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Geologic and hydrogeologic characteristics of the White River Formation, Lance Formation, and Fox Hills Sandstone, northern greater Denver Basin, southeastern Laramie County, Wyoming

In cooperation with the Wyoming State Engineer’s Office, the U.S. Geological Survey studied the geologic and hydrogeologic characteristics of Cenozoic and Upper Cretaceous strata at a location in southeastern Laramie County within the Wyoming part of the Cheyenne Basin, the northern subbasin of the greater Denver Basin. The study aimed to improve understanding of the aquifers/aquifer systems in these strata, motivated in part by declining groundwater levels and interest in exploring future groundwater supplies. Based on detailed geologic characterization using information obtained by drilling and coring a 960-foot-(ft) deep exploratory borehole, and comparisons with previously published descriptions, identified Cenozoic lithostratigraphic units included 40 ft of Quaternary older alluvial fan deposits consisting of an unconsolidated mixture of sand and gravel with lesser quantities of silt and clay in varying proportions and the underlying 407.3-ft-thick White River Formation of late Eocene-Oligocene age consisting largely of mudrocks with sparse thin beds of sandstone, muddy gravel, and conglomeratic mudrocks. Identified Upper Cretaceous lithostratigraphic units included the 351.6-ft-thick Lance Formation, consisting of terrestrial sedimentary rocks including mudrocks (muddy shale and silty and sandy shale, siltstone, claystone, and mudstone) interbedded with much smaller quantities of very fine- to medium-grained muddy and silty sandstone and coal; the 79.6-ft-thick Fox Hills Sandstone, consisting of a transitional marine sequence of muddy or silty sandstone present in five individual beds; and 86.7 ft of the upper transition member of the Pierre Shale, consisting largely of marine sedimentary rocks such as muddy shale. Beds of the upper and lower Fox Hills Sandstone were separated by tongues of the Lance Formation and upper transition member of the Pierre Shale, respectively. The White River hydrogeologic unit, consisting of the entire White River Formation or Group at the study site, did not contain any substantial secondary permeability features in the mudrocks that composed almost all the unit. A monitoring well (BR–1) was completed in the White River aquifer with the well screen open to the only coarse-grained unit (muddy sandstone) that had sufficient thickness and permeability to be considered as an aquifer. Sampling of the well for a broad suite of constituents indicated groundwater generally was of excellent quality except dissolved arsenic was detected at a concentration greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level, and dissolved sodium was measured at a concentration greater than several EPA Drinking Water Advisory Levels (DWAs) for the constituent. Well development, well purging for groundwater sampling, and calculated aquifer properties indicated the sandstone aquifer screened by monitoring well BR–1 was not very productive. Analysis of the well water-level responses in BR–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response with wellbore-storage effects. Hydraulic properties estimated based on these responses yielded values of hydraulic conductivity ( K , 0.057 foot per day [ft/d]), specific storage ( Ss , 1.6×10 −6 per foot [ft −1 ]) and porosity ( n , 0.43). Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated an upward trend (+1.13 foot per year [ft/yr]) during the period analyzed, September 5, 2014, to September 30, 2017. Lithologic characteristics of the Lance hydrogeologic unit, consisting of the entire Lance Formation at the study site, indicated a potential aquifer in a “sandy” interval in the upper part of the unit. Most of the Lance hydrogeologic unit below the “sandy” interval consisted of various low-permeability lithologies unlikely to yield substantial quantities of water. This lower part of the hydrogeologic unit likely functions as a confining unit separating the underlying Lance-Fox Hills aquifer. A geologic cross section constructed for this study indicated fine-grained sediments composed most of the Lance Formation/hydrogeologic unit not only at the study location, but also throughout southern Laramie County along the line of section and throughout the Wyoming and Colorado parts of the Cheyenne Basin. A monitoring well (LN–1) completed in a sandstone bed in the “sandy” interval of the Lance hydrogeologic unit produced a mean of about 23 gallons per minute (gal/min) during well development, indicating sandstone beds can form moderately productive confined subaquifers in this part of the hydrogeologic unit. Analysis of the well water-level responses in well LN–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties estimated based on these responses yielded values for a lower bounding K of 0.60 ft/d, Ss of 1.6×10 −6 ft −1 , and n of 0.38. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−0.86 ft/yr) during the period analyzed (November 8, 2014, to September 30, 2017). Analyses for a broad suite of constituents in samples from well LN–1 indicated groundwater quality generally was excellent, although dissolved sodium was measured at a concentration greater than two EPA DWA levels for the constituent. Because of the absence of any overlying or intertonguing sandstone beds belonging to the lower/basal part of the Lance Formation, the Lance-Fox Hills aquifer at the study site consisted only of the five sandstone beds of the Fox Hills Sandstone. The cross section constructed for this study illustrated how the Fox Hills Sandstone, and thus, most of the Lance-Fox Hills aquifer, consists of a series of sandstone bodies that overlap (shingle) upward to the east across southern Laramie County. These bodies collectively form a fairly continuous body of sandstone, thus potentially forming an areally extensive aquifer across southern Laramie County, and by extension, throughout most of the formation’s extent in the Wyoming part of the Cheyenne Basin, as is the case in the Colorado part of the basin. A monitoring well (FH–1) completed in part of the thickest sandstone bed of the Lance-Fox Hills aquifer was moderately to highly productive and easily produced 25 to 30 gal/min after development. Substantially larger water production rates likely could be obtained by penetrating the full thickness of this bed and by completing a well open to the other overlying and underlying sandstone beds of the aquifer. Analysis of the water-level responses in well FH–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties computed based on these responses yielded values for a lower bounding estimate for K of 0.26 ft/d, for Ss of 1.0×10 −6 ft −1 , and for n of 0.41. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−1.74 ft/yr) during the period analyzed, December 19, 2014, to September 30, 2017. Sampling of monitoring well FH–1 and two production wells completed in the Fox Hills Sandstone in other parts of Laramie County indicated groundwater quality generally is excellent, although pH exceeded a recommended EPA aesthetic drinking-water standard (Secondary Maximum Contaminant Level) in two of three sampled wells, total dissolved solids concentrations exceeded the Secondary Maximum Contaminant Level in one of the two sampled production wells, and dissolved sodium was measured in all three sampled wells at a concentration greater than two EPA DWA levels for the constituent. The Wyoming Class II agricultural (irrigation) sodium adsorption ratio standard of 8 was exceeded in all three sampled wells, indicating these waters are not suitable for irrigation use. Computed vertical hydraulic gradients indicated a strong potential for downward flow throughout the groundwater system at the study site, including from the low-yielding aquifer in the upper White River Formation/hydrogeologic unit (monitoring well BR–1) to the sandstone subaquifer in the Lance Formation/hydrogeologic unit (monitoring well LN–1), and from the Lance subaquifer (monitoring well LN–1) to the sandstone bed/aquifer that composes much of the Lance-Fox Hills aquifer thickness at the study site (monitoring well FH–1). However, large hydraulic-head differences between wells indicated high resistance to vertical flow attributable to the low vertical hydraulic conductivity of intervening strata, which consisted almost entirely of low-permeability mudrocks. The confined nature of the sandstone aquifers monitored by the various wells coupled with dissimilarities between groundwater-level fluctuations and trends in groundwater levels indicated downward flow through the intervening strata (primarily mudrocks in the various lithostratigraphic/hydrogeologic units) between the examined sets of wells likely was small.

Wyoming

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Land Cover Change in the Boston Mountains, 1973-2000

The U.S. Geological Survey (USGS) Land Cover Trends project is focused on understanding the rates, trends, causes, and consequences of contemporary U.S. land-cover change. The objectives of the study are to: (1) to develop a comprehensive methodology for using sampling and change analysis techniques and Landsat Multispectral Scanner (MSS), Thematic Mapper (TM), and Enhanced Thematic Mapper Plus (ETM+) data to measure regional land-cover change across the United States; (2) to characterize the types, rates, and temporal variability of change for a 30-year period; (3) to document regional driving forces and consequences of change; and (4) to prepare a national synthesis of land-cover change (Loveland and others, 1999). The 1999 Environmental Protection Agency (EPA) Level III ecoregions derived from Omernik (1987) provide the geographic framework for the geospatial data collected between 1973 and 2000. The 27-year study period was divided into five temporal periods: 1973-1980, 1980-1986, 1986-1992, 1992-2000, and 1973-2000, and the data are evaluated using a modified Anderson Land Use Land Cover Classification System (Anderson and others, 1976) for image interpretation. The rates of land-cover change are estimated using a stratified, random sampling of 10-kilometer (km) by 10-km blocks allocated within each ecoregion. For each sample block, satellite images are used to interpret land-cover change for the five time periods previously mentioned. Additionally, historic aerial photographs from similar time frames and other ancillary data, such as census statistics and published literature, are used. The sample block data are then incorporated into statistical analyses to generate an overall change matrix for the ecoregion. Field data of the sample blocks include direct measurements of land cover, particularly ground-survey data collected for training and validation of image classifications (Loveland and others, 2002). The field experience allows for additional observations of the character and condition of the landscape, assistance in sample block interpretation, ground truthing of Landsat imagery, and determination of the driving forces of change identified in an ecoregion.

Open-File Report

Assessing the relationship between Section 404 and wetland losses: a feasibility study

The primary objective of the Clean Water Act of 1977 (33 U.S.C. 1251) is to restore and maintain the physical, chemical, and biological integrity of the Nation's waters. Section 404 of the Act regulates the discharge of dredged or fill materials into wetlands and represents the primary Federal authority for regulation of wetland alterations. Since its inception, the Section 404 program has been controversial in regard to the extent to which it was intended to provide wetlands regulation. Section 404 requires those who wish to discharge dredged or fill material into waters of the United States, which include many wetlands, to first obtain a Federal permit. The Environmental Protection Agency (EPA) has overall responsibility for administration of the Section 404 program and promulgates guidelines that must be followed in issuing permits. In addition, EPA has the final authority to prohibit specific discharges if the environmental impacts are unacceptable. The U.S. Army Corps of Engineers (Corps) issues Section 404 permits, which can be of two types. Individual Permits are issued following case-by-case reviews of proposed discharges. General Permits, which can be either nationwide or regional in scope, are authorized by the Corps for categories of activities that are similar in nature and that have only minimal individual and cumulative adverse environmental impacts. EPA, the National Marine Fisheries Service (NMFS), the Fish and Wildlife Service (Service), and State natural resource agencies review and comment on permit applications and offer recommendations on appropriate mitigation measures. Although comments from the Service and other natural resource agencies are advisory in nature (EPA's veto authority excepted), they can serve as the basis for modifying, conditioning, or denying a Section 404 permit. In 1986, in a survey conducted by the National Ecology Research Center, Service personnel indicated interest in additional information concerning both wetland trends and the impacts of activities authorized by the Corps under Section 404 (Roelle 1986). Although there is some information concerning wetland losses for certain geographic areas and for the Nation as a whole (Frayer et al. 1983; Tiner 1984), there appears to be little information on how these losses relate to the Section 404 permitting process. The primary objective of this study was to determine the feasibility of estimating wetland losses in relationship to Individual and General Permits issued under Section 404. A secondary objective was to assemble data on acceptance and implementation of specific mitigation recommendations offered by the Service and other natural resource agencies in connection with development activities on wetlands examined. At present, 26 categories of Nationwide permits have been authorized by the Corps. Nationwide permit 26 was of particular interest in this study because it specifically authorizes discharges into wetlands under certain circumstances (see Figure 1 and related text for a more complete discussion of circumstances under which Nationwide Permit 26 is applicable). All subsequent references to Nationwide or General permits pertain to Nationwide Permit 26.

Report

Integrated science for the study of microplastics in the environment—A strategic science vision for the U.S. Geological Survey

Executive Summary Evidence of the widespread occurrence of microplastics throughout our environment and exposure to humans and other organisms over the past decade has led to questions about the possibility of health hazards and mitigation of exposures. This document discusses nanoplastics as well as microplastics (referred to solely as microplastics); the microplastics have a range from 1 micrometer to 5 millimeters (1 μm–5 mm) in length, whereas the nanoplastics are less than 1 μm in length (sidebar ES1). A myriad of environmental exposure pathways with microplastics to humans and wildlife, including ingestion, inhalation, and bodily absorption, are likely to exist. A growing body of evidence has documented bioaccumulation of microplastics in tissues and organs of humans and wildlife, benthic community effects, and potential nutritional and reproductive effects in some wildlife species. Understanding if or when environmental exposures pose a health risk is complicated by the diversity of microplastic sizes, morphologies, polymer types, and chemicals added during manufacturing or sorbed from the environment; ongoing challenges in analytical methods used to detect, quantify, and characterize microplastics and associated chemicals in our ecosystems; and the fact that ecotoxicological studies regarding microplastics are still in their infancy. Therefore, the study of environmental exposures and potential related health hazards of microplastics to the public and wildlife is a One Health (sidebar ES2) research topic that necessitates integrated science approaches. A better understanding of the sources, pathways, fate, and biological effects of microplastics has become a priority of the Federal Government, State governments, Tribes, stakeholders, and the public. Examples of Federal and State microplasticfocused legislation and programs to prioritize microplastic research and reduction include the Federal Microbead-Free Waters Act of 2015, California Senate Bills 1422 and 1263 (2018), the U.S. Environmental Protection Agency (EPA) Trash Free Waters Program, the National Institute of Standards and Technology’s Microplastic and Nanoplastic Metrology project, and Minnesota’s microplastic project. With its unique expertise and capabilities, the U.S. Geological Survey (USGS) is well positioned to help fill some of the most important microplastic science gaps. This strategic science vision document for microplastics identifies current (2023) microplastic science gaps and prioritizes research relevant to the mission, expertise, and capabilities of the USGS. It is intended for USGS scientists and stakeholders to use as a starting point for planning, prioritizing, and designing collaborative environmental microplastic science. Many of the microplastic science gaps and priorities are scalable, from local to national, and thus, can be made commensurate with available funding and evolving analytical and field tools, laboratory capacity, and stakeholder needs. Current (2023) or future research by academia and other Federal or State agencies, and Tribes may be aimed at some of the same microplastic science gaps identified in this document. Therefore, this document can be used as an information resource to maximize strengths and capabilities and minimize redundancy in communication and collaboration.

Circular

Geochemical assessment of groundwater in the Big Chino subbasin, Arizona, 2011–18

A geochemical characterization of groundwater in the Big Chino subbasin of Arizona was conducted by the U.S. Geological Survey, in cooperation with the City of Prescott, the Town of Prescott Valley, and the Salt River Project, to understand groundwater evolution through the study area and the source of water to springs along the gaining reach of the Verde River just downstream from its confluence with Granite Creek. Samples were collected between 2011 and 2018 in groundwater wells completed in basin-fill and carbonate aquifers and at selected springs, including two discrete springs discharging along the aforementioned stretch of the Verde River. Five newly installed monitoring wells completed in the carbonate aquifer were sampled in 2018. Water-quality results obtained from these samples include the first known geochemical data for carbonate groundwater beneath the basin-fill in the Big Chino subbasin downgradient from Walnut Creek near Paulden, Arizona, as well as other parts of the study area without previous data. Groundwater samples were collected and analyzed for major ions, arsenic, nutrients, stable isotopes of oxygen and hydrogen (δ 18 O and δ 2 H), strontium isotopes ( 87 Sr/ 86 Sr), carbon-14, isotopes of carbon (δ 13 C), and noble gases. Significant differences in groundwater geochemistry between the basin-fill and carbonate aquifers were driven primarily by higher pH, tritium, and δ 18 O and δ 2 H in the basin-fill aquifer samples and higher specific conductance and higher concentrations of calcium, sodium, bicarbonate, fluoride, and arsenic in the carbonate aquifer samples. All but one sample from the carbonate aquifer and two samples from the basin-fill aquifer exceeded the U.S. Environmental Protection Agency (EPA) drinking water standard for arsenic of 10 micrograms per liter. One basin-fill aquifer sample exceeded the EPA drinking water standard for fluoride of 4 milligrams per liter, and one carbonate aquifer sample exceeded the EPA secondary drinking water standard for fluoride of 2 milligrams per liter. A component of modern groundwater recharged following aboveground nuclear testing beginning in the mid-1950s is present in some basin-fill and spring groundwater from this study. Groundwater that can be dated using radiocarbon decay is also present in the study area, with four groundwater samples indicating possible recharge during the Pleistocene with groundwater ages ranging from approximately 34,600 to 13,300 years before present. Other groundwater sampled during this study that can dated using radiocarbon decay ranged in age from about 7,500 to 1,100 years before present, indicating possible recharge during the Holocene. The gaining reach of the Verde River downstream from the confluence with Granite Creek shows areal changes in temperature, pH, and specific conductance, indicating multiple zones of groundwater input. Surface-water samples for analyses of δ 18 O and δ 2 H have been collected at the Verde River near Paulden, Ariz. streamgage (09503700) during discharge measurements since 2009, and a trend analysis of the δ 18 O and δ 2 H data indicated no significant trend exists for the 10-year period of record. Additional groundwater samples from the carbonate aquifer beneath the basin-fill upgradient and downgradient from Walnut Creek would provide valuable information to understand groundwater evolution along the Big Chino subbasin.

Arizona

Land-cover change in the central irregular plains, 1973-2000

Spearheaded by the Geographic Analysis and Monitoring Program of the U.S. Geological Survey (USGS) in collaboration with the U.S. Environmental Protection Agency (EPA) and the National Aeronautics and Space Administration (NASA), the Land Cover Trends is a research project focused on understanding the rates, trends, causes, and consequences of contemporary United States land-use and land-cover change. Using the EPA Level III ecoregions as the geographic framework, scientists process geospatial data collected between 1973 and 2000 to characterize ecosystem responses to land-use changes. The 27-year study period was divided into five temporal periods: 1973-1980, 1980-1986, 1986-1992, 1992-2000 and 1973-2000. General land-cover classes for these periods were interpreted from Landsat Multispectral Scanner, Thematic Mapper, and Enhanced Thematic Mapper Plus imagery to categorize land-cover change and evaluate using a modified Anderson Land Use Land Cover Classification System for image interpretation. The rates of land-cover change are estimated using a stratified, random sampling of 10-kilometer (km) by 10-km blocks allocated within each ecoregion. For each sample block, satellite images are used to interpret land-cover change. Additionally, historical aerial photographs from similar timeframes and other ancillary data such as census statistics and published literature are used. The sample block data are then incorporated into statistical analyses to generate an overall change matrix for the ecoregion. These change statistics are applicable for different levels of scale, including total change for the individual sample blocks and change estimates for the entire ecoregion. The results illustrate that there is no single profile of land-cover change but instead point to geographic variability that results from land uses within ecoregions continuously adapting to various factors including environmental, technological, and socioeconomic.

Open-File Report

The Penobscot River and environmental contaminants: Assessment of tribal exposure through sustenance lifeways

EPA in collaboration with the Penobscot Indian Nation, U.S. Geological Survey (USGS), Agency for Toxic Substances and Disease Registry (ATSDR), and the U.S. Fish and Wildlife Service (USF&WS) collectively embarked on a four year research study to evaluate the environmental health of the riverine system by targeting specific cultural practices and using traditional science to conduct a preliminary contaminant screening of the flora and fauna of the Penobscot River ecosystem. This study was designed as a preliminary screening to determine if contaminant concentrations in fish, eel, snapping turtle, wood ducks, and plants in Regions of the Penobscot River relevant to where PIN tribal members hunt, fish and gather plants were high enough to be a health concern. This study was not designed to be a statistically validated assessment of contaminant differences among study sites or among species. The traditional methodology for health risk assessment used by the U. S. Environmental Protection Agency (EPA) is based on the use of exposure assumptions (e.g. exposure duration, food ingestion rate, body weight, etc.) that represent the entire American population, either as a central tendency exposure (e.g. average, median) or as a reasonable maximum exposure (e.g. 95% upper confidence limit). Unfortunately, EPA lacked exposure information for assessing health risks for New England regional tribes sustaining a tribal subsistence way of life. As a riverine tribe, the Penobscot culture and traditions are inextricably tied to the Penobscot River watershed. It is through hunting, fishing, trapping, gathering and making baskets, pottery, moccasins, birch-bark canoes and other traditional practices that the Penobscot culture and people are sustained. The Penobscot River receives a variety of pollutant discharges leaving the Penobscot Indian Nation (PIN) questioning the ecological health and water quality of the river and how this may affect the practices that sustain their way of life. The objectives of this Regional Applied Research Effort (RARE) study were to: Develop culturally sensitive methodologies for assessing the potential level of exposure tocontaminants that Penobscot Indian Nation tribal members may have from maintainingtribal sustenance practices. Conduct field surveys and laboratory analysis on targeted flora and fauna for chemicalexposure to dioxins/furans, polychlorinated biphenyls (PCBs), total mercury and methyl-mercury. Assist the Agency for Toxic Substances and Disease Registry (ATSDR) by providing thenecessary data to conduct a Public Health Assessment for the Penobscot Indian Nation. Establish protocols for assessing the level of exposure to PCBs, dioxins/furans and mercuryto PIN tribal members as a consequence of gathering tribal plants for medicinal andnutritional purposes; as well as consuming fish, wood duck, and snapping turtle as a primarysource of nutrition. Survey surface water, drinking water, and sediment from the Penobscot River and IndianIsland to assess the exposure of PIN tribal members to environmental genotoxicants thatcontinue cultural sustenance practices. This research initiative collected and analyzed sediment and biota to determine the level of contaminant exposure to Penobscot tribal members. Natural resource utilization patterns and exposure pathways were identified based on discussions with the Tribal elders. Identification of Tribal exposure factors (exposure pathways and contaminant concentrations) was essential for accurately assessing potential long-term Penobscot Indian Nation tribal members’ exposure. Based on this study, ATSDR’s Public Health Assessment (PHA) concluded that the Penobscot Indian Nation (PIN) tribal members who eat fish and snapping turtle at the ingestion levels suggested in the Wabanaki Traditional Cultural Lifeways Exposure Scenario Report (Wabanaki Exposure Scenario) may be exposed to harmful levels of mercury, dioxins/furans, dioxin-like PCBs, and ot

Maine

The National Map hydrography data stewardship: what is it and why is it important?

The National Hydrography Dataset (NHD) and Watershed Boundary Dataset (WBD) were designed and populated by a large consortium of agencies involved in hydrography across the United States. The effort was led by the U.S. Geological Survey (USGS), the U.S. Environmental Protection Agency (EPA), and the Natural Resources Conservation Service (NRCS). The high-resolution NHD dataset, completed in 2007, is based on the USGS 7.5-minute series topographic maps at a scale of 1:24,000. There are now 26 million features in the NHD representing a 7.5 million mile stream network with over 6.5 million waterbodies. The six-level WBD, completed in 2010, is based on 1:24,000 scale data and contains over 23,000 watershed polygons. The NHD’s flow network, attribution, and linear referencing are used to conduct extensive scientific analyses. The NHD is ideal for cartographic applications such as the US Topo topographic map series, and also is available on the Geospatial Platform, which provides shared and trusted geospatial data, services, and applications for use by government agencies, their partners, and the public. The WBD watersheds are used by scientists and managers to identify discrete drainage areas. The ongoing maintenance of the NHD and WBD is essential for improving these datasets to meet the ever increasing demand for currency, additional detail, and more significant attribution. The best source of information about changes in local hydrography are users closest to the data, such as State and local governments, as well as Federal land management agencies, and other users of the data. The need for local knowledge has led to the creation of a collaborative data stewardship process to revise and maintain the NHD.

Fact Sheet

Hydrologic balance, water quality, chemical-mass balance, and geochemical modeling of hyperalkaline ponds at Big Marsh, Chicago, Illinois, 2016–17

Hyperalkaline (pH greater than 12) ponds and groundwater exist at Big Marsh near Lake Calumet, Chicago, Illinois, a site used by the steel industry during the mid-1900s to deposit steel- and iron-making waste, in particular, slag. The hyperalkaline ponds may pose a hazard to human health and the environment. The U.S. Geological Survey (USGS), in cooperation with the Environmental Protection Agency (EPA) and in collaboration with the City of Chicago’s Park District, completed a study to evaluate the hydrologic balance, water quality, and chemical-mass balance of hyperalkaline ponds at Big Marsh and geochemical modeling used to evaluate remediation options for water quality at the site based on data collected in 2016–17. Synoptic measurements of surface-water and groundwater elevations were used to determine flow directions and to enable a preliminary estimate of the hydrologic balance for the ponds. Water-quality samples also were collected and analyzed for selected constituents including major anions and cations, nutrients, metals, and trace elements. The results of the water-quality analyses were used to develop a geochemical model to evaluate concentrations, factors affecting pH, and the state of equilibrium between surface waters and atmospheric carbon dioxide. The geochemical model was used to evaluate remediation scenarios using riprap, spillways, or active aeration. The results indicate that active aeration will decrease the pH to near 7.5 in about 8 hours, the fastest rate of the scenarios. Passive aeration, such as riprap or spillways, also can be effective at decreasing the pH in about 45 hours, but spatial obstacles limit their implementation. Seasonal variations in temperature also affect the rate of equilibration, where colder temperatures may have a lower pH than warmer temperatures and may affect the timing and frequency of remediation.

Illinois

Surface gamma-ray survey of the Barre West quadrangle, Washington and Orange Counties, Vermont

This study was designed to determine the levels of naturally occurring radioactivity in bedrock from surface measurements at outcrops during the course of 1:24,000-scale geologic mapping and to determine which rock types were potential sources of radionuclides. Elevated levels of total alpha particle radiation (gross alpha) occur in a public water system in Montpelier, Vermont. Measured gross alpha levels in the Murray Hill water system (Vermont Dept. of Environmental Conservation, unpub. data, 2005) have exceeded the maximum contaminant level of 15 picocuries per liter (pCi/l) set by the Environmental Protection Agency (EPA) (EPA, 2000). The Murray Hill system began treatment for radium in 1999. Although this treatment was successful, annual monitoring for gross alpha, radium, and uranium continues as required (Jon Kim, written communication, 2005). The water system utilizes a drilled bedrock well located in the Silurian-Devonian Waits River Formation. Kim (2002) summarized radioactivity data for Vermont, and aside from a statewide assessment of radon in public water systems (Manning and Ladue, 1986) and a single flight line from the National Uranium Resource Evaluation (NURE) (Texas Instruments, 1976) (fig. 1), no data are available to identify the potential sources of naturally occurring radioactivity in the local bedrock. Airborne gamma-ray surveys are typically used for large areas (Duval, 2001, 2002), and ground-based surveys are more commonly used for local site assessments. For example, ground-based surveys have been used for fault mapping (Iwata and others, 2001), soil mapping (Roberts and others, 2003), environmental assessments (Stromswold and Arthur, 1996), and mineral exploration (Jubeli and others, 1998). Duval (1980) summarized the methods and applications of gamma- ray spectrometry. In this study, we present the results from a ground-based gamma-ray survey of bedrock outcrops in the 7.5-minute Barre West quadrangle, Vermont. Other related and ongoing studies in the area are addressing potential mineral sources of radionuclides (Satkoski and Walsh, 2004; Satkoski and others, 2005), radionuclides in ground water (Kim and others, 2005), and bedrock geology.

Scientific Investigations Report

Geologic Map of the Edwards Aquifer In Northern Medina and Northeastern Uvalde Counties, South-central Texas

The southern segment of the Edwards aquifer in south-central Texas is one of the most productive subsurface reservoirs of potable water in the world, providing water of excellent quality to more than a million people in the San Antonio region, where the Environmental Protection Agency (EPA) has declared it to be a sole-source aquifer (van der Leeden and others, 1990). Depending on the depositional province within which the associated carbonate rocks originated (Maclay and Small, 1984), the Edwards aquifer is composed of several geologic formations (primarily limestone and dolostone) of Early Cretaceous age. Most water pumped from the Edwards aquifer comes form the Person and Kainer Formations, which were deposited over the San Marcos Platform. The principal source of ground water in study area is the Devils River Formation, which was deposited in the Devils River trend. The Devils River Formation provides large quantities of irrigation water to fertile bottomland areas of Medina and Uvalde Counties, where the success of farming and ranching activities has long depended upon water from the Edwards aquifer. The study area includes all of the Edwards aquifer recharge zone between the Sabinal River (on the west) and the Medina River (on the east) plus an updip fringe of the confined zone in east-central Uvalde and central Medina Counties. Over about ninety percent of the study area--within the Devils River trend--the Edwards aquifer is composed of the Georgetown Formation plus the underlying Devils River Formation. Over the remaining area--over the southwestern margin of the San Marcos platform--the Edwards aquifer consists of the Georgetown Formation plus the underlying Edwards Group (Rose, 1972), which comprises the Kainer and Person Formations.

Open-File Report

2017 Monitoring and tracking wet nitrogen deposition at Rocky Mountain National Park

The Colorado Department of Public Health and Environment (CDPHE), the National Park Service (NPS), and the U.S. Environmental Protection Agency (EPA) issued the Nitrogen Deposition Reduction Plan (NDRP) in 2007 to address the effects and trends of nitrogen deposition at Rocky Mountain National Park (RMNP). The agencies chose a glidepath approach to reduce wet nitrogen deposition to a level of 1.5 kilograms of nitrogen per hectare per year (kg N/ha/yr) by the year 2032 to protect sensitive ecosystems within RMNP from adverse effects. Another goal of the NDRP is to “reverse the trend of increasing nitrogen deposition at the park.” Trends in wet deposition data were analyzed at three sites in RMNP and three regional sites outside of the park. Wet nitrogen deposition (5-year rolling average) at Loch Vale in RMNP was 3.3 kg N/ha/yr, which is above the glidepath (2.4 kg N/ha/yr) in 2017. Wet nitrogen deposition has not decreased at RMNP or other sites in the region over the long-term. Ammonium concentrations showed a statistically significant increasing trend at all sites and nitrate concentrations showed a significant decreasing trend at four of the five sites over the period of record. In more recent years (2011-2017), wet nitrogen deposition showed no significant trend at monitoring sites in RMNP. Ammonium concentrations also showed no significant trend over the short-term, however nitrate concentrations did significantly decrease at two of the six sites.

Colorado

Evaluating environmental and economic consequences of alternative pest management strategies: results of modeling workshops

The U.S. Environmental Protection Agency (EPA) needs a comprehensive method to evaluate the human health and environmental effects of alternative agricultural pest management strategies. This project explored the utility of Adaptive Environmental Assessment (AEA) techniques for meeting this need. The project objectives were to produce models for environmental impact analysis, improve communications, identify research needs and data requirements, and demonstrate a process for resolving conflicts. The project was structured around the construction (in an initial 2 1/2-day workshop) and examination (in a second 2 1/2-day workshop) of a simulation model of a corn agroecosystem. The model conceptualized at the first workshop simulates the effect of corn agrecosystem decisions on crop production, economic returns, and environmental indicators. The model is composed of five interacting submodels: 1) a Production Strategies submodel which makes decisions concerning tillage, planting, fertilizer and pesticide applications, and harvest; 2) a Hydrology/Chemical Transport submodel which represents soil hydrology, erosion, and concentrations of fertilizers and pesticides in the soil, runoff, surface waters, and percolation; 3) a Vegetation submodel which simulates growth of agricultural crops (corns and soybeans) and weeds; 4) a Pests submodel which calculates pest population levels and resulting crop damage; and 5) an Environmental Effects submodel which calculates indicators of potential fish kills, human health effects, and wildlife habitat. The most persistent data gaps encountered in quantifying the model were coefficients to relate environmental consequences to alternative pest management strategies. While the model developed in the project is not yet accurate enough to be used for real-world decisions about the use of pesticides on corn, it does contain the basic structure upon which such a model could be built. More importantly at this stage of development, the project has shown that very complex systems can be modeled in short periods of time and that the process of building such models increases understanding among disciplinary specialists and between diverse institutional interests. This process can be useful to EPA as the agency cooperates with other institutions to meet its responsibilities in less costly ways. Activities at the second 2 1/2-day workshop included a review of the model, incorporation of necessary corrections, simulation of policy scenarios, and examination of techniques to address remaining institutional conflicts. Participants were divided into three groups representing environmental, production or industry, and regulatory interests. Each group developed scenarios that would be most appealing to their particular interest and the scenarios were simulated by the agroecosystem computer model. Negotiators from each of the interest groups decided whether a hypothetical herbicide should be relabeled and if certain restrictions should be imposed on its use. Other participants functioned as experts and consultants on caucus teams. A solution to the hypothetical problem was successfully negotiated. Workshop participants and project staff agreed that the model and processes developed during the project should be used in training students, extension specialists, farmers, researchers, and chemical producers in collaborative problem solving methods. More productive research can be planned, and more realistic models of complex systems can be built in this way. More importantly, greater trust of decisionmakers in computer models, better understanding by technical experts about disciplines other than their own, and improved cooperation between institutional interests can be achieved. This trust, understanding, and cooperation are critical ingredients in solving problems that are too complex to be resolved by independent disciplinary activity and unilateral decision authority.

Report

Water-quality conditions and constituent loads, water years 2013–19, and water-quality trends, water years 1983–2019, in the Scituate Reservoir drainage area, Rhode Island

The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. From October 1, 1982, to September 30, 2019, water years (WYs) 1983–2019 (a water year is the period between October 1 and September 30 and is designated by the year in which it ends), the Providence Water Supply Board maintained a fixed-frequency sampling program at 37 stations to monitor water quality in tributaries to the Scituate Reservoir. The U.S. Geological Survey (USGS), in cooperation with the Providence Water Supply Board, has measured streamflow at selected streamgages in the Scituate Reservoir drainage area since WY 1994, monitored water quality at selected stations since WY 2009, and conducted targeted base-flow and stormflow sampling at five stations in WYs 2016–19. Daily loads and yields of constituents (chloride, nitrite, nitrate, total coliform bacteria, Escherichia coli , and orthophosphate) were determined for sampled days during WYs 2013–19, and trends were examined for the entire period of record, predominantly WYs 1983–2019. USGS water-quality data were used to determine annual loads and yields of chloride and sodium for WYs 2013–19 at 14 stations, and nutrients and suspended sediment for WYs 2016–19 at 5 stations. Tributaries in the Scituate Reservoir drainage area for WYs 2013–19 were slightly acidic (pH values less than 7.0 standard units) and often below the recommended pH range of 6.5 to 8.5 standard units, as described by the U.S. Environmental Protection Agency (EPA) in the secondary drinking-water regulations. Most measurements of water color in the tributaries were greater than the EPA secondary drinking-water regulation of 15 platinum-cobalt units. Chloride concentrations in Providence Water Supply Board samples rarely exceeded the EPA secondary drinking-water regulation for chloride (250 milligrams per liter); however, chloride concentrations estimated from continuous measurements of specific conductance exceeded the EPA criterion continuous concentration recommended for freshwater (230 milligrams per liter) for short periods ranging from 10 minutes to 26 hours at two streamgages. Positive trends in pH, color, alkalinity, and chloride at more than half of the monitoring stations were identified for WYs 1983–2019. Fewer than half of the stations had significant trends in turbidity values, and significant trends varied in direction (positive or negative trends). Trend tests were not performed on total coliform bacteria, Escherichia coli , and nitrate concentrations because of analytical method changes that coincide with abrupt shifts in the magnitude and distribution of concentration data. The median of daily loads and yields of chloride, nitrite, nitrate, orthophosphate, and bacteria determined for each Providence Water Supply Board sample in WYs 2013–19 varied across the 37 monitoring stations, but yields were generally greater at stations in the Moswansicut and Regulating Reservoir subbasins. Average daily yields of chloride and sodium estimated from continuous records of specific-conductance and streamflow data at 14 stations ranged from 42 to 310 kilograms per square mile per day and 28 to 180 kilograms per square mile per day, respectively. The mean annual yields of total phosphorus, total nitrogen, and suspended sediment determined for five stations ranged from 16 to 78 kilograms per square mile, from 370 to 2,100 kilograms per square mile, and from 5,000 to 13,000 kilograms per square mile, respectively. More than half of the nutrient and suspended sediment loads occurred during stormflow.

Rhode Island

Concentrations and Loads of Organic Compounds and Trace Elements in Tributaries to Newark and Raritan Bays, New Jersey

A study was undertaken to determine the concentrations and loads of sediment and chemicals delivered to Newark and Raritan Bays by five major tributaries: the Raritan, Passaic, Rahway, Elizabeth, and Hackensack Rivers. This study was initiated by the State of New Jersey as Study I-C of the New Jersey Toxics Reduction Workplan for the New York-New Jersey Harbor, working under the NY-NJ Harbor Estuary Program (HEP) Contaminant Assessment and Reduction Program (CARP). The CARP is a comprehensive effort to evaluate the levels and sources of toxic contaminants to the tributaries and estuarine areas of the NY-NJ Harbor, including Newark and Raritan Bays. The Raritan and Passaic Rivers are large rivers (mean daily discharges of 1,189 and 1,132 cubic feet per second (ft3/s), respectively), that drain large, mixed rural/urban basins. The Elizabeth and Rahway Rivers are small rivers (mean daily discharges of 25.9 and 49.1 ft3/s, respectively) that drain small, highly urbanized and industrialized basins. The Hackensack River drains a small, mixed rural/urban basin, and its flow is highly controlled by an upstream reservoir (mean daily discharge of 90.4 ft3/s). These rivers flow into urbanized estuaries and ultimately, to the Atlantic Ocean. Each of these tributaries were sampled during two to four storm events, and twice each during low-flow discharge conditions. Samples were collected using automated equipment installed at stations adjacent to U.S. Geological Survey streamflow-gaging stations near the heads-of-tide of these rivers. Large-volume (greater than 50 liters of water and a target of 1 gram of sediment), flow-weighted composite samples were collected for chemical analysis using filtration to collect suspended particulates and exchange resin (XAD-2) to sequester dissolved contaminants. Composite whole-water samples were collected for dissolved polycyclic aromatic hydrocarbons (PAH) and for trace element analysis. Additional discrete grab samples were collected throughout each event for trace-element analysis, and multiple samples were collected for suspended sediment (SS), particulate carbon (POC), and dissolved organic carbon (DOC) analysis. The suspended sediment and exchange resin were analyzed for 114 polychlorinated biphenyls (PCBs, by US EPA method 1668A, modified), seven 2,3,7,8-substituted chlorinated dibenzo-p-dioxins (CDD) and 10 dibenzo-p-difurans (CDF) (by US EPA method 1613), 24 PAHs (by low-resolution isotope dilution/mass-spectral methods), 27 organo-chlorine pesticides (OCPs) (by high resolution isotope dilution/mass-spectral methods), and the trace elements mercury (Hg), methyl-mercury (MeHg), lead (Pb), and cadmium (Cd). Isotope dilution methods using gas chromatography and high-and low-resolution mass spectral (GC/MS) detection were used to accurately identify and quantify organic compounds in the sediment and water phases. Trace elements were measured using inductively coupled plasma-mass spectrometry and cold-vapor atomic fluorescence spectrometry methods. The loads of sediment, carbon, and chemicals were calculated for each storm and low-flow event sampled. Because only a few storm events were sampled, yearly loads of sediment were calculated from rating curves developed using historical SS and POC data. The average annual loads of sediment and carbon were calculated for the period 1975-2000, along with the loads for the selected water years being modeled as part of the New York New Jersey Harbor Estuary Program CARP. Comparison of loads calculated using the rating curve method to loads measured during the sampled storm events indicated that the rating curve method likely underpredicts annual loads. Average annual loads of suspended sediment in the tributaries were estimated to be 395,000 kilograms per year (kg/yr) in the Hackensack River, 417,000 kg/yr in the Elizabeth River, 882,000 kg/yr in the Rahway River, 22,700,000 kg/yr in the Passaic River, and 93,100,000 kg/yr in the Raritan River. Averag

Scientific Investigations Report

Point-source nutrient loads to streams of the conterminous United States, 2012

Total nitrogen and phosphorous loads were estimated for 5,430 major point-source facilities (all types) and 11,537 minor wastewater treatment facilities discharging to streams in the conterminous United States during 2012. Facilities classified as a major discharger are typically a facility that discharges greater than one million gallons of water per day however some industrial facilities are classified as a major based on specific criteria developed by the U.S. Environmental Protection Agency (EPA) and the National Pollutant Discharge Elimination System state program. Data documenting discharge information from point sources were obtained from the EPA’s Integrated Compliance Information System (ICIS) and Permit Compliance System (PCS). When available, actual nutrient concentration measurements were used to calculate point-source loads. In the many cases in which concentration data were not available in either the ICIS or PCS databases, typical pollutant concentrations (TPCs) were developed using data from similar facilities. A new method for calculating TPCs was implemented that allows varying amounts of nutrient concentration data and (or) varying numbers of facilities to determine TPCs. This new method minimized the effect that any single facility discharging extremely large nutrient concentrations had on resultant TPC values. Because of the smaller TPC values from this new TPC method, the total nutrient load for many states was reduced compared to previous TPC methods. Major wastewater treatment facilities are the largest contributor of nutrient loads to streams even though there are almost three times as many minor wastewater treatment facilities. Specifically, 4,218 major wastewater treatment facilities account for 94 percent of the total nitrogen load for the conterminous United States, whereas 11,397 minor wastewater treatment facilities contribute 6 percent of the total nitrogen load. Total phosphorous loads are similarly divided among major (93 percent) and minor (7 percent) wastewater treatment facilities. Total nitrogen loads, including all facility types, primarily are from wastewater treatment facilities and some petroleum refining facilities. Total phosphorous loads also are primarily from wastewater treatment facilities, but several manufacturing facilities such as corn milling, pulp and paper mills, and industrial chemical facilities also contribute to total phosphorous loads.

Data Series

Loads and yields of deicing compounds and total phosphorus in the Cambridge drinking-water source area, Massachusetts, water years 2009–15

The source water area for the drinking-water supply of the city of Cambridge, Massachusetts, encompasses major transportation corridors, as well as large areas of light industrial, commercial, and residential land use. Because of the large amount of roadway in the drinking-water source area, the Cambridge water supply is affected by the usage of deicing compounds and by other constituents that are flushed from such impervious areas. The U.S. Geological Survey (USGS) has monitored surface-water quality in the Cambridge Reservoir and Stony Brook Reservoir Basins, which compose the drinking-water source area, since 1997 (water year 1998) through continuous monitoring and the collection of stream-flow samples. In a study conducted by the USGS, in cooperation with the City of Cambridge Water Department, concentrations and loads of calcium (Ca), chloride (Cl), magnesium (Mg), sodium (Na), and sulfate (SO 4 ) were estimated from continuous records of specific conductance and streamflow for streams and tributaries at 10 continuous water-quality monitoring stations. These data were used to characterize current (2015) water-quality conditions, estimate loads and yields, and describe trends in Cl and Na in the tributaries and main-stem streams in the Cambridge Reservoir and Stony Brook Reservoir Basins. These data also were used to describe how stream-water quality is related to various basin characteristics and provide information to guide future management of the drinking-water source area. Water samples from 2009–15 were analyzed for physical properties and concentrations of Ca, Cl, Mg, Na, potassium (K), SO 4 , and total phosphorus (TP). Values of physical properties and constituent concentrations varied widely, particularly in composite samples of stormflow from tributaries that have high percentages of constructed impervious areas. Median concentrations of Ca, Cl, Mg, Na, and K in samples collected from the tributaries in the Cambridge Reservoir Basin (27.2, 273, 4.7, 154.5, and 2.8 milligrams per liter (mg/L), respectively) were higher than those for the Stony Brook Reservoir Basin (22.2, 128, 4.3, 77.1, and 2.5, respectively). Differences between tributary samples for concentrations of Cl and Na were related to the percentage of developed land and constructed impervious area in the drinking-water source area. Median concentrations of SO 4 in samples collected from the tributaries in the Cambridge Reservoir Basin (10.7 mg/L) were lower than those for the Stony Brook Reservoir Basin (18.0 mg/L). Concentrations of dissolved Cl and Na in samples and those concentrations estimated from continuous records of specific conductance (particularly during base flow) often were greater than the U.S. Environmental Protection Agency (EPA) secondary drinking-water standard for Cl (250 mg/L), the chronic aquatic-life guideline for Cl (230 mg/L), and the Massachusetts Department of Environmental Protection drinking-water guideline for Na (20 mg/L). Concentrations of TP (range from 0.008 to 0.69 mg/L in all subbasins) in tributary samples did not differ substantially between the Cambridge Reservoir and Stony Brook Reservoir Basins. About one-half of the concentrations of TP in samples collected during water years 2013–15 exceeded the EPA proposed reference concentration of 0.024 mg/L. For most tributaries, about 70 percent of the annual loads of Ca, Cl, Mg, Na, and SO 4 were associated with base flow. Concentrations of major ions were negatively correlated with streamflow, indicating that these constituents were diluted during stormflow and tend to increase during the summer when streamflow is low. In contrast, between 57 and 92 percent of the annual load for TP was transported during stormflows. Mean annual yields of Ca, Cl, Mg, Na, and SO 4 in the drinking-water source area were 13, 75, 2.6, 40, and 6.9 metric tons per square kilometer, respectively, for water years 2009–15. The mean annual yield of TP in the drinking-water source area for water years 2013–15 was 0.012 metric tons per square kilometer. Yields for major ions and TP were highest in tributary subbasins adjacent to Interstate 95. Temporal trends in mean annual concentrations for Cl and Na were not significant for water years 1998‒2015 (period of record by the USGS) for the outlet of the Cambridge Reservoir and for the main stem of Stony Brook downstream from the reservoir. Median values of base-flow concentrations of TP at three stations were higher for samples collected during base-flow conditions during water years 2005–7 than for samples collected during water years 2013–15. However, the results were not significant for statistical tests between concentrations in samples collected during storms for the same periods, indicating that the quality of stormwater remains similar.

Massachusetts