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Evaluation of a eutrophication Beneficial Use Impairment in the Grand Calumet River Area of Concern in northwest Indiana, 2021–22

Eutrophication has been regularly documented in the Grand Calumet River and Indiana Harbor Canal in northwest Indiana. The area has undergone various remediation efforts since the development of a Remedial Action Plan for the area in response to a 1987 amendment to the Great Lakes Water Quality Agreement of 1978 between the United States and Canada and the designation of the Grand Calumet River Area of Concern by the U.S. Environmental Protection Agency. To address concerns of eutrophication and its effects, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Indiana Department of Environmental Management, collected data from the Grand Calumet River and Indiana Harbor Canal in 2021 and 2022 to document the effects of remediation and combined sewer overflow releases on water quality. This study used continuous monitors to collect real time data for dissolved oxygen, water temperature, chlorophyll fluorescence, specific conductance, and pH. Discrete sample analysis included biological oxygen demand, chemical oxygen demand, nutrients, nitrogen and oxygen isotopes in nitrate, nitrogen isotopes in ammonia, hydrogen and oxygen isotopes in water, and identification of algal communities (cyanobacteria and eukaryotic algae) by metabarcoding. Eutrophic conditions were found throughout the area. Isotopic results indicated the source of nitrate in samples was either from soil organic nitrogen or combined sewer overflows. Combined sewer overflows were shown to have considerable effects on the sites, and remediation status did not have a great effect. Algal community results identified several taxa capable of becoming nuisance species, including Microcystaceae (cyanobacteria) and Chrysophyceae, Cryptophyceae, and Bacillariophyceae (all eukaryotic algae). When sites with irregular flow patterns were excluded from datasets, minimum dissolved oxygen concentrations were often higher downstream from remediated sites than from unremediated sites. This study shows the potential for further and more targeted exploration into the unusual conditions found throughout the Grand Calumet River and Indiana Harbor Canal area.

Indiana

Variability of discharge, nutrients, and Escherichia coli from tile drains in a small agricultural stream, a synoptic study in the School Branch watershed, Hendricks County, Indiana

The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, sampled a 1-mile stream reach of School Branch in Hendricks County, Indiana. Sampling consisted of 24 tile drain sites and surface-water sites both upstream and downstream from the tile drains. This study intended to (1) assess the variability of discharge, nutrients, and Escherichia coli ( E. coli ) among tiles within a stream reach in variable conditions; (2) define how the tiles affect the stream hydrology and water quality; and (3) determine potential management implications. Samples were collected on three dates—round 1 on June 12, 2018, after fertilizer was applied; round 2 on September 11, 2018, in fall harvest conditions; and round 3 on April 16, 2019, before fertilizer was applied—to encompass differing precipitation events, multiple seasons, and field conditions. Sites were sampled for water-quality parameters, dissolved and total nutrients (ammonia, nitrate plus nitrite, total nitrogen, orthophosphate, and total phosphorus), E. coli , and instantaneous discharge. Instantaneous nutrient loads were calculated from tiles and at the upstream and downstream surface-water sites. Nutrient concentrations and instantaneous loads varied depending on the tile and the sampling date. Tiles contributed between 26.5 and 66.0 percent of increased discharge between the surface-water sites. Tiles contributed between 34.7 and 87.4 percent and between 19.7 and 65.9 percent of the increased total nitrogen and phosphorus loads, respectively, for the downstream site relative to the upstream site. Most of the total nitrogen and total phosphorus from the tiles was in the dissolved forms (nitrate plus nitrite and orthophosphate). Surface-water samples had a nitrate plus nitrite to total nitrogen ratio of 71 to 93 percent, with an average of 82 percent; tile samples ranged from 44 to nearly 100 percent, with an average of 91 percent dissolved nitrogen. Surface-water samples had an orthophosphate to total phosphorus ratio of 30 to 65 percent, with an average of 53 percent; tile samples ranged from 32 to nearly 100 percent, with an average of 85 percent dissolved phosphorus. E. coli was detected in all but 5.79 percent of tile and surface-water samples. The E. coli results indicated the possibility of human or animal fecal contamination by way of septic systems leaking or directly linked to the tiles draining into the study area. Consequently, five microbial source tracking samples were collected from the upstream and downstream surface-water sites between August 3, 2021, and May 18, 2022. Human, canine, ruminant, and avian sources of fecal contamination were evaluated. The microbial source tracking samples indicated that human-specific sources are likely consistently contributing to elevated fecal contamination. Differences in discharge, nutrient concentrations, nutrient loads, and E. coli concentrations show that many factors affect how tiles alter the hydrology and water quality of receiving waters. The timing and severity of precipitation events, season, and the antecedent conditions of the field or watershed before sampling can affect the results. Tiles with the largest discharge rate had the most potential effect on the water quality and quantity of the stream. Targeting high-flowing tiles may affect efforts to improve overall water quality.

Indiana

Use of thematic mapper imagery to assess water quality, trophic state, and macrophyte distributions in Massachusetts lakes

During the spring and summer of 1996, 1997, and 1998, measurements of phytoplankton- chlorophyll concentration, Secchi disk transparency, and color were made at 97 Massachusetts lakes within 24 hours of Landsat Thematic Mapper imaging of the lakes in an effort to assess water quality and trophic state. Spatial distributions of floating, emergent, and submerged macrophytes were mapped in 49 of the lakes at least once during the 3-year period. The maps were digitized and used to assign pixels in the thematic mapper images to one of four vegetation cover classes-open water, 1-50 percent floating-and-emergent-vegetation cover, 51-100 percent floating-and-emergent-vegetation cover, and submerged vegetation at any density. The field data were collected by teams of U.S. Geological Survey and Massachusetts Department of Environmental Management staff and by 76 volunteers. Side-by-side sampling by U.S. Geological Survey and volunteer field teams resulted in statistically similar chlorophyll determinations, Secchi disk readings, and temperature measurements, but concurrent color determinations were not similar, possibly due to contamination of sample bottles issued to the volunteers.Attempts to develop predictive relations between phytoplankton-chlorophyll concentration, Secchi disk transparency, lake color, dissolved organic carbon, and various combinations of thematic mapper bands 1, 2, 3, and 4 digital numbers were unsuccessful, primarily because of the extremely low concentrations of chlorophyll in the lakes studied, and also because of the highly variable dissolved organic carbon concentrations.Predictive relations were developed between Secchi disk transparency and phytoplankton-chlorophyll concentration, and between color and dissolved organic carbon concentration. Phytoplankton-chlorophyll concentration was inversely correlated with Secchi disk transparency during all three sampling periods. The relations were very similar in 1996 and 1997 and indicated that 62 to 67 percent of the variability in Secchi disk transparency could be explained by the chlorophyll concentration. Analysis of color and dissolved organic carbon concentrations in water samples collected by U.S. Geological Survey field teams in 1996-98 indicated that 91 percent of the variance in color in Massachusetts lakes can be explained by variations in dissolved organic carbon.Areas of open-water, submerged vegetation, and two surface-vegetation-cover classes predicted from Thematic Mapper images acquired in the summer of 1996 closely matched the areas observed in a set of field observations. However, the same analysis applied to a set of data acquired in the summer of 1997 resulted in somewhat less reliable predictions, and an attempt to predict 1996 vegetation-cover areas using the relations developed in the 1997 analysis was unsuccessful.

Water-Resources Investigations Report

Geohydrology and limnology of Walden Pond, Concord, Massachusetts

The trophic ecology and ground-water contributing area of Walden Pond, in Concord and Lincoln, Mass., were investigated by the U.S. Geological Survey in cooperation with the Massachusetts Department of Environmental Management from April 1997 to July 2000. Bathymetric investigation indicated that Walden Pond (24.88 hectares), a glacial kettle-hole lake with no surface inlet or outlet, has three deep areas. The maximum depth (30.5 meters) essentially was unchanged from measurements made by Henry David Thoreau in 1846. The groundwater contributing area (621,000 square meters) to Walden Pond was determined from water-table contours in areas of stratified glacial deposits and from land-surface contours in areas of bedrock highs. Walden Pond is a flow-through lake: Walden Pond gains water from the aquifer along its eastern perimeter and loses water to the aquifer along its western perimeter. Walden Pond contributing area also includes Goose Pond and its contributing area. A water budget calculated for Walden Pond, expressed as depth of water over the lake surface, indicated that 45 percent of the inflow to the lake was from precipitation (1.215 meters per year) and 55 percent from ground water (1.47 meters per year). The groundwater inflow estimate was based on the average of two different approaches including an isotope mass-balance approach. Evaporation accounted for 26 percent of the outflow from the lake (0.71 meters per year) whereas lake-water seepage to the groundwater system contributed 74 percent of the outflow (1.97 meters per year). The water-residence time of Walden Pond is approximately 5 years. Potential point sources of nutrients to ground water, the Concord municipal landfill and a trailer park, were determined to be outside the Walden Pond groundwater contributing area. A third source, the septic leach field for the Walden Pond State Reservation facilities, was within the groundwater contributing area. Nutrient budgets for the lake indicated that nitrogen inputs (858 kilograms per year) were dominated (30 percent) by plume water from the septic leach field and, possibly, by swimmers (34 percent). Phosphorus inputs (32 kilograms per year) were dominated by atmospheric dry deposition, background ground water, and estimated swimmer inputs. Swimmer inputs may represent more than 50 percent of the phosphorus load during the summer. The septic-system plume did not contribute phosphorus, but increased the nitrogen to phosphorus ratio for inputs from 41 to 59, on an atom-to-atom basis. The ratio of nitrogen to phosphorus in input loads and within the lake indicated algal growth would be strongly phosphorus limited. Nitrogen supply in excess of plant requirements may mitigate against nitrogen fixing organisms including undesirable blooms of cyanobacteria. Based on areal nutrient loading, Walden Pond is a mesotrophic lake. Hypolimnetic oxygen demand of Walden Pond has increased since a profile was measured in 1939. Currently (1999), the entire hypolimnion of Walden Pond becomes devoid of dissolved oxygen before fall turnover in late November; whereas historical data indicated dissolved oxygen likely remained in the hypolimnion during 1939. The complete depletion of dissolved oxygen likely causes release of phosphorus from the sediments. Walden Pond contains a large population of the deep-growing benthic macro alga Nitella, which has been hypothesized to promote water clarity in other clear-water lakes by sequestering nutrients and keeping large areas of the sediment surface oxygenated. Loss of Nitella populations in other lakes has correlated with a decline in water quality. Although the Nitella standing crop is large in Walden Pond, Nitella still appears to be controlled by nutrient availability. Decreasing phosphorus inputs to Walden Pond, by amounts under anthropogenic control would likely contribute to the stability of the Nitella population in the metalimnion, may reverse oxygen depletion in the hypolimnion, and decreas

Water-Resources Investigations Report

Assessment of water-quality conditions in the J.B. Converse Lake watershed, Mobile County, Alabama, 1990-98

J.B. Converse (Converse) Lake is a 3,600-acre, tributary-storage reservoir in Mobile County, southwestern Alabama. The lake serves as the primary drinking-water supply for the city of Mobile. The Converse Lake watershed lies within the Coastal Plain Physiographic Province. Semiconsolidated to unconsolidated sediments of sand, silt, gravel, and clay underlie the watershed, and are covered by acidic soils. Land use in the watershed is mainly forest (64 percent) and agriculture (31 percent). Residential and commercial development account for only 1 percent of the total land use in the watershed. Converse Lake receives inflow from seven major tributaries. The greatest inflows are from Big Creek, Crooked Creek, and Hamilton Creek that had mean annual streamflows of 72.2, 19.4, and 25.0 cubic feet per second, respectively, for the period 1990 to 1998, which represents about 72 percent of the total annual streamflow to the lake. The total mean annual inflow to the lake is estimated to be about 163 cubic feet per second. In general, water quality in Converse Lake and its tributaries meets the criteria established by the Alabama Department of Environmental Management (ADEM) for drinking-water supplies, whole-body contact, and aquatic life. The exceptions include acidic pH levels, iron and manganese levels above secondary or aesthetic criteria, and fecal bacterial levels in some tributaries above whole-body contact (swimmable) criteria. The pH levels throughout the watershed were commonly below the criteria level of 6.0, but this appears to have been a naturally occurring phenomenon caused by poorly buffered soil types, resistant sediments, and forested land use. Median iron and manganese levels were above aesthetic criteria levels of 300 and 50 micrograms per liter, respectively, in some tributaries. All tributary sites in the Converse Lake watershed had median and minimum dissolved-oxygen concentrations above the ADEM criteria level of 5 milligrams per liter except for Boggy Branch, which had a minimum dissolved-oxygen concentration of 3.7 milligrams per liter. The degree to which nutrient contributions from tributaries were causing nutrient enrichment and eutrophication in Converse Lake was assessed. Trend analysis detected little or no change in nutrient concentrations at the tributary and lake sites in the Converse Lake watershed from the 1991 to 1998 water years. Nutrient concentrations at most tributary sites exhibited a significant, positive relation with streamflow that indicated the dominant source of nutrient input to the watershed is from nonpoint contributions. From 1990 to 1998, computed mean annual loads of 75,400 kilograms of total nitrogen, 36,950 kilograms of total Kjeldahl nitrogen, 28,870 kilograms of total inorganic nitrogen, and 3,480 kilograms of total phosphorus were contributed to the lake by Big Creek, Hamilton Creek, and Crooked Creek combined. These mean annual loads of nutrients corresponded to borderline eutrophic/mesotrophic conditions in the lake. Of the combined loads, 62 percent of the total nitrogen, 70 percent of the total Kjeldahl nitrogen, 54 percent of the total inorganic nitrogen, and 47 percent of the total phosphorus originated from the forested subbasin of Big Creek. The more residential and agricultural subbasins of Crooked Creek and Hamilton Creek, however, yielded over twice the total phosphorus load per hectare of land use. Crooked and Hamilton Creek subbasins also had higher yields of the more bioavailable total inorganic nitrogen. A simplistic empirical model could not explain the relation between year-to-year nutrient contributions to Converse Lake from the tributaries and the lake's ability to assimilate those contributions. The potential presence of pathogens in the lake and its tributaries was assessed based on fecal bacterial concentrations. Fecal bacterial concentrations at some tributary sites were above existing criteria for swimmable uses. Contributions of fecal bacte

Water-Resources Investigations Report

Geohydrology and susceptibility of aquifers to surface contamination in Alabama; area 5

The U.S. Geological Survey, in cooperation with the Alabama Department of Environmental Management, is conducting a series of geohydrologic studies to delineate the major aquifers and their susceptibility to contamination in Alabama. This report delineates and describes the geohydrology and susceptibility of the major aquifers to contamination in Area 5--Chambers, Clay, Cleburne, Coosa, Lee, Randolph, and Tallapoosa Counties. Little groundwater is used for public water supplies in Area 5. Groundwater withdrawals for public supply in 1985 were 0.88 million gal/day. Most cities and towns that formerly used groundwater presently use surface water. None of the sedimentary rocks or unconsolidated deposits is tapped by public supply wells. None of the igneous and metamorphic rocks are considered a major aquifer because of low yields. Aquifers in the study area are susceptible to surface contamination throughout their entire outcrop area. Areas that are highly faulted and valley areas where groundwater is at or near land surface have potential to be highly susceptible to surface contamination. (USGS)

Water-Resources Investigations Report

Water resources and aquifer yields in the Charles River basin, Massachusetts

In 1984, about 66 Mgal/d (million gallons per day) of municipally supplied water was used by towns in the middle and upper Charles River basin and by the city of Cambridge in the lower basin. The Division of Water Resources of the Massachusetts Department of Environmental Management estimates that by the year 2020 an additional 11 Mgal/d of water will be needed to meet demands. The largest sources of un used water in the basin are 15 stratified-drift aquifers along the Charles River that are hydraulically con nected to the river and to its major tributaries. These aquifers, which consist mainly of medium to coarse sand and gravel, are generally unconfined, narrow, and discontinuous. They are as much as 100 feet thick, and transmissivity ranges from about 1,000 to 25,000 cubic feet per day per square foot times foot of aquifer thickness. The depth to the water table from the land surface generally is less than 15 feet and the water table fluctuates about 3 to 5 feet annually. Recharge to the aquifers is mostly derived from precipita tion, and the aquifers continuously discharge ground water to streams, ponds, lakes, and wetlands. Aquifer yields from the 15 aquifers under normal climatic conditions were related to the estimated duration of flow of the streams that drain the aquifers. Long-term (180 days or more) aquifer yields that are derived from interception of ground-water discharge range from less than 1 to more than 5 Mgal/d at the streamflow that is exceeded 95 percent of the time. However, because withdrawal may reduce streamflow in the Charles River to unacceptable levels, these yield estimates were adjusted to meet commonly cited minimum-streamflow criteria. For example, if minimum streamflows in the Charles River are maintained at no less than the annual 7-day, 10-year, mean low flow for 95 percent of the time, only three of the 15 aquifers could sustain yields of more than 1 Mgal/d from intercepted ground-water discharge. However, none of the aquifers could yield an appreciable amount of water from this source if streamflows are maintained at no less than this minimum for 99 percent of the time. Yields also are available to wells front water in duced by pumping to infiltrate through a streambed. Yields front induced infiltration from the Charles River were estimated for four aquifers and range from about 4 to 11 Mgal/d at the 95-percent flow duration. If minimum-streamflow criteria are to be maintained, these yield estimates would be substantially lower. A streamflow-accounting model was used to demonstrate the possible streamflow reductions that could result from further development of the water resources of the middle and upper Charles River basin. Results indicate that pumpage of an additional 11 Mgal/d could reduce flow in the river at Waltham by about 6 ft 3 /s (cubic feet per second) (4 Mgal/d) throughout the year--alt amount equal to about 24 percent of the flow that is exceeded 95 percent of the time. Also, model results indicate that increases in punzpage and the export of was-tewater from the basin of 23 Mgal/d would reduce streamflow at Waltham by about 14 ft 3 / s (9 Mgal/d) throughout the year.

Massachusetts

Nonpoint and Point Sources of Nitrogen in Major Watersheds of the United States

Estimates of nonpoint and point sources of nitrogen were made for 107 watersheds located in the U.S. Geological Survey's National Water-Quality Assessment Program study units throughout the conterminous United States. The proportions of nitrogen originating from fertilizer, manure, atmospheric deposition, sewage, and industrial sources were found to vary with climate, hydrologic conditions, land use, population, and physiography. Fertilizer sources of nitrogen are proportionally greater in agricultural areas of the West and the Midwest than in other parts of the Nation. Animal manure contributes large proportions of nitrogen in the South and parts of the Northeast. Atmospheric deposition of nitrogen is generally greatest in areas of greatest precipitation, such as the Northeast. Point sources (sewage and industrial) generally are predominant in watersheds near cities, where they may account for large proportions of the nitrogen in streams. The transport of nitrogen in streams increases as amounts of precipitation and runoff increase and is greatest in the Northeastern United States. Because no single nonpoint nitrogen source is dominant everywhere, approaches to control nitrogen must vary throughout the Nation. Watershed-based approaches to understanding nonpoint and point sources of contamination, as used by the National Water-Quality Assessment Program, will aid water-quality and environmental managers to devise methods to reduce nitrogen pollution.

Water-Resources Investigations Report

Estimated availability of water from stratified-drift aquifers in the Concord River Basin, Massachusetts

An understanding of water availability in the Concord River Basin for public and private supply requires an understanding of the interaction between surface-water and ground-water systems. This understanding is needed because excessive ground-water withdrawals may reduce streamflows to unacceptable levels. The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Management, Office of Water Resources, studied the Concord River Basin to estimate the volume of water available from stratified-drift aquifers. A combined hydrograph-separation and streamflow-duration-curve analysis indicates that 20.8 million cubic feet of water could be withdrawn from the stratified-drift aquifer above the South Acton streamflow-gaging station during a 102-day period of no recharge before streamflow would be reduced to a prescribed minimum level. This volume, which equals 2.85 million cubic feet per square mile of stratified drift, was used to estimate volume of available water in 17 aquifer areas in the Concord River Basin. The total volume of available water in the Concord River Basin is estimated to be 561 million cubic feet. Finite-difference ground-water-flow models for the River Meadow Brook aquifer area and the Sudbury and Concord aquifer area quantified the current and potential water availability. The results of three withdrawal simulations for each aquifer area indicate that the 1989 ground-water withdrawal rates would not exceed the volume of water that would be available during a 102-day period of no recharge if water-table drawdowns were not considered. However, results do indicate that volumes of withdrawn water would exceed the available water in the two aquifer areas if maximum lowering of the water table as a percentage of total saturated thickness were 10 and 65 percent at existing and hypothetical wells.

Massachusetts

Streamflow, ground-water recharge and discharge, and characteristics of surficial deposits in Buzzards Bay Basin, southeastern Massachusetts

Streamflow measurements at 14 low-flow partial-record stations and two discontinued streamflow-gaging stations were related to concurrent streamflows at six long-term streamflow-gaging stations to estimate streamflows at selected flow durations from 50 to 99 percent for water years 1967-91. At low flows, stream discharge per square mile generally increased with increasing percentage of subbasin underlain by stratified-drift deposits. At the 70-, 90-, and 99-percent flow durations, subbasins underlain primarily by stratified-drift deposits had stream discharges per square mile at least 2, 4, and 8 times greater, respectively, than subbasins underlain primarily by till and bedrock deposits. Streamflow measured three times at the Paskamanset River showed that streamflows downstream of municipal pumped wells increased at a lower rate per unit drainage area than streamflows upstream of the pumped wells. When pumpage from wells near the river was added to measured streamflow at the most downstream station, the sum was similar to the potential streamflow at the station if its streamflow per unit area was the same as that upstream from the pumped wells. Mean ground-water recharge and discharge rates were computed from continuous records of daily mean discharge during water years 1967-91 for six streamflow-gaging stations in southeastern Massachusetts and Rhode Island. Estimates of mean ground-water recharge were 19.7 to 22.6 inches per year for stations with drainage areas primarily underlain by till and bedrock deposits, and 23.8 to 25.2 inches per year for stations with drainage areas primarily underlain by stratified-drift deposits. During drought years, annual ground-water recharge can be less than 50 percent of the mean ground-water recharge rate for water years 1967-91. Estimates of ground-water discharge rates generally were 1 to 4 inches per year less than estimates of ground-water recharge rates. Ground-water discharge-duration curves were calculated from hydrograph separation of streamflow records at the six continuous streamflow-gaging stations for water years 1967-91. When streamflows were less than the median streamflow (50-percent duration), ground-water discharges averaged 85.7 percent of the total streamflow at the six streamflow-gaging stations. Ground-water discharges were estimated at the 14 low-flow partial-record stations and two discontinued streamflow-gaging stations by multiplying streamflows at the selected flow durations from 50 to 99 percent for water years 1967-91 by 85.7 percent. Data on surficial deposits in the basin were obtained by drilling 10 wells, by conducting 12 seismic-refraction surveys, and by collecting well log data for 313 wells from consulting firms and the Massachusetts Department of Environmental Management. These data indicated that a few minor corrections could be made to existing saturated thickness maps for stratified-drift deposits in Buzzards Bay Basin. Few well logs were detailed enough to estimate transmissivities; thus existing transmissivity maps were not updated for stratified-drift deposits in the basin.

Massachusetts

Water-quality assessment of the White River Basin, Indiana: Analysis of selected information on nutrients, 1980-92

Water-quality data from 23 surfacewater-quality monitoring sites operated by the Indiana Department of Environmental Management and streamflow data from 11 U.S. Geological Survey streamflow-gaging stations in the White River Basin were analyzed to determine recent (1981 90 water years) water-quality conditions, trends, and river loads for ammonia, nitrate, total nitrogen, and total phosphorus. The White River Basin drains 11,349 square miles of central and south-central Indiana and is divided into two nearly equal subbasins the East Fork White River and the White River upstream from its confluence with the East Fork (called the "west fork" of the White River by the State's water-management agencies). Nutrient concentrations generally were higher in the more urbanized west fork than in the more rural east fork because of the much larger volumes of treated municipal sewage, combined-sewer overflows, and urban runoff discharged to the west fork. Concentrations of nutrients, especially ammonia and total phosphorus, were higher downstream from Muncie, Anderson, and Indianapolis than they were upstream from these cities. Nutrient concentrations decreased downstream from Indianapolis in the White River and in the downstream reach of the East Fork White River because of dilution, nitrification, adsorption to stream-bottom sediments, and uptake by aquatic vegetation. Seasonal variations in nutrient concentrations and the relations of nutrient concentrations to streamflow depended on the relative contributions of point and nonpoint sources of the nutrients. Total phosphorus increased with increasing streamflow at monitoring sites on the east fork but decreased with increasing streamflow at sites on the west fork. Increasing concentrations of phosphorus with increasing streamflow were consistent with nonpoint sources of phosphorus that wash off land surfaces, whereas decreasing concentrations of phosphorus with increasing streamflow were consistent with dilution of point sources of phosphorus. Median concentrations of total phosphorus were highest during summer and fall downstream from urban areas on the White River because streamflows that dilute point sources of phosphorus are lowest during summer and fall. Median concentrations of ammonia in the White River were highest in winter because of reduced biological uptake and nitrification of ammonia during cold temperatures.

Indiana

Hydrology and geochemistry of a slag-affected aquifer and chemical characteristics of slag-affected ground water, northwestern Indiana and northeastern Illinois

Slag is a by-product of steel manufacturing and a ubiquitous fill material in northwestern Indiana. Ground water associated with slag deposits generally is characterized by high pH and elevated concentrations of many inorganic water-quality constituents. The U.S. Geological Survey, in cooperation with the Indiana Department of Environmental Management, conducted a study in northwestern Indiana from June 1995 to September 1996 to improve understanding of the effects of slag deposits on the water quality of a glacial-outwash aquifer. The Bairstow Landfill, a slag-fill deposit overlying the Calumet aquifer near Hammond, Indiana, was studied to represent conditions in slag-deposit settings that are common in northwestern Indiana. Ground water from 10 observation wells, located in four nests at the site, and surface water from the adjacent Lake George were analyzed for values of field-measured parameters and concentrations of major ions, nutrients, trace elements, and bulk properties. Solid-phase samples of slag and aquifer sediment collected during drilling were examined with X-ray diffraction and geochemical digestion and analysis. Concentrations of calcium, potassium, sodium, and sulfate were highest in wells screened partly or fully in slag. Potassium concentrations in ground water ranged from 2.9 to 120 milligrams per liter (mg/L), were highest in water from slag deposits, and decreased with depth. The highest concentrations for aluminum, barium, molybdenum, nickel, and selenium were in water from the slag. Silica concentrations were highest in wells screened directly beneath the slag-aquifer interface, and magnesium concentrations were highest in intermediate and deep aquifer wells. Silica concentrations in shallow and intermediate aquifer wells ranged from 27 to 41 mg/L and were about 10 times greater than those in water from slag deposits. The highest concentrations for chromium, lead, and zinc were in ground water from immediately below the slag-aquifer interface. The solid-phase analyses indicated that calcite, dolomite, and quartz generally were present throughout the slag-aquifer system; barian celestite, cristobalite, manganese-bearing calcite, and minrecordite were present in fewer samples. Trace elements that are liberated from the slag may be incorporated as impurities during precipitation of major minerals, sorbed onto clays and other grainsize fractions not analyzed as part of this study, or present in low-abundance minerals that were not detected by the X-ray analysis. Mass-balance and speciation programs were used to identify geochemical processes that may be occurring as water infiltrates through the slag, flows into the aquifer, and discharges into Lake George. The geochemical models indicate that precipitation of calcite may be occurring where slag-affected water enters the aquifer. Models also indicate that dolomite precipitation and clay-mineral dissolution may be occurring at the slag-aquifer interface; however, dolomite precipitation is generally believed to require geologically long time periods. Silica may be dissolving where slag-affected ground water enters the aquifer and may be precipitating where slag-affected ground water discharges to the lakebed of Lake George. In addition to the site-specific study, a statistical analysis of regional water quality was done to compare ground water in wells affected and unaffected by slag. When com-pared to wells in background locations in the Calumet aquifer, wells screened in slag across northwestern Indiana and northeastern Illinois generally had relatively higher pH and specific-conductance values and relatively higher concentrations of alkalinity, dissolved solids, suspended solids, total organic carbon, calcium, potassium, sodium, chloride, aluminum, barium, and possibly magnesium, sulfate, chromium, cobalt, copper, cyanide, manganese, mercury, nickel, and vanadium. When compared to wells in slag and wells in background locations, ground water from immediately beneath or immediately downgradient from slag had relatively high concentrations of arsenic and silica. Water-quality characteristics in ground water at the Bairstow Landfill were similar to water-quality characteristics in slag-contact and slag-affected wells throughout northwestern Indiana.

Illinois, Indiana

Streamflow, water-quality, and biological conditions in the Big Black Creek basin, St. Clair County, Alabama, 1997

In 1997 synoptic streamflow, water-quality, and biological investi- gations in the Big Black Creek Basin were conducted by the U.S. Geological Survey in cooperation with the City of Moody, St. Clair County, and the Birmingham Water Works Board. Data obtained during these synoptic investigations provide a one-time look at the streamflow and water-quality conditions in the Big Black Creek Basin during a stable, base-flow period when streamflow originated only from ground-water discharge. These data were used to assess the degree of water-quality degradation in the Big Black Creek Basin from land-use activities in the basin, including leakage of leachate from the Acmar Regional Land- fill. Biological data from the benthic invertebrate community investigation provided an assessment of the cumulative effects of stream conditions on organisms in the basin. The synoptic measurement of streamflow at 28 sites was made during a period of baseflow on August 27, 1997. Two stream reaches above the landfill lost water to the ground-water system, but those below the landfill had significantly higher ground-water gains. If significant leakage of leachate from the landfill had occurred during the measurement period, the distribution of ground-water discharge suggests that leachate would travel relatively short distances before resurfacing as ground-water discharge to the stream. Benthic invertebrate communities were sampled at four sites in the Big Black Creek Basin during July 16-17, 1997. Based on Alabama Department of Environmental Management criteria and on comparison with a nearby unimparied reference site, the benthic invertebrate communities at the sites sampled were considered unimpaired or only slightly impaired during the sample period. This would imply that landfill and coal-mining activities did not have a detrimental effect on the benthic invertebrate communities at the time of the study. Synoptic water-column samples were collected at nine sites on Big Black Creek and its tributaries at the same time that the synoptic streamflow measurements were made. Trace-element and organic compound concentrations in the stream water were below established water-quality standards and criteria for the State of Alabama, with the exception of secondary (aesthetic) drinking-water levels for iron and manganese. Oil and grease concentrations detected in bed sediments were below the corrective action limit of 100 milligrams per kilogram. No significant increases in chloride, specific conductance, total dissolved solids, oil and grease, color, or biochemical oxygen demand were observed at sites downgradient from the landfill. Ground-water samples were collected from three drive-point wells in the vicinity of the landfill. These samples were analyzed for a suite of volatile organic compounds. The solvent 1,1-dichloroethane (the same solvent detected in the ground-water monitoring system at the landfill) was detected in a sample from a drive-point well downgradient from the landfill--an indication of the potential risk of landfill-derived contamination migrating toward Big Black Creek. No distinguishing trend or pattern of contamination was identified that could be attributed solely to landfill activities. Landfill activities did not appear to contribute significant contamination to Big Black Creek during these streamflow conditions. Any contaminant contribution from coal-mining activities in the basin may have served to mask any leachate contributions from the landfill; however, the overall effects on stream water and benthic intervebrate communities apparently were only minimal.

Water-Resources Investigations Report

Impacts and uncertainties of climate-induced changes in watershed inputs on estuarine hypoxia

Multiple climate-driven stressors, including warming and increased nutrient delivery, are exacerbating hypoxia in coastal marine environments. Within coastal watersheds, environmental managers are particularly interested in climate impacts on terrestrial processes, which may undermine the efficacy of management actions designed to reduce eutrophication and consequent low-oxygen conditions in receiving coastal waters. However, substantial uncertainty accompanies the application of Earth system model (ESM) projections to a regional modeling framework when quantifying future changes to estuarine hypoxia due to climate change. In this study, two downscaling methods are applied to multiple ESMs and used to force two independent watershed models for Chesapeake Bay, a large coastal-plain estuary of the eastern United States. The projected watershed changes are then used to force a coupled 3-D hydrodynamic–biogeochemical estuarine model to project climate impacts on hypoxia, with particular emphasis on projection uncertainties. Results indicate that all three factors (ESM, downscaling method, and watershed model) are found to contribute substantially to the uncertainty associated with future hypoxia, with the choice of ESM being the largest contributor. Overall, in the absence of management actions, there is a high likelihood that climate change impacts on the watershed will expand low-oxygen conditions by 2050 relative to a 1990s baseline period; however, the projected increase in hypoxia is quite small (4 %) because only climate-induced changes in watershed inputs are considered and not those on the estuary itself. Results also demonstrate that the attainment of established nutrient reduction targets will reduce annual hypoxia by about 50 % compared to the 1990s. Given these estimates, it is virtually certain that fully implemented management actions reducing excess nutrient loadings will outweigh hypoxia increases driven by climate-induced changes in terrestrial runoff.

Maryland, Virginia

Multi-temporal surface water mapping with high-resolution elevation and image data through weakly supervised deep learning

Monitoring the extent of surface water features (hydrography), accurately storing them in databases, and representing them on topographic maps are essential for various applications such as navigation and policy-making for legislative boundaries and permitting. In this context, hydrographic data includes features that generally have water present or image data showing signs that water is forming a terrain channel, and which would be included in 1:24,000 or larger scale topographic maps. In addition, reliable hydrographic data play a critical role to help manage environmental risks such as droughts, floods, fires, and landslides, as well as monitoring biological resources and pollutants. Inaccuracies in hydrography data can lead to modelling inaccuracies, resulting in economic, social, and environmental risks. However, generating sufficiently accurate high-resolution (HR) hydrography and terrain data for these purposes remains a substantial challenge primarily because of complex surface water dynamics and data handling limitations.

Alaska

Measuring the impacts of natural amenities and the US-Mexico Border, on housing values in the Santa Cruz Watershed, using spatially-weighted hedonic modeling

Assessing the sustainability of International policy or urban development requires consideration of the impacts of these decisions on Ecosystem Services, or the values that humans receive from the ecosystem, including market-land price, environmental, and human well-being values. Hedonic modeling helps to identify the market land price, considering the price is determined by multiple factors affecting it. In U.S. portions of the bi-national Santa Cruz Watershed (SCW), situated at the Arizona-Sonora International border, natural amenities like the riparian corridor and green space have been documented as positive amenities that boost local real estate. The goal of this research is to isolate the effects of the US-Mexico border and known environmental or natural amenities or disamenities on housing prices in the binational watershed, while controlling for housing stock characteristics and social-environmental vulnerability. In the ultimate analysis, the mean house values within census blocks will be used to represent local housing stock. A human well-being index that measures people’s socio-environmental vulnerability for the entire SCW is in publication that is based on access to infrastructure, number of bedrooms per house and other social data from the binational census and local colonias database will also be compared. The hedonic pricing method will be applied to statistically estimate a function that relates property values to the variables described. This presentation will provide a synopsis of the quality of life and hedonics literature review used to develop this research agenda. Variables relevant for local environmental management, having significant effects on property values, will be discussed. The final results obtained from this study can be used determine the benefits of preserving or developing land binationally and will be uploaded to the Santa Cruz Watershed Ecosystem Portfolio Model (SCWEPM), an online Ecosystem Services tool, being created to promote sustainable development in the Borderlands.

Conference Paper

Freshwater aspects of anadromous salmonid enhancement

Freshwater enhancement of anadromous salmonid populations has been practiced in the United States and Canada since the late 1800's. Reduction of natural spawning habitat and increasing fishing pressure make artificial enhancement a possible alternative to declining populations. Enhancement of anadromous salmonids involved improvement of the natural environment and reducing natural mortality. Methods of enhancement include fishways, spawning and rearing channels, stream rehabilitation, lake fertilization, environmental management, and artificial propagation techniques. Five Pacific salmon species and steelhead trout are commonly enhanced, primarily in watershed entering the Pacific Ocean and Great Lakes. Enhancement efforts contribute heavily to a commercial and sport industry realizing over $1.5 billion.

NOAA Technical Report NMFS Circular

Contaminant distribution and accumulation in the surface sediments of Long Island Sound

The distribution of contaminants in surface sediments has been measured and mapped as part of a U.S. Geological Survey study of the sediment quality and dynamics of Long Island Sound. Surface samples from 219 stations were analyzed for trace (Ag, Ba, Cd, Cr, Cu, Hg, Ni, Pb, V, Zn and Zr) and major (Al, Fe, Mn, Ca, and Ti) elements, grain size, and Clostridium perfringens spores. Principal Components Analysis was used to identify metals that may covary as a function of common sources or geochemistry. The metallic elements generally have higher concentrations in fine-grained deposits, and their transport and depositional patterns mimic those of small particles. Fine-grained particles are remobilized and transported from areas of high bottom energy and deposited in less dynamic regions of the Sound. Metal concentrations in bottom sediments are high in the western part of the Sound and low in the bottom-scoured regions of the eastern Sound. The sediment chemistry was compared to model results (Signell et al., 1998) and maps of sedimentary environments (Knebel et al., 1999) to better understand the processes responsible for contaminant distribution across the Sound. Metal concentrations were normalized to grain-size and the resulting ratios are uniform in the depositional basins of the Sound and show residual signals in the eastern end as well as in some local areas. The preferential transport of fine-grained material from regions of high bottom stress is probably the dominant factor controlling the metal concentrations in different regions of Long Island Sound. This physical redistribution has implications for environmental management in the region.

Long Island Sound