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At least 217 records · Page 12Linked to original sources
USGS2008

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗
USGS2008

Determination of dominant biogeochemical processes in a contaminated aquifer-wetland system using multivariate statistical analysis

Determining the processes governing aqueous biogeochemistry in a wetland hydrologically linked to an underlying contaminated aquifer is challenging due to the complex exchange between the systems and their distinct responses to changes in precipitation, recharge, and biological activities. To evaluate temporal and spatial processes in the wetland-aquifer system, water samples were collected using cm-scale multi-chambered passive diffusion samplers (peepers) to span the wetland-aquifer interface over a period of 3 yr. Samples were analyzed for major cations and anions, methane, and a suite of organic acids resulting in a large dataset of over 8000 points, which was evaluated using multivariate statistics. Principal component analysis (PCA) was chosen with the purpose of exploring the sources of variation in the dataset to expose related variables and provide insight into the biogeochemical processes that control the water chemistry of the system. Factor scores computed from PCA were mapped by date and depth. Patterns observed suggest that (i) fermentation is the process controlling the greatest variability in the dataset and it peaks in May; (ii) iron and sulfate reduction were the dominant terminal electron-accepting processes in the system and were associated with fermentation but had more complex seasonal variability than fermentation; (iii) methanogenesis was also important and associated with bacterial utilization of minerals as a source of electron acceptors (e.g., barite BaSO 4 ); and (iv) seasonal hydrological patterns (wet and dry periods) control the availability of electron acceptors through the reoxidation of reduced iron-sulfur species enhancing iron and sulfate reduction.

Journal of Environmental Quality↗
USGS1971

Open-channel integrating-type flow meter

A relatively inexpensive meter for measuring cumulative flow in open channels with a rated control,. called a "totalizer", was developed. It translates the nonlinear function of gage height to flow by use of a cam and a float. A variable resistance element in an electronic circuit is controlled by the float so that the electron flow in the circuit corresponds to the flow of water. The flow of electricity causes electroplating of an electrode with silver. The amount of silver deposited is proportionate to the flow of water. The total flow of water is determined by removing the silver from the electrode at a fixed rate with ·an electronic device and recording the time for removal with a counter. The circuit is designed so that the ,resultant reading on the counter is in acre-feet of water.

Open-File Report↗
USGS2004

Chloroethene biodegradation potential, ADOT/PF Peger Road Maintenance Facility, Fairbanks, Alaska

A series of 14C-radiotracer-based microcosm experiments were conducted to assess: 1) the extent, rate and products of microbial dechlorination of trichloroethene (TCE), cis-dichloroethene (cis-DCE) and vinyl chloride (VC) in sediments at the Peger Road site; 2) the effect of three electron donor amendments (molasses, shrimp and crab chitin, and 'Hydrogen Release Compound' (HRC)) on microbial degradation of TCE in three Peger Road sediments; and 3) the potential significance at the site of chloroethene biodegradation processes other than reductive dechlorination. In these experiments, TCE biodegradation yielded the reduced products, DCE and VC, and the oxidation product CO 2. Biodegradation of DCE and VC involved stoichiometric oxidation to CO 2. Both laboratory microcosm study and field redox assessment results indicated that the predominant terminal electron accepting process in Peger Road plume sediments under anoxic conditions was Mn/Fe-reduction. The rates of chloroethene biodegradation observed in Peger Road sediment microcosms under low temperature conditions (4?C) were within the range of those observed in sediments from temperate (20?C) aquifer systems. This result confirmed that biodegradation can be a significant mechanism for in situ contaminant remediation even in cold temperature aquifers. The fact that CO2 was the sole product of cis-DCE and VC biodegradation detected in Peger Road sediments indicated that a natural attenuation assessment based on reduced daughter product accumulation may significantly underestimate the potential for DCE and VC biodegradation at the Peger Road. Neither HRC nor molasses addition stimulated TCE reductive dechlorination. The fact that molasses and HRC amendment did stimulate Mn/Fe-reduction suggests that addition of these electron donors favored microbial Mn/Fe-reduction to the detriment of microbial TCE dechlorinating activity. In contrast, amendment of sediment microcosms with shrimp and crab chitin resulted in the establishment of mixed Mn/Fe-reducing, SO42--reducing and methanogenic conditions and enhanced TCE biodegradation in two of three Peger Road sediment treatments.

Alaska↗
USGS2016

Gallery of melt textures developed in Westerly Granite during high-pressure triaxial friction experiments

Introduction Melting occurred during stick-slip faulting of granite blocks sheared at room-dry, room-temperature conditions in a triaxial apparatus at 200–400 megapascals (MPa) confining pressure. Petrographic examinations of melt textures focused largely on the 400-MPa run products. This report presents an overview of the petrographic data collected on those samples, followed by brief descriptions of annotated versions of all the images. Scanning electron microscope (SEM) images of the starting materials and the three examined 400-MPa samples are presented in this report. Secondary-electron (SE) and backscattered-electron (BSE) imaging techniques were used on different samples. The SE images look down on the sawcut surfaces, yielding topographic and three-dimensional textural information. The BSE imaging was done on samples cut to provide cross-sectional views of the glass-filled shear band (or zone) that developed along the sawcut. Brightness in the BSE images increases with increasing mean atomic number of the material. Additional chemical information about the quenched melt and adjoining minerals was obtained using the energy dispersive system of the SEM during BSE examinations. However, the very narrow shear-band thicknesses and common occurrence of very fine lamellar compositional layering limited the usefulness of this technique for estimating melt chemistry.

Open-File Report↗
USGS2025

Characterizing Meteor Crater impact melts through geochemistry and textural analysis

The U.S. Geological Survey Astrogeology Science Center houses the Meteor Crater sample collection, an assemblage of over 2,500 meters of cuttings from 161 drill holes into Meteor Crater’s rim, flanks, and ejecta blanket. We have utilized this unique collection to study the composition and spatial distribution of impact-generated materials from within the ejecta blanket. Meteor Crater has historically been known to have generated only a relatively small amount of impact melt compared to other terrestrial craters of similar size. A detailed compositional and textural dataset of impact-derived melts from this impact can therefore be a useful asset in improving our understanding of crater formation, and in particular impact melt formation. We have characterized 42 impact-melt particles from Meteor Crater using a scanning electron microscope and an electron microprobe for textural and compositional analysis. We analyzed samples from six drill holes in the ejecta blanket, situated to the northwest, southeast, south, and southwest of the crater (ejecta northeast of the crater is devoid of impact melts). Impact melts were collected from drill cuttings at various depths within the ejecta blanket, ranging from a few centimeters below the surface down to ~6.5 meters. Backscattered electron (BSE) images were acquired for each analyzed impact-melt particle. To characterize the various textures and phases present in each impact melt, we also took many detailed BSE images. Our geochemical analyses include full spectral profiles using energy dispersive X-ray spectrometry and well-calibrated wavelength dispersive spectrometry for a number of phases, including minerals (olivine, pyroxene, and so on), pristine glass, and metallic inclusions. The full dataset is available in ScienceBase as a data release (Gullikson and others, 2024), accessible at https://doi.org/10.5066/P9OGAJ8P . Our goal for this Open-File Report is to provide a summary of this immense dataset, details on data collection, descriptions of the different phases observed within impact-melt particles (both geochemically and texturally), and observable trends.

Arizona↗
USGS2017

Gallium

Gallium is a soft, silvery metallic element with an atomic number of 31 and the chemical symbol Ga. Gallium is used in a wide variety of products that have microelectronic components containing either gallium arsenide (GaAs) or gallium nitride (GaN). GaAs is able to change electricity directly into laser light and is used in the manufacture of optoelectronic devices (laser diodes, light-emitting diodes [LEDs], photo detectors, and solar cells), which are important for aerospace and telecommunications applications and industrial and medical equipment. GaAs is also used in the production of highly specialized integrated circuits, semiconductors, and transistors; these are necessary for defense applications and high-performance computers. For example, cell phones with advanced personal computer-like functionality (smartphones) use GaAs-rich semiconductor components. GaN is used principally in the manufacture of LEDs and laser diodes, power electronics, and radio-frequency electronics. Because GaN power transistors operate at higher voltages and with a higher power density than GaAs devices, the uses for advanced GaN-based products are expected to increase in the future. Gallium technologies also have large power-handling capabilities and are used for cable television transmission, commercial wireless infrastructure, power electronics, and satellites. Gallium is also used for such familiar applications as screen backlighting for computer notebooks, flat-screen televisions, and desktop computer monitors. Gallium is dispersed in small amounts in many minerals and rocks where it substitutes for elements of similar size and charge, such as aluminum and zinc. For example, gallium is found in small amounts (about 50 parts per million) in such aluminum-bearing minerals as diaspore-boehmite and gibbsite, which form bauxite deposits, and in the zinc-sulfide mineral sphalerite, which is found in many mineral deposits. At the present time, gallium metal is derived mainly as a byproduct of the processing of bauxite ore for aluminum; lesser amounts of gallium metal are produced from the processing of sphalerite ore from three types of deposits (sediment-hosted, Mississippi Valley-type, and volcanogenic massive sulfide) for zinc. The United States is expected to meet its current and expected future needs for gallium through imports of primary, recycled, and refined gallium, as well as through domestic production of recycled and refined gallium. The U.S. Geological Survey estimates that world resources of gallium in bauxite exceed 1 billion kilograms, and a considerable quantity of gallium could be present in world zinc reserves.

Professional Paper↗
USGS2006

Organochlorine compounds and current-use pesticides in snow and lake sediment in Rocky Mountain National Park, Colorado, and Glacier National Park, Montana, 2002-03

Organochlorine compounds and current-use pesticides were measured in snow and lake-sediment samples from Rocky Mountain National Park in Colorado and Glacier National Park in Montana to determine their occurrence and distribution in high-elevation aquatic ecosystems. The U.S. Geological Survey, in cooperation with the National Park Service, collected snow samples at eight sites in Rocky Mountain National Park and at eight sites in Glacier National Park during spring of 2002 and 2003 just prior to the start of snowmelt. Surface sediments were collected from 11 lakes in Rocky Mountain National Park and 10 lakes in Glacier National Park during summer months of 2002 and 2003. Samples were analyzed for organochlorine compounds by gas chromatography with electron-capture detection and current-use pesticides by gas chromatography with electron-impact mass spectrometry. A subset of samples was reanalyzed using a third instrumental technique (gas chromatography with electron-capture negative ion mass spectrometry) to verify detected concentrations in the initial analysis and to investigate the presence of additional compounds. For the snow samples, the pesticides most frequently detected were endosulfan, dacthal, and chlorothalonil, all of which are chlorinated pesticides that currently are registered for use in North America. Concentrations of these pesticides in snow were very low, ranging from 0.07 to 2.36 nanograms per liter. Of the historical-use pesticides, hexachlorobenzene, dieldrin, and trans -nonachlor were detected in snow but only in one sample each. Annual deposition rates of dacthal, endosulfan, and chlorothalonil were estimated at 0.7 to 3.0 micrograms per square meter. These estimates are likely biased low because they do not account for pesticide deposition during summer months. For the lake-sediment samples, DDE ( p,p’ -dichlorodiphenyldichoroethene) and DDD ( p,p’ -dichlorodiphenyldichoroethane) were the most frequently detected organochlorine compounds. DDE and DDD are degradation products of DDT ( p,p’ -dichlorodiphenyltrichloroethane), which is a well-documented, persistent organochlorine insecticide that has been banned from use in the United States since 1972. Detected concentrations were very low, ranging from 0.12 to 4.7 micrograms per kilogram, and probably pose little threat to aquatic organisms in park lakes. DDD and DDE concentrations in a sediment core from Mills Lake in Rocky Mountain National Park indicate that atmospheric deposition of DDT and possibly other banned organochlorine compounds to high-elevation parks has been in decline since the 1970s. Commonly detected current-use pesticides in lake sediments included dacthal and endosulfan sulfate, which ranged in concentrations from 0.11 to 0.26 micrograms per kilogram for dacthal and 0.12 to 1.2 micrograms per kilogram for endosulfan sulfate. Both compounds were found in nearly all the snow samples, confirming that some current-use pesticides entering high-elevation aquatic ecosystems through atmospheric deposition are accumulating in lake sediments and potentially in aquatic biota.

Colorado, Montana↗
USGS2012

Byproduct metals and rare-earth elements used in the production of light-emitting diodes—Overview of principal sources of supply and material requirements for selected markets

The use of light-emitting diodes (LEDs) is expanding because of environmental issues and the efficiency and cost savings achieved compared with use of traditional incandescent lighting. The longer life and reduced power consumption of some LEDs have led to annual energy savings, reduced maintenance costs, and lower emissions of carbon dioxide, sulfur dioxide, and nitrogen oxides from powerplants because of the resulting decrease in energy consumption required for lighting applications when LEDs are used to replace less-energy-efficient sources. Metals such as arsenic, gallium, indium, and the rare-earth elements (REEs) cerium, europium, gadolinium, lanthanum, terbium, and yttrium are important mineral materials used in LED semiconductor technology. Most of the world's supply of these materials is produced as byproducts from the production of aluminum, copper, lead, and zinc. Most of the rare earths required for LED production in 2011 came from China, and most LED production facilities were located in Asia. The LED manufacturing process is complex and is undergoing much change with the growth of the industry and the changes in demand patterns of associated commodities. In many respects, the continued growth of the LED industry, particularly in the general lighting sector, is tied to its ability to increase LED efficiency and color uniformity while decreasing the costs of producing, purchasing, and operating LEDs. Research is supported by governments of China, the European Union, Japan, the Republic of Korea, and the United States. Because of the volume of ongoing research in this sector, it is likely that the material requirements of future LEDs may be quite different than LEDs currently (2011) in use as industry attempts to cut costs by reducing material requirements of expensive heavy rare-earth phosphors and increasing the sizes of wafers for economies of scale. Improved LED performance will allow customers to reduce the number of LEDs in automotive, electronic, and lighting applications, which could reduce the overall demand for material components. Non-Chinese sources for rare earths are being developed, and some of these new sources are likely to be operational in time to meet increasing demand for rare earths from the LED sector. Because most LED component production and manufacturing occurs in Asia and many LED producers have established supply contracts with Chinese producers of rare earths, a significant amount of the metallic gallium, indium, and the rare earths used for LED production will likely continue to come from Chinese sources at least for the next 5 years; however, a greater amount of these materials are now being processed in Japan, the Republic of Korea, and Taiwan. As non-Chinese sources of rare earths come into production, these new mines are likely to be sources of light REEs, but China will likely remain the leading source of supply for the heavy REEs suitable for use as LED dopants and phosphors at least for the next few years. Increased research in the development of phosphors that use smaller amounts of or different REEs is intended to reduce dependence on rare earths from China. Supply disruption of rare earths and other specialty metals could take place if China's specialty metal exports are redirected to domestic markets. The cost of recovery is high and the lifespan for LEDs is comparatively long; thus, the LED waste volume was low in 2010, and few LEDs were recycled. The minute metal content of LEDs leads to a high cost for recovery, so recycling of LEDs outside of electronic waste is unlikely in the near term, although some LED producers are evaluating recycling options. Recycling of metals from LEDs in electronic waste is possible if the costs of recovering metals are justified by demand and metal prices.

Scientific Investigations Report↗
USGS2020

Procedures and best practices for trigonometric leveling in the U.S. Geological Survey

With the advent of highly precise total stations and modern surveying instrumentation, trigonometric leveling has become a compelling alternative to conventional leveling methods for establishing vertical-control networks and for perpetuating a datum to field sites. Previous studies of trigonometric-leveling measurement uncertainty proclaim that first-, second-, and third-order accuracies may be achieved if strict leveling protocols are rigorously observed. Common field techniques to obtain quality results include averaging zenith angles and slope distances observed in direct and reverse instrument orientation (F1 and F2, respectively), multiple sets of reciprocal observations, quality meteorological observations to correct for the effects of atmospheric refraction, and electronic distance measurements that generally do not exceed 500 feet. In general, third-order specifications are required for differences between F1 and F2 zenith angles and slope distances; differences between redundant instrument-height measurements; section misclosure determined from reciprocal observations; and closure error for closed traverse. For F1 observations such as backsight check and check shots, the construction-grade specification is required for elevation differences between known and observed values. Recommended specifications for trigonometric-leveling equipment include a total station instrument with an angular uncertainty specification less than or equal to plus or minus 5 arc-seconds equipped with an integrated electronic distance measurement device with an uncertainty specification of less than or equal to plus or minus 3 millimeters plus 3 parts per million. A paired data collector or integrated microprocessor should have the capability to average multiple sets of measurements in direct and reverse instrument orientation. Redundant and independent measurements by the survey crew and automated or manual reduction of slant heights to the vertical equivalent are recommended to obtain quality instrument heights. Horizontal and vertical collimation tests should be conducted daily during trigonometric-leveling surveys, and electronic distance-measurement instruments should be tested annually on calibrated baselines maintained by the National Geodetic Survey. Specifications that were developed by the National Geodetic Survey for geodetic leveling have been adapted by the U.S. Geological Survey (USGS) for the purpose of developing standards for trigonometric leveling, which are identified as USGS Trigonometric Level I (TL I), USGS Trigonometric Level II (TL II), USGS Trigonometric Level III (TL III), and USGS Trigonometric Level IV (TL IV). TL I, TL II, and TL III surveys have a combination of first, second, and third geodetic leveling specifications that have been modified for plane leveling. The TL III category also has specifications that are adapted from construction-grade standards, which are not recognized by the National Geodetic Survey for geodetic leveling. A TL IV survey represents a leveling approach that does not generally meet criteria of a TL I, TL II, or TL III survey. Site conditions, such as highly variable topography, and the need for cost-effective, rapid, and accurate data collection in response to coastal or inland flooding have emphasized the need for an alternative approach to conventional leveling methods. Trigonometric leveling and the quality-assurance methods described in this manual will accommodate most site and environmental conditions, but measurement uncertainty is potentially variable and dependent on the survey method. Two types of closed traverse surveys have been identified as reliable methods to establish and perpetuate vertical control: the single-run loop traverse and double-run spur traverse. Leveling measurements for a double-run spur traverse are made in the forward direction from the origin to the destination and are then retraced along the same leveling route in the backward direction, from the destination to the origin. Every control point in a double-run spur traverse is occupied twice. Leveling measurements for a single-run loop traverse are made in the forward direction from the origin point to the destination, and then from the destination to the origin point, along a different leveling route. The only point that is redundantly occupied for the single-run loop traverse is the origin. An open traverse method is also considered an acceptable approach to establish and perpetuate vertical control if the foresight prism height is changed between measurement sets to ensure at least two independent observations. A modified version of leap-frog leveling is recommended for all traverse surveys because it reduces measurement uncertainty by forcing the surveying instrumentation into a level and centered condition over the ground point as the instrumentation is advanced to the objective. Sideshots are considered any radial measurement made from the total station that is not part of a traverse survey. F1 and F2 observations are recommended for sideshots measurements for projects that require precise elevations. Quality-assurance measurements made in F1 from the station to network-control points should be considered for surveys that require a high quantity of sideshots. The accuracy of a trigonometric-leveling survey essentially depends on four components (1) the skill and experience of the surveyor, (2) the environmental or site conditions, (3) the surveying method, and (4) the quality of the surveying instrumentation. Although components one and two can sometimes be difficult to evaluate and be highly variable, the objective of this manual is to disseminate information needed to identify, maintain, and operate quality land-surveying instrumentation, and to document procedures and best practices for preparing and executing precision trigonometric-leveling surveys in the USGS.

Techniques and Methods↗
USGS2004

Summary of available state ambient stream-water-quality data, 1990-98, and limitations for national assessment

The investigation described in this report summarized data from State ambient stream-water-quality monitoring sites for 10 water-quality constituents or measurements (suspended solids, fecal coliform bacteria, ammonia as nitrogen, nitrite plus nitrate as nitrogen, total phosphorus, total arsenic, dissolved solids, chloride, sulfate, and pH). These 10 water-quality constituents or measurements commonly are listed nationally as major contributors to degradation of surface water. Water-quality data were limited to that electronically accessible from the U.S. Environmental Protection Agency Storage and Retrieval System (STORET), the U.S. Geological Survey National Water Information System (NWIS), or individual State databases. Forty-two States had ambient stream-water-quality data electronically accessible for some or all of the constituents or measurements summarized during this investigation. Ambient in this report refers to data collected for the purpose of evaluating stream ecosystems in relation to human health, environmental and ecological conditions, and designated uses. Generally, data were from monitoring sites assessed for State 305(b) reports. Comparisons of monitoring data among States are problematic for several reasons, including differences in the basic spatial design of monitoring networks; water-quality constituents for which samples are analyzed; water-quality criteria to which constituent concentrations are compared; quantity and comprehensiveness of water-quality data; sample collection, processing, and handling; analytical methods; temporal variability in sample collection; and quality-assurance practices. Large differences among the States in number of monitoring sites precluded a general assumption that statewide water-quality conditions were represented by data from these sites. Furthermore, data from individual monitoring sites may not represent water-quality conditions at the sites because sampling conditions and protocols are unknown. Because of these factors, a high level of uncertainty exists in a national assessment of water quality. The purpose of this report is to present a summary of electronically available State ambient stream-water-quality data for 10 selected constituents and measurements from monitoring sites with nine or more analyses for 199098 and to discuss limitations for use of the data for national assessment. These analyses were statistiscally summarized by monitoring site and State, and the results presented in tabular format. Most of the selected constituents or measurements have U.S. Environmental Protection Agency criteria or guidelines for aquatic-life or drinking-water purposes. A significant finding of this investigation is that for a large percentage of monitoring sites in the Nation, there are insufficient data to meet U.S. Environmental Protection Agency recommendations for determining if water-quality conditions are degraded and for making informed decisions regarding total maximum daily loads.

Water-Resources Investigations Report↗
USGS2024

Hirsutonosema embarrassi n. gen. n. sp. (Phylum Microsporidia) in the Ovary of Mucket (Actinonaias ligamentina), Plain Pocketbook (Lampsilis cardium), and Fatmucket (Lampsilis siliquoidea) (Unionidae) from the Embarrass River, Wisconsin, USA

During an epidemiological survey following a mortality event of freshwater mussels in 2018 in the Embarrass River, Wisconsin, USA, we identified a novel microsporidian parasite in the ovaries of mucket ( Actinonaias ligamentina ), plain pocketbook ( Lampsilis cardium ), and fatmucket ( Lampsilis siliquoidea ) (Unionidae). Histopathology showed round-to-oval microsporidian spores in the cytoplasm of oocytes in 60% (3/5) of female mucket, 100% (4/4) of female plain pocketbook, and 50% (1/2) of female fatmucket. Using transmission electron microscopy, we found that mature spores were round-to-oval and measured 4.13 ± 0.64 µm (3.14–5.31) long by 2.88 ± 0.37 µm (2.36–3.68) wide. The spores had a thin electron-dense exospore with a spiky “hairy” coat, a thick electron lucent endospore, diplokaryotic nuclei, a polar vacuole, and 27–28 polar filaments arranged in 1–3 rows. Sequencing of the small subunit rRNA produced a 1356 bp sequence most similar to that of Pseudonosema cristatellae (92%), and phylogenetic analysis grouped it within the freshwater Neopereziida. Genetic, morphological, and ultrastructural characteristics did not closely match those of other Pseudonosema spp., and a new genus and species, Hirsutonosema embarrassi n. gen. n. sp., were designated. Additional studies could evaluate host susceptibility, distribution, seasonality, transmission, and lethal or sub-lethal effects of this parasite on freshwater mussels.

Wisconsin↗
USGS2012

Assessing consumption of bioactive micro-particles by filter-feeding Asian carp

Silver carp Hypophthalmichthys molitrix (SVC) and bighead carp H. nobilis (BHC) have impacted waters in the US since their escape. Current chemical controls for aquatic nuisance species are non-selective. Development of a bioactive micro-particle that exploits filter-feeding habits of SVC or BHC could result in a new control tool. It is not fully understood if SVC or BHC will consume bioactive micro-particles. Two discrete trials were performed to: 1) evaluate if SVC and BHC consume the candidate micro-particle formulation; 2) determine what size they consume; 3) establish methods to evaluate consumption of filter-feeders for future experiments. Both SVC and BHC were exposed to small (50-100 μm) and large (150-200 μm) micro-particles in two 24-h trials. Particles in water were counted electronically and manually (microscopy). Particles on gill rakers were counted manually and intestinal tracts inspected for the presence of micro-particles. In Trial 1, both manual and electronic count data confirmed reductions of both size particles; SVC appeared to remove more small particles than large; more BHC consumed particles; SVC had fewer overall particles in their gill rakers than BHC. In Trial 2, electronic counts confirmed reductions of both size particles; both SVC and BHC consumed particles, yet more SVC consumed micro-particles compared to BHC. Of the fish that ate micro-particles, SVC consumed more than BHC. It is recommended to use multiple metrics to assess consumption of candidate micro-particles by filter-feeders when attempting to distinguish differential particle consumption. This study has implications for developing micro-particles for species-specific delivery of bioactive controls to help fisheries, provides some methods for further experiments with bioactive micro-particles, and may also have applications in aquaculture.

Journal of Aquaculture Research & Development↗
USGS2025

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho↗
USGS1987

APPLICATIONS OF CATHODOLUMINESCENCE OF QUARTZ AND FELDSPAR TO SEDIMENTARY PETROLOGY.

Cathodoluminescence (CL), the emission of visible light during electron bombardment, was first used in sandstone petrology in the mid-1960's. CL techniques are especially useful for determining the origin and source of quartz and feldspar, two of the most common constituents in clastic rocks. CL properties of both minerals are dependent on their temperature of crystallization, duration of cooling, and/or history of deformation. Detrital quartz and feldspar are typically derived from igneous and metamorphic sources and luminesce in the visible range whereas authigenic quartz and feldspar form at low temperatures and do not luminesce. Quantification of luminescent and non-luminescent quartz and feldspar with the scanning electron microscope, electron microprobe, or a commercial CL device can allow for the determination of origin, diagenesis, and source of clastic rocks when used in conjunction with field and other petrographic analyses.

Scanning Micros↗
USGS1984

MICROCHARACTERIZATION OF ARSENIC- AND SELENIUM-BEARING PYRITE IN UPPER FREEPORT COAL, INDIANA COUNTY, PENNSYLVANIA.

Optical and scanning electron microscope as well as electron and proton microprobe techniques have been used in a detailed investigation of the modes of occurrence of arsenic and selenium in pyrite in Upper Freeport coal from the Homer City area, Indiana County, Pennsylvania. Polished blocks were prepared from columnar samples of the coal bed to represent particular zones continuously from top to bottom. Initial selection of zones to be studied was based on chemical analysis of bench-channel samples. Microprobe data indicate that the highest concentrations of arsenic (as great as 1. 5 wt. %) are apparently in solid solution in pyrite within a limited stratigraphic interval of the coal bed. Smaller amounts of arsenic and selenium (concentrations up to approximately 0. 1 and 0. 2 wt. % respectively) were detected at isolated points within pyrite grains in various strata of the coal bed.

Scanning Electron Microscopy↗
USGS2025

Cancer risk and estimated lithium exposure in drinking groundwater in the US

Importance Lithium is a naturally occurring element in drinking water and is commonly used as a mood-stabilizing medication. Although clinical studies have reported associations between receiving lithium treatment and reduced cancer risk among patients with bipolar disorder, to our knowledge, the association between environmental lithium exposure and cancer risk has never been studied in the general population. Objectives To evaluate the association between exposure to lithium in drinking groundwater and cancer risk in the general population. Design, Setting, and Participants This cohort study included participants with electronic health record and residential address information but without cancer history at baseline from the All of Us Research Program between May 31, 2017, and June 30, 2022. Participants were followed up until February 15, 2023. Statistical analysis was performed from September 2023 through October 2024. Exposure Lithium concentration in groundwater, based on kriging interpolation of publicly available US Geological Survey data on lithium concentration for 4700 wells across the contiguous US between May 12, 1999, and November 6, 2018. Main Outcome and Measures The main outcome was cancer diagnosis or condition, obtained from electronic health records. Stratified Cox proportional hazards regression models were used to estimate the hazard ratios (HRs) and 95% CIs for risk of cancer overall and individual cancer types for increasing quintiles of the estimated lithium exposure in drinking groundwater, adjusting for socioeconomic, behavioral, and neighborhood-level variables. The analysis was further conducted in the western and eastern halves of the US and restricted to long-term residents living at their current address for at least 3 years. Results A total of 252 178 participants were included (median age, 52 years [IQR, 36-64 years]; 60.1% female). The median follow-up time was 3.6 years (IQR, 3.0-4.3 years), and 7573 incident cancer cases were identified. Higher estimated lithium exposure was consistently associated with reduced cancer risk. Compared with the first (lowest) quintile of lithium exposure, the HR for all cancers was 0.49 (95% CI, 0.31-0.78) for the fourth quintile and 0.29 (95% CI, 0.15-0.55) for the fifth quintile. These associations were found for all cancer types investigated in both females and males, among long-term residents, and in both western and eastern states. For example, for the fifth vs first quintile of lithium exposure for all cancers, the HR was 0.17 (95% CI, 0.07-0.42) in females and 0.13 (95% CI, 0.04-0.38) in males; for long-term residents, the HR was 0.32 (95% CI, 0.15-0.66) in females and 0.24 (95% CI, 0.11-0.52) in males; and the HR was 0.01 (95% CI, 0.00-0.09) in western states and 0.34 (95% CI, 0.21-0.57) in eastern states. Conclusions and Relevance In this cohort study of 252 178 participants, estimated lithium exposure in drinking groundwater was associated with reduced cancer risk. Given the sparse evidence and unknown mechanisms of this association, follow-up investigation is warranted.

contiguous United States↗
USGS1997

Use of geochemical mass balance modelling to evaluate the role of weathering in determining stream chemistry in five mid-Atlantic watersheds on different lithologies

The importance of mineral weathering was assessed and compared for five mid-Atlantic watersheds receiving similar atmospheric inputs but underlain by differing bedrock. Annual solute mass balances and volume-weighted mean solute concentrations were calculated for each watershed for each year of record. In addition, primary and secondary mineralogy were determined for each of the watersheds through analysis of soil samples and thin sections using petrographic, scanning electron microscope, electron microprobe and X-ray diffraction techniques. Mineralogical data were also compiled from the literature. These data were input to NETPATH, a geochemical program that calculates the masses of minerals that react with precipitation to produce stream water chemistry. The feasibilities of the weathering scenarios calculated by NETPATH were evaluated based on relative abundances and reactivities of minerals in the watershed. In watersheds underlain by reactive bedrocks, weathering reactions explained the stream base cation loading. In the acid-sensitive watersheds on unreactive bedrock, calculated weathering scenarios were not consistent with the abundance of reactive minerals in the underlying bedrock, and alternative sources of base cations are discussed.

Hydrological Processes↗