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USGS2019

Three-dimensional basin and fault structure from a detailed seismic velocity model of Coachella Valley, Southern California

The Coachella Valley in the northern Salton Trough is known to produce destructive earthquakes, making it a high seismic hazard area. Knowledge of the seismic velocity structure and geometry of the sedimentary basins and fault zones is required to improve earthquake hazard estimates in this region. We simultaneously inverted first P wave travel times from the Southern California Seismic Network (39,998 local earthquakes) and explosions (251 land/sea shots) from the 2011 Salton Seismic Imaging Project to obtain a 3-D seismic velocity model. Earthquakes with focal depths ≤10 km were selected to focus on the upper crustal structure. Strong lateral velocity contrasts in the top ~3 km correlate well with the surface geology, including the low-velocity (<5 km/s) sedimentary basin and the high-velocity crystalline basement rocks outside the valley. Sediment thickness is ~4 km in the southeastern valley near the Salton Sea and decreases to <2 km at the northwestern end of the valley. Eastward thickening of sediments toward the San Andreas fault within the valley defines Coachella Valley basin asymmetry. In the Peninsular Ranges, zones of relatively high seismic velocities (~6.4 km/s) between 2 to 4 km depth may be related to Late Cretaceous mylonite rocks or older inherited basement structures. Other high-velocity domains exist in the model down to 9 km depth and help define crustal heterogeneity. We identify a potential fault zone in Lost Horse Valley unassociated with mapped faults in Southern California from the combined interpretation of surface geology, seismicity, and lateral velocity changes in the model.

California↗

USGS1999

U-Pb zircon age of metafelsite from the Pinney Hollow formation: Implications for the development of the Vermont Appalachians

The Pinney Hollow Formation of central Vermont is part of a rift-clastic to drift-stage sequence of cover rocks deposited on the Laurentian margin during the development of the Iapetan passive margin in Late Proterozoic to Cambrian time. Conventional U-Pb zircon data indicate an age of 571+ or -5 Ma for a metafelsite from the Pinney Hollow Formation. Geochemical data indicate that the protolith for the metafelsite, now a quartz-albite gneiss or granofels, was rhyolite from a source that was transitional between a within-plate granite and ocean-ridge granite setting and probably came through partially distended continental crust. The transitional setting is consistent with previous data from metabasalts in the Pinney Hollow Formation and supports the idea that the source magma came through continental crust on the rifted margin of the Laurentian craton. The 571+ or -5 Ma age provides the first geochronologic age from the rift-clastic cover sequence in New England and establishes a Late Proterozoic age for the Pinney Hollow Formation. The Late Proterozoic age of the Pinney Hollow confirms the presence of a significant mapped thrust fault between the autochthonous and para-autochthonous rocks of the cover sequence. These findings support the interpretation that the Taconic root zone is located in the hinterland of the Vermont Appalachians on the eastern side of the Green Mountain massif.

Vermont↗

USGS2012

Contaminants in stream sediments from seven U.S. metropolitan areas: Data summary of a National Pilot Study

This report presents data collected as a part of a synoptic survey of stream sediment contaminants, associated watershed characteristics and invertebrate responses in laboratory sediment toxicity tests from 98 streams (sites) in seven metropolitan study areas across the continental United States. The report presents methods, data, and sediment-quality guidelines, including the derivation of a new sediment pyrethroid probable effects concentration, for the purposes of relating measured contaminants to land use and toxicity evaluation. The study evaluated sites that ranged in their degree of relative urbanization within the study areas of Atlanta, Boston, Dallas-Fort Worth, Denver, Milwaukee-Green Bay, Salt Lake City, and Seattle-Tacoma. In all, 108 chemical analytes quantified in the study are presented, by class and number of individual compounds, as follows: polyaromatic hydrocarbons (PAHs) (28), organochlorine pesticides (OCs) (18), polychlorinated biphenyls (Aroclors) (3), pyrethroid insecticides (14), fipronil compounds (4), priority trace and other major elements (41). The potential of these sediments to cause toxicity to sediment-dwelling invertebrates was evaluated using two standard sediment toxicity tests: a 28-day growth and survival toxicity test with the amphipod Hyalella azteca, and a 10-day growth and survival toxicity test with the midge Chironomus dilutus. Further, approximately 95 relevant watershed and reach-level characteristics were generated and are presented to aid in interpretation and explanation of contaminant and toxicity patterns. Interpretation of the findings of this study, including the relationships with urbanization and other factors, the relationship between sediment toxicity and sediment chemistry in the seven study areas, and the sources and occurrence of pyrethroid insecticides, are discussed in detail in a forthcoming series of journal articles.

Boston;Atlanta;Milwaukee;Green Bay;Dallas;Fort Wor↗

USGS2000

Modern pollen deposition in Long Island Sound

Palynological analyses of 20 surface sediment samples collected from Long Island Sound show a pollen assemblage dominated by Carya, Betula, Pinus, Quercus, Tsuga , and Ambrosia , as is consistent with the regional vegetation. No trends in relative abundance of these pollen types occur either from west to east or associated with modern riverine inputs throughout the basin. Despite the large-scale, long-term removal of fine-grained sediment from winnowed portions of the eastern Sound, the composition of the pollen and spore component of the sedimentary matrix conforms to a basin-wide homogeneous signal. These results strongly support the use of select regional palynological boundaries as chronostratigraphic tools to provide a framework for interpretation of the late glacial and Holocene history of the Long Island Sound basin sediments.

Connecticut, New York↗

USGS2026

Bird guilds exhibit varied responses to floodplain forest restoration in the Colorado River delta, Mexico

Grouping species into guilds can be useful to inform management decisions locally and at broader scales because guilds lack species-specificity. We investigated the response of five breeding bird guilds to riparian habitat restoration in the arid Colorado River delta, based on two decades of bird detections (2002–2021) at 230 bird count stations across 7 routes in actively revegetated (“restored”) sites, and 20 routes in non-actively revegetated (“control”) sites. We used guilds based on habitat associations. We also described changes in vegetation and explored their influence on bird species detections and guild dynamics. Riparian forest bird specialists responded positively to active revegetation, but this positive response was delayed and weaker in a river reach where restoration began later and featured less typical riparian vegetation. Birds associated with wetland habitat showed a positive response to restoration in the wettest reach, which had a baseline of high abundance of wetland birds in control sites and relatively abundant macrophyte cover. Conversely, the abundance of desert scrub bird specialists was highest in the driest and least vegetated restored reach. Generalists only exhibited decreased detections in the wettest restored reach. All this occurred while declines of riparian forest, wetland, desert scrub, and generalist bird species observed over a decade prior to restoration had stabilized in control sites. Detections of birds associated with agricultural fields increased in the study area, irrespective of restoration efforts. Our study demonstrates that the choice of bird guilds as ecological indicators can significantly influence the interpretation of restoration outcomes.

Arizona↗

USGS2012

Intrusion of horizontal dikes: tectonic significance of Middle Proterozoic diabase sheets widespread in the upper crust of the southwestern United States

Initially horizontal sheet intrusions of Middle Proterozoic diabase are abundant in a region 650 by 300 km across in Arizona and California. The diabase forms discordant sheets in basement granite and gneiss and sills in overlying shelf sedimentary sequences. Massive granite is the most common basement host for the sheets, probably because it fractured more easily than foliated hosts during sheet emplacement. Steep feeder dikes are rare compared to the sheets. The diabase in many places is exposed in fault blocks that were tilted during Tertiary tectonic extension. Structure sections restored from the map patterns of upended blocks show that the sheets were intruded at levels throughout the upper crust, to depths of at least 13 km. Sheet intrusion implies a vertical orientation of the least compressive stress, so I conclude that the crust was under tectonic compression or in an isotropic state of stress at the time of diabase intrusion about 1.1 Ga. Magma overpressures, water encountered by rising magma, vertical changes in the crustal stress regime, and flotation of low-density granite all may be important factors for sheet intrusion. The stress conditions suggested by the presence of the sheets argue against an extensional tectonic regime earlier proposed for the diabase event. The diabase province contrasts structurally with similar-age provinces of basaltic magmatism elsewhere in North America that show evidence of tectonic extension, such as the midcontinent rift. The consistent orientations of the sheets commonly allow them to be used as structural markers for postdiabase deformation of basement blocks. Sheet intrusions in the geologic record may be seriously underreported. Their recognition is important for the interpretation of seismic reflection profiles of continental crust. Sheets in Arizona may be responsible for the Bagdad reflection sequence, which extends to depths of at least 15 km.

Journal of Geophysical Research↗

USGS2010

A unique approach to estimating lateral anisotropy in complex geohydrologic environments

Aquifers in fractured rock or karstic settings are likely to have anisotropic transmissivity distributions. Aquifer tests that are performed in these settings also are frequently affected by leakage from adjacent confining units. Finite-difference models such as MODFLOW are convenient tools for estimating the hydraulic characteristics of the stressed aquifer and adjacent confining units but are poor tools for the estimation of lateral anisotropy. This limitation of finite-difference methods can be overcome by application of the spin method, a technique whereby the positions of the observation wells are rotated about the production well to estimate anisotropy and orientation. Formal parameter estimation is necessary to analyze aquifer tests because of the number of parameters that are estimated. As a test, transmissivity, anisotropy, and orientation were successfully estimated for a simple hypothetical problem with known properties. The technique also was applied to estimate hydraulic properties of the Santee Limestone/Black Mingo (SL/BM) aquifer and a leaky confining unit beneath Charleston, South Carolina. A 9-day aquifer test with an average discharge of 6441/min was analyzed numerically. Drawdowns in the SL/BM aquifer and confining unit were simulated with a 12-layer MODFLOW model that was discretized into 81 rows of 81 columns. Simulated drawdowns at seven observation wells that ranged from 23 to 2700 m from the production well were matched to measured drawdowns. Transmissivity estimated along the minor axis ranged from 10 to 15 m 2 /day and along the major axis ranged from 80 to 10Om 2 /day. The major axis of transmissivity was oriented along compass heading 116° (degrees clockwise from north), which agrees with geologic interpretations. Vertical hydraulic conductivity and specific storage estimates for the overlying confining unit were 4 x 10 -5 m/day and 2 x 10 -4 1/m, respectively.

South Carolina↗

USGS2014

Investigation of the high-frequency attenuation parameter, κ (kappa), from aftershocks of the 2010 M w 8.8 Maule, Chile earthquake

The Bío Bío region of Chile experienced a vigorous aftershock sequence following the 2010 February 27 M w 8.8 Maule earthquake. The immediate aftershock sequence was captured by two temporary seismic deployments: the Quake Catcher Network Rapid Aftershock Mobilization Program (QCN RAMP) and the Incorporated Research Institutions for Seismology CHile Aftershock Mobilization Program (IRIS CHAMP). Here, we use moderate to large aftershocks ( M L ≥ 4.0) occurring between 2010 March 1 and June 30 recorded by QCN RAMP and IRIS CHAMP stations to determine the spectral decay parameter, kappa ( κ ). First, we compare waveforms and κ estimates from the lower-resolution QCN stations to the IRIS CHAMP stations to ensure the QCN data are of sufficient quality. We find that QCN stations provide reasonable estimates of κ in comparison to traditional seismic sensors and provide valuable additional observations of local ground motion variation. Using data from both deployments, we investigate the variation in κ for the region to determine if κ is influenced primarily by local geological structure, path attenuation, or source properties (e.g. magnitude, mechanism and depth). Estimates of κ for the Bío Bío region range from 0.0022 to 0.0704 s with a mean of 0.0295 s and are in good agreement with κ values previously reported for similar tectonic environments. κ correlates with epicentral distance and, to a lesser degree, with source magnitude. We find little to no correlation between the site kappa, κ 0 , and mapped geology, although we were only able to compare the data to a low-resolution map of surficial geology. These results support an increasing number of studies that suggest κ observations can be attributed to a combination of source, path and site properties; additionally, measured κ are often highly scattered making it difficult to separate the contribution from each of these factors. Thus, our results suggest that contributions from the site, path and source should be carefully considered when interpreting κ values.

Bío Bío Region↗

USGS2006

The influence of hazard models on GIS-based regional risk assessments and mitigation policies

Geographic information systems (GIS) are important tools for understanding and communicating the spatial distribution of risks associated with natural hazards in regional economies. We present a GIS-based decision support system (DSS) for assessing community vulnerability to natural hazards and evaluating potential mitigation policy outcomes. The Land Use Portfolio Modeler (LUPM) integrates earth science and socioeconomic information to predict the economic impacts of loss-reduction strategies. However, the potential use of such systems in decision making may be limited when multiple but conflicting interpretations of the hazard are available. To explore this problem, we conduct a policy comparison using the LUPM to test the sensitivity of three available assessments of earthquake-induced lateral-spread ground failure susceptibility in a coastal California community. We find that the uncertainty regarding the interpretation of the science inputs can influence the development and implementation of natural hazard management policies. Copyright ?? 2006 Inderscience Enterprises Ltd.

International Journal of Risk Assessment and Manag↗

USGS1973

Effects of laboratory treatments on silver and other elements in native gold

Interpretation of the element content of gold and of alloy proportions of gold and silver may have useful applications in prospecting and ore genesis studies. The commonly used methods of concentration and recovery of gold for analysis (acid leach, roasting, or amalgamation), however, alter the content of silver and other elements in the gold. The treatment of gold with four mineral acids (HF, HCL, H 2 S0 4 , and HNO 3 ) and combinations of these acids, amalgamation of the gold, and roasting the gold in a muffle furnace at 650°C for 8 hours caused losses of 0-100 percent of the elements studied. In some of the samples studied these treatments also caused losses totaling as much as 50 percent, by weight, of the silver content (which made up 20 percent of the total sample weight). The other elements studied show similar behavior to a lesser extent. The results of these studies show that before one interprets compositional analyses for prospecting or other applications he must know to what extent a recovery treatment changes the composition of the elements.

Journal of Research of the U.S. Geological Survey↗

USGS1977

Cauldron subsidence near Mount Lewis, Nevada: A misconception

The map and interpretation of the geology of the Mount Lewis quadrangle, northern Shoshone Range, Nev., contained in U.S. Geological Survey Professional Paper 465 (1965) have recently been criticized and reinterpreted by C. T. Wrucke and M. L. Silberman in Professional Paper 876 (1975). I contend, however, that the reinterpretation ignores much cogent evidence and is quite inconsistent with the geometric disposition of the rocks. No justification exists for postulating a caldera. The faults considered by Wrucke and Silberman to constitute the bounding faults of a caldera hence normal faults downthrown toward the "caldera" are in part nonexistent, in part a strike-slip fault formed concurrently with the Roberts thrust fault in Devonian and Mississippian time, and in part a listric thrust branching into the hanging wall of the main thrust. In short, the two real faults of Wrucke and Silberman's postulated caldera ring are about 200 million years older than the Oligocene volcanic rocks dated by Wrucke and Silberman. The paucity of dikes associated with the faults is thus readily understood, whereas it would be highly anomalous were the faults defining a caldera. The evidence for our thrust-fault interpretation was presented in the text, map, and sections of Professional Paper 465; further detail is included here. The evidence is clear and unequivocal: no caldera is here present.

Nevada↗

USGS2003

Seabird tissue archival and monitoring project: Egg collections and analytical results 1999-2002

In 1998, the U.S. Geological Survey Biological Resources Division (USGS-BRD), the U.S. Fish and Wildlife Service (USFWS) Alaska Maritime National Wildlife Refuge (AMNWR), and the National Institute of Standards and Technology (NIST) began the Seabird Tissue Archival and Monitoring Project (STAMP) to collect and cryogenically bank tissues from seabirds in Alaska for future retrospective analysis of anthropogenic contaminants. The approach of STAMP was similar to that of the Alaska Marine Mammal Tissue Archival Project (AMMTAP). AMMTAP was started in 1987 by NIST and the National Oceanic and Atmospheric Administration (NOAA) as part of the Outer Continental Shelf Environmental Assessment Program sponsored by the Minerals Management Service. Presently sponsored by the USGS-BRD, AMMTAP continues its work as part of a larger national program, the Marine Mammal Health and Stranding Response Program. AMMTAP developed carefully designed sampling and specimen banking protocols. Since 1987, AMMTAP has collected tissues from marine mammals taken in Alaska Native subsistence hunts and has cryogenically banked these tissues at the NIST National Biomonitoring Specimen Bank (NBSB). Through its own analytical work and working in partnership with other researchers both within and outside Alaska, AMMTAP has helped to develop a substantial database on contaminants in Alaska marine mammals. In contrast, data and information is limited on contaminants in Alaska seabirds, which are similar to marine mammals in that they feed near the top of the food chain and have the potential for accumulating anthropogenic contaminants. During its early planning stages, STAMP managers identified the seabird egg as the first tissue of choice for study by the project. There is a relatively long history of using bird eggs for environmental monitoring and for investigating the health status of bird populations. Since 1998, protocols for collecting and processing eggs, and cryogenically banking egg samples have been developed by STAMP (see York et al. 2001). Eggs are being collected on an annual basis for several species at nesting colonies throughout Alaska. Aliquots of these egg samples are being analyzed on a regular basis for persistent organic pollutants and mercury. Results of this work have been published in scientific journals (Christopher et al. 2002) and in conference proceedings (Kucklick et al. 2002; Vander Pol et al. 2002a, 2002b). The intent of this report is to provide an up-to-date description of STAMP. The report contains the most recent egg collection inventory, analytical data, preliminary interpretations based on these data, and a discussion of possible future directions of the project.

Report↗

USGS2016

Magnetotelluric investigation of the Vestfold Hills and Rauer Group, East Antarctica

The Vestfold Hills and Rauer Group in East Antarctica have contrasting Archean to Neoproterozoic geological histories and are believed to be juxtaposed along a suture zone that now lies beneath the Sørsdal Glacier. Exact location and age of this suture zone are unknown, as is its relationship to regional deformation associated with the amalgamation of East Gondwana. To image the suture zone, magnetotelluric (MT) data were collected in Prydz Bay, East Antarctica, mainly along a profile crossing the Sørsdal Glacier and regions inland of the Vestfold Hills and Rauer Group islands. Time-frequency analysis of the MT time series yielded three important observations: (1) Wind speeds in excess of &sim;8 m/s reduce coherence between electric and magnetic fields due to charged wind-blown particles of ice and snow. (2) Estimation of the MT transfer function is best between 1000 and 1400 UT when ionospheric Hall currents enhance the magnetic source field. (3) Nonplanar source field effects were minimal but detectable and removed from estimation of the MT transfer function. Inversions of MT data in 2-D and 3-D produce similar resistivity models, where structures in the preferred 3-D resistivity model correlate strongly with regional magnetic data. The electrically conductive Rauer Group is separated from the less conductive Vestfold Hills by a resistive zone under the Sørsdal Glacier, which is interpreted to be caused by oxidation during suturing. Though a suture zone has been imaged, no time constrains on suturing can be made from the MT data.

Journal of Geophysical Research B: Solid Earth↗

USGS2020

Environmental tracer evidence for connection between shallow and bedrock aquifers and high intrinsic susceptibility to contamination of the conterminous U.S. glacial aquifer

Covering a large portion of the northern conterminous United States (1.87 x 106 km2), the glacial aquifer serves as the primary water supply for 39 million public and domestic water users. Mean groundwater age, groundwater age distribution, and susceptibility to land surface contamination, using a new metric (Susceptibility Index; SI) based on the full age distribution and less prone to bias than estimated mean age, is reported for 168 public and domestic wells across the aquifer. Comparison of groundwater age metrics between well networks of varying spatial scale suggest an extensive sample network of equally spaced, long screened interval wells can be used to characterize aquifer wide groundwater age. Estimated mean age ranges from 1 to 50,000 years and, according to the composite age distribution, approximately 63 percent of all sampled water recharged after 1950 (i.e., modern) and 18 percent of the sampled water was recharged greater than 10,000 years ago. The later finding strongly suggests a connection between the glacial aquifer and underlying bedrock aquifers. Statistical analysis of glacial aquifer hydrogeology and age metrics show groundwater ages are young (less than few 100 years) and more susceptible to land surface contamination (larger SI) in unconfined and shallow portions of the aquifer. Old groundwater (greater than 1000 years) is more often associated with thicker sequences of fine grain sediments and/or shallow bedrock. Calculated SI is shown to be more strongly related to the number of land surface contaminants detected than mean age or fraction modern. Statistical analysis of SI and hydrogeology indicates SI is largely dictated by well depth and confinement. This study demonstrates how sample network design can be used to characterize groundwater age of large aquifers with a limited number of samples and how interpretation of environmental tracers can be used to improve conceptual models of groundwater aquifers and identify groundwater susceptible to contamination.

Glacial aquifer↗

USGS2023

Geochemistry and fluxes of gases from hydrothermal features at Newberry Volcano, Oregon, USA

We present the chemical and isotopic compositions of gases and fluxes of CO 2 from the hydrothermal features of Newberry Volcano, a large composite volcano located in Oregon's Cascade Range with a summit caldera that hosts two lakes, Paulina and East Lakes. Gas samples were collected from 1982 to 2021 from Paulina Hot Springs (PHS) on the shore of Paulina Lake, East Lake Hot Springs (ELHS) on the shore of East Lake, and Obsidian Flow Gas Seep (OFGS), an area of diffuse gas emissions. Surveys of CO 2 flux were conducted in 2020 at OFGS (1400 m 2 ) and East Lake (4.1 km 2 ). Gases from all three sites were CO 2 -rich (≥79 mol% in dry gas) but showed considerable compositional variability over time due to interaction with ground and surface water. An increase in H 2 S concentrations and decline in CO 2 /H 2 S ratios in ELHS gases coincided with a drop in East Lake water level from 1999 to 2021. ELHS and OFGS gases were high in CH 4 relative to PHS and the δ 13 C of CH 4 values for ELHS gases (−72.2 and − 63.6 ‰) reflected a predominantly biogenic origin. The dominant source of N 2 and Ar in PHS, ELHS, and OFGS samples was likely groundwater. Helium isotopic ratios (6.47 to 8.02 R c /R a ) support a persistent source of magmatic He beneath Newberry caldera and consistently high values measured at OFGS and PHS relative to ELHS suggest distinct fluid flow paths from depth to the surface features. The δ 13 C of CO 2 and CO 2 / 3 He values (−8.9 to −5.35 ‰ and 1.3 × 10 9 to 4.6 × 10 10 , respectively) measured in gases reflect contributions of CO 2 from both mantle and crustal sources. Measured CO 2 fluxes at OFGS and East Lake ranged from 1 to 8808 and < 1 to 364 g m −2 d −1 , respectively. A CO 2 emission rate of 0.5 t d −1 was calculated for OFGS. The CO 2 emission rate estimated for East Lake was 30 t d −1 and when compared to prior estimates, reflects steady-state lake degassing. An enhanced geochemical monitoring plan, including annual sampling of gases at ELHS, OFGS, and PHS for geochemical analysis, installation of a continuous lake-level monitoring station at East Lake, and annual CO 2 flux surveys at OFGS, would provide valuable background data and insights into any precursor volcanic activity. Integrating geochemical data with data from the real-time seismic and GPS network at Newberry Volcano could better resolve and interpret potential changes in its magma-hydrothermal system.

Oregon↗

USGS2013

Spatial and temporal variations in landscape evolution: historic and longer-term sediment flux through global catchments

Sediment generation and transport through terrestrial catchments influence soil distribution, geochemical cycling of particulate and dissolved loads, and the character of the stratigraphic record of Earth history. To assess the spatiotemporal variation in landscape evolution, we compare global compilations of stream gauge–derived () and cosmogenic radionuclide (CRN)–derived (predominantly 10 Be; ) denudation of catchments (mm/yr) and sediment load of rivers (Mt/yr). Stream gauges measure suspended sediment loads of rivers during several to tens of years, whereas CRNs provide catchment-integrated denudation rates at 10 2 –10 5 -yr time scales. Stream gauge–derived and CRN-derived sediment loads in close proximity to one another (<500 km) exhibit broad similarity ( stream gauge samples; CRN samples). Nearly two-thirds of CRN-derived sediment loads exceed historic loads measured at the same locations (). Excessive longer-term sediment loads likely are a result of longer-term recurrence of large-magnitude sediment-transport events. Nearly 80% of sediment loads measured at approximately the same locations exhibit stream gauge loads that are within an order of magnitude of CRN loads, likely as a result of the buffering capacity of large flood plains. Catchments in which space for deposition exceeds sediment supply have greater buffering capacity. Superior locations in which to evaluate anthropogenic influences on landscape evolution might be buffered catchments, in which temporary storage of sediment in flood plains can provide stream gauge–based sediment loads and denudation rates that are applicable over longer periods than the durations of gauge measurements. The buffering capacity of catchments also has implications for interpreting the stratigraphic record; delayed sediment transfer might complicate the stratigraphic record of external forcings and catchment modification.

The Journal of Geology↗

USGS1994

Classification of vegetation communities in which geese rear broods on the Yukon-Kuskokwim Delta, Alaska

Plant communities are described from an area on the Yukon – Kuskokwim (Y-K) delta of Alaska that is used extensively for brood rearing by three species of geese. Earlier studies identified plant species important as food for young geese, but few studies describe or quantify plant communities. We classified species presence or absence information from over 700 quadrats using a two-way indicator species analysis ( TWINSPAN ) and then tested for agreement of signatures on colour infrared air photos with the identified communities. Sedges were found to dominate all but the wettest and driest communities. Most of the brood-rearing area was covered by Carex ramenskii and Carex rariflora meadows, ponds, Carex mackenziei -dominated pond margins, and C . ramenskii and grass levee meadows. Our interpretation of airphotos accurately predicted vegetation community classes, which will facilitate future studies of habitat selection by geese during the time they are rearing young. The TWINSPAN classification was comparable to classifications of studies conducted elsewhere on the Y-K delta. The interpretation of air photos will enable the identification and evaluation of wetland vegetation complexes and potential goose brood-rearing areas away from our study site.

Alaska↗

USGS1974

Stabilities of calcite and aragonite

A revaluation of the 25° C activity-product constants of calcite ( K C ) and aragonite ( K A ) was made on the basis of the known solubilities of these phases for which the activity of total dissolved calcium was corrected for the presence of the ion pair CaHCO 3 + in the aqueous phase. The value of the dissociation constant of CaHCO 3 + was taken to be 10 -1.225±0.02 . This value, combined with values of the analytical concentrations in solutions with partial pressure P CO2 =0.97 atmosphere, leads to K C =l0 -8.52±0.04 and K A = 10 -8.36±0.04 . Based on these K values, standard free energies of formation of calcite and aragonite were calculated to be -270,144±375 and -269,926±375 calories mole -1 , (-1,130,282±1,569 and -1,129,370±1,569 joules mole -1 ), respectively. From the 25°C K values, using appropriate entropy and heat capacity data, values of K C and K A were calculated over the temperature range 0° to 200°C. Possible errors in interpretation of measured pH values and inferred P CO2 values and the bearing of these errors on calculations of K values are discussed.

Journal of Research of the U.S. Geological Survey↗