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At least 199 records · Page 11Linked to original sources

Summer-time use of west coast U. S. National Marine Sanctuaries by migrating sooty shearwaters ( Puffinus griseus )

Non-breeding sooty shearwaters are the most abundant seabird in the California Current Large Marine Ecosystem (CCLME) during boreal spring and summer months. This, combined with relatively great energy demands, reliance on patchy, shoaling prey (krill, squid, and forage fishes), and unconstrained mobility free from central-place-foraging demands—make shearwaters useful indicators of ecosystem variability. During 2008 and 2009, we used satellite telemetry to evaluate shearwater ranging patterns throughout the CCLME and specifically within the US Exclusive Economic Zone (EEZ) among birds captured at three locations: Columbia River Plume, WA; Monterey Bay, CA; and Santa Barbara Channel, CA. Shearwaters ranged throughout the entire CCLME from southeast Alaska to southern Baja California, Mexico. Within the EEZ during 2008 and 2009, shearwaters spent 68% and 46% of time over the shelf (<200 m), 27% and 43% of time over the slope (200–1000 m), and 5% and 11% of time over the continental rise and abyssal regions (>1000 m), respectively. In 2008 and 2009, shearwaters spent 22% and 25% of their time in the EEZ within the five west coast National Marine Sanctuaries, respectively; high utilization occurred in non-sanctuary waters of the EEZ. Shearwater utilization distribution (based on the Brownianbridge movement model) among sanctuaries was disproportionate according to sanctuary availability (based on area) within the EEZ. Shearwaters utilized the Monterey Bay sanctuary (2008, 2009) and the Channel Islands sanctuary (2009) disproportionately more than other sanctuaries. Although all five sanctuaries were used by shearwaters, waters outside sanctuary zones appeared significantly more important and likely supported large aggregations of shearwaters. Utilization distributions among individual birds from three discrete capture locations were variable and revealed greater similarity in space-use sharing within capture-location groupings and during 2008 when shearwaters were more aggregated than in 2009. We identified several regional ‘‘habitat hotspot’’ areas, including the Columbia River Plume, Cape Blanco, Monterey Bay, Estero/San Luis Obispo Bays, and the eastern Santa Barbara Channel through the inner Southern California Bight.

California;Washington

Advances and opportunities in assessing contaminant sensitivity of freshwater mussel (unionidae) early life stages

Freshwater mussels (family Unionidae, also referred to as freshwater pearly mussels, unionids, or naiades) are one of North America&rsquo;s most endangered faunal groups. Near unanimity exists in characterizations of the imperilment of these ecologically, economically, and culturally important bivalve mollusks. Freshwater mussels are a renewable resource supporting a shell industry in the United States valued at $40&ndash;50 million annually [1]. In addition to being a food source for aquatic and terrestrial vertebrates, this diverse fauna helps stabilize sediment [2] and provides critical nutrient and energy cycling in streams and lakes by filtering phytoplankton, bacteria, and particulate organic matter from the water column [3]. Thirty-five species of freshwater mussels are extinct [4], 70 species are listed as threatened or endangered under the U.S. Endangered Species Act (www.fws.gov/endangered/wildlife.html), and nearly 180 species are identified as critically imperiled or vulnerable (www.natureserve.org/explorer). Declines in freshwater mussels are not unique to North America [5], but because the taxon reaches its greatest richness here, impacts are especially noteworthy.

Environmental Toxicology and Chemistry

Geologic framework for the national assessment of carbon dioxide storage resources: Greater Green River Basin, Wyoming, Colorado, and Utah, and Wyoming-Idaho-Utah Thrust Belt

The 2007 Energy Independence and Security Act (Public Law 110&ndash;140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used by the USGS for the national CO2 assessment follows up on previous USGS work. The methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of 14 storage assessment units (SAUs) in Ordovician to Upper Cretaceous sedimentary rocks within the Greater Green River Basin (GGRB) of Wyoming, Colorado, and Utah, and eight SAUs in Ordovician to Upper Cretaceous sedimentary rocks within the Wyoming-Idaho-Utah Thrust Belt (WIUTB). The GGRB and WIUTB are contiguous with nearly identical geologic units; however, the GGRB is larger in size, whereas the WIUTB is more structurally complex. This report focuses on the characteristics, specified in the methodology, that influence the potential CO2 storage resource in the SAUs. Specific descriptions of the SAU boundaries, as well as their sealing and reservoir units, are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are typically provided to illustrate geologic factors critical to the assessment. This geologic information was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU. Figures in this report show SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one square mile and are derived from interpretations of variably attributed well data and a digital compilation that is known not to include all drilling.

Colorado, Idaho, Utah, Wyoming

Science mission requirements for a globally ranging, riserless drilling vessel for U.S. Scientific Ocean Drilling

Through the collection and analysis of shallow and deep subseafloor sediments, rocks, fluids, and life, scientific ocean drilling has enriched our understanding of the complex Earth system. Among other achievements, scientific ocean drilling has documented the history of Earth’s climate, the waxing and waning of polar ice sheets, the past changes in ocean and atmospheric circulation, the existence and function of microbial life in the subseafloor, the compositional variations in Earth’s crust and underlying mantle, and the physical and chemical processes acting at subduction zones, including those associated with tsunamigenic earthquakes. Over the decades, more than 12,000 articles that depend on analyses of scientific ocean drilling samples and geophysical data have been published, many detailing breakthrough contributions to global knowledge about the Earth system. Approximately 45% of these publications were led by U.S.-affiliated authors (International Ocean Discovery Program Publication Services, 2021). Since the mid-1980s, the workhorse of this multidisciplinary, international research effort has been the riserless D/V JOIDES Resolution, operated by Texas A&M University with funding from the U.S. National Science Foundation (NSF). D/V JOIDES Resolution has conducted the vast majority of scientific ocean drilling expeditions and collected most of the scientific cores over that period, including 82% of the expeditions and 93% of the cores in the last decade alone, despite being one of three platforms that is operated within the International Ocean Discovery Program. However, D/V JOIDES Resolution is approaching the end of its useful life. With a strong commitment to continue scientific ocean drilling beyond the end of the current phase, the community developed a document outlining the research frontiers that should be pursued. Exploring Earth by Scientific Ocean Drilling: 2050 Science Framework (Koppers and Coggon, 2020) describes seven scientific strategic objectives that focus on understanding interconnections within the Earth system and five flagship initiatives that integrate these objectives into long-term research efforts that address issues facing society. Additional elements in the 2050 Science Framework, including STEM education, workforce development, technology development, and innovative applications of data analytics, will advance the goals of scientific ocean drilling. Addressing the 2050 Science Framework also requires building partnerships with allied U.S. and international science programs and strengthening existing ones. To implement a significant portion of the 2050 Science Framework, the U.S. scientific community seeks to lease or acquire a newly built, globally ranging, state-of-the art, riserless drilling vessel. The many and varied technical and human resources requirements for successful accomplishment of scientific and educational goals summarized in this document and described in detail in the 2050 Science Framework require broad community input and careful consideration. Following receipt of NSF’s formal Request for Assistance to the United States Science Support Program (USSSP), the U.S. scientific ocean drilling community conducted a one-year exercise to identify its national scientific needs and priorities in order to determine the Science Mission Requirements (SMRs) presented here. This community effort included: (1) a U.S. community-wide survey to identify the specific operational and technical capabilities critical to addressing science in the 2050 Science Framework; (2) a series of online workshops focusing on critical capabilities identified by the survey; and (3) a large in-person workshop to synthesize the results of the survey and the virtual workshops (Appendix 1). The approach was designed to reach as many participants as possible. Overall, 278 survey responses were received from U.S. community members, representing 104 unique institutions from 39 states and the District of Columbia, and 137 unique individuals participated in the workshops (Appendix 2). The results of this effort comprise two classes of SMRs: Foundational Science Mission Requirements and Primary Science Mission Requirements. Foundational SMRs define minimum criteria for a new riserless drilling vessel that can address significant portions of the 2050 Science Framework. Primary SMRs build upon the Foundational SMRs and will create more robust science opportunities and data collection capabilities, will increase progress in addressing the 2050 Science Framework objectives, and will provide more real-time ship-to-shore interaction to improve science productivity, engagement, and outreach. Modern safety and environmental standards, including meeting standards to access protected waters such as exclusive economic zones, extended continental shelves, or high latitudes, while being cognizant of the vessel’s environmental footprint. Safe and efficient operations in global locations and in water depths from 70 m to 6000+ m, with total drill string length of at least 7000 m. High-quality core and data collection from a range of key subseafloor environments. Advanced heave compensation, dynamic positioning, and drill pipe stability. Modern mud and cement/casing systems. Critical onboard measurements for safety, operational decision-making, documentation of ephemeral properties, mission-specific science, and long-term science goals that extend beyond a single expedition. Designated and appropriate space for sample and data preservation. Highly skilled onboard personnel, including technical staff for curation and core handling; support for safety, time-sensitive, and critical shipboard measurements; computer support; equipment and instrument repair; application support; and data assurance. Primary Science Mission Requirements include: Flexible shipboard space for laboratories and on deck to ensure safe, successful implementation of diverse science objectives and operations. Minimizing contamination of recovered samples. Over-the-side capabilities for science-supporting technology (e.g., remotely operated vehicles, water- column sampling, sediment-water interface sampling). Downhole logging and measurements. Expanded borehole observatory capabilities. Reliable and consistent ship-to-shore communications. NSF’s investment in a new globally ranging, riserless drilling vessel will have a powerful economic multiplier effect, including the infusion of additional science support funds in the United States for training and research, the development of new technologies and tools, and the associated scientific and technical workforce development. The skills and knowledge gained through scientific ocean drilling are translatable to careers in fields such as sustainable energy development (e.g., geothermal and offshore wind), carbon sequestration, data management and cyberinfrastructure, biotechnology, communications, science education, policy, hazard mitigation, and environmental management. The United States is a leader in a well-established and internationally collaborative scientific ocean drilling community. A modern, globally ranging, riserless drilling vessel will allow the United States to expand its leadership position, address broad scientific questions that current capabilities preclude, and cultivate equitable international, multidisciplinary collaborations that will ensure scientific ocean drilling’s future success.

Report

Developing a set of indicators to identify, monitor, and track impacts and change in forests of the United States

United States forestland is an important ecosystem type, land cover, land use, and economic resource that is facing several drivers of change including climatic. Because of its significance, forestland was identified through the National Climate Assessment (NCA) as a key sector and system of concern to be included in a system of climate indicators as part of a sustained assessment effort. Here, we describe 11 informative core indicators of forests and climate change impacts with metrics available or nearly available for use in the NCA efforts. The recommended indicators are based on a comprehensive conceptual model which recognizes forests as a land use, an ecosystem, and an economic sector. The indicators cover major forest attributes such as extent, structural components such as biomass, functions such as growth and productivity, and ecosystem services such as biodiversity and outdoor recreation. Interactions between humans and forests are represented through indicators focused on the wildland-urban interface, cost to mitigate wildfire risk, and energy produced from forest-based biomass. Selected indicators also include drought and disturbance from both wildfires and biotic agents. The forest indicators presented are an initial set that will need further refinement in coordination with other NCA indicator teams. Our effort ideally will initiate the collection of critical measurements and observations and lead to additional research on forest-climate indicators.

Climatic Change

Cadmium isotope fractionation during coal combustion: Insights from two U.S. coal-fired power plants

Coal combustion, one of the principal energy sources of electricity in the United States, produces over 100 million tons of coal combustion products (CCPs) per year in the U.S. The reuse and disposal of CCPs has the potential to release toxic trace elements, including cadmium (Cd), into the environment. In this study, we investigated CCPs, including bottom ash (BA), economizer fly ash (EFA), and fly ash (FA), as well as feed coal (FC) and pulverized coal (PC) collected from two U.S. coal-fired power plants in New Mexico and Ohio with different coal supplies. The New Mexico plant uses high volatile C bituminous, low-sulfur coals mined from the San Juan Basin (Cretaceous Fruitland Formation) and the Ohio plant uses high volatile A bituminous, high-sulfur central Appalachian Basin coals (Upper Pennsylvanian Monongahela Formation). Mineralogical and elemental analysis showed that these CCP samples consist of ∼70% amorphous Al-Si-rich glasses and ∼30% mineral phases of quartz (SiO 2 ) and mullite (Ai 6 Si 2 O 13 ). The Cd isotope compositions (δ 114 Cd, normalized to NIST Cd standard 3108) of FA and EFA samples (ranging from −0.51 to +0.47‰) are distinctively heavier than those of BA samples (−0.75 to −0.52‰) in both power plants. We interpret this Cd isotope difference as a result of Cd condensation from the gas phase during flue gas cooling, instead of evaporation of Cd phase during coal combustion. Cd condensation is the main process to generate the isotopically heavy Cd signatures that preferentially partition on the fine FA particles. We also investigated Cd isotope compositions in different leachate products from a series of batch-leaching experiments with these CCPs, using diluted acetic acid, hydroxyl ammonium chloride, hydrogen peroxide followed by ammonium acetate, and 5% nitric acid, as a possible means to identify CCP-released Cd in the environment. Unusually and significantly heavier Cd isotope compositions were observed in each leachate of FA samples (+1.10 to +7.09‰), which fall far outside from the range of Cd isotope ratios observed in natural soils and rocks, but less so for the EFA samples (−0.43 to +1.18‰). Such an observation is consistent with the interpretation that isotopically heavy Cd preferentially partitions on the fine FA particles after coal combustion and is readily to be released during these leaching experiments. This study demonstrates that high-temperature coal combustion can lead to a very large degree of fractionation of Cd isotopes that can be used as a unique tracer for identifying anthropogenic metal inputs in the environment. The major Cd isotope fractionation process occurs as the Cd gas phase condenses on fine FA particles during the flue gas cooling stage after coal combustion.

New Mexico, Ohio

Geologic framework for the national assessment of carbon dioxide storage resources: Columbia Basin of Oregon, Washington, and Idaho, and the Western Oregon-Washington basins

The 2007 Energy Independence and Security Act (Public Law 110&ndash;140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO 2 ). The methodology used by the USGS for the national CO 2 assessment follows that of previous USGS work. The methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of three storage assessment units (SAUs) in Eocene and Oligocene sedimentary rocks within the Columbia, Puget, Willapa, Astoria, Nehalem, and Willamette Basins of Oregon, Washington, and Idaho, and focuses on the characteristics, specified in the methodology, that influence the potential CO 2 storage resource in those SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are provided to illustrate geologic factors critical to the assessment. The designated sealing unit in the Columbia Basin is tentatively chosen to be the ubiquitous and thick Miocene Columbia River Basalt Group. As a result of uncertainties regarding the seal integrity of the Columbia River Basalt Group, the SAUs were not quantitatively assessed. Figures in this report show SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one square mile and are derived from interpretations of incompletely attributed well data, a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on the cell maps.

Idaho, Oregon, Washington

Geologic framework for the national assessment of carbon dioxide storage resources: Arkoma Basin, Kansas Basins, and Midcontinent Rift Basin study areas

2007 Energy Independence and Security Act (Public Law 110&ndash;140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO 2 ). The methodology used by the USGS for the national CO 2 assessment follows that of previous USGS work. This methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of three storage assessment units (SAUs) in Upper Cambrian to Mississippian sedimentary rocks within the Arkoma Basin study area, and two SAUs in Upper Cambrian to Mississippian sedimentary rocks within the Kansas Basins study area. The Arkoma Basin and Kansas Basins are adjacent with very similar geologic units; although the Kansas Basins area is larger, the Arkoma Basin is more structurally complex. The report focuses on the characteristics, specified in the methodology, that influence the potential CO 2 storage resource in the SAUs. Specific descriptions of the SAU boundaries as well as their sealing and reservoir units are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are usually provided to illustrate geologic factors critical to the assessment. Although assessment results are not contained in this report, the geologic information herein was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU. The Midcontinent Rift Basin study area was not assessed, because no suitable storage formations meeting our size, depth, reservoir quality, and regional seal guidelines were found. Figures in this report show study area boundaries along with the SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one-square mile and are derived from interpretations of incompletely attributed well data and from a digital compilation that is known not to include all drilling. The USGS does not expect to know the location of all wells and cannot guarantee the amount of drilling through specific formations in any given cell shown on the cell maps.

Arkansas;Louisiana;Oklahoma;Texas

A geologic and anthropogenic journey from the Precambrian to the new energy economy through the San Juan volcanic field

The San Juan volcanic field comprises 25,000 km 2 of intermediate composition mid-Tertiary volcanic rocks and dacitic to rhyolitic calderas including the San Juan&ndash;Uncompahgre and La Garita caldera-forming super-volcanoes. The region is famous for the geological, ecological, hydrological, archeological, and climatological diversity. These characteristics supported ancestral Puebloan populations. The area is also important for its mineral wealth that once fueled local economic vitality. Today, mitigating and/or investigating the impacts of mining and establishing the region as a climate base station are the focuses of ongoing research. Studies include advanced water treatment, the acid neutralizing capacity (ANC) of propylitic bedrock for use in mine-lands cleanup, and the use of soil amendments including biochar from beetle-kill pines. Biochar aids soil productivity and revegetation by incorporation into soils to improve moisture retention, reduce erosion, and support the natural terrestrial carbon sequestration (NTS) potential of volcanic soils to help offset atmospheric CO 2 emissions. This field trip will examine the volcano-tectonic and cultural history of the San Juan volcanic field as well as its geologic structures, economic mineral deposits and impacts, recent mitigation measures, and associated climate research. Field trip stops will include a visit to (1) the Summitville Superfund site to explore quartz alunite-Au mineralization, and associated alteration and new water-quality mitigation strategies; (2) the historic Creede epithermal-polymetallic&ndash;vein district with remarkably preserved resurgent calderas, keystone-graben, and moat sediments; (3) the historic mining town of Silverton located in the nested San Juan&ndash;Silverton caldera complex that exhibits base-metal Au-Ag mineralization; and (4) the site of ANC and NTS studies. En route back to Denver, we will traverse Grand Mesa, a high NTS area with Neogene basalt-derived soils and will enjoy a soak in the geothermal waters of the Aspen anomaly at Glenwood Springs.

Colorado

Projected gains and losses of wildlife habitat from bioenergy-induced landscape change

Domestic and foreign renewable energy targets and financial incentives have increased demand for woody biomass and bioenergy in the southeastern United States. This demand is expected to be met through purpose-grown agricultural bioenergy crops, short-rotation tree plantations, thinning and harvest of planted and natural forests, and forest harvest residues. With results from a forest economics model, spatially explicit state-and-transition simulation models, and species–habitat models, we projected change in habitat amount for 16 wildlife species caused by meeting a renewable fuel target and expected demand for wood pellets in North Carolina, USA. We projected changes over 40 years under a baseline ‘business-as-usual’ scenario without bioenergy production and five scenarios with unique feedstock portfolios. Bioenergy demand had potential to influence trends in habitat availability for some species in our study area. We found variation in impacts among species, and no scenario was the ‘best’ or ‘worst’ across all species. Our models projected that shrub-associated species would gain habitat under some scenarios because of increases in the amount of regenerating forests on the landscape, while species restricted to mature forests would lose habitat. Some forest species could also lose habitat from the conversion of forests on marginal soils to purpose-grown feedstocks. The conversion of agricultural lands on marginal soils to purpose-grown feedstocks increased habitat losses for one species with strong associations with pasture, which is being lost to urbanization in our study region. Our results indicate that landscape-scale impacts on wildlife habitat will vary among species and depend upon the bioenergy feedstock portfolio. Therefore, decisions about bioenergy and wildlife will likely involve trade-offs among wildlife species, and the choice of focal species is likely to affect the results of landscape-scale assessments. We offer general principals to consider when crafting lists of focal species for bioenergy impact assessments at the landscape scale.

GCB Bioenergy

The 3D Elevation Program—Supporting Michigan’s economy

High-quality elevation data are proving to be a resource of value in addressing many important economic issues in Michigan. The expanding statewide availability of current and accurate high-resolution elevation data can help support agriculture and precision farming, natural resource conservation, flood risk management, and geologic resource assessment and hazard mitigation. Water supply and quality assessment, coastal zone management, infrastructure and construction management, solar potential and other renewable energy programs, and identification of features of interest or concern such as archaeological and historical sites are other notable areas that are supported with accurate, high-resolution elevation data. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Michigan

Maps showing gas-hydrate distribution off the east coast of the United States

These maps present the inferred distribution of natural-gas hydrate within the sediments of the eastern United States continental margin (Exclusive Economic Zone) in the offshore region from Georgia to New Jersey (fig. 1). The maps, which were created on the basis of seismic interpretations, represent the first attempt to map volume estimates for gas hydrate. Gas hydrate forms a large reservoir for methane in oceanic sediments. Therefore it potentially may represent a future source of energy and it may influence climate change because methane is a very effective greenhouse gas. Hydrate breakdown probably is a controlling factor for sea-floor landslides, and its presence has significant effect on the acoustic velocity of sea-floor sediments.

East Coast

Energy-related rare earth element sources

Energy-related materials such as coal, coal-bearing wastes, and coal combustion products are traditionally thought of as sources or by-products of electric power generation. Increasingly, these materials are considered resources for their content of rare earth elements (REEs) and other useful constituents. In this chapter, we examine the distribution, modes of occurrence, and relative extractability of REEs from coal-derived materials. We also consider economic factors associated with recovery of REEs from these sources. While several coal-derived sources show promise for REE recovery at the pilot scale, in all cases, REE contents are much below those of primary ores, such that extraction and concentrating the REEs require new and innovative approaches that are largely developmental. Among coal-related sources, fly ash is the most REE-enriched, as REEs from coal are strongly retained in these refractory solids remaining after coal combustion. Partitioning of coal-derived elements into fly ash has been known for decades but this has yet to be commercially exploited. A key drawback shown in this chapter is that a significant fraction of REEs in fly ash is contained in highly insoluble aluminosilicate glasses that make up the largest portion of this material. In addition to testing chemical or physical pretreatment approaches to help improve the extractability of REEs from fly ash, current research is applying modern analytical approaches to better understand the distribution of REEs on increasingly smaller scales, in the interest of targeting their recovery. Next-most REE-enriched among coal-related materials are solid waste products of coal mining and wastes from coal preparation, both of which are REE-enriched relative to coal itself. These waste coals concentrate mineralogical constituents that are excluded during mining or removed during coal preparation because they do not contribute to the heating value of coal for power generation. Recovery of REEs from coal waste has shown promise at the pilot scale and has the added benefit of converting a waste into useful constituents. Total REE contents of commercial coals are, on average, much below the 300 parts per million interest level for REE recovery set by the U.S. Department of Energy (DOE). However, as reviewed in this chapter, certain horizons within coal beds show preferential REE enrichment and could be targeted by selective mining. Beyond this, certain coals are REE-enriched overall due to their unique geologic histories involving derivation from REE-enriched sediment sources, deposition of volcanic ash during coal formation, or interaction of coal with REE-bearing fluids. Acidic drainage from abandoned coal mines is produced by the breakdown of pyrite (FeS 2 ), which is unstable in oxygenated conditions. While these acidic fluids have lower REE contents than any of the coal-based solids described above, they are proportionally enriched in certain heavy rare earths, especially yttrium (Y). Precipitates from coal-based acid-mine drainage concentrate REEs to levels that are of interest for recovery, and these are also promising sources for extraction at the pilot scale.

Book chapter

Temperature-influenced energetics model for migrating waterfowl

Climate and weather affect avian migration by influencing when and where birds fly, the energy costs and risks of flight, and the ability to sense cues necessary for proper navigation. We review the literature of the physiology of avian migration and the influence of climate, specifically temperature, on avian migration dynamics. We use waterfowl as a model guild because of the ready availability of empirical physiological data and their enormous economic value, but our discussion and expectations are broadly generalizable to migratory birds in general. We detail potential consequences of an increasingly warm climate on avian migration, including the possibility of the cessation of migration by some populations and species. Our intent is to lay the groundwork for including temperature effects on energetic gains and losses of migratory birds with the expected consequences of increasing temperatures into a predictive modeling framework. To this end, we provide a simulation of migration progression exclusively focused on the influence of temperature on the physiological determinants of migration. This simulation produced comparable results to empirically derived and observed values for different migratory factors (e.g., body fat content, flight range, departure date). By merging knowledge from the arenas of avian physiology and migratory theory we have identified a clear need for research and have developed hypotheses for a path forward.

Ecological Modelling

Remote sensing-based actual evapotranspiration assessment in a data-scarce area of Brazil: A case study of the Urucuia Aquifer System

The large groundwater reserves of the Urucuia Aquifer System (UAS) enabled agricultural development and economic growth in the western Bahia State, in northeastern Brazil. Over the last several years, concern has grown around the aquifer’s diminishing water levels, and water balance (WB) studies are in demand. Considering the lack of measured actual evapotranspiration (ET a ), a major component of the water cycle, this work uses the Operational Simplified Surface Energy Balance (SSEBop) model to estimate ET a , and compares it to basin-scale estimates from the Soil Moisture Accounting Procedure (SMAP) monthly model and from an annual WB closure method, based on gridded meteorological data and the Gravity Recovery and Climate Experiment (GRACE) product. Additionally, a comparative assessment of different versions of the SSEBop parameterization was performed. Moderate Resolution Imaging Spectroradiometer (MODIS) imagery was used to implement eight different versions of the SSEBop algorithm over the UAS between 2000 and 2013. SSEBop and SMAP ET a yielded similar seasonal patterns, with correlation coefficient (r) up to 0.65, mean difference (MD) of 0.8 mm/month and mean absolute difference (MAD) of 18.5 mm/month. Comparison of SSEBop annual ET a estimates to annual SMAP and WB closure estimates yielded low MD (12.1 and −7.3 mm/year, respectively) and MAD (82.5 and 82.8 mm/year, respectively), but also low r values (0.00 and 0.37, respectively). The comparison of the different SSEBop versions indicated the need to incorporate a calibration step of the aerodynamic heat resistance (r ah ) parameter. SSEBop results were also used for land cover and drought monitoring. Analysis indicates that agriculture, associated with an increasing trend of atmospheric evaporative demand, is responsible for the decrease in groundwater levels and streamflow in the studied time period.

Urucuia Aquifer System

Oblique Aerial Photography of the Arctic Coast of Alaska, Nulavik to Demarcation Point, August 7-10, 2006

The Arctic Coastal Plain of northern Alaska, an area of strategic economic importance to the United States, is home to remote Native American communities and encompasses unique habitats of global significance. Coastal erosion along the Arctic coast is chronic and widespread; recent evidence suggests that erosion rates are among the highest in the world (up to ~16 m/yr) and may be accelerating. Coastal erosion adversely impacts energy-related infrastructure, natural shoreline habitats, and Native American communities. Climate change is thought to be a key component of recent environmental changes in the Arctic. Reduced sea-ice cover in the Arctic Ocean is one of the probable mechanisms responsible for increasing coastal exposure to wave attack and the resulting increase in erosion. Extended periods of permafrost melting and associated decrease in bluff cohesion and stability are another possible source of the increase in erosion. Several studies of selected areas on the Alaska coast document past shoreline positions and coastal change, but none have examined the entire North coast systematically. Results from these studies indicate high rates of coastal retreat that vary spatially along the coast. To address the need for a comprehensive and regionally consistent evaluation of shoreline change along the North coast of Alaska, the U.S. Geological Survey (USGS), as part of their Coastal and Marine Geology Program's (CMGP) National Assessment of Shoreline Change Study, is evaluating shoreline change from Peard Bay to the United States/Canadian border, using historical maps and photography and a standardized methodology that is consistent with other shoreline-change studies along the Nation's coastlines (for example, URL http://coastal.er.usgs.gov/shoreline-change/ (last accessed March 2, 2009). This report contains photographs collected during an aerial-reconnaissance survey conducted in support of this study. An accompanying ESRI ArcGIS shape file (and plain-text copy) indicates the position of the aircraft and time when each photograph was taken. The USGS-CMGP Field Activity ID for the survey is A-1-06-AK, and more information on the survey and how to view the photographs using Google Earth software is available online at: URL http://walrus.wr.usgs.gov/infobank/a/a106ak/html/a-1-06-ak.meta.html (last accessed March 2, 2009).

Data Series

Oblique Aerial Photography of the Arctic Coast of Alaska, Cape Sabine to Milne Point, July 16-19, 2009

The Arctic Coastal Plain of northern Alaska, an area of strategic economic importance to the United States, is home to remote Native American communities and encompasses unique habitats of global significance. Coastal erosion along the Arctic coast is chronic and widespread; recent evidence suggests that erosion rates are among the highest in the world (as high as ~16 m/yr) and may be accelerating. Coastal erosion adversely impacts energy-related infrastructure, natural shoreline habitats, and Native American communities. Climate change is thought to be a key component of recent environmental changes in the Arctic. Reduced sea-ice cover in the Arctic Ocean is one of the probable mechanisms responsible for increasing coastal exposure to wave attack and the resulting increase in erosion. Extended periods of permafrost melting and associated decreases in bluff cohesion and stability are another possible source of the increase in erosion. Several studies of selected areas on the Alaska coast document past shoreline positions and coastal change, but none have examined the entire North coast systematically. Results from these studies indicate high rates of coastal retreat that vary spatially along the coast. To address the need for a comprehensive and regionally consistent evaluation of shoreline change along the North coast of Alaska, the U.S. Geological Survey (USGS), as part of their Coastal and Marine Geology Program's (CMGP) National Assessment of Shoreline Change Study, is evaluating shoreline change from Peard Bay to the United States/Canadian border, using historical maps and photography and a standardized methodology that is consistent with other shoreline-change studies along the Nation's coastlines (see, for example, http://coastal.er.usgs.gov/shoreline-change/, last accessed February 12, 2010). This is the second in a series of publications containing photographs collected during reconnaissance surveys conducted in support of the National Assessment of Shoreline Change Study. An accompanying ESRI ArcGIS shape file (and plaintext copy) indicates the position of the aircraft and time when each photograph was taken. The USGS-CMGP Field Activity ID for the survey is A-5-09-AK, and more information on the survey and how to view the photographs using Google Earth software is available online at http://walrus.wr.usgs.gov/infobank/a/a509ak/html/a-5-09-ak.photos.kmz (last accessed February 12, 2010). The initial report ?Oblique aerial photography of the Arctic coast of Alaska, Nulavik to Demarcation Point, August 7-10, 2006? is available online at http://pubs.usgs.gov/ds/436/, and the associated Google Earth .kmz file is available at http://walrus.wr.usgs.gov/infobank/a/a106ak/html/a-1-06-ak.photos.kmz (last accessed February 12, 2010).

Data Series

Evapotranspiration from forage grass replacing native vegetation in the Gila River valley of Arizona

Estimates of evapotranspiration from an area of forage grass, which had been planted to replace native vegetation of little economic value, were made daily for a 363-day period in 1969 and 1970. The measurement site was located in the Gila River valley in east-central Arizona. The forage, panigrass (Panicum antidotale Retz.), grew from seed during the early summer of 1969 and after winterkill, regrew in 1970. Daily evapotranspiration estimates, which were based on energy budget measurements, ranged from a maximum of 9.2 millimeters to small amounts of condensation. Two daily values of substantial condensation (0.9 and 0.4 millimeter) were of dubious quality, but were retained in the record. The annual evapotranspiration was 989 millimeters, of which about 332 millimeters came from precipitation at the site. The water table fluctuated between 210 and 280 centimeters below land surface. However, the measurement site was near a wash, so that undocumented, shallower subterranean flows may have occurred. (USGS)

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