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At least 199 records · Page 11Linked to original sources

Machine learning classifiers for attributing tephra to source volcanoes: An evaluation of methods for Alaska tephras

Glass composition-based correlations of volcanic ash (tephra) traditionally rely on extensive manual plotting. Many previous statistical methods for testing correlations are limited by using geochemical means, masking diagnostic variability. We suggest that machine learning classifiers can expedite correlation, quickly narrowing the list of likely candidates using well-trained models. Eruptives from Alaska's Aleutian Arc-Alaska Peninsula and Wrangell volcanic field were used as a test environment for 11 supervised classification algorithms, trained on nearly 2000 electron probe microanalysis measurements of glass major oxides, representing 10 volcanic sources. Artificial neural networks and random forests were consistently among the top-performing learners (accuracy and kappa > 0.96). Their combination as an average ensemble effectively improves their performance. Using this combined model on tephras from Eklutna Lake, south-central Alaska, showed that predictions match traditional methods and can speed correlation. Although classifiers are useful tools, they should aid expert analysis, not replace it. The Eklutna Lake tephras are mostly from Redoubt Volcano. Besides tephras from known Holocene-active sources, Holocene tephra geochemically consistent with Pleistocene Emmons Lake Volcanic Center (Dawson tephra), but from a yet unknown source, is evident. These tephras are mostly anchored by a highly resolved varved chronology and represent new important regional stratigraphic markers.

Journal of Quaternary Science

Geochemistry and fluxes of gases from hydrothermal features at Newberry Volcano, Oregon, USA

We present the chemical and isotopic compositions of gases and fluxes of CO 2 from the hydrothermal features of Newberry Volcano, a large composite volcano located in Oregon's Cascade Range with a summit caldera that hosts two lakes, Paulina and East Lakes. Gas samples were collected from 1982 to 2021 from Paulina Hot Springs (PHS) on the shore of Paulina Lake, East Lake Hot Springs (ELHS) on the shore of East Lake, and Obsidian Flow Gas Seep (OFGS), an area of diffuse gas emissions. Surveys of CO 2 flux were conducted in 2020 at OFGS (1400 m 2 ) and East Lake (4.1 km 2 ). Gases from all three sites were CO 2 -rich (≥79 mol% in dry gas) but showed considerable compositional variability over time due to interaction with ground and surface water. An increase in H 2 S concentrations and decline in CO 2 /H 2 S ratios in ELHS gases coincided with a drop in East Lake water level from 1999 to 2021. ELHS and OFGS gases were high in CH 4 relative to PHS and the δ 13 C of CH 4 values for ELHS gases (−72.2 and − 63.6 ‰) reflected a predominantly biogenic origin. The dominant source of N 2 and Ar in PHS, ELHS, and OFGS samples was likely groundwater. Helium isotopic ratios (6.47 to 8.02 R c /R a ) support a persistent source of magmatic He beneath Newberry caldera and consistently high values measured at OFGS and PHS relative to ELHS suggest distinct fluid flow paths from depth to the surface features. The δ 13 C of CO 2 and CO 2 / 3 He values (−8.9 to −5.35 ‰ and 1.3 × 10 9 to 4.6 × 10 10 , respectively) measured in gases reflect contributions of CO 2 from both mantle and crustal sources. Measured CO 2 fluxes at OFGS and East Lake ranged from 1 to 8808 and < 1 to 364 g m −2 d −1 , respectively. A CO 2 emission rate of 0.5 t d −1 was calculated for OFGS. The CO 2 emission rate estimated for East Lake was 30 t d −1 and when compared to prior estimates, reflects steady-state lake degassing. An enhanced geochemical monitoring plan, including annual sampling of gases at ELHS, OFGS, and PHS for geochemical analysis, installation of a continuous lake-level monitoring station at East Lake, and annual CO 2 flux surveys at OFGS, would provide valuable background data and insights into any precursor volcanic activity. Integrating geochemical data with data from the real-time seismic and GPS network at Newberry Volcano could better resolve and interpret potential changes in its magma-hydrothermal system.

Oregon

U-Th-Pb systematics of some granitoids from the northeastern Yilgarn Block, Western Australia and implications for uranium source rock potential

The Mount Boreas‐type granite and spatially associated syenitic granitoid of Western Australia yield Pb‐Pb ages of 2370 ± 100 Ma and 2760 ± 210 Ma, respectively. Th‐Pb ages, although less precise, are concordant with these ages, and therefore the apparent ages are interpreted to be the crystallisation ages for these two units. U‐Pb ages are variable and for the most part anomalously old, which suggests a Cainozoic uranium loss. However, this loss is generally small (< 3 μ g/g); therefore, neither granitoid in its fresh state provides a good source for nearby calcrete‐hosted uranium deposits. The possibility remains that the Mount Boreas‐type granite that has been completely weathered during the Tertiary could have been a source for the calcrete‐type uranium deposits in W.A. Although the Mount Boreas‐type granite is highly fractionated, it does not bear a strong geochemical imprint of a sedimentary precursor. This feature contrasts it with apparently fresh granitoids from other parts of the world that have lost large amounts of uranium (∼ 20 μ g/g ) and are associated with large roll‐type and other low temperature‐type uranium deposits.

Journal of the Geological Society of Australia

Forecasts and predictions of eruptive activity at Mount St. Helens, USA: 1975-1984

Public statements about volcanic activity at Mount St. Helens include factual statements, forecasts, and predictions. A factual statement describes current conditions but does not anticipate future events. A forecast is a comparatively imprecise statement of the time, place, and nature of expected activity. A prediction is a comparatively precise statement of the time, place, and ideally, the nature and size of impending activity. A prediction usually covers a shorter time period than a forecast and is generally based dominantly on interpretations and measurements of ongoing processes and secondarily on a projection of past history. The three types of statements grade from one to another, and distinctions are sometimes arbitrary. Forecasts and predictions at Mount St. Helens became increasingly precise from 1975 to 1982. Stratigraphic studies led to a long-range forecast in 1975 of renewed eruptive activity at Mount St. Helens, possibly before the end of the century. On the basis of seismic, geodetic and geologic data, general forecasts for a landslide and eruption were issued in April 1980, before the catastrophic blast and landslide on 18 May 1980. All extrusions except two from June 1980 to the end of 1984 were predicted on the basis of integrated geophysical, geochemical, and geologic monitoring. The two extrusions that were not predicted were preceded by explosions that removed a substantial part of the dome, reducing confining pressure and essentially short-circuiting the normal precursors.

Journal of Geodynamics

Understanding organic matter heterogeneity and maturation rate by Raman spectroscopy

Solid organic matter (OM) in sedimentary rocks produces petroleum and solid bitumen when it undergoes thermal maturation. The solid OM is a ‘geomacromolecule’, usually representing a mixture of various organisms with distinct biogenic origins, and can have high heterogeneity in composition. Programmed pyrolysis is a common method to reveal bulk geochemical characteristics of the dominant OM, while detailed organic petrography is required to reveal information about the biogenic origin of contributing macerals. Despite the advantages of programmed pyrolysis, it cannot provide information about the heterogeneity of chemical compositions present in the individual OM types. Therefore, other analytical techniques such as Raman spectroscopy are necessary. In this study, we compared geochemical characteristics and Raman spectra of two sets of naturally and artificially matured Bakken source rock samples. A continuous Raman spectral map on solid bitumen particles was created from the artificially matured hydrous pyrolysis residues, in particular, to show the systematic chemical modifications in microscale. Spectroscopic data was plotted for both sets against thermal maturity to compare maturation rate/path for these two separate groups. The outcome showed that artificial maturation through hydrous pyrolysis does not follow the same trend as naturally-matured samples although having similar solid bitumen reflectance values (%SBRo). Furthermore, Raman spectroscopy of solid bitumen from artificially matured samples indicated the heterogeneity of OM decreases as maturity increases. This may represent an alteration in chemical structure towards more uniform compounds at higher maturity. This study may emphasize the necessity of using analytical methods such as Raman spectroscopy along with conventional geochemical methods to better reveal the underlying chemical structure of OM. Finally, observation by Raman spectroscopy of chemical alteration of OM during artificial maturation may assist in the proposal of improved pyrolysis protocols to better resemble natural geologic processes.

North Dakota

An improved ion-selective electrode method for the rapid determination of fluorine in rocks and soil

An improved method based on an ion-selective electrode technique for the analysis of fluorine in rocks and soils is presented. Analyses are made by using a sodium carbonate-potassium carbonate fusion and a citric acid dissolution of the fuseate. Prior to determining the fluorine concentration by a standard-addition procedure, sodium citrate buffer is added to the solution. The proposed method yields fluorine values in agreement with known values for standard rocks. Values of this method are also presented for six geochemical exploration rock-and-soil reference samples and compared to those from other ion-selective electrode techniques. Fifty samples can be analyzed in 1 person-day. The sensitivity of the method is 100 parts per million, and samples containing up to 45 percent fluorine have been successfully analyzed.

Journal of Research of the U.S. Geological Survey

Understanding melt evolution and eruption dynamics of the 1666 C.E. eruption of Cinder Cone, Lassen Volcanic National Park, California: Insights from olivine-hosted melt inclusions

Cinder Cone is the youngest scoria cone volcano in the continental United States. Erupted in 1666 C.E. within what is now Lassen Volcanic National Park, Cinder Cone is an un-vegetated scoria cone with well-preserved lava flows and tephra deposits that display complex geochemical variability. In this study, we utilize the volatile (H 2 O, CO 2, Cl), major, and trace element chemistry of olivine-hosted melt inclusions from the tephra deposit of Cinder Cone to better understand the sub-surface evolution of magmas that erupt to produce scoria cones. High-Fo olivine phenocrysts from all erupted units contain melt inclusions that are more primitive in composition than the erupted material. The evolved compositions of the lava and bulk tephra and the abundance of quartz xenocrysts within the deposits suggest the basaltic parental magmas were rapidly contaminated by granitic material in the middle to upper crust, after melt inclusion entrapment. Distinct compositional variability between early and late erupted units suggests two different mantle-derived basaltic magmas were tapped and erupted sequentially as two distinct eruptive phases. The CO 2 concentrations in the melt inclusions, after correction for the presence of vapor bubbles, suggest minimum entrapment depths of ~9.5–20 km and show no resolvable differences between early and late erupted units at the time of olivine crystallization. Diffusion modeling of Ni and Fo gradients in olivine rims indicates that olivine residence times in an evolving magma were on the order of weeks to years, similar to those calculated for longer-lived scoria cone eruptions, such as Jorullo, in Mexico. Additionally, geochemical evidence suggests that the evolution of parental magmas was likely driven by the partial melting, disaggregation, and assimilation of granitic material in the upper crust. Our combined results provide new insight into the complexities of short-lived monogenetic eruptions.

California

Cokriging of compositional balances including a dimension reduction and retrieval of original units

Compositional data constitutes a special class of quantitative measurements involving parts of a whole. The sample space has an algebraic-geometric structure different from that of real-valued data. A subcomposition is a subset of all possible parts. When compositional data values include geographical locations, they are also regionalized variables. In the Earth sciences, geochemical analyses are a common form of regionalized compositional data. Ordinarily, there are measurements only at data locations. Geostatistics has proven to be the standard for spatial estimation of regionalized variables but, in general, the compositional character of the geochemical data has been ignored. This paper presents in detail an application of cokriging for the modelling of compositional data using a method that is consistent with the compositional character of the data. The uncertainty is evaluated by a Monte Carlo procedure. The method is illustrated for the contents of arsenic and iron in groundwaters in Bangladesh, which have the peculiarity of being measured in milligrams per litre, units for which the sum of all parts does not add to a constant. Practical results include maps of estimates of the geochemical elements in the original concentration units, as well as measures of uncertainty, such as the probability that the concentration may exceed a given threshold. Results indicate that probabilities of exceedance in previous studies of the same data are too low.

Journal of the Southern African Institute of Minin

Phase separation in seafloor geothermal systems: An experimental study of the effects on metal transport

Experimental investigations were carried out by reacting natural and evolved sea-water with crystalline basalt from the Juan de Fuca Ridge in order to study the effects of vapour-liquid phase separation on metal mobilization in sea-floor geothermal systems in which phase separation occurs between the top of a magma chamber (300-500 bar) and the sea-floor (230-250 bar). The geochemical processes produced by a combination of closed-system phase separation and adiabatic expansion under the conditions characterizing the sea-floor geothermal systems resulted in a significant increase in the acidity and concentration of heavy metals in the liquid phase and strikingly high concentrations of metals in the vapour.

American Journal of Science

Possible extension of mineral belts, northern part of Coeur d'Alene district, Idaho

The ore deposits in the northern part of the Coeur d'Alene district are located within rocks of the Belt Supergroup that have been intruded by Cretaceous quartz monzonites. Lead-zinc-silver replacement veins constitute most of the deposits. The geometry of the district has been modified by post-ore faulting along the Osburn, Dobson Pass, and other faults. The original position of the Gem stocks, before their separation from the Diego Peak stocks by the Dobson Pass fault, can be approximately reconstructed by moving the truncated stocks and associated geochemical dispersion patterns back into matching positions. The known mineral belts are defined by dispersion patterns of both lead and the Pb:Zn ratio. Similar dispersion patterns of lead and the Pb:Zn ration northwest of the original position of the Gem stocks suggest that the mineral belts extend into that area.

Idaho

Broadening the perspectives of sedimentary organic matter analysis to understand Earth system response to change

This paper broadens the description of sedimentary organic matter from the conventional use of coal petrography to include palynological and geochemical sedimentary organic matter. Palynological sedimentary organic matter includes all chemically resistant organic microfossils, such as pollen and spores, dinocysts, microforaminifera (chitinoid-like linings of foraminifera), microscopic algae, charcoal, palynodebris, acritarchs, chitinozoans, and scolecodonts. Geochemical sedimentary organic matter includes organic biomarkers, lipids, and photosynthetic pigments. We provide examples of the use of palynological and geochemical analysis of sedimentary organic matter to understand patterns and impacts of changing climate, fire regimes, hydrologic extremes, water quality, and land change on terrestrial and marine systems through geologic time to provide a long-term perspective to evaluate anthropogenic impacts on the Earth as well as to support forensics investigations.

International Journal of Coal Geology

Heterogeneity in hyporheic flow, pore water chemistry, and microbial community composition in an alpine streambed

The hyporheic zone, where surface water and groundwater mix, is an important microbial habitat where biogeochemical reactions influence water quality. We show that spatial variability in hyporheic flow in the East River near Crested Butte, Colorado, drives heterogeneity in streambed geochemical conditions and microbial community assemblages, but the diversity of assemblages remains nearly constant throughout the reach. In July 2018, we collected approximately 100 pore water samples at 20 cm depth and analyzed them for anions, cations, dissolved organic carbon, dissolved organic matter (DOM) quality, and basic water quality parameters. Vertical hydraulic head gradients were also measured to assess the potential for upward or downward flow, and heat tracing was used to quantify vertical flux rates at a subset of locations. We found that regions of the streambed that are more groundwater-dominated contain less dissolved oxygen, higher concentrations of reduced metals, and more microbially-processed, recalcitrant DOM, while more surface water-dominated locations contain higher dissolved oxygen concentrations and terrestrially-derived, labile DOM. 16S rRNA gene sequencing of extracted DNA revealed that microbial community composition varies with geochemical gradients related to hyporheic flow. These findings provide a better understanding of hyporheic controls on streambed biogeochemistry during the baseflow season, which is expected to lengthen with climate change in alpine watersheds due to earlier snowmelt onset and reduced snowpack.

Colorado

Remarkable isotopic and trace element trends in potassic through sodic Cretaceous plutons of the Yukon-Koyukuk Basin, Alaska, and the nature of the lithosphere beneath the Koyukuk terrane

During the period from 110 to 80 m.y. ago, a 450-km-long magmatic belt was active along the northern margin of Yukon-Koyukuk basin and on eastern Seward Peninsula. The plutons intruded Upper Jurassic(?) and Lower Cretaceous volcanic arc rocks and Cretaceous sedimentary rocks in Yukon-Koyukuk basin and Proterozoic and lower Paleozoic continental rocks in Seward Peninsula. Within Yukon-Koyukuk basin, the plutons vary in composition from calc-alkalic plutons on the east to potassic and ultrapotassic alkalic plutons on the west. Plutons within Yukon-Koyukuk basin were analyzed for trace element and isotopic compositions in order to discern their origin and the nature of the underling lithosphere. Farthest to the east, the calc-alkalic rocks of Indian Mountain pluton are largely tonalite and sodic granodiorite, and have low Rb (average 82 ppm), high Sr (>600 ppm), high chondrite-normalized (cn) Ce/Yb (16&ndash;37), low &delta; 18 O (+6.5 to +7.1), low initial 87 Sr/ 86 Sr (SIR) (0.704), and high initial 143 Nd/ 144 Nd (NIR) (0.5126). These rocks resemble those modelled elsewhere as partial melts and subsequent fractionates of basaltic or gabbroic metaigneous rocks, and may be products of melting in the deeper parts of the Late Jurassic(?) and Early Cretaceous volcanic arc. Farthest to the west, the two ultrapotassic bodies of Selawik and Inland Lake are high in Cs (up to 93 ppm), Rb (up to 997 ppm), Sr, Ba, Th, and light rare earth elements, have high (Ce/Yb)cn (30, 27), moderate to low &delta; 18 O (+8.4, +6.9), high SIR (0.712, 0.710), and moderate NIR (0.5121&ndash;0.5122). These rocks resemble rocks of Australia and elsewhere that were modelled as melts of continental mantle that had been previously enriched in large cations. This mantle may be Paleozoic or older. The farthest west alkalic pluton of Selawik Hills is largely monzonite, quartz monzonite, and granite; has moderate Rb (average 284 ppm), high Sr (>600 ppm), high (Ce/Yb)cn (15&ndash;25), moderate &delta; 18 O (+8.3 to +8.6), high SIR (0.708&ndash;0.712), and moderate NIR (0.5121&ndash;0.5122). These rocks may be the product of interaction of magma derived from old continental mantle and magma derived from old continental crust. Plutons between eastern and western extremes show completely gradational variations in the concentration of K and Rb and in the isotopic compositions of Sr, Nd, and O. These plutons probably originated either by melting in a mixed source composed of a Paleozoic or older continental section (mantle + crust) overlain by Mesozoic mafic arc rocks, or by mixing of ultrapotassic to potassic magmas from continental sources (mantle + crust), and tonalitic magmas from arc sources. We infer from these results that the northwest portion of Yukon-Koyukuk basin is underlain by a substantial continental basement of Paleozoic or greater age. This basement probably thins out to the east. There is no geochemical evidence for continental basement east of about longitude 157&deg;, or along a belt of at least 50 km width flanking Ruby Geanticline as far to the southwest as about longitude 161&deg;. These areas are probably underlain by oceanic and Mesozoic arc rocks.

Alaska

Microbial endophytes and compost improve plant growth in two contrasting types of hard rock mining waste

The re-vegetation of mining wastes with native plants is a comparatively low-cost solution for mine reclamation. However, re-vegetation fails when extreme pH values, low organic matter, or high concentrations of phytotoxic elements inhibit plant establishment and growth. Our aim was to determine whether the combined addition of municipal waste compost and diazotrophic endophytes (i.e., microorganisms that fix atmospheric N 2 and live within plants) could improve plant growth, organic matter accumulation, and phytostabilization of trace element contaminants in two types of hard rock mine waste. We grew a widespread native perennial grass, Bouteloua curtipendula , for one month in alkaline waste rock (porphyry copper mine) and tailings (Ag-Pb-Au mine, amended with dolomite) sourced from southeastern Arizona, United States. B. curtipendula tolerated elevated concentrations of multiple phytotoxic trace elements in the tailings (Mn, Pb, Zn), stabilizing them in roots without foliar translocation. Adding compost and endophyte seed coats improved plant growth, microbial biomass, and organic matter accumulation despite stark differences in the geochemical and physical characteristics of the mining wastes. The widespread grass B. curtipendula is a potential candidate for re-vegetating mine wastes when seeded with soil additives to increase pH and with microbial and organic amendments to increase plant growth.

International Journal of Phytoremediation

Inverse geochemical modeling of groundwater evolution with emphasis on arsenic in the Mississippi River Valley alluvial aquifer, Arkansas (USA)

Inverse geochemical modeling (PHREEQC) was used to identify the evolution of groundwater with emphasis on arsenic (As) release under reducing conditions in the shallow (25-30 m) Mississippi River Valley Alluvial aquifer, Arkansas, USA. The modeling was based on flow paths defined by high-precision (??2 cm) water level contour map; X-ray diffraction (XRD), scanning electron microscopic (SEM), and chemical analysis of boring-sediments for minerals; and detailed chemical analysis of groundwater along the flow paths. Potential phases were constrained using general trends in chemical analyses data of groundwater and sediments, and saturation indices data (MINTEQA2) of minerals in groundwater. Modeling results show that calcite, halite, fluorite, Fe oxyhydroxide, organic matter, H2S (gas) were dissolving with mole transfers of 1.40E - 03, 2.13E - 04, 4.15E - 06, 1.25E + 01, 3.11, and 9.34, respectively along the dominant flow line. Along the same flow line, FeS, siderite, and vivianite were precipitating with mole transfers of 9.34, 3.11, and 2.64E - 07, respectively. Cation exchange reactions of Ca2+ (4.93E - 04 mol) for Na+ (2.51E - 04 mol) on exchange sites occurred along the dominant flow line. Gypsum dissolution reactions were dominant over calcite dissolution in some of the flow lines due to the common ion effect. The concentration of As in groundwater ranged from <0.5 to 77 ??g/L. Twenty percent total As was complexed with Fe and Mn oxyhydroxides. The redox environment, chemical data of sediments and groundwater, and the results of inverse geochemical modeling indicate that reductive dissolution of Fe oxyhydroxide is the dominant process of As release in the groundwater. The relative rate of reduction of Fe oxyhydroxide over SO42 - with co-precipitation of As into sulfide is the limiting factor controlling dissolved As in groundwater. ?? 2007 Elsevier B.V. All rights reserved.

Journal of Hydrology

Chemical analyses of pore water from boreholes USW SD-6 and USW WT-24, Yucca Mountain, Nevada

Analyses of pore water extracted from cores of boreholes USW SD-6 in the central part and USW WT-24 in the northern part of Yucca Mountain, Nevada, show significant vertical and lateral variations in dissolved-ion concentrations. Analyses of samples of only a few milliliters of pore water extracted by uniaxial or triaxial compression and by ultracentrifugation methods from adjacent core samples are generally in agreement, within the analytical error of 10% to 15%. However, the values of silica for water obtained by ultracentrifugation are consistently lower than values for water obtained by compression. The larger concentrations probably are due to localized pressure solution of silicate minerals during compression. The shallower water from core in borehole USW SD-6 was extracted from nonwelded units collectively referred to as the Paintbrush Tuff nonwelded (PTn). The deeper water was from core in both boreholes USW SD-6 and USW WT-24 in the nonwelded units referred to as the Calico Hills nonwelded (CHn). Significant differences in mean dissolved-ion concentrations in pore water between the PTn and CHn are (1) decreases in Ca, Mg, SO4, and NO3 and (2) increases in HCO3 and (Na+K)/(Ca+Mg) ratios. The decrease in NO3 and the increase in HCO3 could be the result of denitrification through the oxidation of organic matter. The decrease in Ca and associated increase in (Na+K)/(Ca+Mg) is the result of ion exchange with zeolites in the CHn in borehole USW WT-24. This effect is not nearly as pronounced in borehole USW SD-6, probably reflecting a smaller amount of zeolitization of the CHn in USW SD-6. Geochemical calculations using the PHREEQC code indicate that the pore water from both boreholes USW SD-6 and USW WT-24 is uniformly undersaturated in anhydrite, gypsum, and amorphous silica, but supersaturated in quartz and chalcedony. The saturation of calcite, aragonite, sepiolite, and dolomite is more variable from sample to sample. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology

Complex resistivity signatures of ethanol biodegradation in porous media

Numerous adverse effects are associated with the accidental release of ethanol (EtOH) and its persistence in the subsurface. Geophysical techniques may permit non-invasive, real time monitoring of microbial degradation of hydrocarbon. We performed complex resistivity (CR) measurements in conjunction with geochemical data analysis on three microbial-stimulated and two control columns to investigate changes in electrical properties during EtOH biodegradation processes in porous media. A Debye Decomposition approach was applied to determine the chargeability ( m ), normalized chargeability ( m n ) and time constant ( &tau; ) of the polarization magnitude and relaxation length scale as a function of time. The CR responses showed a clear distinction between the bioaugmented and control columns in terms of real ( &sigma;&prime; ) and imaginary ( &sigma;&Prime; ) conductivity, phase ( ϕ ) and apparent formation factor ( F app ). Unlike the control columns, a substantial decrease in &sigma;&prime; and increase in F app occurred at an early time (within 4 days) of the experiment for all three bioaugmented columns. The observed decrease in &sigma;&prime; is opposite to previous studies on hydrocarbon biodegradation. These columns also exhibited increases in ϕ (up to ~ 9 mrad) and &sigma;&Prime; (up to two order of magnitude higher) 5 weeks after microbial inoculation. Variations in m and m n were consistent with temporal changes in ϕ and &sigma;&Prime; responses, respectively. Temporal geochemical changes and high resolution scanning electron microscopy imaging corroborated the CR findings, thus indicating the sensitivity of CR measurements to EtOH biodegradation processes. Our results offer insight into the potential application of CR measurements for long-term monitoring of biogeochemical and mineralogical changes during intrinsic and induced EtOH biodegradation in the subsurface.

Journal of Contaminant Hydrology

Zircon geochronology and geochemistry of Quaternary rhyolite domes of the Coso volcanic field, Inyo County, California

The Quaternary Coso volcanic field (CVF) is a compositionally bimodal volcanic field located within a releasing bend along the eastern range-front Sierra Nevada fault zone in California's southern Owens Valley. The erupted products of CVF silicic magmatism since ~1 Ma comprise 38 high-silica rhyolite domes, with the volumetric majority (~99%) of rhyolite emplaced within the past ~300 ka. The CVF hosts an economically important geothermal field driven by heat associated with a shallow (~5 km) igneous intrusion. The CVF is potentially an immature analog to the nearby Long Valley system, which culminated in generation and eruption of the voluminous and widespread Bishop Tuff. As such, the CVF represents a considerable volcanic hazard, making a detailed understanding of the eruptive history and pre-eruptive conditions of the system critically important. We present uranium-series isochron dates from zircon ± allanite crystal surfaces and zircon trace element geochemical data on the youngest 17 rhyolite domes at Coso, which represent ~60% (by volume) of the silicic magma erupted by the system. These data suggest: (1) a shorter emplacement duration than previously recognized for these domes, with a duration of 20 ± 5 ka; (2) 4 shorter-duration eruption pulses within this interval, all of which occur during the marine isotope stage (MIS) 5 interglacial period; (3) an uptick in the volume of CVF magma erupted between ~200 ka and ~ 78 ka relative to that emplaced over the lifetime of the system; (4) near-coeval eruption of geochemically distinct magma in close geographic proximity, either sourced from different portions of the same magma system at depth or from discrete, uncommunicating bodies; (5) ambiguity with respect to whether or not CVF magmatism is time-predictable, as previously suggested, or erupted as a series of punctuated episodes; (6) no rhyolite volcanism in the past ~78 kyr.

California