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At least 199 records · Page 11Linked to original sources

Field tests of polyethylene-membrane diffusion samplers for characterizing volatile organic compounds in stream-bottom sediments, Nyanza Chemical Waste Dump Superfund site, Ashland, Massachusetts

A plume of volatile organic compounds (VOCs) in ground water extends from the Nyanza Chemical Waste Dump Superfund site in Ashland, Massachusetts, northward toward a mill pond on the Sudbury River and eastward toward the Sudbury River and former mill raceway downstream from the mill pond. Polyethylene-membrane water-to-vapor (vapor) and water-to-water (water) diffusion samplers were installed January 1999 in bottom sediments along the Sudbury River and former mill raceway in a pilot study to determine if vapor samplers would be useful in this setting for delineating a plume of contaminants in ground water near the river and raceway, to evaluate equilibration time for vapor-diffusion samplers, and to determine if diffusion samplers might be an alternative to seepage meters (inverted steel drums) and sediment sampling for evaluating concentrations of VOCs in bottom sediments. Of five tested compounds (benzene, trichloroethene, toluene, tetrachloroethene, and chlorobenzene), chlorobenzene and trichloroethene were most frequently detected in vapor from vapor-diffusion samplers. The distribution of VOCs was generally consistent with a previously mapped plume of contaminants in ground water. The field evaluation of equilibration times for vapor-diffusion samplers was inconclusive because of changing hydrologic conditions that may have affected concentrations of VOCs, possible variations in concentrations ofVOCs over short distances, and imprecise sampling and analytical methods. The limited data, however, indicated that equilibration may require 3 weeks or more in some settings. VOCs detected in samples from water-diffusion samplers and their concentrations were comparable to results from seepage meters, and VOCs detected in vapor-diffusion samplers correlated with VOCs detected in water-diffusion samplers. These results indicate that either vapor-or water-diffusion samplers would serve as an economical alternative to seepage meters for sampling of VOCs in pore water from stream-bottom sediments. Results from diffusion samplers correlated poorly with results from sediment samples, partly because of high quantitation limits for chemical analyses of sediments. In general, results from the diffusion samplers better represented the distribution of VOCs than the results from the sediment samples. This pilot study indicates that diffusion samplers are an economical means of identifying 'hotspots' for contaminants in bottom sediments and can provide insights on transport pathways for contaminants near surface-water bodies. After establishing equilibration times for a particular site, diffusion samplers also may be useful for studying variations in concentrations of VOCs over short distances, variations with time and changing hydrologic conditions, and processes such as chemical transformations by biodegradation and exchanges between surface water and ground water in the hyporheic zone.

Water-Resources Investigations Report

Tracking phosphorus and sediment sources and transport from fields and channels in Great Lakes Restoration Initiative priority watersheds

A multi-agency, integrated series of studies were initiated in 2017 under the Great Lakes Restoration Initiative (GLRI) by the U.S. Geological Survey, U.S. Forest Service, and the University of Minnesota to quantify the source, downstream travel time, and storage of particulate-bound phosphorus and sediment in agricultural tributaries to the Great Lakes. Of particular interest are contributions at the edge of field, channels, and riparian corridors. Results will be used to help identify upland and stream conservation practices that may reduce phosphorus and sediment inputs to the Great Lakes. The two study watersheds are the 50 km2 Black Creek in the Maumee River basin (Lake Erie) and the 90 km2 Plum Creek in the Lower Fox River basin (Lake Michigan). As part of other GLRI work, Black Creek and Plum Creek have existing, nested, edge-of-field studies in addition to phosphorus and sediment monitoring stations along their mainstems. Sediment-source tracking provides a direct method to quantify suspended sediment, and consequently phosphorus, sources by identifying a minimal set of properties (or fingerprint) that uniquely defines each source of sediment in the basin. This fingerprint can then be used to apportion sources of sediment from agricultural fields as well as other uplands including developed areas, forests, and pastures. These methods can also help distinguish sediment from ditches, ravines and eroding slopes, and streambanks. Multiple tracking methods are being used and adapted for best results in these watersheds, including a suite of trace elements for overall source apportionment in addition to short-term fallout radionuclides beryllium-7 (7Be) and lead-210 (210Pb) for high-flow event-based transport on fields and in stream channels. Tile drain connectivity to the surface is also of interest, especially in the Black Creek watershed. Preliminary results from the overall source apportionment from analyses of streambed sediment and monthly suspended sediment in Plum Creek indicate that the proportion attributed to different land cover varied by season and events. Further data analyses are being conducted for examining event-based pathways on individual fields, while most basin-wide sampling was monthly. Results from both watersheds will help describe the variations in transport of particulate-bound phosphorus across both steep and gentle landscapes representative of the Great Lakes basin. (this is from IP-101450)

Great Lakes

Tributary stream infiltration as a source of herbicides in an alluvial aquifer

Where Walnut Creek flows across the South Skunk River alluvial aquifer, it provides a potential source of herbicides and herbicide metabolites. This straightened reach of the creek loses water and dissolved contaminants to the alluvial aquifer through a layer of fine-grained flood plain deposits. Estimates of potential flux of chemicals were based on measurements taken during baseflow in April 1994 before herbicides were applied to the watershed and in June 1994 after chemical application and when stream discharge included runoff and tile-drainage water. Hydraulic head measurements between the creek and flood plain deposits and between the creek and aquifer confirmed the potential for downward groundwater flow during both sampling periods. Hydraulic conductivity estimates from slug tests were used to calculate an average linear groundwater velocity of 0.5 m d −1 in the fine-grained flood plain deposits. At this velocity, contaminants could be advectively transported to the aquifer within 6 d. The potential for atrazine (2-chloro-4-ethylamino-6-isopropylamino- s -triazine) flux to the aquifer from the creek was estimated to be between 60 and 3000 µg d −1 m −2 . This rate is one to three orders of magnitude greater than the estimated flux via leaching beneath a typical field. If the process of vertical stream leakage occurs in many hydrologic settings, it may constitute a substantial source of herbicides to shallow alluvial aquifers in many areas of the Midwest.

Iowa

Lidar-based approaches for estimating solar insolation in heavily forested streams

Methods to quantify solar insolation in riparian landscapes are needed due to the importance of stream temperature to aquatic biota. We have tested three lidar predictors using two approaches developed for other applications of estimating solar insolation from airborne lidar using field data collected in a heavily forested narrow stream in western Oregon, USA. We show that a raster methodology based on the light penetration index (LPI) and a synthetic hemispherical photograph approach both accurately predict solar insolation, explaining more than 73 % of the variability observed in pyranometers placed in the stream channel. We apply the LPI-based model to predict solar insolation for an entire riparian system and demonstrate that no field-based calibration is necessary to produce an unbiased prediction of solar insolation using airborne lidar alone.

Oregon

Connecting flood-related fluvial erosion and deposition with vulnerable downstream road-stream crossings

Fluvial erosion is increasingly responsible for infrastructure and building damages associated with floods as the intensity of extreme rainfalls hit rural and urban rivers in a variety of climate settings across the United States. Extreme floods in 2016 and 2018 caused widespread culvert blockages and road failures, including extensive damage along steep tributaries and ravines in the Marengo River, Wisconsin, watershed during 2016 and 2018. A study conducted by the U.S. Geological Survey (USGS), Wisconsin Wetlands Association (WWA), Ashland County, and the Northwest Wisconsin Regional Planning Commission (NWRPC) investigated the special concern of fluvial erosion hazards (FEHs) associated with gullying, streamside landslides, and the loss of wetland storage in headwaters. In 2019, a pilot study was begun to map and classify ephemeral and perennial streams and wetlands in terms of their sensitivity to FEHs. This study combined data from field-based rapid geomorphic assessments (RGAs) coupled with a stream network-wide geographic information system (GIS) approach for mapping stream segments, referred to as fluvial process zones (FPZ), sensitive to erosion, deposition, and channel change. The GIS approach used nationally available 10-meter (m) resolution topology and an extended stream network to map FPZs based on Strahler stream order, stream power, channel slope, presence of adjacent steep valley sides and headwater flats, and adjacent landform setting. Bankfull channel widths derived from RGA-based hydraulic geometry curves combined with drainage areas, an estimate of bankfull flow, and channel slope were used to calculate specific stream power for the FPZs. Lastly, the FPZs were characterized by their location within three major landform settings that affect erosion potential. The resulting vulnerability maps provided a screening framework to identify FPZs that are sensitive to incision, gullying and mass wasting along steep headwater ephemeral channels, as well as downstream perennial channels that have the potential for valley-side landslides, coarse sediment deposition, and channel change. Lastly, each FPZ was characterized in terms of hydrologic alteration associated with ditching. The vulnerability mapping products and rankings of sensitivity of FPZs will ultimately be used by Ashland County and their collaborators to prioritize natural flood management projects that mitigate FEHs, restore hydrology, and reconnect channels with adjacent wetlands and floodplains.

Wisconsin

Classification of ephemeral, intermittent, and perennial stream reaches using a TOPMODEL-based approach

Whether a waterway is temporary or permanent influences regulatory protection guidelines, however, classification can be subjective due to a combination of factors, including time of year, antecedent moisture conditions, and previous experience of the field investigator. Our objective was to develop a standardized protocol using publicly available spatial information to classify ephemeral, intermittent, and perennial streams. Our hypothesis was that field observations of flow along the stream channel could be compared to results from a hydrologic model, providing an objective method of how these stream reaches can be identified. Flow-state sensors were placed at ephemeral, intermittent, and perennial stream reaches from May to December 2011 in the Appalachian coal basin of eastern Kentucky. This observed flow record was then used to calibrate the simulated saturation deficit in each channel reach based on the topographic wetness index used by TOPMODEL. Saturation deficit values were categorized as flow or no-flow days, and the simulated record of streamflow was compared to the observed record. The hydrologic model was more accurate for simulating flow during the spring and fall seasons. However, the model effectively identified stream reaches as intermittent and perennial in each of the two basins.

Journal of the American Water Resources Associatio

Community-powered urban stream restoration: A vision for sustainable and resilient urban ecosystems

Urban streams can provide amenities to people living in cities, but those benefits are reduced when streams become degraded, potentially even causing harm (disease, toxic compounds, etc.). Governments and institutions invest resources to improve the values and services provided by urban streams; however, the conception, development, and implementation of such projects may not include meaningful involvement of community members and other stakeholders. Consequently, project objectives may be misaligned with community desires and needs, and projects may fail to achieve their goals. In February 2020, the 5 th Symposium on Urbanization and Stream Ecology, an interdisciplinary meeting held every 3 to 5 y, met in Austin, Texas, USA, to explore new approaches to urban stream projects, including ways to maximize the full range of potential benefits by better integrating community members into project identification and decision making. The symposium included in-depth discussion about 4 nearby field case studies, participation of multidisciplinary urban stream experts from 5 continents, and input from the Austin community. Institutional barriers to community inclusion were identified and analyzed using real-world examples, both from the case studies and from the literature, which clarified disparities in power, equity, and values. Outcomes of the symposium have been aggregated into a vision that challenges the present institutional approach to urban stream management and a set of strategies to systematically address these barriers to improve restoration solutions. Integrating community members and other stakeholders throughout the urban restoration process, and a transparent decision-making process to resolve divergent objectives, can help identify appropriate goals for realizing both the ecological and social benefits of stream restoration.

Texas

Reactive solute transport in an acidic stream: Experimental pH increase and simulation of controls on pH, aluminum, and iron

Solute transport simulations quantitatively constrained hydrologic and geochemical hypotheses about field observations of a pH modification in an acid mine drainage stream. Carbonate chemistry, the formation of solid phases, and buffering interactions with the stream bed were important factors in explaining the behavior of pH, aluminum, and iron. The precipitation of microcrystalline gibbsite accounted for the behavior of aluminum; precipitation of Fe(OH)3 explained the general pattern of iron solubility. The dynamic experiment revealed limitations on assumptions that reactions were controlled only by equilibrium chemistry. Temporal variation in relative rates of photoreduction and oxidation influenced iron behavior. Kinetic limitations on ferrous iron oxidation and hydrous oxide precipitation and the effects of these limitations on field filtration were evident. Kinetic restraints also characterized interaction between the water column and the stream bed, including sorption and desorption of protons from iron oxides at the sediment-water interface and post-injection dissolution of the precipitated aluminum solid phase.

Environmental Science & Technology

Contaminants in stream sediments from seven United States metropolitan areas: part II—sediment toxicity to the amphipod Hyalella azteca and the midge Chironomus dilutus

Relationships between sediment toxicity and sediment chemistry were evaluated for 98 samples collected from seven metropolitan study areas across the United States. Sediment-toxicity tests were conducted with the amphipod Hyalella azteca (28 day exposures) and with the midge Chironomus dilutus (10 day exposures). Overall, 33 % of the samples were toxic to amphipods and 12 % of the samples were toxic to midge based on comparisons with reference conditions within each study area. Significant correlations were observed between toxicity end points and sediment concentrations of trace elements, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), or organochlorine (OC) pesticides; however, these correlations were typically weak, and contaminant concentrations were usually below sediment-toxicity thresholds. Concentrations of the pyrethroid bifenthrin exceeded an estimated threshold of 0.49 ng/g (at 1 % total organic carbon) in 14 % of the samples. Of the samples that exceeded this bifenthrin toxicity threshold, 79 % were toxic to amphipods compared with 25 % toxicity for the samples below this threshold. Application of mean probable effect concentration quotients (PECQs) based on measures of groups of contaminants (trace elements, total PAHs, total PCBs,OCpesticides, and pyrethroid pesticides [bifenthrin in particular]) improved the correct classification of samples as toxic or not toxic to amphipods compared with measures of individual groups of contaminants. Sediments are a repository for many contaminants released into surface waters. Because of this, organisms inhabiting sediments may be exposed to a wide range of contaminants (United States Environmental Protection Agency (USEPA) United States Environmental Protection Agency 2000; American Society for Testing and Materials [ASTM] American Society for Testing and Materials International 2012). Contaminants of potential concern in sediments typically include trace elements (metals), organochlorine (OC) pesticides, polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs; Ingersoll et al. 2001). In 2000, the USEPA began to restrict the use of organophosphate pesticides, such as diazinon and chlorpyrifos (Spurlock and Lee 2008). These restrictions have led to increased use of pyrethroid pesticides, which have widespread applications in both agricultural and urban environments (Kuivila et al. 2012). Pyrethroids are hydrophobic compounds that have been observed to accumulate in sediments (Laskowski 2002). Toxicity of pyrethroids in field-collected sediment from small urban streams (Weston et al. 2005; Holmes et al. 2008; Ding et al. 2010; Domagalski et al. 2010) or with pyrethroids spiked into sediment (Amweg et al. 2006; Hintzen et al. 2009) have been evaluated primarily in 10 day lethality tests conducted with the amphipod Hyalella azteca . However, the sublethal effects in long-term exposures to pyrethroids in sediment have not been evaluated, and the distribution of pyrethroids sediments has not typically been evaluated in wadeable streams (Gilliom et al. 2006). This article is the second in a series that describe the results of a study of the distribution and toxicity of pyrethroids and other co-occurring trace elements and organic contaminants (PCBs, PAHs, OC pesticides) in stream sediments from 7 metropolitan areas across the United States (Moran et al. 2012). The study evaluated 98 sediment samples collected from streams ranging from undeveloped to highly urban and differs from previous studies by sampling larger wadeable streams and avoiding point sources (such as storm drains) and other inflows (Gilliom et al. 2006). Part 1 of the series characterizes sediment contaminants in relation to urbanization and other factors in the 7 metropolitan study areas (Nowell et al. 2012). Part 2 (this article) evaluates relationships between sediment chemistry and sediment toxicity in 28 day whole-sediment exposures conducted with the amphipod H. azteca and in 10 day whole-sediment exposure conducted with the midge Chironomus dilutus (USEPA United States Environmental Protection Agency 2000; ASTM American Society for Testing and Materials International 2012). Toxicity end points evaluated in the amphipod and midge exposures included the effects of these field-collected sediments on survival, weight, or biomass of the test organisms.

Georgia;Massachusetts;Texas;Colorado;Wisconsin;Uta

Field-based evaluations of horizontal flat-plate fish screens, II: Testing of a unique off-stream channel device - The Farmers Screen

Screens are installed at water diversion sites to reduce entrainment of fish. Recently, the Farmers Irrigation District (Oregon) developed a unique flat-plate screen (the “Farmers Screen”) that operates passively and may offer reduced installation and operating costs. To evaluate the effectiveness of this screen on fish, we conducted two separate field experiments. First, juvenile coho salmon Oncorhynchus kisutch were released over a working version of this screen under a range of inflows (0.02–0.42 m 3 /s) and diversion flows (0.02–0.34 m 3 /s) at different water depths. Mean approach velocities ranged from 0 to 5 cm/s and sweeping velocities ranged from 36 to 178 cm/s. Water depths over the screen surface ranged from 1 to 25 cm and were directly related to inflow. Passage of fish over the screen under these conditions did not severely injure them or cause delayed mortality, and no fish were observed becoming impinged on the screen surface. Second, juvenile coho salmon and steelhead O. mykiss were released at the upstream end of a 34-m flume and allowed to volitionally move downstream and pass over a 3.5-m section of the Farmers Screen to determine whether fish would refuse to pass over the screen after encountering its leading edge. For coho salmon, 75–95% of the fish passed over the screen within 5 min and 82–98% passed within 20 min, depending on hydraulic conditions. For steelhead, 47–90% of the fish passed over the screen within 5 min and 79–95% passed within 20 min. Our results indicate that when operated within its design criteria, the Farmers Screen provides safe and efficient downstream passage of juvenile salmonids under a variety of hydraulic conditions.

North American Journal of Fisheries Management

Development of regional curves relating bankfull-channel geometry and discharge to drainage area for streams in Pennsylvania and selected areas of Maryland

Natural-stream designs are commonly based on the dimensions of the bankfull channel, which is capable of conveying discharges that transport sediment without excessive erosion or deposition. Regional curves relate bankfull-channel geometry and discharge to drainage area in watersheds with similar runoff characteristics and commonly are utilized by practitioners of natural-stream design to confirm or refute selection of the field-identified bankfull channel. Data collected from 66 streamflow-gaging stations and associated stream reaches between December 1999 and December 2003 were used in one-variable ordinary least-squares regression analyses to develop regional curves relating drainage area to cross-sectional area, discharge, width, and mean depth of the bankfull channel. Watersheds draining to these stations are predominantly within the Piedmont, Ridge and Valley, and Appalachian Plateaus Physiographic Provinces of Pennsylvania and northern Maryland. Statistical analyses of physiography, percentage of watershed area underlain by carbonate bedrock, and percentage of watershed area that is glaciated indicate that carbonate bedrock, not physiography or glaciation, has a controlling influence on the slope of regional curves. Regional curves developed from stations in watersheds underlain by 30 percent or less carbonate bedrock generally had steeper slopes than the corresponding relations developed from watersheds underlain by greater than 30 percent carbonate bedrock. In contrast, there is little evidence to suggest that regional curves developed from stations in the Piedmont or Ridge and Valley Physiographic Province are different from the corresponding relations developed from stations in the Appalachian Plateaus Physiographic Province. On the basis of these findings, regional curves are presented to represent two settings that are independent of physiography: (1) noncarbonate settings characterized by watersheds with carbonate bedrock underlying 30 percent or less of watershed area, and (2) carbonate settings characterized by watersheds with carbonate bedrock underlying greater than 30 percent of watershed area. All regional curves presented in this report have slopes that are significantly different from zero and normally distributed residuals that vary randomly with drainage area. Drainage area explains the most variability in bankfull cross-sectional area and bankfull discharge in the noncarbonate setting (R2 = 0.92 for both). Less variability is explained in bankfull width and depth (R2 = 0.81 and 0.72, respectively). Regional curves representing the carbonate setting are generally not as statistically robust as the corresponding noncarbonate relations because there were only 11 stations available to develop these curves and drainage area cannot explain variance resulting from karst features. The carbonate regional curves generally are characterized by less confidence, lower R2 values, and higher residual standard errors. Poor representation by watersheds less than 40 mi2 causes the carbonate regional curves for bankfull discharge, cross-sectional area, and mean depth to be disproportionately influenced by the smallest watershed (values of Cook's Distance range from 3.6 to 8.4). Additional bankfull discharge and channel-geometry data from small watersheds might reduce this influence, increase confidence, and generally improve regional curves representing the carbonate setting. Limitations associated with streamflow-gaging station selection and development of the curves result in some constraints for the application of regional curves presented in this report. These curves apply only to streams within the study area in watersheds having land use, streamflow regulation, and drainage areas that are consistent with the criteria used for station selection. Regardless of the setting, the regional curves presented here are not intended for use as the sole method for estimation of bankfull characteristics; however, th

Scientific Investigations Report

Scaling hyporheic exchange and its influence on biogeochemical reactions in aquatic ecosystems

Hyporheic exchange and biogeochemical reactions are difficult to quantify because of the range in fluid‐flow and sediment conditions inherent to streams, wetlands, and nearshore marine ecosystems. Field measurements of biogeochemical reactions in aquatic systems are impeded by the difficulty of measuring hyporheic flow simultaneously with chemical gradients in sediments. Simplified models of hyporheic exchange have been developed using Darcy's law generated by flow and bed topography at the sediment‐water interface. However, many modes of transport are potentially involved (molecular diffusion, bioturbation, advection, shear, bed mobility, and turbulence) with even simple models being difficult to apply in complex natural systems characterized by variable sediment sizes and irregular bed geometries. In this study, we synthesize information from published hyporheic exchange investigations to develop a scaling relationship for estimating mass transfer in near‐surface sediments across a range in fluid‐flow and sediment conditions. Net hyporheic exchange was quantified using an effective diffusion coefficient ( D e ) that integrates all of the various transport processes that occur simultaneously in sediments, and dimensional analysis was used to scale D e to shear stress velocity, roughness height, and permeability that describe fluid‐flow and sediment characteristics. We demonstrated the value of the derived scaling relationship by using it to quantify dissolved oxygen (DO) uptake rates on the basis of DO profiles in sediments and compared them to independent flux measurements. The results support a broad application of the D e scaling relationship for quantifying coupled hyporheic exchange and biogeochemical reaction rates in streams and other aquatic ecosystems characterized by complex fluid‐flow and sediment conditions.

Water Resources Research

A spatially referenced regression model (SPARROW) for suspended sediment in streams of the Conterminous U.S.

Suspended sediment has long been recognized as an important contaminant affecting water resources. Besides its direct role in determining water clarity, bridge scour and reservoir storage, sediment serves as a vehicle for the transport of many binding contaminants, including nutrients, trace metals, semi-volatile organic compounds, a nd numerous pesticides (U.S. Environmental Protection Agency, 2000a). Recent efforts to addr ess water-quality concerns through the Total Maximum Daily Load (TMDL) process have iden tified sediment as the single most prevalent cause of impairment in the Nation’s streams a nd rivers (U.S. Environmental Protection Agency, 2000b). Moreover, sediment has been identified as a medium for the tran sport and sequestration of organic carbon, playing a potentia lly important role in understa nding sources and sinks in the global carbon budget (Stallard, 1998). A comprehensive understanding of sediment fate a nd transport is considered essential to the design and implementation of effective plans for sediment management (Osterkamp and others, 1998, U.S. General Accounting Office, 1990). An exte nsive literature addr essing the problem of quantifying sediment transport has produced a nu mber of methods for estimating its flux (see Cohn, 1995, and Robertson and Roerish, 1999, for us eful surveys). The accuracy of these methods is compromised by uncertainty in the concentration measurements and by the highly episodic nature of sediment movement, particul arly when the methods are applied to smaller basins. However, for annual or decadal flux es timates, the methods are generally reliable if calibrated with extended periods of data (Robertson and Roerish, 1999). A substantial literature also supports the Universal Soil Loss Equation (U SLE) (Soil Conservation Service, 1983), an engineering method for estimating sheet and rill erosion, although the empirical credentials of the USLE have recently been questioned (Tri mble and Crosson, 2000). Conversely, relatively little direct evidence is available concerning the fate of sediment. The common practice of quantifying sediment fate with a sediment deliv ery ratio, estimated from a simple empirical relation with upstream basin area, does not artic ulate the relative importance of individual storage sites within a basin (Wolman, 1977). Rates of sediment deposition in reservoirs and flood plains can be determined from empirical measurement s , but only a limited number of sites have been monitored, and net rates of deposition or loss from other potential sinks and sources is largely unknown (Stallard, 1998). In particular, little is known about how much sediment loss from fields ultimately makes its way to stream channels, and how much sediment is subsequently stored in or lost from th e streambed (Meade and Parker, 1985, Trimble and Crosson, 2000). This paper reports on recent progress made to a ddress empirically the question of sediment fate and transport on a national scale. The model pres ented here is based on the SPAtially Referenced Regression On Watershed attr ibutes (SPARROW) methodology, fi rst used to estimate the distribution of nutrients in str eams and rivers of the United Stat es, and subsequently shown to describe land and stream processes affecting the delivery of nutrients (Smith and others, 1997, Alexander and others, 2000, Preston and Brakeb ill, 1999). The model makes use of numerous spatial datasets, available at the national level, to explain long-term sediment water-quality conditions in major streams and rivers throughou t the United States. Sediment sources are identified using sediment erosion rates from the National Resources I nventory (NRI) (Natural Resources Conservation Service, 2000) and apportioned over the landscape according to 30- meter resolution land-use information from th e National Land Cover Data set (NLCD) (U.S. Geological Survey, 2000a). More than 76,000 reservoirs from the National Inventory of Dams (NID) (U.S. Army Corps of Engin eers, 1996) are identified as pot ential sediment sinks. Other, non-anthropogenic sources and sinks are identified using soil in formation from the State Soil Survey Geographic (STATSGO) data base (Schwarz and Alexander, 1995) and spatial coverages representing surficial rock t ype and vegetative cover. The SPA RROW model empirically relates these diverse spatial datasets to estimates of long-term, mean annual sediment flux computed from concentration and flow measurements co llected over the period 1985 -95 from more than 400 monitoring stations maintained by the Na tional Stream Quality Accounting Network (Alexander and others, 1998), the National Wa ter Quality Assessment Program, and U.S. Geological Survey District offices (Turcios and Gray, in press). Th e calibrated model is used to estimate sediment flux for over 60,000 stream segments included in the River Reach File 1 (RF1) stream network (Alexander and others, 1999). SPARROW uses statis tical methods to calibrate a simple, structural model of riverine water quality, one that imposes mass ba lance in accounting for changes in contaminant flux. As applied here, the mass-balance approach facilitates the interpretation of model results in terms of physical processes affecting sediment transport, and makes possible the estimation of various rates of sediment generation and loss associated with stream channels and features of the landscape. The statistical approach provides a basi s for assessing the error of these inferred rates and of the error in extrapolated estimates of sediment flux made for streams in the RF1 network. An important implication of the holistic modeling approach adopted in this analysis is that estimates of sediment production and loss ar e based on, and therefore consistent with, measurements of in-stream flux. Other ancillary information, such as direct measurements of long-term sediment storage and release from rese rvoirs (Steffen, 1996), is incorporated into the analysis by specifying additional equations expl aining these ancillary variables. The imposition of cross-equation constraints affords this info rmation a statistically consistent weight in explaining in-stream sediment flux. Thus, the me thodology described here represents a general framework for synthesizing a wide spectrum of available information relevant to the understanding of sediment fate and transport.

Conterminous United States

Water quality of the Delaware and Raritan Canal, New Jersey, 1998-99

Since 1934, the Delaware and Raritan Canal has been used to transfer water from the Delaware River Basin to the Raritan River Basin. The water transported by the Delaware and Raritan Canal in New Jersey is used primarily for public supply after it has been treated at drinking-water treatment plants located in the Raritan River Basin. Recently (1999), the raw water taken from the canal during storms has required increased amounts of chemical treatments for removal of suspended solids, and the costs of removing the additional sludge or residuals generated during water treatment have increased. At present, action to control algae is unnecessary. The water quality of the Delaware and Raritan Canal was studied for approximately 16.5 months from mid-January 1998 through May 1999 to determine whether changes in water quality along the length of the canal are associated with storms. Nine water-quality constituents, and field measured specific conductance and turbidity were statistically tested. Instantaneous or grab samples of water were collected from the Delaware and Raritan Canal after five storms and during four nonstorm events. Median values of water-quality constituents in samples collected immediately after storms and during nonstorm conditions when statistically compared by sampling location were not significantly different. Therefore, the data were combined or aggregated to eliminate one of the two explanatory variables, either individual sampling sites or the two types of sampling events, in order to generate a sample population large enough to show statistically significant differences. After combining sampling events, only the median concentration of suspended organic carbon, and field measured specific conductance and turbidity, were significantly different among sampling sites. Median concentrations of total and filtered ammonia plus organic nitrogen, total phosphorous, turbidity, ultraviolet absorbance at 254 nanometers, and dissolved organic carbon in samples collected after storms were significantly greater than in samples collected during nonstorm conditions, when the sampling locations were aggregated in the statistical analysis. Methyl tert-butyl ether, the most frequently detected volatile organic compound (VOC), was detected in 55 of 80 samples. The highest concentration of methyl tert-butyl ether, 3.2 micrograms per liter, was measured in a sample collected during nonstorm conditions. The median of the continuously monitored specific conductance during nonstorm conditions at Port Mercer, N.J., increased by approximately 3 to 4 ?S/cm (microsiemens per centimeter) (1.5 to 2 percent of the median specific conductance) relative to that at the nearest upstream site, at Lower Ferry Road. The land use in the influent basins for this reach of the Delaware and Raritan Canal is primarily urban. One possible source of water with high specific conductance is either domestic or industrial wastewater that continuously discharges into pipes, then empties into the canal. Another possible source is ground water from an area within this reach where the elevation of the water table is higher than that of the water surface of the Delaware and Raritan Canal. The median continuously monitored specific conductance measured during nonstorm conditions at the Route 18 Spillway site increased relative to that of the nearest upstream site, Ten Mile Lock, by approximately 3 to 4 ?S/cm. The mean net change in continuously monitored specific conductance for this reach during storms also increased. Land use in the two largest influent basins within this reach, the Borough of South Bound Brook and Als Brook, is predominantly urban. The mean and median of continuously monitored turbidity varied along the length of the canal. In the reach between Raven Rock and Lower Ferry Road, the mean and median for continuously monitored turbidity during the study period increased by 7.2 and 6.2 NTU (nephelometric turbidity units), respectively. The mean of continuously monitored turbidity decreased downstream from Lower Ferry Road to Ten Mile Lock. Turbidity could increase locally downstream from influent streams or outfalls, but because the average velocity of water in the canal is low, particles that cause turbidity are not transported appreciable distances. In the reach between Ten Mile Lock and the Route 18 Spillway, the mean and median of the continuously monitored turbidity changed less than 0.5 NTU during the period of record. The small change in turbidity in this reach is not consistent with an average velocity for the reach; the average velocity in this reach was the lowest in all of the reaches studied. The expected decrease in turbidity due to settling of suspended solids is likely offset by turbid water entering the canal from influent streams or discharges from storm drains. Field observation of a sand bar immediately downstream from the confluence of Als Brook and the canal confirmed that the Als Brook drainage basin has contributed stormwatergenerated sediment to the canal that could reach the monitor located at the Route 18 Spillway and the raw water intakes for two drinking-water treatment plants.

New Jersey

Effects of historical coal mining and drainage from abandoned mines on streamflow and water quality in Bear Creek, Dauphin County, Pennsylvania — March 1999–December 2002

More than 100 years of anthracite coal mining has changed surface- and ground-water hydrology and contaminated streams draining the Southern Anthracite Coal Field in east-central Pennsylvania. Bear Creek drains the western prong of the Southern Anthracite Coal Field and is affected by metals in drainage from abandoned mines and streamwater losses. Total Maximum Daily Loads (TMDL) developed for dissolved iron of about 5 lb/d (pounds per day) commonly are exceeded in the reach downstream of mine discharges. Restoration of Bear Creek using aerobic ponds to passively remove iron in abandoned mine drainage is under consideration (2004) by the Dauphin County Conservation District. This report, prepared in cooperation with the Dauphin County Conservation District, evaluates chemical and hydrologic data collected in Bear Creek and its receiving waters prior to implementation of mine-drainage treatment. The data collected represent the type of baseline information needed for documentation of water-quality changes following passive treatment of mine drainage in Pennsylvania and in other similar hydrogeologic settings. Seven surface-water sites on Bear Creek and two mine discharges were monitored for nearly three years to characterize the chemistry and hydrology of the following: (1) Bear Creek upstream of the mine discharges (BC-UMD), (2) water draining from the Lykens-Williamstown Mine Pool at the Lykens Water-Level Tunnel (LWLT) and Lykens Drift (LD) discharges, (3) Bear Creek after mixing with the mine discharges (BC-DMD), and (4) Bear Creek prior to mixing with Wiconisco Creek (BCM). Two sites on Wiconisco Creek, upstream and downstream of Bear Creek (WC-UBC and WC-DBC, respectively), were selected to evaluate changes in streamflow and water quality upon mixing with Bear Creek. During periods of below-normal precipitation, streamwater loss was commonly 100 percent upstream of site BC-UMD (streamflow range = 0 to 9.7 ft3/s (cubic feet per second)) but no loss was detected downstream owing to sustained mine water drainage from the Lykens Water-Level Tunnel (range = 0.41 to 3.7 ft3/s), Lykens Drift (range = 0.40 to 6.1 ft3/s), and diffuse zones of seepage. Collectively, mine water inputs contributed about 84 percent of base flow and 53 percent of stormflow measured in the downstream reach. An option under consideration by the Dauphin County Conservation District for treatment of the discharge from the LWLT requires the source of the discharge to be captured and rerouted downstream, bypassing approximately 1,000 feet of stream channel. Because streamwater loss upstream of the tunnel was commonly 100 percent, rerouting the discharge from the LWLT may extend the reach of Bear Creek that is subject to dryness. Differences in the chemistry of water discharging from the LWLT compared to the LD suggest that the flow path through the Lykens-Williamstown Mine Pool to each mine discharge is unique. The LWLT is marginally alkaline (median net acid neutralizing capacity (ANC) = 9 mg/L (milligrams per liter) as CaCO3; median pH = 5.9), commonly becomes acidic (minimum net ANC = -74 mg/L as CaCO3) at low flow, and may benefit from alkaline amendments prior to passive treatment. Water discharging from the LD provides excess ANC (median net ANC = 123 mg/L as CaCO3; median pH = 6.5) to the downstream reach and is nearly anoxic at its source (median dissolved oxygen = 0.5 mg/L). Low dissolved oxygen water with relatively high ANC and metals concentrations discharging from the LD is characteristic of a deeper flow path and longer residence time within the mine pool than the more acidic, oxygenated water discharging from the LWLT. TMDLs for iron have been developed for dissolved species only. Consequently, distinguishing between dissolved and suspended iron in Bear Creek is important for evaluating water-quality improvement through TMDL attainment. Median total iron concentration increased from 550 mg/L (micrograms per liter) at site BC-UM

Pennsylvania

Estimating occupancy and abundance of stream amphibians using environmental DNA from filtered water samples

Environmental DNA (eDNA) methods for detecting aquatic species are advancing rapidly, but with little evaluation of field protocols or precision of resulting estimates. We compared sampling results from traditional field methods with eDNA methods for two amphibians in 13 streams in central Idaho, USA. We also evaluated three water collection protocols and the influence of sampling location, time of day, and distance from animals on eDNA concentration in the water. We found no difference in detection or amount of eDNA among water collection protocols. eDNA methods had slightly higher detection rates than traditional field methods, particularly when species occurred at low densities. eDNA concentration was positively related to field-measured density, biomass, and proportion of transects occupied. Precision of eDNA-based abundance estimates increased with the amount of eDNA in the water and the number of replicate subsamples collected. eDNA concentration did not vary significantly with sample location in the stream, time of day, or distance downstream from animals. Our results further advance the implementation of eDNA methods for monitoring aquatic vertebrates in stream habitats.

Canadian Journal of Fisheries and Aquatic Sciences

Hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and parts of the Aucilla-Suwannee-Ochlockonee River basins in Georgia and adjacent parts of Florida and Alabama during drought conditions, July 2011

As part of the U.S. Department of the Interior sustainable water strategy, WaterSMART, the U.S. Geological Survey documented hydrologic and water-quality conditions in the lower Apalachicola-Chattahoochee-Flint and western and central Aucilla-Suwannee-Ochlockonee River basins in Alabama, Florida, and Georgia during low-flow conditions in July 2011. Moderate-drought conditions prevailed in this area during early 2011 and worsened to exceptional by June, with cumulative rainfall departures from the 1981-2010 climate normals registering deficits ranging from 17 to 27 inches. As a result, groundwater levels and stream discharges measured below median daily levels throughout most of 2011. Water-quality field properties including temperature, dissolved oxygen, specific conductance, and pH were measured at selected surface-water sites. Record-low groundwater levels measured in 12 of 43 surficial aquifer wells and 128 of 312 Upper Floridan aquifer wells during July 2011 underscored the severity of drought conditions in the study area. Most wells recorded groundwater levels below the median daily statistic, and 7 surficial aquifer wells were dry. Groundwater-level measurements taken in July 2011 were used to determine the potentiometric surface of the Upper Floridan aquifer. Groundwater generally flows to the south and toward streams except in reaches where streams discharge to the aquifer. The degree of connection between the Upper Floridan aquifer and streams decreases east of the Flint River where thick overburden hydraulically separates the aquifer from stream interaction. Hydraulic separation of the Upper Floridan aquifer from streams located east of the Flint River is shown by stream-stage altitudes that differ from groundwater levels measured in close proximity to streams. Most streams located in the study area during 2011 exhibited below normal flows (streamflows less than the 25th percentile), substantiating the severity of drought conditions that year. Streamflow and springflow measured at 202 sites along 2,122 stream miles during July 20-24, 2011, identified about 286 miles of losing streams, about 1,230 miles of gaining streams, and about 606 miles of streams with no flow. Water-quality field properties measured at 123 stream and 5 spring sites during July 2011 yielded water temperatures ranging from 20.6 to 31.6 degrees Celsius, dissolved oxygen ranging from 0.47 to 9.98 milligrams per liter, specific conductance ranging from 13 to 834 microsiemens per centimeter at 25 degrees Celsius, and pH ranging from 3.6 to 8.03.

Alabama, Florida, Georgia

Development of two quantitative PCR assays for detection of several Cottus species from environmental DNA in Pacific coast watersheds of North America

We developed two quantitative PCR assays for use with environmental DNA (eDNA) to detect numerous species in the genus Cottus that are indigenous to the Pacific coast watersheds of North America. We conducted in vitro assay validations on ten Cottus species and 32 potentially co-occurring non- Cottus species. We demonstrate the efficacy of these assays by field testing eDNA samples collected from streams inhabited by Cottus . These assays will be particularly useful for detecting Cottus in habitats where one (or more) of several Cottus species could be present.

Pacific Northwest