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Geohydrology of the valley-fill aquifer in the Bath area, Lower Cohocton River, Steuben County, New York

The Bath valley-fill aquifer, southern New York, composed of outwash, ice-contact, and ice-disintegration sand and gravel, is highly productive and is in many areas in hydraulic contact with the Cohocton River. Potential well yields range 50 to more than 1,000 gallons per minute. Most of the aquifer is under shallow water-table conditions and vulnerable to surface contamination. Thickness ranges from 20 to 40 feet. Buried aquifers are present locally. The aquifer system underlies an area containing only a few small communities and therefore is not heavily pumped. Geohydrologic data are compiled on six maps at 1:24,000 scale and on a sheet of geologic sections. The maps depict surficial geology, soil-infiltration capacity, potentiometric surface, aquifer thickness, well yields, and land use. This map report set is one in a series of four that depict selected aquifers in Wester New York. It supplements a series that is being done by the U.S. Geological Survey in cooperation with State agencies. The maps are based largely on published reports, data filled in several State agencies, and some additional field data collection. (USGS)

Water-Resources Investigations Report

Precision and bias of selected analytes reported by the National Atmospheric Deposition Program and National Trends Network, 1983; and January 1980 through September 1984

Blind-audit samples with known analyte concentrations have been prepared by the U.S. Geological Survey and distributed to the National Atmospheric Deposition Program 's Central Analytical Laboratory. The difference between the National Atmospheric Deposition Program and National Trends Network reported analyte concentrations and known analyte concentrations have been calculated, and the bias has been determined. Calcium, magnesium , sodium, and chloride were biased at the 99-percent confidence limit; potassium and sulfate were unbiased at the 99-percent confidence limit, for 1983 results. Relative-percent differences between the measured and known analyte concentration for calcium , magnesium, sodium, potassium, chloride, and sulfate have been calculated for 1983. The median relative percent difference for calcium was 17.0; magnesium was 6.4; sodium was 10.8; potassium was 6.4; chloride was 17.2; and sulfate was -5.3. These relative percent differences should be used to correct the 1983 data before user-analysis of the data. Variances have been calculated for calcium, magnesium, sodium, potassium, chloride, and sulfate determinations. These variances should be applicable to natural-sample analyte concentrations reported by the National Atmospheric Deposition Program and National Trends Network for calendar year 1983. (USGS)

Water-Resources Investigations Report

Vulnerability of ground water to atrazine leaching in Kent County, Michigan

A steady-state model of pesticide leaching through the unsaturated zone was used with readily available hydrologic, lithologic, and pesticide characteristics to estimate the vulnerability of the near-surface aquifer to atrazine contamination from non-point sources in Kent County, Michigan. The modelcomputed fraction of atrazine remaining at the water table, RM , was used as the vulnerability criterion; time of travel to the water table also was computed. Model results indicate that the average fraction of atrazine remaining at the water table was 0.039 percent; the fraction ranged from 0 to 3.6 percent. Time of travel of atrazine from the soil surface to the water table averaged 17.7 years and ranged from 2.2 to 118 years. Three maps were generated to present three views of the same atrazine vulnerability characteristics using different metrics (nonlinear transformations of the computed fractions remaining). The metrics were chosen because of the highly (right) skewed distribution of computed fractions. The first metric, rm = RM λ (where λ was 0.0625), depicts a relatively uniform distribution of vulnerability across the county with localized areas of high and low vulnerability visible. The second metric, rm λ-0.5 , depicts about one-half the county at low vulnerability with discontinuous patterns of high vulnerability evident. In the third metric, rm λ-1.0 ( RM ), more than 95 percent of the county appears to have low vulnerability; small, distinct areas of high vulnerability are present. Aquifer vulnerability estimates in the RM metric were used with a steady-state, uniform atrazine application rate to compute a potential concentration of atrazine in leachate reaching the water table. The average estimated potential atrazine concentration in leachate at the water table was 0.16 μg/L (micrograms per liter) in the model area; estimated potential concentrations ranged from 0 to 26 μg/L. About 2 percent of the model area had estimated potential atrazine concentrations in leachate at the water table that exceeded the USEPA (U.S. Environmental Protection Agency) maximum contaminant level of 3 μg/L. Uncertainty analyses were used to assess effects of parameter uncertainty and spatial interpolation error on the variability of the estimated fractions of atrazine remaining at the water table. Results of Monte Carlo simulations indicate that parameter uncertainty is associated with a standard error of 0.0875 in the computed fractions (in the rm metric). Results of kriging analysis indicate that errors in spatial interpolation are associated with a standard error of 0.146 (in the rm metric). Thus, uncertainty in fractions remaining is primarily associated with spatial interpolation error, which can be reduced by increasing the density of points where the leaching model is applied. A sensitivity analysis indicated which of 13 hydrologic, lithologic, and pesticide characteristics were influential in determining fractions of atrazine remaining at the water table. Results indicate that fractions remaining are most sensitive to the unit changes in pesticide half life and in organic-carbon content in soils and unweathered rocks, and least sensitive to infiltration rates. The leaching model applied in this report provides an estimate of the vulnerability of the near-surface aquifer in Kent County to contamination by atrazine. The vulnerability estimate is related to water-quality criteria developed by the USEPA to help assess potential risks from atrazine to the near-surface aquifer. However, atrazine accounts for only 28 percent of the herbicide use in the county; additional potential for contamination exists from other pesticides and pesticide metabolites. Therefore, additional work is needed to develop a comprehensive understanding of the relative risks associated with specific pesticides. The modeling approach described in this report provides a technique for estimating relative vulnerabilities to specific pesticides and for helping to assess potential risks.

Michigan

Guidelines for quality assurance and quality control of fish taxonomic data collected as part of the National Water-Quality Assessment Program

Fish community structure is characterized by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program as part of a perennial, multidisciplinary approach to evaluating the physical, chemical, and biological conditions of the Nation's water resources. The objective of quality assurance and quality control of fish taxonomic data that are collected as part of the NAWQA Program is to establish uniform guidelines and protocols for the identification, processing, and archiving of fish specimens to ensure that accurate and reliable data are collected. Study unit biologists, collaborating with regional biologists and fish taxonomic specialists, prepare a pre-sampling study plan that includes a preliminary faunal list and identification of an ichthyological curation center for receiving preserved fish specimens. Problematic taxonomic issues and protected taxa also are identified in the study plan, and collecting permits are obtained in advance of sampling activities. Taxonomic specialists are selected to identify fish specimens in the field and to assist in determining what fish specimens should be sacrificed, fixed, and preserved for laboratory identification, independent taxonomic verification, and long-term storage in reference or voucher collections. Quantitative and qualitative sampling of fishes follows standard methods previously established for the NAWQA Program. Common ichthyological techniques are used to process samples in the field and prepare fish specimens to be returned to the laboratory or sent to an institutional repository. Taxonomic identifications are reported by using a standardized list of scientific names that provides nomenclatural consistency and uniformity across study units.

Water-Resources Investigations Report

Time of concentration and storage coefficient values for Illinois streams

Values of time of concentration and storage coefficient, two unit hydrograph parameters, are presented for 194 and 120 basins in Illinois. Tabulated values consist of those computed by previous investigators as well as those computed for 98 basins as part of this investigation. These additional values were computed by calibration of the U.S. Army Corps of Engineers Flood Hydrograph Package (HEC-1). The significance of differences in method used by each investigator to compute these unit hydrography parameters was evaluated by statistical comparison of four sets of time of concentration values and three sets of storage coefficient values. Because no difference due to method was identified, it is concluded that all of the values tabulated in this report can be used in any application for which time of concentration and storage coefficient are required.

Illinois

Distribution of petroleum hydrocarbons and toluene biodegradation, Knox Street fire pits, Fort Bragg, North Carolina

An investigation was conducted at the Knox Street fire pits, Fort Bragg, North Carolina, to monitor the distribution of toluene, ethylbenzene, and xylene (TEX) in soil vapor, ground water, and ground-water/vapor to evaluate if total concentrations of TEX at the site are decreasing with time, and to quantify biodegradation rates of toluene in the unsaturated and saturated zones. Soil-vapor and ground-water samples were collected around the fire pits and ground-water/vapor samples were collected along the ground-water discharge zone, Beaver Creek, on a monthly basis from June 1994 through June 1995. Concentrations of TEX compounds in these samples were determined with a field gas chro- matograph. Laboratory experiments were performed on aquifer sediment samples to measure rates of toluene biodegradation by in situ micro- organisms. Based on field gas chromatographic analytical results, contamination levels of TEX compounds in both soil vapor and ground water appear to decrease downgradient of the fire-pit source area. During the 1-year study period, the observed temporal and spatial trends in soil vapor TEX concentrations appear to reflect differences in the distribution of TEX among solid, aqueous, and gaseous phases within fuel-contaminated soils in the unsaturated zone. Soil temperature and soil moisture are two important factors which influence the distribution of TEX com- pounds among the different phases. Because of the short period of data collection, it was not possible to distinguish between seasonal fluc- tuations in soil vapor TEX concentrations and an overall net decrease in TEX concentrations at the study site. No seasonal trend was observed in total TEX concentrations for ground- water samples collected at the study site. Although the analytical results could not be used to determine if ground-water TEX concen- trations decreased during the study at a specific location, the data were used to examine rate constants of toluene biodegradation. Based on ground-water toluene concentration data, a maximum rate constant for anaerobic biodegradation of toluene in the saturated zone was estimated to be as low as 0.002 d-1 or as high as 0.026 d-1. Based on analyses of ground-water/vapor samples, toluene was the prin- cipal TEX compound identified in ground water discharging to Beaver Creek. Observed decreases in ground-water/vapor toluene concentrations during the study period may reflect a decrease in source inputs, an increase in dilution caused by higher ground-water flow, and(or) removal by biological or other physical processes. Rate constants of toluene anaerobic biodegradation determined by laboratory measurements illustrate a typical acclimation response of micro-organisms to hydrocarbon contamination in sediments collected from the site. Toluene biodegradation rate constants derived from laboratory microcosm studies ranged from 0.001 to 0.027 d-1, which is similar to the range of 0.002 to 0.026 d-1 for toluene biodegradation rate constants derived from ground-water analytical data. The close agreement of toluene biodegradation rate constants reported using both approaches offer strong evidence that toluene can be degraded at environmentally significant rates at the study site.

Water-Resources Investigations Report

Regional equations for estimation of peak-streamflow frequency for natural basins in Texas

Peak-streamflow frequency estimates are needed for flood-plain management; for objective assessment of flood risk; and for cost-effective design of dams, levees, other flood-control structures, roads, bridges, and culverts. Peak-streamflow frequency represents the peak discharges for recurrence intervals of 2, 5, 10, 25, 50, and 100 years. The U.S. Geological Survey, in cooperation with the Texas Department of Transportation, conducted an investigation to develop regional regression equations for the estimation of peak-streamflow frequency for ungaged sites in natural basins in Texas. Peak-streamflow frequency data from streamflow-gaging stations in natural drainage basins of Texas were used. Peak-streamflow frequency for 559 Texas stations with natural (unregulated and rural or nonurbanized) basins was estimated with annual peak-streamflow data through 1993. The peak-streamflow frequency and drainage-basin characteristics for the Texas stations were used to develop 16 sets of equations to estimate peak-streamflow frequency for ungaged natural stream sites in each of 11 regions in Texas. The relation between peak-streamflow frequency and contributing drainage area for 5 of the 11 regions is curvilinear, requiring that one set of equations be developed for drainage areas less than 32 square miles and another set be developed for drainage areas greater than 32 square miles. These equations, developed through multiple-regression analysis using weighted least squares, are based on the relation between peak-streamflow frequency and basin characteristics for streamflow-gaging stations. The regions represent areas with similar flood characteristics. The use and limitations of the regression equations also are discussed. Additionally, procedures are presented to compute the 50-, 67-, and 90-percent confidence limits for any estimation from the equations. Also, supplemental peak-streamflow frequency and basin characteristics for 105 selected stations bordering Texas are included in the report. This supplemental information will aid in interpretation of flood characteristics for sites near the state borders of Texas.

Texas

Dissolved-mineral inflow to Great Salt Lake and chemical characteristics of the salt lake brine. Part I: Selected hydrologic data

This report presents the data collected for a study of the dissolved-mineral load contributed by surficial sources to Great Salt Lake, Utah. The study was conducted by the U.S. Geological Survey in cooperation with the University of Utah during the period from July 1959 through June 1962, and is part of an overall investigation of the Great Salt Lake basin by the University. Financial support for the study was provided by the U.S. Geological Survey and by the University of Utah Research Fund and Uniform School Fund. Some of the data presented in this report were obtained as part of cooperative programs between the Geological Survey and other agencies.

Utah

Metal interferences and their removal prior to the determination of As(T) and As(III) in acid mine waters by hydride generation atomic absorption spectrometry

Hydride generation atomic absorption spectrometry (HGAAS) is a sensitive and selective method for the determination of total arsenic (arsenic(III) plus arsenic(V)) and arsenic(III); however, it is subject to metal interferences for acid mine waters. Sodium borohydride is used to produce arsine gas, but high metal concentrations can suppress arsine production. This report investigates interferences of sixteen metal species including aluminum, antimony(III), antimony(V), cadmium, chromium(III), chromium(IV), cobalt, copper(II), iron(III), iron(II), lead, manganese, nickel, selenium(IV), selenium(VI), and zinc ranging in concentration from 0 to 1,000 milligrams per liter and offers a method for removing interfering metal cations with cation exchange resin. The degree of interference for each metal without cation-exchange on the determination of total arsenic and arsenic(III) was evaluated by spiking synthetic samples containing arsenic(III) and arsenic(V) with the potential interfering metal. Total arsenic recoveries ranged from 92 to 102 percent for all metals tested except antimony(III) and antimony(V) which suppressed arsine formation when the antimony(III)/total arsenic molar ratio exceeded 4 or the antimony(V)/total arsenic molar ratio exceeded 2. Arsenic(III) recoveries for samples spiked with aluminum, chromium(III), cobalt, iron(II), lead, manganese, nickel, selenium(VI), and zinc ranged from 84 to 107 percent over the entire concentration range tested. Low arsenic(III) recoveries occurred when the molar ratios of metals to arsenic(III) were copper greater than 120, iron(III) greater than 70, chromium(VI) greater than 2, cadmium greater than 800, antimony(III) greater than 3, antimony(V) greater than 12, or selenium(IV) greater than 1. Low recoveries result when interfering metals compete for available sodium borohydride, causing incomplete arsine production, or when the interfering metal oxidizes arsenic(III). Separation of interfering metal cations using cation-exchange prior to hydridegeneration permits accurate arsenic(III) determinations in acid mine waters containing high concentrations of interfering metals. Stabilization of the arsenic redox species for as many as 15 months is demonstrated for samples that have been properly filtered and acidified with HCl in the field. The detection limits for the method described in this report are 0.1 micrograms per liter for total arsenic and 0.8 micrograms per liter for arsenic(III).

Water-Resources Investigations Report

Index of time-of-travel studies of the US Geological Survey

This index identifies locations on streams where the U. S. Geological Survey has investigated the time of travel of a highly soluble material moving through a reach of stream channel. This index provides information only on the location of studied stream reaches; it contains no basic data. It does contain, however, a list of references to published data and analytical reports on time of travel and a list of U.S. Geological Survey offices where basic time-of-travel data are on file.

Water-Resources Investigations Report

Bathymetric surveys of Morse and Geist Reservoirs in central Indiana made with acoustic Doppler current profiler and global positioning system technology, 1996

Acoustic Doppler current profiler, global positioning system, and geographic information system technology were used to map the bathymetry of Morse and Geist Reservoirs, two artificial lakes used for public water supply in central Indiana. The project was a pilot study to evaluate the use of the technologies for bathymetric surveys. Bathymetric surveys were last conducted in 1978 on Morse Reservoir and in 1980 on Geist Reservoir; those surveys were done with conventional methods using networks of fathometer transects. The 1996 bathymetric surveys produced updated estimates of reservoir volumes that will serve as base-line data for future estimates of storage capacity and sedimentation rates.An acoustic Doppler current profiler and global positioning system receiver were used to collect water-depth and position data from April 1996 through October 1996. All water-depth and position data were imported to a geographic information system to create a data base. The geographic information system then was used to generate water-depth contour maps and to compute the volumes for each reservoir.The computed volume of Morse Reservoir was 22,820 acre-feet (7.44 billion gallons), with a surface area of 1,484 acres. The computed volume of Geist Reservoir was 19,280 acre-feet (6.29 billion gallons), with a surface area of 1,848 acres. The computed 1996 reservoir volumes are less than the design volumes and indicate that sedimentation has occurred in both reservoirs. Cross sections were constructed from the computer-generated surfaces for 1996 and compared to the fathometer profiles from the 1978 and 1980 surveys; analysis of these cross sections also indicates that some sedimentation has occurred in both reservoirs.The acoustic Doppler current profiler, global positioning system, and geographic information system technologies described in this report produced bathymetric maps and volume estimates more efficiently and with comparable or greater resolution than conventional bathymetry methods.

Water-Resources Investigations Report

Plan of study for the High Plains regional aquifer-system analysis in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming

The Ogallala Formation and associated Tertiary and Quarternary deposits form the principal aquifers supporting irrigation in the High Plains of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming. The volume of water in storage within the aquifers is declining in most of the High Plains because water is being withdrawn in excess of the rate of replenishment. The U.S. Geological Survey has initiated a 5-year study of the High Plains aquifer system to develop the geohydrologic data base and computer models of the ground-water flow system needed to evaluate the response of the aquifer,system to ground-water management alternatives. This report describes the objectives, plan, and organization of the study and outlines the work to be accomplished in each state in the study area.

Colorado, Kansas, Nebraska, New Mexico, Oklahoma,

Initial assessment of time of travel and mixing through Gulf Island Pond and the lower Androscoggin River, Maine

Flow-stratification patterns were observed in Gulf Island Pond during time-of-travel studies in May and August 1980. The stratification patterns in this 70 million cubic-meter impoundment were due to a temperature differences between inflowing water and reservoir water. Separation was observed at temperature differences of 0.5 degrees C in May 1980 and 1.0 degrees C in August 1980. The pathway taken by inflowing water through the reservoir was governed by the temperature-related density forces acting between the two water masses. Data collected during August 1980 to define differences in dye concentrations with depth at two fixed profile points in Gulf Island Pond showed average water velocity to be seven times faster near the bottom than near the surface. A concept of mass flow was used to analyze data collected at sites downstream from Gulf Island Dam where flow varied rapidly with time. This report presents the mathematical derivation of controid traveltime, skewness, and percentage recovery of dye mass as determined from mass versus time curves. (USGS)

Water-Resources Investigations Report

Effects of sanitary sewers on ground-water levels and streams in Nassau and Suffolk Counties, New York; part 2: Development and application of southwest Suffolk County model

By 1990, sanitary sewers in Nassau County Sewage Disposal Districts 2 and 3 and Suffolk County Southwest Sewer District will discharge to the ocean 140 cu ft of water/sec that would otherwise be returned to the groundwater system through septic tanks and similar systems. To evaluate the effects of this loss on groundwater levels and streamflow, the U.S. Geological Survey developed a groundwater flow model that couples a fine-scale subregional model to a regional model of larger scale. The regional model generates flux boundary conditions for the subregional model, and the subregional model provides detail in the area of concern. Results indicate that the water table will decline by as much as 8 ft along the Suffolk-Nassau county line, with effects decreasing eastward. Base flow is predicted to decrease by as much as 73% in a stream along the county line, but this effect will decrease to zero just east of the sewered area. This report is one of a series describing the predicted hydrologic effects of sewers in southern Nassau and southwest Suffolk Counties. (USGS)

New York

Primary productivity by phytoplankton in the tidal, fresh Potomac River, Maryland, May 1980 to August 1981

Primary productivity by phytoplankton was measured on samples collected from the Potomac Tidal River, Maryland. The studies were performed monthly from May 1980 to September 1981. Additional studies were done once a week in August 1980, twice a week from August 4 to 8, 1980 and twice in September 1980. Depth-integrated samples were collected at five stations and incubated in boxes that were exposed to natural sunlight. The boxes were covered with neutral density filters transmitting 100 , 65, 32, 16, and 6 percent surface light. River water was pumped continuously over the samples. The extinction of light in the water column by phytoplankton was measured when samples were collected. Experiments were performed to select a method for routine productivity analysis. No difference was found between productivity: (1) determined in situ and in boxes; (2) measured in 300 ml and (4) calculated from short term (4 hours) and long term (10-24 hours) incubations. There were higher productivity differences in samples that were rotated among different light intensities every 15 minutes (simulating mixing) than those remaining stationary. Respiration was significantly less in samples pumped through a hose from those collected using a depth-integrating sampler. Depth-integrated primary productivity was determined from the productivity data using an equation modified from one reported in the literature. Depth-integrated gross primary productivity was highest in August 1980 and 1981 and lowest in January 1980. (USGS)

Water-Resources Investigations Report

Hydrogeology and preliminary assessment of the potential for contamination of the Memphis aquifer in the Memphis area, Tennessee

Detailed maps of the thickness of the Jackson-upper Claiborne confining unit and the altitude of the water table in the alluvium and fluvial deposits provide much new information concerning areas where downward leakage is or may be occurring from the water-table aquifers to the Memphis aquifer in the Memphis area. A detailed map of the altitude of the potentiometric surface of the Memphis aquifer and the locations of 44 sites where contaminants have been detected in the water-table aquifers indicate that many of these sites are located in areas where the direction of ground-water flow in the Memphis aquifer is toward municipal well fields. Consequently, if contaminants enter the Memphis aquifer, a hydraulic potential exists for their transport to those wellfields. Recently (1986-88), volatile organic compounds were detected in water from five municipal wells screened in the Memphis aquifer - three in the Allen well field of the Memphis Light, Gas and Water Division at Memphis and two in the west well field at Collierville. Concentrations of seven volatile organic compounds totaled about 11 micrograms per liter in a sample from one well in the Allen wellfield at Memphis, and the concentration of one compound was 25 micrograms per liter in a sample from one well at Collierville. These are the first reported occurrences of synthetic organic compounds in the Memphis aquifer and prove that the principal aquifer in the Memphis area is vulnerable to contamination.

Tennessee

Techniques for estimating specific yield and specific retention from grain-size data and geophysical logs from clastic bedrock aquifers

Specific yield and specific retention are aquifer characteristics that are important in determining the volume of water in storage in an aquifer. These characteristics can be determined by laboratory analyses of undisturbed samples of aquifer material. However. quicker, less costly alternatives to these laboratory analyses are needed. This report presents techniques for estimating specific yield and specific retention based on grain-size analyses, and based on interpretation of borehole geophysical logs.

Water-Resources Investigations Report

Identification of potential public water-supply areas of the Cape Cod aquifer, Massachusetts, using a geographic information system

Potential public water-supply areas of the Cape Cod aquifer, Massachusetts, were identified using a geographic information system (GIS) to aid regional and local ground-water resource management efforts. Criteria were selected to identify potential areas on the basis of data restrictions in addition to State requirements for siting new public water- supply wells, Federal or local restrictions on land use, and general hydrogeologic or water-quality concerns. Data layers were created for each criterion and overliad to eliminate areas from consideration as potential public water supplies. Remaining areas, those not included within the applied criteria, are the primary areas to consider for potential public water supplies. The areas identified in this analysis as potential public water supplies range from 0.5 to 7.9 percent of the individual flow cells, or 5.6 percent of the total flow cell area. The criteria were ranked so that criteria more limiting to potential public water supplies were given a higher rank than other criteria. The ranking scheme allows for the inclusion of areas with lower ranked criteria as potential public water supplies. Results can be viewed on a plat in this report, or accessed using the map-based, menu-driven GIS application, which provides interactive display and query of investigation results.

Water-Resources Investigations Report