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USGS2012

Deformation from 1973 to 1987 in the epicentral area of the 1959 Hebgen Lake, Montana, earthquake (Ms = 7.5)

A 40‐km aperture trilateration network centered on the 1959 Hebgen Lake earthquake epicenter has been surveyed in 1973, 1974, 1976, 1978, 1981, 1984, and 1987. The deformation inferred from those surveys is described roughly by a uniaxial, 0.266 ± 0.014 μstrain/yr, N15°E ± 1°extension that is uniform in both time and space. That extension is orthogonal to the strike (N78°W ± 5°) of the 1959 rupture plane inferred from focal mechanism solutions. The absence of strain accumulation in the N75°W direction suggests that the source of deformation must be greatly elongated in that direction. Looked at in greater detail, the deformation is found to be concentrated in the northern part of the network. The zone of concentrated deformation coincides with a part of a well‐defined trend in seismicity that extends at least 100 km N75°W from the Sour Creek resurgent dome in the Yellowstone caldera. Extension perpendicular to that trend is indicated by focal mechanism solutions. Thus, the zone of rifting identified within the Hebgen Lake network apparently extends east southeast to the Yellowstone caldera. About 8 mm/yr extension is observed across a 20‐km width within the zone.

Montana, Wyoming↗

USGS2007

An evaluation of the mobility of pathogen indicators, Escherichia coli and bacteriophage MS-2, in a highly weathered tropical soil under unsaturated conditions

Laboratory column experiments were conducted to study the effects of anionic polyacrylamide (PAM) polymer and surfactant linear alkylbenzene sulfonate (LAS) on the movement of Escherichia coli and the FRNA phage MS-2. The study was designed to evaluate if PAM or PAM + LAS would enhance the mobility of human pathogens in tropical soils under unsaturated conditions. No breakthrough of phage was observed in a 10 cm column after passing 100 pore volumes of solution containing 1 ?? 108 plaque-forming units (PFU)/ml. In later experiments, after passing 10-20 pore volumes of influent containing 1 ?? 108/ml MS-2 or E. coli through 15 cm columns, the soil was sliced and the organisms eluted. Phage moved slightly deeper in the polymer-treated column than in the control column. There was no measurable difference in the movement of E. coli in either polymer-treated or control columns. The properties of the soil (high amounts of metal oxides, kaolinitic clay), unsaturated flow conditions, and relatively high ionic strengths of the leaching solution attributed to significant retention of these indicators. The impacts of PAM and LAS on the mobility of E. coli or MS-2 phage in the chosen soils were not significant. ?? IWA Publishing 2008.

Journal of Water and Health↗

USGS2012

Rapid runoff via shallow throughflow and deeper preferential flow in a boreal catchment underlain by frozen silt (Alaska, USA)

In high-latitude catchments where permafrost is present, runoff dynamics are complicated by seasonal active-layer thaw, which may cause a change in the dominant flowpaths as water increasingly contacts mineral soils of low hydraulic conductivity. A 2-year study, conducted in an upland catchment in Alaska (USA) underlain by frozen, well-sorted eolian silt, examined changes in infiltration and runoff with thaw. It was hypothesized that rapid runoff would be maintained by flow through shallow soils during the early summer and deeper preferential flow later in the summer. Seasonal changes in soil moisture, infiltration, and runoff magnitude, location, and chemistry suggest that transport is rapid, even when soils are thawed to their maximum extent. Between June and September, a shift occurred in the location of runoff, consistent with subsurface preferential flow in steep and wet areas. Uranium isotopes suggest that late summer runoff erodes permafrost, indicating that substantial rapid flow may occur along the frozen boundary. Together, throughflow and deep preferential flow may limit upland boreal catchment water and solute storage, and subsequently biogeochemical cycling on seasonal to annual timescales. Deep preferential flow may be important for stream incision, network drainage development, and the release of ancient carbon to ecosystems

Alaska↗

USGS1981

A transient laboratory method for determining the hydraulic properties of 'tight' rocks-I. Theory

Transient pulse testing has been employed increasingly in the laboratory to measure the hydraulic properties of rock samples with low permeability. Several investigators have proposed a mathematical model in terms of an initial-boundary value problem to describe fluid flow in a transient pulse test. However, the solution of this problem has not been available. In analyzing data from the transient pulse test, previous investigators have either employed analytical solutions that are derived with the use of additional, restrictive assumptions, or have resorted to numerical methods. In Part I of this paper, a general, analytical solution for the transient pulse test is presented. This solution is graphically illustrated by plots of dimensionless variables for several cases of interest. The solution is shown to contain, as limiting cases, the more restrictive analytical solutions that the previous investigators have derived. A method of computing both the permeability and specific storage of the test sample from experimental data will be presented in Part II.

International Journal of Rock Mechanics and Mining↗

USGS2014

Post-earthquake relaxation using a spectral element method: 2.5-D case

The computation of quasi-static deformation for axisymmetric viscoelastic structures on a gravitating spherical earth is addressed using the spectral element method (SEM). A 2-D spectral element domain is defined with respect to spherical coordinates of radius and angular distance from a pole of symmetry, and 3-D viscoelastic structure is assumed to be azimuthally symmetric with respect to this pole. A point dislocation source that is periodic in azimuth is implemented with a truncated sequence of azimuthal order numbers. Viscoelasticity is limited to linear rheologies and is implemented with the correspondence principle in the Laplace transform domain. This leads to a series of decoupled 2-D problems which are solved with the SEM. Inverse Laplace transform of the independent 2-D solutions leads to the time-domain solution of the 3-D equations of quasi-static equilibrium imposed on a 2-D structure. The numerical procedure is verified through comparison with analytic solutions for finite faults embedded in a laterally homogeneous viscoelastic structure. This methodology is applicable to situations where the predominant structure varies in one horizontal direction, such as a structural contrast across (or parallel to) a long strike-slip fault.

Geophysical Journal International↗

USGS1999

XAFS measurements on zinc chloride aqueous solutions from ambient to supercritical conditions using the diamond anvil cell

The structure and bonding properties of metal complexes in subcritical and supercritical fluids are still largely unknown. Conventional high pressure and temperature cell designs impose considerable limitations on the pressure, temperature, and concentration of metal salts required for measurements on solutions under supercritical conditions. In this study, we demonstrate the first application of the diamond anvil cell, specially designed for x-ray absorption studies of first-row transition metal ions in supercritical fluids. Zn K-edge XAFS spectra were measured from aqueous solutions of 1-2 m ZnCl 2 and up to 6 m NaCl, at temperatures ranging from 25-660 °C and pressures up to 800 MPa. Our results indicate that the ZnCl 4 2- complex is predominant in the 1 m ZnCl 2 /6 m NaCl solution, while ZnCl 2 (H 2 O) 2 is similarly predominant in the 2 m ZnCl 2 solution, at all temperatures and pressures. The Zn-Cl bond length of both types of chlorozinc(II) complexes was found to decrease at a rate of about 0.01 Å/100 °C.

Journal of Synchrotron Radiation↗

USGS2014

Evaluation of the importance of clay confining units on groundwaterflow in alluvial basins using solute and isotope tracers: the case of Middle San Pedro Basin in southeastern Arizona (USA)

As groundwater becomes an increasingly important water resource worldwide, it is essential to understand how local geology affects groundwater quality, flowpaths and residence times. This study utilized multiple tracers to improve conceptual and numerical models of groundwater flow in the Middle San Pedro Basin in southeastern Arizona (USA) by determining recharge areas, compartmentalization of water sources, flowpaths and residence times. Ninety-five groundwater and surface-water samples were analyzed for major ion chemistry (water type and Ca/Sr ratios) and stable ( 18 O, 2 H, 13 C) and radiogenic ( 3 H, 14 C) isotopes, and resulting data were used in conjunction with hydrogeologic information (e.g. hydraulic head and hydrostratigraphy). Results show that recent recharge (<60 years) has occurred within mountain systems along the basin margins and in shallow floodplain aquifers adjacent to the San Pedro River. Groundwater in the lower basin fill aquifer (semi confined) was recharged at high elevation in the fractured bedrock and has been extensively modified by water-rock reactions (increasing F and Sr, decreasing 14 C) over long timescales (up to 35,000 years BP ). Distinct solute and isotope geochemistries between the lower and upper basin fill aquifers show the importance of a clay confining unit on groundwater flow in the basin, which minimizes vertical groundwater movement.

Arizona↗

USGS1998

Field and laboratory evidence for intrinsic biodegradation of vinyl chloride contamination in a Fe(III)-reducing aquifer

Intrinsic bioremediation of chlorinated ethenes in anaerobic aquifers previously has not been considered feasible, due, in large part, to 1) the production of vinyl chloride during microbial reductive dechlorination of higher chlorinated contaminants and 2) the apparent poor biodegradability of vinyl chloride under anaerobic conditions. In this study, a combination of field geochemical analyses and laboratory radiotracer ([1,2-14C] vinyl chloride) experiments was utilized to assess the potential for intrinsic biodegradation of vinyl chloride contamination in an Fe(III)-reducing, anaerobic aquifer. Microcosm experiments conducted under Fe(III)-reducing conditions with material from the Fe(III)-reducing, chlorinated-ethene contaminated aquifer demonstrated significant oxidation of [1,2-14C] vinyl chloride to 14CO2 with no detectable production of ethene or other reductive dehalogenation products. Rates of degradation derived from the microcosm experiments (0.9-1.3% d-1) were consistent with field-estimated rates (0.03-0.2% d-1) of apparent vinyl chloride degradation. Field estimates of apparent vinyl chloride biodegradation were calculated using two distinct approaches; 1) a solute dispersion model and 2) a mass balance assessment. These findings demonstrate that degradation under Fe(III) reducing conditions can be an environmentally significant mechanism for intrinsic bioremediation of vinyl chloride in anaerobic ground-water systems.

Journal of Contaminant Hydrology↗

USGS1975

Lithium in sediments and brines--how, why and where to search

The possibility of using lithium in batteries to power electric vehicles and as fuel for thermonuclear power has focused attention on the limited resources of lithium other than in pegmatite minerals. The Clayton Valley, Nev., subsurface lithium brine has been the major source of lithium carbonate since about 1967, but the life of this brine field is probably limited to several more decades at the present rate of production. Lithium is so highly soluble during weathering and in sedimentary environments that no lithium-rich sedimentary minerals other than clays have been identified to date. The known deposits of lithium, such as the clay mineral hectorite and the lithium-rich brines, occur in closed desert basins of the Southwest in association with nonmarine evaporites. However, the ultimate source for the lithium in these deposits may be from hydrothermal solutions. The search for previously unreported deposits of nonpegmatitic lithium should consider its probable association, not only with nonmarine evaporite minerals, but also with recent volcanic and tectonic activity, as well as with deposits of boron, beryllium, fluorine, manganese, and possibly phosphate.

Journal of Research of the U.S. Geological Survey↗

USGS2021

Stormwater systems as a source of marine debris: A case study from the Mediterranean coast of Israel

Drainage (or stormwater) systems are a potential source of marine debris. Approximately 67 km (33%) of the land along the Mediterranean coast of Israel is considered urban, covered by concrete and asphalt. The purpose of the present pilot study was to determine the composition of the solid waste in a drainage system and evaluate to what extent municipal sources contribute to marine debris. We sampled the waste in Netanya, a medium-size city (245,000 residents) on the central Mediterranean coast of Israel. Samples were taken from seven street stormwater receptacles prior to the first significant rain and then on the beach near a drainage outlet, a few hours after this substantial rain. In terms of composition of the debris, paper, cigarette butts, and sanitary items made up a higher proportion of the drainage system debris than those items did on the beach. In contrast, single-use items, polystyrene pieces, bottle caps, and plastic drinking bottles composed more of the debris on the beaches compared to the debris in the drainage system. Overall, we found that municipal stormwater systems contribute significant amounts of solid waste to marine debris on Israeli beaches. Preventing the waste from reaching the streets might help reduce marine debris on the beaches, especially at the beginning of the rainy season. There are multiple solutions, but all will require creativity and resources and constant maintenance. Educating the public to prevent disposal of solid waste items in the street is also important as a way to reduce terrestrial as well as marine debris.

Journal of Coastal Conservation↗

USGS1985

Salt-water-freshwater transient upconing - An implicit boundary-element solution

The boundary-element method is used to solve the set of partial differential equations describing the flow of salt water and fresh water separated by a sharp interface in the vertical plane. In order to improve the accuracy and stability of the numerical solution, a new implicit scheme was developed for calculating the motion of the interface. The performance of this scheme was tested by means of numerical simulation. The numerical results are compared to experimental results for a salt-water upconing under a drain problem.

Journal of Hydrology↗

USGS1987

Gravitational stresses in anisotropic rock masses

This paper presents closed-form solutions for the stress field induced by gravity in anisotropic rock masses. These rocks are assumed to be laterally restrained and are modelled as a homogeneous, orthotropic or transversely isotropic, linearly elastic material. The analysis, constrained by the thermodynamic requirement that strain energy be positive definite, gives the following important result: inclusion of anisotropy broadens the range of permissible values of gravity-induced horizontal stresses. In fact, for some ranges of anisotropic rock properties, it is thermodynamically admissible for gravity-induced horizontal stresses to exceed the vertical stress component; this is not possible for the classical isotropic solution. Specific examples are presented to explore the nature of the gravity-induced stress field in anisotropic rocks and its dependence on the type, degree and orientation of anisotropy with respect to the horizontal ground surface. ?? 1987.

International Journal of Rock Mechanics and Mining↗

USGS1992

Geochemical heterogeneity in a sand and gravel aquifer: Effect of sediment mineralogy and particle size on the sorption of chlorobenzenes

The effect of particle size, mineralogy and sediment organic carbon (SOC) on sorption of tetrachlorobenzene and pentachlorobenzene was evaluated using batch-isotherm experiments on sediment particle-size and mineralogical fractions from a sand and gravel aquifer, Cape Cod, Massachusetts. Concentration of SOC and sorption of chlorobenzenes increase with decreasing particle size. For a given particle size, the magnetic fraction has a higher SOC content and sorption capacity than the bulk or non-magnetic fractions. Sorption appears to be controlled by the magnetic minerals, which comprise only 5–25% of the bulk sediment. Although SOC content of the bulk sediment is <0.1%, the observed sorption of chlorobenzenes is consistent with a partition mechanism and is adequately predicted by models relating sorption to the octanol/water partition coefficient of the solute and SOC content. A conceptual model based on preferential association of dissolved organic matter with positively-charged mineral surfaces is proposed to describe micro-scale, intergranular variability in sorption properties of the aquifer sediments.

Journal of Contaminant Hydrology↗

USGS2020

A two-stage step-wise framework for fast optimization of well placement in coalbed methane reservoirs

Coalbed methane (CBM) has emerged as a clean energy resource in the global energy mix, especially in countries such as Australia, China, India and the USA. The economical and successful development of CBM requires a thorough evaluation and optimization of well placement prior to field-scale exploitation. This paper presents a two-stage, step-wise optimization framework to obtain the optimal placement of wells for large-scale development of CBM reservoirs. In the first stage, an optimal uniform well pattern is obtained by optimizing well pattern description parameters with the particle swarm optimization (PSO) algorithm. Subsequently, the location and status (active/inactive) of each well are perturbed and optimized within the patterns through the integration of the generalized pattern search (GPS) algorithm and a quality map (QM) representing the production potential. This framework was tested in a synthetic anthracite CBM reservoir in the Qinshui basin (with high gas content and low permeability) and a real field high volatile bituminous reservoir in the Illinois basin (with low gas content and high permeability). The results show that: (i) significant variations in the net present value (NPV) exist with respect to different uniform well patterns (even for cases where the total number of wells are identical), the optima of which can be efficiently determined by the PSO within 100 numerical simulation runs; (ii) the optimization of well perturbations by the GPS results in a more noticeable improvement in NPVs for the synthetic (12.3%) than for the real field model (4.6%); (iii) for the low permeable synthetic model with narrow optimal well spacings (320 m × 200 m), the contribution of the optimization of well perturbation to the NPV increment is heavily dependent on the uniform well placement solution; (iv) for the high permeable real field model with large optimal well spacings (1300 m × 1300 m), the initial uniform well placement has a very minor effect on the subsequent well perturbation solutions in terms of NPV; (v) the proposed framework significantly outperforms the conventional well-by-well concatenation procedure in terms of computational efficiency, robustness and optimal criteria set for production potential.

International Journal of Coal Geology↗

USGS2009

Examining the influence of heterogeneous porosity fields on conservative solute transport

It is widely recognized that groundwater flow and solute transport in natural media are largely controlled by heterogeneities. In the last three decades, many studies have examined the effects of heterogeneous hydraulic conductivity fields on flow and transport processes, but there has been much less attention to the influence of heterogeneous porosity fields. In this study, we use porosity and particle size measurements from boreholes at the Boise Hydrogeophysical Research Site (BHRS) to evaluate the importance of characterizing the spatial structure of porosity and grain size data for solute transport modeling. Then we develop synthetic hydraulic conductivity fields based on relatively simple measurements of porosity from borehole logs and grain size distributions from core samples to examine and compare the characteristics of tracer transport through these fields with and without inclusion of porosity heterogeneity. In particular, we develop horizontal 2D realizations based on data from one of the less heterogeneous units at the BHRS to examine effects where spatial variations in hydraulic parameters are not large. The results indicate that the distributions of porosity and the derived hydraulic conductivity in the study unit resemble fractal normal and lognormal fields respectively. We numerically simulate solute transport in stochastic fields and find that spatial variations in porosity have significant effects on the spread of an injected tracer plume including a significant delay in simulated tracer concentration histories.

Journal of Contaminant Hydrology↗

USGS2006

Ge/Si and 87Sr/86Sr tracers of weathering reactions and hydrologic pathways in a tropical granitoid system

Ge/Si and 87Sr/86Sr data from primary and secondary minerals, soil waters, and stream waters in a tropical granitoid catchment quantitatively reflect mineral alteration reactions that occur at different levels within the bedrock-saprolite-soil zone. Near the bedrock-saprolite interface, plagioclase to kaolinite reaction yields low Ge/Si and 87Sr/86Sr. Higher in the regolith column, biotite weathering and kaolinite dissolution drive Ge/Si and 87Sr/86Sr to high values. Data from streams at base flow sample the bedrock-saprolite interface zone, while at high discharge solutes are derived from upper saprolite-soil zone. Coupled Ge/Si and 87Sr/86Sr can be effective tools for quantifying the importance of specific weathering reactions, and for geochemical hydrograph separation. ?? 2005 Elsevier B.V. All rights reserved.

Journal of Geochemical Exploration↗

USGS2020

Sources, fate, and flux of riverine solutes in the Southwest Yellowstone Plateau Volcanic Field, USA

Since the 1970s, temporal variations of hydrothermal discharge and thermal output from the numerous hydrothermal features in the Yellowstone Plateau Volcanic Field (YPVF) have been studied by measuring the chloride flux in the major rivers. In this study, the sources, fate, and flux of solutes in the Fall River and its major tributaries, in southwest Yellowstone National Park, were determined. The considerable precipitation in southwest YPVF and high groundwater flow through Quaternary rhyolites results in river solute fluxes that originate from shallow non-thermal groundwater and deep-thermal water. Specific conductance serves as a surrogate measure for thirteen riverine solute concentrations. Combining continuous 15-minute specific conductance and discharge data, the annual chloride, arsenic, fluoride, and silica fluxes from the Fall River were determined to be 11%, 5%, 25%, and 19% of the total flux exiting YPVF. Approximately 11% of the Fall River chloride flux is from non-thermal waters, which is larger than the previous estimate of 4 to 6%. Furthermore, a large proportion of fluoride and silica in the Fall River are derived from water-rock interaction in the shallow non-thermal groundwater system and the non-thermal weathering rate (30 ± 2 t/yr·km 2 ) is higher than other rivers draining the Yellowstone caldera. Consequently, 73 ± 3% of the annual total dissolved solid flux in the Fall River is from thermal sources. Synoptic sampling of river water and discharge measurements was performed during low-flow conditions that allowed for the determination of solute sources and their downstream fate. It was determined that chloride, sodium, arsenic, rubidium, lithium, and boron are primarily (>89%) associated with thermal waters and the Bechler River is the primary source of most hydrothermal solutes in the Fall River, but the major source of arsenic is Boundary Creek. Using the chloride inventory method, the thermal water discharge from several thermal areas was also determined.

Wyoming↗

USGS1993

The erosion of carbonate stone by acid rain: Laboratory and field investigations

One of the goals of research on the effects of acidic deposition on carbonate stone surfaces is to define the incremental impact of acidic deposition relative to natural weathering processes on the rate of carbonate stone erosion. If rain that impacts carbonate stone surfaces is resident on the surface long enough to approach chemical equilibrium, the incremental effect of hydrogen ion is expected to be small (i.e., 6% for a rain of pH 4.0). Under nonequilibrium (i.e., high flow rate) conditions, kinetic considerations suggest that the incremental effect of hydrogen ion deposition could be quite significant. Field run-off experiments involving the chemical analysis of rain collected from inclined stone slabs have been used to evaluate stone dissolution processes under ambient conditions of wet and dry deposition of acidic species. The stoichiometry of the reaction of stone with hydrogen ion is difficult to define from the field data due to scatter in the data attributed to hydrodynamic effects. Laboratory run-off experiments show that the stoichiometry is best defined by a reaction with H+ in which CO2 is released from the system. The baseline effect caused by water in equilibrium with atmospheric CO2 is identical in the field and in laboratory simulation. The experiments show that the solutions are close enough to equilibrium for the incremental effect of hydrogen ion to be minor (i.e., 24% for marble for a rain of pH 4.0) relative to dissolution due to water and carbonic acid reactions. Stone erosion rates based on physical measurement are approximately double the recession rates that are due to dissolution (estimated from the observed calcium content of the run-off solutions). The difference may reflect the loss of granular material not included in recession estimates based on the run-off data. Neither the field nor the laboratory run-off experiments indicate a pH dependence for the grain-removal process.

Journal of Chemical Education↗