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USGS1935

Geology and ground-water resources of the island of Oahu, Hawaii

Oahu, one of the islands of the Hawaiian group, lies in the Mid-Pacific 2,100 miles southwest of San Francisco. The principal city is Honolulu. The Koolau Range makes up the eastern part of the island, and the Waianae Range the western part. Both are extinct basaltic volcanoes deeply dissected by erosion. The Koolau Volcano was the later to become extinct. The Waianae Range is made up of three groups of lavas erupted in Tertiary and possibly in early Pleistocene time. The exposed part of the older lava is nearly 2,000 feet thick and consists largely of thin-bedded pahoehoe. It is separated in most places from the middle lavas by an angular unconformity and talus breccia and in a few places by an erosional unconformity. The middle basalts are about 2,000 feet thick and closely resemble the lower ones except that they contain more aa. The upper lavas reach a thickness of about 2,300 feet and are mostly massive aa flows. The last eruptions produced large cinder cones and some nephelite basalts. The Waianae Volcano, like other Hawaiian volcanoes, produced only small amounts of ash, and the lavas were largely extruded from fissures a few feet wide, now occupied by dikes. The center of activity was near Kolekole Pass, at the head of Lualualei Valley. The Koolau Volcano is made up of two groups of lavas extruded in Tertiary and early Pleistocene (?) time. The older group, the Kailua volcanic series, is greatly altered by hydrothermal action and was extruded from fissures near Lanikai. The flows of the younger group, the Koolau volcanic series, were extruded from fissures about a mile south of the Kailua rift and have an exposed thickness of about 3,000 feet. The Koolau Volcano produced even less ash than the Waianae Volcano, and its flows are thin-bedded pahoehoe and aa. The eruptive center of the Koolau Volcano lies between Kaneohe and Waimanalo. Great amounts of both the Waianae and Koolau Ranges were removed by fluvial and marine erosion during the Pleistocene. The master streams are characterized by deep amphitheater-headed valleys. After this erosion cycle the island was submerged more than 1,200 feet, and these great valleys were drowned and alluviated. Besides this submergence, several strand lines, preserved up to 100 feet above present sea level occur, which may be due to world-wide changes in sea level in response to the withdrawal and restoration of water concurrent with the advances and recessions of the polar ice caps and to accompanying changes in the ocean floor. During this time of shifting ocean levels spasmodic eruptions occurred on the southeast end of the Koolau Range, producing numerous lava flows and tuff cones, most of which are nephelite basalt. The last of these eruptions occurred in Recent time. A description of the climate, rates of run-off, and results of experiments to determine evaporation and transpiration in the areas of high rainfall are given. It was found that the consumptive use decreases materially and becomes a very small percentage of the rainfall in the areas of high precipitation. The lava rocks of the island are very permeable and, because of a rainfall reaching a maximum of 300 inches a year, carry large amounts of ground water, confined and unconfined, basal and perched. The basal ground water floats on salt water because of its lower specific gravity. Consequently for each foot the water table stands above sea level, salt water lies about 42 feet below sea level, in accordance with the sea along the coast as basal ground water. In most places the lava rocks along the shore are overlain by an impermeable or nearly impermeable caprock consisting of submerged lateritic soils and marine noncalcareous sediments. These deposits retard the escape of basal ground water into the sea and give rise to artesian water, but unlike most other artesian systems, this one has no lower restraining formation. The artesian water is the principal source of domestic, municipal, and irrigation supplies. The average annual quantity pumped for the period 1928 to 1933 amounted to about 105,000,000,000 gallons, nearly 90 percent of which came from Koolau hasalt and the remainder from Waianae basalt. There are ten artesian areas in the Koolau Range and two in the Waianae Range. Hydraulic gradients in these basins were found to range from 1.2 to 3 feet to the mile. Because of these extremely flat gradients and the high permeability of the aquifers it is possible to reverse the hydraulic gradients by draft and make the water flow from one artesian area to another. The artesian water levels fluctuate in response to seasonal variations in draft and recharge and in a lesser way to tidal, barometric, and seismic pressures. The water, as shown by chemical analysis, is of excellent quality except where it is contaminated with sea water. Methods have been devised for freshening wells that have gone salty, for detecting leaks, for sealing leaky and defective wells, and for recharging the artesian basins. Owing to the danger of the wells becoming brackish with increased draft, it is believed that further large developments will be more successful if shafts are sunk to sea level in the basalt as far inland as practicable, and tunnels are driven from the bottom of the shafts near the top of the saturated zone. Favorable places for such development exist in Honolulu. In addition to the basal water in the volcanic rocks, water is found in the recent gravel, beach, and dune deposits, and the emerged reef limestone. This water has been recovered by wells and tunnels, and there are favorable localities for developing additional water of this type. The island contains two types of basal springs—those like the Pearl Harbor Springs, which issue from basalt and are supplied by overflow and leakage from the artesian basin, and those which issue from the coastal-plain sediments and are mainly return irrigation water. The total quantity of basal ground water issuing as springs is estimated to be 100,000,000 gallons a day. Ground water occurs at high levels, confined by dikes and perched on tuff, alluvium, and soil beds. These structures give rise to innumerable high-level springs. In the Koolau Range 60 tunnels yield about 33,000,000 gallons daily, of which about 95 percent is obtained from tunnels penetrating the dike complex of the Koolau volcanic series, about 2 percent from tunnels entering post-Koolau ash or tuff deposits, and the remainder from tunnels whose geologic relations are not certainly known. The average daily yield of the tunnels that recover dike water is 2,330 gallons a foot, but the average daily yield of the tunnels in post-Koolau tuff is 450 gallons a foot, and that of the tunnels in alluvium or soil is only 23 gallons a foot. Owing largely to the much lower rainfall on the Waianac Range, its 35 tunnels (not including two new tunnels under construction) yield only about 2,400,000 gallons daily, about 94 percent of which is believed to be obtained from dike systems. The average daily yield of the tunnels in this range that are supplied by dike systems is 581 gallons a foot, as compared to 5 gallons a foot from tunnels in ash or tuff. An extensive tunnel system is proposed to develop a large supply of high-level water for Honolulu from the dike complex of the Koolau series, and high-level water can be recovered by tunnels at many other places. The average daily discharge of all high-level springs in the Koolau Range is about 58,000,000 gallons, of which about 94 percent comes from the Koolau dike complex and about 6 percent from post-Koolau volcanic rocks. The average daily discharge of all high-level springs in the Waianae Range is about 500,000 gallons of which about 81 percent issues from the dike complex.

Hawaii↗
USGS1988

The aqueous geochemistry of uranium in a drainage containing uraniferous organic-rich sediments, Lake Tahoe area, Nevada, USA

Anomalously uraniferous waters occur in a small (4.2 km2) drainage in the west-central Carson Range, Nevada, on the eastern side of Lake Tahoe. The waters transport uranium from local U-rich soils and bedrock to organic-rich valley-fill sediments where it is concentrated, but weakly bound. The dissolved U and the U that is potentially available from coexisting sediments pose a threat to the quality of drinking water that is taken from the drainage. The U concentration in samples of 6 stream, 11 spring and 7 near-surface waters ranged from <1 to 177 ??g l-1 with an average value of 17 ?? 14 ??g l-1 for stream and spring waters. This value significantly exceeds a reported regional average value of ~5 ??g l-1, and is comparable to proposed maximum contaminant levels of U in drinking water. Calculations that utilize chemical compositions of the waters and thermodynamic data indicate that uranyl-carbonate and uranyl-phosphate complexes are the major inorganic species of dissolved U. In addition, dialysis experiments suggest an association of at least some dissolved U with macromolecular organic matter, particularly in near-surface waters that are in contact with organic-rich sediments. Calculations of the saturation index for uranous and uranyl-bearing minerals indicate that all of the waters are undersaturated with uranium minerals as long as ambient Eh is oxidizing (i.e. > 0.1 V). Possible precipitation of U(IV) minerals is predicted under the more reducing conditions that are particularly likely in near-surface waters, but the inhibitory effects of sluggish kinetics or organic complexing are not considered. These combined results suggest that a process such as adsorption or ion exchange, rather than mineral saturation, is the most probable mechanism for uranium fixation in the sediments. -Authors

Uranium↗
USGS1997

Concentrations of chlorinated organic compounds in biota and bed sediment in streams of the San Joaquin Valley, California

Samples of resident biota and bed sediments were collected in 1992 from 18 sites on or near the floor of the San Joaquin Valley, California, for analysis of 33 organochlorine compounds. The sites were divided into five groups on the basis of physiographic region and land use. Ten compounds were detected in tissue, and 15 compounds were detected in bed sediment. The most frequently detected compound in both media was p,p'-DDE. Concentrations of ??DDT (sum of o,p'- and p, p' forms of DDD, DDE, and DDT) were statistically different among groups of sites for both tissue and sediment (Kruskal- Wallis, p < 0.05). Concentrations in both media were highest in streams draining the west side of the valley. Concentrations of ??DDT in tissue were significantly correlated with specific conductance, pH, and total alkalinity (p < 0.05), which are indicators of the proportion of irrigation return flows in stream discharge. Concentrations in sediment on a dry-weight basis were not correlated with these water-quality parameters, but total organic carbon (TOC) normalized concentrations were significantly correlated with specific conductance and pH (p < 0.05). Regressions of the concentration of ??DDT in tissue, as a function of ??DDT in bed sediment, were significant and explained up to 76% of the variance in the data. The concentration of ??DDT in sediment may be related to mechanisms of soil transport to surface water with bioavailability of compounds related to the concentration of TOC in sediment. The results of this study did not indicate any clear advantage to using either bed sediment or tissues in studies of organochlorine chemicals in the environment. Some guidelines for protection of fish and wildlife were exceeded. Concentrations of organochlorine chemicals in biota, and perhaps sediment, have declined from concentrations measured in the 1970s and 1980s, but remain high compared to other regions of the United States.

Archives of Environmental Contamination and Toxico↗
USGS1988

Effects of highway runoff on streamflow and water quality in the Sevenmile Creek basin, a rural area in the Piedmont Province of North Carolina, July 1981 to July 1982

An evaluation of water-quality data from streams that receive stormwater runoff from a segment of Interstate Highway 85 in North Carolina indicated increased levels of many constituents compared to levels in nearby undeveloped basins. Additional data collected from a network of dry and wet atmospheric deposition collectors, lysimeter samples, soil surveys, wind measurements, and road sweepings helped define the general sources and migration of chemical substances near the highway. The eight study basins, located in a rural area in the Piedmont of North Carolina, had a combined area of 17.5 square miles and drained a 4.8-mile-long segment of the interstate. The average traffic flow along this section was 25,000 vehicles per day. During storm runoff, streamflow in basins traversed by the highway rose and fell more rapidly than that in the undeveloped basins. This more rapid response is due to the impervious, paved area of the basins and the manmade drainage systems designed to rapidly move water off the highway. Alkalinity, specific conductance, and concentrations of calcium, sodium, and chloride were greater at the highway stations than in the undeveloped basins as a result of highway salting for control of ice. Specific conductance and concentrations of dissolved and total nitrogen peaked at the beginning of each storm event. The data indicated that, for the study basins, highway runoff had little or no effect on suspended sediment, water temperature, dissolved oxygen, and pH. However, the pH at all stations decreased during stormflow because the rainfall drained off by the streams had pH values less than 5.7. High metals concentrations were found in the soils within 100 feet of the highway and in the soil water infiltrating the soil zone. Chromium, copper, nickel, and zinc concentrations in the streams near the highway generally were above the maximum levels recommended by the U.S. Environmental Protection Agency (EPA) for the protection of aquatic life. Lead and cadmium concentrations frequently exceeded the maximum levels recommended by the EPA for drinking water. The highway is a source of contaminants to surrounding areas. Particulate and metal loads in dustfall and chemical-constituent concentrations in soils decrease exponentially with distance from the highway. The highest concentrations of contaminants were found on the downwind side. Increased concentrations of metals (cadmium, chromium, iron, lead, nickel, and zinc) in rainfall were observed in samples collected near the highway and in samples collected approximately one-half mile away. Material loading due to dustfall was greater than loading due to rainfall. Loading due to saltated particles, those heavier particles bounced along the highway surface, was higher than loading due to dustfall. Saltation loads were greatest during the winter months because of highway deicing and sanding, which supplied an estimated two-thirds of the saltated materials. The remaining one-third of the saltated load came primarily from the deposition of particles from vehicles. Some of the greatest constituent concentrations were measured in the soil water sampled from the lysimeters located adjacent to the highway.

North Carolina↗
USGS1986

Environmental fate of mercury discharged into the upper Wisconsin River

The authors studied the distribution of Hg in sediments, fish, and crayfish in a 60 km reach of the Upper Wisconsin River that formerly received Hg in discharges from pulp and paper mills. The most heavily contaminated strata of sediments were deposited during the 1950s and early 1960s and buried under subsequent deposits; however, surficial sediments remained substantially enriched at certain sites in 1981. Median concentrations of Hg in surficial sediments, adjusted for grain size, were at least 10-fold greater at the main study area than at an upstream reference site. Total concentrations exceeded 1.0 mu g g super(-1) wet weight in axial muscle tissue in only 2 of 173 fish analyzed from the study area; however, historical comparisons revealed that Hg contamination of fish (common carp Cyprinus carpio and walleye Stizostedion vitreum vitreum ) and crayfish (Orconectes ) in the river had not decreased since the early 1970s.

Water, Air, & Soil Pollution↗
USGS1990

The geology of selected peat-forming environments in temperate and tropical latitudes

We studied peat in several geologic and climatic settings: (1) a glaciated terrain in cold-temperate Maine and Minnesota, U.S.A.; (2) an island in a temperate maritime climate in the Atlantic Ocean off the coast of Maine, U.S.A., where sea level is rising rapidly and changing the environment of peat accumulation; (3) swamps along the warm-temperate U.S. Atlantic and Gulf Coastal Plains, where sea level has changed often, thus creating sites for accumulation; and (4) in a tropical climate along the coast of Sarawak, Malaysia, and the delta of the Batang Hari River, Sumatra, Indonesia (Figs. 1 and 2). With the exception of the deposits on the Atlantic and Gulf Coastal Plains, most of the deposits described are domed bogs in which peat accumulation continued above the surface of the surrounding soil. The bogs of the U.S. Atlantic and Gulf Coastal Plains have almost level surfaces. All domed bogs are not entirely ombrotrophic (watered only from precipitation); multidomed bogs that rise from irregular or hilly surfaces may be crossed by streams that supply water to the bogs. The geologic processes or organic sedimentation, namely terrestrialization and paludification, are similar in all peat deposits considered here. Differences in geomorphology affecting the quantity and that quality of peat that has ash contents of less than 25%, which are desirable for commercial purposes, depend chiefly on: (1) high humidity, which is favorable to luxuriant growth of peat-forming vegetation; (2) a depositional setting that permits extensive accumulation relatively free from inorganic contamination from sea water and streams and from dust and volcanic ash; and (3) a stable regional water table that controls the rate of decomposition under aerobic conditions and protects the deposit against the ravages of fire. Differences in peat textures are due to the type of vegetation and to the degree of decomposition. The rate of decomposition is largely the result of the amount of oxidation and aerobic microbial activity. Stratigraphic distribution of various textures and amounts of inorganic components within a peat deposit is largely determined by the vertical positions occupied by peat-forming environments, such as pond, marsh, swamp and heath where vegetation accumulated, and the depth to zones of unoxygenated water. Peat also differs in the rate of accumulation. On the basis of carbon-14 dating, an estimated 8 m of peat in the tropical Batang Hari River deposit in Sumatra has been accumulating at the rate of about 1.5 m/1,000 yr, whereas peat in the cold-temperate deposit in Maine has been accumulating at the rate of 0.66 m/1,000 yr. Accumulation rates in domed deposits such as these are affected not only by factors controlling volume of biomass and aerobic decay but also by stream erosion and fires that remove peat. Such disconformities (see Fig. 2) within the deposit may be recognized by sudden vertical changes in degree of decomposition and/or the presence of charcoal. The trace-element content of peat deposits is affected by the environments of their settings. Samples of peat that have an ash content of less than 25% dry weight and that are from small, almost level swamp deposits along the Atlantic Coastal Plain of North Carolina were compared with similar samples from small domed bogs in Maine, a glaciated area. Samples from Nort Carolina, which are from deposits in thick fluvial and nearshore marine sediments far from the bedrock source, are generally higher in Ti, Cr and Pb. The Maine samples from deposits in glacial drift close to the bedrock source contain more Zn, Mn, P, Ca, Na and Fe. The kind and amount of trace elements within the deposits appear to relate largely to depositional setting, to kinds of bedrock source, and to the modes of transportation from source to peat swamp. Trace-element concentrations in the extensive Sumatra peat deposit, which represents a potentially commercial coal bed, are similar to those found in Appalachian coals except for As and Au, which are higher in the former. This similarity most likely implies that geochemical controls on mineral matter controlled the concentrations in both. Most peat deposits found in the world today are not precursors of economic coal beds because they are too local in extent, lack beds of commercial-quality peat greater than 6 m thick, and/or are too far from sea level to be rapidly by marine or marginal marine sediments before destruction by erosion and decomposition. However, the two domed deposits in Sarawak and Sumatra described above are parts of extensive, thick, low-sulfur, fuel-quality peat deposits, which have bases below the levels of rivers on coastal deltas. These are likely to be preserved in their lower part and to become precursors of tropical coal seams of potential economic importance. The lenticular and tabular peat deposits of the Atlantic and Gulf Coastal Plains, which have little chance of survival, have features resembling those in Tertiary peat deposits in alluvial settings of western North America. The quality, shape, and extent of modern and ancient peat deposits are controlled by the same factors - humidity, vegetation type, ground- and surface-water regimes, and physiographic and geologic setting. Thus, a study of modern peat deposits may help in studies of the areal distribution and the thickness and quality of ancient coal beds.

International Journal of Coal Geology↗
USGS2002

Effect of adsorbed metals ions on the transport of Zn- and Ni-EDTA complexes in a sand and gravel aquifer

Adsorption, complexation, and dissolution reactions strongly influenced the transport of metal ions complexed with ethylenediaminetetraacetic acid (EDTA) in a predominantly quartz-sand aquifer during two tracer tests conducted under mildly reducing conditions at pH 5.8 to 6.1. In tracer test M89, EDTA complexes of zinc (Zn) and nickel (Ni), along with excess free EDTA, were injected such that the lower portion of the tracer cloud traveled through a region with adsorbed manganese (Mn) and the upper portion of the tracer cloud traveled through a region with adsorbed Zn. In tracer test S89, Ni- and Zn-EDTA complexes, along with excess EDTA complexed with calcium (Ca), were injected into a region with adsorbed Mn. The only discernable chemical reaction between Ni-EDTA and the sediments was a small degree of reversible adsorption leading to minor retardation. In the absence of adsorbed Zn, the injected Zn was displaced from EDTA complexes by iron(III) [Fe(III)] dissolved from the sediments. Displacement of Zn by Fe(III) on EDTA became increasingly thermodynamically favorable with decreasing total EDTA concentration. The reaction was slow compared to the time-scale of transport. Free EDTA rapidly dissolved aluminum (Al) from the sediments, which was subsequently displaced slowly by Fe. In the portion of tracer cloud M89 that traveled through the region contaminated with adsorbed Zn, little displacement of Zn complexed with EDTA was observed, and Al was rapidly displaced from EDTA by Zn desorbed from the sediments, in agreement with equilibrium calculations. In tracer test S89, desorption of Mn dominated over the more thermodynamically favorable dissolution of Al oxyhydroxides. Comparison with results from M89 suggests that dissolution of Al oxyhydroxides in coatings on these sediment grains by Ca-EDTA was rate-limited whereas that by free EDTA reached equilibrium on the time-scale of transport. Rates of desorption are much faster than rates of dissolution of Fe oxyhydroxides from sediment-grain surfaces and, therefore, adsorbed metal ions can strongly influence the speciation of ligands like EDTA in soils and sediments, especially over small temporal and spatial scales.

Geochimica et Cosmochimica Acta↗
USGS2006

Water-quality characteristics and contaminants in the rural karst-dominated Spring Mill Lake watershed, southern Indiana

The Spring Mill Lake watershed is located in the Mitchell Plateau, a karst area that developed on Mississippian carbonates in southern Indiana. Spring Mill Lake is a reservoir built in the late 1930s and is located in Spring Mill State Park. Within the park, groundwater from subsurface conduits issues as natural springs and then flows in surface streams to the lake. From 1998 to 2002, surface and subsurface hydrology and water quality were investigated to determine the types and sources of potential contaminants entering the lake. Water samples collected during base flow and a February 2000 storm event were analyzed for selected cations, anions, trace elements, selected U.S. Environmental Protection Agency (EPA) primary and secondary drinkingwater contaminants, nitrogen isotopes, suspended solids, Escherichia coli, and pesticides. All of the water samples met the EPA drinking-water standards for inorganic constituents, except those collected at five sites in August 1999 during a drought. Nitrate nitrogen (NO 3 -N) concentrations were highest during base-flow conditions and displayed a dilutional trend during peak-flow periods. The NO 3 -N concentrations in water samples collected during the 2001 spring fertilizer applications tended to increase from early to late spring. All of the ?? 15 N values were low, which is indicative of either an inorganic source or soil organic matter. Storm discharge contained increased concentrations of total suspended solids; thus, storms are responsible for most of the sediment accumulation in the lake. E. coli levels in 24% of the samples analyzed contained a most probable number (MPN) greater than 235/100 mL, which is the maximum acceptable level set for recreational waters in Indiana. E. coli does appear to be a potential health risk, particularly at Rubble spring. The sources of E. coli found at this spring may include barnyard runoff from a horse barn or wastes from a wastewater treatment facility. The pesticides atrazine, metolachlor, acetochlor, and simazine were detected during the spring of 2001. Atrazine, metolachlor, acetochlor, and simazine are used to suppress weeds during corn and soybean production. Additional sources of atrazine and simazine may result from application to right-of-ways, orchards, and managed forest areas. ?? 2006 Geological Society of America.

Special Paper of the Geological Society of America↗
USGS2005

Determination of total mercury in biological and geological samples

The analytical chemist is faced with several challenges when determining mercury in biological and geological materials. These challenges include widespread mercury contamination, both in the laboratory and the environment, possible losses of mercury during sample preparation and digestion, the wide range of mercury values commonly observed, ranging from the low nanogram per gram or per liter for background areas to hundreds of milligrams per kilogram in contaminated or ore-bearing areas, great matrix diversity, and sample heterogeneity1. These factors can be naturally occurring or anthropogenic, but must be addressed to provide a precise and accurate analysis. Although there are many instrumental methods available for the successful determination of mercury, no one technique will address all problems or all samples all of the time. The approach for the determination of mercury used at the U.S. Geological Survey, Crustal Imaging and Characterization Team, Denver Laboratories, utilizes a suite of complementary instrumental methods when approaching a study requiring mercury analyses. Typically, a study could require the analysis of waters, leachates or selective digestions of solids, vegetation, and biological materials such as tissue, bone, or shell, soils, rocks, sediments, coals, sludges, and(or) ashes. No one digestion or sample preparation method will be suitable for all of these matrices. The digestions typically employed at our laboratories include: (i) a closed-vessel microwave method using nitric acid and hydrogen peroxide, followed by digestion/dilution with a nitric acid/sodium dichromate solution, (ii) a robotic open test-tube digestion with nitric acid and sodium dichromate, (iii) a sealed Teflon? vessel with nitric acid and sodium dichromate, (iv) a sealed glass bottle with nitric acid and sodium dichromate, or (v) open test tube digestion with nitric and sulfuric acids and vanadium pentoxide. The common factor in all these digestions is that they are very oxidative to ensure the conversion of all mercury forms into Hg (II). Each method of digestion has its advantages and limitations. The method of detection used in our laboratories involves a combination of an in-house, custom, classic continuous-flow cold-vapor atomic absorption spectrometry (CVAAS), a commercially available, automated, flow-injection and a continuous flow cold-vapor atomic fluorescence spectrometry (CV-AFS) systems, and a relatively new, automated and integrated approach where solid or liquid samples are thermally decomposed under an oxygen atmosphere (a nitrogen atmosphere is used for coals) and the released mercury vapor trapped onto a gold gauze and then thermally released into an AAS system. Other less frequently used instrumental methods available for the determination of mercury include inductively coupled plasma ? optical emission spectrometry (ICP-OES), inductively couple plasma ? mass spectrometry (ICP-MS) (both solution nebulization and laser ablation), and instrumental neutron activation analysis (INAA). Results from two case studies involving the determination of mercury in the challenging matrices of biological materials will be presented. These will include fillet, liver and stomach-content samples from grayling for a baseline/background study in Alaska, and samples of meat tissue and shell material from Tanner crabs from Glacier Bay, Alaska. These studies show that the method of digestion is more important than a very sensitive detection limit for mercury.

Open-File Report↗
USGS1997

Surface-water quality changes after 5 years of nutrient management in the Little Conestoga Creek headwaters, Pennsylvania, 1989-91

A 5.82-square-mile drainage basin in the headwaters of the Little Conestoga Creek in Lancaster County, Pa., was investigated from October 1989 through September 1991 as part of a longer-term effort to determine the effects of nutrient management on surface-water quality. A previous investigation found no statistical evidence that implementation of nutrient management from 1986 to 1989 affected water quality. Basin land use is 68 percent agriculture and includes all or part of 51 farms. Agricultural land under nutrient management ranged from 55 percent in 1989 to 80 percent in 1991. Nitrate nitrogen, the dominant nonpoint-source contaminant, averaged about 7.5 milligrams per liter in base flow. Implementation of nutrient management on 90 percent of applicable land in a 1.42-square-mile subbasin resulted in a 7 percent decrease in nitrogen applications from before nutrient management. Recognizing that some uncertainty exists in the nutrient-application data, the decrease consisted of a 44-percent decrease in commercial fertilizer nitrogen combined with a 3-percent increase in manure nitrogen applications. Manure accounted for 83 percent of the applied nitrogen. Amounts of nitrate nitrogen in the top 4 feet of soil ranged from 43 to 315 pounds per acre in the subbasin and were not substantially reduced from before nutrient management. Statistical analysis of nutrient and suspended-sediment concentrations detected few significant step trends in water quality in a comparison with water quality before nutrient management. A decrease in base-flow concentrations of dissolved ammonium and suspended sediment was detected at a site draining a 1.43-square-mile subbasin with 40-percent implementation of nutrient-management plans. An increase in base-flow concentrations of suspended sediment was detected at a site draining the 1.42-square-mile subbasin with 90-percent implementation. A comparison of the dissolved nitrate plus nitrite in base-flow relations between paired subbasins detected no change from 1984-86 (before nutrient management) to 1989-91. Mean concentrations in stormflow were not reduced significantly from 1984-86 to 1989-91. Data collected during the entire 1986-91 nutrient-management period suggest a reduction in nitrogen input as large as the 30-percent reduction recorded from 1986-89 is needed to effect a 0.5-milligram-per-liter decrease in dissolved nitrate plus nitrite.

Pennsylvania↗
USGS1986

A new model for humic materials and their interactions with hydrophobic organic chemicals in soil-water or sediment-water systems

A generalized model of humic materials in soils and sediments, which is consistent with their observed properties, is presented. This model provides a means of understanding the interaction of hydrophobic pollutants with humic materials. In this model, it is proposed that the humic materials in soils and sediments consist of a number of different oligomers and simple compounds which result from the partial degradation of plant remains. These degradation products are stabilized by incorporation into humic aggregates bound together by weak bonding mechanisms, such as hydrogen bonding, pi bonding, and hydrophobic interactions. The resulting structures are similar to micelles or membranes, in which the interiors of the structures are hydrophobic and the exteriors are hydrophilic. Hydrophobic compounds will partition into the hydrophobic interiors of the humic micelles or "membrane-like" structures. ?? 1986.

Journal of Contaminant Hydrology↗
USGS2021

Uranium(VI) attenuation in a carbonate-bearing oxic alluvial aquifer

Uranium minerals are commonly found in soils and sediment across the United States at an average concentration of 2–4 mg/kg. Uranium occurs in the environment primarily in two forms, the oxidized, mostly soluble uranium(VI) form, or the reduced, sparingly soluble reduced uranium(IV) form. Here we describe subsurface geochemical conditions that result in low uranium concentrations in an alluvial aquifer with naturally occurring uranium in soils and sediments in the presence of complexing ligands under oxidizing conditions. Groundwater was saturated with respect to calcite and contained calcium (78–90 mg/L) with elevated levels of carbonate alkalinity (291–416 mg/L as HCO 3 − ). X-ray adsorption near edge structure (XANES) spectroscopy identified that sediment-associated uranium was oxidized as a uranium(VI) form (85%). Calcite was the predominant mineral by mass in the ultrafine fraction in uranium-bearing sediments (>16 mg/kg). Groundwater geochemical modeling indicated calcite and/or a calcium-uranyl-carbonate mineral such as liebigite in equilibrium with groundwater. The δ 13 C (0.57‰ ± 0.15‰) was indicative of abiotic carbonate deposition. Thus, solid-phase uranium(VI) associated with carbonate is likely maintaining uranium(VI) groundwater levels below the maximum contaminant level (MCL; 30 µg/L), presenting a deposition mechanism for uranium attenuation rather than solely a means of mobilization.

Nebraska↗
USGS2005

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin — Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

As part of a national analysis of the effects of land use on ground-water quality for the National Water-Quality Assessment Program, the U.S. Geological Survey sampled wells along a flow system in surficial glacial aquifers in the northwestern part of the Twin Cities metropolitan area during 1997 and 1998. In addition, a reconnaissance steady-state ground-water model was developed to estimate flowpaths and dates of ground-water recharge using a particle-tracking routine. Sediment samples collected during drilling had high horizontal hydraulic conductivities (ranging from about 3.1 to about 190 feet per day, based on sediment-size analysis of well cuttings), small organic carbon concentrations (ranging from less than 0.2 to 160 grams per kilogram), and pH values that were mostly alkaline (ranging from 4.9 to 8.2). Water samples were analyzed for physical properties, major ions, iron, manganese, nutrients, organic carbon, radon, pesticides, volatile organic compounds (VOCs), chlorofluorocarbons, tritium, and isotopes of nitrogen, hydrogen, and oxygen. Most of the water samples had small dissolved-oxygen concentrations (less than 1 milligram per liter). Calcium, magnesium, sodium, bicarbonate, sulfate, and chloride were the primary dissolved constituents in water samples. Nitrite plus nitrate as nitrogen (nitrate) concentrations were less than the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level of 10 mg/L. Nitrogen isotope ratios indicated that the sources of nitrate primarily were soils, animal waste, or denitrification that increased nitrogen isotope ratios in nitrate. Small concentrations of pesticides were detected in the shallow parts of the aquifer. The herbicide prometon was the most frequently detected pesticide. Herbicides applied to control grasses and weeds in corn (atrazine, simazine, and metolachlor) also were frequently detected in water samples. All pesticide and VOCs detected were below USEPA Maximum Contaminant Levels or Health Advisory Limits. Chlorofluorocarbon compounds and tritium concentrations were used to estimate dates of recharge of ground-water samples. In general, shallower ground-water samples were more recently recharged although most water sampled from the aquifer was recharged after 1955. Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Minnesota↗
USGS2023

Hydrologic investigations of green infrastructure by the Central Midwest Water Science Center

The water management system within developed communities includes stormwater, wastewater, and drinking-water sources and sinks. Each water management system component provides critical services that support public health in these areas. Stormwater can be quite variable and difficult to manage in developed communities because the amount of stormwater that must be routed through a developed area depends on changing land cover and variable precipitation. In addition to flooding concerns, stormwater also is a major cause of water contamination in developed communities because it carries contaminants such as trash, bacteria, heavy metals, and sediments to local waterways. Historically, communities have managed stormwater with gray infrastructure such as street gutters, culverts, sewer systems, and tunnels. Although these structures efficiently capture and route stormwater to a local waterway or treatment plant, they do not filter any contaminants. Furthermore, many older communities have combined storm sewer and sanitary sewer systems. These combined systems result in an excessive amount of wastewater to be treated before being released into receiving water or the untreated waters are released directly to receiving waters during storms. Many communities are now incorporating green infrastructure stormwater mitigating solutions—pervious surfaces (allows water through), grassed swales, bioretention basins, and rain gardens—into their stormwater-management systems. Green infrastructure can absorb and filter stormwater where it falls by taking advantage of natural soil and plant storage and filtration capabilities. Thus, green infrastructure projects can potentially reduce the amount of stormwater and the concentration and transport of contaminants. Increasing green infrastructure in a developed community may reduce the requirements for new storm sewer infrastructure, improve the water quality of nearby waterways, and enhance aesthetics. The U.S. Geological Survey has partnered with several cooperators to quantify the effects of green infrastructure projects in several developed communities throughout the central Midwest. As part of these green infrastructure projects, the U.S. Geological Survey Central Midwest Water Science Center and cooperators installed, calibrated, and monitored equipment to measure hydrologic responses (including flooding and water movement) and selected water-quality constituents in developed communities.

Fact Sheet↗
USGS2004

Surficial materials in the conterminous United States

Introduction: The Earth's bedrock is overlain in many places by a loosely compacted and mostly unconsolidated blanket of sediments in which soils commonly are developed. These sediments generally were eroded from underlying rock, and then were transported and deposited. In places, they exceed 1,000 ft (330 m) in thickness. Where the sediment blanket is absent, bedrock is either exposed or has been weathered to produce a residual soil. This map shows the sediments and the weathered, residual material; for ease of discussion, these are referred to here as 'surficial materials.' Certain areas on this map include a significant number of rock outcrops, which cannot be shown at the scale of the map; this is noted in the 'Description of Map Units' section. Most daily human activities occur on or near the Earth's surface. Homeowners, communities, and governments can make improved decisions about hazard, resource, and environmental issues, when they understand the nature of surficial materials and how they vary from place to place. For example, are the surficial materials upon which a home is built stable enough to resist subsidence or lateral movement during an earthquake? Do these materials support a ground water resource adequate for new homes? Can they adequately filter contaminants and protect buried aquifers both in underlying sediments and in bedrock? Are they suitable for development of a new wetland? Where can we find materials suitable for aggregate? The USGS National Cooperative Geologic Mapping Program (NCGMP) works with the State geological surveys to identify priority areas for mapping of surficial materials (for example, in areas of complex and poorly understood deposits of various sediment types, where metropolitan areas are experiencing rapid growth). To help establish these priorities, a modern, synoptic overview of the geology is needed. This map represents an overview of our current knowledge of the composition and distribution of surficial materials in the conterminous United States. (The map covers only the conterminous U.S. because similar geologic information in digital form was not readily available for Alaska and Hawaii.) The best available map has been a highly generalized depiction at 1:7,500,000-scale (about 120 miles to the inch), prepared for the USGS National Atlas (Hunt, 1979; 1986). This map is compiled at a slightly more detailed scale (about 80 miles to the inch) than Hunt (1979; 1986). We used digital methods, which enabled us to rapidly incorporate the variety of source maps available to us. State-scale geologic maps from the western United States were brought directly into this map, without expending the time needed to resolve interpretive differences among them. Therefore, abrupt changes in surficial materials are indicated along many State boundaries. This of course is an artifact of our compilation technique, and a limitation on its utility. However, this approach supports the basic premise of the map -- to provide an overview of surficial materials, and to identify areas where additional work may be needed in order to resolve scientific issues that can, in turn, lead to improved mapping.

Open-File Report↗
USGS1993

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Pine River Project area, Southern Ute Indian Reservation, southwestern Colorado and northwestern New Mexico, 1988-89

During 1988-89, water, bottom sediment, biota, soil, and plants were sampled for a reconnaissance investigation of the Pine River Project area in southwestern Colorado. Irrigation drainage does not seem to be a major source of dissolved solids in streams. Concentrations of manganese, mercury, and selenium exceeded drinking-water regulations in some streams. The maximum selenium concentration in a stream sample was 94 microg/L in Rock Creek. Irrigation drainage and natural groundwater are sources of some trace elements to streams. Water from a well in a nonirrigated area had 4,800 microg/L of selenium. Selenium concentrations in soil on the Oxford Tract were greater in areas previously or presently irrigated than in areas never irrigated. Some forage plants on the Oxford Tract had large selenium concentrations, including 180 mg/km in alfalfa. Most fish samples had selenium concentrations greater than the National Contaminant Biomonitoring Program 85th percentile. Selenium concentrations in aquatic plants, aquatic inverte- brates, and small mammals may be of concern to fish and wildlife because of possible food-chain bioconcentration. Selenium concentrations in bird samples indicate selenium contamination of biota on the Oxford Tract. Mallard breasts had selenium concentrations exceeding a guideline for human consumption. The maximum selenium concentration in biota was 50 microg/g dry weight in a bird liver from the Oxford Tract. In some fish samples, arsenic, cadmium, copper, and zinc exceeded background concentrations, but concentrations were not toxic. Mercury concentrations in 16 fish samples exceeded the background concentration. Ten mercury concentrations in fish exceeded a guideline for mercury in food for consumption by pregnant women.

Colorado↗
USGS2009

Mercury sources to Lake Ozette and Lake Dickey: Highly contaminated remote coastal lakes, Washington State, USA

Mercury concentrations in largemouth bass and mercury accumulation rates in age-dated sediment cores were examined at Lake Ozette and Lake Dickey in Washington State. Goals of the study were to compare concentrations in fish tissues at the two lakes with a larger statewide dataset and examine mercury pathways to the lakes. After accounting for fish length, tissue concentrations at the lakes were significantly higher than other Washington State lakes. Wet deposition and historical atmospheric monitoring from the area show no indication of enhanced local or regional deposition. Sediment core records from the lakes indicate rising sedimentation rates coinciding with logging in the lakes’ drainages has greatly increased the net flux of mercury to the waterbodies.

Washington↗
USGS2014

Mercury cycling in agricultural and managed wetlands: a synthesis of methylmercury production, hydrologic export, and bioaccumulation from an integrated field study

With seasonal wetting and drying, and high biological productivity, agricultural wetlands (rice paddies) may enhance the conversion of inorganic mercury (Hg(II)) to methylmercury (MeHg), the more toxic, organic form that biomagnifies through food webs. Yet, the net balance of MeHg sources and sinks in seasonal wetland environments is poorly understood because it requires an annual, integrated assessment across biota, sediment, and water components. We examined a suite of wetlands managed for rice crops or wildlife during 2007–2008 in California's Central Valley, in an area affected by Hg contamination from historic mining practices. Hydrologic management of agricultural wetlands for rice, wild rice, or fallowed — drying for field preparation and harvest, and flooding for crop growth and post-harvest rice straw decay — led to pronounced seasonality in sediment and aqueous MeHg concentrations that were up to 95-fold higher than those measured concurrently in adjacent, non-agricultural permanently-flooded and seasonally-flooded wetlands. Flooding promoted microbial MeHg production in surface sediment of all wetlands, but extended water residence time appeared to preferentially enhance MeHg degradation and storage. When incoming MeHg loads were elevated, individual fields often served as a MeHg sink, rather than a source. Slow, horizontal flow of shallow water in the agricultural wetlands led to increased importance of vertical hydrologic fluxes, including evapoconcentration of surface water MeHg and transpiration-driven advection into the root zone, promoting temporary soil storage of MeHg. Although this hydrology limited MeHg export from wetlands, it also increased MeHg exposure to resident fish via greater in situ aqueous MeHg concentrations. Our results suggest that the combined traits of agricultural wetlands — slow-moving shallow water, manipulated flooding and drying, abundant labile plant matter, and management for wildlife — may enhance microbial methylation of Hg(II) and MeHg exposure to local biota, as well as export to downstream habitats during uncontrolled winter-flow events.

California↗