Uranium in the metal-mining districts of Colorado
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The Wood-East Calhoun mine area is underlain by complexly folded Precambrian gneiss and pegmatite. The major fold in the area is an anticline that trends about N. 60° E. The Precambrian rocks are intruded by bostonite porphyry dikes of Tertiary age. All the rocks are cut by east- to northeast - trending faults that have been filled by precious metal-sulfide veins which have been worked chiefly for gold. The Wood vein occurs in an east-trending fault; the Calhoun vein occurs in a northeast-trending fault. Much of the uranium production of the Central City district has come from the Wood vein on Quartz Hill. The veins consist chiefly of quartz; pyrite is the chief metallic mineral and chalcopyrite is next in abundance. Sphalerite, galena, tetrahedrite-tennantite, and pitchblende are locally present. Deposition began with alteration-stage quartz and pyrite followed in order by pitchblend, light-yellow pyrite, massive quartz, yellow pyrite, shalerite, comb quartz, chalcopyrite, tetrahedrite-tennantite, galena, chalcopyrite, pyrite, and gray to light-brown fine-grained quartz. The veins of the Central City district are zoned, with quartz-pyrite veins near the center and galena-sphalerite veins on the periphery. The known pitchblende bodies are in the transition between these, but paragenetically, the pitchblende is earlier than all other metallic minerals. A trace element study of the ore indicates an association of zirconium and molybdenum with uranium, of bismuth, antimony, and arsenic with copper, and of cadmium with zinc. The pitchblende and other ore minerals are concentrated in ore shoots. The shoots are in open spaces controlled by the competency of the wall rocks, the presence of a prevailing direction of weakness in the rocks, and changes in strike and dip of the vein. The pitchblende is thought to be a local constituent of the quartz-pyrite ores and to owe its origin to residual solutions from the quartz bostonite magma.
Uranium deposits that contain uraniferous pyrobitumen of possible hydrothermal origin occur at the Weatherly and Robinson properties near Placerville, San Miguel County, Colo. These deposits were mined for copper, silver, and gold more than 50 years ago and were developed for uranium in 1950.
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The first field work for the purpose of determining the radioactivity of Pennsylvania black shales in Oklahoma was done in October, 1944, in the vicinity of Tulsa. Small phosphatic nodules were found to have relatively high radioactivity, particularly those in the black shale overlying the Checkerboard limestone. In May and June, 1945, more work was done in order to determine with more assurance, the abundance and radioactivity of the nodules. The later work covered all known black shale horizons in the Pennsylvanian system that could be found. The work extended as far north as Kansas City. A number of coals of Pennsylvanian age were tested. They are all much too low in radioactivity to be of further interest. The black shale over the Checkerboard limestone is the best horizon from the standpoint of abundance and radioactivity of nodules. One sample of nodules from this shale contains 0.186 percent equivalent uranium, 0.095 percent uranium. However, the distribution and radioactivity of the nodules are widely variable. The average nodule content of the black shale is about two percent over a thickness of about 2.5 feet. The average equivalent uranium content of the nodules is about 0.035 percent and the average uranium content 0.015 to 0.020 percent. With a product of this grade in view, the large mining operation necessary to produce a relatively small amount of nodules does not seem justified. Two black shale beds, each about two feet thick and neither of which contains any nodules, contain 0.024 and 0.017 percent equivalent uranium and 0.013 and 0.010 percent uranium respectively. Too little work was done to permit calculations of tonnage, but material of this grade does not merit more detailed work at this time.
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Several mines and prospects in the Fairbanks and Livengood quadrangles, east-central Alaska, were examined for the possible presence of radioactive materials in the summer of 1949. Also tested were pre-Cambrian and Paleozoic metamorphic and sedimentary rocks crossed by the Elliott Highway, which extends from Fox, near Fairbanks, northward about 70 miles to the town of Livengood. None of the lodes tested exhibited radioactivity in excess of 0.003 percent equivalent uranium, although nuggets consisting chiefly of native bismuth and containing as much as 0.1 percent equivalent uranium had been found previously in a placer on Fish Creek several miles below the reported bismuth-bearing lode on Melba Creek. The greatest radioactivity found in the rocks along the Elliott Highway was in an iron-stained schist of pre-Cambrian age and in carbonaceous shale of Middle Devonian or Carboniferous age. Respective samples of these rocks contain 0.003 and 0.004 percent equivalent uranium. A possible local bedrock source for a euxenite-polycrase mineral found in a placer concentrate containing about 0.04 percent equivalent uranium was sought in the watershed of Goodluck Creek, near Livengood. The bedrock source of this mineral could not be located; it is believed that the source could be outside of the Goodluck watershed, as drainage changes in the area during Quaternary time might well have introduced gravels from nearby areas.
Reconnaissance for uranium in coal and black shale in New Mexico during 1952 was largely an extension of work initiated during the 1951 field season. No uranium deposits of economic interest were found, although minor amounts of uranium were noted at several localities.
The search for uranium in the United States is one of the most intensive ever made for any metal during our history. The number of prospectors and miners involved is difficult to estimate but some measure of the size of the effort is indicated by the fact that about 500 geologists are employed by government and industry in the work--more than the total number of geologists engaged in the study of all other minerals together except oil. The largest part of the effort has been concentrated in the western states. No single deposit of major importance by world standards has been discovered but the search has led to the discovery of important minable deposits of carnotite and related minerals on the Colorado Plateau; of large, low grade deposits of uranium in phosphates in the northwestern states and in lignites in the Dakotas, Wyoming, Idaho and New Mexico; and of many new and some promising occurrences of uranium in carnotite-like deposits and in vein deposits. Despite the fact that a large number of the districts considered favorable for the occurrence of uranium have already been examined, the outlook for future discoveries is bright, particularly for uranium in vein and in carnotite-like deposits in the Rocky Mountain States.
Procedures are presented in detail of two methods for the determination of very small percentages of uranium (down to 0.0028). The methods are applicable to a wide variety of materials. Notes on the methods and confirmatory experiments are also given.