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At least 199 records · Page 11Linked to original sources

USGS2017

Reassessing rainfall in the Luquillo Mountains, Puerto Rico: Local and global ecohydrological implications

Mountains receive a greater proportion of precipitation than other environments, and thus make a disproportionate contribution to the world’s water supply. The Luquillo Mountains receive the highest rainfall on the island of Puerto Rico and serve as a critical source of water to surrounding communities. The area’s role as a long-term research site has generated numerous hydrological, ecological, and geological investigations that have been included in regional and global overviews that compare tropical forests to other ecosystems. Most of the forest- and watershed-wide estimates of precipitation (and evapotranspiration, as inferred by a water balance) have assumed that precipitation increases consistently with elevation. However, in this new analysis of all known current and historical rain gages in the region, we find that similar to other mountainous islands in the trade wind latitudes, leeward (western) watersheds in the Luquillo Mountains receive lower mean annual precipitation than windward (eastern) watersheds. Previous studies in the Luquillo Mountains have therefore overestimated precipitation in leeward watersheds by up to 40%. The Icacos watershed, however, despite being located at elevations 200–400 m below the tallest peaks and to the lee of the first major orographic barrier, receives some of the highest precipitation. Such lee-side enhancement has been observed in other island mountains of similar height and width, and may be caused by several mechanisms. Thus, the long-reported discrepancy of unrealistically low rates of evapotranspiration in the Icacos watershed is likely caused by previous underestimation of precipitation, perhaps by as much as 20%. Rainfall/runoff ratios in several previous studies suggested either runoff excess or runoff deficiency in Luquillo watersheds, but this analysis suggests that in fact they are similar to other tropical watersheds. Because the Luquillo Mountains often serve as a wet tropical archetype in global assessments of basic ecohydrological processes, these revised estimates are relevant to regional and global assessments of runoff efficiency, hydrologic effects of reforestation, geomorphic processes, and climate change.

Luquillo Mountains↗

USGS2024

Carbon dioxide toxicity to zebra mussels (Dreissena polymorpha) is dependent on water chemistry

Carbon dioxide (CO 2 ) is gaining interest as a tool to combat aquatic invasive species, including zebra mussels ( Dreissena polymorpha ). However, the effects of water chemistry on CO 2 efficacy are not well described. We conducted five trials in which we exposed adult zebra mussels to a range of CO 2 in water with adjusted total hardness and specific conductance. We compared dose–responses and found differences in lethal concentration to 50% of organisms (LC50) estimates ranging from 108.3 to 179.3 mg/L CO 2 and lethal concentration to 90% of organisms (LC90) estimates ranging from 163.7 to 216.6 mg/L CO 2 . We modeled LC50 and LC90 estimates with measured water chemistry variables from the trials. We found sodium (Na + ) concentration to have the strongest correlation to changes in the LC50 and specific conductance to have the strongest correlation to changes in the LC90. Our results identify water chemistry as an important factor in considering efficacious CO 2 concentrations for zebra mussel control. Additional research into the physiological responses of zebra mussels exposed to CO 2 may be warranted to further explain mode of action and reported selectivity. Further study could likely develop a robust and relevant model to refine CO 2 applications for a wider range of water chemistries. Environ Toxicol Chem 2024;00:1–8. Published 2024. This article is a U.S. Government work and is in the public domain in the USA. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Environmental Toxicology and Chemistry↗

USGS2002

Denitrification in the recharge area and discharge area of a transient agricultural nitrate plume in a glacial outwash sand aquifer, Minnesota

Recharge rates of nitrate (NO 3 − ) to groundwater beneath agricultural land commonly are greater than discharge rates of NO 3 − in nearby streams, but local controls of NO 3 − distribution in the subsurface generally are poorly known. Groundwater dating (CFC, 3 H) was combined with chemical (ions and gases) and stable isotope (N, S, and C) analyses to resolve the effects of land use changes, flow patterns, and water‐aquifer reactions on the distributions of O 2 , NO 3 − , SO 4 = , and other constituents in a two‐dimensional vertical section leading from upland cultivated fields to a riparian wetland and stream in a glacial outwash sand aquifer near Princeton, Minnesota. Within this section a “plume” of oxic NO 3 − ‐rich groundwater was present at shallow depths beneath the fields and part of the wetland but terminated before reaching the stream or the wetland surface. Groundwater dating and hydraulic measurements indicate travel times in the local flow system of 0 to >40 years, with stratified recharge beneath the fields, downward diversion of the shallow NO 3 − ‐bearing plume by semiconfining organic‐rich valley‐filling sediments under the wetland and upward discharge across the valley and stream bottom. The concentrations and δ 15 N values of NO 3 − and N 2 indicate that the NO 3 − plume section was bounded in three directions by a curvilinear zone of active denitrification that limited its progress; however, when recalculated to remove the effects of denitrification, the data also indicate changes in both the concentrations and δ 15 N values of NO 3 − that was recharged in the past. Isotope data and mass balance calculations indicate that FeS 2 and other ferrous Fe phases were the major electron donors for denitrification in at least two settings: (1) within the glacial‐fluvial aquifer sediments beneath the recharge and discharge areas and (2) along the bottom of the valley‐filling sediments in the discharge area. Combined results indicate that the shape and progress of the oxic NO 3 − plume termination were controlled by a combination of (1) historical and spatial variations in land use practices, (2) contrast in groundwater flow patterns between the agricultural recharge area and riparian wetland discharge area, and (3) distribution and abundance of electron donors in both the sand aquifer and valley‐filling sediments. The data are consistent with slow migration of redox zones through the aquifer in response to recharging oxic groundwater during Holocene time, then an order‐of‐magnitude increase in the flux of electron acceptors as a result of agricultural NO 3 − contamination in the late twentieth century, to which the redox zone configuration still may be adjusting. The importance of denitrification for NO 3 − movement through formerly glaciated terrains should depend on the source areas and depositional environments of the glacial sediments, as well as geomorphology and recent stream‐valley sediment history.

Water Resources Research↗

USGS2010

Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland

The history and fate of groundwater nitrate (NO 3 − ) contamination were compared in 2 small adjacent agricultural watersheds in the Atlantic coastal plain by combined use of chronologic (CCl 2 F 2 , 3 H), chemical (dissolved solids, gases), and isotopic (δ 15 N,δ 13 C, δ 34 S) analyses of recharging groundwaters, discharging groundwaters, and surface waters. The results demonstrate the interactive effects of changing agricultural practices, groundwater residence times, and local geologic features on the transfer of NO 3 − through local flow systems. Recharge dates of groundwaters taken in 1990–1992 from the surficial aquifer in the Chesterville Branch and Morgan Creek watersheds near Locust Grove, Maryland, ranged from pre-1940 to the late 1980’s. When corrected for localized denitrification by use of dissolved gas concentrations, the dated waters provide a 40-year record of the recharge rate of NO 3 − , which increased in both watersheds by a factor of 3–6, most rapidly in the 1970's. The increase in groundwater NO 3 − over time was approximately proportional to the documented increase in regional N fertilizer use, and could be accounted for by oxidation and leaching of about 20–35% of the fertilizer N. Groundwaters discharging upward beneath streams in both watersheds had measured recharge dates from pre-1940 to 1975, while chemical data for second-order reaches of the streams indicated average groundwater residence times in the order of 20+ years. At the time of the study, NO 3 − discharge rates were less than NO 3 − recharge rates for at least two reasons: (1) discharge of relatively old waters with low initial NO 3 − concentrations, and (2) local denitrification. In the Chesterville Branch watershed, groundwaters remained oxic throughout much of the surficial aquifer and discharged relatively unaltered to the stream, which had a relatively high NO 3 − concentration (9–10 mg/L as N). In the Morgan Creek watershed, groundwaters were largely reduced and denitrified before discharging to the stream, which had a relatively low NO 3 − concentration (2–3 mg/L as N). Chemical and isotopic data indicate that quantitative denitrification occurred within buried calcareous glauconitic marine sediments that are present at relatively shallow depths beneath the Morgan Creek watershed. NO 3 − removal by forests, wetlands, and shallow organic-rich soils in near-stream environments was largely avoided by groundwaters that followed relatively deep flow paths before converging and discharging rapidly upward to the streams.

Maryland↗

USGS2016

Collision and displacement vulnerability among marine birds of the California Current System associated with offshore wind energy infrastructure

With growing climate change concerns and energy constraints, there is an increasing need for renewable energy sources within the United States and globally. Looking forward, offshore wind-energy infrastructure (OWEI) has the potential to produce a significant proportion of the power needed to reach our Nation’s renewable energy goal. Offshore wind-energy sites can capitalize open areas within Federal waters that have persistent, high winds with large energy production potential. Although there are few locations in the California Current System (CCS) where it would be acceptable to build pile-mounted wind turbines in waters less than 50 m deep, the development of technology able to support deep-water OWEI (>200 m depth) could enable wind-energy production in the CCS. As with all human-use of the marine environment, understanding the potential impacts of wind-energy infrastructure on the marine ecosystem is an integral part of offshore wind-energy research and planning. Herein, we present a comprehensive database to quantify marine bird vulnerability to potential OWEI in the CCS (see https://doi.org/10.5066/F79C6VJ0 ). These data were used to quantify marine bird vulnerabilities at the population level. For 81 marine bird species present in the CCS, we created three vulnerability indices: Population Vulnerability, Collision Vulnerability, and Displacement Vulnerability. Population Vulnerability was used as a scaling factor to generate two comprehensive indicies: Population Collision Vulnerability (PCV) and Population Displacement Vulnerability (PDV). Within the CCS, pelicans, terns (Forster’s [ Sterna forsteri ], Caspian [ Hydroprogne caspia ], Elegant [ Thalasseus elegans ], and Least Tern [ Sternula antillarum ]), gulls (Western [ Larus occidentalis ] and Bonaparte’s Gull [ Chroicocephalus philadelphia ]), South Polar Skua ( Stercorarius maccormicki ), and Brandt’s Cormorant ( Phalacrocorax penicillatus ) had the greatest PCV scores. Brown Pelican ( Pelicanus occidentalis ) had the greatest overall PCV score. Some alcids (Scripps’s Murrelet [ Synthliboramphus scrippsi ], Marbled Murrelet [ Brachyramphus marmoratus ], and Tufted Puffin [ Fratercula cirrhata ]), terns (Elegant and Least Lern), and loons (Yellow-billed [ Gavia adamsii ] and Common Loon [ G. immer ]) had the greatest PDV scores. Ashy Storm-Petrel ( Oceanodroma homochroa ) had the greatest overall PDV score. To help inform decisions that will impact seabird conservation, vulnerability assessment results can now be combined with recent marine bird at-sea distribution and abundance data for the CCS to evaluate vulnerability areas where OWEI development is being considered. Lastly, it is important to note that as new information about seabird behavior and populations in the CCS becomes available, this database can be easily updated and modified.

Open-File Report↗

USGS2013

Drivers of circulation in a fringing coral reef embayment: A wave-flow coupled numerical modeling study of Hanalei Bay, Hawaii

A coupled wave-circulation numerical model of Hanalei Bay, Hawaii, was constructed to investigate controls on nearshore hydrodynamics and overall circulation of a bathymetrically-complex coral reef embayment that is exposed to large waves and river floods several times per annum. The model was calibrated using in situ data representative of the two conditions that dominate the region's wave climate: one associated with local trade winds and associated trade-wind waves, and the other with distant-source episodic large swells. The model results were improved by including spatially-varying hydrodynamic bed roughness and making the semi-empirical wave-breaking parameter dependent on incident wave steepness and reef slope. During trade-wind conditions, circulation was primarily wind-driven and volume flux-based flushing times of the bay were on the order of 35 h. Under the episodic swell conditions, circulation were dominated by wave-driven flows and flushing times decreased to as little as 2 h. The vigorous hydrodynamics that occur during the upper 10% most energetic swell conditions indicate that only a few (0–10) events each year are likely capable of exporting significant volumes of sediment from the bay. Like many fringing reef areas backed by steep-sided watersheds on tropical and sub-tropical high islands worldwide, Hanalei Bay receives high episodic fluvial sediment load during a similarly low number of flood events. These similarly episodic but decoupled processes of sediment delivery and removal identified here suggest that the water quality and sedimentary environment of Hanalei Bay and similar linked watershed-reef systems are sensitive to changes in annual storm frequency and intensity.

Hawaii↗

USGS1978

Pressure gradients and boiling as mechanisms for localizing ore in porphyry systems

Fluid inclusions in ore zones of porphyry systems indicate that extensive boiling of hydrothermal fluids accompanies deposition of ore and gangue minerals. The boiling commonly accompanied a change from a lithostatic to a hydrostatic environment during evolution of an epizonal stock. Pressure gradients near the margin of the stock can determine whether ore or only a diffuse zone of mineralization is formed. A sharp drop in pressure in an epizonal environment is more likely to cause extensive boiling than a comparable change in a deeper environment, as the slope of the boiling curve steepens with an increase 'in pressure. The drop in pressure causes the hydrothermal fluids to boil and creates a crackle (stockwork) breccia, which hosts the veinlets of gangue quartz and ore minerals. The boiling selectively partitions CO 2 , H 2 S, and HCl into the vapor phase, changing the pH, composition, ionic strength, and thus the solubility product of metal complexes in the remaining liquid and causing the ore and gangue to come out of solution. Fluid inclusions trapped from boiling solutions can exhibit several forms, depending on the physical and chemical conditions of the hydrothermal fluid from which they were trapped. In one case, inclusions when heated can homogenize to either liquid or vapor at the same temperature, which is the true boiling temperature. In another case, homogenization of various inclusions can occur through a range of temperatures. The latter case results from the trapping of mixture of liquid and vapor. Variations in salinity can result from boiling of the hydrothermal fluid, or intermittent incorporation of high-salinity fluids from the magma, or trapping of fluids of varying densities at pressure-temperature conditions above the critical point of the fluid. In places, paleopressure-temperature transition zones can be recognized by fluid-inclusion homogenization temperatures and phase relationships and by the presence of anhydrite daughter minerals. Boiling of a hydrothermal fluid in the porphyry environment affects light stable isotopes. Hydrogen is preferentially fractionated into the vapor phase from water boiling below 223°C; above this temperature deuterium is selectively enriched in the vapor phase. In certain environments boiling creates a vapor-dominated system in which the condensate is swept away by meteoric waters and the H/D in the residual fluids is progressively increased through time.

Utah↗

USGS2004

Toward a scientifically rigorous basis for developing mapped ecological regions.

Despite the wide use of ecological regions in conservation and resource-management evaluations and assessments, a commonly accepted theoretical basis for ecological regionalization does not exist. This fact, along with the paucity of focus on ecological regionalization by professional associations, journals, and faculties, has inhibited the advancement of a broadly acceptable scientific basis for the development, use, and verification of ecological regions. The central contention of this article is that ecological regions should improve our understanding of geographic and ecological phenomena associated with biotic and abiotic processes occurring in individual regions and also of processes characteristic of interactions and dependencies among multiple regions. Research associated with any ecoregional framework should facilitate development of hypotheses about ecological phenomena and dominant landscape elements associated with these phenomena, how these phenomena are structured in space, and how they function in a hierarchy. Success in addressing the research recommendations outlined in this article cannot occur within an ad hoc, largely uncoordinated research environment. Successful implementation of this plan will require activities--coordination, funding, and education--that are both scientific and administrative in nature. Perhaps the most important element of an infrastructure to support the scientific work of ecoregionalization would be a national or international authority similar to the Water and Science Technology Board of the National Academy of Sciences.

Environmental Management↗

USGS2016

Role of riparian shade on the fish assemblage of a reservoir littoral

Research into the effects of shade on reservoir fish assemblages is lacking, with most investigations focused on streams. Unlike many streams, the canopy in a reservoir shades only a narrow fringe of water adjacent to the shoreline, and may not have the influential effect on the aquatic environment reported in streams. We compared fish assemblages between shaded and unshaded sites in a shallow reservoir. Overall species richness (gamma diversity) was higher in shaded sites, and fish assemblage composition differed between shaded and unshaded sites. Average light intensity was 66 % lower in shaded sites, and differences in average temperature and dissolved oxygen were small. Unlike streams where shade can have large effects on water physicochemistry, in reservoirs shade-related differences in fish assemblages seemed to be linked principally to differences in light intensity. Diversity in light intensity in shaded and unshaded sites in reservoirs can create various mosaics of light-based habitats that enable diversity of species assemblages. Managing to promote the habitat diversity provided by shade may require coping with the artificial nature of reservoir riparian zones and water level fluctuations.

Environmental Biology of Fishes↗

USGS1974

Pesticides data-collection activities of the U.S. Geological Survey in Texas

The water-resources investigations program of the Geological Survey has the objective of seeing that the Nation's water resources are appraised and that the necessary water data to develop and manage them efficiently are available when needed. In carrying out this objective, the Survey is the primary source of hydrologic data that are basic not only to the quantification of the water resource but also to its development and conservation. In recent years, the need has developed for the Survey to provide data and technology to predict the impact of man's activities upon the water resource and the water environment. To accomplish its mission, the Geological Survey determines the source, quantity, quality, distribution, movement, and availability of both surface and ground water. This work includes the assessment of the chemical, physical, and biological quality of water resources and its relation to various parts of the hydrologic cycle; research to improve the scientific basis of investigations and techniques; design and operation of a national water-data network; and publication of its investigations.

Texas↗

USGS2006

Environmental Effects of Agricultural Practices - Summary of Workshop Held on June 14-16, 2005

A meeting between the U.S. Geological Survey (USGS) and its partners was held June 14-16, 2005, in Denver, CO, to discuss science issues and needs related to agricultural practices. The goals of the meeting were to learn about the (1) effects of agricultural practices on the environment and (2) tools for identifying and quantifying those effects. Achieving these goals required defining the environmental concerns, developing scientific actions to address assessment of environmental effects, and creating collaborations to identify future research requirements and technical gaps. Five areas of concern were discussed-emerging compounds; water availability; genetically modified organisms; effects of conservation practices on ecosystems; and data, methods, and tools for assessing effects of agricultural practices.

Scientific Investigations Report↗

USGS2016

Elucidating the role of vegetation in the initiation of rainfall-induced shallow landslides: Insights from an extreme rainfall event in the Colorado Front Range

More than 1100 debris flows were mobilized from shallow landslides during a rainstorm from 9 to 13 September 2013 in the Colorado Front Range, with the vast majority initiating on sparsely vegetated, south facing terrain. To investigate the physical processes responsible for the observed aspect control, we made measurements of soil properties on a densely forested north facing hillslope and a grassland-dominated south facing hillslope in the Colorado Front Range and performed numerical modeling of transient changes in soil pore water pressure throughout the rainstorm. Using the numerical model, we quantitatively assessed interactions among vegetation, rainfall interception, subsurface hydrology, and slope stability. Results suggest that apparent cohesion supplied by roots was responsible for the observed connection between debris flow initiation and slope aspect. Results suggest that future climate-driven modifications to forest structure could substantially influence landslide hazards throughout the Front Range and similar water-limited environments where vegetation communities may be more susceptible to small variations in climate.

Geophysical Research Letters↗

USGS2016

Freshwater wrack along Great Lakes coasts harbors Escherichia coli: Potential for bacterial transfer between watershed environments

We investigated the occurrence, persistence, and growth potential of Escherichia coli associated with freshwater organic debris (i.e., wrack) frequently deposited along shorelines (shoreline wrack), inputs from rivers (river CPOM), and parking lot runoffs (urban litter). Samples were collected from 9 Great Lakes beaches, 3 creeks, and 4 beach parking lots. Shoreline wrack samples were mainly composed of wood chips, straw, sticks, leaf litter, seeds, feathers, and mussel shells; creek and parking lot samples included dry grass, straw, seeds, wood chips, leaf/pine needle litter; soil particles were present in parking lot samples only. E. coli concentrations (most probable number, MPN) were highly variable in all sample types: shoreline wrack frequently reached 10 5 /g dry weight (dw), river CPOM ranged from 81 to 7,916/g dw, and urban litter ranged from 0.5 to 24,952/g dw. Sequential rinsing studies showed that 61–87% of E. coli concentrations were detected in the first wash of shoreline wrack, with declining concentrations associated with 4–8 subsequent washings; viable counts were still detected even after 8 washes. E. coli grew readily in shoreline wrack and river CPOM incubated at 35 °C. At 30°C, growth was only detected in river CPOM and not in shoreline wrack or urban litter, but the bacteria persisted for at least 16 days. In summary, freshwater wrack is an understudied component of the beach ecosystem that harbors E. coli and thus likely influences estimations of water quality and the microbial community in the nearshore as a result of transfer between environments.

Illinois, Indiana, Ontario↗

USGS2024

Temporal variability in irrigated land and climate influences on salinity loading across the Upper Colorado River Basin, 1986-2017

Freshwater salinization is a growing global concern impacting human and ecosystem needs with impacts to water availability for human and ecological uses. In the Upper Colorado River Basin (UCRB), dissolved solids in streams compound ongoing water supply challenges to further limit water availability and cause economic damages. Much effort has been dedicated to understanding dissolved solid sources, transport, and management in the region, yet temporal variability in loading from key sources such as irrigated lands and the influence of climate on dissolved solids loading remains unknown. Quantifying the contributions and temporal variability of dissolved solids loads from irrigated lands may benefit salinity management efforts. This study applies a time-varying (dynamic) modeling approach to predict annual dissolved solids loads across the UCRB from 1986 through 2017. Between 66% and 82% of the total accumulated dissolved solids load in the basin is from groundwater (storage and baseflow). Our findings link climate, irrigation, and groundwater, and confirm large storage contributions that have declined slightly with time. Dissolved solids loads increase during wet periods and decrease during dry periods, although the relative contributions of different sources vary little with time. Irrigation enhances loading efficiency relative to unirrigated areas through runoff and groundwater, and can locally be a major source of dissolved solids where irrigation occurs. Results indicate that loads from irrigated areas increase when irrigated area and/or water available for runoff increase. Increased regional aridification over the study period may have contributed to decreasing stream salinity through both quicker surface runoff and lagged groundwater storage processes. Study results may be relevant to salinity management in arid environments where water availability is limited and where irrigation influences salinity loading to streams.

Upper Colorado River Basin↗

USGS2013

Knowledge and understanding of dissolved solids in the Rio Grande–San Acacia, New Mexico, to Fort Quitman, Texas, and plan for future studies and monitoring

Availability of water in the Rio Grande Basin has long been a primary concern for water-resource managers. The transport and delivery of water in the basin have been engineered by using reservoirs, irrigation canals and drains, and transmountain-water diversions to meet the agricultural, residential, and industrial demand. In contrast, despite the widespread recognition of critical water-quality problems, there have been minimal management efforts to improve water quality in the Rio Grande. Of greatest concern is salinization (concentration of dissolved solids approaching 1,000 mg/L), a water-quality problem that has been recognized and researched for more than 100 years because of the potential to limit both agricultural and municipal use. To address the issue of salinization, water-resource managers need to have a clear conceptual understanding of the sources of salinity and the factors that control storage and transport, identify critical knowledge gaps in this conceptual understanding, and develop a research plan to address these gaps and develop a salinity management program. In 2009, the U.S. Geological Survey (USGS) in cooperation with the U.S. Army Corps of Engineers (USACE), New Mexico Interstate Stream Commission (NMISC), and New Mexico Environment Department (NMED) initiated a project to summarize the current state of knowledge regarding the transport of dissolved solids in the Rio Grande between San Acacia, New Mexico, and Fort Quitman, Texas. The primary objective is to provide hydrologic information pertaining to the spatial and temporal variability present in the concentrations and loads of dissolved solids in the Rio Grande, the source-specific budget for the mass of dissolved solids transported along the Rio Grande, and the locations at which dissolved solids enter the Rio Grande. Dissolved-solids concentration data provide a good indicator of the general quality of surface water and provide information on the factors governing salinization within the Rio Grande study area. The pattern in dissolved-solids concentrations along the Rio Grande is one of increasing concentration with increasing distance downstream from Elephant Butte and Caballo Reservoirs. The concentration of dissolved solids in the Rio Grande doubles (approximately 500 to 1,000 mg/L) from below Elephant Butte Reservoir to El Paso and increases by more than a factor of 5 (approximately 500 to 3,200 mg/L) from below Elephant Butte Reservoir to Fort Quitman. Marked increases in the concentration of dissolved solids commonly coincide with contributions from agricultural drains, wastewater-treatment plants, regional groundwater, and upward-flowing saline groundwater. The greatest factor, from the surface-water system, in controlling dissolved solids in the Rio Grande is the amount of water that is being transported or stored. Annual variation in streamflow is influenced primarily by climate (precipitation and evaporation) and management of Elephant Butte and Caballo Reservoirs (water storage and release cycles). Seasonal variation in streamflow within the Rio Grande study area is generally categorized generally as irrigation (March–September) and nonirrigation (October–February) seasons; with streamflow in the Rio Grande is highest during the irrigation season and lowest during the nonirrigation season. Dissolved-solids loads during the irrigation season decrease between Leasburg and Fort Quitman primarily because of irrigation diversions and losses to the underlying alluvial aquifer. Conversely, dissolved-solids loads during the nonirrigation season increase between Caballo Dam and Fort Quitman primarily because of the inflow of dissolved solids from agricultural drains, wastewater-treatment plants, and groundwater with elevated concentrations of dissolved solids. Many studies have mass-balance budgets that account for the mass of dissolved solids transported along the Rio Grande. Results from mass-balance budgets developed for dissolved solids indicated that (1) the inflow of saline groundwater, inflow of regional groundwater, and chemical reactions between mineral phases are the primary sources controlling dissolved solids in the Rio Grande, and (2) groundwater pumping and mineral precipitation are causing a net storage of dissolved solids in the Leasburg to El Paso and El Paso to Fort Quitman reaches of the Rio Grande. Looking forward, multiple water-resource managers from State and local agencies in New Mexico and Texas and Federal agencies formed the Rio Grande Salinity Management Coalition with the goal to reduce the amount of dissolved solids that are transported and stored in the Rio Grande study area. The recommendations for additional monitoring to assist the coalition are as follows: -Monitoring: Couple water-quality and streamflow monitoring in the Rio Grande and agricultural drains; perform groundwater-seepage investigations in the Rio Grande and major agricultural drains; nonitor groundwater water-quality conditions in the Mesilla and Hueco Basins. -Focused Hydrogeology Studies at Inflow Sources: Map dissolved-solids concentrations in the Rio Grande and underlying alluvial aquifer; perform hydrogeologic characterization of subsurface areas containing unusually high concentrations of dissolved solids. -Modeling of Dissolved Solids: Develop models to simulate the transport and storage of dissolved solids in both surface-water and groundwater systems.

New Mexico;Texas↗

USGS2020

Robotic environmental DNA bio-surveillance of freshwater health

Autonomous water sampling technologies may help to overcome the human resource challenges of monitoring biological threats to rivers over long time periods and large geographic areas. The Monterey Bay Aquarium Research Institute has pioneered a robotic Environmental Sample Processor (ESP) that overcomes some of the constraints associated with traditional sampling since it can automate water sample filtration and preservation of the captured material or homogenize it for immediate analyses in situ. The ESP was originally developed for marine environment applications. Here we evaluated whether the ESP can provide reliable, timely information on environmental (e)DNA detections of human and fish pathogens and introduced fishes at U.S. Geological Survey streamgage sites in freshwater rivers. We compared eDNA collected via ESP at high frequency (e.g., every 3 h) with manual eDNA collections collected at lower frequency (e.g., weekly). We found that water samples filtered and preserved by ESPs successfully detected the DNA of human pathogens, fish pathogens and introduced fishes. Both ESP and manually collected samples provided similar information about target DNA presence. We suggest that the greatest current benefit of the ESP is the cost savings of high frequency, bio-surveillance at remote or hard to access sites. The full potential of robotic technologies like the ESP will be realized when they can more easily execute in situ analyses of water samples and rapidly transmit results to decision-makers.

Idaho, Montana, Wyoming↗

USGS1999

Natural attenuation of chlorinated volatile organic compounds in a freshwater tidal wetland: Field evidence of anaerobic biodegradation

Field evidence collected along two groundwater flow paths shows that anaerobic biodegradation naturally attenuates a plume of chlorinated volatile organic compounds as it discharges from an aerobic sand aquifer through wetland sediments. A decrease in concentrations of two parent contaminants, trichloroethylene (TCE) and 1,1,2,2‐tetrachloroethane (PCA), and a concomitant increase in concentrations of anaerobic daughter products occurs along upward flow paths through the wetland sediments. The daughter products 1,2‐dichloroethylene, vinyl chloride, 1,1,2‐trichloroethane, and 1,2‐dichloroethane are produced from hydrogenolysis of TCE and from PCA degradation through hydrogenolysis and dichloroelimination (reductive dechlorination) pathways. Total concentrations of TCE, PCA, and their degradation products, however, decrease to below detection levels within 0.15–0.30 m of land surface. The enhanced reductive dechlorination of TCE and PCA in the wetland sediments is associated with the naturally higher concentrations of dissolved organic carbon and the lower redox state of the groundwater compared to the aquifer. This field study indicates that wetlands and similar organic‐rich environments at groundwater/surface‐water interfaces may be important in intercepting groundwater contaminated with chlorinated organics and in naturally reducing concentrations and toxicity before sensitive surface‐water receptors are reached.

Water Resources Research↗

USGS2022

Great Lakes spatial priorities study

Spatial data about the bathymetry, habitat characteristics, underlying geology, and other features of the ocean and inland seas are essential for decision-making. Marine research and management organizations use these data to help ensure safe navigation, promote sustainable fisheries, extract energy, and protect marine habitats in the coastal and ocean waters of the U.S. Exclusive Economic Zone (EEZ) and Laurentian Great Lakes. Many of these organizations may have overlapping or shared mapping interests without knowing it. In a multi-jurisdictional planning environment, it can be challenging and cumbersome to determine where other entities have shared or overlapping mapping interests, especially across a transnational region such as the Great Lakes. State and provincial governments, federal governments, academia, tribes and First Nations, and other stakeholders from both the U.S. and Canada all have mapping interests across Great Lakes waters. Identifying and communicating target geographies for new data collection that are shared among multiple organizations can both help to avoid redundancy of new mapping efforts, and create opportunities for greater efficiency through collaboration. To address this issue, a spatial priorities study was conducted using a geospatial tool developed by the National Ocean Services National Centers for Coastal and Ocean Science (NCCOS). The tool provided an easy-to-use online interface in which programs can identify their priorities in a simple and straightforward way. This study asked representatives of Great Lakes management and science organizations to identify the areas for which they needed maps of lakebed features on a near-term, mid-term, and long-term timeframe, and why. Then, the responses were analyzed and overlaid to determine areas of shared mapping need and opportunity and to determine the types of map products needed. The analysis revealed high interest among multiple organizations in discrete geographies including the Minnesota and Wisconsin shoreline from Duluth to the eastern extent of the Bayfield Peninsula, Green Bay in Lake Michigan, and the southern coastlines of Lake Erie and Lake Ontario, the St. Marys River, and the northern Lake Superior coastal waters near Grand Portage, MN. Lower priority mapping interest were distributed widely across all lakes, but tended to be concentrated in nearshore areas (<30 m depth). The analysis also indicated that the top mapping justifications were Habitat/biota/natural area, Benthic exploration, Commercial and recreational fishing, and Scientific research. The top desired map product types were Elevation, Substrate/sub-bottom geologic characterization, and Habitat map/characterization, although participants on some lakes noted other less prevalent product types. Following from previously conducted NOAA and non-NOAA Federal spatial prioritization exercises, the results of this regional focus can help mapping organizations better understand how their priorities align with the needs of regional organizations, allow for more efficient coordination and funding, and enable partners to leverage assets and resources to fill their most pressing data and information gaps across Great Lakes waters. The U.S. Mapping Coordination Site hosts the results of this study and other spatial prioritization studies. Through this website, one can interact with the study results along with recent and planned mapping efforts. NOAA intends to update their spatial priorities on a three- to five-year basis. Future studies should strive to expand participation of federal agencies, state and local governments, federally-recognized tribes, academia, and private industry (among other stakeholders) to seek out ocean mapping partnerships in conjunction with the National Ocean Mapping, Exploration and Characterization (NOMEC) goals map once, use many times.”

Great Lakes↗