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Toxicity of nickel-spiked freshwater sediments to benthic invertebrates-Spiking methodology, species sensitivity, and nickel bioavailability

This report summarizes data from studies of the toxicity and bioavailability of nickel in nickel-spiked freshwater sediments. The goal of these studies was to generate toxicity and chemistry data to support development of broadly applicable sediment quality guidelines for nickel. The studies were conducted as three tasks, which are presented here as three chapters: Task 1, Development of methods for preparation and toxicity testing of nickel-spiked freshwater sediments; Task 2, Sensitivity of benthic invertebrates to toxicity of nickel-spiked freshwater sediments; and Task 3, Effect of sediment characteristics on nickel bioavailability. Appendices with additional methodological details and raw chemistry and toxicity data for the three tasks are available online at http://pubs.usgs.gov/sir/2011/5225/downloads/.

Scientific Investigations Report↗

Preliminary assessment of sources of nitrogen in groundwater at a biosolids-application area near Deer Trail

Concentrations of dissolved nitrite plus nitrate increased fairly steadily in samples from four shallow groundwater monitoring wells after biosolids applications to nonirrigated farmland began in 1993. The U.S. Geological Survey began a preliminary assessment of sources of nitrogen in shallow groundwater at part of the biosolids-application area near Deer Trail, Colorado, in 2005 in cooperation with the Metro Wastewater Reclamation District. Possible nitrogen sources in the area include biosolids, animal manure, inorganic fertilizer, atmospheric deposition, and geologic materials (bedrock and soil). Biosolids from the Metro Wastewater Reclamation District plant in Denver and biosolids, cow manure, geologic materials (bedrock and soil), and groundwater from the study area were sampled to measure nitrogen content and nitrogen isotopic compositions of nitrate or total nitrogen. Biosolids also were leached, and the leachates were analyzed for nitrogen content and other concentrations. Geologic materials from the study area also were sampled to determine mineralogy. Estimates of nitrogen contributed from inorganic fertilizer and atmospheric deposition were calculated from other published reports. The nitrogen information from the study indicates that each of the sources contain sufficient nitrogen to potentially affect groundwater nitrate concentrations. Natural processes can transform the nitrogen in any of the sources to nitrate in the groundwater. Load calculations indicate that animal manure, inorganic fertilizer, or atmospheric deposition could have contributed the largest nitrogen load to the study area in the 13 years before biosolids applications began, but biosolids likely contributed the largest nitrogen load to the study area in the 13 years after biosolids applications began. Various approaches provided insights into sources of nitrate in the groundwater samples from 2005. The isotopic data indicate that, of the source materials considered, biosolids and (or) animal manure were the most likely sources of nitrate in the wells at the time of sampling (2005), and that inorganic fertilizer, atmospheric deposition, and geologic materials were not substantial sources of nitrate in the wells in 2005. The large total nitrogen content of the biosolids and animal-manure samples and biosolids leachates also indicates that the biosolids and animal manure had potential to leach nitrogen and produce large dissolved nitrate concentrations in groundwater. The available data, however, could not be used to distinguish between biosolids or manure as the dominant source of nitrate in the groundwater because the nitrogen isotopic composition of the two materials is similar. Major-ion data also could not be used to distinguish between biosolids or manure as the dominant source of nitrate in the groundwater because the major-ion composition (as well as the isotopic composition) of the two materials is similar. Without additional data, chloride/bromide mass ratios do not necessarily support or refute the hypothesis that biosolids and (or) animal manure were the primary sources of nitrate in water from the study-area wells in 2005. Concentrations of water-extractable nitrate in the soil indicate that biosolids could be an important source of nitrate in the groundwater recharge. Nitrogen inventories in the soil beneath biosolids-application areas and the nitrogen-input estimates for the study area both support the comparisons of isotopic composition, which indicate that some type of human waste (such as biosolids) and (or) animal manure was the source of nitrate in groundwater sampled from the wells in 2005. The nitrogen-load estimates considered with the nitrogen isotopic data and the soil-nitrogen inventories indicate that biosolids applications likely are a major source of nitrogen to the shallow groundwater at these monitoring wells.

Colorado↗

Analysis and inundation mapping of the April-May 2011 flood at selected locations in northern and eastern Arkansas and southern Missouri

Precipitation that fell from April 19 through May 3, 2011, resulted in widespread flooding across northern and eastern Arkansas and southern Missouri. The first storm produced a total of approximately 16 inches of precipitation over an 8-day period, and the following storms produced as much as 12 inches of precipitation over a 2-day period. Moderate to major flooding occurred quickly along many streams within Arkansas and Missouri (including the Black, Cache, Illinois, St. Francis, and White Rivers) at levels that had not been seen since the historic 1927 floods. The 2011 flood claimed an estimated 21 lives in Arkansas and Missouri, and damage caused by the flooding resulted in a Federal Disaster Declaration for 59 Arkansas counties that received Federal or State assistance. To further the goal of documenting and understanding floods, the U.S. Geological Survey, in cooperation with the Federal Emergency Management Agency, the U.S. Army Corps of Engineers–Little Rock and Memphis Districts, and Arkansas Natural Resources Commission, conducted a study to summarize meteorological and hydrological conditions before the flood; computed flood-peak magnitudes for 39 streamgages; estimated annual exceedance probabilities for 37 of those streamgages; determined the joint probabilities for 11 streamgages paired to the Mississippi River at Helena, Arkansas, which refers to the probability that locations on two paired streams simultaneously experience floods of a magnitude greater than or equal to a given annual exceedance probability; collected high-water marks; constructed flood-peak inundation maps showing maximum flood extent and water depths; and summarized flood damages and effects. For the period of record used in this report, peak-of-record stage occurred at 24 of the 39 streamgages, and peak-of-record streamflow occurred at 13 of the 30 streamgages where streamflow was determined. Annual exceedance probabilities were estimated to be less than 0.5 percent at three streamgages. The joint probability values for streamgages paired with the Mississippi River at Helena, Ark., streamgage indicate a low probability of concurrent flooding with the paired streamgages. The inundation maps show the flood-peak extent and water depth of flooding for two stream reaches on the White River and two on the Black River; the vicinities of the communities of Holly Grove and Cotton Plant, Ark.; a reach of the White River that includes the crossing of Interstate 40 north of De Valls Bluff, Ark.; and the Tailwaters of Beaver Dam near Eureka Springs, Ark., Table Rock Dam near Branson, Mo., and Bull Shoals Dam near Flippin, Ark. The data and inundation maps can be used for flood response, recovery, and planning efforts by Federal, State, and local agencies.

Arkansas;Missouri↗

Assessment of metal and trace element contamination in water, sediment, plants, macroinvertebrates, and fish in Tavasci Marsh, Tuzigoot National Monument, Arizona

Tavasci Marsh is a large freshwater marsh within the Tuzigoot National Monument in central Arizona. It is the largest freshwater marsh in Arizona that is unconnected to the Colorado River and is designated as an Important Bird Area by the Audubon Society. The marsh has been altered significantly by previous land use and the monument’s managers are evaluating the restoration of the marsh. In light of historical mining activities located near the marsh from the first half of the 20th century, evaluations of water, sediment, plant, and aquatic biota in the marsh were conducted. The evaluations were focused on nine metals and trace elements commonly associated with mining and other anthropogenic activities (As, Cd, Cr, Cu, Hg, Ni, Pb, Se, and Zn) together with isotopic analyses to understand the presence, sources and timing of water and sediment contaminants to the marsh and the occurrence in aquatic plants, dragonfly larvae, and fish. Results of water analyses indicate that there were two distinct sources of water contributing to the marsh during the study: one from older high elevation recharge entering the marsh at Shea Spring (as well as a number of unnamed seeps and springs on the northeastern edge of the marsh) and the other from younger low elevation recharge or from Pecks Lake. Water concentrations for arsenic exceeded the U.S. Environmental Protection Agency primary drinking water standard of 10 μg/L at all sampling sites. Surface waters at Tavasci Marsh may contain conditions favorable for methylmercury production. All surficial and core sediment samples exceeded or were within sample concentration variability of at least one threshold sediment quality guideline for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn. Several sediment sites were also above or were within sample concentration variability of severe or probable effect sediment quality guidelines for As, Cd, and Cu. Three sediment cores collected in the marsh have greater metal and trace element concentrations at depth for Bi, Cd, Cu, Hg, In, Pb, Sb, Sn, Te, and Zn. Radioisotope dating indicates that the elevated metal and trace element concentrations are associated with sediments deposited before 1963. Arsenic concentration was greater in cattail roots compared with surrounding sediment at Tavasci Marsh. Concentrations of As, Ni, and Se from yellow bullhead catfish (Ameiurus natalis) in Tavasci Marsh exceeded the 75th percentile of several other regional studies. Mercury concentration in dragonfly larvae and fish from Tavasci Marsh were similar to or greater than in Tavasci Marsh sediment. Future work includes a biologic risk assessment utilizing the data collected in this study to provide the monument management with additional information for their restoration plan.

Arizona↗

Flood recovery maps for the White River in Bethel, Stockbridge, and Rochester, Vermont, and the Tweed River in Stockbridge and Pittsfield, Vermont, 2014

From August 28 to 29, 2011, Tropical Storm Irene delivered rainfall ranging from about 4 inches to more than 7 inches in the White River Basin. The rainfall resulted in severe flooding throughout the basin and significant damage along the White River and Tweed River. In response to the flooding, the U.S. Geological Survey, in cooperation with the Federal Emergency Management Agency, conducted a new flood study to aid in the flood recovery and restoration. This flood study includes a 20.7-mile reach of the White River from the downstream end at about 2,000 feet downstream from the State Route 107 bridge in the Village of Bethel, Vermont, to the upstream end at about 1,000 feet upstream from the River Brook Drive bridge in the Village of Rochester, Vt., and a 7.9-mile reach of the Tweed River from its mouth in Stockbridge, Vt., to the confluence of the West and South Branches of the Tweed River and continuing upstream on the South Branch Tweed River to the Pittsfield, Vt., town line. This report presents water-surface elevations determined for the study reaches using the U.S. Army Corps of Engineers one-dimensional step-backwater Hydrologic Engineering Center River Analysis System model, also known as HEC– RAS. The water-surface elevations were determined for floods having a 10-, 4-, 2-, 1-, and 0.2-percent annual exceedance probability (AEP) and for the floodway. Eighteen high-water marks from Tropical Storm Irene were available along the studied reaches. The discharges in the Tropical Storm Irene HEC–RAS model were adjusted so that the resulting water-surface elevations matched the high-water mark elevations along the study reaches. This allowed for an estimation of the water-surface profile throughout the study area resulting from Tropical Storm Irene. From a comparison of the estimated water-surface profile of Tropical Storm Irene to the water-surface profiles of the 1- and 0.2-percent AEP floods, it was determined that the high-water elevations resulting from Tropical Storm Irene exceeded the estimated 1-percent AEP flood throughout the White River and Tweed River study reaches and exceeded the estimated 0.2-percent AEP flood in 16.7 of the 28.6 study reach miles. The simulated water-surface profiles were then combined with a geographic information system digital elevation model derived from light detection and ranging (lidar) data having a 18.2-centimeter vertical accuracy at the 95-percent confidence level and 1-meter horizontal resolution to delineate the area flooded for each water-surface profile.

Vermont↗

Evaluating the potential for near-shore bathymetry on the Majuro Atoll, Republic of the Marshall Islands, using Landsat 8 and WorldView-3 imagery

Satellite-derived near-shore bathymetry (SDB) is becoming an increasingly important method for assessing vulnerability to climate change and natural hazards in low-lying atolls of the northern tropical Pacific Ocean. Satellite imagery has become a cost-effective means for mapping near-shore bathymetry because ships cannot collect soundings safely while operating close to the shore. Also, green laser light detection and ranging (lidar) acquisitions are expensive in remote locations. Previous research has demonstrated that spectral band ratio-based techniques, commonly called the natural logarithm approach, may lead to more precise measurements and modeling of bathymetry because of the phenomenon that different substrates at the same depth have approximately equal ratio values. The goal of this research was to apply the band ratio technique to Landsat 8 at-sensor radiance imagery and WorldView-3 atmospherically corrected imagery in the coastal waters surrounding the Majuro Atoll, Republic of the Marshall Islands, to derive near-shore bathymetry that could be incorporated into a seamless topobathymetric digital elevation model of Majuro. Attenuation of light within the water column was characterized by measuring at-sensor radiance and reflectance at different depths and calculating an attenuation coefficient. Bathymetric lidar data, collected by the U.S. Naval Oceanographic Office in 2006, were used to calibrate the SDB results. The bathymetric lidar yielded a strong linear relation with water depths. The Landsat 8-derived SDB estimates derived from the blue/green band ratio exhibited a water attenuation extinction depth of 6 meters with a coefficient of determination R 2 =0.9324. Estimates derived from the coastal/red band ratio had an R 2 =0.9597. At the same extinction depth, SDB estimates derived from WorldView-3 imagery exhibited an R 2 =0.9574. Because highly dynamic coastal shorelines can be affected by erosion, wetland loss, hurricanes, sea-level rise, urban development, and population growth, consistent bathymetric data are needed to better understand sensitive coastal land/water interfaces in areas subject to coastal disasters.

Majuro Atoll↗

Methods for peak-flow frequency analysis and reporting for streamgages in or near Montana based on data through water year 2015

This report documents the methods for peak-flow frequency (hereinafter “frequency”) analysis and reporting for streamgages in and near Montana following implementation of the Bulletin 17C guidelines. The methods are used to provide estimates of peak-flow quantiles for 50-, 42.9-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities for selected streamgages operated by the U.S. Geological Survey Wyoming-Montana Water Science Center (WY–MT WSC). These annual exceedance probabilities correspond to 2-, 2.33-, 5-, 10-, 25-, 50-, 100-, 200-, and 500-year recurrence intervals, respectively. Standard procedures specific to the WY–MT WSC for implementing the Bulletin 17C guidelines include (1) the use of the Expected Moments Algorithm analysis for fitting the log-Pearson Type III distribution, incorporating historical information where applicable; (2) the use of weighted skew coefficients (based on weighting at-site station skew coefficients with generalized skew coefficients from the Bulletin 17B national skew map); and (3) the use of the Multiple Grubbs-Beck Test for identifying potentially influential low flows. For some streamgages, the peak-flow records are not well represented by the standard procedures and require user-specified adjustments informed by hydrologic judgement. The specific characteristics of peak-flow records addressed by the informed-user adjustments include (1) regulated peak-flow records, (2) atypical upper-tail peak-flow records, and (3) atypical lower-tail peak-flow records. In all cases, the informed-user adjustments use the Expected Moments Algorithm fit of the log-Pearson Type III distribution using the at-site station skew coefficient, a manual potentially influential low flow threshold, or both. Appropriate methods can be applied to at-site frequency estimates to provide improved representation of long-term hydroclimatic conditions. The methods for improving at-site frequency estimates by weighting with regional regression equations and by Maintenance of Variance Extension Type III record extension are described. Frequency analyses were conducted for 99 example streamgages to indicate various aspects of the frequency- analysis methods described in this report. The frequency analyses and results for the example streamgages are presented in a separate data release associated with this report consisting of tables and graphical plots that are structured to include information concerning the interpretive decisions involved in the frequency analyses. Further, the separate data release includes the input files to the PeakFQ program, version 7.1, including the peak-flow data file and the analysis specification file that were used in the peak-flow frequency analyses. Peak-flow frequencies are also reported in separate data releases for selected streamgages in the Beaverhead River and Clark Fork Basins and also for selected streamgages in the Ruby, Jefferson, and Madison River Basins.

Montana↗

Use of set blanks in reporting pesticide results at the U.S. Geological Survey National Water Quality Laboratory, 2001-15

Executive Summary Background .—Pesticide results from the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) are used for water-quality assessments by many agencies and organizations. The USGS is committed to providing data of the highest possible quality to the consumers of its data. A cooperator’s inquiries about specific pesticide detections in water revealed potential laboratory contamination issues for some results. Consequently, the USGS conducted an extensive evaluation of potential low-level contamination related to processing or analysis of water-quality samples at NWQL for 21 pesticide compounds of interest to the cooperator. This is the most comprehensive study of NWQL pesticide quality-control (QC) results to date. Purpose and scope .—The purpose of this study was to document protocols used by the NWQL to censor pesticide results and to determine the effects of laboratory contamination—as determined from detections in laboratory set blanks—on pesticide detections in groundwater and surface-water samples. More than 30,000 pesticide results from 113 selected batches of samples (2 percent or less of total batches) analyzed by the NWQL during the 15 years from 2001 to 2015 were reviewed. All laboratory results from the selected batches, including results from environmental (surface water and groundwater) and QC (set-blank, blind-blank, and blind-spike) samples, were evaluated. The study includes results for 21 pesticide compounds analyzed in groundwater and surface-water samples collected across the United States. Eleven pesticide compounds were analyzed by a gas chromatography/mass spectrometry method and 10 compounds by a liquid chromatography/mass spectrometry method. Objectives and methods .—The objectives of this study were to (1) determine the characteristics of laboratory contamination over time, (2) compare distributions of pesticide results in set blanks with distributions in environmental samples, (3) evaluate the potential for false-positive and false-negative reporting of results, and (4) evaluate the effects of reevaluating historical pesticide results using 2017 compound identification protocols on detections of pesticides in groundwater and surface-water samples. The 113 instrument batches selected for this study contained detections of one or more of the 21 pesticide compounds in set blanks or were among those batches with the highest pesticide detection frequencies in set blanks. As a result, the dataset for this study was targeted toward pesticides and batches with laboratory contamination. The objectives were addressed by statistically comparing environmental and set-blank results; computing moving averages of set-blank detection frequencies to identify periods of episodic contamination; and using summary statistics, tabular summaries, and graphical approaches, such as time-series plots and cumulative distribution functions. Results .— Objective 1 : Laboratory contamination, as determined by pesticide detections in set blanks, was found in 13 percent of set-blank results from the 113 targeted batches included in this study (as compared to 6 percent of set-blank results from all 7,620 batches analyzed during the study period). It is estimated that 92 percent of the laboratory contamination during the study period was episodic, meaning that it occurred during discrete periods of time. All 21 of the targeted pesticide compounds had periods of episodic contamination, with most episodes ranging in duration from about 1 to 8 months. The remaining 8 percent of laboratory contamination was random or from a known source (deterministic). Objective 2 : For some compounds, graphs of cumulative distribution functions of the entire distributions of set-blank and environmental samples overlap, suggesting that there is no difference in the distributions of the two types of samples. However, time-series graphs show that detections in set blanks often occur at different times (sometimes separated by years) than detections in environmental samples, indicating clear differences in those distributions, and indicating the importance of evaluating the timing of detections in all sample types. For most compounds detected in set-blank and environmental samples, detection frequencies were significantly greater in set blanks than in groundwater or surface-water samples ( p <0.05). There are several explanations for this finding, including that the 113 batches of samples chosen for this study targeted batches with detections in set blanks or that detections in set-blank samples were historically determined with less stringent identification criteria than for environmental samples (groundwater and surface-water samples). Objective 3 : The false-positive and false-negative rates from blind samples submitted during the study period by the USGS Quality Systems Branch generally were less than 1 and 5 percent, respectively, for the 21 pesticides. The only compound with a false-positive rate greater than 1 percent was flumetsulam (2.6 percent), indicating that there is a higher likelihood of flumetsulam being reported as a detection when it is not present in an environmental sample compared with the reporting of other compounds. Objective 4 : Altogether, for data in targeted batches, NWQL would have reported 0.1 percent of results from groundwater samples and 1.4 percent of results from surface-water samples differently if 2017 identification protocols were applied to historical pesticide results. In most of these cases, detections observed in historical results would change to nondetections. The small percentages of changes that would occur if historical data were reevaluated indicate that historical protocols used by the NWQL to identify detections in environmental samples were robust and produced results that are predominantly consistent with current [2017] practices. Conclusions .—The NWQL produces high-quality pesticide results at environmentally relevant concentrations. NWQL identification protocols and censoring practices are largely effective at minimizing the reporting of false-positive and false-negative results. Laboratory contamination, when it occurred, tended to occur in episodes; thus, evaluating the timing and magnitude of detections in set blanks relative to detections in environmental samples was determined to be an important consideration for analysis of environmental results. Because NWQL censoring practices do not address all types and occurrences of laboratory contamination, options for additional censoring practices are provided for data users with more specific or stringent data-quality objectives. The methods used to analyze the 21 compounds for this report can similarly be applied to all 173 pesticide compounds that were analyzed by the NWQL during the same time period. This study also has helped to identify potential improvements in reporting USGS data, such as conducting more frequent review of set-blank datasets.

Scientific Investigations Report↗

Hydrogeology and groundwater geochemistry of till confining units and confined aquifers in glacial deposits near Litchfield, Cromwell, Akeley, and Olivia, Minnesota, 2014–18

Confined (or buried) aquifers of glacial origin overlain by till confining units provide drinking water to hundreds of thousands of Minnesota residents. The sustainability of these groundwater resources is not well understood because hydraulic properties of till that control vertical groundwater fluxes (leakage) to underlying aquifers are largely unknown. The U.S. Geological Survey, Iowa State University, Minnesota Geological Survey, and Minnesota Department of Health investigated hydraulic properties and groundwater flow through till confining units using field studies and heuristic MODFLOW simulations. Till confining units in the following late-Wisconsinan stratigraphic units (with locations in parentheses) were characterized: Des Moines lobe till of the New Ulm Formation (Litchfield, Minnesota), Superior lobe till of the Cromwell and Aitkin Formations (Cromwell, Minn.), and Wadena lobe till of the Hewitt Formation (hydrogeology field camp [HFC] near Akeley, Minn.). Pre-Illinoian till of the Good Thunder formation (Olivia, Minn.) was also characterized. Hydraulic and geochemical field data were collected from sediment cores and a series of five piezometer nests. Each nest consisted of five to eight piezometers screened at short vertical intervals in hydrostratigraphic units including (if present) surficial aquifers, till confining units, confined/buried aquifers, and underlying bedrock. Till hydraulic conductivity was estimated from slug tests (horizontal [ K h ]) and constant-rate aquifer tests in the confined aquifer (vertical [ K v ]). Travel times through the till were evaluated with Darcy’s law and stable isotope concentrations. A series of heuristic MODFLOW simulations were used to evaluate groundwater fluxes through till across the range of till hydraulic properties and pumping rates observed at the field sites. The field data demonstrated variability in hydraulic properties between and within till stratigraphic units horizontally and vertically. The variability in hydraulic properties within and between sites resulted in substantial differences in groundwater flux through till. A conceptual understanding that emerges from the vertical till profiles is that they are not homogeneous hydrostratigraphic units with uniform properties; rather, each vertical sequence is a heterogeneous mixture of glacial sediment with differing abilities to transmit water. Till thicknesses varied from 60 to 166 feet, and till textures ranged from a sandy loam (Hewitt Formation, HFC site) to a silt loam/clay loam (Good Thunder formation, Olivia site). Till Kh varied by one to three orders of magnitude within each piezometer nest. Four piezometer nests had downward hydraulic gradients ranging from 0.04 to 0.56, and one nest had a slight upward hydraulic gradient of 0.02. The Cromwell, HFC, and Litchfield 1 sites were examples of “leaky” tills with high Kv (0.001 to 1.1 feet per day [ft/d]) and geometric mean Kh (0.03 to 0.07 ft/d) and extensive vertical hydraulic connectivity between the confined aquifer and the overlying till. Estimated groundwater travel times through these sites ranged from 1 to 81 years, and two of these sites had tritium throughout their till profiles. The tills at the other two sites, Olivia and Litchfield 2, were effective confining units that had low Kv (0.001 to 0.0005 ft/d) and geometric mean Kh (0.0002 to 0.004 ft/d). The till piezometers at these sites had no drawdown response to short-term (up to 10 hours for Olivia and up to 5 days for Litchfield) high-capacity pumping from the confined aquifer. Estimated groundwater travel times through the tills at these sites ranged from 165 to nearly 1,800 years, and tritium was only detected in the upper one-third of these till profiles. Across all sites, the till vertical anisotropy (ratio of K h to K v ) ranged by four orders of magnitude from 0.05 at the Cromwell nest to 70 at the Litchfield 1 nest. Stable isotopes of oxygen and hydrogen indicate that groundwater throughout all five till profiles is younger than the last glacial advance into Minnesota at about 11,000 years ago. The heuristic modeling demonstrated that, for understanding sustainability of groundwater pumping from confined aquifers, knowledge of till hydraulic properties is just as important as knowledge of aquifer hydraulic properties. Substantial differences in groundwater fluxes into and through till were observed across hydrogeologic settings representative of the field sites. Over long periods of time (hundreds of years), pumping-induced hydraulic gradients are established in confined aquifer systems and, even in low hydraulic conductivity tills, these pumping-induced hydraulic gradients increase leakage into and through till compared to ambient conditions. In conclusion, groundwater flowing vertically downward through till confining units (leakage) replenishes water pumped from confined aquifers. Till hydraulic properties, such as those presented in this report, provide important information that can be used to quantify leakage rates through till. Till hydraulic properties are variable over short distances and profoundly affect leakage rates, demonstrating the importance of site-specific till hydraulic data for evaluating the sustainability of groundwater withdrawals from confined aquifers.

Minnesota↗

Major winter and nonwinter floods in selected basins in New York and Pennsylvania

The scientific design of flood-control works is based on an evaluation of the hydrologic factors basic to flood events, particularly how rainfall and snow runoff, soil conditions, and channel influences can combine to produce greater or lesser floods. For this purpose an analysis of the pertinent hydrologic data is needed. The methods of analysis adopted should conform as closely as possible to those already in use and must be adapted to the quality of the available information. Maximum floods in 8 basins in New York and Pennsylvania during the winter and nonwinter months were studied, a total of 21 floods. The most outstanding winter flood of record in the North Atlantic region was that of March 1936. Rainfall plus snow melt in the basins studied ranged between 3.04 and 6.87 inches, and associated volumes of direct runoff from 1.88 to 5.63 inches. Winter floods have a common characteristic in their relation to freezing temperature. The antecedent periods, representing a period of snow accumulation and frost penetration, are below freezing, and the flood itself is contemporaneous with a period of above-freezing temperatures, usually associated with rain, during which the previously accumulated snow is melted. A second common characteristic of major winter floods is their tendency to be associated with widespread causal meteorologic conditions. There was a more complete conversion of rainfall and snow melt into runoff during the winter storms studied than during the wettest nonwinter flood. Snow melt during winter floods ranged from 0.04 to 0.07 inch per degree-day above 32° F. The depth of mean areal rainfall produced by the nonwinter storms studied ranged from 3.05 to 4.96 inches. The maximum 24-hour quantity at single stations was 14 inches, which was measured during the storm of July 1935 in New York. The volume of direct runoff ranged between 1.39 and 3.41 inches. The portion of rainfall that was converted into runoff varied in accordance with the rate of antecedent base flow, expressed in second-feet per square mile, and emphasized the influence of antecedent conditions. The average volume of direct runoff during winter floods was 4.24 inches, and the average during nonwinter floods was 2.44 inches. The latter, however, were more concentrated as to time, tending to compensate for large volume of runoff in winter, so that the crest rates of direct runoff averaged 0.056 inches per hour during the winter and 0.051 inches during the nonwinter period.

New York, Pennsylvania↗

Vision for a worldwide fluvial-sediment information network

The nations of the world suffer both from the deleterious effects of some natural and human-altered fluxes of fluvial sediment and a lack of consistent and reliable information on the temporal and spatial occurrence of fluvial sediments. Decades ago, this difficulty was unavoidable due to a lack of understanding of the magnitude and scope of environmental influences exerted by fluvial sediment coupled with a dearth of tools for monitoring and studying the data. Such is no longer the case. Fluvial sediment has a broad influence on the environment and humanity. Data needs that were once limited primarily to reservoir and channel maintenance now include issues associated with public water supply; contaminated sediment management; productivity of agricultural lands; stream restoration and watershed health; in-stream biotic stability; post-wildfire channel morphology; dam decommissioning, rehabilitation, or removal; and legal requirements for sediment management (Gray and Glysson, 2005). The adverse effects of poorly managed or unmanaged sediment movement related to these and other issues are well-known qualitatively, and in some cases quantitatively. For example, physical, chemical, and biological damages attributable to fluvial sediment in North America alone are now estimated to range between $20 billion and $50 billion annually (Pimental and others, 1995; Osterkamp and others, 1998; 2004). Capabilities for monitoring, analyzing, storing, and sharing fluvial-sediment data have been developed and, in many cases, are sufficiently mature for consideration for global utilization. Hence, there is not only a strong and expanding need for a global effort to gauge and understand fluvial-sediment characteristics and processes better, but the knowledge and tools to achieve these ends are largely available and ready for their applicability to be evaluated. Given the increasing importance of erosion and sediment processes for water-resources management, an International Sedimentation Initiative (ISI, 2007a), under the United Nations Educational, Scientific, and Cultural Organization&rsquo;s International Hydrologic Programme (IHP, 2007) was adopted in 2004. The ISI, the focus of which is on sustainable water-resources management on the global scale, features six major activities and projects, which are listed as part of the section entitled, &ldquo;Relation of the WoFSIN concept to the thrusts of the International Sedimentation Initiative,&rdquo; that precedes the &ldquo;Conclusions&rdquo; section of this paper. Based on the need for more, and more consistent and reliable fluvial-sediment information and on the existence of the ISI and other international and national sediment programs, we envision the need for a Worldwide Fluvial Sediment-Information Network (WoFSIN) with a focus on data acquisition, storage, and dissemination globally. Envisioned components of a WoFSIN, administered largely via the Internet and relying mostly on the benefits derived from existing resources and programs, follow that summary. The goal of the WoFSIN is to maximize the availability and usefulness of the world&rsquo;s historical and current fluvial-sediment and ancillary data through collaboration with existing programs so as to require few additional resources in the long-term. Thus, the WoFSIN concept was developed recognizing that informed resource management is predicated on the availability of adequate and reliable information. The WoFSIN is described in the ensuing sections in stand-alone fashion, followed by a section that describes the complementary aspects of the WoFSIN and the International Sediment Initiative. Thus, our first objective is to describe the fundamental components of a WoFSIN. Our second objective is to identify overlap or gaps between the WoFSIN and ISI concepts that might be useful in refining the ISI&rsquo;s ability to meet its global mission to develop decision support for sediment management at the global scale more fully, cost-effectively, and (or) with enhanced quality.

Conference Paper↗

U.S. Geological Survey Science Strategy for the Wyoming Landscape Conservation Initiative

Southwest Wyoming's wildlife and habitat resources are increasingly affected by energy and urban/exurban development, climate change, and other key drivers of ecosystem change. To ensure that southwest Wyoming's wildlife populations and habitats persist in the face of development and other changes, a consortium of public resource-management agencies proposed the Wyoming Landscape Conservation Initiative (WLCI), the overall goal of which is to implement conservation actions. As the principal agency charged with conducting WLCI science, the U.S. Geological Survey (USGS) has developed a Science Strategy for the WLCI. Workshops were held for all interested parties to identify and refine the most pressing management needs for achieving WLCI goals. Research approaches for addressing those needs include developing conceptual models for understanding ecosystem function, identifying key drivers of change affecting WLCI ecosystems, and conducting scientific monitoring and experimental studies to better understand ecosystems processes, cumulative effects of change, and effectiveness of habitat treatments. The management needs drive an iterative, three-phase framework developed for structuring and growing WLCI science efforts: Phase I entails synthesizing existing information to assess current conditions, determining what is already known about WLCI ecosystems, and providing a foundation for future work; Phase II entails conducting targeted research and monitoring to address gaps in data and knowledge during Phase I; and Phase III entails integrating new knowledge into WLCI activities and coordinating WLCI partners and collaborators. Throughout all three phases, information is managed and made accessible to interested parties and used to guide and improve management and conservation actions, future habitat treatments, best management practices, and other conservation activities.

Scientific Investigations Report↗

Risk management of El Chichón and Tacaná Volcanoes: Lessons learned from past volcanic crises: Chapter 8

Before 1985, Mexico lacked civil-protection agencies with a mission to prevent and respond to natural and human-caused disasters; thus, the government was unprepared for the sudden eruption of El Chichón Volcano in March–April 1982, which produced the deadliest volcanic disaster in the country’s recorded history (~2,000 fatalities). With the sobering lessons of El Chichón still fresh, scientists and governmental officials had a higher awareness of possible disastrous outcome when Tacaná Volcano began to exhibit unrest in late 1985. Seismic and geochemical studies were quickly initiated to monitor activity. At the same time, scientists worked actively with officials of the Federal and local agencies to develop the “Plan Operativo” (Operational Plan)—expressly designed to effectively communicate hazards information and reduce confusion and panic among the affected population. Even though the volcano-monitoring data obtained during the Tacaná crisis were limited, when used in conjunction with protocols of the Operational Plan, they proved useful in mitigating risk and easing public anxiety. While comprehensive monitoring is not yet available, both El Chichón and Tacaná volcanoes are currently monitored—seismically and geochemically—within the scientific and economic resources available. Numerous post-eruption studies have generated new insights into the volcanic systems that have been factored into subsequent volcano monitoring and hazards assessments. The State of Chiapas is now much better positioned to deal with any future unrest or eruptive activity at El Chichón or Tacaná, both of which at the moment are quiescent as of 2014. Perhaps more importantly, the protocols first tested in 1986 at Tacaná have served as the basis for the development of risk-management practices for hazards from other active and potentially active volcanoes in Mexico. These practices have been most notably employed since 1994 at Volcán Popocatépetl since a major eruption under unfavorable prevailing winds may constitute a substantial threat to densely populated metropolitan Mexico City. While the 1982 El Chichón disaster was a national tragedy, it greatly accelerated volcanic emergency preparedness and multidisciplinary scientific studies of eruptive processes and products, not only at El Chichón but also at other explosive volcanoes in Mexico and elsewhere in the world.

Chiapas↗

A critical review of the postulated role of the non-essential amino acid, β-N-methylamino-L-alanine, in neurodegenerative disease in humans

The compound BMAA (β- N -methylamino-L-alanine) has been postulated to play a significant role in four serious neurological human diseases: Amyotrophic Lateral Sclerosis/Parkinsonism Dementia Complex (ALS/PDC) found on Guam, and ALS, Parkinsonism, and dementia that occur globally. ALS/PDC with symptoms of all three diseases first came to the attention of the scientific community during and after World War II. It was initially associated with cycad flour used for food because BMAA is a product of symbiotic cycad root-dwelling cyanobacteria. Human consumption of flying foxes that fed on cycad seeds was later suggested as a source of BMAA on Guam and a cause of ALS/PDC. Subsequently, the hypothesis was expanded to include a causative role for BMAA in other neurodegenerative diseases including Alzheimer’s disease (AD) through exposures attributed to proximity to freshwaters and/or consumption of seafood due to its purported production by most species of cyanobacteria. The hypothesis that BMAA is the critical factor in the genesis of these neurodegenerative diseases received considerable attention in the medical, scientific, and public arenas. This review examines the history of ALS/PDC and the BMAA-human disease hypotheses; similarities and differences between ALS/PDC and the other diseases with similar symptomologies; the relationship of ALS/PDC to other similar diseases, studies of BMAA-mediated effects in lab animals, inconsistencies and data gaps in the hypothesis; and other compounds and agents that were suggested as the cause of ALS/PDC on Guam. The review concludes that the hypothesis of a causal BMAA neurodegenerative disease relationship is not supported by existing data.

Journal of Toxicology and Environmental Health, Pa↗

Warming and earlier spring increase Western U.S. forest wildfire activity

Western United States forest wildfire activity is widely thought to have increased in recent decades, yet neither the extent of recent changes nor the degree to which climate may be driving regional changes in wildfire has been systematically documented. Much of the public and scientific discussion of changes in western United States wildfire has focused instead on the effects of 19th- and 20th-century land-use history. We compiled a comprehensive database of large wildfires in western United States forests since 1970 and compared it with hydroclimatic and land-surface data. Here, we show that large wildfire activity increased suddenly and markedly in the mid-1980s, with higher large-wildfire frequency, longer wildfire durations, and longer wildfire seasons. The greatest increases occurred in mid-elevation, Northern Rockies forests, where land-use histories have relatively little effect on fire risks and are strongly associated with increased spring and summer temperatures and an earlier spring snowmelt.

Science↗

Dipping reflectors in the Norwegian Sea—ODP Leg 104 drilling results: LEG 104 SCIENTIFIC PARTY

Ocean Drilling Program (ODP) Leg 104 successfully completed a number of deep drill holes on the Outer V0ring Plateau and the Vering Basin during July and August 1985 (Fig. 1; Eldholm, Thiede, Taylor et al. 1986). One of the principal objectives of the leg was to drill and sample a thick oceanward-dipping wedge of seismic reflectors, known to characterize much of the multichannel seismic (MCS) profile data recorded across ocean-continent transitions in the NE Atlantic north of 55°N. Elsewhere, these reflectors have previously been the target of deep drilling during Legs 48 and 81 of the International Phase of Ocean Drilling IPOD (Montadert, Roberts et al. 1979; Roberts, Schnitker et al. 1984). These efforts met with some success, sampling only the uppermost part of the sequence and identifying a series of tholeiitic lava flows. Over the Outer V~ring Plateau, a number of MCS profiles reveal a distinct change in seismic character at the base of the well-stratified dipping reflector sequence, where an irregular surface characterized by a band of low-frequency, high-amplitude reflectors occurs. This surface is referred to as K. Prior to Leg 104, therefore, relatively little was known regarding the variation in petrographic character of the flows at depth, their evolution and origin, and particularly the character of the material below the reflector sequence. A single deep drillhole (642E) successfully recovered a section through the

Journal of the Geological Society↗

The Distribution of Submersed Aquatic Vegetation in the Fresh and Oligohaline Tidal Potomac River, 2004

Introduction Submersed aquatic vegetation (SAV) is a critical component of the Potomac River ecosystem. Though SAV provides important habitat for fauna and stabilizes bottom sediment, very dense beds may restrict recreational and commercial navigation. Exotic species of SAV are managed by the Metropolitan Washington Council of Governments Potomac Aquatic Plant Management Program (PAPMP). Selected beds of exotic SAV species that limit navigation are harvested mechanically. The program began in 1986 when approximately 40 acres of plants were harvested from 18 sites (Metropolitan Washington Council of Governments 1987). Monitoring efforts are an effective means of quantifying the distribution and abundance of the exotic species, Hydrilla verticillata (hydrilla) and other SAV species. These annual surveys provide a basis for identifying large-scale changes throughout the ecosystem and allow managers to evaluate the effectiveness of resource management policies based on a reliable scientific foundation. The U.S. Geological Survey (USGS) has monitored the distribution and composition of SAV beds in the fresh and oligohaline (salinity 0.5 to 5) tidal Potomac River since 1978 using transect sampling (1978 to 1981, 1985 to 1987, and 2002) and shoreline surveys (1983 to 2004). Shoreline survey data from the tidal Potomac River are incorporated into the Virginia Institute of Marine Science (VIMS) annual report on SAV distribution in Chesapeake Bay. The VIMS report and methods are available at http://www.vims.edu/bio/sav. Additional publications concerning SAV distribution in the Potomac River can be found at http://water.usgs.gov/nrp/proj.bib/sav/wethome.htm.

Open-File Report↗

Water-resources activities of the U.S. Geological Survey in Nebraska, 1984

The State of Nebraska has a greater abundance of water than most of the surrounding States. The major water issues in the State concern the management of these water resources in regard to their availability areally across the State and temporally over the changing seasons and cycles of weather. Management also concerns the protection of the supply of water from deterioration through contamination. The U.S. Geological Survey (USGS) in Nebraska began providing data to allow for better management of the State 's water near the end of the 19th Century. Since then the USGS activities have continued and have included the monitoring of hydrologic conditions, detailed studies to describe the hydrology of specific areas, and studies to add to the basic scientific knowledge of hydrology. Projects in all these areas continue. The work has been supported through Federal funding, through support from other Federal agencies, and through cooperative programs with many State and local agencies. This report summarizes these activities which are ongoing in the State of Nebraska. (Lantz-PTT)

Open-File Report↗

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