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At least 199 records · Page 11Linked to original sources

Modeling to evaluate the response of savanna-derived cropland to warming–drying stress and nitrogen fertilizers

Many savannas in West Africa have been converted to croplands and are among the world’s regions most vulnerable to climate change due to deteriorating soil quality. We focused on the savanna-derived cropland in northern Ghana to simulate its sensitivity to projected climate change and nitrogen fertilization scenarios. Here we show that progressive warming–drying stress over the twenty-first century will enhance soil carbon emissions from all kinds of lands of which the natural ecosystems will be more vulnerable to variation in climate variables, particularly in annual precipitation. The carbon emissions from all croplands, however, could be mitigated by applying nitrogen fertilizer at 30–60 kg N ha − 1 year − 1 . The uncertainties of soil organic carbon budgets and crop yields depend mainly on the nitrogen fertilization rate during the first 40 years and then are dominated by climate drying stress. The replenishment of soil nutrients, especially of nitrogen through fertilization, could be one of the priority options for policy makers and farm managers as they evaluate mitigation and adaptation strategies of cropping systems and management practices to sustain agriculture and ensure food security under a changing climate.

Climatic Change

Aluminum- and iron-based coagulation for in-situ removal of dissolved organic carbon, disinfection byproducts, mercury and other constituents from agricultural drain water

Agricultural production on wetland soils can be significant sources of dissolved organic carbon (DOC), disinfection byproduct precursors, mercury and nutrients to downstream water bodies and accelerate land subsidence. Presented as a potential solution for in-situ water quality improvement and land subsidence mitigation, chemically enhanced treatment wetlands (CETWs) were used to leverage both coagulation and wetland processes. In this study, we evaluated the performance of coagulants ferric sulfate (Fe dosing) and polyaluminum chloride (Al dosing) to remove pollutants from agricultural drain water using the coagulation system designed for CETWs. Both coagulation treatments removed over 70% DOC from source waters, resulting in removal efficiencies (mg-DOC removed per mg-metal dosed) of 1 under Al dosing and 0.5 under Fe dosing. Coagulation by both treatments preferentially removed UV254 active compounds compared to the bulk DOC concentration, suggesting coagulation targeted aromatics more effectively. Phosphates and haloacetic acids were also removed more readily, whereas trihalomethanes, dissolved organic nitrogen and filtered mercury species were removed at similar or lower rates than DOC. Dissolved inorganic nitrogen was not amenable to coagulation and removal was not observed. Freundlich, Langmuir and Monod models explained 33% of the variance for Al dosing and 78 – 89% of the variance for Fe dosing. All three models indicated Al dosing had higher removal efficiency and affinity for DOC than Fe dosing under study conditions, but when used to predict maximum removal efficiency there was no cohesiveness between the three models due to different model assumptions. Consideration of fluorescence dissolved organic matter and UV254 as surrogates for DOC concentration showed both were equally suitable before coagulant application, but as surrogates after coagulant application, neither could be deemed more fit as a surrogate since both were shown suitable for different treatment scenarios.

Ecological Engineering

Land cover mapping of North and Central America—Global Land Cover 2000

The Land Cover Map of North and Central America for the year 2000 (GLC 2000-NCA), prepared by NRCan/CCRS and USGS/EROS Data Centre (EDC) as a regional component of the Global Land Cover 2000 project, is the subject of this paper. A new mapping approach for transforming satellite observations acquired by the SPOT4/VGTETATION (VGT) sensor into land cover information is outlined. The procedure includes: (1) conversion of daily data into 10-day composite; (2) post-seasonal correction and refinement of apparent surface reflectance in 10-day composite images; and (3) extraction of land cover information from the composite images. The pre-processing and mosaicking techniques developed and used in this study proved to be very effective in removing cloud contamination, BRDF effects, and noise in Short Wave Infra-Red (SWIR). The GLC 2000-NCA land cover map is provided as a regional product with 28 land cover classes based on modified Federal Geographic Data Committee/Vegetation Classification Standard (FGDC NVCS) classification system, and as part of a global product with 22 land cover classes based on Land Cover Classification System (LCCS) of the Food and Agriculture Organisation. The map was compared on both areal and per-pixel bases over North and Central America to the International Geosphere–Biosphere Programme (IGBP) global land cover classification, the University of Maryland global land cover classification (UMd) and the Moderate Resolution Imaging Spectroradiometer (MODIS) Global land cover classification produced by Boston University (BU). There was good agreement (79%) on the spatial distribution and areal extent of forest between GLC 2000-NCA and the other maps, however, GLC 2000-NCA provides additional information on the spatial distribution of forest types. The GLC 2000-NCA map was produced at the continental level incorporating specific needs of the region.

Remote Sensing of Environment

Relations of groundwater quality to long-term surface disposal of produced water near the Midway-Sunset and Buena Vista Oil Fields, California, USA

Contamination of groundwater by oil-field fluids in proximity to oil and gas development has been an issue of concern to water users and regulators given long histories of development and legacy disposal practices. A robust set of geochemical tracers including petroleum hydrocarbon compounds, thermogenic gases, inorganic ion concentrations, stable isotopes, radioactive isotopes, and noble gases were used to assess if oil-field fluids mixed with groundwater near the Midway-Sunset and Buena Vista Oil Fields in California, USA. Results show evidence of mixing of oil-field fluids with groundwater within the study area from either anthropogenic or natural processes. Produced water plumes associated with modern surface disposal facilities, used since the late 1950s, extend up to 1.5 km and currently remain within the boundaries of the oil fields. Plumes associated with earlier routing of produced water down natural drainages and in large retention structures (Midway Basin and Sunset Basin) near the Buena Vista Lake Bed are present in groundwater east of the oil fields. Based on geochemical tracer evidence, aerial imagery, and aerial electromagnetic surveys, these legacy plumes reach the western portion of the Central Valley aquifer system, an important groundwater resource for agricultural and domestic supply. The legacy plume associated with Sunset Basin may further be detected downgradient in deeper groundwater beneath the southern extent of the Buena Vista Lake Bed based on the presence of thermogenic gases and petroleum hydrocarbon compounds.

California

Influence of grazing and land use on stream-channel characteristics among small dairy farms in the Eastern United States

Rotational grazing (RG) is a livestock management practice that rotates grazing cattle on a scale of hours to days among small pastures termed paddocks. It may beneficially affect stream channels, relative to other livestock management practices. Such effects and other beneficial effects on hydrology are important to RG's potential to provide a highly multifunctional mode of livestock farming. Previous comparisons of effects of RG and confinement dairy (CD) on adjoining streams have been restricted in scale and scope. We examined 11 stream-channel characteristics on a representative sample of 37 small dairy farms that used either RG or CD production methods. Our objectives were: (1) to compare channel characteristics on RG and CD farms, as these production methods are implemented in practice, in New York, Pennsylvania and Wisconsin, USA; and (2) to examine land use on these farms that may affect stream-channel characteristics. To help interpret channel characteristic findings, we examined on-farm land use in riparian areas 50 m in width along both sides of stream reaches and whole-farm land use. In all states, stream-channel characteristics on RG and CD farms did not differ. Whole-farm land use differed significantly between farm types; CD farms allocated more land to annual row crops, whereas RG farms allocated more land to pasture and grassland. However, land cover in 50 m riparian areas was not different between farm types within states; in particular, many RG and CD farms had continuously grazed pastures in riparian areas, typically occupied by juvenile and non-lactating cows, which may have contributed sediment and nutrients to streams. This similarity in riparian management practices may explain the observed similarity of farm types with respect to stream-channel characteristics. To realize the potential benefits of RG on streams, best management practices that affect stream-channel characteristics, such as protection of riparian areas, may improve aggregate effects of RG on stream quality and also enhance other environment, economic and social benefits of RG.

Renewable Agriculture and Food Systems

Emerging investigator series: Municipal wastewater as a year-round point source of neonicotinoid insecticides that persist in an effluent-dominated stream

Neonicotinoids in aquatic systems have been predominantly associated with agriculture, but some are increasingly being linked to municipal wastewater. Thus, the aim of this work was to understand the municipal wastewater contribution to neonicotinoids in a representative, characterized effluent-dominated temperate-region stream. Our approach was to quantify the spatiotemporal concentrations of imidacloprid, clothianidin, thiamethoxam, and transformation product imidacloprid urea: 0.1 km upstream, the municipal wastewater effluent, and 0.1 and 5.1 km downstream from the wastewater outfall (collected twice-monthly for one year under baseflow conditions). Quantified results demonstrated that wastewater effluent was a point-source of imidacloprid (consistently) and clothianidin (episodically), where chronic invertebrate exposure benchmarks were exceeded for imidacloprid (36/52 samples; 3/52 > acute exposure benchmark) and clothianidin (8/52 samples). Neonicotinoids persisted downstream where mass loads were not significantly different than those in the effluent. The combined analysis of neonicotinoid effluent concentrations, instream seasonality, and registered uses in Iowa all indicate imidacloprid, and seasonally clothianidin, were driven by wastewater effluent, whereas thiamethoxam and imidacloprid urea were primarily from upstream non-point sources (or potential in-stream transformation for imidacloprid urea). This is the first study to quantify neonicotinoid persistence in an effluent-dominated stream throughout the year—implicating wastewater effluent as a point-source for imidacloprid (year-round) and clothianidin (seasonal). These findings suggest possible overlooked neonicotinoid indoor human exposure routes with subsequent implications for instream ecotoxicological exposure.

Environmental Sciences: Processes & Impacts

Using the Soil and Water Assessment Tool (SWAT) to Simulate Runoff in Mustang Creek Basin, California

This study is an evaluation of the calibration and validation of the Soil and Water Assessment Tool (SWAT) version 2005 watershed model for the Mustang Creek Basin, San Joaquin Valley, California. The study is part of a national study on the process of agricultural chemical movement through the hydrologic system, which is being done by the U.S. Geological Survey (USGS) National Water-Quality Assessment program. The SWAT model was used to simulate streamflow in the Mustang Creek Basin on the basis of a set of model inputs derived and modified from various data sources. The 2005 version of the model was calibrated for 29 days in February 2004, and validated for 58 days in January and February 2005. Measured streamflow for a USGS gaging station was used for model calibration and validation. Results of the simulated monthly streamflow had a Nash Sutcliffe efficiency value of 0.72 during the calibration period. The 2005 version of the model was unsuccessful in simulating streamflow during the validation period, as indicated by a Nash Sutcliffe efficiency value of 0.33. This lack of a successful simulation probably is due to the limited amount of measured streamflow data available for calibration, the ephemeral nature of flows in Mustang Creek, and the fact that the SWAT model was developed primarily for long time period (2 years and more) simulations and not for limited monthly simulations as used in Mustang Creek.

Scientific Investigations Report

Water budget and water quality of Ward Lake, flow and water-quality characteristics of the Braden River estuary, and the effects of Ward Lake on the hydrologic system, west-central Florida

The Braden River is the largest tributary to the Manatee River. The river was dammed in 1936 to provide the city of Bradenton a source of freshwater supply. The resulting impoundment was called Ward Lake and had a storage capacity of about 585 million gallons. Reconstruction in 1985 increased the size of the reservoir to about 1,400 million gallons. The lake has been renamed the Bill Evers Reservoir and drains about 59 square miles. The Braden River watershed can be subdivided into three hydrologic reaches. The upper reach consists of a naturally incised free-flowing channel. The middle reach consists of a meandering channel affected by backwater as a result of the dam. The lower reach is a tidal estuary. Water budgets were calculated for the 1993 through 1997 water years. Mean surface-water inflow to Ward Lake for the 5-year period was 1,645 inches per year (equivalent depth over the surface of the lake), or about 81.8 percent of total inflow. Mean ground-water inflow was 311 inches per year, or about 15.5 percent. A mean of 55 inches of rain fell directly on the lake and accounted for only 2.7 percent. Mean surface-water outflow was 1,736 inches, or about 86.4 percent of total water leaving the lake. There was no net ground-water outflow from the lake. Mean surface-water withdrawal for public supply was 229 inches per year, or about 11.4 percent. Mean evaporation was 45 inches and accounted for only 2.2 percent of the mean outflow. Change in lake storage on the budget was negligible. Most chemical constituents contained in water flowing to Ward Lake meet the standards specified by the Florida Department of Environmental Protection and the U.S. Environmental Protection Agency. Phosphorus is the exception, exceeding the U.S. Environmental Protection Agency limits of 0.10 milligram per liter in most samples. However, the source of the phosphorus is naturally occurring phosphate deposits underlying the watershed. Organic nitrogen and orthophosphate are the dominant species of nutrients in the streams and the lake. A major source of water to the streams is the surficial aquifer system. Mineralized water pumped from the intermediate aquifer system and the Upper Floridan aquifer for irrigation of agricultural areas or golf courses has influenced the chemical composition of the surficial aquifer and surface-water systems. The Braden River estuary receives freshwater inflow from Ward Lake and from three major streams discharging downstream from the dam. Salinity levels in the estuary are affected by freshwater flow from these sources and by antecedent conditions in the estuary prior to flow events. The lowest salinity levels are often measured at the confluence with Williams and Gap Creeks rather than at the outfall from the lake. The chemical composition of water flowing from the tributaries to the estuary is similar to the chemical composition of water in the tributaries flowing to Ward Lake and does not appear to be affected by brackish water from high tides. Nitrogen concentrations in water from Glen Creek were greater than in water from all other tributaries in the watershed. Fertilizer from orange groves and stormwater runoff from urban and industrial areas affect the water quality in Glen Creek. The effects of the reservoir on the hydrology of the watershed were to change the middle reach of the river from a brackish water estuary ecosystem to a freshwater lake ecosystem, raise water levels in the surficial aquifer system adjacent to the river, change water quality, and reduce freshwater flow to the estuary during periods of low flow. The lake acts as a sink for total organic carbon, dissolved solids, calcium, chloride, and sulfate, thereby decreasing loads of these constituents to the estuary.

Water-Resources Investigations Report

Water-quality monitoring and process understanding in support of environmental policy and management

The quantity and quality of freshwater at any point on the landscape reflect the combined effects of many processes operating along hydrological pathways within a drainage basin/watershed/catchment. Primary drivers for the availability of water are landscape changes and patterns, and the processes affecting the timing, magnitude, and intensity of precipitation, including global climate change. The degradation of air, land, and water in one part of a drainage basin can have negative effects on users downstream; the time and space scales of the effects are determined by the residence time along the various hydrological pathways. Hydrology affects transport, deposition, and recycling of inorganic materials and sediment. These components affect biota and associated ecosystem processes, which rely on sustainable flows throughout a drainage basin. Human activities on all spatial scales affect both water quantity and quality, and some human activities can have a disproportionate effect on an entire drainage basin. Aquatic systems have been continuously modified by agriculture, through land-use change, irrigation and navigation, disposal of urban, mining, and industrial wastes, and engineering modifications to the environment. Interdisciplinary integrated basin studies within the last several decades have provided a more comprehensive understanding of the linkages among air, land, and water resources. This understanding, coupled with environmental monitoring, has evolved a more multidisciplinary integrated approach to resource management, particularly within drainage basins.

Conference Paper

Chloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States

A study of chloride in groundwater and surface water was conducted for the glacial aquifer system of the northern United States in forested, agricultural, and urban areas by analyzing data collected for the National Water-Quality Assessment Program from 1991 to 2004. Groundwater-quality data from a sampling of 1,329 wells in 19 states were analyzed. Chloride concentrations were greater than the secondary maximum contaminant level established by the U.S. Environmental Protection Agency of 250 milligrams per liter in 2.5 percent of samples from 797 shallow monitoring wells and in 1.7 percent of samples from 532 drinking-water supply wells. Water samples from shallow monitoring wells in urban areas had the largest concentration of chloride, followed by water samples from agricultural and forested areas (medians of 46, 12, and 2.9 milligrams per liter, respectively). An analysis of chloride:bromide ratios, by mass, and chloride concentrations compared to binary mixing curves for dilute groundwater, halite, sewage and animal waste, potassium chloride fertilizer, basin brines, seawater, and landfill leachate in samples from monitoring wells indicated multiple sources of chloride in samples from wells in urban areas and agricultural areas. Water from shallow monitoring wells in urban areas had the largest chloride:bromide ratio, and samples with chloride:bromide ratios greater than 1,000 and chloride concentrations greater than 100 milligrams per liter were dominated by halite; however, the samples commonly contained mixtures that indicated input from sewage or animal waste. Chloride:bromide ratios were significantly larger in samples from public-supply drinking-water wells than from private drinking-water wells, and ratios were significantly larger in all drinking-water wells in eastern and central regions of the glacial aquifer system than in west-central and western regions of the glacial aquifer system. Surface-water-quality data collected regularly during varying time periods from 1991-2004 from 100 basins dominated by forested, agricultural, or urban land in 15 states were analyzed to determine maximum measured chloride concentrations. Samples from 15 sites in east, central, and west-central areas, collected primarily in winter, had chloride concentrations higher than the U.S. Environmental Protection Agency recommended chronic criterion concentration for aquatic life of 230 milligrams per liter. Concentrations of chloride in base-flow samples were predictive of maximum measured chloride concentrations, indicating that inputs of chloride from groundwater and (or) point-source wastewater discharges increase the likelihood of samples exceeding the recommended chronic aquatic criterion. Multiple linear regression analyses showed that the density of major roads, potential evapotranspiration, and the percentage of annual runoff from saturated overland flow were significant factors in describing the range of maximum measured chloride concentrations in the basins studied. Chloride loads and yields were determined at 95 surface-water-monitoring stations in basins dominated by forested, agricultural, or urban land. Annual chloride yield was largest in the urban basins (median of 88 tons per square mile) and smallest in the forested basins (median of 6.4 tons per square mile). The median chloride yield in the agricultural basins was 15.4 tons per square mile. Multiple linear regression analyses showed that the density of highways (roads in U.S. highway system), the number of major wastewater discharges in the basin, potential evapotranspiration, and urban minus agricultural land area were significant factors in describing the range of average annual chloride yields. Upward trends in chloride loads were apparent in several urban basins for which additional long-term data were available. Increases in chloride loads over time may be related to a variety of factors, including increases in road area and consequent deicing, incr

Scientific Investigations Report

Shallow deformation on the Kirby Hills fault, Sacramento–San Joaquin Delta, California (USA), revealed from high-resolution seismic reflection data and coring in a fluvial system

The Sacramento–San Joaquin Delta (Delta) in California (USA) is an important part of the state’s freshwater system and is also a major source of agricultural and natural resources. However, the Delta is traversed by a series of faults that make up the easternmost part of the San Andreas fault system at this latitude and pose seismic hazard to this region. In this study, we use new high-resolution chirp subbottom data to map and characterize the shallow expression of the Kirby Hills fault, where it has been mapped to cross the Sacramento River at the western extent of the Delta. The fault is buried here, but we document a broad zone of deformation associated with the eastern strand of the fault that changes in character, along strike, across ~600 m of the river channel. Radiocarbon dates from sediment cores collected in the Sacramento River provide some minimum constraints on the age of deformation. We do not observe evidence of the western strand as previously mapped. We also discuss difficulties of conducting a paleoseismologic study in a fluvial environment.

California

Water quality and trend analysis of Colorado-Big Thompson system reservoirs and related conveyances, 1969 through 2000

The U.S. Geological Survey, in an ongoing cooperative monitoring program with the Northern Colorado Water Conservancy District, Bureau of Reclamation, and City of Fort Collins, has collected water-quality data in north-central Colorado since 1969 in reservoirs and conveyances, such as canals and tunnels, related to the Colorado–Big Thompson Project, a water-storage, collection, and distribution system. Ongoing changes in water use among agricultural and municipal users on the eastern slope of the Rocky Mountains in Colorado, changing land use in reservoir watersheds, and other water-quality issues among Northern Colorado Water Conservancy District customers necessitated a reexamination of water-quality trends in the Colorado–Big Thompson system reservoirs and related conveyances. The sampling sites are on reservoirs, canals, and tunnels in the headwaters of the Colorado River (on the western side of the transcontinental diversion operations) and the headwaters of the Big Thompson River (on the eastern side of the transcontinental diversion operations). Carter Lake Reservoir and Horsetooth Reservoir are off-channel water-storage facilities, located in the foothills of the northern Colorado Front Range, for water supplied from the Colorado–Big Thompson Project. The length of water-quality record ranges from approximately 3 to 30 years depending on the site and the type of measurement or constituent. Changes in sampling frequency, analytical methods, and minimum reporting limits have occurred repeatedly over the period of record. The objective of this report was to complete a retrospective water-quality and trend analysis of reservoir profiles, nutrients, major ions, selected trace elements, chlorophyll- a , and hypolimnetic oxygen data from 1969 through 2000 in Lake Granby, Shadow Mountain Lake, and the Granby Pump Canal in Grand County, Colorado, and Horsetooth Reservoir, Carter Lake, Lake Estes, Alva B. Adams Tunnel, and Olympus Tunnel in Larimer County, Colorado. This report summarizes and assesses: Water-quality and field-measurement profile data collected by the U.S. Geological Survey and stored in the U.S. Geological Survey National Water Information System, Time-series trends of chemical constituents and physical properties, Trends in oxygen deficits in the hypolimnion of the reservoirs in the late summer season by the seasonal Kendall trend test method, Nutrient limitation and trophic status indicators, and Water-quality data in terms of Colorado water-quality standards. Water quality was generally acceptable for primary uses throughout the Colorado–Big Thompson system over the site periods of record, which are all within the span of 1969 to 2000. Dissolved solids and nutrient concentrations were low and typical of a forested/mountainous/crystalline bedrock hydrologic setting. Most of the more toxic trace elements were rarely detected or were found in low concentrations, due at least in part to a relative lack of ore-mineral deposits within the drainage areas of the Colorado–Big Thompson Project. Constituent concentrations consistently met water-quality standard thresholds set by the State of Colorado. Trophic-State Index Values indicated mesotrophic conditions generally prevailed at reservoirs, based on available Secchi depth, total phosphorus concentrations, and chlorophyll- a concentrations. Based on plots of time-series values and concentrations and seasonal Kendall nonparametric trends testing, dissolved solids and most major ions are decreasing at most sites. Many of the nutrient data did not meet the minimum criteria for time-series testing; but for those that did, nutrient concentrations were generally stable (no statistical trend) or decreasing (ammonia plus organic nitrogen and total phosphorus). Iron and manganese concentrations were stable or decreasing at most sites that met testing criteria. Chlorophyll- a data were only collected for 11 years but generally indicated quasi-stable or downward temporal trends.

Colorado

Chemical and biological quality of water in part of the Everglades, southeastern Florida

A comprehensive monitoring network was established in a part of the Everglades to evaluate the quality of water being delivered to Everglades National Park. Physical, chemical, and biological parameters were determined in surface water, bottom sediment, and bulk precipitation (rainfall and dry fallout). The geology of the area, bottom sediment, bulk precipitation, natural, urban, and agricultural runoff, and the characteristics of the hydrologic system in the Everglades influence the type and concentration of each chemical constituent and how it affects the water quality. The quality of surface water in the agricultural area between Lake Okeechobee and the water conservation areas is markedly different from that of other surface water in southeastern Florida. In general, the water in this area is higher in concentrations of most chemical constituents. Man has engaged in cultural activities, both agricultural and urban, which have affected the water quality in the northern and eastern segments of the area of investigation. The quality of the water improves, however, as it flows to the south and east because there is minimal input from man's activities and many of the constituents are assimilated by plants, sorbed on organic material and clay in the bottom sediments, and entrapped within the sediments. Dilution by rainfall and concentration by evapotranspiration are also important factors that influence the quality of surface water in the area of investigation. The area of investigation in the Everglades is a sink for macronutrients, trace metals, and chlorinated-hydrocarbon insecticides. These constituents do not move through the system freely. They become tied up in various complexes and for that reason, the water being delivered to Everglades National Park is of better quality than the water entering the northern edge of the water conservation areas. The various physical and biological processes and chemical reactions combine to improve the water quality as the water flows southward. The data presented in this report may be used as a baseline for determination of future changes in water quality at the several places in the Everglades where recurrent sampling of rainfall, surface water, and bottom sediments was undertaken during the course of the investigation.

Florida

Hypothesis of historical effects from selenium on endangered fish in the Colorado River basin

Anthropogenic selenium contamination of aquatic ecosystems was first associated with cooling reservoirs of coal-fired power plants in the late 1970s, and later with drainage water from agricultural irrigation activities in the 1980s. In the 1990s, selenium contamination has been raised as a concern in the recovery of currently endangered fish in the Colorado River system. Widespread contamination from seleniferous drain waters from agriculture has been documented in the upper and lower Colorado River basins. Historically, irrigation started in the upper Colorado River basin in the late 1880s. In the 1930s, selenium concentrations in various drains, tributaries, and major rivers in the upper and lower Colorado River basins were in the 100 s and 1000 s of µg/L. Native fish inhabiting large rivers such as the Colorado pikeminnow and razorback sucker were abundant before 1890, but became rare after 1910 to 1920, before the influence of mainstem reservoirs in the upper and lower Colorado River. A hypothesis is presented that selenium contamination of the tributaries and major rivers of the Colorado River basin in the 1890 to 1910 period caused the decline of the endangered fish and continues to inhibit their recovery.

Human and Ecological Risk Assessment

Groundwater-flow and land-subsidence model of Antelope Valley, California

Antelope Valley, California, is a topographically closed basin in the western part of the Mojave Desert, about 50 miles northeast of Los Angeles. The Antelope Valley groundwater basin is about 940 square miles and is separated from the northern part of Antelope Valley by faults and low-lying hills. Prior to 1972, groundwater provided more than 90 percent of the total water supply in the valley; since 1972, it has provided between 50 and 90 percent. Most groundwater pumping in the valley occurs in the Antelope Valley groundwater basin, which includes the rapidly growing cities of Lancaster and Palmdale. Groundwater-level declines of more than 270 feet in some parts of the groundwater basin have resulted in an increase in pumping lifts, reduced well efficiency, and land subsidence of more than 6 feet in some areas. Future urban growth and limits on the supply of imported water may increase reliance on groundwater. In 2011, the Los Angeles County Superior Court of California ruled that the Antelope Valley groundwater basin is in overdraft—groundwater extractions are in excess of the Court-defined safe yield of the groundwater basin. The Court determined that the safe yield of the adjudicated area of the basin was 110,000 acre-feet per year (acre-ft/yr). Natural recharge is an important component of total groundwater recharge in Antelope Valley; however, the exact quantity and distribution of natural recharge, primarily in the form of mountain-front recharge, is uncertain, with total estimates ranging from 30,000 to 160,000 acre-ft/yr. Technical experts, retained by parties to the adjudication, used 60,000 acre-ft/yr to estimate the sustainable yield of the basin, and this value was used in this study. In order to better understand the uncertainty associated with natural recharge and to provide a tool to aid in groundwater management, a numerical model of groundwater flow and land subsidence in the Antelope Valley groundwater basin was developed using old and new geohydrologic information. The groundwater-flow system consists of three aquifers: the upper, middle, and lower aquifers. The three aquifers, which were identified on the basis of the hydrologic properties, age, and depth of the unconsolidated deposits, consist of gravel, sand, silt, and clay alluvial deposits and clay and silty clay lacustrine deposits. Prior to groundwater development in the valley, recharge was primarily the infiltration of runoff from the surrounding mountains. Groundwater flowed from the recharge areas to discharge areas around the playas where it discharged from the aquifer system as either evapotranspiration or from springs. Partial barriers to horizontal groundwater flow, such as faults, have been identified in the groundwater basin. Water-level declines owing to groundwater development have eliminated the natural sources of discharge, and pumping for agricultural and urban uses have become the primary source of discharge from the groundwater system. Infiltration of return flow from agricultural irrigation has become an important source of recharge to the aquifer system. The groundwater-flow model of the basin was discretized horizontally into a grid of 130 rows and 118 columns of square cells 1 kilometer (0.621 mile) on a side, and vertically into four layers representing the upper (two layers), middle (one layer), and lower (one layer) aquifers. Faults that were thought to act as horizontal-flow barriers were simulated in the model. The model was calibrated to simulate steady-state conditions, represented by 1915 water levels and transient-state conditions during 1915–95, by using water-level and subsidence data. Initial estimates of the aquifer-system properties and stresses were obtained from a previously published numerical model of the Antelope Valley groundwater basin; estimates also were obtained from recently collected hydrologic data and from results of simulations of groundwater-flow and land-subsidence models of the Edwards Air Force Base area. Some of these initial estimates were modified during model calibration. Groundwater pumpage for agriculture was estimated on the basis of irrigated crop acreage and crop consumptive-use data. Pumpage for public supply, which is metered, was compiled and entered into a database used for this study. Estimated annual agricultural pumpage peaked at 395,000 acre-feet (acre-ft) in 1951 and then declined because of declining agricultural production. Recharge from irrigation return flows was assumed to be 30 percent of agricultural pumpage; delays associated with return flow moving through the unsaturated zone were also simulated. The annual quantity of mountain-front recharge initially was based on estimates from previous studies. The model was calibrated using the PEST software suite; prior information from the area was incorporated through the use of Tikhonov regularization. During model calibration, the estimated mountain-front recharge was reduced from the previous estimate of 30,300 acre-ft/yr to 29,150 acre-ft/yr. Results of the simulations using the calibrated model indicate that simulated groundwater pumpage exceeded recharge in most years, resulting in an estimated cumulative depletion in groundwater storage of 8,700,000 acre-ft during the transient-simulation period (1915–2005). About 15,000,000 acre-ft of cumulative groundwater pumpage was simulated during the transient-simulation period (1915–2005), reaching a maximum rate of about 400,000 acre-ft/yr in 1951. Groundwater pumpage resulted in simulated hydraulic heads declining by more than 150 feet (ft) compared to 1915 conditions in agricultural areas. The decline in hydraulic head in the groundwater basin is the result of this depletion of groundwater storage. In turn, the simulated decline in hydraulic head in the groundwater basin has resulted in the decrease in natural discharge from the basin and has caused compaction of aquitards, resulting in land subsidence. The areal distribution of total simulated land subsidence for 2005, after about 90 years of groundwater development, indicates that land subsidence occurred throughout almost the entire Lancaster subbasin, with a maximum of about 9.4 ft in the central and eastern parts of the subbasin. An important objective of this study was to systematically address the uncertainty in estimates of natural recharge and related aquifer parameters by using the groundwater-flow and land-subsidence model with observational data and expert knowledge. After the model was calibrated to the observations and a reasonable parameter set obtained, the parameter null space—parameter values that do not appreciably affect the model calibration but may have importance for prediction—was identified. The effect of parameter uncertainty on the estimation of mountain-front recharge was addressed using the Null-Space Monte Carlo method. The Pareto trade-off method of visualizing uncertainty was also used to portray the reasonableness of larger natural-recharge rates. Results indicate that the total mountain-front recharge likely ranges between 28,000 and 44,000 acre-ft/yr, which is appreciably less than published estimates of 60,000 acre-ft/yr. Additionally, expected errors associated with agricultural pumpage estimates used in this study were found to have relatively little effect on the estimates of mountain-front recharge, reflecting the difficulty in increasing recharge through manipulation of other components of the water budget. The calibrated model was used to simulate the response of the aquifer to potential future pumping scenarios: (1) no change in the distribution of pumpage, or status quo; (2) redistribution of pumpage; and (3) artificial recharge. All three of these scenarios specify a total pumpage throughout the Antelope Valley of 110,000 acre-ft/yr according to the safe yield value ruled by the Los Angeles County Superior Court of California. This reduction in groundwater pumpage is assumed uniform throughout the basin, based on a 10-percent reduction of the total pumpage in 2005 to achieve the 110,000 acre-ft/yr level. The calibrated Antelope Valley groundwater-flow and land-subsidence model was used to simulate the hydrologic effects of the three groundwater-management scenarios during a 50-year period by using the reduced, temporally constant, pumpage distribution. Results from the first scenario indicated that the total drawdown observed since predevelopment would continue, with values exceeding 325 ft near Palmdale; consequently, land subsidence would also continue, with additional subsidence (since 2005) exceeding 3 ft in the central part of the Lancaster subbasin. The second scenario evaluated redistributing pumpage from areas in the Lancaster subbasin where simulated hydraulic-head declines were the greatest to areas where declines were smallest. Neither a formal optimization algorithm nor water-rights allocations were considered when redistributing the pumpage. Results indicated that hydraulic heads near Palmdale, where the pumpage was reduced, would recover by about 200 ft compared to 2005 conditions, with only 30 ft of additional drawdown in the northwestern part of the Lancaster subbasin, where the pumpage was increased. The magnitude of the simulated additional land subsidence decreased slightly compared to the first, status quo, scenario but land subsidence continued to be simulated throughout most of the northern part of the Lancaster subbasin. The third scenario consisted of two artificial-recharge simulations along the Upper Amargosa Creek channel and at a site located north of Antelope Buttes. Results indicate that applying artificial recharge at these sites would yield continued drawdowns and associated land subsidence. However, the magnitudes of drawdown and subsidence would be smaller than those simulated in the status quo scenario, indicating that artificial-recharge operations in the Antelope Valley could be expected to reduce the magnitude and extent of continued water-level declines and associated land subsidence.

California

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas -- Shallow ground-water quality and land use in the Albuquerque area, central New Mexico, 1993

This report describes the quality of shallow ground water and the relations between land use and the quality of that shallow ground water in an urban area in and adjacent to Albuquerque, New Mexico. Water samples were collected from 24 shallow wells. Samples were analyzed for selected common constituents, nutrients, trace elements, radionuclides, volatile organic compounds, and pesticides. The study area, which is in the Albuquerque Basin in central New Mexico, was limited to the Rio Grande flood plain; depth to water in this area generally is less than 25 feet. The amount and composition of recharge to the shallow ground-water system are important factors that affect shallow ground-water composition in this area. Important sources of recharge that affect shallow ground-water quality in the area include infiltration of surface water, which is used in agricultural land-use areas to irrigate crops, and infiltration of septic-system effluent in residential areas. Agricultural land use represents about 28 percent of the area, and residential land use represents about 35 percent of the total study area. In most of the study area, agricultural land use is interspersed with residential land use and neither is the dominant land use in the area. Land use in the study area historically has been changing from agricultural to urban. The composition of shallow ground water in the study area varies considerably. The dissolved solids concentration in shallow ground water in the study area ranges from 272 to 1,650 milligrams per liter, although the relative percentages of selected cations and anions do not vary substantially. Calcium generally is the dominant cation and bicarbonate generally is the dominant anion. Concentrations of nutrients generally were less than 1 milligram per liter. The concentration of many trace elements in shallow ground water was below or slightly above 1 microgram per liter and there was little variation in the concentrations. Barium, iron, manganese, molybdenum, and uranium were the only trace elements analyzed for that had median concentrations greater than 5 micrograms per liter. Volatile organic compounds were detected in 5 of 24 samples. Cis-1,2-dichloroethene and 1,1-dichloroethane were the most commonly detected volatile organic compounds (detected in two samples each). Pesticides were detected in 8 of 24 samples. Prometon was the most commonly detected pesticide (detected in 5 of 24 samples). Concentrations of volatile organic compounds and pesticides detected were much smaller than any U.S. Environmental Protection Agency standards that have been established. Infiltration of surface water and the evaporation or transpiration of this water, which partially is the result of past and present agricultural land use, seem to affect the concentrations of common constituents in shallow ground water in the study area. The small excess chloride in shallow ground water relative to surface water that has been affected by evaporation or transpiration could be due to mixing of shallow ground water with small amounts of precipitation/bulk deposition or septic-system effluent. Infiltration of septic-system effluent (residential land use) has affected the shallow ground-water composition in parts of the study area on the basis of the small dissolved oxygen concentrations, large dissolved organic carbon concentrations, and excess chloride. Despite the loading of nitrogen to the shallow ground-water system as the result of infiltration of septic-system effluent, the small nitrogen concentrations in shallow ground water probably are due to the small dissolved oxygen concentrations and relatively large dissolved organic carbon concentrations. The small concentrations and lack of variation of most trace elements indicate that land use has not substantially affected the concentration

New Mexico

A case study examining the efficacy of drainage setbacks for limiting effects to wetlands in the Prairie Pothole Region, USA

The enhancement of agricultural lands through the use of artificial drainage systems is a common practice throughout the United States, and recently the use of this practice has expanded in the Prairie Pothole Region. Many wetlands are afforded protection from the direct effects of drainage through regulation or legal agreements, and drainage setback distances typically are used to provide a buffer between wetlands and drainage systems. A field study was initiated to assess the potential for subsurface drainage to affect wetland surface-water characteristics through a reduction in precipitation runoff, and to examine the efficacy of current U.S. Department of Agriculture drainage setback distances for limiting these effects. Surface-water levels, along with primary components of the catchment water balance, were monitored over 3 y at four seasonal wetland catchments situated in a high-relief terrain (7–11% slopes). During the second year of the study, subsurface drainage systems were installed in two of the catchments using drainage setbacks, and the drainage discharge volumes were monitored. A catchment water-balance model was used to assess the potential effect of subsurface drainage on wetland hydrology and to assess the efficacy of drainage setbacks for mitigating these effects. Results suggest that overland precipitation runoff can be an important component of the seasonal water balance of Prairie Pothole Region wetlands, accounting on average for 34% (19–49%) or 45% (39–49%) of the annual (includes snowmelt runoff) or seasonal (does not include snowmelt) input volumes, respectively. Seasonal (2014–2015) discharge volumes from the localized drainage systems averaged 81 m 3 (31–199 m 3 ), and were small when compared with average combined inputs of 3,745 m 3 (1,214–6,993 m 3 ) from snowmelt runoff, direct precipitation, and precipitation runoff. Model simulations of reduced precipitation runoff volumes as a result of subsurface drainage systems showed that ponded wetland surface areas were reduced by an average of 590 m 2 (141–1,787 m 2 ), or 24% (3–46%), when no setbacks were used (drainage systems located directly adjacent to wetland). Likewise, wetland surface areas were reduced by an average of 141 m 2 (23–464 m 2 ), or 7% (1–28%), when drainage setbacks (buffer) were used. In totality, the field data and model simulations suggest that the drainage setbacks should reduce, but not eliminate, impacts to the water balance of the four wetlands monitored in this study that were located in a high-relief terrain. However, further study is required to assess the validity of these conclusions outside of the limited parameters (e.g., terrain, weather, soils) of this study and to examine potential ecological effects of altered wetland hydrology.

North Dakota

Character and evolution of the ground-water flow system in the central part of the western San Joaquin Valley, California

The occurrence of selenium in agricultural drain water derived from the western San Joaquin Valley, California, has focused concern on the ground-water flow system of the western valley. In this investigation, previous work and recently collected texture and water-level data are used to evaluate the character and evolution of the regional ground-water flow system in the central part of the western valley, with particular emphasis on the deposits overlying the Corcoran Clay Member of the Tulare Formation. The Corcoran Clay Member, where present, divides the flow system into an upper semiconfined zone and a lower con-fined zone. Above the Corcoran, three hydrogeologic units can be recognized: Coast Range alluvium, Sierran sand, and flood-basin deposits. These units differ in texture, hydrologic properties, and oxidation state. The development of irrigated agriculture in the central part of the western valley has significantly altered the flow system. Percolation of irrigation water past crop roots has caused a rise in the altitude of the water table in midfan and distal-fan areas. Pumpage of ground water from wells has caused a lowering of the water table beneath parts of the fanheads and a lowering of the potentiometric surface of the confined zone over much of the western valley. The combination of percolation and pumpage has resulted in development of a large downward hydraulic head gradient in the semi-confined zone and has created a groundwater divide along the western margin of the valley. Surface-water deliveries from the California Aqueduct have allowed a decrease in pumpage and a consequent recovery in hydraulic head throughout the system.

California