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At least 181 records · Page 10Linked to original sources

Chapter 5: Petrology and geochemistry of the metaluminous to peraluminous Chemehuevi Mountains Plutonic Suite, southeastern California

Structural relief resulting from middle Tertiary extensional deformation in the Chemehuevi Mountains exposes a unique cross section through a temporally and compositionally zoned (both vertically and horizontally), laccolith-shaped intrusion of Late Cretaceous age. The calc-alkalic, metaluminous to peraluminous Chemehuevi Mountains Plutonic Suite exhibits crude normal, vertical, and temporal zonation. The zones are progressively younger and more felsic away from the roof and walls; the most differentiated material is concentrated toward the center and floor of the intrusion. Hornblende-biotite- and biotite granodiorite are metaluminous and form the outer margin of the intrusion along the northern and southern walls, and sill-like bodies in an older suite of granitoids and Proterozoic basement rocks. Locally these rocks bear a sub-horizontal, southwest-trending, mylonitic lineation, considered to be synchronous with regional mylonitic deformation. Later and more evolved units are subequigranular to porphyritic, metaluminous to weakly peraluminous biotite granodiorite to granite, and make up the greatest proportion of the intrusion. The youngest, most leucocratic members of the suite are undeformed, locally garnetiferous muscovite granite and granodiorite that form the central part of the intrusion. Major, trace, and rare earth element data indicate that the magmas of the Cheme-huevi Mountains Plutonic Suite became progressively enriched in Si, K, Rb, Mn, Y, U, and heavy rare earth elements (REE). Fractional crystallization of some REE–rich accessory minerals was important in producing some of these trends. Although modest compositional breaks occur across internal contacts, the general continuity of trends from field, modal, and chemical data suggests that these rocks constitute a comagmatic intrusive suite. Estimates for the pressure of emplacement of the suite vary from 4 to 6 kbar, or a minimum depth of 12 km. Preliminary Pb-, Sr-, and oxygen-isotopic data, together with the REE chemistry, suggest that the Chemehuevi Mountains Plutonic Suite was derived from a heterogeneous crustal source. Compositional variations within the plutonic suite are consistent with open-system fractionation, involving fractional crystallization of discrete batches of magma derived from the melting of a heterogeneous crustal source under H 2 O-saturated conditions.

California↗

Sulphide petrology and ore genesis of the stratabound Sheep Creek sediment-hosted Zn–Pb–Ag–Sn prospect, and U–Pb zircon constraints on the timing of magmatism in the northern Alaska Range

The Sheep Creek prospect is a stratabound Zn–Pb–Ag–Sn massive sulfide occurrence in the Bonnifield mining district, northern Alaska Range. The prospect is within a quartz–sericite–graphite–chlorite schist unit associated with Devonian carbonaceous and siliceous metasedimentary rocks. Volcanogenic massive sulfide (VMS) deposits in the district are hosted in felsic metavolcanic rocks (362 ± 2 Ma) associated with siliciclastic and carbonaceous sedimentary rocks that overlie the stratigraphic sequence hosting the Sheep Creek prospect. Felsic metaigneous rocks in underlying units are 372 ± 4 to 366 ± 4 Ma. Sheep Creek is atypical of the other sulfide deposits in the district in (1) having Sn grades up to 1.2%; (2) being contained in fine-grained, quartz-rich rocks and quartz–pebble conglomerate that likely originated as chert and chert-clast sediment, respectively; and (3) showing minimal evidence of volcanic components in the host rocks. Comparison of immobile trace-element proportions for graphitic and siliceous rocks from the Sheep Creek area with those for argillite associated with the Bonnifield VMS deposits indicates a continental volcanic-arc provenance for the former and a within-plate and passive margin provenance for the latter. In contrast to previously published interpretations, our data analysis supports a clastic-dominated (CD) rather than a VMS affinity for the Sheep Creek prospect. In our model, Zn–Pb–Ag–Sn mineralization formed by syngenetic or early diagenetic processes on or beneath the seafloor, possibly in the shallow-water environment of an outer continental shelf setting. Potential analogues are the Paleozoic CD deposits in the Canadian Selwyn Basin outboard of the Laurentian continental margin.

Alaska↗

Petrology, composition, and age of intrusive rocks associated with the Quartz Hill molybdenite deposit, southeastern Alaska

A large porphyry molybdenum deposit (Quartz Hill deposit) was recently discovered in the heart of the Coast Range batholithic complex about 70 km east of Ketchikan, southeastern Alaska. Intrusive rocks associated with the mineral deposit form two composite epizonal to hypabyssal stocks and many dikes in country rocks. The stocks are characterized by a variety of textural rock types varying from equigranular or weakly seriate biotite granite to porphyries with aphanitic or very fine grained and aplitic groundmasses. These rocks contain about equal amounts of quartz, albitic plagioclase, and microperthitic microcline and less than 2.5% biotite. Unaltered rocks contain between 0.2 and 1% CaO, less than 1.7% combined Fe 2 O 3 , FeO, and MgO, and 74.4 to 77.7% SiO 2 . Total alkalis are between 8 and 9%, and K 2 O/Na 2 O is about 1.1. The range of major-oxide variation is small, but it is systematically related to lithology. Many trace-elements, including B, Pb, Sn, and Li have low concentrations. Intrusive rocks associated with the Quartz Hill deposit are more albitic and possibly trace-element depleted compared to some other rocks associated with porphyry molybdenum deposits.All observed metallization and alteration is within the Quartz Hill stock. Molybdenite forms fracture coatings and occurs in veins with quartz. Alteration is widespread and includes development of secondary quartz, pyrite, K-feldspar, biotite, white mica, chlorite, and zeolite. Field relations indicate that the stocks were emplaced after regional uplift and erosion of the Coast Range batholithic complex, and K–Ar data show that intrusion and alteration took place in late Oligocene time, about 27 to 30 Ma ago. Data from the Ketchikan quadrangle indicate that porphyry molybdenum metallization in the Coast Range batholithic complex is associated with regionally extensive but spotty, middle Tertiary or younger, felsic magmatism.

Alaska↗

Petrology and age of volcanic-arc rocks from the continental margin of the Bering Sea: Implications for Early Eocene relocation of plate boundaries

Eocene volcanic flow and dike rocks from the Beringian margin have arc characteristics, implying a convergent history for this region during the early Tertiary. The extrusive rocks are basalt, basaltic andesite, andesite, and minor dacite and rhyolite. The intrusive sample is from a quartz diorite dike intruding serpentinized peridotite. Major-element oxide contents, particularly FeO*/MgO versus SiO 2 , identify both tholeiitic and calc-alkalic basalt; more silicic lavas have calc-alkalic affinities. Consistent with volcanic-arc compositions, spidergrams show pronounced Nb–Ta depletion and alkali enrichment relative to light-rare-earth-element ( LREE ) abundance. Chondrite-normalized REE plots show relatively flat patterns, with only slight LREE enrichment for tholeiitic compositions and greater LREE enrichment and lower heavy-rare-earth-element ( HREE ) abundance for calc-alkalic compositions. The samples, particularly those with calc-alkalic compositions, are rich in plagioclase that is strongly zoned; the more silicic samples contain orthopyroxene, clinopyroxene, and primary amphibole. The quartz diorite dike contains iron-rich almandine phenocrysts that appear to be magmatic, suggesting emplacement at great depth near the base of the crust or upper mantle.Chemical and mineralogical compositions are similar to those of modern Aleutian-arc lavas. They also resemble volcanic-arc compositions from western mainland Alaska, although greater chemical diversity and a stronger continental influence are observed in the Alaskan mainland rocks.Early Eocene ages of 54.4–50.2 Ma for the Beringian samples are well constrained by conventional K–Ar ages of nine plagioclase separates and by concordant 40 Ar/ 39 Ar incremental heating and total-fusion experiments. A concordant U–Pb zircon age of 53 Ma for the quartz-diorite dike is in good agreement with the K–Ar data.Plate motion studies of the North Pacific Ocean indicate more northerly directed subduction prior to the Tertiary and a continuous belt of arc-type volcanism extending from Siberia, along the Beringian margin, into mainland Alaska. Around 56 Ma (chron 25–24), subduction changed to a more westerly direction and subduction-related volcanism ceased for most of mainland Alaska. The increasingly oblique angle of convergence should have ended subduction along the Beringian margin as well. However, consistent ages of 54–50 Ma indicate a final pulse in arc-type magmatism during this period of plate adjustment, which may be explained by three different models: (1) The northern and central part of the Beringian margin maintained a higher angle of convergence, allowing a final pulse of arc-type magmatism. (2) The rocks erupted in an early, or proto, Aleutian arc and were rafted against the continental margin along transform faults. (3) The rocks erupted along a leaky transform fault, analogous to calc-alkalic volcanism in the southern California borderland.

Alaska↗

Petrology and isotopic composition of Quaternary basanites dredged from the Bering Sea continental margin near Navarin Basin

Quaternary basanites were recovered from shallow water depth from the continental margin of the Bering Sea (58°39.0′N, 177°12.9′W) near Navarin Basin. The basanites are highly vesicular flow rock and hyaloclastites similar to other alkalic volcanic rocks erupted repeatedly during the late Cenozoic on islands in the Bering Sea region and in mainland Alaska. K–Ar ages for the basanites indicate at least two episodes of volcanism at about 1.1 and 0.4 Ma. Similar alkalic volcanism occurred sporadically at geographically widely separated centers in the Bering Sea region for at least the past 6 Ma. Chemically, these alkalic lavas are intraplate basalts similar to those erupted from oceanic islands and in some continental settings. Trace-element data indicate these alkalic lavas have been generated by small, but variable, amounts of partial melting of a meta-somatized lherzolite source. The relatively primitive compositions (MgO > 9%), presence of mantle-derived xenoliths in some alkalic lavas, and presence of forsteritic olivine with low CaO and high NiO suggest that magma rose rapidly from greath depth without spending time in large, long-lived magma chambers. Although lavas from different volcanic centers in the Bering Sea region are similar with respect to major elements and many trace-element ratios, isotopic compositions indicate heterogeneities in the source. The Navarin basanites have higher 87 Sr/ 86 Sr and lower 143 Nd/ 144 Nd values than any other lavas so far reported from this region. The 207 Pb/ 204 Pb isotopic ratios indicate involvement of a crustal component, which may have resulted from metasomatism associated with subduction-related magmatic activity during the Early Eocene in this region. Although some volcanic episodes appear to have occurred roughly synchronously at geographically widely separated centers, no large-scale regional extension nor presence of large mantle plumes are indicated. Instead, alkalic volcanism apparently resulted from upwelling and decompressional melting of small isolated mantle diapirs in response to local lithospheric attenuation associated with jostling of blocks during adjustment to regional stresses.

Alaska↗

Chapter 4: Compositional zoning and petrology of the Thera pyroclastics

Compositional zoning is a common feature of pyroclastic deposits erupted from calderas worldwide (Smith 1979; Hildreth 1981; Bacon & Druitt 1988; De Silva 1991; Feeley & Davidson 1994). Compositionally zoned tuffs provide a geologically instantaneous snapshot of the vertical stratigraphy and density stratification in the chamber immediately before eruption. Magma bodies are commonly zoned in density, with light, relatively cool, silicic magma overlying hotter, more mafic magma. Vertical zonation can arise by a number of processes, including crystallization and convective fractionation on the chamber.

Santorini↗

Organic geochemistry and petrology of Devonian shale in eastern Ohio: Implications for petroleum systems assessment

Recent production of light sweet oil has prompted reevaluation of Devonian petroleum systems in the central Appalachian Basin. Upper Devonian Ohio Shale (lower Huron Member) and Middle Devonian Marcellus Shale organic-rich source rocks from eastern Ohio and nearby areas were examined using organic petrography and geochemical analysis of solvent extracts to test ideas related to organic matter sources, oil–source rock correlation, thermal maturity, and distances of petroleum migration. The data from these analyses indicate organic matter in the Ohio and Marcellus Shales primarily was derived from marine algae and its degradation products, including bacterial biomass. Absence of odd-over-even n - alkane distributions (n - C 13 to n - C 21 range) in gas chromatograms and low gammacerane index values in Devonian source rocks are similar to those of Devonian-reservoired oils in eastern Ohio, suggesting an oil–source rock correlation. Lower Paleozoic oils from eastern Ohio, in contrast, are characterized by the presence of odd-over-even n - alkane distributions (n - C 13 to n - C 21 range) and higher gammacerane values, which discriminate them from Devonian shale-derived oils. Thermal maturity estimates from equilibrium(?) biomarker isomerization ratios suggest that some of the Devonian source rock samples are at middle to peak oil window conditions (i.e., approximate vitrinite reflectance values of 0.8%–0.9%). This observation requires local to short-distance (<50 mi) lateral migration for emplacement of Devonian-sourced oils into Devonian reservoirs of eastern Ohio and may impact exploration and assessment of petroleum resources in the Upper Devonian Berea Sandstone.

Ohio↗

Organic petrology and geochemistry of the Sunbury and Ohio Shales in eastern Kentucky and southeastern Ohio

As part of a study to determine the origin of oil and gas in the Berea Sandstone in northeastern Kentucky and southeastern Ohio, 158 samples of organic-rich shale from the Upper Devonian Olentangy and Ohio Shales and the Lower Mississippian Sunbury Shale, collectively referred to as the “black shale,” were collected and analyzed from 12 cores. The samples were analyzed for total organic carbon ( TOC ) content, organic petrography, and programmed pyrolysis. Previously acquired analytical data for 11 samples from 2 additional wells in eastern Kentucky were also used. Most of the samples were organic rich (>5 wt. % TOC ), high in sulfur (>2.0 wt. %), and dominated by liptinite macerals. The vitrinite reflectance ( VR o ) and equivalent vitrinite reflectance ( VR eq ) values, calculated from bitumen reflectance ( BR o ) measurements, were found to be in close agreement. The calculated reflectance values from programmed pyrolysis temperature at which the maximum release of hydrocarbons occurs ( T max ) showed better agreement with measured VR o after T max was corrected for excessive hydrogen index values for several samples. Thermal maturation parameters were found to increase in a northwest–southeast direction, paralleling an increase in black shale thickness and depth of burial. The thermal maturity proxies indicate the northwestern part of the study area to be more thermally mature than previously indicated. Geochemical and biomarker data from Berea oils indicate migration of oil from more thermally mature to less thermally mature areas. As such, the occurrence of petroleum liquids in the Berea Sandstone cannot be predicted directly from conventional thermal maturity proxies ( T max , VR o , and BR o ) because these methods do not account for migrated petroleum.

Ohio, Kentucky↗

Petrology and reservoir quality of the Gaikema Sandstone: Initial impressions

The Division of Geological & Geophysical Surveys (DGGS) and Division of Oil & Gas (DOG) are currently conducting a study of the hydrocarbon potential of Cook Inlet basin (LePain and others, 2011). The Tertiary stratigraphic section of the basin includes coal-bearing units that are prolific gas reservoirs, particularly the Neogene sandstones. The Paleogene sandstones are locally prolific oil reservoirs that are sourced largely from the underlying Middle Jurassic Tuxedni Group. Several large structures act as hydrocarbon traps and the possibility exists for stratigraphic traps although this potential has not been fully exploited. As part of this study a significant number of Tertiary sandstones from the basin have been already collected and analyzed (Helmold and others, 2013). Recent field programs have shifted attention to the Mesozoic stratigraphic section to ascertain whether it contains potential hydrocarbon reservoirs. During the 2013 Cook Inlet field season, two days were spent on the Iniskin Peninsula examining outcrops of the Middle Jurassic Gaikema Sandstone along the south shore of Chinitna Bay (fig. 7-1). A stratigraphic section approximately 34 m in thickness was measured and a detailed description was initiated (Stanley and others, 2015), but due to deteriorating weather it was not possible to complete the description. During the 2014 field season two additional days were spent completing work on the Gaikema section. Analyses of thin sections from six of the samples collected in 2013 are available for incorporation in this report (table 7-1). Data from samples collected during the 2014 field season will be included in future reports.

Alaska↗

Regional geologic and petrologic framework for iron oxide ± apatite ± rare earth element and iron oxide copper-gold deposits of the Mesoproterozoic St. Francois Mountains terrane, southeast Missouri, USA

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.

Missouri↗

Geologic setting, petrology, and geochemistry of zoned tungsten-bearing skarns at the Strawberry Mine, central Sierra Nevada, California

The Strawberry mine, 90 km northeast of Fresno, California, occurs on the margin of a small roof pendant of Early Jurassic metasedimentary rocks and middle Cretaceous metaigneous rocks. Middle Cretaceous granitic intrusions surround and intrude the roof pendant. Adjacent to one granodiorite intrusion, several subvertical marble layers are replaced by scheelite-bearing skarns. The skarns form spears that project as much as 300 m upward and into the marble layers. Between the marble and granodiorite, the skarns comprise a metasomatic column and are subdivided into four zones: (1) wollastonite skarn, adjacent to and replacing marble, and containing wollastonite, grossularite, idocrase, and diopside; (2) garnet skarn, containing andradite-grossularite, diopside-hedenbergite, and scheelite; (3) pyroxene skarn containing hedenbergite-diopside, plagioclase, magnetite, and scheelite; and (4) hornblende skarn, adjacent to granodiorite, and containing hornblende, plagioclase, microcline, magnetite, and scheelite. Important features of the skarn zonation are: sharp contacts between skarn zones; relative constancy of whole-rock, mineral, and modal compositions within each skarn zone; major changes in whole-rock, mineral, and modal compositions across contacts between skarn zones; and systematic replacement between skarn zones, with any given skarn zone replaced by the next lower and adjacent skarn zone toward the granodiorite. Volume remained approximately constant in the replacement of marble by various skarn zones. Marble and skarn exhibit uniformly low porosity. Data on mineral paragenesis and mineral composition indicate that in the replacement of any skarn the most calcic mineral is consumed and the residual calc-silicate minerals in the replacing skarn increase in abundance and are richer in total Fe and MnO. This mineral paragenesis can be related to systematic variations in whole-rock composition. From the marble to the granodiorite, skarns are progressively depleted in CaO and CO 2 , and progressively enriched in SiO 2 , total Fe, MgO, MnO, Al 2 O 3 , Na 2 O, K 2 O, and WO 3 . The skarns probably formed when an aqueous fluid containing a solute fraction relatively depleted in Ca and CO 2 , and relatively enriched in Si, Fe, Mg, Mn, Al, Na, K, and W, was expelled from a granitic magma into country rock. The tendency toward local equilibrium between fluid and marble resulted in formation of skarns with systematic stepwise changes in mineral and rock composition at contacts between skarns. Achievement of local equilibrium occurred mainly by infiltration metasomatism with a possible minor component of diffusion metasomatism.

California↗

Geologic setting, petrology, and geochemistry of stratiform sphalerite-galena-barite deposits, Red Dog Creek and Drenchwater Creek areas, northwestern Brooks Range, Alaska

Similar stratiform sphalerite-galena-barite deposits occur in the Red Dog Creek area, De Long Mountains quadrangle, and in the Drenchwater Creek area, Howard Pass quadrangle, northwestern Brooks Range, Alaska. The deposits, located approximately 180 km apart, are hosted by Mississippian and Pennsylvanian strata of the Kagvik structural sequence of late Paleozoic and early Mesozoic age. This sequence is situated in the lowermost structural plate of a series of predominantly east-striking, shallow-dipping thrust plates that characterize the regional structure. The deposits occur in shale, tuff, tuffaceous sandstone, altered chert, and quartz exhalite. These units are in places interlayered with or adjacent to bedded or nodular barite or submarine keratophyre flows. Chert and shale commonly contain abundant highly altered, fine-grained feldspar, pumice lapilli, and mafic volcanic rock fragments.The main types of occurrences at Red Dog Creek are: (1) disseminated and stratiform sulfides thinly bedded in organic-rich Mississippian and Pennsylvanian shale and chert, (2) massive sulfide veins and breccia fillings in silicified Mississippian and Pennsylvanian shale, and (3) stratiform sulfide-bearing lenses subdivided into (3a) quartz-exhalite with up to several percent sulfides and barite, (3b) massive sulfide-quartz lenses with up to several percent barite, and (3c) barite-quartz lenses with up to several percent sulfides.At Drenchwater Creek sulfides and barite occur as: (1) disseminations in shale, chert, tuff, and tuffaceous sandstone; (2) disseminations to aggregates in quartz exhalite; and (3) occurrences in veins crosscutting cleavages in brecciated chert and shale.The stratiform sulfides occur in zones up to several thousand meters long and several tens of meters thick. Preliminary grades at Red Dog Creek are 17.1 percent zinc, 5.0 percent lead, and 2.4 oz silver per ton contained in at least 85 million tons.The range of sulfide sulfur isotope values at Red Dog Creek is -16.6 per mil to +3.6 per mil. Sphalerite averages 0.8 per mil. Pyrite is isotopically lighter than coexisting sphalerite in quartz exhalite and massive sulfide lenses. This isotopic relationship is compatible with paragenetic relationships which show pyrite crystallized both earlier and later than other sulfides. Galena is isotopically lighter than coexisting sphalerite. Three groups of geologically and isotopically distinct barites exist including isotopic values appropriate for derivation from late Paleozoic seawater sulfate.Early in the depositional sequence isotopically light pyrite formed from organically reduced seawater sulfate. Sphalerite, galena, late pyrite, and some barite precipitated from two sulfur-bearing solutions that mixed at the mineralization site. Isotopically light barite associated with sulfides precipitated from oxidized H 2 S without seawater sulfate contribution. Lead isotope data from Red Dog and Drenchwater Creeks are compatible with generation of lead in a Phanerozoic mature island-arc setting, a typical orogene, or possibly a back-arc type intracratonic basin.The stratiform sphalerite-galena-barite deposits probably formed in an incipient island-arc environment near a continental margin, containing magmas of keratophyric and andesitic composition, where metal-laden hydrothermal fluids discharged into a deep (?) water, low-energy environment. Later intense deformation, associated with plate docking and thrusting, disrupted and partly remobilized and stratiform deposits.

Alaska↗

Geochemistry, petrologic evolution, and ore deposits of the Miocene Bodie Hills Volcanic Field, California and Nevada

The southern segment of the ancestral Cascades magmatic arc includes numerous volcanic fields; among these, the Bodie Hills volcanic field (BHVF), astride the California-Nevada border north of Mono Lake, is one of the largest (>700 km2) and most well studied. Episodic magmatism in the BHVF spanned about 9 million years between about 15 and 6 Ma; magmatic output was greatest between ca. 15.0 to 12.6 Ma and ca. 9.9 to 8.0 Ma. About two dozen contiguous and coalescing eruptive centers above middle- to shallow-crustal-level reservoirs generated several trachyandesite stratovolcanoes and numerous silicic trachyandesite to rhyolite flow dome complexes whose compositional variations are consistent with fractionation of observed phenocryst phases. BHVF rocks have high-potassium calc-alkaline compositions consistent with generation of subduction-related continental margin arc magmas beneath thick continental crust. Radiogenic isotope ratios in BHVF rocks vary considerably but suggest somewhat enriched, crustal sources; isotopic ratios for some of the more primitive units are consistent with more depleted, mantle sources. Neither age nor whole-rock compositions of BHVF rocks are well correlated with isotopic variations. Textures and compositions of phenocrysts in BHVF rocks are in accord with the associated magma reservoirs evolving via open-system behavior. Reservoir recharge and subsequent incomplete homogenization are evidenced by the broad compositional diversity characteristic of many BHVF eruptive units. Significant compositional diversity among the products of coeval eruptive centers further suggests that centers responsible for BHVF magmatism were underlain by small, discrete, compositionally distinct, and closely spaced reservoirs. Volcanic rocks of the BHVF host quartz-adularia and quartz-alunite epithermal gold-silver deposits, from which about 3.4 Moz. of gold and 28 Moz. of silver have been produced. The volcanic rocks and contained deposits are broadly coeval, which suggests that the associated magmas are the sources of heat, fluids, and metals involved in deposit genesis. Characteristics of the quartz-adularia deposits are consistent with derivation from near-neutral pH fluids at ≤250 °C, whereas those of the quartz-alunite systems require more acidic, oxidized, and sulfur-rich fluids at temperatures <250 °C. Economically viable precious metal accumulations are in fault-hosted vein deposits in the Bodie and Aurora districts. Circulation of hydrothermal fluids through permeable pyroclastic deposits but lacking prominent structural conduits resulted in large areas of altered but unmineralized rock.

California, Nevada↗

Petrologic characteristics of the 1982 and pre-1982 eruptive products of El Chichon volcano, Chiapas, Mexico

Studies on a suite of rocks from this volcano indicate that the juvenile materials of the 1982 and pre-1982 eruptions of the volcano have essentially the same mineralogy and chemistry. Data suggest that chemical composition changed little over the 0.3 m.y. sample period. Modally, plagioclase is the dominant phenocryst, followed by amphibole, clinopyroxene and minor phases including anhydrite. Plagioclase phenocrysts show complex zoning: the anorthite-rich zones are probably the result of changing volatile P on the magma and may reflect the changes in the volcano's magma reservoir in response to repetitive, explosive eruptive activity.-R.E.S.

Chiapas↗

Petrology and U-PB geochronology of the Robertson River Igneous Suite, Blue Ridge province, Virginia - Evidence for multistage magmatism associated witn an early episode of Laurentian rifting

The Late Neoproterozoic (735-702 Ma) Robertson River Igneous Suite includes at least eight plutons ranging in composition from syenogranite to alkali feldspar granite to alkali feldspar syenite. These plutons intruded Mesoproterozoic (1.2-1.0 Ga) gneissic basement of the Blue Ridge anticlinorium in northern and central Virginia during an early episode of Laurentian rifting. Robertson River plutons range in composition from metaluminous to peralkaline and, relative to other granite types, exhibit compositional characteristics of A-type granitoids including (1) marked enrichment in Nb, Zr, Y, REE (except Eu), and Ga, (2) high Ga/Al and FeO (total) /MgO, and (3) depletion of Ba and Sr. High Ga/Al ratios are particularly diagnostic of the suite and serve as an effective discriminant between originally metaluminous and peralkaline bulk compositions, providing a useful proxy for widely used indicators based on major elements that are prone to remobilization. U-Pb isotopic analyses of zircons indicate that the suite was emplaced in two pulses, occurring at 735 to 722 and 706 to 702 Ma. Metaluminous magmas were emplaced during both pulses, formed most of the main batholith, and fractionated as independent, time-correlative groups. Peralkaline magmas were emplaced only during the final pulse, formed a volcanic center that erupted unknown quantities of rhyolite, and experienced a style of fractionation similar to the metaluminous types. Differences in Ce/Nb, Y/Nb, and Yb/Ta ratios suggest that the metaluminous and peralkaline magmas were derived from different sources. The Robertson River Igneous Suite is part of a regional group of Late Neoproterozoic (760-700 Ma) plutons including at least 20 other A-type granitoid bodies exposed throughout the Laurentian terrane of Virginia and northwestern North Carolina. Like the Robertson River, most of the other granitoids are metaluminous in composition, typically form multi-intrusive, elongate plutons, and are not geographically constrained to the vicinity of major Neoproterozoic volcanic centers. The Late Neoproterozoic plutons of the Laurentian Appalachians are similar in lithology, composition, and style of emplacement to Miocene granitoids that occur on the southern flanks of the present Red Sea rift and that are considered a younger analog of the Appalachian plutons. However, the Red Sea granitoids were emplaced within a few million years of the initial development of oceanic crust whereas the Appalachian plutons appear largely to have pre-dated development of the Iapetus Ocean by about 130 my.

Virginia↗