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At least 181 records · Page 10Linked to original sources

Fluvial-sediment discharge to the oceans from the conterminous United States

This report is a contribution to the UNESCO-sponsored project of the International Hydrological Decade called the World Water Balance. Annual fluvial-sediment discharge from the conterminous United States averages 491,449,600 short tons, of which 14,204,000 is discharged to the Atlantic Ocean, 378,179,000 to the Gulf of Mexico, and 99,066,600 to the Pacific Ocean. Data from 27 drainage areas were used to estimate the average annual discharge, yield, and concentration of fluvial sediment. The data may be used to extrapolate part of the total world sediment yield to the marine environment.

Circular

Quantitative controls on location and architecture of carbonate depositional sequences: upper miocene, cabo de gata region, se Spain

Sequence stratigraphy, pinning-point relative sea-level curves, and magnetostratigraphy provide the quantitative data necessary to understand how rates of sea-level change and different substrate paleoslopes are dominant controls on accumulation rate, carbonate depositional sequence location, and internal architecture. Five third-order (1-10 my) and fourth-order (0.1-1.0 my) upper Miocene carbonate depositional sequences (DS1A, DS1B, DS2, DS3, TCC) formed with superimposed higher-frequency sea-level cycles in an archipelago setting in SE Spain. Overall, our study indicates when areas of high substrate slope (>15 degrees ) are in shallow water, independent of climate, the location and internal architecture of carbonate deposits are not directly linked to sea-level position but, instead, are controlled by location of gently sloping substrates and processes of bypass. In contrast, if carbonate sediments are generated where substrates of low slope (<15 degrees in our area) are in shallow water, then architecture and location of deposits may be more directly controlled by the relative position of sea level. For these systems, the rates of relative sea-level change are important for determining which systems tracts develop. DS1A-DS1B, cooler-water ramps, result from sediment bypass across steep paleoslopes to toes of slopes. Accumulation rates decreased from >15.6 cm/ky to approximately 2 cm/ky and overall relative sea level rose at rates of 17-21.4 cm/ky. Higher frequency sea-level rates were about 111 to more than 260 cm/ky, producing onlapping, fining- (deepening-) upward cycles. Decreasing accumulation rates resulted from decreasing surface area for shallow-water sediment production, drowning of shallow-water substrates, and complex sediment dispersal related to the archipelago setting. Typical systems tract and parasequence development should not be expected in "bypass ramp" settings; facies of onlapping strata do not track base level and are likely to be significantly different compared to onlapping strata associated with coastal onlap. Basal and upper DS2 reef megabreccias (indicating the transition from cool to warmer climatic conditions) were eroded from steep upslope positions and redeposited downslope onto areas of gentle substrate during rapid sea-level falls (>22.7 cm/ky) of short duration. Such rapid sea-level falls and presence of steep slopes are not conducive to formation of forced regressive systems tracts composed of down-stepping reef clinoforms. The DS3 reefal platform formed where shallow water coincided with gently sloping substrates created by earlier deposition. Slow progradation (0.39-1.45 km/my) is best explained by the lack of an extensive bank top, progressively falling sea level, and low productivity resulting from siliciclastic debris and excess nutrients shed from nearby volcanic islands. Although DS3 strata were deposited during a third-order relative sea-level cycle, a typical transgressive systems tract is not recognizable, indicating that the initial relative rise in sea level was too rapid (>>19 cm/ky). Downstepping reefs, forming a forced regressive systems tract, were deposited during the relative sea-level fall at the end of DS3, indicating that relatively slow rates of fall (10 cm/ky or less) over favorable paleoslope conditions are conducive to generation of forced regressive systems tracts consisting of downstepping reef clinoforms. The TCC sequence consists of four shallow-water sedimentary cycles that were deposited during a 400 ky to 100 ky time span. Such shallow-water cycles, typical of many platforms, form only where shallow water intersects gently sloping substrates. The relative thicknesses of cycles (<2 m to 15 m thick), magnitudes of relative sea-level fluctuations associated with each cycle (25-30 m), high rates of relative sea-level fluctuations (minimum of 25-120 cm/ky), and the widespread distribution of similar TCC cycles in the Mediterranean and elsewhere are supportive of a glacio-eustatic influence. With rates of sea-level change so high, typical systems tracts do not form.

Journal of Sedimentary Research

Workgroup report: Drinking-water nitrate and health - Recent findings and research needs

Human alteration of the nitrogen cycle has resulted in steadily accumulating nitrate in our water resources. The U.S. maximum contaminant level and World Health Organization guidelines for nitrate in drinking water were promulgated to protect infants from developing methemoglobinemia, an acute condition. Some scientists have recently suggested that the regulatory limit for nitrate is overly conservative; however, they have not thoroughly considered chronic health outcomes. In August 2004, a symposium on drinking-water nitrate and health was held at the International Society for Environmental Epidemiology meeting to evaluate nitrate exposures and associated health effects in relation to the current regulatory limit. The contribution of drinking-water nitrate toward endogenous formation of N-nitroso compounds was evaluated with a focus toward identifying subpopulations with increased rates of nitrosation. Adverse health effects may be the result of a complex interaction of the amount of nitrate ingested, the concomitant ingestion of nitrosation cofactors and precursors, and specific medical conditions that increase nitrosation. Workshop participants concluded that more experimental studies are needed and that a particularly fruitful approach may be to conduct epidemiologic studies among susceptible subgroups with increased endogenous nitrosation. The few epidemiologic studies that have evaluated intake of nitrosation precursors and/or nitrosation inhibitors have observed elevated risks for colon cancer and neural tube defects associated with drinking-water nitrate concentrations below the regulatory limit. The role of drinking-water nitrate exposure as a risk factor for specific cancers, reproductive outcomes, and other chronic health effects must be studied more thoroughly before changes to the regulatory level for nitrate in drinking water can be considered.

Environmental Health Perspectives

Evaluation and correlation of water-quality data for the North Fork Flathead River, northwestern Montana

This report is a compilation and evaluation of water-quality measurements that have been made by the U.S. Geological Survey at two stations on the North Fork Flathead River in Montana. Historical streamflow records show an annual mean daily discharge of 3,010 cubic feet per second near the mouth--a threefold increase compared to discharge at the international boundary. The chemical character of the water is dominated by calcium and magnesium cations and the bicarbonate anion. Base flow, in contrast to high flows from runoff, is characterized by higher dissolved constituents and lower concentrations of suspended sediment. The several lakes that contribute water throughout the middle and lower drainage have a dampening effect on both streamflow and constituent concentrations. Using the available data and computer techniques, regression equations were developed between certain water-quality variables. (Woodard-USGS)

Water-Resources Investigations Report

Section 1. Simulation of surface-water integrated flow and transport in two-dimensions: SWIFT2D user's manual

A numerical model for simulation of surface-water integrated flow and transport in two (horizontal-space) dimensions is documented. The model solves vertically integrated forms of the equations of mass and momentum conservation and solute transport equations for heat, salt, and constituent fluxes. An equation of state for salt balance directly couples solution of the hydrodynamic and transport equations to account for the horizontal density gradient effects of salt concentrations on flow. The model can be used to simulate the hydrodynamics, transport, and water quality of well-mixed bodies of water, such as estuaries, coastal seas, harbors, lakes, rivers, and inland waterways. The finite-difference model can be applied to geographical areas bounded by any combination of closed land or open water boundaries. The simulation program accounts for sources of internal discharges (such as tributary rivers or hydraulic outfalls), tidal flats, islands, dams, and movable flow barriers or sluices. Water-quality computations can treat reactive and (or) conservative constituents simultaneously. Input requirements include bathymetric and topographic data defining land-surface elevations, time-varying water level or flow conditions at open boundaries, and hydraulic coefficients. Optional input includes the geometry of hydraulic barriers and constituent concentrations at open boundaries. Time-dependent water level, flow, and constituent-concentration data are required for model calibration and verification. Model output consists of printed reports and digital files of numerical results in forms suitable for postprocessing by graphical software programs and (or) scientific visualization packages. The model is compatible with most mainframe, workstation, mini- and micro-computer operating systems and FORTRAN compilers. This report defines the mathematical formulation and computational features of the model, explains the solution technique and related model constraints, describes the model framework, documents the type and format of inputs required, and identifies the type and format of output available.

Techniques and Methods

Rapid fluctuations in flow and water-column properties in Asan Bay, Guam: implications for selective resilience of coral reefs in warming seas

Hydrodynamics and water-column properties were investigated off west-central Guam from July 2007 through January 2008. Rapid fluctuations, on time scales of 10s of min, in currents, temperature, salinity, and acoustic backscatter were observed to occur on sub-diurnal frequencies along more than 2 km of the fore reef but not at the reef crest. During periods characterized by higher sea-surface temperatures (SSTs), weaker wind forcing, smaller ocean surface waves, and greater thermal stratification, rapid decreases in temperature and concurrent rapid increases in salinity and acoustic backscatter coincided with onshore-directed near-bed currents and offshore-directed near-surface currents. During the study, these cool-water events, on average, lasted 2.3 h and decreased the water temperature 0.57 °C, increased the salinity 0.25 PSU, and were two orders of magnitude more prevalent during the summer season than the winter. During the summer season when the average satellite-derived SST anomaly was +0.63 °C, these cooling events, on average, lowered the temperature 1.14 °C along the fore reef but only 0.11 °C along the reef crest. The rapid shifts appear to be the result of internal tidal bores pumping cooler, more saline, higher-backscatter oceanic water from depths >50 m over cross-shore distances of 100 s of m into the warmer, less saline waters at depths of 20 m and shallower. Such internal bores appear to have the potential to buffer shallow coral reefs from predicted increases in SSTs by bringing cool, offshore water to shallow coral environments. These cooling internal bores may also provide additional benefits to offset stress such as supplying food to thermally stressed corals, reducing stress due to ultraviolet radiation and/or low salinity, and delivering coral larvae from deeper reefs not impacted by surface thermal stress. Thus, the presence of internal bores might be an important factor locally in the resilience of select coral reefs facing increased thermal stress.

Coral Reefs

An updated numerical simulation of the ground-water flow system for the Castle Lake debris dam, Mount St. Helens, Washington, and implications for dam stability against heave

A numerical simulation of the ground-water flow system in the Castle Lake debris dam, calibrated to data from the 1991 and 1992 water years, was used to estimate factors of safety against heave and internal erosion. The Castle Lake debris dam, 5 miles northwest of the summit of Mount St. Helens, impounds 19,000 acre-ft of water that could pose a flood hazard in the event of a lake breakout. A new topographic map of the Castle Lake area prior to the 1980 eruption of Mount St. Helens was prepared and used to calculate the thickness of the debris avalanche deposits that compose the dam. Water levels in 22 piezometers and discharges from seeps on the dam face measured several times per year beginning in 1990 supplemented measurements in 11 piezometers and less frequent seep discharge measurements made since 1983. Observations in one group of piezometers reveal heads above the land surface and head gradients favoring upward flow that correspond to factors of safety only slightly greater than 2. The steady-state ground-water flow system in the debris dam was simulated using a threedimensional finite difference computer program. A uniform, isotropic model having the same shape as the dam and a hydraulic conductivity of 1.55 ft/day simulates the correct water level at half the observation points, but is in error by 10 ft or more at other points. Spatial variations of hydraulic conductivity were required to calibrate the model. The model analysis suggests that ground water flows in both directions between the debris dam and Castle Lake. Factors of safety against heave and internal erosion were calculated where the model simulated upward flow of ground water. A critical gradient analysis yields factors of safety as low as 2 near the piezometers where water level observations indicate low factors of safety. Low safety factors are also computed near Castle Creek where slumping was caused by a storm in January, 1990. If hydraulic property contrasts are present in areas of the debris dam unsampled by piezometers, then low safety factors may exist that are not evident in the numerical model analysis. Numerical model simulations showed that lowering Castle Lake by 40 feet increases many factors of safety by 0.1, but increases greater than 1 are limited to the area of 1990 slumping.

Washington

Phase II modification of the W ater A vailability T ool for E nvironmental R esources (WATER) for Kentucky: The sinkhole-drainage process, point-and-click basin delineation, and results of karst test-basin simulations

This report describes Phase II modifications made to the Water Availability Tool for Environmental Resources (WATER), which applies the process-based TOPMODEL approach to simulate or predict stream discharge in surface basins in the Commonwealth of Kentucky. The previous (Phase I) version of WATER did not provide a means of identifying sinkhole catchments or accounting for the effects of karst (internal) drainage in a TOPMODEL-simulated basin. In the Phase II version of WATER, sinkhole catchments are automatically identified and delineated as internally drained subbasins, and a modified TOPMODEL approach (called the sinkhole drainage process, or SDP-TOPMODEL) is applied that calculates mean daily discharges for the basin based on summed area-weighted contributions from sinkhole drain-age (SD) areas and non-karstic topographically drained (TD) areas. Results obtained using the SDP-TOPMODEL approach were evaluated for 12 karst test basins located in each of the major karst terrains in Kentucky. Visual comparison of simulated hydrographs and flow-duration curves, along with statistical measures applied to the simulated discharge data (bias, correlation, root mean square error, and Nash-Sutcliffe efficiency coefficients), indicate that the SDPOPMODEL approach provides acceptably accurate estimates of discharge for most flow conditions and typically provides more accurate simulation of stream discharge in karstic basins compared to the standard TOPMODEL approach. Additional programming modifications made to the Phase II version of WATER included implementation of a point-and-click graphical user interface (GUI), which fully automates the delineation of simulation-basin boundaries and improves the speed of input-data processing. The Phase II version of WATER enables the user to select a pour point anywhere on a stream reach of interest, and the program will automatically delineate all upstream areas that contribute drainage to that point. This capability enables automatic delineation of a simulation basin of any size (area) and having any level of stream-network complexity. WATER then automatically identifies the presence of sinkholes catchments within the simulation basin boundaries; extracts and compiles the necessary climatic, topographic, and basin characteristics datasets; and runs the SDP-TOPMODEL approach to estimate daily mean discharges (streamflow).

Kentucky

A rapid high-performance liquid-chromatographic method for simultaneously determining the concentrations of TFM and Bayer 73 in water during lampricide treatments

The high-performance liquid-chromatography (HPLC) procedure requires only minutes per sample, is specific, and is relatively sensitive (limit of detection < 0.005 mg/L for both chemicals). A combined buffer (pH 4) and internal standard (3-chlorodiphenylamine) reagent is added to the water sample, which is injected through a Sep Pak C 18 disposable cartridge. The cartridge adsorbs and retains both the lampricides and the internal standard. The quantitative elution of the three chemicals from the cartridge with a small volume of methanol effectively concentrates the sample and provides sample cleanup. The methanol extract is then analyzed directly by HPLC on an MCH 10 reverse phase column by using a methanol:0.01 mol/L acetate buffer (87:13, v:v) as the mobile phase at 2 mL/min and detected by ultraviolet spectrophotometry at 330 (or 254) nm. A microprocessor data system further facilitates the procedure by quantifying off-scale peaks and yielding results directly in units of concentration (mg/L).

Canadian Journal of Fisheries and Aquatic Sciences

Rethinking a groundwater flow system using a multiple-tracer geochemical approach: A case study in Moab-Spanish Valley, Utah

The Glen Canyon Group Aquifer (GCGA) is the sole source of public water supply for the city of Moab, Utah, a domestic and international tourist destination. Population and tourism growth are likely to target the GCGA for future water resources, but our analysis indicates that additional withdrawals would likely be sourced from groundwater storage and not be sustained by recharge. A quantitative estimate of groundwater discharge from the GCGA is problematic because the downgradient aquifer boundary is the Colorado River, and groundwater discharge to the river is very small compared to the river flow. A water budget based on a conceptual model of GCGA discharging into an adjacent alluvial Valley-Fill Aquifer (VFA) was reported by Sumsion (1971) and numerous subsequent studies have repeated and utilized this water budget. The GCGA contains stable isotopes, tritium, 3 He/ 4 He ratios, dissolved solids, and sulfate concentrations that contrast with the VFA, indicating it is instead recharged by local streams rather than from the GCGA. Water-budget calculations, based on: (1) measured spring discharge and streamflow gains, (2) horizontal gradients in VFA groundwater age, and (3) GCGA outcrop area vadose-zone pore waters are all less than previously thought. Using a lumped parameter model and 14 C groundwater ages, we estimate recharge to the deeper GCGA (DGCGA) to be 4.2 ± 2.3 × 10 6 m 3 /yr, which is approximately equal to the measured discharge from wells and springs.

Utah

Integrating urban planning and water management through green infrastructure in the United States-Mexico border

Creating sustainable, resilient, and livable cities calls for integrative approaches and collaborative practices across temporal and spatial scales. However, practicability is challenged by institutional, social, and technical complexities and the need to build collective understanding of integrated approaches. Rapid urbanization along the United States-Mexico border, fueled by industrialization, trade, and migration, has resulted in cities confronted with recurrent flooding risk, extended drought, water pollution, habitat destruction and systemic vulnerabilities. The international border, which separates natural and built ecosystems, is both a challenge and an opportunity, making a unique social and institutional setting ideal for testing the integration of urban planning and water management. Our research focuses on fusing multi-functional and multi-scalar green infrastructure to restore ecosystem services through a strategic binational planning process. This paper describes this planning process, including the development and application of both a land suitability analysis and a hydrological model to optimally site green infrastructure in the Nogales, Arizona, United States—Nogales, Sonora, Mexico, cross border region. We draw lessons from this process and stakeholder feedback focused on the potential for urban green infrastructure, to allow for adaptation and even transformation in the face of current and future challenges such as limited resources, underdeveloped governance, bordering, and climate change. In sum, a cross border network of green infrastructure can provide a backbone to connect this transboundary watershed while providing both hydrological and social benefits.

Frontiers in Water

Development of the benethic nepheloid layer on the south Texas continental shelf, western Gulf of Mexico

A monitoring study of suspended sediment on the South Texas Continental Shelf indicates that a turbid benthic nepheloid layer is regionally persistent. A sequence of quasi-synoptic measurements of the water column obtained during six cruises in an 18-month period indicates substantial spatial and temporal variability in nepheloidlayer characteristics. Regionally, the thickness of the shelf nepheloid layer increases both seaward and in a convergent alongshelf direction. Greatest thicknesses occur over a muddy substrate, indicating a causal relationship; maximum observed local thickness is 35 m which occurs along the southern shelf break. Analyses of suspended particulate matter in shelf bottom waters indicate mean concentrations ranging from 49 · 10 4 to 111 · 10 4 particle counts/cc; concentrations persistently increase shoreward throughout the region. Bottom particulate matter is predominantly composed of inorganic detritus. Admixtures of organic skeletal particles, primarily diatoms, are generally present but average less than 10% of the total particulate composition. Texturally, the particulate matter in bottom waters is predominantly poorly sorted sediment composed of very fine silt (3.9–7.8 μm). The variability in nepheloid-layer characteristics indicates a highly dynamic shelf feature. The relationship of nepheloid-layer characteristics to hydrographic and substrate conditions suggests a conceptual model whereby nepheloid-layer development and maintenance are the results of the resuspension of sea-floor sediment. Bottom turbulence is attributed primarily to vertical shear and shoaling progressive internal waves generated by migrating shelf-water masses, especially oceanic frontal systems, and secondarily to shoaling surface gravity waves.

Texas

Voyageurs National Park: Water-level regulation and effects on water quality and aquatic biology

Following dam installations in the remote Rainy Lake Basin during the early 1900s, water - level fluctuations were considered extreme (1914–1949) compared to more natural conditions. In 1949, the International Joint Commission (IJC), which sets rules governing dam operation on waters shared by the United States and Canada, established the first rule curves to regulate water levels on these waterbodies. However, rule curves established prior to 2000 were determined to be detrimental to the ecosystem. Therefore, the IJC implemented an order in 2000 to change rule curves and to restore a more natural water regime. After 2000, measured chlorophyll- a concentrations in the two most eutrophic water bodies decreased whereas concentrations in oligotrophic lakes did not show significant water - quality differences. Fish mercury data were inconclusive, due to the variation in water levels and fish mercury concentrations, but can be used by the IJC as part of a long term data set.

Minnesota

Synthesis of monthly and annual streamflow records (water years 1950-2003) for Big Sandy, Clear, Peoples, and Beaver Creeks in the Milk River basin, Montana

To address concerns expressed by the State of Montana about the apportionment of water in the St. Mary and Milk River basins between Canada and the United States, the International Joint Commission requested information from the United States government about water that originates in the United States but does not cross the border into Canada. In response to this request, the U.S. Geological Survey synthesized monthly and annual streamflow records for Big Sandy, Clear, Peoples, and Beaver Creeks, all of which are in the Milk River basin in Montana, for water years 1950-2003. This report presents the synthesized values of monthly and annual streamflow for Big Sandy, Clear, Peoples, and Beaver Creeks in Montana. Synthesized values were derived from recorded and estimated streamflows. Statistics, including long-term medians and averages and flows for various exceedance probabilities, were computed from the synthesized data. Beaver Creek had the largest median annual discharge (19,490 acre-feet), and Clear Creek had the smallest median annual discharge (6,680 acre-feet). Big Sandy Creek, the stream with the largest drainage area, had the second smallest median annual discharge (9,640 acre-feet), whereas Peoples Creek, the stream with the second smallest drainage area, had the second largest median annual discharge (11,700 acre-feet). The combined median annual discharge for the four streams was 45,400 acre-feet. The largest combined median monthly discharge for the four creeks was 6,930 acre-feet in March, and the smallest combined median monthly discharge was 48 acre-feet in January. The combined median monthly values were substantially smaller than the average monthly values. Overall, synthesized flow records for the four creeks are considered to be reasonable given the prevailing climatic conditions in the region during the 1950-2003 base period. Individual estimates of monthly streamflow may have large errors, however. Linear regression was used to relate logarithms of combined annual streamflow to water years 1950-2003. The results of the regression analysis indicated a significant downward trend (regression line slope was -0.00977) for combined annual streamflow. A regression analysis using data from 1956-2003 indicated a slight, but not significant, downward trend for combined annual streamflow.

Scientific Investigations Report

Groundwater – The disregarded component in lake water and nutrient budgets. Part 2: effects of groundwater on nutrients

Lacustrine groundwater discharge (LGD) transports nutrients from a catchment to a lake, which may fuel eutrophication, one of the major threats to our fresh waters. Unfortunately, LGD has often been disregarded in lake nutrient studies. Most measurement techniques are based on separate determinations of volume and nutrient concentration of LGD: Loads are calculated by multiplying seepage volumes by concentrations of exfiltrating water. Typically low phosphorus (P) concentrations of pristine groundwater often are increased due to anthropogenic sources such as fertilizer, manure or sewage. Mineralization of naturally present organic matter might also increase groundwater P. Reducing redox conditions favour P transport through the aquifer to the reactive aquifer-lake interface. In some cases, large decreases of P concentrations may occur at the interface, for example, due to increased oxygen availability, while in other cases, there is nearly no decrease in P. The high reactivity of the interface complicates quantification of groundwater-borne P loads to the lake, making difficult clear differentiation of internal and external P loads to surface water. Anthropogenic sources of nitrogen (N) in groundwater are similar to those of phosphate. However, the environmental fate of N differs fundamentally from P because N occurs in several different redox states, each with different mobility. While nitrate behaves essentially conservatively in most oxic aquifers, ammonium's mobility is similar to that of phosphate. Nitrate may be transformed to gaseous N 2 in reducing conditions and permanently removed from the system. Biogeochemical turnover of N is common at the reactive aquifer-lake interface. Nutrient loads from LGD were compiled from the literature. Groundwater-borne P loads vary from 0.74 to 2900 mg PO 4 -P m −2 year −1 ; for N, these loads vary from 0.001 to 640 g m −2 year −1 . Even small amounts of seepage can carry large nutrient loads due to often high nutrient concentrations in groundwater. Large spatial heterogeneity, uncertain areal extent of the interface and difficult accessibility make every determination of LGD a challenge. However, determinations of LGD are essential to effective lake management.

Hydrological Processes

Water-quality response to changes in phosphorus loading of the Winnebago Pool Lakes, Wisconsin, with special emphasis on the effects of internal loading in a chain of shallow lakes

The Winnebago Pool is a chain of four shallow lakes (Lake Poygan, Lake Winneconne, Lake Butte des Morts, and Lake Winnebago) that are fed primarily by the Fox and Wolf Rivers, two large agriculturally dominated rivers in Wisconsin, United States. Because the lakes have received extensive phosphorus inputs from their watershed, they have become highly eutrophic with much phosphorus in the water column as well as trapped in their sediments. Each of the four Winnebago Pool lakes has been included on the Wisconsin Department of Natural Resources impaired waters list because of their high total phosphorus concentrations, water-quality use restrictions, and excess algal growth. The study described in this report is part of a Total Maximum Daily Load investigation to determine what actions are needed to improve the water quality (trophic status) of these lakes and thus be able to be removed from the impaired waters list and restore their designated uses. As part of this study, data were collected to describe the existing water quality of the lakes, detailed phosphorus budgets were developed for each of the lakes to describe the different sources of the phosphorus, and two eutrophication models (BATHTUB and Jensen models) were used to determine how much of the phosphorus being input to the lakes needs to be reduced for the lakes to be removed from the impaired waters list and restore their designated uses. In-lake water-quality data indicated that each of the lakes had extensive vertical mixing that resulted in their water quality deteriorating throughout summer. Each of the lakes had mean summer total phosphorus concentrations exceeding 0.088 milligram per liter (mg/L), well above the 0.040 mg/L criterion for the lakes. Detailed phosphorus budgets for the lakes indicated that the primary sources of phosphorus were from their tributaries (for the most upstream lake in the Winnebago Pool–Lake Poygan) or from a combination of input from the upstream lakes and phosphorus release from the bottom sediment when only the summer months were considered (for the other three lakes). Model simulations with the BATHTUB and Jensen models indicated that (1) the lakes should have almost linear response in their total phosphorus concentrations to changes in their phosphorus inputs; (2) phosphorus inputs need to be reduced by about 60 percent to the Upper Pool Lakes and 69–73 percent to Lake Winnebago to reduce their mean summer total phosphorus concentrations to 0.040 mg/L; and (3) if all the anthropogenic phosphorus inputs to the lakes could be eliminated, their best possible mean summer total phosphorus concentrations should decrease to about 0.022–0.028 mg/L in the Upper Pool Lakes and to 0.032–0.033 mg/L in Lake Winnebago. The effects of any reduction in phosphorus loading will take many years (50 to more than 75 years) to be fully realized in lake water quality because of phosphorus release from the lake sediments. The effects of nutrient reductions in the watershed of a chain of lakes, such as the Winnebago Pool, gradually cascades down the chain, which has beneficial and detrimental effects. Any action made in the watershed of upstream lakes to reduce phosphorus inputs should improve the water quality of all downstream lakes; however, the upstream lakes delay the response in the downstream lakes, especially in lakes where internal phosphorus loading is important.

Wisconsin

Investigation of denitrification rates in an ammonia-dominated constructed wastewater treatment wetland

Denitrification measurements were made under simulated field conditions using sediment cores and water collected from the Hemet/San Jacinto Multipurpose Demonstration Wetland (Riverside County, California, USA). The 9.9 ha constructed wetland is used to both polish ammonia-dominated secondary municipal effluent and provide migratory bird habitat. The wetland was originally constructed as a marsh-pond-marsh system in 1994. Over the period from January through March 1998, measured denitrification rates averaged 20.9 ± 20.9 μmol N m −2 h −1 within the emergent marsh portions of the wetland and 646 ± 353 μmol N m −2 h −1 in open water areas. The mean areal denitrification removal rate for this period was 0.70 kg N ha −1 d −1 , which accounted for about 8% of the total N removed by the wetland. Internal retention was the main N-removal mechanism. Synoptic water quality surveys indicated that denitrification was limited by a lack of nitrification within the wetland. Between April 1998 and January 1999, the wetland was reconfigured as a hemi-marsh system, having equal areas of interspersed emergent marsh and deep open water. In May 1999, measured denitrification rates averaged 1414 ± 298 μmol N m −2 h −1 within the emergent marsh zones and 682 ± 218 μmol N m −2 h −1 in the open water areas. The mean areal denitrification removal rate was 3.58 kg N ha −1 d −1 , which accounted for 40% of the total N removed by the wetland. A synoptic water quality survey indicated that nitrification within the wetland had been enhanced by the reduction of emergent macrophyte biomass and the increase in the area of interspersed deep open water. The modifications to the wetland shifted the nitrogen balance from a large internal storage component and a small denitrification component in 1998 to a more denitrifying system in 1999.

Wetlands