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At least 217 records · Page 12Linked to original sources

Uranium-lead isotopic ages from the Sierra Nevada Batholith, California

This study provides new information on the timing and distribution of Mesozoic magmatic events in the Sierra Nevada batholithic complex chiefly between 36° and 37°N. latitude. U-Pb ages have been determined for 133 zircon and 7 sphene separates from 82 samples of granitoid rocks. Granitoid rocks in this area range in age from 217 to 80 m.y. Triassic intrusions are restricted to the east side of the batholith; Jurassic plutons occur south of the Triassic plutons east of the Sierra Nevada, as isolated masses within the Cretaceous batholith, and in the western foothills of the range; Cretaceous plutons form a continuous belt along the axis of the batholith and occur as isolated masses east of the Sierra Nevada. No granitic intrusions were emplaced for 37 m.y. east of the Sierra Nevada following the end of Jurassic plutonism. However, following emplacement of the eastern Jurassic granitoids, regional extension produced a fracture system at least 350 km long into which the dominantly mafic, calc-alkalic Independence dike swarm was intruded 148 m.y. ago. The dike fractures probably represents a period of regional crustal extension caused by a redistribution of the regional stress pattern accompanying the Nevadan orogeny. Intrusion of Cretaceous granitic plutons began in large volume about 120 m.y. ago in the western Sierra Nevada and migrated steadily eastward for 40 m.y. at a rate of 2.7 mm/y. This slow and constant migration indicates remarkably uniform conditions of subduction with perhaps downward migration of parent magma generation or a slight flattening of the subduction zone. Such steady conditions could be necessary for the production of large batholithic complexes such as the Sierra Nevada. The abrupt termination of plutonism 80 m.y. ago may have resulted from an increased rate of convergence of the American and eastern Pacific plates and dramatic flattening of the subduction zone. U-Pb ages of the Giant Forest-alaskite sequence in Sequoia National Park are all in the range 99±3 m.y., indicating a relatively short period of emplacement and cooling for this nested group of plutons. U-Pb ages of a mafic inclusion and its host granodiorite indicate that both were derived from a common source or that the mafic inclusion was totally equilibrated with the granodioritic magma. Comparison of isotopic ages determined by different methods such as zircon U-Pb, sphene U-Pb, hornblende K-Ar, and biotite K-Ar suggests that zircon U-Pb ages generally approximate the emplacement age of a pluton. However, some plutons probably contain inherited or entrained old zircons, and the zircons of some samples are disturbed by younger thermal and metamorphic events. The ages reported here are consistent with U-Pb age determinations previously made on granitic rocks to the north [Stern et al., 1981], The age distribution of granitic belts determined here is in general agreement with those established by K-Ar dating [Evernden and Kistler, 1970] but does not differentiate the five epochs of plutonism determined in their study.

California

Denitrification in marine shales in northeastern Colorado

Parts of the South Platte River alluvial aquifer in northeastern Colorado are underlain by the Pierre Shale, a marine deposit of Late Cretaceous age that is <1000 m thick. Ground water in the aquifer is contaminated with NO 3 ‐ , and the shale contains abundant potential electron donors for denitrification in the forms of organic carbon and sulfide minerals. Nested piezometers were sampled, pore water was squeezed from cores of shale, and an injection test was conducted to determine if denitrification in the shale was a sink for alluvial NO 3 − and to measure denitrification rates in the shale. Measured values of NO 3 − , N 2 , NH 4 + , δ 15 N[NO 3 − ], δ 15 N[N 2 ], and δ 15 N[NH 4 + ] in the alluvial and shale pore water indicated that denitrification in the shale was a sink for alluvial NO 3 − . Chemical gradients, reaction rate constants, and hydraulic head data indicated that denitrification in the shale was limited by the slow rate of NO 3 − transport (possibly by diffusion) into the shale. The apparent in situ first‐order rate constant for denitrification in the shale based on diffusion calculations was of the order of 0.04–0.4 yr −1 , whereas the potential rate constant in the shale based on injection tests was of the order of 60 yr −1 . Chemical data and mass balance calculations indicate that organic carbon was the primary electron donor for denitrification in the shale during the injection test, and ferrous iron was a minor electron donor in the process. Flux calculations for the conditions encountered at the site indicate that denitrification in the shale could remove only a small fraction of the annual agricultural NO 3 ‐ input to the alluvial aquifer. However, the relatively large potential first‐order rate constant for denitrification in the shale indicated that the percentage of NO 3 − uptake by the shale could be considerably larger in areas where NO 3 − advection.

Colorado

Cretaceous planktic foraminiferal biostratigraphy of the Calera Limestone, Northern California, USA

The Calera Limestone is the largest, most stratigraphically extensive limestone unit of oceanic character included in the Franciscan Complex of northern California. The aim of this paper is to place the Calera Limestone at its type locality (Rockaway Beach, Pacifica) in a high-resolution biostratigraphy utilizing planktic foraminifers studied in thin section. A section, about 110 m-thick, was measured from the middle thrust slice exposed by quarrying on the southwest side of Calera Hill at Pacifica Quarry. Lithologically, the section is divided in two units; a lower unit with 73 m of black to dark-grey limestone, black chert and tuff, and an upper unit with 36.8 m of light-grey limestone and medium-grey chert. Two prominent black-shale layers rich in organic carbon occur 11 m below the top of the lower black unit and at the boundary with overlying light-grey unit, yielding a total organic content (TOC) of 4.7% and 1.8% t.w., respectively. The fossiliferous Calera Limestone section measured at Pacifica Quarry, from the lower black shale, contains eleven zones and three subzones that span approximately 26 m.y. from the early Aptian to the late Cenomanian. The zones indentified range from the Globigerinelloides blowi Zone to the Dicarinella algeriana Subzone of the Rotalipora cushmani Zone. Within this biostratigraphic interval, the Ticinella bejaouaensis and Hedbergella planispira Zones at the Aptian/Albian boundary are missing as are the Rotalipora subticinensis Subzone of the Biticinella breggiensis Zone and the overlying Rotalipora ticinensis Zone in the late Albian owing both to low-angle thrust faulting and to unconformities. The abundance and preservation of planktic foraminifers are poor in the lower part and improve only within the upper G. algerianus Zone. The faunal relationship indicate that the lower black shale occurs in the upper part of the G. blowi Zone and correlates with the Selli Event recognized at global scale in the early Aptian. The upper black shale occurs at or near the boundary between the G. ferreolensis and G. algerianus Zone in the late Aptian. This black layer, or Thalmann Event as named here, seems to represent the sedimentary expression, at the scale of Permanente Terrane, of a global perturbation of the carbon cycle.

Journal of Foraminiferal Research

The record of global change in mid-Cretaceous (Barremian-Albian) sections from the Sierra Madre, Northeastern Mexico

Our current understanding of mid-Cretaceous global change is largely based on investigations of pelagic sections from southern Europe and deep sea drilling sites. Much less information exists from other continents and from hemipelagic sections deposited on continental margins. This investigation seeks to broaden our understanding of mid-Cretaceous global change by focusing on the record from hemipelagic sections deposited along the continental margin of northeastern Mexico. The major goals are to compare the record, timing, and extent of the Oceanic Anoxic Events (OAEs) in Mexico and other areas, and to determine the relationship between these events and the global burial of organic material using carbon isotopes. We have investigated four sections from the Sierra Madre Oriental, integrating biostratigraphy, magnetostratigraphy and carbon isotope stratigraphy. Carbon isotopes, measured on the organic carbon (Corg) fraction, show identical stratigraphic changes to curves from Barremian to lower Albian European and Pacific deep-sea sections. Our results add new detail to the C-isotope stratigraphy of the middle and late Albian interval. Three abrupt peaks in Corg content correlate with OAE1a (early Aptian), OAE1b (early Albian) and an event in the late Aptian Globigerinelloides algerianus Zone. All three events are marked by short-term, 0.5-3 per mil decreases in C-isotope values followed by increases of similar magnitude. The decreases may reflect changes in the type of Corg, the nature of carbon cycling, or an increase in hydrothermal activity. The increases in C-isotope values reflect widespread burial of Corg. The similar shape of the C-isotope curves in Mexico and other areas, and the response of C-isotopes to the OAEs, indicate that the late Aptian episode was extensive, and that OAE1a and OAE1b were global. The three anoxic events appear to correlate with rising relative sea level. OAE1a also corresponds to major changes in nannofossil assemblages; the well-known "nannoconid crisis" can be easily recognized in the Mexican sections. This event is characterized by an increase in abundance of nannofossils and foraminifera in sediments, possibly reflecting a decrease in dilution as a result of the rise in relative sea level.

Journal of Foraminiferal Research

Diagenesis of lower Cretaceous pelagic carbonates, North Atlantic: Paleoceanographic signals obscured

The stable isotope and minor element geochemistry of Neocomian (Lower Cretaceous) pelagic carbonates of the North Atlantic Basin (Deep Sea Drilling Project Sites 105, 367, 387, 391, and 603) was examined to develop a diagenetic model for pelagic limestones. In particular, we hoped to test the fidelity of whole-rock geochemical records as paleoceanographic indicators for pelagic deposits of pre-Aptian age, in which individual microfossils are not available for analysis. Data indicate that in addition to depth of burial, rhythmic variations in primary carbonate content have strongly controlled diagenetic patterns and associated geochemical signatures in these Neocomian sequences. Samples become increasingly depleted in Sr and 18O with increasing CaCO3 content. Within individual sedimentary sections, substantial decreases in Sr/Ca ratios and ??18O values are evident over a range of 4 to 98% CaCO3. However, even over a relatively narrow range of 50 to 98% CaCO3 a 2.5%c variation in ??18O values and a change of a factor of 1.7 in Sr/Ca ratios are observed. Carbon isotope compositions do not vary as extensively with CaCO3 content, but carbonate-rich intervals tend to be relatively depleted in 13C. Petrographic analysis reveals that these geochemical patterns are related to the transfer of CaCO3 from carbonate-poor intervals (calcareous shales and marlstones) to adjacent carbonate-rich intervals (limestones) during burial compaction and pressure solution. This process results in the addition of diagenetic cement to carbonate-rich intervals to produce a bulk composition that is relatively depleted in Sr and 18O and, at the same time, enables the retention of more-or-less primary carbonate that is relatively enriched in Sr and 18O in adjacent carbonate-poor intervals. Thus, although cyclic variations in CaCO3 content are primary in the Neocomian sequences examined, measured variations in Sr/Ca ratios and ??18O values are not and, as such, do not provide reliable proxies for past variations in climate, oceanographic conditions, or global ice volume.

Journal of Foraminiferal Research

Sensitivity of the North Atlantic Basin to cyclic climatic forcing during the early Cretaceous

Striking cyclic interbeds of laminated dark-olive to black marlstone and bioturbated white to light-gray limestone of Neocomian (Early Cretaceous) age have been recovered at Deep Sea Drilling Project (DSDP) and Ocean Drilling Project (ODP) sites in the North Atlantic. These Neocomian sequences are equivalent to the Maiolica Formation that outcrops in the Tethyan regions of the Mediterranean and to thick limestone sequences of the Vocontian Trough of France. This lithologic unit marks the widespread deposition of biogenic carbonate over much of the North Atlantic and Tethyan seafloor during a time of overall low sealevel and a deep carbonate compensation depth. The dark clay-rich interbeds typically are rich in organic carbon (OC) with up to 5.5% OC in sequences in the eastern North Atlantic. These eastern North Atlantic sequences off northwest Africa, contain more abundant and better preserved hydrogen-rich, algal organic matter (type II kerogen) relative to the western North Atlantic, probably in response to coastal upwelling induced by an eastern boundary current in the young North Atlantic Ocean. The more abundant algal organic matter in sequences in the eastern North Atlantic is also expressed in the isotopic composition of the carbon in that organic matter. In contrast, organic matter in Neocomian sequences in the western North Atlantic along the continental margin of North America has geochemical and optical characteristics of herbaceous, woody, hydrogen-poor, humic, type III kerogen. The inorganic geochemical characteristics of the dark clay-rich (<60% CaCO3) interbeds in Neocomian sequences in the North American Basin and the Cape Verde Basin off northwest Africa suggest that most of the detrital clastic material was derived from deep-sea fans off North America and Morocco during relatively wet intervals to dilute pelagic biogenic carbonate. Inorganic geochemical characteristics of the clastic material in the bioturbated, white, carbonate-rich (>80% CaCO3) interbeds in both the eastern and western basins of the North Atlantic suggest that they contain minor amounts of relatively unweathered eolian dust derived from northwest Africa during dry intervals.

Journal of Foraminiferal Research

A methodology for the assessment of unconventional (continuous) resources with an application to the Greater Natural Buttes gas field, Utah

The Greater Natural Buttes tight natural gas field is an unconventional (continuous) accumulation in the Uinta Basin, Utah, that began production in the early 1950s from the Upper Cretaceous Mesaverde Group. Three years later, production was extended to the Eocene Wasatch Formation. With the exclusion of 1100 non-productive (“dry”) wells, we estimate that the final recovery from the 2500 producing wells existing in 2007 will be about 1.7 trillion standard cubic feet (TSCF) (48.2 billion cubic meters (BCM)). The use of estimated ultimate recovery (EUR) per well is common in assessments of unconventional resources, and it is one of the main sources of information to forecast undiscovered resources. Each calculated recovery value has an associated drainage area that generally varies from well to well and that can be mathematically subdivided into elemental subareas of constant size and shape called cells. Recovery per 5-acre cells at Greater Natural Buttes shows spatial correlation; hence, statistical approaches that ignore this correlation when inferring EUR values for untested cells do not take full advantage of all the information contained in the data. More critically, resulting models do not match the style of spatial EUR fluctuations observed in nature. This study takes a new approach by applying spatial statistics to model geographical variation of cell EUR taking into account spatial correlation and the influence of fractures. We applied sequential indicator simulation to model non-productive cells, while spatial mapping of cell EUR was obtained by applying sequential Gaussian simulation to provide multiple versions of reality (realizations) having equal chances of being the correct model. For each realization, summation of EUR in cells not drained by the existing wells allowed preparation of a stochastic prediction of undiscovered resources, which range between 2.6 and 3.4 TSCF (73.6 and 96.3 BCM) with a mean of 2.9 TSCF (82.1 BCM) for Greater Natural Buttes. A second approach illustrates the application of multiple-point simulation to assess a hypothetical frontier area for which there is no production information but which is regarded as being similar to Greater Natural Buttes.

Utah

Remarkable isotopic and trace element trends in potassic through sodic Cretaceous plutons of the Yukon-Koyukuk Basin, Alaska, and the nature of the lithosphere beneath the Koyukuk terrane

During the period from 110 to 80 m.y. ago, a 450-km-long magmatic belt was active along the northern margin of Yukon-Koyukuk basin and on eastern Seward Peninsula. The plutons intruded Upper Jurassic(?) and Lower Cretaceous volcanic arc rocks and Cretaceous sedimentary rocks in Yukon-Koyukuk basin and Proterozoic and lower Paleozoic continental rocks in Seward Peninsula. Within Yukon-Koyukuk basin, the plutons vary in composition from calc-alkalic plutons on the east to potassic and ultrapotassic alkalic plutons on the west. Plutons within Yukon-Koyukuk basin were analyzed for trace element and isotopic compositions in order to discern their origin and the nature of the underling lithosphere. Farthest to the east, the calc-alkalic rocks of Indian Mountain pluton are largely tonalite and sodic granodiorite, and have low Rb (average 82 ppm), high Sr (>600 ppm), high chondrite-normalized (cn) Ce/Yb (16&ndash;37), low &delta; 18 O (+6.5 to +7.1), low initial 87 Sr/ 86 Sr (SIR) (0.704), and high initial 143 Nd/ 144 Nd (NIR) (0.5126). These rocks resemble those modelled elsewhere as partial melts and subsequent fractionates of basaltic or gabbroic metaigneous rocks, and may be products of melting in the deeper parts of the Late Jurassic(?) and Early Cretaceous volcanic arc. Farthest to the west, the two ultrapotassic bodies of Selawik and Inland Lake are high in Cs (up to 93 ppm), Rb (up to 997 ppm), Sr, Ba, Th, and light rare earth elements, have high (Ce/Yb)cn (30, 27), moderate to low &delta; 18 O (+8.4, +6.9), high SIR (0.712, 0.710), and moderate NIR (0.5121&ndash;0.5122). These rocks resemble rocks of Australia and elsewhere that were modelled as melts of continental mantle that had been previously enriched in large cations. This mantle may be Paleozoic or older. The farthest west alkalic pluton of Selawik Hills is largely monzonite, quartz monzonite, and granite; has moderate Rb (average 284 ppm), high Sr (>600 ppm), high (Ce/Yb)cn (15&ndash;25), moderate &delta; 18 O (+8.3 to +8.6), high SIR (0.708&ndash;0.712), and moderate NIR (0.5121&ndash;0.5122). These rocks may be the product of interaction of magma derived from old continental mantle and magma derived from old continental crust. Plutons between eastern and western extremes show completely gradational variations in the concentration of K and Rb and in the isotopic compositions of Sr, Nd, and O. These plutons probably originated either by melting in a mixed source composed of a Paleozoic or older continental section (mantle + crust) overlain by Mesozoic mafic arc rocks, or by mixing of ultrapotassic to potassic magmas from continental sources (mantle + crust), and tonalitic magmas from arc sources. We infer from these results that the northwest portion of Yukon-Koyukuk basin is underlain by a substantial continental basement of Paleozoic or greater age. This basement probably thins out to the east. There is no geochemical evidence for continental basement east of about longitude 157&deg;, or along a belt of at least 50 km width flanking Ruby Geanticline as far to the southwest as about longitude 161&deg;. These areas are probably underlain by oceanic and Mesozoic arc rocks.

Alaska

Structural evidence for northeastward movement on the Chocolate Mountains Thrust, southeasternmost California

The Late Cretaceous Chocolate Mountains thrust of southeastern California and southwestern Arizona places a block of Proterozoic and Mesozoic continental crust over the late Mesozoic continental margin oceanic sedimentary and volcanic rocks of the regionally distinctive Orocopia Schist. The Chocolate Mountains thrust is interpreted as a thrust (burial, subduction) fault rather than a low-angle normal (exhumation, unroofing, uplift) fault. An important parameter required to understand the tectonic significance of the Chocolate Mountains and related thrusts is their sense of movement. The Chocolate Mountains thrust zone contains sparse to locally abundant mesoscopic asymmetric folds. Fabric relations, supported by regional geologic evidence, indicate that these folds are an integral part of and coeval with the thrust zone. On a lower hemisphere equal-area plot representing the orientation and sense of asymmetry of 80 thrust zone folds from 36 localities, spread over an area 60 by 10 km, Z folds plot northwest of and S folds plot southeast of a northeast-southwest striking vertical plane of overall monoclinic symmetry. The only sense of movement consistent with the collective asymmetry of the thrust zone folds is top to the northeast. Asymmetric microstructures studied at several localities also indicate top to the northeast movement. Paleomagnetic data suggest that the original sense of thrusting, prior to Neogene vertical axis tectonic rotation related to the San Andreas fault system, was northward. The essential point is that movement of the upper plate of the Chocolate Mountains thrust evidently was continentward. Continentward thrusting suggests a tectonic scenario in which an insular or peninsular microcontinental fragment collided with mainland southern California. The suture predicted by this model is elusive; but the Chocolate Mountains thrust and underlying Orocopia Schist themselves may represent the suture, at the present level of exposure. Alternative tectonic models involving subduction of the Orocopia Schist eastward beneath continental southern California circumvent the suture problem but are presently not supported by any direct structural evidence.

Journal of Geophysical Research

Summary appraisals of the nation's ground-water resources – Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snowfall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55&deg; to 118&deg; F (-48.3&deg; to 47.8&deg; C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important freshwater aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock aquifers generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5x10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Freshwater could be stored in saline- or freshwater aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use, and pollution.

Minnesota, Montana, North Dakota, South Dakota

Geology, geochemistry, and genesis of the Greens Creek massive sulfide deposit, Admiralty Island, southeastern Alaska

In 1996, a memorandum of understanding was signed by representatives of the U.S. Geological Survey and Kennecott Greens Creek Mining Company to initiate a cooperative applied research project focused on the Greens Creek massive sulfide deposit in southeastern Alaska. The goals of the project were consistent with the mandate of the U.S. Geological Survey Mineral Resources Program to maintain a leading role in national mineral deposits research and with the need of Kennecott Greens Creek Mining Company to further development of the Greens Creek deposit and similar deposits in Alaska and elsewhere. The memorandum enumerated four main research priorities: (1) characterization of protoliths for the wall rocks, and elucidation of their alteration histories, (2) determination of the ore mineralogy and paragenesis, including metal residences and metal zonation within the deposit, (3) determination of the ages of events important to ore formation using both geochronology and paleontology, and (4) development of computer models that would allow the deposit and its host rocks to be examined in detail in three dimensions. The work was carried out by numerous scientists of diverse expertise over a period of several years. The written results, which are contained in this Professional Paper, are presented by 21 authors: 13 from the U.S. Geological Survey, 4 from Kennecott Greens Creek Mining Company, 2 from academia, and 2 from consultants. The Greens Creek deposit (global resource of 24.2 million tons at an average grade of 13.9 percent zinc, 5.1 percent lead, 0.15 troy ounce per ton gold, and 19.2 troy ounces per ton silver at zero cutoff) formed in latest Triassic time during a brief period of rifting of the Alexander terrane. The deposit exhibits a range of syngenetic, diagenetic, and epigenetic features that are typical of volcanogenic (VMS), sedimentary exhalative (SEDEX), and Mississippi Valley-type (MVT) genetic models. In the earliest stages of rifting, formation of precious-metal-rich silica-barite-carbonate white ores began at low temperature in a shallow, subaqueous setting, probably a thin carbonate shelf on the flanks of the Alexander landmass. Epigenetic carbonate replacement textures in the footwall dolostones are overlain by stratiform silica-carbonate-barite-rich ores and indicate that early mineralization formed at and just beneath the paleo sea floor by mixing of a reduced, precious-metal-rich, base-metal-poor hydrothermal fluid with oxygenated seawater. As rifting intensified, the shelf was downfaulted and isolated as a graben. Isolation of the basin and onset of starved-basin shale sedimentation was concurrent with emplacement of mafic-ultramafic intrusives at shallow levels in the rift, resulting in an increasingly higher temperature and progressively more anoxic ore-forming environment. The formation of the main stage of massive sulfide ores began as the supply of bacterially reduced sulfur increased in the accumulating shales. As the main-stage mineralization intensified, shale sedimentation inundated the hydrothermal system, eventually forming a cap. Biogenic sulfate reduction supplied reduced sulfur to the base of the shales where mixing occurred with hot, base-metal-rich hydrothermal fluids. Ore deposition continued by destruction and epigenetic replacement of the early white ores in proximal areas and by inflation and diagenetic replacement of unlithified shale at the interface between the white ores and the base of the shale cap. Ore deposition waned as the shales became lithified and as the supply of bacterially reduced sulfur to the site of ore deposition ceased. The final stages of rifting resulted in the emplacement of mafic-ultramafic intrusive rocks into the Greens Creek system and extrusion of voluminous basaltic flows at the top of the Triassic section. Greenschist facies metamorphism during the Jurassic-Cretaceous accretion of the Alexander terrane to the continental margin resulted in recrystalli

Professional Paper

Geology of El Chichon volcano, Chiapas, Mexico

The (pre-1982) 850-m-high andesitic stratovolcano El Chicho??n, active during Pleistocene and Holocene time, is located in rugged, densely forested terrain in northcentral Chiapas, Me??xico. The nearest neighboring Holocene volcanoes are 275 km and 200 km to the southeast and northwest, respectively. El Chicho??n is built on Tertiary siltstone and sandstone, underlain by Cretaceous dolomitic limestone; a 4-km-deep bore hole near the east base of the volcano penetrated this limestone and continued 770 m into a sequence of Jurassic or Cretaceous evaporitic anhydrite and halite. The basement rocks are folded into generally northwest-trending anticlines and synclines. El Chicho??n is built over a small dome-like structure superposed on a syncline, and this structure may reflect cumulative deformation related to growth of a crustal magma reservoir beneath the volcano. The cone of El Chicho??n consists almost entirely of pyroclastic rocks. The pre-1982 cone is marked by a 1200-m-diameter (explosion?) crater on the southwest flank and a 1600-m-diameter crater apparently of similar origin at the summit, a lava dome partly fills each crater. The timing of cone and dome growth is poorly known. Field evidence indicates that the flank dome is older than the summit dome, and K-Ar ages from samples high on the cone suggest that the flank dome is older than about 276,000 years. At least three pyroclastic eruptions have occurred during the past 1250 radiocarbon years. Nearly all of the pyroclastic and dome rocks are moderately to highly porphyritic andesite, with plagioclase, hornblende and clinopyroxene the most common phenocrysts. Geologists who mapped El Chicho??n in 1980 and 1981 warned that the volcano posed a substantial hazard to the surrounding region. This warning was proven to be prophetic by violent eruptions that occurred in March and April of 1982. These eruptions blasted away nearly all of the summit dome, blanketed the surrounding region with tephra, and sent pyroclastic flows down radial drainages on the flanks of the cone; about 0.3 km3 of material (density of all products normalized to 2.6 g cm-3) was erupted. More debris entered the stratosphere than from any other volcanic eruption within at least the past two decades. Halite and a calcium sulfate mineral (anhydrite?) recovered from the stratospheric cloud, and anhydrite as a common accessory mineral in 1982 juvenile erupted products may reflect contamination of El Chicho??n magma by the evaporite sequence revealed by drilling. ?? 1984.

Journal of Volcanology and Geothermal Research

Petrology and geochronology of metamorphosed volcanic rocks and a middle Cretaceous volcanic neck in the east-central Sierra Nevada, California

Metamorphosed Mesozoic volcanic rocks from the east-central Sierra Nevada range in composition from basalt to rhyolite and have ages, based on whole rock Rb-Sr and U-Pb zircon dating, of about 237–224, 185, 163, 134, and 100 m.y. The major plutons of the batholith in this area are of Triassic (215–200 m.y.) and Cretaceous (94–80 m.y.) ages. Initial 87 Sr/ 86 Sr values for the metamorphosed volcanic rocks of the area are in the range from 0.7042 to 0.7058 and are generally different from the values for the surrounding batholithic rocks (0.7056–0.7066). A circular, zoned granitic pluton, with an outcrop area of 2.5 km 2 , similar in appearance to a ring dike complex, was apparently a conduit for some or possibly all of the middle-Cretaceous metamorphosed volcanic rocks exposed about 5 km to the south in the western part of the Ritter Range. Samples from the metamorphosed volcanic rocks and the pluton yield a Rb-Sr whole rock isochron age of 99.9 ± 2.2 m.y. with an initial 87 Sr/ 86 Sr of 0.7048 ± 0.0001. Major element variation diagrams of the pluton and volcanic rocks define coincident compositional trends. The pluton, intruded into Early Jurassic metamorphosed volcanic rocks (Rb-Sr whole rock isochron age of 185 ± 6 m.y., initial 87 / 86 Sr = 0.70474 ± 0.00009), is composed of a central body of granite that is intruded into and almost completely surrounded by a crescent-shaped outer rim of quartz monzodiorite. Contact relations between the granitic rocks, intrusive in some places and completely gradational at other places, indicate that the quartz monzodiorite was not completely crystallized prior to the intrusion of the granite. Modal minerology within the pluton is also consistent with this inferred crystallization history. The granitic rock textures are cataclastic, characterized by a groundmass of feldspar and quartz that surrounds larger grains of feldspar, hornblende, and biotite. Widely spaced aplite dikes from the granite intrude the quartz monzodiorite along the contact between the granitic rocks. The aplite dikes and interstitial alkali feldspar associated with myrmekite in the pluton, being undeformed, indicate crystallization of a small amount of silicate liquid after cataclasis. Aplite compositions suggest a minimum crystallization pressure of 0.5 kb (1–2 km); this depth is consistent with crystallization near the base of a large stratovolcano. The pluton is characterized by steep, linear features, defined by mineral clots and inclusions, that probably formed during the upward movement of the nearly crystallized magma in the volcanic conduit. The ages of volcanic events relative to the ages of the major intrusive epochs and the major element and isotopic compositions of the volcanic rocks relative to the major plutons indicate that the volcanic rocks are not simply or directly related to the major plutons in the Sierra Nevada.

Journal of Geophysical Research Solid Earth

Summary appraisals of the Nation's ground-water resources; Souris-Red-Rainy region

A broad-perspective analysis of the ground-water resources and present and possible future water development and management in the Souris-Red-Rainy Region is presented. The region includes the basins of the Souris River within Montana and North Dakota; the Red River of the North in South Dakota, North Dakota, and Minnesota; and the Rainy River within Minnesota. The region includes 59,645 square miles, mostly in North Dakota and Minnesota. The terrain is relatively flat, but ranges in altitude from 2,541 to 750 feet. Annual average precipitation ranges from 14 inches in the west to 28 inches in the east and about 75 percent of it is rain. The mean annual snow fall ranges from 32 inches in the west to 64 inches in the east. Temperatures range from -55&deg; to 118&deg;F (-48.3&deg; to 47.8&deg;C). Irrigation is needed at least part of the time to assure crop production, particularly in the western part of the region. Sand and gravel deposits in the drift form the most important fresh-water aquifers. Other aquifers are found in at least parts of the region in the Precambrian, Paleozoic, Cretaceous, and Tertiary rocks. The potentiometric surface in the bedrock generally decreases in altitude toward the Red River of the North, indicating that the general direction of ground-water movement is toward the river. Ground-water with less than 3,000 milligrams per liter dissolved solids is available throughout the region. Ground water with less than 1,000 milligrams per liter occurs in most of the region east of the Red River of the North and in most of the shallow aquifers west of the river. The total volume of water available from storage having less than 3,000 milligrams per liter dissolved solids is estimated to be 5 x 10 8 acre-feet. In addition to the fresh and slightly saline water, the region has abundant highly mineralized water that can be considered as a resource. Yields of wells in individual bedrock aquifers are generally less than 100 gallons per minute but locally yields may be as much as 500 gallons per minute and more. Yields in drift aquifers are frequently less than 100 gallons per minute but range from 5 to 1,000 gallons per minute. In a few places outwash yields more than 1,000 gallons per minute. Ground water is the sole or a primary source of water supply in much of the region, including supplies for irrigation, domestic and livestock, municipal, and industrial needs. Reportedly, the potential irrigation development is 1,550,000 acres, as compared with 50,200 acres in 1975. Both ground- and surface-water supplies would be required to meet these demands. Rural domestic and livestock water supplies are derived almost entirely from ground-water sources. Smaller communities and towns generally rely on ground water, and the cities and industries use ground water, surface water, or both. The municipalities using surface water generally depend upon reservoir storage. Water quality rather than quantity is the greater water-supply problem for many communities in the region. Increased demands on both ground-water and surface-water supplies likely will be made in the future. Storage of surface water in the ground-water reservoirs during times of surplus for withdrawal during times of scarcity would aid in meeting these demands. The surplus (flood) water is of better chemical quality than underlying ground water in parts of the western half of the region. Fresh water could be stored in saline- or fresh-water aquifers, and pumped out later, as needed. Thus, the ground-water reservoirs have a definite present and potential role in water management. To understand the hydrologic system for management purposes there is a need to determine more adequately the geologic and hydrologic characteristics of existing aquifers and the location of new aquifers. Also, as pumping and other stresses on any part of the hydrologic system affect other parts of the system, monitoring programs ideally should be started and maintained to detect changes and determine effects of the stresses. Many alternatives are available for managing water in the region. Some of these are operational and others are undergoing research. Adequate hydrologic information is needed to aid in solving problems of water supply, use and pollution.

Minnesota, Montana, North Dakota, South Dakota

Crustal structure of the Colorado Plateau, Arizona: Application of new long-offset seismic data analysis techniques

The Colorado Plateau is a large crustal block in the southwestern United States that has been raised intact nearly 2 km above sea level since Cretaceous marine sediments were deposited on its surface. Controversy exists concerning the thickness of the plateau crust and the source of its buoyancy. Interpretations of seismic data collected on the plateau vary as to whether the crust is closer to 40 or 50 km thick. A thick crust could support the observed topography of the Colorado Plateau isostatically, while a thinner crust would indicate the presence of an underlying low-density mantle. This paper reports results on long-offset seismic data collected during the 1989 segment of the U.S. Geological Survey Pacific to Arizona Crustal Experiment that extended from the Transition Zone into the Colorado Plateau in northwest Arizona. We apply two new methods to analyze long-offset data that employ finite difference travel time calculations: (1) a first-arrival time inverter to find upper crustal velocity structure and (2) a forward-modeling technique that allows the direct use of the inverted upper crustal solution in modeling secondary reflected arrivals. We find that the crustal thickness increases from 30 km beneath the metamorphic core complexes in the southern Basin and Range province to about 42 km beneath the northern Transition Zone and southern Colorado Plateau margin. We observe some crustal thinning (to ∼37 km thick) and slightly higher lower crustal velocities farther inboard; beneath the Kaibab uplift on the north rim of the Grand Canyon the crust thickens to a maximum of 48 km. We observe a nonuniform crustal thickness beneath the Colorado Plateau that varies by ∼15% and corresponds approximately to variations in topography with the thickest crust underlying the highest elevations. Crustal compositions (as inferred from seismic velocities) appear to be the same beneath the Colorado Plateau as those in the Basin and Range province to the southwest, implying that the plateau crust represents an unextended version of the Basin and Range. Some of the variability in crustal structure appears to correspond to preserved lithospheric discontinuities that date back to the Proterozoic Era.

Journal of Geophysical Research B: Solid Earth

Late Quaternary stratigraphy and depositional history of the Long Island Sound basin

The stratigraphy of Late Quaternary geologic units beneath Long Island Sound (LIS) is interpreted from 3,500 km of high-resolution, seismic-reflection profiles supplemented by vibracore data. Knowledge gained from onshore regional geologic studies and previous offshore investigations is also incorporated in these interpretations. Glacial deposits overlie and nearly fill an Inner Lowland which is floored by crystalline rocks in the north and bounded to the south by an irregular, north-facing cuesta scarp in Cretaceous Coastal-Plain strata. The thick glacial section consists largely of sediment that was deposited in glacial Lake Connecticut during the retreat of the last (late Wisconsin) ice sheet. Ice-marginal lacustrine fan deposits and submerged extensions of the southeastern Connecticut recessional moraines mark positions of the ice margin during systematic northward retreat. When the ice margin stood at positions just north of the present shoreline of Connecticut (17.6-16.5 ka), glacial Lake Connecticut was slightly larger than Long Island Sound is today. Ice-marginal deltas and near-ice marginal fluviodeltaic deposits occur along coastal Connecticut. Delta-building was diachronous; progressively younger deltas record northwesterly retreat of the ice margin and lowering lake levels. Distally from the deltas, varied lake-clays (up to 150 m thick) drape the underlying topography. The lake spillway cut across the Harbor Hill-Roanoke Point-Fishers Island-Charlestown end moraine at its lowest point just west of Fishers Island (The Race). Lake levels fell as the spillway notch was erosionally deepened, and gradually the lakebed became subaerially exposed. A largely preserved channel system cuts the lake-deposit surface; fluvial channel-fill sediments are overlain by estuarine sediments in the channel system. Perhaps as early as 15 ka, but no later than 13 ka, the sea entered the Basin through the channel at The Race and quickly transgressed westward via the lakebed channel system. As the sea rose further and spread throughout the Basin, a wave-cut surface was formed. Extensive marine deltaic deposits, up to 40 m thick, overlie the wave-cut marine unconformity in the east-central part of the Basin. These sediments were derived from erosion of the drained bed of Lake Hitchcock, in the Connecticut valley to the north, and were deposited in a -40-m relative sea at about 12.4 ka. Where quiet waters prevail, marine mud generally less than 15 m thick blankets the older deposits of the Basin. Elsewhere, especially in eastern LIS, tidal currents are actively reworking and transporting glacial and postglacial deposits.

Connecticut, New York

Chemistry of rock-forming minerals of the Cretaceous-Paleocene batholith in southwestern Japan and implications for magma genesis

Petrographic descriptions and electron microprobe analyses of minerals are presented for 35 specimens from seven suites chosen to examine the transition from magnetite series to ilmenite series granitoids along two transects across the Cretaceous-Paleocene Inner Zone batholith of southwestern Japan. Regularities in chemical compositions of amphiboles, biotites, and feldspars suggest that fundamentally similar processes produced the magmas that formed the two series. Constant or decreasing Fe/(Fe+Mg) for biotites and amphiboles with increasing host rock silica content, coupled with the absence of early formed magnetite and sphene, suggest that magnetite series rocks may have become oxidized during crystallization near the level of intrusion, through the processes of second boiling and differential loss of hydrogen. For the Daito-Yokota, magnetite series suite, Fe/(Fe+Mg) for biotites decreased from 0.48 to 0.37 as SiO 2 content of the host rock increased from 55.3 to 75.5 wt %; for an ilmenite series suite from the Takanawa Peninsula, Fe/(Fe+Mg) for biotites increased from 0.51 to 0.77 with an increase in host rock SiO 2 from 53.4 to 75.5. Detailed consideration of amphibole chemistry shows predominance of edenitic and tschermakitic substitution schemes as well as coupling between substitutions of Ti in octahedral sites and Al IV . Interrelations between amphibole and biotite chemistry show that Fe/(Fe+Mg) and Mn contents can be interpreted in terms of equilibration, whereas Ti content cannot. The chemistry of chlorites correlates well with that of biotites; primary and secondary muscovites are distinct in composition. Plagioclase in all studied suites shows igneous zoning appropriate to host rock composition; perthitic alkali feldspars in all samples have lost albite component, and temperatures based on the two-feldspar geothermometer are low. The biotite-apatite geothermometer is also inoperative for this group of samples because fully fluorinated apatites typically occur in biotites of modest F content. Whereas magnetites have reequilibrated, analyses of ilmenites for the representative Daito-Yokota and Takanawa suites corroborate biotite compositional data and suggest that f O2 probably differed by 2 to 3 orders of magnitude during crystallization of silica-rich magnetite and ilmenite series granites. Whole-rock chemistry supports mineral chemistry in suggesting that the studied granitoids have crystallized from magmas generated in a lower crustal environment in which mantle-derived magmas partially melted source materials with igneous characteristics.

Journal of Geophysical Research Solid Earth

Integrated provenance analysis of a complex orogenic terrane: Mesozoic uplift of the Bogda Shan and Inception of the Turpan-Hami Basin, NW China

We employ petrographic and advanced geochemical techniques to better document the evolution of the Turpan–Hami basin based on the unique geologic histories of the arc terranes that served as potential sources of Turpan–Hami deposits. First, a provenance study of Permian through Cretaceous sandstone of the Turpan–Hami basin reveals temporal and spatial changes in dominant source terranes that provided detritus to the basin. Volcanic-lithic-rich Upper Permian sandstone (mean Qm 19 F 18 Lt 63 ; Qp 7 Lvm 89 Lsm 4 ; Qm 48 P 39 K 13 ) followed by more quartzose compositions in Triassic sandstone (mean Qm 41 F 19 Lt 40 ; Qp 20 Lvm 75 Lsm 5 ; Qm 68 P 21 K 11 ) indicate progressive unroofing of the extinct northern and central Tian Shan arc terranes to the south of Turpan–Hami. A sharp change to sedimentary-lithic-rich Lower Jurassic sandstone (mean Qm 47 F 16 Lt 37 ; Qp 16 Lvm 42 Lsm 42 ; Qm 75 P 12 K 13 ) overlain by a return to volcanic–lithic-rich Middle Jurassic sandstone (mean Qm 39 F 21 Lt 40 ; Qp 14 Lvm 51 Lsm 35 ; Qm 65 P 21 K 14 ) points to the initial uplift and unroofing of the largely andesitic Bogda Shan to the north, which first shed its sedimentary cover as it emerged to become the partition between the Turpan–Hami and southern Junggar basins. Second, geochronological, trace-element, and Sm-Nd isotopic variations among granitoids in the late Paleozoic Tian Shan orogenic belt provide a further test of Mesozoic uplift of the Bogda Shan. On the basis of previous models of crustal compositions throughout the South, Central, and North Tian Shan, Bogda Shan, and East and West Junggar terranes, we infer that isotopically enriched granitic cobbles (average εNd i = −0.50, n = 6) contained in Lower Triassic deposits in the north-central Turpan–Hami basin were derived from the continental crustal Central Tian Shan terrane, south of Turpan–Hami, and not from the more oceanic North Tian Shan, Bogda Shan, and East and West Junggar terranes, north of the Turpan–Hami basin. We therefore infer that the ancestral Bogda Shan had not been uplifted by the Early Triassic, and that prior to this time, a unified Junggar–Turpan–Hami basin existed during Late Permian deposition of extensive lacustrine deposits

Turpan-Hami Basin