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The Hf isotopic composition of ferromanganese nodules and crusts and hydrothermal manganese deposits: Implications for seawater Hf

We present Hf and Pb isotopic data, and chemical compositions of the outermost layers of marine ferromanganese deposits of different types (hydrogenous and hydrothermal) with a worldwide distribution. The Hf isotopic compositions display a broad range and refine previously reported regional differences as follows: Atlantic Ocean ɛ Hf = −4to+2, Indian Ocean ɛ Hf = +2to+4, Pacific Ocean ɛ Hf = +3to+10. The most radiogenic Hf isotopic compositions in the Pacific samples are for hydrothermal manganese deposits that also have low 207 Pb 204 Pb, demonstrating that this signature reflects a contribution from hydrothermal venting of Hf leached from oceanic volcanic rocks rather than from riverine inputs, volcanic ash, or eolian dust. Hafnium concentrations in the deposits increase from 20 ppb to 20 ppm with decreasing ɛ Hf , The Hf and Pb isotopic compositions for ferromanganese crusts define an apparent mixing trend between literature values of average continental crust and MORB. The range in ɛ Hf for ferromanganese crusts is narrower than it is for 206 Pb 204 Pb compared to the differences in isotopic composition of the sources of Hf and Pb. This is consistent with Hf having a longer residence time than Pb. The concentration of Hf in ferromanganese crusts has been found to co-vary with growth rate, and inversely correlates with Hf isotopic compositions. Hf isotope ratios may be used to determine not only the source of Hf, but possibly the source of Fe and Mn. Measurements of ɛ Hf and Hf concentrations in nodule tops, bottoms and associated sediments show that the ɛ Hf of nodules is sensitive to sedimentary oxic and sub-oxic diagenetic processes and thus most nodules may not reliably reflect the isotopic composition of Hf in seawater.

Earth and Planetary Science Letters↗

Report of the Science Community Workshop on the proposed First Sample Depot for the Mars Sample Return Campaign

The Mars 2020/Mars Sample Return (MSR) Sample Depot Science Community Workshop was held on September 28 and 30, 2022, to assess the Scientifically-Return Worthy (SRW) value of the full collection of samples acquired by the rover Perseverance at Jezero Crater, and of a proposed subset of samples to be left as a First Depot at a location within Jezero Crater called Three Forks. The primary outcome of the workshop was that the community is in consensus on the following statement: The proposed set of ten sample tubes that includes seven rock samples, one regolith sample, one atmospheric sample, and one witness tube constitutes a SRW collection that: (1) represents the diversity of the explored region around the landing site, (2) covers partially or fully, in a balanced way, all of the International MSR Objectives and Samples Team scientific objectives that are applicable to Jezero Crater, and (3) the analyses of samples in this First Depot on Earth would be of fundamental importance, providing a substantial improvement in our understanding of Mars. At the conclusion of the meeting, there was overall community support for forming the First Depot as described at the workshop and placing it at the Three Forks site. The community also recognized that the diversity of the Rover Cache (the sample collection that remains on the rover after placing the First Depot) will significantly improve with the samples that are planned to be obtained in the future by the Perseverance rover and that the Rover Cache is the primary target for MSR to return to Earth.

Meteoritics and Planetary Science↗

Short-period volcanic gas precursors to phreatic eruptions: Insights from Poás Volcano, Costa Rica

Volcanic eruptions involving interaction with water are amongst the most violent and unpredictable geologic phenomena on Earth. Phreatic eruptions are exceptionally difficult to forecast by traditional geophysical techniques. Here we report on short-term precursory variations in gas emissions related to phreatic blasts at Poás volcano, Costa Rica, as measured with an in situ multiple gas analyzer that was deployed at the edge of the erupting lake. Gas emitted from this hyper-acid crater lake approaches magmatic values of SO 2 /CO 2 1–6 days prior to eruption. The SO 2 flux derived from magmatic degassing through the lake is measureable by differential optical absorption spectrometry (sporadic campaign measurements), which allows us to constrain lake gas output and input for the major gas species during eruptive and non-eruptive periods. We can further calculate power supply to the hydrothermal system using volatile mass balance and thermodynamics, which indicates that the magmatic heat flux into the shallow hydrothermal system increases from ∼27 MW during quiescence to ∼59 MW during periods of phreatic events. These transient pulses of gas and heat from the deeper magmatic system generate both phreatic eruptions and the observed short-term changes in gas composition, because at high gas flux scrubbing of sulfur by the hydrothermal system is both kinetically and thermodynamically inhibited whereas CO 2 gas is always essentially inert in hyperacid conditions. Thus, the SO 2 /CO 2 of lake emissions approaches magmatic values as gas and power supply to the sub-limnic hydrothermal system increase, vaporizing fluids and priming the hydrothermal system for eruption. Our results suggest that high-frequency real-time gas monitoring could provide useful short-term eruptive precursors at volcanoes prone to phreatic explosions.

Poás Volcano↗

Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the Southern Andes

Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33–46°S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49–54°S) range for 87 Sr/ 86 Sr from 0.70280 to 0.70591 and for 143 Nd/ 144 Nd from 0.51314 to 0.51255. The ranges are significantly greater than previously reported from the southern Andes but are different from the isotopic compositions of volcanoes in the central and northern Andes. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87 Sr/ 86 Sr , 143 Nd/ 144 Nd , La/Yb , Ba/La , and Hf/Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35°S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33° and 34°S, basaltic andesites and andesites have higher 87 Sr/ 86 Sr , Rb/Cs , and Hf/Lu , and lower 143 Nd/ 144 Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54°S) has Sr and Nd isotopic compositions and KR/b and Ba/La similar to MORB. The high La/Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO 2 , K 2 O, Rb, Ba, Ba/La , and 87 Sr/ 86 Sr/ and decrease in MgO, Sr, KR/b , Rb/Cs , and 143 Nd/ 144 Nd , suggesting increasingly greater degrees of fractional crystallization and associated intra-crustal contamination.

Earth and Planetary Science Letters↗

Analysis of a cryolava flow-like feature on Titan

This paper reports on the analysis of the highest spatial resolution hyperspectral images acquired by the Visual and Infrared Mapping Spectrometer (VIMS) onboard the Cassini spacecraft during its prime mission. A bright area matches a flow-like feature coming out of a caldera-like feature observed in Synthetic Aperture Radar (SAR) data recorded by the Cassini radar experiment [Lopes et al., 2007. Cryovolcanic features on Titan's surface as revealed by the Cassini Titan Radar Mapper. Icarus 186, 395–412, doi:10.1016/j.icarus.2006.09.006]. In this SAR image, the flow extends about 160 km east of the caldera. The contrast in brightness between the flow and the surroundings progressively vanishes, suggesting alteration or evolution of the composition of the cryolava during the lifetime of the eruptions. Dunes seem to cover part of this flow on its eastern end. We analyze the different terrains using the Spectral Mixing Analysis (SMA) approach of the Multiple-Endmember Linear Unmixing Model (MELSUM, Combe et al., 2008). The study area can be fully modeled by using only two types of terrains. Then, the VIMS spectra are compared with laboratory spectra of known materials in the relevant atmospheric windows (from 1 to 2.78 μm). We considered simple molecules that could be produced during cryovolcanic events, including H 2 O, CO 2 (using two different grain sizes), CH 4 and NH 3 . We find that the mean spectrum of the cryoflow-like feature is not consistent with pure water ice. It can be best fitted by linear combinations of spectra of the candidate materials, showing that its composition is compatible with a mixture of H 2 O, CH 4 and CO 2.

Planetary and Space Science↗

Planetary defense preparedness: Identifying the potential for post-asteroid impact time delayed and geographically displaced hazards

A considerable amount of effort has been done to quantify impact effects from the impact of an asteroid. The effects usually considered are: blast, overpressure shock, thermal radiation, cratering, seismic shaking, ejecta, and tsunami (e.g. Hills & Goda, 1993; Collins et al., 2005, Rumpf et al., 2017). These first-order effects typically are localized in time and diminish with increased distance from the impact (or air burst) location. However, there are delayed effects that will propagate through time and occur in areas not immediately affected by the initial impact. These delayed effects include, but are not limited to, down-stream and down-wind effects. Down-stream effects could occur months after the impact as sediment and debris are washed into reservoirs, potentially impacting water quality for populations not originally affected by the impact event. Down-wind effects could deposit dust and debris hundreds or thousands of kilometers down-wind, reducing insolation and ultimately settling out over large areas which could include cropland. Depending on when this occurs, significant damage could occur to croplands, thus reducing or eliminating whole sections of the global food chain. In addition, depending on the amount of ashfall, the deposition of dust and debris could cross watershed boundaries and thus affect water quality for a larger population than just those who live in the initial impacted watershed. For most smaller asteroid impacts, these delayed effects can be neglected. However, there are likely a class of impacts (e.g. impactor size and composition, impact location and time of year) where failure to consider these effects could complicate post-impact relief and recovery efforts. For example, evacuation of the population within the initial damage zone from an impact to a city down-stream could exacerbate water quality issues and water usage months later. An impact in western Nebraska might have minimal civil defense requirements for evacuation (due to the low population density) but the down-wind effects could disrupt both the economic health of the American Midwest while threatening global food security. Understanding when these time-delayed and geographically displaced effects become relevant is key to successful civil defense and recovery planning.

Bulletin of the AAS↗

Geochronology and paleoclimatic implications of the last deglaciation of the Mauna Kea Ice Cap, Hawaii

We present new 3He surface exposure ages on moraines and bedrock near the summit of Mauna Kea, Hawaii, which refine the age of the Mauna Kea Ice Cap during the Local Last Glacial Maximum (LLGM) and identify a subsequent fluctuation of the ice margin. The 3He ages, when combined with those reported previously, indicate that the local ice-cap margin began to retreat from its LLGM extent at 20.5??2.5ka, in agreement with the age of deglaciation determined from LLGM moraines elsewhere in the tropics. The ice-cap margin receded to a position at least 3km upslope for ~4.5-5.0kyr before readvancing nearly to its LLGM extent. The timing of this readvance at ~15.4ka corresponds to a large reduction of the Atlantic meridional overturning circulation (AMOC) following Heinrich Event 1. Subsequent ice-margin retreat began at 14.6??1.9ka, corresponding to a rapid resumption of the AMOC and onset of the B??lling warm interval, with the ice cap melting rapidly to complete deglaciation. Additional 3He ages obtained from a flood deposit date the catastrophic outburst of a moraine-dammed lake roughly coeval with the Younger Dryas cold interval, suggesting a more active hydrological cycle on Mauna Kea at this time. A coupled mass balance and ice dynamics model is used to constrain the climate required to generate ice caps of LLGM and readvance sizes. The depression of the LLGM equilibrium line altitude requires atmospheric cooling of 4.5??1??C, whereas the mass balance modeling indicates an accompanying increase in precipitation of as much as three times that of present. We hypothesize (1) that the LLGM temperature depression was associated with global cooling, (2) that the temperature depression that contributed to the readvance occurred in response to an atmospheric teleconnection to the North Atlantic, and (3) that the precipitation enhancement associated with both events occurred in response to a southward shift in the position of the inter-tropical convergence zone (ITCZ). Such a shift in the ITCZ would have allowed midlatitude cyclones to reach Mauna Kea more frequently which would have increased precipitation at high elevations and caused additional cooling. ?? 2010 Elsevier B.V.

Earth and Planetary Science Letters↗

Composition of Titan's surface from Cassini VIMS

Titan's bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite's dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan's solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan's history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission's visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5 ??m were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan Ta encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79 ??m in the poorly understood 2.8-??m methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-??m methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8 ??m that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface. ?? 2006 Elsevier Ltd. All rights reserved.

Planetary and Space Science↗

Crystallisation ages in coeval silicic magma bodies: 238U-230Th disequilibrium evidence from the Rotoiti and earthquake flat eruption deposits, Taupo volcanic zone, New Zealand

The timescales over which moderate to large bodies of silicic magma are generated and stored are addressed here by studies of two geographically adjacent, successive eruption deposits in the Taupo Volcanic Zone, New Zealand. The earlier, caldera-forming Rotoiti eruption (>100 km3 magma) at Okataina volcano was followed, within months at most, by the Earthquake Flat eruption (??? 10 km3 magma) from nearby Kapenga volcano; both generated nonwelded ignimbrite and coeval widespread fall deposits. The Rotoiti and Earthquake Flat deposits are both crystal-rich high-silica rhyolites, with sparse glass-bearing granitoid fragments also occurring in Rotoiti lag breccias generated during caldera collapse. Here we report 238U-230Th disequilibrium data on whole rocks and mineral separates from representative Rotoiti and Earthquake Flat pumices and the co-eruptive Rotoiti granitoid fragments using TIMS and in situ zircon analyses by SIMS. Multiple-grain zircon-controlled crystallisation ages measured by TIMS from the Rotoiti pumice range from 69??3 ka (<63 ?? size fraction) to 76??6 (125-250 ?? fraction), with a weighted mean of all size fractions of 71??2 ka. SIMS model ages from single zircons in pumice range from 50??24 ka to > 350 ka, with a pronounced peak at 70-90 ka. The weighted mean of isochrons is 83??14 ka, in accord with the TIMS data. One glass-bearing Rotoiti granitoid clast yielded an age of 57??8 ka by TIMS (controlled by Th-rich phases that, however, are not apparently present in the juvenile pumices). Another glass-bearing Rotoiti granitoid yielded SIMS zircon model ages peaking at 60-90 ka, having a similar age distribution to the pumice. Age data from pumices are consistent with a published 64??4 ka eruptive age (now modified to 62??2 ka), but chemical and/or mineralogical data imply that the granitoid lithics are not largely crystalline Rotoiti rhyolite, but instead represent contemporaneous partly molten intrusions reflecting different sources in their chemistries and mineralogies. Similarly, although the Earthquake Flat eruption immediately followed (and probably was triggered by) the Rotoiti event, age data from juvenile material are significantly different. A multiple-grain zircon-controlled crystallisation age measured by TIMS from a representative pumice is 173??5 ka, while SIMS model ages range from 70-26+34 ka to >350 ka, with a peak at 105 ka. These age data coupled with previously published geochemical and isotopic data show that the Rotoiti and Earthquake Flat deposits were erupted from independent, unconnected magma bodies. Published by Elsevier Science B.V.

Earth and Planetary Science Letters↗

Rapid Holocene deposition in the Mackenzie Trough and Barrow Canyon areas in the western Arctic Ocean

The Arctic Ocean and terrestrial environment have recently been reported to be changing drastically, but it is unclear whether these changes are similar to natural variations in the past or how sudden and large the changes are compared to natural variations. This premise served as motivation to collect sediment cores during the summer of 2022 at four sites on the Canadian continental shelf and Alaskan upper continental slope to reconstruct changes in the marine and terrestrial environments to provide a comprehensive picture of the ocean environment during the preindustrial period before anthropogenic influences. We dated the sediments based on the 137 Cs radioactivity of bulk sediments and the 14 C concentrations of mollusk shells. The 137 Cs radioactivity shows a distinct onset corresponding to 1950 Common Era (CE) and the most prominent peak corresponding to 1963 CE. Multiple peaks appeared above the most prominent one, coinciding with nuclear power plant accidents in 1986 and 2011. Inventories of excess 210 Pb in all cores exceed the estimated supply of excess 210 Pb from atmospheric deposition, likely due to the scavenging supply of excess 210 Pb. By comparing 137 Cs and radiocarbon conventional ages, we estimated the local radiocarbon reservoir age value of each site. Using these local radiocarbon reservoir age and the conventional ages of mollusk shell samples, we established the age-depth models by the Bayesian method. The optimal ΔR values were 598, 511, 65, and –60 years at the MT1, MT2, BC2, and BC2-2 sites, respectively. The cores consist of clayey silts continuously deposited with uniquely high sedimentation rates of 0.17 to 0.74 cm y −1 . Variation in the Ca/Ti ratio indicates ~ 20, ~ 30, 50–60, 100–125, and 300-year cycles, likely attributed to the variation in the Aleutian Low that controls the Bering Strait inflow of Pacific waters influencing our core sites. These sediments will be used for further high-resolution, multi-proxy studies with forthcoming results.

western Arctic Ocean↗

Osmium isotope and highly siderophile element systematics of the lunar crust

Coupled 187 Os/ 188 Os and highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, and Re) abundance data are reported for pristine lunar crustal rocks 60025, 62255, 65315 (ferroan anorthosites, FAN) and 76535, 78235, 77215 and a norite clast in 15455 (magnesian-suite rocks, MGS). Osmium isotopes permit more refined discrimination than previously possible of samples that have been contaminated by meteoritic additions and the new results show that some rocks, previously identified as pristine, contain meteorite-derived HSE. Low HSE abundances in FAN and MGS rocks are consistent with derivation from a strongly HSE-depleted lunar mantle. At the time of formation, the lunar floatation crust, represented by FAN, had 1.4 ?? 0.3 pg g - 1 Os, 1.5 ?? 0.6 pg g - 1 Ir, 6.8 ?? 2.7 pg g - 1 Ru, 16 ?? 15 pg g - 1 Pt, 33 ?? 30 pg g - 1 Pd and 0.29 ?? 0.10 pg g - 1 Re (??? 0.00002 ?? CI) and Re/Os ratios that were modestly elevated ( 187 Re/ 188 Os = 0.6 to 1.7) relative to CI chondrites. MGS samples are, on average, characterised by more elevated HSE abundances (??? 0.00007 ?? CI) compared with FAN. This either reflects contrasting mantle-source HSE characteristics of FAN and MGS rocks, or different mantle-crust HSE fractionation behaviour during production of these lithologies. Previous studies of lunar impact-melt rocks have identified possible elevated Ru and Pd in lunar crustal target rocks. The new results provide no supporting evidence for such enrichments. If maximum estimates for HSE in the lunar mantle are compared with FAN and MGS averages, crust-mantle concentration ratios (D-values) must be ??? 0.3. Such D-values are broadly similar to those estimated for partitioning between the terrestrial crust and upper mantle, with the notable exception of Re. Given the presumably completely different mode of origin for the primary lunar floatation crust and tertiary terrestrial continental crust, the potential similarities in crust-mantle HSE partitioning for the Earth and Moon are somewhat surprising. Low HSE abundances in the lunar crust, coupled with estimates of HSE concentrations in the lunar mantle implies there may be a 'missing component' of late-accreted materials (as much as 95%) to the Moon if the Earth/Moon mass-flux estimates are correct and terrestrial mantle HSE abundances were established by late accretion. ?? 2009 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

U.S. Geological Survey Karst Interest Group proceedings, Nashville, Tennessee, October 22-24, 2024

Karst hydrogeologic systems represent challenging and unique conditions to scientists studying groundwater flow and contaminant transport. Karst terrains are characterized by distinct and beautiful landscapes, caverns, and springs, and many of the exceptional karst areas are designated as national or state parks. The range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than any other aquifer type. The U.S. Geological Survey (USGS) Karst Interest Group (KIG), formed in 2000, is a loosely knit, grassroots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst aquifers. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. To accomplish its mission, the KIG has organized a series of workshops. To date (2024), nine KIG workshops, including the workshop documented in this report, have been held. The abstracts and extended abstracts provide a snapshot in time of past and current karst related studies. The USGS Water Availability and Use Science Program funded the workshop and proceedings. The planning committee for the ninth workshop includes Thomas D. Byl (USGS and Tennessee State University), Allan K. Clark (USGS), Laura M. DeMott (USGS), Eve L. Kuniansky (USGS, Emeritus), Benjamin V. Miller (USGS), and Lawrence E. Spangler (USGS, Emeritus). The workshop proceedings are edited by Eve L. Kuniansky and Lawrence E. Spangler. The field trip guide was produced by Benjamin V. Miller and Brian Ham (Tennessee Department of Environment and Conservation) and included in the proceedings from the KIG’s 2021 virtual workshop to be used on the optional field trip held on Thursday, October 24, 2024.

Open-File Report↗

Geologic map of the Ganiki Planitia quadrangle (V-14), Venus

The Ganiki Planitia (V-14) quadrangle on Venus, which extends from 25&deg; N. to 50&deg; N. and from 180&deg; E. to 210&deg; E., derives its name from the extensive suite of plains that dominates the geology of the northern part of the region. With a surface area of nearly 6.5 x 10 6 km 2 (roughly two-thirds that of the United States), the quadrangle is located northwest of the Beta-Atla-Themis volcanic zone and southeast of the Atalanta Planitia lowlands, areas proposed to be the result of large scale mantle upwelling and downwelling, respectively. The region immediately south of Ganiki Planitia is dominated by Atla Regio, a major volcanic rise beneath which localized upwelling appears to be ongoing, whereas the area just to the north is dominated by the orderly system of north-trending deformation belts that characterize Vinmara Planitia. The Ganiki Planitia quadrangle thus lies at the intersection between several physiographic regions where extensive mantle flow-induced tectonic and volcanic processes are thought to have occurred. The geology of the V-14 quadrangle is characterized by a complex array of volcanic, tectonic, and impact-derived features. There are eleven impact craters with diameters from 4 to 64 km, as well as four diffuse 'splotch' features interpreted to be the product of near-surface bolide explosions. Tectonic activity has produced heavily deformed tesserae, belts of complex deformation and rifts as well as a distributed system of fractures and wrinkle ridges. Volcanic activity has produced extensive regional plains deposits, and in the northwest corner of the quadrangle these plains host the initial (or terminal) 700 km of the Baltis Vallis canali, an enigmatic volcanic feature with a net length of ~7,000 km that is the longest channel on Venus. Major volcanic centers in V-14 include eight large volcanoes and eight coronae; all but one of these sixteen features was noted during a previous global survey. The V-14 quadrangle contains an abundance of minor volcanic features including individual shield volcanoes and localized fissure eruptions as well as many small annular structures and domes, which often serve as the source for local lava flows. The topographic and geophysical characteristics of the Ganiki Planitia quadrangle are less complex than the surface geology, but they yield equally valuable information about the region&rsquo;s formation and evolution. Referenced to the mean planetary radius of 6051.84 km, the average elevation in the quadrangle is -0.26&plusmn;0.86 km (2&sigma;) with a full range of -2.58 km to 1.85 km. The highest 2.5 percent of elevations in the quadrangle (above 0.60 km) are associated primarily with the major tessera blocks and the peaks of a few volcanic edifices, whereas the lowest 2.5 percent (below -1.12 km) mostly occur within corona interiors and in the northwest corner of the quadrangle where the plains begin to merge into the Atalanta Planitia lowlands. At the ~4.6 km/pixel scale of the topography data, the mean point-to-point topographic slope is 0.63&deg; and topographic slopes greater than 2&deg; cover less than 5 percent of the region. Overall, the topography of the Ganiki Planitia quadrangle can be characterized as flat, low lying, and nearly devoid of abrupt topographic variation. Complementing this gentle topography, the geoid anomaly has a generally linear gradient that decreases north-northwest from a high of ~20 m at the southern edge of the quadrangle (the northern border of the Atla Regio anomaly) to a low of -30 to -40 m along the northern edge (Konopliv and others, 1999). The vertical component of the gravity anomaly varies from ~50 mGal to -40 mGal, and integrated analysis of the gravity and topography data indicates that dynamically supported regions and areas of thickened crust are both present within the quadrangle. Because the Ganiki Planitia quadrangle is a plains-dominated lowland area that lies between several major physiographic provinces (namely, Atla Regio, Atalanta Planitia, and Vinmara Planitia), a geologic map of the region may yield insight into a wide array of important problems in Venusian geology. The current mapping effort and analysis complements previous efforts to characterize aspects of the region&rsquo;s geology, for example stratigraphy near parabolic halo crater sites, volcanic plains emplacement, wrinkle ridges, volcanic feature distribution, volcano deformation, coronae characteristics, lithospheric flexure, and various features along a 30&plusmn;7.58&deg; N. geotraverse. Our current research focuses on addressing four specific questions. Has the dominant style of volcanic expression within the quadrangle varied in a systematic fashion over time? Does the tectonic deformation within the quadrangle record significant regional patterns that vary spatially or temporally, and if so what are the scales, orientations and sources of the stress fields driving this deformation? If mantle upwelling and downwelling have played a significant role in the formation of Atla Regio and Atalanta Planitia as has been proposed, does the geology of Ganiki Planitia record evidence of northwest-directed lateral mantle flow connecting the two sites? Finally, can integration of the tectonic and volcanic histories preserved within the quadrangle help constrain competing resurfacing models for Venus?

Scientific Investigations Map↗

Summary of the history and research of the U.S. Geological Survey gas hydrate properties laboratory in Menlo Park, California, active from 1993 to 2022

The U.S. Geological Survey (USGS) Clathrate Hydrate Properties Project, active from 1993 to 2022 in Menlo Park, California, stemmed from an earlier project on the properties of planetary ices supported by the National Aeronautics and Space Administration’s (NASA’s) Planetary Geology and Geophysics Program. We took a material science approach in both projects, emphasizing chemical purity of samples, having controlled grain size and grain texture, and having verified crystal structures and phase relations. A foundational contribution from our USGS Gas Hydrate Properties Laboratory (GHPL) was in demonstrating the ability to reproducibly create such pure clathrate hydrate samples for study. Clathrate sample synthesis was achieved by heating sieved and weighed pure granular water ice in the presence of cold clathrate-forming gas or liquid. During heating, the ice melts at the grain scale and reacts with the gas to form clathrate. The resulting material has the desired uniformity and purity, with known intergranular porosity; our subsequent measurements showed that these clathrates exhibited the established clathrate structures and phase relations. This novel synthesis method was successful in creating clathrates of pure methane, ethane, propane, carbon dioxide, and multi-component gases. By mixing sand or silt with granular ice, we were also able to make clathrate-sediment aggregates with controlled grain textures. This simple method, adopted by many others in the community, permitted us to measure the physical and chemical properties of well-characterized and well-crystallized clathrates and clathrate/sediment aggregates. At about the same time, we adapted conventional scanning electron microscopy to cryogenic conditions for analysis of grain-scale characteristics of clathrates made in the GHPL as well as those collected from nature by drill core. The uniformity and reproducibility of our samples also allowed us to investigate how clathrates respond to environmental changes in chemistry, temperature, and pressure: we measured chemical exchange rates with dissolved gas species—such as noble gases and chlorofluorocarbons—as well as rates of clathrate dissolution and decomposition. These advances include the first accurate mapping of the conditions that promote the remarkable process of “anomalous preservation” at room pressure, a metastability that offers potential application for low-cost and safe transportation of natural gas from gas fields far from pipelines. Another advancement stemming from the GHPL was the compaction of as-synthesized porous clathrates to nearly full density by applying external pressure using three different techniques. Compaction allows for high-accuracy measurements of many fundamental physical and chemical properties of these materials, such as elastic wavespeeds and moduli, complete thermal properties, decomposition rates, thermal expansion, and clathrate equations of state. These properties and others, in turn, have helped USGS scientists to interpret geophysical well logs and active geophysical surveys, as well as model the rates of gas production from hydrate deposits in nature. Studying this class of icy minerals that occur in abundance on Earth and in the outer solar system has been a fascinating laboratory journey. Here, we summarize the history and major findings of the USGS GHPL in Menlo Park, including both in-house research as well as findings from the synergistic collaborations with other agencies and institutes that were key to the success of our laboratory. The Menlo Park GHPL was more formally incorporated within the USGS Gas Hydrates Project, a collaboration among multiple USGS Science Centers, in the early 2000s under the leadership of Deborah Hutchinson, and now under the leadership of Carolyn Ruppel and Timothy Collett.

Open-File Report↗

Geologic map of the Agnesi quadrangle (V-45), Venus

The Agnesi quadrangle (V&ndash;45), named for centrally located Agnesi crater, encompasses approximately 6,500,000 km 2 extending from lat 25&deg; to 50&deg; S. and from long 30&deg; to 60&deg; E. The V&ndash;45 quadrangle lies within Venus&rsquo; lowland broadly between highlands Ovda Regio to the northeast and Alpha Regio to the west. The region ranges in altitude from 6,051 to 6,054 km, with an average of ~6,052 km, which is essentially mean planetary radius. The quadrangle displays a wide range of features including large to small arcuate exposures of ribbon-tessera terrain (Hansen and Willis, 1998), ten lowland coronae, two montes, 13 pristine impact craters, and long but localized volcanic flows sourced to the west in V&ndash;44. Shield terrain (Hansen, 2005) occurs across much of the V&ndash;45 quadrangle. Although V&ndash;45 lies topographically within the lowland, it includes only one planitia (Fonueha Planitia), perhaps because the features mentioned decorate it. Geologic mapping of the Agnesi quadrangle (V&ndash;45) provides an opportunity (1) to examine the nature of lowland ribbon-tessera terrain, as compared to highland ribbon-tessera terrain; (2) to examine the nature and history of lowland coronae and montes to evaluate hypotheses for the evolution of these features; and (3) to evaluate global catastrophic/episodic resurfacing hypotheses. Ribbon-tessera terrain (Hansen and Willis, 1998), a structurally distinctive terrain marked by roughly orthogonal fold axes and ribbon troughs, characterizes Venusian crustal plateaus (Hansen and others, 1999), although this distinctive fabric is also variably preserved across some lowland regions (Hansen and Willis, 1996, 1998), including the Agnesi quadrangle. Isolated kipukas of ribbon-tessera terrain protrude through the shield-terrain veneer and preserve evidence of local surface processes that predated shield-terrain emplacement, including those leading to regional development of tessera terrain fabrics. The ribbon-tessera fabrics are similar to the fabrics that characterize high-standing crustal plateaus, such as nearby Ovda and Alpha Regiones. Ribbon-bearing kipukas may preserve evidence of ancient collapsed crustal plateaus (Phillips and Hansen, 1994; Ivanov and Head, 1996; Hansen and Willis, 1998; Ghent and Tibuleac, 2002), or they may record different, but rheologically similar, processes. Geologic mapping of the V&ndash;45 quadrangle constrains the geologic history of 12 lowland coronae and montes. Lowland coronae are relatively rare (10% of coronae); they do not form chains, typical of mesoland coronae (Phillips and Hansen, 1994), nor do they cluster, typical of highland coronae associated with volcanic rises (Stofan and others, 2001). The evolution of all coronae, whether by a single mechanism or a range of mechanisms, is a topic of debate (for example, Stofan and others, 1992, 2001; Vita-Finzi and others, 2005; Hamilton, 2005). The V&ndash;45 quadrangle hosts about 20 percent of the lowland coronae on Venus; the geologic history of these features should provide critical insight toward understanding coronae evolution. Two general classes of hypotheses have emerged to address the near random spatial distribution of ~970 apparently pristine impact craters across the surface of Venus: (1) catastrophic/episodic resurfacing and (2) equilibrium/evolutionary resurfacing. Catastrophic/episodic hypotheses propose that a global-scale, temporally punctuated event or events dominated Venus&rsquo; evolution and that the generally uniform impact crater distribution (Schaber and others, 1992; Phillips and others, 1992; Herrick and others, 1997) reflects craters that accumulated during relative global quiescence since that event (for example, Strom and others, 1994; Herrick, 1994; Turcotte and others, 1999). Equilibrium/evolutionary hypotheses suggest instead that the near random crater distribution results from relatively continuous, but spatially localized, resurfacing in which volcanic and (or) tectonic processes occur across the planet through time, although the style of operative processes may have varied temporally and spatially (for example, Phillips and others, 1992; Guest and Stofan, 1999; Hansen and Young, 2007). Geologic relations within the map area allow us to test the catastrophic/episodic versus equilibrium/evolutionary resurfacing hypotheses.

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Geologic map of the Lakshmi Planum quadrangle (V-7), Venus

The Lakshmi Planum quadrangle is in the northern hemisphere of Venus and extends from lat 50 degrees to 75 degrees N., and from long 300 degrees to 360 degrees E. The elevated volcanic plateau of Lakshmi Planum, which represents a very specific and unique class of highlands on Venus, dominates the northern half of the quadrangle. The surface of the planum stands 3-4 km above mean planetary radius and the plateau is surrounded by the highest Venusian mountain ranges, 7-10 km high. Before the Magellan mission, the geology of the Lakshmi Planum quadrangle was known on the basis of topographic data acquired by the Pioneer-Venus and Venera-15/16 altimeter and radar images received by the Arecibo telescope and Venera-15/16 spacecraft. These data showed unique topographic and morphologic structures of the mountain belts, which have no counterparts elsewhere on Venus, and the interior volcanic plateau with two large and low volcanic centers and large blocks of tessera-like terrain. From the outside, Lakshmi Planum is outlined by a zone of complexly deformed terrains that occur on the regional outer slope of Lakshmi. Vast low-lying plains surround this zone. After acquisition of the Venera-15/16 data, two classes of hypotheses were formulated to explain the unique structure of Lakshmi Planum and its surrounding. The first proposed that the western portion of Ishtar Terra, dominated by Lakshmi Planum, was a site of large-scale upwelling while the alternative hypothesis considered this region as a site of large-scale downwelling and underthrusting. Early Magellan results showed important details of the general geology of this area displayed in the Venera-15/16 images. Swarms of extensional structures and massifs of tesserae populate the southern slope of Lakshmi. The zone of fractures and grabens form a giant arc thousands of kilometers long and hundreds of kilometers wide around the southern flank of Lakshmi Planum. From the north, the deformational zones consist mostly of contractional structures such as ridges. Corona and corona-like structures are not typical features of this zone but occur within separate branches of extensional structures oriented radial to the edge of Lakshmi. The southeastern edge of Lakshmi appears to be the source of large volcanic flows that extend to the south toward the lowland areas of Sedna Planitia. Colette and Sacajawea Paterae in the interior of Lakshmi are low volcanic centers with very deep central depressions. Lava flows sourced by Colette and Sacajawea form distinctive radial patterns around these volcanoes. Magellan gravity data show that the northern and northeastern portions of the quadrangle, which correspond to Lakshmi Planum, represent a significant geoid anomaly with the peak value of about 90 m over Maxwell Montes at the eastern edge of the map area. Maxwell is characterized also by very high vertical gravity acceleration values (as much as 268 mGal). The lowland of Sedna Planitia to the south of Lakshmi has mostly negative geoid values (down to -40 m). The key geological structure of the quadrangle is Lakshmi Planum, the mode of formation of which is still a major unresolved problem. The topographic configuration, gravity signature, and pattern of deformation inside Lakshmi and along its boundaries make this feature unique on Venus. Thus, geological mapping of this region allows addressing several important questions that should help to put some constraints on the existing models of Lakshmi formation. What is the sequence of events in the formation and evolution of such a unique morphologic and topographic feature? What are the characteristics of the marginal areas of Lakshmi: the compact mountain belts and broad zones of deformation in the transition zone between Lakshmi and surrounding lowlands? How do the units in Lakshmi Planum quadrangle compare with the units mapped in neighboring and distant regions of Venus and what information do they provide concerning models for Venus

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