SEARCH · Search USGS

Results for “Fast Times”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 199 records · Page 11Linked to original sources

USGS2012

Loss and modification of habitat

Amphibians live in a wide variety of habitats around the world, many of which have been modified or destroyed by human activities. Most species have unique life history characteristics adapted to specific climates, habitats (e.g., lentic, lotic, terrestrial, arboreal, fossorial, amphibious), and local conditions that provide suitable areas for reproduction, development and growth, shelter from environmental extremes, and predation, as well as connectivity to other populations or habitats. Although some species are entirely aquatic or terrestrial, most amphibians, as their name implies, lead a dual life and require a mosaic of habitats in both aquatic and terrestrial ecosystems. With over 6 billion people on Earth, most species are now persisting in habitats that have been directly or indirectly influenced by human activities. Some species have disappeared where their habitats have been completely destroyed, reduced, or rendered unsuitable. Habitat loss and degradation are widely considered by most researchers as the most important causes of amphibian population decline globally (Barinaga 1990; Wake and Morowitz 1991; Alford and Richards 1999). In this chapter, a background on the diverse habitat requirements of amphibians is provided, followed by a discussion of the effects of urbanization, agriculture, livestock grazing, timber production and harvesting, fire and hazardous fuel management, and roads on amphibians and their habitats. Also briefly discussed is the influence on amphibian habitats of natural disturbances, such as extreme weather events and climate change, given the potential for human activities to impact climate in the longer term. For amphibians in general, microhabitats are of greater importance than for other vertebrates. As ectotherms with a skin that is permeable to water and with naked gelatinous eggs, amphibians are physiologically constrained to be active during environmental conditions that provide appropriate body temperatures and adequate water balance (Thorson and Svihla 1943; Brattstrom 1963; Tracy 1976). Hence, individuals require and seek specific microhabitats that maintain their preferred body temperature while at the same time reducing water loss or allowing individuals to re-hydrate. Amphibians also possess relatively few physical attributes that protect them from predators. Although they may avoid predators behaviourally or deter them by skin toxins, amphibians lack defensive shells or hardened cuticles, do not have protective teeth or claws, and most are insufficiently fast to escape predators. Hence, they are relatively dependent on sites that conceal or protect them from predation. Most amphibians also differ significantly from other vertebrates in possessing a complex two-phase life cycle: the pre-metamorphic larval (tadpole) stage and the post-metamorphic juvenile and adult stage (Wilbur 1980, 1984). Most amphibian species have two distinct econes (Heatwole 1989), each with different habitat requirements, the larvae being aquatic and the post-metamorphic animals more terrestrial. The habitats required by the two phases can differ greatly, but both are essential to the survival of a species. However, amphibian diversity is great and exceptions to this general pattern exist. For example, some species have direct development without going through a larval stage and are fully terrestrial, whereas the larvae of other species can reach sexual maturity without going through metamorphosis (i.e., neoteny) and are fully aquatic.

Book chapter↗

USGS2021

Polar bear foraging behavior

Polar bears forage in the marine environment, primarily on the sea ice over the shallow waters of the continental shelf. They are solitary, ambush hunters that catch ringed and bearded seals when they surface to breathe in ice holes or haul out on the ice to rest and molt. In most parts of their range, polar bears experience dramatic seasonal variability in their ability to catch seals, with foraging success peaking in late spring and early summer when seal pups are weaned. During this time, the body mass of polar bears can nearly double, especially in pregnant females, such that body composition may reach 49% body fat. The accumulation of body fat is vital for these bears to survive through the autumn and winter when seals are less accessible or when pregnant adult female bears enter dens and fast. When the sea ice retreats in summer, some bears exhibit a temporary switch to omnivory, feeding on a variety of terrestrial food. However, the energetic benefit of most terrestrial food is small relative to their marine mammal prey and, in some regions, increased land use has been associated with declines in body condition. Reduced accessibility of seal prey to polar bears as a result of global climate change threatens the long-term sustainability of this Arctic predator.

Book chapter↗

USGS2009

Interacción termal entre magmas graníticos laramídicos y rocas encajonantes mesoproterozoicas: Historia de enfriamiento de intrusivos de la sierrita blanca, NW Sonora

A semi-quantitative thermochronological study, combining U-Pb and 40 Ar/ 39 Ar geochronology, has allowed assessment of the crystallization and cooling history of the Laramide Sierrita Blanca granite as well as the thermal effects resulting from the intrusion into the Mesoproterozoic host rocks (~1.1 Ga Murrieta granite). The U-Pb zircon age discrepancy between two samples of the Sierrita Blanca granite (72.6 ± 1.2 Ma and 69.7 ± 1.0 Ma) could be explained by a process of faster magma cooling in the contact zone with the host Murrieta granite. However, that the Sierrita Blanca granitic unit was made up of multiple intrusions of similar compositions emplaced relatively close in time cannot be discarded. The 40 Ar/ 39 Ar ages of both biotite and K-feldspar for the granite collected close to the contact are also significantly older than the ages for the sample collected in a more internal zone of the intrusion. The initial cooling of the Sierrita Blanca granite was fairly fast and monotonous from the closure temperature of zircon to that of biotite (~36–32°C/Ma). Subsequently, the cooling of these Laramide rocks became relatively slow (~10–9°C/Ma) between the closure temperature of biotite and K-feldspar. These estimated cooling rates are similar, perhaps slightly slower, to the ones estimated for other Laramide granitoids in NW Mexico. Three samples of the host Murrieta granite, collected at different distances from the Laramide intrusion, were dated by U-Pb zircon geochronology at ~1.1 Ga, reiterating that the U-Pb zircon systematics are quite resistant to thermal effects inflicted by intrusions like the one in the Sierrita Blanca. However, close inspection of the U-Pb zircon data suggests the presence of Pb loss for some of the zircons. This Pb-loss phenomenon is most pronounced in the zircons from the sample collected at the contact with the Sierrita Blanca intrusive where heat and/or hydrothermal fluids are released by the Laramide intrusion. It is important to note that away from the intrusion-host contact there is a gradual decrease of such thermal effects in the rocks until samples with zircons that show no effects of resetting as suggested by their total U-Pb zircon concordance. This thermal resetting is more prominent in the 40Ar/39Ar systematics of biotite and K-feldspar, since they are totally reset to Laramide ages, including the sample collected the farthest away from the contact. The estimation of post-resetting cooling of biotite and K-feldspar from the host rocks at ~18–15°C/Ma is, in a sense, coherent with the cooling estimates for the same minerals for the Sierrita Blanca granite. This suggests that the general cooling of the Sierrita Blanca after the Laramide intrusion was, for the most part, coherent for the entire area and ended, as expected, in the more internal zones of the Laramide intrusion. Lastly, it is important to point out that the Miocene magmatic pulse present in the Sierrita Blanca and adjacent areas has not caused any thermal disturbance to the Cretaceous or Mesoproterozoic igneous rocks studied in the area.

Northwest Sonora↗

USGS2014

Sex in the Suwannee, the secretive love life of Gulf Sturgeons

Mid-February in the Gulf of Mexico and a timeless ritual is about to repeat itself for perhaps the millionth time. Some mysterious signal, possibly increasing day length, flips an internal switch, feeding stops, and the homeward migration begins for the Gulf Sturgeon ( Acipenser oxyrinchus desotoi ). From far flung places along the Gulf Coast, Gulf Sturgeons start heading back to their natal rivers – they know the way instinctively. Maybe they seek out the special chemical taste of their home river, imprinted at hatching. Or perhaps the ultrasensitive electric organs decorating the underside of the snout can follow the map of the earth’s magnetic field. Either way, time to make a beeline for the welcoming waters of the Suwannee River, or maybe the Apalachicola, Choctawhatchee, or one of four other spawning rivers. Some of the adults are on a special mission – time to spawn, time to perpetuate the species. Mature males form the first wave in this homebound marathon, eager to get to the spawning grounds, eager to be the first to greet ready females with a series of sharp clicking sounds. Only spawning once each three years, females laden with large black eggs demure, taking their time, arriving in mid to late March, a month behind the early males. But most sturgeons, juveniles and immature adults not ready to spawn, are simply heading home. Not prompted by the spawning urge, they are just following the ancient annual cycle of intense winter feeding in the Gulf, followed by several months of fasting and R&R in the river.

Alabama, Florida, Georgia, Louisiana, Mississippi↗

USGS2005

Development and use of in-stream PIT-tag detection systems to assess movement behavior of fish in tributaries of the Columbia River Basin, USA

We have developed detector systems for fish implanted with Passive Integrated Transponder (PIT) tags to assess their movement behavior and habitat use within fast flowing streams. Fish tested have primarily been wild anadromous and resident forms of rainbow trout Oncorhynchus mykiss and cutthroat trout O. clarki . Longitudinal arrangements of two- and six-antennas allow determination of direction of movement and efficiency of detection. Our first detector system became operational in August 2001, with subsequent improvements over time. In tests with a two-antenna system, detection efficiency of tagged, downstreammoving fish was high (96%) during low flows, but less (69%) during high flows. With an increase in the number of antennas to six, arranged in a 2x3 array, the detection efficiency of downstream-moving fish was increased to 95-100% at all flows. Detection efficiency of upstream-moving fish was high (95-100%) in both the two-and six-antenna system during all flows. Antennas were anchored to the substrate and largely spanned the bank-full width. Modifications to the methods used to anchor antennas have increased the likelihood of the system remaining intact and running at full detection capability during challenging flow and debris conditions, largely achieving our goal to have continuous monitoring of fish movement throughout an annual cycle. In August 2004, we placed a similar detector system in another watershed. Success has much relied on the quality of transceivers and electrical power. Detection of tagged fish passing our static PIT-tag detectors has produced valuable information on how selected fish species use the network of streams in a watershed. Integrating information from our detectors in tributary streams with that from detectors downstream at dams in the Columbia River has promise to be a powerful tool for monitoring movement patterns of anadromous fish species and to understanding full lifecycle fish behavior and habitat use.

Conference Paper↗

USGS2010

Recent subsidence-rate reductions in the Mississippi Delta and their geological implications

The Mississippi Delta has long been characterized as an area of rapid subsidence; however, recent subsidence rates are substantially lower than previously reported. Tide-gauge records indicate that rates of relative sea-level rise were slow from 1947 until the mid-1960s, relatively fast from the mid-1960s until the early 1990s, and then slow since the early 1990s. These trends and rates are independently verified by repeat benchmark surveys and height monitoring at continuously operating geographic positioning system stations. Subsidence rates for the slow periods were a few millimeters per year, comparable to rates averaged over geological time scales that are attributed to natural processes such as shallow sediment compaction and deep crustal loading. The decadal pattern of slow, then rapid, then slow subsidence may be caused by natural deep-basin processes ( e.g., gravity gliding and salt migration), but it is more likely related to rates of hydrocarbon production that followed the same temporal trends. If accelerated subsidence was primarily induced by reservoir compaction and fault reactivation associated with fluid withdrawal that also accelerated in the 1960s and 1970s, then the recent reductions in subsidence rates likely reflect a balancing of subsurface stresses and a return to near preproduction conditions.

Arkansas, Louisiana, Mississippi↗

USGS1998

Evaluation of generalized habitat criteria for assessing impacts of altered flow regimes on warmwater fishes

Assessing potential effects of flow regulation on southeastern warmwater fish assemblages is problematic because of high species richness and poor knowledge of habitat requirements for most species. Our study investigated relationships between availability and temporal persistence of key habitats and fish assemblage structure at regulated and unregulated sites in the Tallapoosa River system. Fish assemblage characteristics at seven sites were quantified based on 1,400 electrofishing samples collected during 1994 and 1995. Physical Habitat Simulation (PHABSIM) programs were used to model availability and persistence of key habitats at regulated and unregulated sites. Associations between fish assemblages and availability or persistence of key habitats were identified via regression and analysis of variance. We found that hydropeaking dam operation reduced the average length of time that shallow‐water habitats persisted and also reduced year‐to‐year variation in the persistence of shallow‐water habitats compared with unregulated sites. Across sites and years, proportional representation of catostomids was positively correlated with persistence of shallow and slow‐water habitats during spring. Proportion of individuals as cyprinids was positively correlated with median availability of deep–fast habitat whereas proportion of percids was inversely related to median availability of deep–fast habitat. Mean fish density was positively correlated with the persistence of shallow and slow‐water habitats. Comparisons of key‐habitat measures and fish abundances between 1994 and 1995 at each site indicated that higher abundances of percids, catostomids, and cyprinids were associated with increased availability and persistence of shallow and slow‐water habitats in 1995. These findings demonstrate that the temporal and spatial availability of key habitats could serve as useful measures of the potential effects of flow alteration on lotic fish assemblages and suggest that both short‐term persistence of key habitats as well as annual variation in key‐habitat availability are important for maintaining diverse fish assemblages.

Transactions of the American Fisheries Society↗

USGS2021

Identification of low-frequency earthquakes on the San Andreas fault with deep learning

Low-frequency earthquakes are a seismic manifestation of slow fault slip. Their emergent onsets, low amplitudes, and unique frequency characteristics make these events difficult to detect in continuous seismic data. Here, we train a convolutional neural network to detect low-frequency earthquakes near Parkfield, CA using the catalog of Shelly (2017), https://doi.org/10.1002/2017jb014047 as training data. We explore how varying model size and targets influence the performance of the resulting network. Our preferred network has a peak accuracy of 85% and can reliably pick low-frequency earthquake (LFE) S-wave arrival times on single station records. We demonstrate the abilities of the network using data from permanent and temporary stations near Parkfield, and show that it detects new LFEs that are not part of the Shelly (2017), https://doi.org/10.1002/2017jb014047 catalog. Overall, machine-learning approaches show great promise for identifying additional low-frequency earthquake sources. The technique is fast, generalizable, and does not require sources to repeat.

Geophysical Research Letters↗

USGS1999

D/H isotope ratios of kerogen, bitumen, oil, and water in hydrous pyrolysis of source rocks containing kerogen types I, II, IIS, and III

Immature source rock chips containing different types of kerogen (I, II, IIS, III) were artificially matured in isotopically distinct waters by hydrous pyrolysis and by pyrolysis in supercritical water. Converging isotopic trends of inorganic (water) and organic (kerogen, bitumen, oil) hydrogen with increasing time and temperature document that water-derived hydrogen is added to or exchanged with organic hydrogen, or both, during chemical reactions that take place during thermal maturation. Isotopic mass-balance calculations show that, depending on temperature (310–381°C), time (12–144 h), and source rock type, between ca. 45 and 79% of carbon-bound hydrogen in kerogen is derived from water. Estimates for bitumen and oil range slightly lower, with oil–hydrogen being least affected by water-derived hydrogen. Comparative hydrous pyrolyses of immature source rocks at 330°C for 72 h show that hydrogen in kerogen, bitumen, and expelled oil/wax ranks from most to least isotopically influenced by water-derived hydrogen in the order IIS > II ≈ III > I. Pyrolysis of source rock containing type II kerogen in supercritical water at 381°C for 12 h yields isotopic results that are similar to those from hydrous pyrolysis at 350°C for 72 h, or 330°C for 144 h. Bulk hydrogen in kerogen contains several percent of isotopically labile hydrogen that exchanges fast and reversibly with hydrogen in water vapor at 115°C. The isotopic equilibration of labile hydrogen in kerogen with isotopic standard water vapors significantly reduces the analytical uncertainty of D/H ratios when compared with simple D/H determination of bulk hydrogen in kerogen. If extrapolation of our results from hydrous pyrolysis is permitted to natural thermal maturation at lower temperatures, we suggest that organic D/H ratios of fossil fuels in contact with formation waters are typically altered during chemical reactions, but that D/H ratios of generated hydrocarbons are subsequently little or not affected by exchange with water hydrogen at typical reservoir conditions over geologic time. It will be difficult to utilize D/H ratios of thermally mature bulk or fractions of organic matter to quantitatively reconstruct isotopic aspects of paleoclimate and paleoenvironment. Hope resides in compound-specific D/H ratios of thermally stable, extractable biomarkers (“molecular fossils”) that are less susceptible to hydrogen exchange with water-derived hydrogen.

Geochimica et Cosmochimica Acta↗

USGS2018

Research to improve ShakeAlert earthquake early warning products and their utility

Earthquake early warning (EEW) is the rapid detection of an earthquake and issuance of an alert or notification to people and vulnerable systems likely to experience potentially damaging ground shaking. The level of ground shaking that is considered damaging is defined by the specific application; for example, manufacturing equipment may experience damage at a lower intensity ground shaking than would cause damage to a building. Along the West Coast of the United States, the warning times for ground shaking could range as high as tens of seconds for moderate levels of ground shaking, or potentially longer, if a lower ground-shaking threshold is used to issue alerts. However, it is not always possible to provide advance warning of ground shaking, particularly for locations close to an earthquake that are most likely to experience very strong ground shaking. EEW alerts may be useful to individuals who can use a few seconds to move to a safe zone and to electromechanical systems that can take automatic actions to reduce damage and injuries. An EEW system, ShakeAlert, has been under development in the United States since 2006. Federal and State governments, as well as the private sector, are now investing in the ShakeAlert prototype system that will, when completed, become an operational public system for the West Coast of the United States. While the current prototype is delivering alerts to test users, improvements to the accuracy, timeliness, and utility of the alerts are needed. For this reason, it is essential that the ShakeAlert system be continuously improved through targeted research, involving not only the current ShakeAlert partner organizations, but also the broader scientific, engineering, and emergencyresponse communities. To this end, this report describes the opportunities for improvement that can be addressed through research and development over the next 5 years. Our recommendations are organized into four areas: (1) understand EEW capabilities and user needs, (2) make alerts as fast and accurate as possible, (3) ensure reliability when it counts, and (4) explore the use of new instrumentation. The first challenge is to understand EEW capabilities and user needs. EEW must deliver actionable information to people and to automated systems to mitigate short- and longterm impacts of damaging ground shaking, so development of EEW must be motivated by the needs of users. Within this challenge, we must study the technical capabilities and limitations of EEW in general, and the ShakeAlert system specifically. This includes development of performance metrics that assess the timeliness and accuracy of alerts to understand the value and utility of the ShakeAlert EEW product(s) for various user groups, including different industry sectors, emergency-management agencies, and the public. Research is needed to define the alerting choices that maximize the utility of the system for users and to determine what the available communication pathways are for providing timely alert information. Additionally, we engage users to assess how alerts will be used by different sectors to mitigate losses and to inform EEW product design. Further, social-science research is needed to develop alert messaging, including what relevant prior and follow-up information are required, to ensure effective use of alerts. The second challenge is to make alerts as fast and as accurate as possible. The timeliness and accuracy of an EEW alert is important because it will set in motion a series of actions and downstream products. An EEW alert will trigger notification across emergency-alert systems and across multiple communication channels to populations in impacted regions. The EEW alert region may grow as the earthquake fault-rupture length increases, and the EEW system’s characterization of it, evolves. We must continue research into new or improved seismic and geodetic waveform-processing methods necessary to rapidly characterize the expected ground shaking and associated uncertainties. It is important to thoroughly evaluate whether new methods improve alerts through more accurate ground-motion estimates and (or) reduced latencies (that is, longer warning times). New methods could include tracking the extent of a large rupture in real time (known as finite-fault algorithms) and ground-motionbased EEW algorithms. Additionally, ground motion predictions could be optimized for each earthquake as the earthquake fault rupture progresses by using, for example, event terms to shift ground-motion curves for more (or less) energetic ruptures. The third challenge is to ensure reliability when it counts. This challenge requires us to explore approaches that assess the expected performance of ShakeAlert across the range of earthquake magnitudes, locations, and depths that may occur within the alerting region. Large, damaging earthquakes and their associated aftershock sequences matter most for hazard and for EEW, but these large-earthquake sequences occur infrequently. We expect ShakeAlert to respond robustly to these large-earthquake sequences despite potentially long periods of relative seismic quiescence in the intervening years, and in spite of inevitable communication challenges that arise during and after a large earthquake. We must develop methods to utilize the broadest available datasets to test EEW performance, including ground-motion data recorded in other parts of the world. The observational period for large, damaging earthquakes in any particular region has been short in comparison to estimated large-earthquake recurrence times. Ground-motion records for very large, damaging western United States events and major aftershock sequences do not yet exist, nor do data exist for all potential sources of noise and spurious signals that ShakeAlert must be “tuned” to reject. In addition, robust synthetic data could provide the flexibility to test a wider range of earthquake magnitude, tectonic-setting, and noise scenarios than are covered by existing observational data. Synthetic ground-motion data must be thoroughly vetted against records of smaller magnitude earthquakes to ensure that they accurately capture both the onset and the amplitude of the ground shaking. The final challenge is to explore the use of new instrumentation. The development of EEW around the world to date has focused on the use of high-quality, scientific-grade seismic and geodetic instrumentation. The use of additional types of instrumentation or information may also improve EEW products by filling gaps in sensor coverage in countries that already have dense seismic networks or enable EEW in countries without such networks. We must keep up with these developments and continuously assess their value in supplementing existing EEW systems, such as ShakeAlert, or enabling EEW where such systems do not exist. Such developments include low-cost instrumentation with microelectromechanical system (MEMS) sensors and global positioning system (GPS)/global navigation satellite system (GNSS) antennas embedded in low-cost consumer electronics, sea-floor seismometers, geodetic instrumentation deployed along the Cascadia and Alaska megathrust margins of western North America, and borehole strainmeters that are already deployed across the region.

Open-File Report↗

USGS2024

The post-emergence period for denning polar bears: Phenology and influence on cub survival

Among polar bears ( Ursus maritimus ), only parturient females den for extended periods, emerging from maternal dens in spring after having substantially depleted their energy reserves during a fast that can exceed 8 months. Although den emergence coincides with a period of increasing prey availability, polar bears typically do not depart immediately to hunt, but instead remain at the den for up to a month. This delay suggests that there are likely adaptive advantages to remaining at the den between emergence and departure, but the influence of the timing and duration of this post-emergence period on cub survival has not been evaluated previously. We used temperature and location data from 70 denning bears collared within the Southern Beaufort Sea and Chukchi Sea subpopulations to estimate the phenology of the post-emergence period. We evaluated the influence of various spatial and temporal features on duration of the post-emergence period and evaluated the potential influence of post-emergence duration on litter survival early in the spring following denning. For dens that likely contained viable cubs at emergence ( n = 56), mean den emergence occurred on 16 March (SE = 1.4 days) and mean departure on 24 March (SE = 1.6 days), with dates typically occurring later in the Chukchi Sea relative to Southern Beaufort Sea and on land relative to sea ice. Mean duration of the post-emergence period was 7.9 days (SE = 1.4) for bears that were observed with cubs later in the spring, which was over 4 times longer than duration of those observed without cubs (1.9 days). Litter survival in the spring following denning ( n = 31 dens) increased from 0.5 to 0.9 when duration of the post-emergence period increased by ~4 days and other variables were held at mean values. Our limited sample size and inability to verify cub presence at emergence suggests that future research is merited to improve our understanding of this relationship. Nonetheless, our results highlight the importance of the post-emergence period in contributing to reproductive success and can assist managers in developing conservation and mitigation strategies in denning areas, which will be increasingly important as human activities expand in the Arctic.

Journal of Mammalogy↗

USGS2019

Is the timing, pace and success of the monarch migration associated with sun angle?

A basic question concerning the monarch butterfly’s fall migration is which monarchs succeed in reaching overwintering sites in Mexico, which fail—and why. We document the timing and pace of the fall migration, ask whether the sun’s position in the sky is associated with the pace of the migration, and whether timing affects success in completing the migration. Using data from the Monarch Watch tagging program, we explore whether the fall monarch migration is associated with the daily maximum vertical angle of the sun above the horizon (Sun Angle at Solar Noon, SASN) or whether other processes are more likely to explain the pace of the migration. From 1998 to 2015, more than 1.38 million monarchs were tagged and 13,824 (1%) were recovered in Mexico. The pace of migration was relatively slow early in the migration but increased in late September and declined again later in October as the migrating monarchs approached lower latitudes. This slow-fast-slow pacing in the fall migration is consistent with monarchs reaching latitudes with the same SASN, day after day, as they move south to their overwintering sites. The observed pacing pattern and overall movement rates are also consistent with monarchs migrating at a pace determined by interactions among SASN, temperature, and daylength. The results suggest monarchs successfully reaching the Monarch Butterfly Biosphere Reserve (MBBR) migrate within a “migration window” with an SASN of about 57° at the leading edge of the migration and 46° at the trailing edge. Migrants reaching locations along the migration route with SASN outside this migration window may be considered early or late migrants. We noted several years with low overwintering abundance of monarchs, 2004 and 2011–2014, with high percentages of late migrants. This observation suggests a possible effect of migration timing on population size. The migration window defined by SASN might serve as a framework against which to establish the influence of environmental factors on the size, geographic distribution, and timing of past and future fall migrations.

Frontiers in Ecology and Evolution↗

USGS2021

Fatty acid profiles of feeding and fasting bears: Estimating calibration coefficients, the timeframe of diet estimates, and selective mobilization during hibernation

Accurate information on diet composition is central to understanding and conserving carnivore populations. Quantitative fatty acid signature analysis (QFASA) has emerged as a powerful tool for estimating the diets of predators, but ambiguities remain about the timeframe of QFASA estimates and the need to account for species-specific patterns of metabolism. We conducted a series of feeding experiments with four juvenile male brown bears ( Ursus arctos ) to (1) track the timing of changes in adipose tissue composition and QFASA diet estimates in response to a change in diet and (2) quantify the relationship between consumer and diet FA composition (i.e., determine “calibration coefficients”). Bears were fed three compositionally distinct diets for 90–120 days each. Two marine-based diets were intended to approximate the lipid content and composition of the wild diet of polar bears ( U. maritimus ). Bear adipose tissue composition changed quickly in the direction of the diet and showed evidence of stabilization after 60 days. During hibernation, FA profiles were initially stable but diet estimates after 10 weeks were sensitive to calibration coefficients. Calibration coefficients derived from the marine-based diets were broadly similar to each other and to published values from marine-fed mink ( Mustela vison ), which have been used as a model for free-ranging polar bears. For growing bears on a high-fat diet, the temporal window for QFASA estimates was 30–90 days. Although our results reinforce the importance of accurate calibration, the similarities across taxa and diets suggest it may be feasible to develop a generalized QFASA approach for mammalian carnivores.

Journal of Comparative Physiology B: Biochemical, ↗

USGS2018

In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary

Cassiterite (SnO 2 ), a main ore mineral in tin deposits, is suitable for U–Pb isotopic dating because of its relatively high U/Pb ratios and typically low common Pb. We report a LA-ICPMS analytical procedure for U–Pb dating of this mineral with no need for an independently dated matrix-matched cassiterite standard. LA-ICPMS U-Th-Pb data were acquired while using NIST 612 glass as a primary non-matrix-matched standard. Raw data are reduced using a combination of Iolite™ and other off-line data reduction methods. Cassiterite is extremely difficult to digest, so traditional approaches in LA-ICPMS U-Pb geochronology that utilize well-characterized matrix-matched reference materials (e.g., age values determined by ID-TIMS) cannot be easily implemented. We propose a new approach for in situ LA-ICPMS dating of cassiterite, which benefits from the unique chemistry of cassiterite with extremely low Th concentrations (Th/U ratio of 10 −4 or lower) in some cassiterite samples. Accordingly, it is assumed that 208 Pb measured in cassiterite is mostly of non-radiogenic origin—it was initially incorporated in cassiterite during mineral formation, and can be used as a proxy for common Pb. Using 208 Pb as a common Pb proxy instead of 204 Pb is preferred as 204 Pb is much less abundant and is also compromised by 204 Hg interference during the LA-ICPMS analyses. Our procedure relies on 208 Pb/ 206 Pb vs 207 Pb/ 206 Pb (Pb-Pb) and Tera-Wasserburg 207 Pb/ 206 Pb vs 238 U/ 206 Pb (U-Pb) isochron dates that are calculated for a ~1.54 Ga low-Th cassiterite reference material with varying amounts of common Pb that we assume remained a closed U-Pb system. The difference between the NIST 612 glass normalized biased U-Pb date and the Pb-Pb age of the reference material is used to calculate a correction factor (F) for instrumental U-Pb fractionation. The correction factor (F) is then applied to measured U/Pb ratios and Tera-Wasserburg isochron dates are obtained for the unknown cassiterite analyzed in the same analytical session. This allows for U-Pb dating of cassiterite of any age with no need for an independently dated matrix-matched reference material, nor assumptions about the isotopic composition o f common Pb. Results for cassiterite from tin deposits in Bolivia, Brazil, China, Russia, Saudi Arabia, South Africa, Spain, and the United Kingdom, with ages ranging from ~20 Ma to ~2060 Ma, demonstrate the applicability of this approach across a broad range of geologic time. These ages are in good agreement with published geochronology of the host rocks assoc iated with the tin deposits and with previously published U-Pb ages of some cassiterites from the same deposits. Thus, our in situ LA-ICPMS methodology verifies the use of cassiterite as a reliable U-Pb mineral-geochronometer with the advantages of fast and relatively low cost in situ analyses with moderate spatial resolution.

Chemical Geology↗

USGS1992

Methodology for rapid assessment of the radon potential of soils

A technique using a small diameter probe and a portable alpha-particle scintillometer for sample collection and analysis has been developed. It is fast, efficient, cost-effective, and can be modified to accommodate a wide spectrum of sampling conditions. When soil-gas sampling for radon is combined with geophysical gamma-ray measurements, pedological characteristics of surficial materials, and geologic knowledge of bedrock, the combination forms a powerful technological basis for estimating radon potential of soils. The method can help provide information on a short time-frame so that local governments, land developers, and builders can take appropriate measures when planning new construction.

Conference Paper↗

USGS1992

Decomposition techniques

Sample decomposition is a fundamental and integral step in the procedure of geochemical analysis. It is often the limiting factor to sample throughput, especially with the recent application of the fast and modern multi-element measurement instrumentation. The complexity of geological materials makes it necessary to choose the sample decomposition technique that is compatible with the specific objective of the analysis. When selecting a decomposition technique, consideration should be given to the chemical and mineralogical characteristics of the sample, elements to be determined, precision and accuracy requirements, sample throughput, technical capability of personnel, and time constraints. This paper addresses these concerns and discusses the attributes and limitations of many techniques of sample decomposition along with examples of their application to geochemical analysis. The chemical properties of reagents as to their function as decomposition agents are also reviewed. The section on acid dissolution techniques addresses the various inorganic acids that are used individually or in combination in both open and closed systems. Fluxes used in sample fusion are discussed. The promising microwave-oven technology and the emerging field of automation are also examined. A section on applications highlights the use of decomposition techniques for the determination of Au, platinum group elements (PGEs), Hg, U, hydride-forming elements, rare earth elements (REEs), and multi-elements in geological materials. Partial dissolution techniques used for geochemical exploration which have been treated in detail elsewhere are not discussed here; nor are fire-assaying for noble metals and decomposition techniques for X-ray fluorescence or nuclear methods be discussed.

Journal of Geochemical Exploration↗

USGS1998

Investigation of anion-exchange and immunoaffinity particle-loaded membranes for the isolation of charged organic analytes from water

Anion-exchange and immunoaffinity particle loaded membranes (PLMs) were investigated as a mechanism for the isolation of charged organic analytes from water. Kinetic properties determined theoretically included dynamic capacity, pressure drop (Δ P ), residence and diffusion times ( T r , T d ), and total membrane porosity (ε T ). These properties were confirmed through experimental evaluation, and the PLM method showed significant improvement over conventional solid-phase extraction (SPE) and ion-exchange formats. Recoveries of more than 90% were observed for a variety of test compounds at flow rates up to 70 mL/min (equipment-limited maximum flow rate). A fast-flow immunoaffinity column was developed using antibodies (Abs) attached to the PLMs. Reproducible recoveries (88% ± 4%) were observed at flow rates up to 70 mL/min for the antibody (Ab)-loaded PLMs. Findings indicate increased selectivity over anion-exchange PLMs and conventional SPE or ion-exchange methods and rapid Ab−antigen binding rates given the excellent mass-transfer characteristics of the PLMs.

Analytical Chemistry↗

USGS2010

Coral Ba/Ca records of sediment input to the fringing reef of the southshore of Moloka'i, Hawai'i over the last several decades

The fringing reef of southern Moloka’i is perceived to be in decline because of land-based pollution. In the absence of historical records of sediment pollution, ratios of coral Ba/Ca were used to test the hypothesis that sedimentation has increased over time. Baseline Ba/Ca ratios co-vary with the abundance of red, terrigenous sediment visible in recent imagery. The highest values at One Ali’i are near one of the muddiest parts of the reef. This co-varies with the lowest growth rate of all the sites, perhaps because the upstream Kawela watershed was historically leveed all the way to the nearshore, providing a fast-path for sediment delivery. Sites adjacent to small, steep watersheds have ∼decadal periodicities whereas sites adjacent to mangrove forests have shorter-period fluctuations that correspond to the periodicity of sediment transport in the nearshore, rather than the watershed. All four sites show a statistically significant upward trend in Ba/Ca.

Hawai'i↗