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At least 199 records · Page 11Linked to original sources

A Precambrian diamictite below the base of the Stillwater Complex, southwestern Montana

The metasedimentary rocks of Precambrian age below the base of the Stillwater Complex, southwestern Montana, contain a metamorphosed diamictite similar to diamictite in strata of late Precambrian and Early Cambrian age in Canada and the Western United States. The diamictite consists of a quartz-cordierite matrix containing an average 10-15 percent of rock fragments diverse in shape, size, angularity, lithologic types, and textures. The diamictite unit is poorly sorted, crops out discontinuously for 14 miles, and locally has a crude layering containing dropstones. Its origin is debatable, but the rock is suggestive of glacial marine deposition. The minimum age of the diamictite of the complex is 2,750 m.y. from U-Pb determination on zircon of intrusive quartz monzonite, the maximum 3,140 m.y. as determined on zircon from metasedimentary rocks interbedded with the diamictite.

Montana

Metamorphic facies indicated by vein minerals in basal beds of the Great Valley sequence, northern California

A reexamination of reported blueschist mineral localities in the basal strata of the Great Valley sequence revealed only prehnite-pumpellyite facies minerals. Franciscan graywacke thrust below the Great Valley rocks contains lawsonite-quartz blueschist assemblages. At a common pressure of about 4 kb, the Franciscan blueschists formed at lower temperatures than the overlying Great Valley prehnite-bearing rocks, lending support to tectonic models that involve rapid subduction of the Franciscan rocks.

California

Boron-bearing potassium feldspar of authigenic origin in closed-basin deposits

Silicic vitric tuffs in saline, alkaline lacustrine deposits are commonly altered to a variety of zeolites and potassium feldspar. The tuffs generally show a lateral gradation, in a basinward direction, of fresh glass to zeolites and then to potassium feldspar. Zeolites were formed early in diagenesis by reaction of the glass with the interstitial water. The feldspar, however, was formed later by reaction of the zeolites with interstitial water, and its formation can be correlated with water of relatively high salinity and alkalinity. Semiquantitative spectrographic analyses for boron in the zeolites and potassium feldspar show that most of the boron resides in the relatively late feldspar. The boron content of the zeolites is commonly less than 100 ppm, whereas the boron content of the potassium feldspar is commonly greater than 1,000 ppm. Boron apparently substitutes for aluminum in the feldspar structure and causes distortion of the monoclinic unit cell such that the b and c dimensions are shortened. These boron-bearing potassium feldspars having anomalous cell parameters seem unique to saline, alkaline lacustrine deposits and could serve as a prospecting aid for locating buried saline minerals.

Journal of Research of the U.S. Geological Survey

Permian paleogeography of the Arctic

Three large land areas were dominant in the Arctic during the Permian: Fennoscandia, central and southern Siberia (Angara), and Canada. Smaller landmasses were in China, the Seward-Chukotskiy region, northern and eastern Siberia, and near Alaska. Coal deposits and strata bearing land plants covered a large area in central Siberia; saline basins containing red beds formed in the Zechstein, Perm, and West Texas basins as the seas withdrew, generally in the later Permian. Eugeosynclinal troughs, apparently limited to the Pacific border regions, were marked by volcanism and deposition of predominantly clastic sediments in many areas. Platform and miogeosynclinal deposits, dominated by carbonate rocks, preceded saline deposition in the basins and persisted on shallow shelves adjacent to the geosynclines. The Arctic Permian marine fauna evolved in middle Permian time because of partial isolation of the Arctic areas from the southern ocean. Endemism, latitudinal temperature controls, and the effect of ocean currents explain in large part the faunal patterns in Permian seas. Post-Permian tectonic movements account for anomalies in the present positions of some rock sequences and fossils. Northeasterly drift and counterclockwise rotation of the northern landmasses are suggested. Right-lateral shear along the southern edge of Asia is supported, followed by northward movement of peninsular India.

Journal of Research of the U.S. Geological Survey

Pliocene marine fossils in the Paso Robles Formation, California

Marine invertebrates from the Paso Robles Formation recently discovered near Atascadero, Calif., indicate that the basal part of this chiefly nonmarine deposit is of provincial early Pliocene age. Heretofore the lack of direct fossil or radiometric evidence of the age of the Paso Robles has made it a difficult unit to place in the late Cenozoic history of the Coast Ranges. The assemblage is dominated by Ostrea vespertina and by Nettastomella rostrata , a rock-boring bivalve; its mode of preservation indicates that the fossils are in place and have not been recycled from older marine formations. This occurrence suggests that during the early Pliocene a seaway connected the present southern Salinas Valley area with the northern part of the Santa Maria basin; the fossils occur about halfway between the southernmost exposures of the Pancho Rico Formation near San Miguel and fossiliferous strata east of Pismo Beach, both marine units of early Pliocene age.

California

Galkhaite, (Hg,Cu,Tl,Zn) (As,Sb)S2, from the Getchell mine, Humboldt County, Nevada

The first reported occurrence in the United States of galkhaite (Hg,Cu,Tl,Zn)(As,Sb)S 2 is at the Getchell mine, Humboldt County, Nev. The mineral occurs as brownish-black cubes associated with graphite, pyrite, and realgar. In polished section galkhaite is grayish white and isotropic with a deep-red internal reflection; reflectivity at 590 nm is 21.6 percent. Spectrographic analysis gave Hg 42 percent, Cu 5 percent, Zn 1.5 percent, Fe 0.7 percent, Tl 5 percent, As 24 percent, Sb 0.3 percent, and S (by difference) 21.3 percent. The mineral is cubic, a=10.36, and the strong lines of the X-ray powder pattern are 2.99 (100), 4.21 (90), 2.76 (80), 1.831 (70), 7.25 (60), 2.58 (40), 1.561 (40). The pattern is very similar to that of tetrahedrite except for the strong lines at 7.25, 4.21, and 2.76.

Nevada

Disseminated pyrite in a latite porphyry at Texan Mountain, Hudspeth County, Texas

A pyrite-bearing latite porphyry that contains fragments of syenite and a quartz porphyry intruded into the Cretaceous Cox Sandstone are well exposed in a roadcut at Texan Mountain, Hudspeth County, Tex. The pyrite, which occurs along tiny fractures as well as disseminated, and the multiple episodes of intrusion, coupled with copper minerals in veins in the overlying Cox Sandstone, indicate a slight potential for porphyry-type copper or molybdenum deposits at depth.

Texas

Soda Creek springs - metamorphic waters in the eastern Alaska Range

The Soda Creek springs are a group of small, cold mineral springs on the southern flank of the eastern Alaska Range. The spring waters contain anomalous concentrations of carbon dioxide, sodium, chlorine, sulfate, boron, and ammonia and are actively precipitating deposits of calcite and aragonite. Sparingly present in these deposits are mixed-layer illite-montmorillonite clays and zeolite minerals. Low-temperature metamorphic reactions in subjacent marine sedimentary rocks of Jurassic and Cretaceous age may have produced the fluids and silicate minerals. With only a few exceptions, cool bicarbonate-rich springs in Alaska are concentrated south of the Denali fault system in south-central Alaska, southeastern Alaska, and along the Kaltag-Tintina fault system. These areas are characterized by active or recently active tectonism, major faults and folds, and an abundance of marine sedimentary rocks.

Alaska

A calorimetric determination of the standard enthalpies of formation of huntite, CaMg3 (CO3)4 , and artinite, Mg2(OH)2 CO3 * 3H2O, and their standard Gibbs free energies of formation

The enthalpies of formation, ΔH° f, of huntite, CaMg 3 (CO 3 ) 4 , and artinite, Mg 2 (OH) 2 CO 3 * 3H 2 O, have been determined by HCl solution calorimetry using a constant-volume isoperibol reaction calorimeter. For the reaction CaO(c) + 3MgO(c) + 4CO 2 (g) = CaMg 3 (CO 3 ) 4 (c), the enthalpy change at 298.15 K, ΔH° 298 , is -123,203±145 cal mol -1 . For the reaction 2MgO(c) + 4H 2 O(l) + CO 2 (g)=Mg 2 (OH) 2 CO 3 * 3H 2 O(c), we obtained -45,132±100 cal mol -1 . These results combined with the standard enthalpies of formation of CaO, MgO, H 2 O, and CO 2 lead to ΔH° 298 (huntite) = -1,082,600±375 cal mol -1 and ΔH° 298 (artinite) = -698,043±170 cal mol -1 . Using recently determined values for the standard entropies of huntite, CaMg 3 (CO 3 ) 4 , and artinite, Mg 2 (OH) 2 CO 3 * 3H 2 O, and of Mg, Ca, C, O 2 , and H 2 , we calculate ΔG° f,298 (huntite) = -1,004,707±390 cal mol -1 and ΔG° f,298 (artinite) = -613,924±180 cal mol -1 .

Journal of Research of the U.S. Geological Survey

The enthalpies of formation of nesquehonite, MgCO3 * 3H2O, and hydromagnesite, 5MgO * 4CO2 * 5H2O

The enthalpies of formation, ΔH° f , of nesquehonite, MgCO 3 * 3H 2 O, and hydromagnesite, 5MgO * 4CO 2 * 5H 2 O, have been determined by HCl solution calorimetry. For the reaction MgO(c) + CO 2 (g) + 3H 2 O(l) = MgCO 2 * 3H 2 O(c), the enthalpy change at 298.15 K is -29,781*40 cal mor' . For the reaction 5MgO(c) + 4CO 2 + 5H 2 O = 5MgO * 4CO 2 * 5H 2 O, the enthalpy change at 298.15 K is -120,310±120 cal. For MgCO 3 * 3H 2 O the standard molar enthalpy and standard Gibbs free energy of formation, ΔH° f,298 and ΔG° f,298 are -472,576+110 and 412,040±120 cal. ΔH° f,298 and ΔG° f,298 for 5MgO * 4CO 2 * 5H 2 O are -1,557,090±250 and -1,401,71 0±250 cal.

Journal of Research of the U.S. Geological Survey

Chemical analysis of rutile - a pyrocatechol violet spectrophotometric procedure for the direct microdetermination of zirconium

The ZrO 2 content of rutile is determined spectrophotometrically by a direct pyrocatechol violet procedure. The sample is decomposed by potassium pyrosulfate fusion in a transparent quartz crucible, and a sulfuric acid solution of the melt is used for the determination at a pH of 5.1. Of the elements commonly present in rutile, only titanium and niobium occur in concentrations large enough to interfere. Titanium and niobium interference is overcome by adding the titanium and niobium contents of the sample to the standard zirconium solutions used for the standard zirconium curve. The absorbance is measured at 570 nm. Beer's law is obeyed within the range of 0.05-1.50 ppm ZrO 2 . In the presence of 50 ppm TiO 2 , the range is 0.15-1.50 ppm ZrO 2 . The tolerances of 47 elements were determined. The sensitivity is 0.0058 ug Zr/cm 2 . The variables in the method were studied, and typical results are given for commercial rutile concentrates.

Journal of Research of the U.S. Geological Survey

Spectrophotometric determination of tungsten in rocks by an isotope dilution procedure

Samples are decomposed with hydrofluoric acid and perchloric acid in the presence of W 181 tracer. Molybdenum is extracted from a hydrochloric acid solution with tributyl phosphate. Tungsten is separated from most other elements by extraction of the a-benzoinoximate into chloroform. Stannous chloride in concentrated hydrochloric acid is used to strip tungsten and reduce it to W +5 . The amount of tungsten is determined spectrophotometrically after extraction as the thiocyanate complex into amyl alcohol. The correction for chemical losses is determined by counting W 181 .

Journal of Research of the U.S. Geological Survey

Spectrochemical computer analysis - argon-oxygen d-c arc method for silicate rocks

Use of an argon-oxygen atmosphere eliminates the interference of cyanogen bands with many sensitive analytical lines. The jet-controlled atmosphere also improves the stability of the arc. These procedural changes, coupled with computerized analysis of the spectra, result in increased detectability, precision, and speed as compared to the former visual semiquantitative technique.

Journal of Research of the U.S. Geological Survey

Bathymetry of the continental margin off Liberia, West Africa

A bathymetric map based on new data allows examination of geomorphic features on the narrow continental margin off Liberia. The continental shelf in this region is relatively flat and featureless. The northwestern part of the continental slope, off Monrovia and Cape Mount, shows complex slump features and two submarine valleys. The central part of the slope is smoother, apparently as a result of progradation. The southeastern part of the slope, near Cape Palmas, is crossed oblique to the shoreline by a structural valley that has been modified by large slumps or landslides. This valley may be the termination, at the continental margin, of an oceanic fracture zone. The major slumplike features of the Liberian continental margin appear to be surface manifestations of deep faulting which has been partially masked by sedimentation.

Journal of Research of the U.S. Geological Survey

Ice ages and the thermal equilibrium of the earth

A model for climatic change, and particularly for the changes of the late Cenozoic, involves as its primary variables the albedo of the earth and the heat storage characteristics of the oceans. Geography exerts a strong influence. The model proposed does not require metaphysical causes or astronomical events other than known variations in the earth's orbit.

Journal of Research of the U.S. Geological Survey

Aquifer diffusivity of the Ohio River alluvial aquifer by the flood-wave response method

Aquifer diffusivity (T/S) was calculated for 10 sites in the alluvial aquifer adjacent to the Ohio River by observing the response of the aquifer to a flood wave in the river. The calculated type curves matched the observed aquifer response reasonably well at eight of the 10 sites. The diffusivities ranged from 0.4 ft 2 sec -1 to 10.3 ft 2 sec -1 and were generally in agreement with diffusivity values calculated from pump-test methods at two of the sites. Interference from pumping 1/2 mile upstream from one site and localized aquifer inhomogeneity at another site precluded calculation of diffusivity. Determining the shape of the ground-water recession curve may be difficult, but it can be done satisfactorily by collecting water-level data during an extended period of ground-water discharge and transposing the average recession curve to the flood period being analyzed. The flood-wave response method for estimating aquifer diffusivity provides a relatively inexpensive technique for obtaining a significant part of the data needed to predict the aquifer's response to river and pumping stresses.

Ohio River

A study of the distribution of the polychlorinated biphenyls in the aquatic environment

Data gathered from monitoring activities and project studies indicate the ubiquitous occurrence and distribution of polychlorinated biphenyls in the aquatic environment. Residues have been detected in samples from 19 States, representing nearly every region of the country. Concentrations ranged from 0.1 to 4.0 ug/l in unfiltered water samples and 5.0 to 3,200 ug/kg in bottom sediments. PCB residues were also found in fish and aquatic plants. Samples were prepared by the same techniques used for general chlorinated insecticide detection, with special attention to cleanup and separation of PCB's from other compounds. Basic identification and quantification were made by dual-column electron-capture gas chromatography and confirmed by gas chromatography mass spectrometry whenever possible. The sampling program is expected to be broadened geographically in 1973 and increased in successive years in order to more adequately define the distribution of PCB residues in the major drainage basins of the United States.

Journal of Research of the U.S. Geological Survey

Remote sensing of turbidity plumes in Lake Ontario

High-altitude photography provides an effective method of monitoring the spatial extent of turbidity plumes in Lake Ontario. Large plumes generated by the Niagara, Genesee, and Oswego Rivers are identifiable on photographs obtained from about 60,000 feet above the lake on July 6, 1970, October 19, 1970, and May 29, 1971. The Niagara plume, covering as much as 43 sq mi of the lake's surface, is the largest turbidity feature. The configuration of the plumes is a function of river discharge, level of turbidity, and wind speed and direction.

Journal of Research of the U.S. Geological Survey