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Road salt collection and redistribution at an urban rain garden on sandy soil, Gary, Indiana

Rain gardens installed as green infrastructure to divert storm runoff from entering combined sewers also collect dissolved constituents and particulates. An urban rain garden in northwestern Indiana, USA, was continuously monitored from November 2019 to May 2021 to evaluate the fate of dissolved constituents entering the rain garden in runoff. Physical and chemical properties of soils in the rain garden were also monitored, along with underlying groundwater. Linear regression models relating specific conductance to chloride concentration indicated that the 0.0371-ha (3998 square feet) rain garden collected approximately 1490 kg (3285 pounds) of road salt from the surrounding 0.2228 ha (24,500 square feet) of impervious surfaces. Soils and groundwater were seasonally affected by road salt application but carryover from year to year was not indicated. Rain garden soil permeability (5.20 × 10 −5 to 9.72 × 10 −5 m/s) remained unchanged during the study period and soil organic carbon generally increased under native vegetation. The results suggest that a rain garden built on sandy soil can divert substantial quantities of runoff and dissolved constituents from combined sewers; however, chloride is transported to sub-infrastructure groundwater that eventually discharges to adjacent waterways with concentrations lower than those observed in runoff.

Indiana↗

Physical Climate Forces

Key Findings The coasts of the U.S. are home to many large urban centers and important infrastructure such seaports, airports, transportation routes, oil import and refining facilities, power plants, and military bases. All are vulnerable to varying degrees to impacts of global warming such as sea-level rise, storms, and flooding. High Confidence. Physical observations collected over the past several decades from the land, coasts, oceans, and the atmosphere, as well as environmental indicators, show that warming and some related environmental changes are occurring globally at rates greater than can be expected due to natural processes. These climate-related changes are highly varied, but some are likely due in large part to anthropogenically increased atmospheric concentrations of greenhouse gases and altered land surface properties. High Confidence. Findings from many independent scientific studies conclude that these changes are consistent with global warming. The primary changes observed are rising sea level and average global air, land, and ocean temperatures; heightening temperature and precipitation extremes in some regions; and increasing levels of oceans acidification and rates of glacier and ice sheet melt. High Confidence. Most coastal landforms, such as barrier islands, deltas, bays, estuaries, wetlands, coral reefs, are highly dynamic and sensitive to even small changes in physical forces and feedbacks such as warming, storms, ocean circulation, waves and currents, flooding, sediment budgets, and sea-level rise. High Confidence. The effects of sea-level rise on coasts vary considerably from region-to-region and over a range of spatial and temporal scales. Land subsidence in certain locations causes relative sea-level rise to exceed global mean sea-level rise. Land uplift such as that found in Alaska and the Northwestern Pacific coast can reduce effects of global mean rise. The effects will be greatest and most immediate on low-relief, low-elevation parts of the U.S. coast along the Gulf of Mexico, mid-Atlantic states, northern Alaska, Hawaii, and island territories and especially on coasts containing deltas, coastal plains, tidal wetlands, bays, estuaries, and coral reefs. Beaches and wetlands on steep cliff coasts and shores backed with seawalls may be unable to move landward or maintain their landform with sea-level rise. Many areas of the coast are especially vulnerable because of the often detrimental effects of development on natural processes. High Confidence. The gradual inundation from recent sea-level rise is evident in many regions such as the mid-Atlantic and Louisiana where high tides regularly flood roads and areas that were previously dry, and in stands of “ghost forests,” in which trees are killed by intrusion of brackish water. High Confidence. Sea level change and storms are dominant driving forces of coastal change as observed in the geologic record of coastal landforms. Increasingly, sea-level rise will become a hazard for coastal regions because of continued global mean sea-level rise, including possibly accelerated rates of rise that increase risk to coastal regions. As the global climate continues to warm and ice sheets melt, coasts will become more dynamic and coastal cities and low-lying areas will be increasingly exposed to erosion, inundation, and flooding. High Confidence. No coordinated, interagency process exists in the U.S. for identifying agreed upon global mean sea-level rise projections for the purpose of coastal planning, policy, or management, even though this is a critical first step in assessing coastal impacts and vulnerabilities. High Confidence. Global sea level rose at a rate of 1.7 millimeters/year during the 20th century. The rate has increased to over 3 millimeters/year in the past 20 years and scientific studies suggest high confidence (>9 in 10 chance) that global mean sea level will rise 0.2 to 2 meters by the end of this century. Some regions such as Louisiana and the Chesapeake Bay will experience greater relative rise due to factors such as land subsidence, gravitational redistribution of ice-sheet meltwater, ocean circulation changes, and regional ocean thermostatic effects. Other regions undergoing land uplift, such as Alaska, will experience lesser sea-level rise. High Confidence. Variability in the location and time-of-year of storm genesis can influence landfalling storm characteristics, and even small changes can lead to large changes in landfalling location and impact. Although scientists have only low confidence in the sign of projected changes to the coast of storm-related hazards that depend on a combination of factors such as frequency, track, intensity, and storm size, any sea-level rise is virtually certain to exacerbate storm-related hazards. High Confidence. Although sea-level rise and climate change have occurred in the past, the increasing human presence in the coastal zone will make the impacts different for the future. Land use and other human activities often inhibit the natural response of physical processes and adaptation by plants and animals. In some areas, erosion and wetland loss are common because sediment budgets have been reduced, while, in other regions, excess sediment is in-filling harbors, channels, and bays. High Confidence. Observations continue to indicate an ongoing, warming-induced intensification of the hydrologic cycle that will likely result in heavier precipitation events and, combined with sea-level rise and storm surge, an increased flooding severity in some coastal areas, particularly the northeast U.S. Moderate Confidence. Temperature is primarily driving environmental change in the Alaskan coastal zone. Sea ice and permafrost make northern regions particularly susceptible to temperature change. For example, an increase of two degrees Celsius could basically transform much of Alaska from frozen to unfrozen, with extensive implications. Portions of the north and west coast of Alaska are seeing dramatic increases in the rate of coastal erosion and flooding due to sea ice loss and permafrost melting. As a consequence, several coastal communities are planning to relocate to safer locations. Relocation is a difficult decision that is likely to become more common in the future for many coastal regions. High Confidence. Methane is a primary greenhouse gas. Large reserves of methane are bound-up in Alaska’s frozen permafrost. These are susceptible to disturbance and methane release if the Arctic continues to warm. The additional methane released may result in even greater greenhouse warming of the atmosphere. High Confidence.

Book chapter↗

Geologie study off gravels of the Agua Fria River, Phoenix, AZ

The annual consumption of sand and gravel aggregate in 2006 in the Phoenix, AZ metropolitan area was about 76 Mt (84 million st) (USGS, 2009), or about 18 t (20 st) per capita. Quaternary alluvial deposits in the modern stream channel of the Agua Fria River west of Phoenix are mined and processed to provide some of this aggregate to the greater Phoenix area. The Agua Fria drainage basin (Fig. 1) is characterized by rugged mountains with high elevations and steep stream gradients in the north, and by broad alluvial filled basins separated by elongated faultblock mountain ranges in the south. The Agua Fria River, the basin’s main drainage, flows south from Prescott, AZ and west of Phoenix to the Gila River. The Waddel Dam impounds Lake Pleasant and greatly limits the flow of the Agua Fria River south of the lake. The southern portion of the watershed, south of Lake Pleasant, opens out into a broad valley where the river flows through urban and agricultural lands to its confluence with the Gila River, a tributary of the Colorado River.

Mining Engineering↗

Hydrogeology of the Sulphur Springs area, Tampa, Florida

The Sulfur Springs area includes about 56 square miles in west-central Hillsborough County, Florida. The north-central part of the city of Tampa is highly urbanized; the north-west part of the area is rural or undeveloped. The area has numerous sinkholes, two of which are used as retention basins for urban storm runoff. An intermittent stream discharges into a sinkhole that is hydraulically connected with the Floridian aquifer. A well-developed cavity system occurs in the upper part of the aquifer in the southwestern and southeastern parts of the area. Groundwater velocities of 4,200 to 9,200 feet per day were determined from dye tests conducted in a sinkhole area north of Sulfur Springs. Sulfur Springs provides the city of Tampa a supplemental water supply of 20 million gallons per day. Periodically, the spring pool is closed to swimming because of the high bacteria counts in the water. The source of bacteria appears to be an internally drained sinkhole area north of the spring. In 1980, groundwater use in the study area, excluding withdrawals from Sulphur Springs, was 7.2 million gallons per day, largely for public water supplies. The city of Tampa pumped an average of 48.5 million gallons per day from the Tampa Dam Reservoir on the Hillsborough River. (USGS)

Water-Resources Investigations Report↗

Effect of erosion-control structures on sediment and nutrient transport, Edgewood Creek drainage, Lake Tahoe basin, Nevada, 1981-83

Three sites in the Edgewood Creek basin with a combined drainage area of about 1.2 sq mi were selected to assess the effect of erosion-control structures along Nevada State Highway 207, on sediment and nutrient transport. The flow at site one is thought to have been largely unaffected by urban development, and was completely unaffected by erosion control structures. The flow at site two was from a basin affected by urban development and erosion control structures. Site three was downstream from the confluence of streams measured at sites one and two. Most data on streamflow and water quality were collected between June 1981 and May 1983 to assess the hydrologic characteristics of the three sites. As a result of the erosion control structures, mean annual concentrations of total sediment were reduced from about 24,000 to about 410 mg/l at site two and from about 1,900 to about 190 ml/l at site three. Sediment loads were reduced from about 240 to about 10 tons/year at site two and from about 550 to about 110 tons/year at site three. At site one, in contrast, mean concentrations and loads remained low throughout the study period. At site two, sediment particle size changed from predominately coarse prior to construction, to predominately fine thereafter; at site three, it changed from about half coarse sediments to predominately fine. Mean concentration and loads of total iron also were significantly reduced after construction at sites two and three, whereas mean concentrations of nitrogen and phosphorus species did not change appreciably. (Author 's abstract)

Water-Resources Investigations Report↗

Historical changes in annual peak flows in Maine and implications for flood-frequency analyses

To safely and economically design bridges, culverts, and other structures that are in or near streams (fig. 1 for example), it is necessary to determine the magnitude of peak streamflows such as the 100-year flow. Flood-frequency analyses use statistical methods to compute peak flows for selected recurrence intervals (100 years, for example). The recurrence interval is the average number of years between peak flows that are equal to or greater than a specified peak flow. Floodfrequency analyses are based on annual peak flows at a stream. It has long been assumed that annual peak streamflows are stationary over very long periods of time, except in river basins subject to urbanization, regulation, and other direct human activities. Stationarity is the concept that natural systems fluctuate within an envelope of variability that does not change over time (Milly and others, 2008). Because of the potential effects of global warming on peak flows, the assumption of peak-flow stationarity has recently been questioned (Milly and others, 2008). Maine has many streamgaging stations with 50 to 105 years of recorded annual peak streamflows. This long-term record has been tested for historical flood-frequency stationarity, to provide some insight into future flood frequency (Hodgkins, 2010). This fact sheet, prepared by the U.S. Geological Survey (USGS) in cooperation with the Maine Department of Transportation (MaineDOT), provides a partial summary of the results of the study by Hodgkins (2010).

Fact Sheet↗

Velocity and Density Models Incorporating the Cascadia Subduction Zone for 3D Earthquake Ground Motion Simulations

In support of earthquake hazards and ground motion studies in the Pacific Northwest, three-dimensional P- and S-wave velocity (3D Vp and Vs) and density (3D rho) models incorporating the Cascadia subduction zone have been developed for the region encompassed from about 40.2°N to 50°N latitude, and from about -122°W to -129°W longitude. The model volume includes elevations from 0 km to 60 km (elevation is opposite of depth in model coordinates). Stephenson and Frankel (2003) presented preliminary ground motion simulations valid up to 0.1 Hz using an earlier version of these models. The version of the model volume described here includes more structural and geophysical detail, particularly in the Puget Lowland as required for scenario earthquake simulations in the development of the Seattle Urban Hazards Maps (Frankel and others, 2007). Olsen and others (in press) used the model volume discussed here to perform a Cascadia simulation up to 0.5 Hz using a Sumatra-Andaman Islands rupture history. As research from the EarthScope Program (http://www.earthscope.org ) is published, a wealth of important detail can be added to these model volumes, particularly to depths of the upper-mantle. However, at the time of development for this model version, no EarthScope-specific results were incorporated. This report is intended to be a reference for colleagues and associates who have used or are planning to use this preliminary model in their research. To this end, it is intended that these models will be considered a beginning template for a community velocity model of the Cascadia region as more data and results become available.

Open-File Report↗

Occurrence of organic wastewater compounds in drinking water, wastewater effluent, and the Big Sioux River in or near Sioux Falls, South Dakota, 2001-2004

The U.S. Geological Survey (USGS) in cooperation with the city of Sioux Falls conducted several rounds of sampling to determine the occurrence of organic wastewater compounds (OWCs) in the city of Sioux Falls drinking water and waste-water effluent, and the Big Sioux River in or near Sioux Falls during August 2001 through May 2004. Water samples were collected during both base-flow and storm-runoff conditions. Water samples were collected at 8 sites, which included 4 sites upstream from the wastewater treatment plant (WWTP) discharge, 2 sites downstream from the WWTP discharge, 1 finished drinking-water site, and 1 WWTP effluent (WWE) site. A total of 125 different OWCs were analyzed for in this study using five different analytical methods. Analyses for OWCs were performed at USGS laboratories that are developing and/or refining small-concentration (less than 1 microgram per liter (ug/L)) analytical methods. The OWCs were classified into six compound classes: human pharmaceutical compounds (HPCs); human and veterinary antibiotic compounds (HVACs); major agricultural herbicides (MAHs); household, industrial,and minor agricultural compounds (HIACs); polyaromatic hydrocarbons (PAHs); and sterol compounds (SCs). Some of the compounds in the HPC, MAH, HIAC, and PAH classes are suspected of being endocrine-disrupting compounds (EDCs). Of the 125 different OWCs analyzed for in this study, 81 OWCs had one or more detections in environmental samples reported by the laboratories, and of those 81 OWCs, 63 had acceptable analytical method performance, were detected at concentrations greater than the study reporting levels, and were included in analyses and discussion related to occurrence of OWCs in drinking water, wastewater effluent, and the Big Sioux River. OWCs in all compound classes were detected in water samples from sampling sites in the Sioux Falls area. For the five sampling periods when samples were collected from the Sioux Falls finished drinking water, only one OWC was detected at a concentration greater than the study reporting level (metolachlor; 0.0040 ug/L). During base-flow conditions, Big Sioux River sites upstream from the WWTP discharge had OWC contributions that primarily were from nonpoint animal or crop agriculture sources or had OWC concentrations that were minimal. The influence of the WWTP discharge on OWCs at downstream river sites during base-flow conditions ranged from minimal influence to substantial influence depending on the sampling period. During runoff conditions, OWCs at sites upstream from the WWTP discharge probably were primarily contributed by nonpoint animal and/or crop agriculture sources and possibly by stormwater runoff from nearby roads. OWCs at sites downstream from the WWTP discharge probably were contributed by sources other than the WWTP effluent discharge, such as stormwater runoff from urban and/or agriculture areas and/or resuspension of OWCs adsorbed to sediment deposited in the Big Sioux River. OWC loads generally were substantially smaller for upstream sites than downstream sites during both base-flow and runoff conditions.discharge had OWC contributions that primarily were from nonpoint animal or crop agriculture sources or had OWC concentrations that were minimal. The influence of the WWTP discharge on OWCs at downstream river sites during base-flow conditions ranged from minimal influence to substantial influence depending on the sampling period. During runoff conditions, OWCs at sites upstream from the WWTP discharge probably were primarily contributed by nonpoint animal and/or crop agriculture sources and possibly by stormwater runoff from nearby roads. OWCs at sites downstream from the WWTP discharge probably were contributed by sources other than the WWTP effluent discharge, such as stormwater runoff from urban and/or agriculture areas and/or resuspension of OWCs adsorbed to sediment deposited in the Big Sioux River. OWC loads generally were substantially smaller for

South Dakota↗

Colonization of southern flying squirrels (Glaucomys volans) to urban Nebraska: Range expansion or human assisted translocation?

Southern flying squirrels ( Glaucomys volans; Linnaeus 1758) were first observed in Lincoln, Nebraska, in 2018, 80 km north of their described range. Given that southern flying squirrels are a species of concern within Nebraska, determining the origin of this new population (natural expansion or pet-trade) garnered interest from state biologists. Further, the recent colonization of Lincoln by southern flying squirrels presents a unique opportunity to investigate the genetic implications of a founding event on a small arboreal mammal. The Lincoln population had genetic characteristics suggestive of a single-event colonization with fewer rare alleles and lower genetic diversity than potential source populations and a high genetic variation between populations. Sample size and absence of other geographically close populations in our data set make it difficult to ascertain the origin of the Lincoln population. Based on shared co-ancestry and membership assignment clustering algorithms, the Lincoln population had greater genetic associations with an individual sampled from the native south-eastern Nebraska population relative to other studied locations, suggesting that Lincoln was colonized by a native population.

Nebraska↗

Network analysis of a northern long-eared bat (Myotis septentrionalis) maternity colony in a suburban forest patch

Many bat species are highly social, forming groups of conspecifics, particularly during the maternity season. In temperate North America, these social groups are typically comprised of closely related individuals or individuals that share some common trait (i.e. reproductive state or shared hibernacula from the previous winter). In the summer, when bats use forests for day-roosts, these social groups often demonstrate nonrandom patterns of periodically associating in common roosts and disassociating using different roosts as a ‘fission–fusion society’. As cave hibernating bat species in North America continue to decline due to the impacts of White-nose Syndrome, opportunities to describe these dynamics are becoming rare. Unfortunately, these patterns often are still poorly documented, yet understanding these behaviors is critical for species-specific habitat conservation and management. In our study, we tracked female northern long-eared bats ( Myotis septentrionalis ) to their day-roosts in a small, suburban forest fragment in coastal New York, USA, in the summers of 2018 and 2019. We confirmed that the bats shared roost sites and, using network analyses, analyzed social dynamics and space use. In contrast to previous research on this imperiled species in large, unfragmented core forests, we found a more dense, connected roost network that concentrated around forest patch edges. Unusual for this species, primary roosts were anthropogenic structures. Our findings suggest that northern long-eared bats can utilize small forest patches and that incorporation of specific types of anthropogenic roosts might be an effective strategy for long-term conservation in more urbanized landscapes where forest management actions to enhance day-roosting conditions a

New York↗

Description and Analytical Results for Deposited Dust Samples from a Two-Year Monitoring Program Near Deer Trail, Colorado, USA, 2006-2007

Biosolids reclaimed from municipal wastewater have been applied since 1993 on nonirrigated farmland and rangeland east of Deer Trail, Colo., by Metro Wastewater Reclamation District of Denver. The U.S. Geological Survey has monitored ground water at this site since 1993, and began monitoring the biosolids, soils, and stream sediments in 1999. To investigate the possible effects of airborne dust blowing from the application fields, passive dust samplers were deployed in 2006 and 2007. These samplers measured the quantity and composition of dust being deposited downwind of a farmed field where biosolids had been applied, compared to a farmed field upwind of the application area. The dust-deposition rates and dust compositions measured at the two study sites are consistent with rates and compositions measured elsewhere in Utah, Nevada, and California using the same methods and equipment. Higher deposition rates were measured at the biosolids site compared to the control site during 2006. Higher deposition rates at both sites appear to be associated with episodes of cultivation and harvest during dry periods. No consistent differences in elements likely to be associated with biosolids disposal were detected between the sites. However, the contents of copper, lead, and zinc in the dust samples are generally much higher than average values of these elements in crustal rocks and sediments. Such values for dust samples are consistent with measurements on modern dust samples from southern Nevada and California and probably reflect inputs from regional urban and manufacturing activities.

Open-File Report↗

Coastal wetlands in the Anthropocene

We review the functioning and sustainability of coastal marshes and mangroves. Urbanized humans have a 7,000-year-old enduring relationship to coastal wetlands. Wetlands include marshes, salt flats, and saline and freshwater forests. Coastal wetlands occur in all climate zones but are most abundant in deltas. Mangroves are tropical, whereas marshes occur from tropical to boreal areas. Quantification of coastal wetland areas has advanced in recent years but is still insufficiently accurate. Climate change and sea-level rise are predicted to lead to significant wetland losses and other impacts on coastal wetlands and the humans associated with them. Landward migration and coastal retreat are not expected to significantly reduce coastal wetland losses. Nitrogen watershed inputs are unlikely to alter coastal marsh stability because watershed loadings are mostly significantly lower than those in fertilization studies that show decreased belowground biomass and increased decomposition of soil organic matter. Blue carbon is not expected to significantly reduce climate impacts. The high values of ecosystem goods and services of wetlands are expected to be reduced by area losses. Humans have had strong impacts on coastal wetlands in the Holocene, and these impacts are expected to increase in the Anthropocene.

Annual Review of Environment and Resources↗

Benthic community dynamics in Coyote Creek and Artesian Slough, southern San Francisco Bay, California, May 2016 to March 2018

The primary objective of this study is to quantify current (2016–18) benthic-community structure and function in the southern San Francisco Bay, and to compare those communities to the communities in the neighboring sloughs. The study area is inclusive of the area south of the Dumbarton Bridge including Coyote Creek and Artesian Slough. The southern San Francisco Bay is a system dependent on phytoplankton as the base to the food web. Despite abundant nutrients, southern San Francisco Bay has had limited phytoplankton production in the last several decades owing to poor light conditions caused by high turbidities, and high grazing losses from the water column by benthic invertebrates and zooplankton. However, the balance of biogeochemical conditions during spring of most years accommodates a short phytoplankton bloom in the southern San Francisco Bay. This balance between available light, nutrients, and grazing has maintained the phytoplankton biomass in the southern San Francisco Bay at low levels relative to other high-nutrient urban estuaries. The role of benthic invertebrates during episodic spring events, as well as in other seasons, remains of great interest to water-quality and biological resource managers.

California↗

Fatty acid composition at the base of aquatic food webs is influenced by habitat type and watershed land use

Spatial variation in food resources strongly influences many aspects of aquatic consumer ecology. Although large-scale controls over spatial variation in many aspects of food resources are well known, others have received little study. Here we investigated variation in the fatty acid (FA) composition of seston and primary consumers within (i.e., among habitats) and among tributary systems of Lake Michigan, USA. FA composition of food is important because all metazoans require certain FAs for proper growth and development that cannot be produced de novo, including many polyunsaturated fatty acids (PUFAs). Here we sampled three habitat types (river, rivermouth and nearshore zone) in 11 tributaries of Lake Michigan to assess the amount of FA in seston and primary consumers of seston. We hypothesize that among-system and among-habitat variation in FAs at the base of food webs would be related to algal production, which in turn is influenced by three land cover characteristics: 1) combined agriculture and urban lands (an indication of anthropogenic nutrient inputs that fuel algal production), 2) the proportion of surface waters (an indication of water residence times that allow algal producers to accumulate) and 3) the extent of riparian forested buffers (an indication of stream shading that reduces algal production). Of these three land cover characteristics, only intense land use appeared to strongly related to seston and consumer FA and this effect was only strong in rivermouth and nearshore lake sites. River seston and consumer FA composition was highly variable, but that variation does not appear to be driven by the watershed land cover characteristics investigated here. Whether the spatial variation in FA content at the base of these food webs significantly influences the production of economically important species higher in the food web should be a focus of future research.

Michigan;Wisconsin↗

Watershed Effects on Streamflow Quantity and Quality in Six Watersheds of Gwinnett County, Georgia

Watershed management is critical for the protection and enhancement of streams that provide multiple benefits for Gwinnett County, Georgia, and downstream communities. Successful watershed management requires an understanding of how stream quality is affected by watershed characteristics. The influence of watershed characteristics on stream quality is complex, particularly for the nonpoint sources of pollutants that affect urban watersheds. The U.S. Geological Survey (USGS), in cooperation with Gwinnett County Department of Water Resources (formerly known as Public Utilities), established a water-quality monitoring program during late 1996 to collect comprehensive, consistent, high-quality data for use by watershed managers. Between 1996 and 2003, more than 10,000 analyses were made for more than 430 water-quality samples. Continuous-flow and water-quality data have been collected since 1998. Loads have been computed for selected constituents from 1998 to 2003. Changing stream hydrology is a primary driver for many other water-quality and aquatic habitat effects. Primary factors affecting stream hydrology (after watershed size and climate) within Gwinnett County are watershed slope and land uses. For the six study watersheds in Gwinnett County, watershedwide imperviousness up to 12 percent does not have a well-defined influence on stream hydrology, whereas two watersheds with 21- and 35-percent impervious area are clearly impacted. In the stream corridor, however, imperviousness from 1.6 to 4.4 percent appears to affect baseflow and stormflow for all six watersheds. Relations of concentrations to discharge are used to develop regression models to compute constituent loads using the USGS LOAD ESTimator model. A unique method developed in this study is used to calibrate the model using separate baseflow and stormflow sample datasets. The method reduced model error and provided estimates of the load associated with the baseflow and stormflow parts of the hydrograph. Annual load of total suspended sediment is a performance criterion in Gwinnett County's Watershed Protection Plan. Median concentrations of total suspended solids in stormflow range from 30 to 180 times greater than in baseflow. This increase in total suspended solids concentration with increasing discharge has a multiplied effect on total suspended solids load, 97 to 99 percent of which is transported during stormflow. Annual total suspended solids load is highly dependent on annual precipitation; between 1998 and 2003 load for the wettest year was up to 28 times greater than for the driest year. Average annual total suspended solids yield from 1998-2003 in the six watersheds increased with high-density and transportation/utility land uses, and generally decreased with low-density residential, estate/park, and undeveloped land uses. Watershed characteristics also were related to annual loads of total phosphorus, dissolved phosphorus, total nitrogen, total dissolved solids, biochemical oxygen demand, and total zinc, as well as stream alkalinity. Flow-adjusted total suspended solids, total phosphorus, and total zinc stormflow concentrations between 1996 and 2003 have a seasonal pattern in five of the six watersheds. Flow-adjusted concentrations typically peak during late summer, between July and August. The seasonal pattern is stronger for more developed watersheds and may be related to seasonal land-disturbance activities and/or to seasonal rainfall intensity, both of which increase in summer. Adjusting for seasonality in the computation of constituent load caused the standard error of annual total suspended solids load to improve by an average of 11 percent, and increased computed summer total suspended solids loads by an average of 45 percent and decreased winter total suspended solids loads by an average of 40 percent. Total annual loads changed by less than 5 percent on the average. Graphical and statistical analyses do not indicate a time tre

Georgia↗

Estimating seismic site response in Christchurch City (New Zealand) from dense low-cost aftershock arrays

The Mw 7.1 September 2010 Darfield earthquake, New Zealand, produced widespread damage and liquefaction ~40 km from the epicentre in Christchurch city. It was followed by the even more destructive Mw 6.2 February 2011 Christchurch aftershock directly beneath the city’s southern suburbs. Seismic data recorded during the two large events suggest that site effects contributed to the variations in ground motion observed throughout Christchurch city. We use densely-spaced aftershock recordings of the Darfield earthquake to investigate variations in local seismic site response within the Christchurch urban area. Following the Darfield main shock we deployed a temporary array of ~180 low-cost 14-bit MEMS accelerometers linked to the global Quake-Catcher Network (QCN). These instruments provided dense station coverage (spacing ~2 km) to complement existing New Zealand national network strong motion stations (GeoNet) within Christchurch city. Well-constrained standard spectral ratios were derived for GeoNet stations using a reference station on Miocene basalt rock in the south of the city. For noisier QCN stations, the method was adapted to find a maximum likelihood estimate of spectral ratio amplitude taking into account the variance of noise at the respective stations. Spectral ratios for QCN stations are similar to nearby GeoNet stations when the maximum likelihood method is used. Our study suggests dense low-cost accelerometer aftershock arrays can provide useful information on local-scale ground motion properties for use in microzonation. Preliminary results indicate higher amplifications north of the city centre and strong high-frequency amplification in the small, shallower basin of Heathcote Valley.

Christchurch↗

Using local monitoring results to inform the Chesapeake Bay Program’s Watershed Model

The Chesapeake Bay Program’s Watershed Model (CBWM) has been used as an accounting tool for the Chesapeake Bay Total Maximum Daily Load (TMDL). However, some of the fundamental parameters that underpin the watershed model may not represent local watershed characteristics at all scales. Significant investments have been made by state and local governments, and other local stakeholders, who are interested in validating loads and progress in implementing measures to achieve the pollutant reductions called for in the TMDL through local monitoring data. For the purposes of this STAC workshop, local monitoring is considered any relevant data collected by a local, regional, state, or federal organization that has not been used previously in the development, calibration, or validation of the CBWM. Some of these local monitoring efforts have been collecting data over the past 5-10 years, with some datasets extending back over more than two decades. However, the data and the CBWM are often not directly comparable due to differences in temporal and spatial scales or because the water quality parameters being monitored are not those estimated by the model. Therefore, a Scientific and Technical Advisory Committee (STAC) workshop was convened to bring together Chesapeake Bay Program (CBP) modelers, local and state government stakeholders, and scientists who are monitoring and analyzing local water quality data to recommend ways in which local monitoring data can be used to inform the CBWM, identify gaps between modeled and monitored data, and validate model predictions at the local scale. The workshop, “Using Local Monitoring Results to Inform the Chesapeake Bay Program’s Watershed Model”, was held in March 2023 to provide insight on the scope of local water quality monitoring efforts within and outside of the Bay watershed that could be used to inform the CBWM. Scientists and managers developed recommendations that could be used by modelers for either calibration or knowledge generation to inform the Phase 7 version of the CBWM currently under development for a 2027 decision by the CBP, recommendations for how local monitoring efforts could be designed or altered to better inform the CBWM, and recommendations for how monitored trends could be used in management. The preliminary presentations for the workshop provided essential background information on the CBWM and data used to parameterize it. This information was the foundation for discussions on existing data gaps, the importance of current local monitoring networks, and best practices for developing future monitoring networks. More information on this STAC-funded effort including workshop presentation slides and recordings can be accessed on the workshop webpage. Confidence in the loading estimates of the CBWM is critical because of its role as the accounting mechanism for measuring progress toward the Bay TMDL’s nutrient and sediment reduction goals. Those who are being asked or required to pay for these reductions, from state and local government managers to farmers, property owners and developers, must have confidence in the scientific validity of the CBWM’s loading estimates or trust in the restoration effort will dissipate. Toward that end, several local entities have invested in extensive urban, suburban, and agricultural monitoring programs to characterize nutrient and sediment loading (among other water quality parameters) at a relatively fine scale (from a few acres to 5 square miles). Monitoring networks outside of the Bay watershed were also included as their relevance and similarities to Bay watershed landscapes, hydrology, and climate conditions can help build the body of knowledge necessary for better parameterization of the CBWM. Local monitoring results could be analyzed for loads and trends for calibration of Phase 7, comparison against trends, informing the structure and parameterization of the model, and potentially in policy evaluation. The effectiveness of management practices at the small watershed scale is a primary question of watershed managers that could be addressed by local monitoring, but to do so study design and statistical techniques may need to be altered if these datasets are intended to inform parameterization of the Bay modeling tools. The partnership would benefit from the redesign of some existing monitoring programs so that they are hypothesis-driven, with fully described inputs, outputs, and practices. New statistical tools could be applied to evaluate the relative importance of various drivers affecting water quality and influenced by hydrogeologic setting and watershed condition.

Chesapeake Bay watershed↗

Environmentally persistent free radicals and other paramagnetic species in wildland-urban interface fire ashes

Wildland-urban interface (WUI) fires consume fuels, such as vegetation and structural materials, leaving behind ash composed primarily of pyrogenic carbon and metal oxides. However, there is currently limited understanding of the role of WUI fire ash from different sources as a source of paramagnetic species such as environmentally persistent free radicals (EPFRs) and transition metals in the environment. Electron paramagnetic resonance (EPR) was used to detect and quantify paramagnetic species, including organic persistent free radicals and transition metal spins, in fifty-three fire ash and soil samples collected following the North Complex Fire and the Sonoma-Lake-Napa Unit (LNU) Lightning Complex Fire, California, 2020. High concentrations of organic EPFRs ( e.g., 1.4 × 10 14 to 1.9 × 10 17 spins g −1 ) were detected in the studied WUI fire ash along with other paramagnetic species such as iron and manganese oxides, as well as Fe 3+ and Mn 2+ ions. The mean concentrations of EPFRs in various ash types decreased following the order: vegetation ash (1.1 × 10 17 ± 1.1 × 10 17 spins g −1 ) > structural ash (1.6 × 10 16 ± 3.7 × 10 16 spins g −1 ) > vehicle ash (6.4 × 10 15 ± 8.6 × 10 15 spins g −1 ) > soil (3.2 × 10 15 ± 3.7 × 10 15 spins g −1 ). The mean concentrations of EPFRs decreased with increased combustion completeness indicated by ash color; black (1.1 × 10 17 ± 1.1 × 10 17 spins g −1 ) > white (2.5 × 10 16 ± 4.4 × 10 16 spins g −1 ) > gray (1.8 × 10 16 ± 2.4 × 10 16 spins g −1 ). In contrast, the relative amounts of reduced Mn 2+ ions increased with increased combustion completeness. Thus, WUI fire ash is an important global source of EPFRs and reduced metal species ( e.g., Mn 2+ ). Further research is needed to underpin the formation, transformation, and environmental and human health impacts of these paramagnetic species in light of the projected increased frequency, size, and severity of WUI fires.

California↗

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