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At least 199 records · Page 11Linked to original sources

USGS2013

Naturally occurring contaminants in the Piedmont and Blue Ridge crystalline-rock aquifers and Piedmont Early Mesozoic basin siliciclastic-rock aquifers, eastern United States, 1994–2008

Groundwater quality and aquifer lithologies in the Piedmont and Blue Ridge Physiographic Provinces in the eastern United States vary widely as a result of complex geologic history. Bedrock composition (mineralogy) and geochemical conditions in the aquifer directly affect the occurrence (presence in rock and groundwater) and distribution (concentration and mobility) of potential naturally occurring contaminants, such as arsenic and radionuclides, in drinking water. To evaluate potential relations between aquifer lithology and the spatial distribution of naturally occurring contaminants, the crystalline-rock aquifers of the Piedmont and Blue Ridge Physiographic Provinces and the siliciclastic-rock aquifers of the Early Mesozoic basin of the Piedmont Physiographic Province were divided into 14 lithologic groups, each having from 1 to 16 lithochemical subgroups, based on primary rock type, mineralogy, and weathering potential. Groundwater-quality data collected by the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program from 1994 through 2008 from 346 wells and springs in various hydrogeologic and land-use settings from Georgia through New Jersey were compiled and analyzed for this study. Analyses for most constituents were for filtered samples, and, thus, the compiled data consist largely of dissolved concentrations. Concentrations were compared to criteria for protection of human health, such as U.S. Environmental Protection Agency (USEPA) drinking water maximum contaminant levels and secondary maximum contaminant levels or health-based screening levels developed by the USGS NAWQA Program in cooperation with the USEPA, the New Jersey Department of Environmental Protection, and Oregon Health & Science University. Correlations among constituent concentrations, pH, and oxidation-reduction (redox) conditions were used to infer geochemical controls on constituent mobility within the aquifers. Of the 23 trace-element constituents evaluated, arsenic, manganese, and zinc were detected in one or more water samples at concentrations greater than established human health-based criteria. Arsenic concentrations typically were less than 1 microgram per liter (µg/L) in most groundwater samples; however, concentrations of arsenic greater than 1 µg/L frequently were detected in groundwater from clastic lacustrine sedimentary rocks of the Early Mesozoic basin aquifers and from metamorphosed clastic sedimentary rocks of the Piedmont and Blue Ridge crystalline rock aquifers. Groundwater from these rock units had elevated pH compared to other rock units evaluated in this study. Of the nine samples for which arsenic concentration was greater than 10 µg/L, six were classified as oxic and three as anoxic, and seven had pH of 7.2 or greater. Manganese concentrations typically were less than 10 µg/L in most samples; however, 8.3 percent of samples from the Piedmont and Blue Ridge crystalline-rock aquifers and 3.0 percent of samples from the Early Mesozoic basin siliciclastic rock aquifers had manganese concentrations greater than the 300-µg/L health-based screening level. The positive correlation of manganese with iron and ammonia and the negative correlation of manganese with dissolved oxygen and nitrate are consistent with the reductive dissolution of manganese oxides in the aquifer. Zinc concentrations typically were less than 10 µg/L in the groundwater samples considered in the study, but 0.4 percent and 5.5 percent of the samples had concentrations greater than the health-based screening level of 2,000 µg/L and one-tenth of the health-based screening level, respectively. The mean rank concentration of zinc in groundwater from the quartz-rich sedimentary rock lithologic group was greater than that for other lithologic groups even after eliminating samples collected from wells constructed with galvanized casing. Approximately 90 percent of 275 groundwater samples had radon-222 concentrations that were greater than the proposed alternative maximum contaminant level of 300 picocuries per liter. In contrast, only 2.0 percent of 98 samples had combined radium (radium-226 plus radium-228) concentrations greater than the maximum contaminant level of 5.0 picocuries per liter, and 0.6 percent of 310 samples had uranium concentrations greater than the maximum contaminant level of 30 µg/L. Radon concentrations were highest in the Piedmont and Blue Ridge crystalline-rock aquifers, especially in granite, and elevated median concentrations were noted in the Piedmont Early Mesozoic basin aquifers, but without the extreme maximum concentrations found in the crystalline rocks (granites). Although the siliciclastic lithologies had a greater frequency of elevated uranium concentrations, radon and radium were commonly detected in water from both siliciclastic and crystalline lithologies. Uranium concentrations in groundwater from clastic sedimentary and clastic lacustrine/evaporite sedimentary lithologic groups within the Early Mesozoic basin aquifers, which had median concentrations of 3.6 and 3.1 µg/L, respectively, generally were higher than concentrations for other siliciclastic lithologic groups, which had median concentrations less than 1 µg/L. Although 89 percent of the 260 samples from crystalline-rock aquifers had uranium concentrations less than 1 µg/L, 0.8 percent had uranium concentrations greater than the 30-µg/L maximum contaminant level, and 6.5 percent had concentrations greater than 3 µg/L.

Alabama;Delaware;Georgia;Maryl;New Jersey;North Ca↗

USGS2021

Occurrence and distribution of PFAS in sampled source water of public drinking-water supplies in the surficial aquifer in Delaware, 2018; PFAS and groundwater age-dating results

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (1) describe the occurrence and distribution of PFAS, and (2) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Delaware Coastal Plain between 2000 and 2008 and between 2008 and 2018. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November 2018. Groundwater collected from the wells was analyzed for the occurrence and distribution of 18 per- and polyfluorinated alkyl substances (PFAS) as well as groundwater age. Descriptive statistical analyses were performed to assess PFAS analytical results within the well network and the combined perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) concentrations were compared to the U.S. Environmental Protection Agency’s (EPA) health advisory level (HAL) for informational purposes only and not for evidence of compliance or noncompliance with Federal regulations. The EPA’s HAL is a health-based reference level for public drinking water as supplied to customers and is not applied to source (raw) water. Groundwater-age data were compared for sites sampled in 2000, 2008, and 2018 to document any changes. All samples were analyzed for 18 PFAS using EPA Method 537 (modified). Forty-four percent of the analyzed PFAS were detected in the study well network. Sixteen of the sampled wells have one or more PFAS detections, and as many as eight different PFAS were found in a single sample. Wells with a higher number of PFAS detected (five or more) were in New Castle and Sussex Counties. The PFAS most frequently detected were PFOA, with 47 percent detection; perfluorohexanoic acid (PFHxA), with 33 percent detection; and PFOS and perfluorohexane sulfonate (PFHxS), with 27 percent detection each. PFAS concentrations were below 1,000 parts per trillion (ppt). Two wells exceeded the EPA’s lifetime-drinking water health advisory level of 70 ppt for combined concentrations of PFOA and PFOS. The average age of groundwater entering the screens of the supply wells sampled in 2018 ranged from 8.2 to 45.8 years, with a median groundwater age of 25.7 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Groundwater age and PFAS concentrations were negatively correlated in the Columbia aquifer. Data from the 23 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2018 was generally 5 years older than the average groundwater age from samples collected in 2008. The same pattern was found during cycle two (2008) of this study, where the 2008 groundwater age was on average 7 years older than the samples collected in 2000. The distribution of groundwater sample ages among the 17 trend wells and during the three study cycles (2000, 2008, and 2018) indicates that sample-age medians were statistically different from zero; well-water sample-age data show a slight increase in groundwater sample age.

Delaware↗

USGS2013

Analysis and simulation of regional subsidence accompanying groundwater abstraction and compaction of susceptible aquifer systems in the USA

Regional aquifer-system compaction and land subsidence accompanying groundwater abstraction in susceptible aquifer systems in the USA is a challenge for managing groundwater resources and mitigating associated hazards. Developments in the assessment of regional subsidence provide more information to constrain analyses and simulation of aquifer-system compaction. Current popular approaches to simulating vertical aquifer-system deformation (compaction), such as those embodied in the aquitard drainage model and the MODFLOW subsidence packages, have proven useful from the perspective of regional groundwater resources assessment. However, these approaches inadequately address related local-scale hazards-ground ruptures and damages to engineered structures on the land surface arising from tensional stresses and strains accompanying groundwater abstraction. This paper presents a brief overview of the general approaches taken by the U.S. Geological Survey toward understanding aquifer-system compaction and subsidence with regard to a) identifying the affected aquifer systems; b) making regional assessments; c) analyzing the governing processes; and d) simulating historical and future groundwater flow and subsidence conditions. Limitations and shortcomings of these approaches, as well as future challenges also are discussed.

Boletín de la Sociedad Geológica Mexicana↗

USGS1987

Ground-water resources of Jones County, Mississippi

Jones County, Mississippi, is supplied with groundwater from aquifers in strata of Eocene and younger age. The largest groundwater withdrawals are from aquifers in the Catahoula Sandstone of the Miocene aquifer system that occur at depths of 200 and 400 ft in the Laurel area. Several public and industrial water supply wells obtain water from deeper Eocene strata that occur at depths of more than 900 ft. Pumpage from all aquifers in Jones County for all uses increased from < 1 million gal/day (mgd) in 1925 to a maximum of 21.6 mgd in 1975. The city of Laurel used about 6.2 mgd in 1984 and total water use for the county was about 14.1 mgd. The extreme irregularity of the sand beds that form the aquifers is reflected in the wide range in hydraulic characteristics. Transmissivity values range from 600 to 10,000 sq ft/day and average about 6,000 sq ft/day. The average hydraulic conductivity is about 90 ft/day. Water levels in key observation wells in the lower Catahoula aquifer at Laurel have declined from about 150 ft above sea level in 1945 to about 80 ft above sea level in 1985. Since 1975, water levels in the Catahoula aquifers in the Laurel area have declined at a slower rate, but the cone of depression has enlarged because of areal changes in pumping. Water in the major aquifers is usable for most purposes, and concentrations of common constituents do not exceed water quality criteria for drinking water supplies. Iron concentrations are highest in the Catahoula and Vicksburg aquifers, exceeding 0.30 mg/L in water from 33% of the wells for which data are available. Color is highest in the Eocene Cockfield aquifer, exceeding 50 units in water from 60% of the wells. Dissolved solids concentrations range from 487 to 840 mg/L in water from wells in the Cockfield and Sparta aquifers. The pH values generally are < 7.0 in water from wells in the Catahoula and Vicksburg aquifers and > 8.4 in water from wells in the Cockfield and Sparta aquifers. Hardness of water from all aquifers rarely exceeds 50 mg/L. (Lantz-PTT)

Water-Resources Investigations Report↗

USGS2015

Geochemical evolution of groundwater in the Mud Lake area, eastern Idaho, USA

Groundwater with elevated dissolved-solids concentrations—containing large concentrations of chloride, sodium, sulfate, and calcium—is present in the Mud Lake area of Eastern Idaho. The source of these solutes is unknown; however, an understanding of the geochemical sources and processes controlling their presence in groundwater in the Mud Lake area is needed to better understand the geochemical sources and processes controlling the water quality of groundwater at the Idaho National Laboratory. The geochemical sources and processes controlling the water quality of groundwater in the Mud Lake area were determined by investigating the geology, hydrology, land use, and groundwater geochemistry in the Mud Lake area, proposing sources for solutes, and testing the proposed sources through geochemical modeling with PHREEQC. Modeling indicated that sources of water to the eastern Snake River Plain aquifer were groundwater from the Beaverhead Mountains and the Camas Creek drainage basin; surface water from Medicine Lodge and Camas Creeks, Mud Lake, and irrigation water; and upward flow of geothermal water from beneath the aquifer. Mixing of groundwater with surface water or other groundwater occurred throughout the aquifer. Carbonate reactions, silicate weathering, and dissolution of evaporite minerals and fertilizer explain most of the changes in chemistry in the aquifer. Redox reactions, cation exchange, and evaporation were locally important. The source of large concentrations of chloride, sodium, sulfate, and calcium was evaporite deposits in the unsaturated zone associated with Pleistocene Lake Terreton. Large amounts of chloride, sodium, sulfate, and calcium are added to groundwater from irrigation water infiltrating through lake bed sediments containing evaporite deposits and the resultant dissolution of gypsum, halite, sylvite, and bischofite.

Idaho↗

USGS2023

Karst groundwater vulnerability determined by modeled age and residence time tracers

Karst aquifers are a vital groundwater resource globally, but features such as rapid recharge and conduit flow make them highly vulnerable to land-surface contamination. We apply environmental age tracers to the south-central Texas Edwards aquifer, a karst resource in a rapidly urbanizing and drought-prone region, to assess vulnerability to land-surface contamination and risks unique to karst aquifers. We show that vulnerability of Edwards aquifer groundwater follows similar spatial and depth patterns common to porous-media type aquifers, despite complicated karst hydrogeologic features. Shallow and unconfined parts are more vulnerable to land-surface contamination than the deeper and confined parts, although even the oldest groundwater is mixed with some recent recharge. When modeled age-tracer results are coupled with other independent geochemical tracers of water-rock interaction specific to karst settings, they can yield insight into residence time and associated vulnerability.

Texas↗

USGS1999

Management of groundwater supply and water quality in the Los Angeles Basin, California

Water use and water needs in the coastal Los Angeles Basin in California have been very closely tied to the development of the region during the last 150 years. The first water wells were drilled in the mid-1800s. Currently about 40% of the water supply (9.4 m3 s-1) in the region is provided by groundwater. Other sources of water supply include reclaimed water and surface water imported from Owens Valley, the Colorado River, and northern California. Increasing groundwater use in the basin led to over-abstraction and seawater instrusion. Because of this, an important component of water management in the area has been the artificial recharge of local, imported, and reclaimed water which is spread in ponds and injected in wells to recharge the aquifer system and control seawater intrusion. The US Geological Survey (USGS) is working co-operatively with the Water Replenishment District of Southern California to evaluate the hydraulic and water-quality effects of these recharge operations and to assess the potential impacts of alternative water-management strategies, including changes in pumping and increases in the use of reclaimed water. As part of this work, the USGS has developed a geographic information system (GIS), collected water-quality and geohydrological data from new and existing wells, and developed a multi-aquifer regional groundwater flow model. Chemical and isotopic data were used to identify the age and source of recharge to groundwater throughout the study area. This information is key to understanding the fate of artificially recharged water and helps define the three-dimensional groundwater flow system. The geohydrological data, especially the geophysical and geological data collected from 11 newly installed multi-completion monitoring wells, were used to redefine the regional hydrostratigraphy. The groundwater flow model is being used to enhance the understanding of the geohydrological system and to quantitatively evaluate new water-management strategies.As part of the work aimed at evaluating the hydraulic and water-quality effects of recharge operations and to assess the potential impacts of alternative water-management strategies, the US Geological Survey (USGS), has developed a geographic information system (GIS), collected water-quality and geohydrological data from new and existing wells, and developed a multi-aquifer regional groundwater flow model. At present, the developed model is being used to enhance the understanding of the geohydrological system and to quantitatively evaluate new water-management strategies.

Conference Paper↗

USGS2014

Characterization of the structure, clean-sand percentage, dissolved-solids concentrations, and estimated quantity of groundwater in the Upper Cretaceous Nacatoch Sand and Tokio Formation, Arkansas

The West Gulf Coastal Plain, Mississippi embayment, and underlying Cretaceous aquifers are rich in water resources; however, large parts of the aquifers are largely unusable because of large concentrations of dissolved solids. Cretaceous aquifers are known to have large concentrations of salinity in some parts of Arkansas. The Nacatoch Sand and the Tokio Formation of Upper Cretaceous age were chosen for investigation because these aquifers produce groundwater to wells near their outcrops and have large salinity concentrations away from their outcrop areas. Previous investigations have indicated that dissolved-solids concentrations of groundwater within the Nacatoch Sand, 2–20 miles downdip from the outcrop, render the groundwater as unusable for purposes requiring freshwater. Groundwater within the Tokio Formation also exhibits large concentrations of dissolved solids downdip. Water-quality data showing elevated dissolved-solids concentrations are limited for these Cretaceous aquifers because other shallower aquifers are used for water supply. Although not suitable for many uses, large, unused amounts of saline groundwater are present in these aquifers. Historical borehole geophysical logs were used to determine the geologic and hydrogeologic properties of these Cretaceous aquifers, as well as the quality of the groundwater within the aquifers. Based on the interpretation of borehole geophysical logs, in Arkansas, the altitude of the top of the Nacatoch Sand ranges from more than 200 to less than -4,000 feet; the structural high occurs in the outcrop area and the structural low occurs in southeastern Arkansas near the Desha Basin structural feature. The thickness of the Nacatoch Sand ranges from 0 to over 550 feet. The minimum thickness occurs where the formation pinches out in the outcrop area, and the maximum thickness occurs in the southwestern corner of Arkansas. Other areas of large thickness include the area of the Desha Basin structural feature in southeastern Arkansas and in an area on the border of Cross and St. Francis Counties in eastern Arkansas. The clean-sand percentage of the total Nacatoch Sand thickness ranges from less than 20 percent to more than 60 percent and generally decreases downdip. The Nacatoch Sand contains more than 120.5 million acre-feet of water with a dissolved-solids concentration between 1,000 and 10,000 milligrams per liter (mg/L), more than 57.5 million acre-feet of water with a dissolved-solids concentration between 10,000 and 35,000 mg/L, and more than 122.5 million acre-feet of water with a dissolved-solids concentration more than 35,000 mg/L. The altitude of the top of the Tokio Formation, in Arkansas, ranges from more than 200 feet to less than -4,400 feet; the structural high occurs in the outcrop area and the structural low occurs in southeastern Arkansas near the Desha Basin structural feature. The thickness of the Tokio Formation, in Arkansas, ranges from 0 to over 400 feet. The minimum thickness occurs where the formation pinches out in the outcrop area, and the maximum thickness occurs in the southwestern corner of Arkansas. The clean-sand percentage of the total Tokio Formation thickness ranges from less than 20 percent to more than 60 percent and generally decreases away from the outcrop area. The Tokio Formation contains more than 2.5 million acre-feet of water with a dissolved-solids concentration between 1,000 and 10,000 mg/L, more than 12.5 million acre-feet of water with a dissolved-solids concentration between 10,000 and 35,000 mg/L, and nearly 43.5 million acre-feet of water with a dissolved-solids concentration more than 35,000 mg/L.

Arkansas↗

USGS2011

Assessing groundwater availability in the Northern Atlantic Coastal Plain aquifer system

The U.S. Geological Survey's Groundwater Resources Program is conducting an assessment of groundwater availability throughout the United States to gain a better understanding of the status of the Nation's groundwater resources and how changes in land use, water use, and climate may affect those resources. The goal of this National assessment is to improve our ability to forecast water availability for future economic and environmental uses. Assessments will be completed for the Nation's principal aquifer systems to help characterize how much water is currently available, how water availability is changing, and how much water we can expect to have in the future (Reilly and others, 2008). The concept of groundwater availability is more than just how much water can be pumped from any given aquifer. Groundwater availability is a function of many factors, including the quantity and quality of water and the laws, regulations, economics, and environmental factors that control its use. The primary objective of the North Atlantic Coastal Plain groundwater-availability study is to identify spatial and temporal changes in the overall water budget by more fully determining the natural and human processes that control how water enters, moves through, and leaves the groundwater system. Development of tools such as numerical models can help hydrologists gain an understanding of this groundwater system, allowing forecasts to be made about the response of this system to natural and human stresses, and water quality and ecosystem health to be analyzed, throughout the region.

Fact Sheet↗

USGS2010

Quality of groundwater at and near an aquifer storage and recovery site, Bexar, Atascosa, and Wilson Counties, Texas, June 2004-August 2008

The U.S. Geological Survey, in cooperation with the San Antonio Water System, did a study during 2004–08 to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near an aquifer storage and recovery (ASR) site in Bexar, Atascosa, and Wilson Counties, Texas. Groundwater samples were collected and analyzed for selected physical properties and constituents to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near the ASR site. Geochemical and isotope data indicated no substantial changes in major-ion, trace-element, and isotope chemistry occurred as the water from the Edwards aquifer was transferred through a 38-mile pipeline to the aquifer storage and recovery site. The samples collected from the four ASR recovery wells were similar in major-ion and stable isotope chemistry compared to the samples collected from the Edwards aquifer source wells and the ASR injection well. The similarity could indicate that as Edwards aquifer water was injected, it displaced native Carrizo aquifer water, or, alternatively, if mixing of Edwards and Carrizo aquifer waters was occurring, the major-ion and stable isotope signatures for the Carrizo aquifer water might have been obscured by the signatures of the injected Edwards aquifer water. Differences in the dissolved iron and dissolved manganese concentrations indicate that either minor amounts of mixing occurred between the waters from the two aquifers, or as Edwards aquifer water displaced Carrizo aquifer water it dissolved the iron and manganese directly from the Carrizo Sand. Concentrations of radium-226 in the samples collected at the ASR recovery wells were smaller than the concentrations in samples collected from the Edwards aquifer source wells and from the ASR injection well. The smaller radium-226 concentrations in the samples collected from the ASR recovery wells likely indicate some degree of mixing of the two waters occurred rather than continued decay of radium-226 in the injected water. Geochemical and isotope data measured in samples collected in May 2005 from two Carrizo aquifer monitoring wells and in July 2008 from the three ASR production-only wells in the northern section of the ASR site indicate that injected Edwards aquifer water had not migrated to these five sites. Geochemical and isotope data measured in samples collected from Carrizo aquifer wells in 2004, 2005, and 2008 were graphically analyzed to determine if changes in chemistry could be detected. Major-ion, trace element, and isotope chemistry varied spatially in the samples collected from the Carrizo aquifer. With the exception of a few samples, major-ion concentrations measured in samples collected in Carrizo aquifer wells in 2004, 2005, and 2008 were similar. A slightly larger sulfate concentration and a slightly smaller bicarbonate concentration were measured in samples collected in 2005 and 2008 from well NC1 compared to samples collected at well NC1 in 2004. Larger sodium concentrations and smaller calcium, magnesium, bicarbonate, and sulfate concentrations were measured in samples collected in 2008 from well WC1 than in samples collected at this well in 2004 and 2005. Larger calcium and magnesium concentrations and a smaller sodium concentration were measured in the samples collected in 2008 at well EC2 compared to samples collected at this well in 2004 and 2005. While in some cases the computed percent differences (compared to concentrations from June 2004) in dissolved iron and dissolved manganese concentrations in 11 wells sampled in the Carrizo aquifer in 2005 and 2008 were quite large, no trends that might have been caused by migration of injected Edwards aquifer water were observed. Because of the natural variation in geochemical data in the Carrizo aquifer and the small data set collected for this study, differences in major-ion and trace element data among the samples collected in 2004, 2005 and 2008 cannot be directly attributed to the ASR site operations. When the data were analyzed graphically, no appreciable differences in isotope concentrations were observed between samples collected in 2004 and 2008 from Carrizo aquifer wells, indicating that the Edwards aquifer source water might not have affected the isotope chemistry of the native Carrizo aquifer water near the sampled Carrizo wells by July 2008.

Texas↗

USGS2009

Hydrogeology and Groundwater Resources of the Coastal Aquifers of Southeastern Massachusetts

The glacially derived aquifer systems of southeastern Massachusetts compose the largest groundwater reservoir in the State. Population increases, land-use changes, and climate change in this area could lead to three primary environmental effects that relate directly to groundwater resources - (1) increases in pumping that could adversely affect environmentally sensitive groundwater-fed surface waters, such as ponds, streams, and wetlands; (2) changes in land use that could affect the quality of water in the aquifer; and (3) changes in precipitation and mean sea level that can affect water levels, streamflow, and the position of the freshwater/saltwater boundary. Therefore, understanding groundwater flow and the factors that can affect it is critical to managing and protecting this vital resource.

Circular↗

USGS2023

Volcanic aquifers of Hawaiʻi—Contributions to assessing groundwater availability on Kauaʻi, Oʻahu, and Maui

The volcanic aquifers of the Hawaiian Islands supply water to 1.46 million residents, diverse industries, and a large component of the U.S. military in the Pacific. Groundwater also supplies fresh water that supports ecosystems in streams and near the coast. Hawaii’s aquifers are remarkably productive given their small size, but the capacity of the islands to store fresh groundwater is limited because each island is surrounded by seawater, and salt water underlies much of the fresh groundwater. The amount of fresh groundwater available for human use from Hawai‘i’s volcanic aquifers is constrained by the consequences of groundwater withdrawal. Restrictions placed on these consequences can translate to limitations on groundwater availability. Changes in recharge resulting from changes in land cover or climate can alter the effect of withdrawals. This study uses numerical models of the volcanic aquifers of the islands of Kaua‘i, O‘ahu, and Maui to quantify the consequences of historical and plausible future withdrawals and changes in recharge. The study compares the results of model simulations of multiple scenarios of historical and projected future withdrawal and recharge. Results of the simulations using the groundwater models of the islands of Kaua‘i, O‘ahu, and Maui have implications for other islands in Hawai‘i. Since the first modern water well was drilled in Hawai‘i in 1879, total groundwater withdrawals on Kaua‘i, O‘ahu, and Maui have risen to nearly 400 million gallons per day. Model simulations indicate that these withdrawals have caused reductions in groundwater discharge to streams and springs, reductions in groundwater discharge to the ocean, changes in subsurface flow between sectors within an island, lowering of groundwater levels, and rise of the interface between fresh water and salt water in the aquifers. Future increases in withdrawals will increase the severity of the consequences. Changes in recharge can alter the effect of withdrawals—increases in recharge can offset the consequences of withdrawals, whereas decreases in recharge can exacerbate the effects of withdrawals. This study quantifies the consequences of withdrawals for past and plausible future circumstances. The models can be used to test other circumstances. Limits placed on the consequences of withdrawals—such as restrictions to protect stream or coastal ecosystems that rely on groundwater discharge and limitations on water-level decline and rise of the freshwater-saltwater interface to protect the productivity of existing wells—can translate to limits on groundwater availability from Hawai‘i’s volcanic aquifers. Setting acceptable limits to the consequences of groundwater withdrawal is also a critical part of assessing groundwater availability. Once these limits are set, numerical models can be used to quantify the amount of water that can be withdrawn within those limits and thereby inform management decisions that seek to balance the need to limit the consequences of groundwater withdrawals with the need to develop water for human use.

Hawaii↗

USGS2012

Hydrologic conditions, groundwater quality, and analysis of sink hole formation in the Albany area of Dougherty County, Georgia, 2009

The U.S. Geological Survey, in cooperation with the Albany Water, Gas, and Light Commission has conducted water resources investigations and monitored groundwater conditions and availability in the Albany, Georgia, area since 1977. This report presents an overview of hydrologic conditions, water quality, and groundwater studies in the Albany area of Dougherty County, Georgia, during 2009. Historical data also are presented for comparison with 2009 data. During 2009, groundwater-level data were collected in 29 wells in the Albany area to monitor water-level trends in the surficial, Upper Floridan, Claiborne, Clayton, and Providence aquifers. Groundwater-level data from 21 of the 29 wells indicated an increasing trend during 2008–09. Five wells show no trend due to lack of data and three wells have decreasing trends. Period-of-record water levels (period of record ranged between 1957–2009 and 2003–2009) declined slightly in 10 wells and increased slightly in 4 wells tapping the Upper Floridan aquifer; declined in 1 well and increased in 2 wells tapping the Claiborne aquifer; declined in 4 wells and increased in 2 wells tapping the Clayton aquifer; and increased in 1 well tapping the Providence aquifer. Analyses of groundwater samples collected during 2009 from 12 wells in the Upper Floridan aquifer in the vicinity of a well field located southwest of Albany indicate that overall concentrations of nitrate plus nitrite as nitrogen increased slightly from 2008 in 8 wells. A maximum concentration of 12.9 milligrams per liter was found in a groundwater sample from a well located upgradient from the well field. The distinct difference in chemical constituents of water samples collected from the Flint River and samples collected from wells located in the well-field area southwest of Albany indicates that little water exchange occurs between the Upper Floridan aquifer and Flint River where the river flows adjacent to, but downgradient of, the well field. Water-quality data collected during 2008 from two municipal wells located in northern Albany and downgradient from a hazardous waste site indicate low-level concentrations of pesticides in one of the wells; however, no pesticides were detected in samples collected during 2009. Detailed geologic cross sections were used to create a three-dimensional, hydrogeologic diagram of the well field southwest of Albany in order to examine the occurrence of subsurface features conducive to sinkhole formation. Monitored groundwater-level data were used to assess the possible relations between sinkhole formation, precipitation, and water levels in the Upper Floridan aquifer. Although the water levels in well 12L382 oscillated above and below the top of the aquifer on a regular basis between 2007 and 2009, sinkhole development did not appear to correlate directly with either well-field pumping or water levels in the Upper Floridan aquifer. Specifically, two sinkholes formed in each of the years 2003 and 2005 when water levels were almost 20 feet above the top of the aquifer during most of the year. Water-level and sinkhole-formation data continue to be collected to allow further study and analysis.

Georgia↗

USGS2015

Hydrogeologic framework, hydrology, and refined conceptual model of groundwater flow for Coastal Plain aquifers at the Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2005-12

From 1966 to 2002, activities at the Standard Chlorine of Delaware chemical facility in New Castle County, Delaware resulted in the contamination of groundwater, soils, and wetland sediment. In 2005, the U.S. Geological Survey (USGS), in partnership with the U.S. Environmental Protection Agency, Region 3, and the Delaware Department of Natural Resources and Environmental Control began a multi-year investigation of the hydrogeologic framework and hydrology of the confined aquifer system. The goals of the ongoing study at the site (the Potomac Aquifer Study) are to determine the hydraulic connection between the Columbia and Potomac aquifers, determine the direction of groundwater flow in the Potomac aquifer, and identify factors affecting the fate of contaminated groundwater. This report describes progress made towards these goals based on available data collected through September 2012. The regional hydrogeologic framework indicates that the site is underlain by Coastal Plain sediments of the Columbia, Merchantville, and Potomac Formations. Two primary aquifers underlying the site, the Columbia and the upper Potomac, are separated by the Merchantville Formation confining unit. Local groundwater flow in the surficial (Columbia) aquifer is controlled by topography and generally flows northward and discharges to nearby surface water. Regional flow within the Potomac aquifer is towards the southeast, and is strongly influenced by major water withdrawals locally. Previous investigations at the site indicated that contaminants, primarily benzene and chlorinated benzene compounds, were present in the Columbia aquifer in most locations; however, there were only limited detections in the upper Potomac aquifer as of 2004. From 2005 through 2012, the USGS designed a monitoring network, assisted with exploratory drilling, collected data at monitoring wells, conducted geophysical surveys, evaluated water-level responses in wells during pumping of a production well, and evaluated major aquifer withdrawals. Data collected through these efforts were used to refine the local conceptual flow system. The refined conceptual flow system for the site includes: (a) identification of gaps in confining units in the study area, (b) identification and correlation of multiple water-bearing sand intervals within the upper Potomac Formation, (c) connections between groundwater and surface water, (d) connections between shallow and deeper groundwater, (e) new water-level (or potentiometric surface) maps and inferred flow directions, and (f) identification of major local pumping well influences. The implications of the revised conceptual flow system on the occurrence and movement of site contaminants are that the resulting detection of contaminants in the upper Potomac aquifer at specific well locations can be attributed primarily to either advective lateral transport, direct vertical contaminant transport, or a combination of vertical and lateral movement resulting from changes in water withdrawal rates over time.

Delaware↗

USGS2020

Water-quality comparison of the Gulf Coast aquifer system and Carrizo-Wilcox aquifer in Texas from National Water-Quality Assessment Project Principal Aquifer Surveys, 2013 and 2015

The U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Project assessed the quality of groundwater in aquifers that are important sources of drinking water in the United States. One major aquifer in Texas that was assessed by NAWQA in 2013 is the coastal lowlands aquifer system, which is often referred to in Texas as the “Gulf Coast aquifer system.” The coastal lowlands aquifer system supplies water for millions of people; self-supplied (private) well withdrawals in 2005 from this aquifer system were the sixth largest among all major aquifer systems in the Nation. A major aquifer in Texas that was assessed by NAWQA in 2015 is the Texas coastal uplands aquifer system; the Carrizo-Wilcox aquifer is one of several aquifers that compose this aquifer system in Texas. The rocks composing the Texas coastal uplands aquifer system extend east from Texas as part of the Mississippi embayment aquifer system and underlie areas of several States. The Texas coastal uplands aquifer system and Mississippi embayment aquifer system are often collectively referred to as the “Mississippi embayment-Texas coastal uplands aquifer system.” Self-supplied withdrawals from the Mississippi embayment-Texas coastal uplands aquifer system in 2005 were the eighth largest among all major aquifer systems in the Nation. The coastal lowlands aquifer system and Mississippi embayment-Texas coastal uplands aquifer system were assessed as part of the NAWQA Principal Aquifer Surveys (PAS), which were designed to evaluate constituent concentrations in water samples obtained from domestic and public-supply wells prior to any treatment. PAS assessments like these allow for the comparison of water-quality concentrations in untreated groundwater using preestablished benchmarks for the protection of human health and for aesthetic qualities such as taste, color, and odor. The use of preestablished benchmarks can provide a basis for comparison of groundwater quality among principal aquifers.

Texas↗

USGS2022

Long-term groundwater availability in the Waihe‘e, ‘Īao, and Waikapū aquifer systems, Maui, Hawai‘i

Groundwater levels have declined since the 1940s in the Wailuku area of central Maui, Hawai‘i, on the eastern flank of West Maui volcano, mainly in response to increased groundwater withdrawals. Available data since the 1980s also indicate a thinning of the freshwater lens and an increase in chloride concentrations of pumped water from production wells. These trends, combined with projected increases in demand for groundwater in central Maui, have led to concerns over groundwater availability and have highlighted a need to improve general understanding of the hydrologic effects of proposed groundwater withdrawals in the Waihe‘e, ‘Īao, and Waikapū areas of central Maui. A numerical groundwater model was constructed to simulate the flow and salinity of groundwater in central Maui. The model simulates the effects of changes in groundwater withdrawals and recharge on water levels, freshwater-lens thicknesses, and chloride concentrations of pumped water from production wells. The model incorporates updated water-budget estimates of groundwater recharge from infiltration and direct recharge, seepage in stream channels, and inflow from inland areas. Mean annual groundwater recharge from infiltration and direct recharge was estimated using a daily water-budget model and the most current data, including the distributions of monthly rainfall and potential evapotranspiration, for the study area for nine historical periods from 1926 through 2012: 1926–69, 1970–79, 1980–84, 1985–89, 1990–94, 1995–99, 2000–04, 2005–09, and 2010–12. The water-budget model also estimated groundwater recharge based on one hypothetical scenario that used 1980–2010 rainfall and 2017 land cover. For the nine historical periods, estimated recharge from infiltration and direct recharge within the area of the groundwater model ranged from 30.4 million gallons per day (Mgal/d) during 2010–12 to 98.7 Mgal/d during 1926–69. Variability in recharge during these periods mainly reflects changes in rainfall and irrigation over time. Between 2010 and 2014, streamflow restoration in previously diverted streams resulted in an estimated increase in recharge from seepage in stream channels of about 12.5 Mgal/d. Average groundwater inflow of about 39.6 Mgal/d from inland, dike-intruded areas to the main area of interest was estimated from an existing island-wide numerical groundwater-flow model, which is at a larger scale and incorporates a greater number of simplifying assumptions. The numerical groundwater model developed for this study was calibrated to 1926–2012 transient water levels, vertical salinity profiles, and chloride concentrations of water pumped by production wells in the study area. The model was then used to evaluate one future recharge and six selected withdrawal scenarios, developed in consultation with the Maui Department of Water Supply, in terms of long-term changes in water level and 50-percent ocean-water salinity surface. The groundwater model was also used to simulate the future salinity of water withdrawn by existing and proposed production wells. The simulations were run to steady-state conditions, providing an estimate of the long-term effects of changes in withdrawal and recharge on the groundwater resource. Results of the simulated future withdrawal scenarios indicate that, relative to 2017–18 rates, the scenarios’ long-term effect of increased withdrawals ultimately leads to lower water levels and a higher 50-percent ocean-water salinity surface indicating a thinning of the freshwater lens. Results also indicate that the increased withdrawals produce some groundwater with chloride concentration below 250 milligrams per liter and some groundwater with higher chloride concentration. The amount of drawdown near production wells and the quality of water withdrawn from production wells is dependent on the rate and spatial distribution of the withdrawals. The model was also used to evaluate how groundwater availability may be affected for a drier recharge scenario based on a published study of future climate. Model results of the future recharge scenario indicate that the rate of groundwater recharge is a controlling factor for (1) water levels, (2) the 50-percent ocean-water salinity surface, and (3) the quality of water withdrawn from production wells in the Wailuku area. Coupled with reduced groundwater recharge (with all other factors remaining equal), the modeled future withdrawals in the scenario would tend to cause lower water levels, a higher 50-percent ocean-water salinity surface, and increased salinity of water withdrawn from production wells. The three-dimensional numerical groundwater model developed for this study utilizes the latest available hydrologic and geologic information and is a useful tool for understanding the long-term hydrologic effects of additional groundwater withdrawals in central Maui. The model has several limitations, including its non-uniqueness and inability to account for local-scale heterogeneities. Short-term effects of changes in recharge and withdrawals—and optimization of pumping rates to meet increased demand for water with acceptable salinity—are possible conditions for future simulation analyses.

Hawaii↗

USGS2012

Simulation of groundwater flow in the shallow aquifer system of the Delmarva Peninsula, Maryland and Delaware

Estimating future loadings of nitrogen to the Chesapeake Bay requires knowledge about the groundwater flow system and the traveltime of water and chemicals between recharge at the water table and the discharge to streams and directly to the bay. The Delmarva Peninsula has a relatively large proportion of its land devoted to agriculture and a large associated nitrogen load in groundwater that has the potential to enter the bay in discharging groundwater. To better understand the shallow aquifer system with respect to this loading and the traveltime to the bay, the U.S. Geological Survey constructed a steady-state groundwater flow model for the region. The model is based on estimates of recharge calculated using recently developed regression equations for evapotranspiration and surface runoff. The hydrogeologic framework incorporated into the model includes unconfined surficial aquifer sediments, as well as subcropping confined aquifers and confining beds down to 300 feet below land surface. The model was calibrated using 48 water-level measurements and 24 tracer-based ages from wells located across the peninsula. The resulting steady-state flow solution was used to estimate ages of water in the shallow aquifer system through the peninsula and the distribution and magnitude of groundwater traveltime from recharge at the water table to discharge in surface-water bodies (referred to as return time). Return times vary but are typically less than 10 years near local streams and greater than 100 years near the stream divides. The model can be used to calculate nitrate transport parameters in various local watersheds and predict future trends in nitrate loadings to Chesapeake Bay for different future nitrogen application scenarios.

Delaware;Maryl↗

USGS2006

Examples of transient sounding from groundwater exploration in sedimentary aquifers

Examples of the use of transient electromagnetic soundings for three ground-water exploration problems in sedimentary aquifers are given. The examples include: (1) estimating depths to water table and bedrock in an alluvium-filled basin, (2) mapping a confined fresh-water aquifer in bedrock sediments, and (3) locating a freshwater/salt-water interface in a glacial-outwash aquifer. The technique works quite well for these problems within the limitations imposed by the problem of equivalence. For thin conductive targets (S-equivalence) such as a salt-water lens, the ratio of the layer thickness to its resistivity can be determined, but not the individual layer parameters. The thickness of thin resistive zones (H-equivalence) can be resolved, but the resistivity of such layers is not well determined. The problem of H-equivalence is more severe than the S-equivalence. Equivalence imposes restrictions on the transient sounding method for some ground-water exploration problems. Model studies prior to field work can be used to assess the usefulness of the technique for a particular exploration objective.

Groundwater↗