and Travis Peak formations of the onshore U.S. Gulf Coast region. Quantitative assessment results are detailed in U.S. Geological Survey Fact Sheet 2025–3021 and associated Data Release.

GCAGS Journal

Remote sensing-based actual evapotranspiration assessment in a data-scarce area of Brazil: A case study of the Urucuia Aquifer System

The large groundwater reserves of the Urucuia Aquifer System (UAS) enabled agricultural development and economic growth in the western Bahia State, in northeastern Brazil. Over the last several years, concern has grown around the aquifer’s diminishing water levels, and water balance (WB) studies are in demand. Considering the lack of measured actual evapotranspiration (ET a ), a major component of the water cycle, this work uses the Operational Simplified Surface Energy Balance (SSEBop) model to estimate ET a , and compares it to basin-scale estimates from the Soil Moisture Accounting Procedure (SMAP) monthly model and from an annual WB closure method, based on gridded meteorological data and the Gravity Recovery and Climate Experiment (GRACE) product. Additionally, a comparative assessment of different versions of the SSEBop parameterization was performed. Moderate Resolution Imaging Spectroradiometer (MODIS) imagery was used to implement eight different versions of the SSEBop algorithm over the UAS between 2000 and 2013. SSEBop and SMAP ET a yielded similar seasonal patterns, with correlation coefficient (r) up to 0.65, mean difference (MD) of 0.8 mm/month and mean absolute difference (MAD) of 18.5 mm/month. Comparison of SSEBop annual ET a estimates to annual SMAP and WB closure estimates yielded low MD (12.1 and −7.3 mm/year, respectively) and MAD (82.5 and 82.8 mm/year, respectively), but also low r values (0.00 and 0.37, respectively). The comparison of the different SSEBop versions indicated the need to incorporate a calibration step of the aerodynamic heat resistance (r ah ) parameter. SSEBop results were also used for land cover and drought monitoring. Analysis indicates that agriculture, associated with an increasing trend of atmospheric evaporative demand, is responsible for the decrease in groundwater levels and streamflow in the studied time period.

Urucuia Aquifer System

Nonstationary demographic state-space models using unreplicated counts for species undergoing environmental stressors

A fundamental task in ecological statistics is to estimate abundance and growth rate distributions from wildlife monitoring data to inform conservation management. Modeling time series of wildlife populations presents a number of challenges from both statistical and ecological perspectives, including discreteness; lack of replication; nonstationarity; and observation, demographic, and other phenomenological processes. Nonstationary dynamics are often exhibited by populations undergoing environmental stressors. Models must account for these characteristics to produce reliable estimates of abundance and trends, yet estimation can be challenging with unreplicated data. We propose nonstationary demographic state-space models using unreplicated counts for populations undergoing environmental stressors. A reduced growth rate model matches the complexity of the unreplicated count data, and a fecundity bound on growth rate distributions allows the separation of processes affecting growth rates like environmental stressors from those affecting abundance external to growth rates like migration. NDSSMs allow for the embedding of nonstationary model components, and we explore the use of changepoints, volatility clustering, and migration processes. We apply the proposed nonstationary models in case studies of herons affected by predator/competitor reestablishment and three bat species affected by a fungal pathogen causing white-nose syndrome. Nonstationary models outperform stationary models and generalized linear mixed effects models according to model scoring and visual inspection of predictions, and provide estimates more consistent with published values. Incorporating migration improves model fit universally, even with approximate one-way immigration, most likely because populations are extirpated, recolonized, and increase multiple-fold over the upper bound set by species fecundity. In addition, estimates of the timing and severity of the environmental stressor differed for models with migration. Including nonstationary and demographic components in a fecundity-bounded growth rate model improves inference and benefits interpretability of hyperparameters. In turn, this adjusts uncertainties in predictions of abundance and growth rates over time, providing the ingredients needed for informed conservation analysis and for directing future monitoring of at-risk species.

Journal of Agricultural, Biological and Environmen

Groundwater drought in the United States: Spatial and temporal variability

Many communities and ecosystems in the United States that are dependent on groundwater are potentially adversely affected by groundwater drought. We computed yearly groundwater-drought metrics and mean groundwater levels at well locations across the conterminous United States (CONUS), using data from wells and remotely sensed and modeled Gravity Recovery and Climate Experiment Drought Monitor Data Assimilation (GRACE-DADM). We also modeled the probability of low or high human impact at each well location. The spatial distribution of groundwater-drought duration and severity from 2001 to 2020 for 1,510 wells shows longer maximum duration and higher maximum severity events in drier regions like the Southwest than in wetter regions like the Northeast. Based on 613 wells in CONUS from 1981 to 2020, there are many significant decreases in drought duration and severity in the Northeast and many significant increases in annual-mean groundwater levels. In contrast, there are many significant increases in drought metrics and decreases in mean water levels in parts of the Southeast. There are major differences in trends from 2001 to 2020 between well-based and GRACE-DADM-based groundwater metrics in some CONUS regions and a very low correlation between trends at individual locations across CONUS. A potential reason for this disparity is the low GRACE-DADM resolution (∼12 km) and the potential for a large amount of groundwater variation at the local scale. Also, GRACE-DADM represents shallow, unconfined aquifers which may not match the screened interval of the monitoring wells we evaluated. Large spatial gaps in long-term, high frequency, and quality-assured groundwater-well monitoring data present a challenge for understanding groundwater-drought variability across CONUS. Remote sensing tools such as GRACE can help but cannot fully replace well monitoring, as highlighted by our study results. Substantially more long-term monitoring wells would more accurately represent groundwater-drought trends and spatial variability across CONUS, particularly in western regions.

conterminous United States

Time-varying rates of organic and inorganic mass accumulation in southeast Louisiana marshes: Relationships to sea-level anomalies and tropical storms

Louisiana's coastal wetlands are complex systems that require a continuous input of organic and inorganic material to keep pace with relative sea-level rise. Coastal restoration projects such as sediment diversions are being implemented to mitigate land loss and increase availability of inorganic sediment to coastal wetlands, and marshes specifically rely on organic material to build soil volume and maintain surface elevation. Interannual-to-decadal sea-level anomalies such as hurricanes can affect marsh accretion, mineral deposition, and plant productivity. In this light, complex ecogeomorphic feedback controls whether a marsh surface is sustainable or eroded/drowns. This study performs some of the first differential vertical accretion rates (VARs) and organic and inorganic mass accumulation rates (MARs) over time in SE Louisiana marshes determined from the 210 Pb Constant Rate of Supply model, coupled with standard 137 Cs VARs. These accumulation rates over the past ∼100 years were measured from a total of six brackish and salt marsh locations in Barataria Basin near the proposed Mid-Barataria Sediment Diversion. They were then related to interannual sea-surface elevations at Grand Isle, Louisiana, over the last ∼60 years and recorded hurricane activity in the delta. Results show VARs range from 0.63 cm/y to 1.69 cm/y and total MARs range from 0.11 to 0.43 g/cm 2 /y. Temporally, VARs and MARs (total, inorganic, and organic) are characterized by gradual increases in rates with decreasing age along with episodic peaks in VARs and MARs. The findings of this study indicate that no relationship occurs between sea-level anomalies and VARs or organic and inorganic MARs; however, a strong relationship appears to occur between major hurricanes to VAR and MAR contributions. Furthermore, high water content (81 ± 8%) and organic-rich soils in the sediment cores highlight the significance of belowground biomass and associated pore volume in maintaining marsh elevation in the study area.

Louisiana

Groundwater quality near an oil field in a stream-dominated recharge setting, California, USA

Alluvial valley aquifers are important sources of water supply in many areas but effects of co-located oil and gas development on these resources have not been widely reported, especially in settings where recharge is dominated by stream infiltration. Interpreting the presence of geochemical indicators in the context of hydrology, geology, and other factors provides a more complete understanding of the relations between groundwater and sources of oil-field fluids and aids in identifying risks associated with oil and gas development. Groundwater and Salinas River water samples were collected in an alluvial valley near the San Ardo Oil Field in Monterey County, California and analyzed for a wide range of dissolved chemical, gas, and isotopic constituents to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with fresh groundwater used for supply. Hydraulic gradients, age-dating tracers, and other geochemical indicators show that recharge from the Salinas River has the potential to dilute oil-field fluids that might migrate or seep into the aquifer. Groundwater and Salinas River water collected downgradient of the San Ardo Oil Field showed little or no evidence of mixing with oil-field fluids. Some samples within the oil field contained trace amounts of hydrocarbons or elevated temperatures, indicating that any potential effects from oil-field activities are minor or have been diluted by recharge from the Salinas River. The two samples with the most geochemical evidence of potential mixing with oil-field fluids (SP-18 and GW-17) were collected west of or along the Los Lobos fault, where naturally occurring hydrocarbons are near the land surface. Those samples are also near active or inactive oil-field wells, and so anthropogenic activities and pathways cannot be ruled out as a cause of trace detections of hydrocarbons and elevated temperatures in the aquifer.

California

Hydrogeology, groundwater salinity distributions, and assessment of the effect of oil-production activities on groundwater in the Midway Valley area, western Kern County, San Joaquin Valley, California

This study seeks to determine the effects of oil field produced water disposal operations and well mechanical integrity issues on groundwater quality in oil fields in the southwest San Joaquin Valley, California. Whereas previous studies used groundwater wells to study shallow aquifers outside the oil fields, this study demonstrates that future approaches may use oil well geophysical logs to map groundwater head gradients, create salinity profiles and document changes in salinity over time in oil field areas with sparse groundwater well data and at depths greater than 330 m. We also incorporate an analysis of well histories to determine potential effects of compromised wellbore seals on changes in aquifer quality that cannot be explained by water disposal practices. Water quality in the aquifers is naturally brackish across most of the area, with better quality groundwater occurring in the eastern part. Geophysical logs are used to determine salinity variations within aquifers including the depth at which TDS exceeds 10,000 mg/L. This depth ranges from 366 m in the northwest to approximately 1,500 m in the southeast. Oil well porosity logs are used to determine water table elevations. These logs indicate the water table slopes south-southeast, showing the predominant groundwater flow direction is from oil field disposal areas toward better quality groundwater east of the oil fields. Geophysical logs show formation resistivity near some disposal facilities has decreased over time, indicating the salinity of the aquifer has increased due to disposal of saline produced water in injection wells and ponds. Oil well history analysis suggests that increased salinity over time in water-saturated sand intervals >1.5 km from disposal facilities may be caused by mechanical failures and/or incomplete borehole seals in poorly constructed or abandoned wellbores prevalent throughout the study area—particularly wells drilled prior to 1930.

California

Shallow differentiation of primitive arc magmas at the Jurassic Emigrant Gap mafic complex, Sierra Nevada, California

The Emigrant Gap composite pluton exposes ultramafic to silicic intrusive rocks that preserve the chemical evolution of primitive mafic arc magmas and their open-system interactions in the upper crust during mid-Jurassic growth of the Sierra Nevada batholith (California). We present field and petrographic observations and mineral and whole-rock chemistry of the ~35-km 2 ultramafic to dioritic Emigrant Gap mafic complex and an adjacent penecontemporaneous ~90-km 2 granodiorite that together make up the composite pluton. In the Emigrant Gap mafic complex, four roughly central masses of dunite, wehrlite, and olivine clinopyroxenite are surrounded by weakly layered gabbronorite and non-layered diorite. The ultramafic rocks are cumulates formed from near-liquidus minerals of primitive arc magmas that accumulated in steep feeder zones with substantial modification by melt–mush reaction as primitive liquids repeatedly transited the mush-filled conduits. The dominant gabbronoritic rocks are the variably accumulative products of more advanced crystallization–differentiation of arc tholeiitic basalts and basaltic andesites. The adjacent granodiorite intrusion originated separately and preserves field and geochemical evidence for assimilation of metasedimentary rocks. Open-system hybridization between the gabbronoritic mushes and the granodioritic magma produced an intervening body of two-pyroxene diorite. We infer that the ultramafic rocks and gabbronorite of the Emigrant Gap mafic complex crystallized from near-primitive arc basaltic to basaltic andesitic magmas at ~0.15–0.3 GPa, with estimated f O 2 of ≥FMQ +1 and dissolved H 2 O concentrations of only ~0.5–2 wt %. Notably, the Emigrant Gap composite pluton is distinct from other Mesozoic plutons in the Sierra Nevada batholith because of (1) its abundance of mafic and ultramafic rocks that crystallized from relatively primitive mafic melts and (2) the low inferred H 2 O concentrations of its parental magmas, indicated by a near absence of igneous amphibole and by the intermediate rather than calcic compositions of plagioclase. A Jurassic regional extension event probably accounts for the formation of relatively dry primitive arc magmas, as well as for their ascending to the upper crust.

California

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

Cold blood in warming waters: Effects of air temperature, precipitation, and groundwater on Gulf Sturgeon thermal habitats in a changing climate

Objective In a changing climate, the effects of air temperature, precipitation, and groundwater on water temperature and thermal habitat suitability for Gulf Sturgeon Acipenser desotoi , listed as threatened under the U.S. Endangered Species Act, are not well understood. Hence, we incorporated these factors into thermal habitat models to forecast how Gulf Sturgeon may be affected by wide‐ranging climate change scenarios in 2024–2074. Methods Using data from the Choctawhatchee River, Florida, we developed precipitation‐ and groundwater‐corrected air–water temperature models, compared their accuracy with that of conventional air–water temperature models used in fisheries management, and projected future Gulf Sturgeon thermal habitat suitability for normal physiological functioning and fieldwork (i.e., population sampling and telemetry surgeries) in summer (May–August) under 16 climate change scenarios. Result Precipitation‐ and groundwater‐corrected models were more accurate than conventional air–water temperature models (mean improvement in adjusted R 2 = +0.45; range = +0.09 to +0.75). Water temperature was projected to warm at widely variable rates across climate change scenarios encompassing different air temperature, precipitation, and groundwater regimes. Importantly, Gulf Sturgeon summer aggregation areas were cooler and influenced more by precipitation and groundwater and less by air temperature than were non‐aggregation areas. If precipitation and groundwater—as drivers of cooling—become warm in a changing climate, summer aggregation areas were projected to exhibit thermal habitat degradation equivalent to or greater than that of non‐aggregation areas. Conclusion Our results add hydrological context to the premise that aggregation areas provide cool water and energetic savings for Gulf Sturgeon during summer, underscoring the importance of protecting these habitats through groundwater conservation, water quality monitoring, and riparian/watershed habitat management. Our findings indicate that identifying thermally appropriate times for fieldwork activities will be increasingly important and time‐restricted as climate change intensifies. However, our research provides managers with a portfolio of water temperature models and an accurate, cost‐effective, management‐relevant approach to forecasting thermal habitat conditions for Gulf Sturgeon and other species in a changing climate.

Alabama, Florida