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The fate and transport of nitrate in shallow groundwater in northwestern Mississippi, USA

Agricultural contamination of groundwater in northwestern Mississippi, USA, has not been studied extensively, and subsurface fluxes of agricultural chemicals have been presumed minimal. To determine the factors controlling transport of nitrate-N into the Mississippi River Valley alluvial aquifer, a study was conducted from 2006 to 2008 to estimate fluxes of water and solutes for a site in the Bogue Phalia basin (1,250 km 2 ). Water-quality data were collected from a shallow water-table well, a vertical profile of temporary sampling points, and a nearby irrigation well. Nitrate was detected within 4.4 m of the water table but was absent in deeper waters with evidence of reducing conditions and denitrification. Recharge estimates from 6.2 to 10.9 cm/year were quantified using water-table fluctuations, a Cl – tracer method, and atmospheric age-tracers. A mathematical advection-reaction model predicted similar recharge to the aquifer, and also predicted that 15% of applied nitrogen is leached into the saturated zone. With current denitrification and application rates, the nitrate-N front is expected to remain in shallow groundwater, less than 6–9 m deep. Increasing application rates resulting from intensifying agricultural demands may advance the nitrate-N front to 16–23 m, within the zone of groundwater pumping.

Mississippi↗

Groundwater quality of southeastern Wyoming

Groundwater is an important resource for domestic, municipal, stock, and irrigation uses in southeastern Wyoming. Thirty-seven percent of water used in the tri-County area, which includes Laramie, Platte, and Goshen Counties, is from groundwater. Most groundwater use in the tri-County area is withdrawn from three primary aquifer groups: Quaternary-age unconsolidated-deposit aquifers, Tertiary-age units of the High Plains aquifer system, and Upper Cretaceous bedrock aquifers (Lance Formation and Fox Hills Sandstone). Authors include selected physical properties and chemicals found in water samples, describe sources and importance, and report maximum levels established by the U.S. Environmental Protection Agency. They also show concentration ranges for selected physical properties and chemicals in samples collected from the three primary aquifer groups in the tri-County area.

Wyoming↗

Ground-water reconnaissance of the Sailor Creek area, Owyhee, Elmore, and Twin Falls Counties, Idaho

This reports evaluates the ground-water resources of about 1,000 square miles in the semiarid uplands south of the Snake River between Bruneau River and Salmon Falls Creek. The outcropping rocks are the Idavada Volcanics of Pliocene age, and the Idaho Group of Pliocene and Plieistocene age, consisting of the Banbury Basalt of middle Pliocene age and overlying predominantly sedimentary deposits of middle Pliocene through middle Pleistocene age. These rocks dip gently northward. The volcanic rocks are the best aquifers, but the yield of water from the sedimentary deposits is adequate for domestic and stock use. About 6,000 acre-feet of water is withdrawn annually from the Idavada Volcanics by 9 irrigation wells to irrigate about 3,000 acres. Only a few tends of acre-feet of water withdrawn from the other formations. The regional dip of the rocks induces weak artesian conditions in the volcanic rocks and somewhat higher artesian head in the sedimentary rocks. Estimated depth to water ranges from less than 250 feet to more than 750 feet, as shown in an accompanying map. The eastern part of the area appears to be more favorable for the development of ground water for irrigation than the western part because of better aquifers at shallower depth.

Idaho↗

Groundwater quality in the Western San Joaquin Valley study unit, 2010: California GAMA Priority Basin Project

Water quality in groundwater resources used for public drinking-water supply in the Western San Joaquin Valley (WSJV) was investigated by the USGS in cooperation with the California State Water Resources Control Board (SWRCB) as part of its Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The WSJV includes two study areas: the Delta–Mendota and Westside subbasins of the San Joaquin Valley groundwater basin. Study objectives for the WSJV study unit included two assessment types: (1) a status assessment yielding quantitative estimates of the current (2010) status of groundwater quality in the groundwater resources used for public drinking water, and (2) an evaluation of natural and anthropogenic factors that could be affecting the groundwater quality. The assessments characterized the quality of untreated groundwater, not the quality of treated drinking water delivered to consumers by water distributors. The status assessment was based on data collected from 43 wells sampled by the U.S. Geological Survey for the GAMA Priority Basin Project (USGS-GAMA) in 2010 and data compiled in the SWRCB Division of Drinking Water (SWRCB-DDW) database for 74 additional public-supply wells sampled for regulatory compliance purposes between 2007 and 2010. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency (EPA) and SWRCB-DDW regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a spatially weighted, grid-based method to estimate the proportion of the groundwater resources used for public drinking water that has concentrations for particular constituents or class of constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale within the WSJV study unit, and permits comparison of the two study areas to other areas assessed by the GAMA Priority Basin Project statewide. Groundwater resources used for public drinking water in the WSJV study unit are among the most saline and most affected by high concentrations of inorganic constituents of all groundwater resources used for public drinking water that have been assessed by the GAMA Priority Basin Project statewide. Among the 82 GAMA Priority Basin Project study areas statewide, the Delta–Mendota study area ranked above the 90th percentile for aquifer-scale proportions of groundwater resources having concentrations of total dissolved solids (TDS), sulfate, chloride, manganese, boron, chromium(VI), selenium, and strontium above benchmarks, and the Westside study area ranked above the 90th percentile for TDS, sulfate, manganese, and boron. In the WSJV study unit as a whole, one or more inorganic constituents with regulatory or non-regulatory, health-based benchmarks were present at concentrations above benchmarks in about 53 percent of the groundwater resources used for public drinking water, and one or more organic constituents with regulatory health-based benchmarks were detected at concentrations above benchmarks in about 3 percent of the resource. Individual constituents present at concentrations greater than health-based benchmarks in greater than 2 percent of groundwater resources used for public drinking water included: boron (51 percent, SWRCB-DDW notification level), chromium(VI) (25 percent, SWRCB-DDW maximum contaminant level (MCL)), arsenic (10 percent, EPA MCL), strontium (5.1 percent, EPA Lifetime health advisory level (HAL)), nitrate (3.9 percent, EPA MCL), molybdenum (3.8 percent, EPA HAL), selenium (2.6 percent, EPA MCL), and benzene (2.6 percent, SWRCB-DDW MCL). In addition, 50 percent of the resource had TDS concentrations greater than non-regulatory, aesthetic-based SWRCB-DDW upper secondary maximum contaminant level (SMCL), and 44 percent had manganese concentrations greater than the SWRCB-DDW SMCL. Natural and anthropogenic factors that could affect the groundwater quality were evaluated by using results from statistical testing of associations between constituent concentrations and values of potential explanatory factors, inferences from geochemical and age-dating tracer results, and by considering the water-quality results in the context of the hydrogeologic setting of the WSJV study unit. Natural factors, particularly the lithologies of the source areas for groundwater recharge and of the aquifers, were the dominant factors affecting groundwater quality in most of the WSJV study unit. However, where groundwater resources used for public supply included groundwater recharged in the modern era, mobilization of constituents by recharge of water used for irrigation also affected groundwater quality. Public-supply wells in the Westside study area had a median depth of 305 m and primarily tapped groundwater recharged hundreds to thousands of years ago, whereas public-supply wells in the Delta–Mendota study area had a median depth of 85 m and primarily tapped either groundwater recharged within the last 60 years or groundwater consisting of mixtures of this modern recharge and older recharge. Public-supply wells in the WSJV study unit are screened in the Tulare Formation and zones above and below the Corcoran Clay Member are used. The Tulare Formation primarily consists of alluvial sediments derived from the Coast Ranges to the west, except along the valley trough at the eastern margin of the WSJV study unit where the Tulare Formation consists of fluvial sands derived from the Sierra Nevada to the east. Groundwater from wells screened in the Sierra Nevada sands had manganese-reducing or manganese- and iron-reducing oxidation-reduction (redox) conditions. These redox conditions commonly were associated with elevated arsenic or molybdenum concentrations, and the dominance of arsenic(III) in the dissolved arsenic supports reductive dissolution of iron and manganese oxyhydroxides as the mechanism. In addition, groundwater from many wells screened in Sierra Nevada sands contained low concentrations of nitrite or ammonium, indicating reduction of nitrate by denitrification or dissimilatory processes, respectively. Geology of the Coast Ranges westward of the study unit strongly affects groundwater quality in the WSJV. Elevated concentrations of TDS, sulfate, boron, selenium and strontium in groundwater were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by Cretaceous-to-Miocene age, organic-rich, reduced marine shales, known as the source of selenium in WSJV soils, surface water, and groundwater. Low sulfur-isotopic values (δ34S) of dissolved sulfate indicate that the sulfate was largely derived from oxidation of biogenic pyrite from the shales, and correlations with trace element concentrations, geologic setting, and groundwater geochemical modeling indicated that distributions of sulfate, strontium, and selenium in groundwater were controlled by dissolution of secondary sulfate minerals in soils and sediments. Elevated concentrations of chromium(VI) were primarily associated with aquifer sediments and recharge derived from areas of the Coast Ranges dominated by the Franciscan Complex and ultramafic rocks. The Franciscan Complex also has boron-rich, sodium-chloride dominated hydrothermal fluids that contribute to elevated concentrations of boron and TDS. Groundwater from wells screened in Coast Ranges alluvium was primarily oxic and relatively alkaline (median pH value of 7.55) in the Delta–Mendota study area, and primarily nitrate-reducing or suboxic and alkaline (median pH value of 8.4) in the Westside study area. Many groundwater samples from those wells have elevated concentrations of arsenic(V), molybdenum, selenium, or chromium(VI), consistent with desorption of metal oxyanions from mineral surfaces under those geochemical conditions. High concentrations of benzene were associated with deep wells located in the vicinity of petroleum deposits at the southern end of the Westside study area. Groundwater from these wells had premodern age and anoxic geochemical conditions, and the ratios among concentrations of hydrocarbon constituents were different from ratios found in fuels and combustion products, which is consistent with a geogenic source for the benzene rather than contamination from anthropogenic sources. Water stable-isotope compositions, groundwater recharge temperatures, and groundwater ages were used to infer four types of groundwater: (1) groundwater derived from natural recharge of water from major rivers draining the Sierra Nevada; (2) groundwater primarily derived from natural recharge of water from Coast Ranges runoff; (3) groundwater derived from recharge of pumped groundwater applied to the land surface for irrigation; and (4) groundwater derived from recharge during a period of much cooler paleoclimate. Water previously used for irrigation was found both above and below the Corcoran Clay, supporting earlier inferences that this clay member is no longer a robust confining unit. Recharge of water used for irrigation has direct and indirect effects on groundwater quality. Elevated nitrate concentrations and detections of herbicides and fumigants in the Delta–Mendota study area generally were associated with greater agricultural land use near the well and with water recharged during the last 60 years. However, the extent of the groundwater resource affected by agricultural sources of nitrate was limited by groundwater redox conditions sufficient to reduce nitrate. The detection frequency of perchlorate in Delta–Mendota groundwater was greater than expected for natural conditions. Perchlorate, nitrate, selenium, and strontium concentrations were correlated with one another and were greater in groundwater inferred to be recharge of previously pumped groundwater used for irrigation. The source of the perchlorate, selenium, and strontium appears to be salts deposited in the soils and sediments of the arid WSJV that are dissolved and flushed into groundwater by the increased amount of recharge caused by irrigation. In the Delta–Mendota study area, the groundwater with elevated concentrations of selenium was found deeper in the aquifer system than it was reported by a previous study 25 years earlier, suggesting that this transient front of groundwater with elevated concentrations of constituents derived from dissolution of soil salts by irrigation recharge is moving down through the aquifer system and is now reaching the depth zone used for public drinking water supply.

California↗

Ground-water resources of Waupaca County, Wisconsin

Waupaca County is in east-central Wisconsin. No serious ground-water problems existed in 1960 except in a few localities where crystalline rock is near land surface or is covered by nearly impermeable till. The use of ground water for irrigation has not appreciably affected ground-water levels. The county is covered by Pleistocene till, glaciolacustrine (lake), glaciofluvial (stream), and eolian (wind) deposits. In the northern three-quarters of the county these deposits overlie Precambrian crystalline rocks; in the remainder, they overlie sandstone of Cambrian age and, to a minor extent, dolomite of the Prairie du Chien Group of Ordovician age. The deposits of Pleistocene age, particularly outwash, are the principal sources of ground water except in those areas where the saturated thickness is slight or the permeability low. The sandstone of Cambrian age is an important aquifer in the southeastern part of the county. The crystalline rocks of Precambrian age yield little water except from fractures, joints, and weathered zones, and they are a source of water only in areas where better aquifers are absent. Ground water in Waupaca County occurs under both water-table and artesian conditions. The source of this ground water is precipitation that falls on the county and percolates downward to the zone of saturation. Regional movement of ground water is to the Wolf River. In most of the county the direction of movement is eastward or southeastward, except in the southeastern corner of the county, where the movement is westward. Water-level fluctuations reflect the variations of ground-water storage or artesian pressure in response to variations in recharge and discharge. Declining water levels from 1956 to 1959 reflect a period of below-normal precipitation, and rising water levels in late 1959 and 1960 reflect above-normal precipitation. Average precipitation, runoff, and evapotranspiration in 1959 are estimated to be 1,000, 400, and 600 mgd (million gallons per day) respectively. Pumpage in the county was estimated to be about 4 mgd in 1959, and about half of this amount was used for public supplies. A pumping test of a well in outwash deposits near Waupaca indicated that at that point the coefficient of transmissibility is about 100,000 gpd (gallons per day) per ft, the permeability is about 1,000 gpd per sq ft, the coefficient of storage is about 0.2, and the specific capacity is 41 gpm (gallons per minute) per ft of drawdown. These hydraulic characteristics are probably in the same order of magnitude as the characteristics of outwash deposits in the county in general. The water from wells in Waupaca County, although hard and generally containing iron, is good for most purposes.

Wisconsin↗

Quality of groundwater in the Denver Basin aquifer system, Colorado, 2003-5

Groundwater resources from alluvial and bedrock aquifers of the Denver Basin are critical for municipal, domestic, and agricultural uses in Colorado along the eastern front of the Rocky Mountains. Rapid and widespread urban development, primarily along the western boundary of the Denver Basin, has approximately doubled the population since about 1970, and much of the population depends on groundwater for water supply. As part of the National Water-Quality Assessment Program, the U.S. Geological Survey conducted groundwater-quality studies during 2003–5 in the Denver Basin aquifer system to characterize water quality of shallow groundwater at the water table and of the bedrock aquifers, which are important drinking-water resources. For the Denver Basin, water-quality constituents of concern for human health or because they might otherwise limit use of water include total dissolved solids, fluoride, sulfate, nitrate, iron, manganese, selenium, radon, uranium, arsenic, pesticides, and volatile organic compounds. For the water-table studies, two monitoring-well networks were installed and sampled beneath agricultural (31 wells) and urban (29 wells) land uses at or just below the water table in either alluvial material or near-surface bedrock. For the bedrock-aquifer studies, domestic- and municipal-supply wells completed in the bedrock aquifers were sampled. The bedrock aquifers, stratigraphically from youngest (shallowest) to oldest (deepest), are the Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers. The extensive dataset collected from wells completed in the bedrock aquifers (79 samples) provides the opportunity to evaluate factors and processes affecting water quality and to establish a baseline that can be used to characterize future changes in groundwater quality. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating constituents and tracers. This report discusses spatial and statistical distributions of chemical constituents and evaluates natural and human-related processes that affect water quality. Findings are synthesized to assess the vulnerability of the Denver Basin aquifer system to groundwater contamination. The chemistry of groundwater samples collected from the water-table wells was generally different from that of samples collected from the bedrock-aquifer wells. Samples from the water-table wells tended to have higher concentrations of total dissolved solids and most major ions. Concentrations of several constituents with potential human-health concerns, including nitrate, selenium, uranium, and arsenic, decreased with depth and were highest in samples from the water-table wells. Exceedances of drinking-water standards and water-quality benchmarks were more frequently associated with shallow groundwater samples; concentrations of total dissolved solids and sulfate exceeded water-quality benchmarks for about half or more of samples from the water-table wells. The sediments and rocks of the Denver Basin are natural sources of the trace elements selenium, uranium, and arsenic, which affect their concentrations in groundwater. Detections of organic contaminants, which are typically indicative of human sources of contamination to groundwater, were more frequent in samples from the water-table wells. Pesticide compounds and volatile organic compounds were detected in 33 and 62 percent, respectively, of water-table well samples. Detected organic contaminant concentrations were much less than the associated drinking-water standards. Samples collected from the bedrock aquifers had lower concentrations of total dissolved solids than did samples collected from the water-table wells, although within the bedrock-aquifer samples, concentrations increased from the Dawson to Denver to Arapahoe to Laramie-Fox Hills aquifers. Concentrations of total dissolved solids and many constituents varied spatially and with depth in the bedrock aquifers, likely as a result of ion-exchange and oxidation-reduction reactions, which are important processes affecting water quality. Major-ion chemistry generally evolved from a calcium-bicarbonate to calcium-sulfate composition, with some sodium-bicarbonate and sodium-sulfate facies in the deeper bedrock aquifers, likely resulting from longer residence times and more extensive water-rock interaction. Oxidation-reduction conditions generally evolved from oxic at the water table to anoxic with increasing depth in the bedrock aquifers. Most samples from the bedrock aquifers were anoxic. Exceedances of drinking-water standards and water-quality benchmarks for the bedrock aquifers occurred in 1 percent or less of samples for nitrate, selenium, or arsenic; there were no exceedances for uranium. Exceedances for total dissolved solids, sulfate, manganese, and iron were generally between about 10 and 20 percent for the bedrock-aquifer samples. Radon concentrations, which were only measured in samples collected from two of the bedrock aquifers, exceeded the lower proposed drinking-water standard for more than 90 percent of samples but exceeded the higher alternative standard for less than 5 percent of samples. Pesticide compounds and volatile organic compounds were detected in 3 and 22 percent, respectively, of bedrock-aquifer samples, all at concentrations that were that were much less than drinking-water standards. Water-quality data were synthesized to evaluate factors that affect spatial and depth variability in water quality and to assess aquifer vulnerability to contaminants from geologic materials and those of human origin. The quality of shallow groundwater in the alluvial aquifer and shallow bedrock aquifer system has been adversely affected by development of agricultural and urban areas. Land use has altered the pattern and composition of recharge. Increased recharge from irrigation water has mobilized dissolved constituents and increased concentrations in the shallow groundwater. Concentrations of most constituents associated with poor or degraded water quality in shallow groundwater decreased with depth; many of these constituents are not geochemically conservative and are affected by geochemical reactions such as oxidation-reduction reactions. Groundwater age tracers provide additional insight into aquifer vulnerability and help determine if young groundwater of potentially poor quality has migrated to deeper parts of the bedrock aquifers used for drinking-water supply. Age-tracer results were used to group samples into categories of young, mixed, and old groundwater. Groundwater ages transitioned from mostly young in the water-table wells to mostly mixed in the shallowest bedrock aquifer, the Dawson aquifer, to mostly old in the deeper bedrock aquifers. Although the bedrock aquifers are mostly old groundwater of good water quality, several lines of evidence indicate that young, contaminant-bearing recharge has reached shallow to moderate depths in some areas of the bedrock aquifers. The Dawson aquifer is the most vulnerable of the bedrock aquifers to contamination, but results indicate that the older (deeper) bedrock aquifers are also vulnerable to groundwater contamination and that mixing with young recharge has occurred in some areas. Heavy pumping has caused water-level declines in the bedrock aquifers in some parts of the Denver Basin, which has the potential to enhance the transport of contaminants from overlying units. Results of this study are consistent with the existing conceptual understanding of aquifer processes and groundwater issues in the Denver Basin and add new insight into the vulnerability of the bedrock aquifers to groundwater contamination.

Colorado↗

Hydrology of Sanpete Valley, Sanpete and Juab Counties, Utah, and simulation of ground-water flow in the valley-fill aquifer

The surface-and ground-water hydrology of Sanpete Valley and the San Pitch River drainage basin, Sanpete and Juab Counties, Utah, was studied to define the current conditions of the hydrologic system, to detect causes for downstream changes in water quality in the San Pitch River and in areas of high concentration of dissolved solids in ground water, and to determine the possible effects of present changes in irrigation methods and possible future increased ground-water withdrawals from the valley-fill aquifer. Measurements of water levels in wells show responses to climatic variation. The dissolved-solids concentration of water from the San Pitch River increases downstream. Principal areas of ground water with high concentrations of dissolved solids occur downgradient from outcrops of rocks of Jurassic and Tertiary age. One local-scale ground-water flow system discharges small volumes of water with high concentrations of dissolved solids to the San Pitch River southwest of Ephraim. Although ground water occurs in both valley-fill and consolidated-rock aquifers in the study area, more hydrologic information is available for the valley-fill aquifer. The valley-fill aquifer consists primarily of fine-grained silt and clay in the center of the valley and coarser deposits along the margin of the valley. Surface- water inflow to the valley is estimated to be about 152,000 acre-feet per year. Recharge to the valley-fill aquifer is estimated to be between 74,000 and 103,000 acre-feet per year. A three-dimensional, ground-water flow model was developed to better define present ground-water conditions and to determine possible effects of future changes in ground-water withdrawals from the valley-fill aquifer. Computer simulation results indicate the possibility of recharge to the valleyfill aquifer as subsurface inflow from consolidated-rock aquifers. Simulation of water-level changes during the late 1980's indicate that some of the declines could have been caused by conversion from flood irrigation to sprinkler irrigation. Predictive simulations using three times the average pumping rates indicate possible water-level declines of as much as 70 feet.

Utah↗

Hydrologic characteristics of soils in the High Plains, northern Great Plains, and Central Texas Carbonates Regional Aquifer Systems

Certain physical characteristics of soils, including permeability, available water capacity, thickness, and topographic position, have a measurable effect on the hydrology of an area. These characteristics control the rate at which precipitation infiltrates or is transmitted through the soil, and thus they have an important role in determining the rates of actual evapotranspiration (consumptive water use), groundwater recharge, and surface runoff. In studies of groundwater hydrology, it is useful to differentiate soils spatially according to their physical characteristics and to assign values that indicate their hydrologic responses. The principal purpose of this report is to describe the relation between the hydrologic characteristics of the soils in the study area and those environmental factors that affect the development and distribution of the soils. This objective will be achieved by (1) defining both qualitatively and quantitatively those soil characteristics that affect hydrology, and (2) classifying and delineating the boundaries of the soils in the study area according to these hydrologic characteristics. The study area includes the High Plains, Northern Great Plains, the Central Texas Carbonates, and parts of the Central Midwest Regional Aquifer Systems as described by the U.S. Geological Survey Regional Aquifer-System Analysis (RASA) Program (Sun, 1986, p.5and Sun, personal commun., June 1985) and shown in figures 1 through 5. The spatial patterns of the soils classified according to their quantifiable hydrologic characteristics will subsequently serve as an integral component in the analysis of actual evapotranspiration (consumptive water use), consumptive irrigation requirements, and potential ground-water recharge of the study area. The classification system used to describe the soils in this report is compatible with that of Dugan (1986). Dugan described the same characteristics of soils that are immediately underlain by principal aquifers of Cretaceous or older age in adjacent parts of the Central Midwest Regional Aquifer System. However, map scales and mapping detail are different between this report and the report by Dugan (1986) because of the size of the study area.

Hydrologic Atlas↗

Water resources of the Warm Springs Indian Reservation, Oregon

Water-resources data for the 1,000-square-mile Warm Springs Indian Reservation in north-central Oregon were obtained and evaluated. The area is bounded on the west by the crest of the Cascade Range and on the south and east by the Metolius and Deschutes Rivers. The mountainous western part is underlain by young volcanic rocks, and the plateaus and valleys of the eastern part are underlain by basalt, tuff, sand, and gravel of Tertiary and Quaternary ages. There are numerous springs, some developed for stock use, and about 50 domestic and community wells; yields are small, ranging from less than 1 to as much as 25 gallons per minute. Chemical quality of most ground water is suitable for stock or human consumption and for irrigation. Average flows of the Warm Springs River, Metolius River, and Deschutes River are 440, 1,400, and 4,040 cubic feet per second (cfs), respectively. Shitike Creek, which has an average flow of 108 cfs had a peak of 4,000 cfs in January 1974. Most streams have fewer than 100 milligrams per liter (mg/liter) of dissolved solids. Chemical and biological quality of the mountain lakes is also good; of 10 lakes studied, all had fewer than 50 mg/liter of dissolved solids and none had measurable fecal coliform bacteria. (Woodard-USGS)

Water-Resources Investigations Report↗

Geology and ground-water resources of the upper Lodgepole Creek drainage basin, Wyoming, with a section on chemical quality of the water

The principal sources of ground-water supply in the upper Lodgepole Creek drainage basin-the part of the basin west of the Wyoming-Nebraska State line-are the Brule formation of Oligocene age, the Arikaree formation of Miocene age, the Ogallala formation of Pliocene age, and the unconsolidated deposits of Quaternary age. The Brule formation is a moderately hard siltstone that generally is not a good aquifer. However, where it is fractured or where the upper part consists of pebbles of reworked siltstone, it will yield large quantities of water to wells. Many wells in the Pine Bluffs lowland, at the east end of the area, derive water from the Brule. The Arikaree formation, which consists of loosely to moderately cemented fine sand, will yield small quantities of water to wells but is not thick enough or permeable enough to supply sufficient water for irrigation. Only a few wells derive water from it. The Ogallala formation consists of lenticular beds of clay, silt, sand, and gravel which, in part, are cemented with calcium carbonate. Only the lower part of the formation is saturated. Nearly all the wells in the upland part of the area tap the Ogallala, but they supply water in amounts sufficient for domestic and stock use only. Two of the wells have a moderately large discharge, and other wells of comparable discharge probably could be drilled in those parts of the upland where the saturated part of the Ogallala is fairly thick. Most of the unconsolidated deposits of Quaternary age are very permeable and, where a sufficient thickness is saturated, will yield large quantities of water to wells. These deposits are a significant source of water supply in the southeastern part of the area. The Chadron formation of Oligocene age, which underlies the Brule formation, is a medium- to coarse-grained sandstone where it crops out in the Islay lowland. No wells tap the Chadron, but it probably would yield small quantities of water to wells. It lies at a relatively shallow depth beneath most of the Islay lowland, near the west end of the area, and at a depth of about 800 feet beneath the Pine Bluffs lowland. In the latter area it probably is finer grained and may not be permeable enough to yield water to wells. All the ground water in the area is derived from precipitation. It is estimated that about 5 percent of the precipitation infiltrates directly to the zone of saturation. The remainder either is evaporated immediately; is retained by the soil, later to be evaporated or transpired; or is discharged by overland flow to the surface drainage courses. Most of the water that reaches the surface drainage courses eventually sinks to the zone of saturation or is evaporated. The slope of the water table and the movement of ground water are generally eastward. The depth to water ranges from less than 10 feet in parts of the valley to about 300 feet in the upland areas. In much of the Pine Bluffs lowland, the depth to water is less than 50 feet. Ground water not pumped from wells within the area is discharged by evapotranspiration where the water table is close to the land surface, by outflow into streams, or by underflow eastward beneath the State line. The chemical quality of ground water from the principal sources is remarkably uniform, and the range in concentration of dissolved constituents is narrow. In general, the water is of the calcium bicarbonate type, is hard (hardness as CaC03 is as high as 246 ppm), and contains less than about 400 parts per million of dissolved solids, which is a moderate mineralization. Silica constitutes a large proportion of the dissolved solids. The water is suitable for irrigation and, except for iron in water from some wells that tap the Ogallala formation, meets the drinking water standards of the U.S. Public Health Service for chemical constituents. Because the water is siliceous, alkaline, and hard, it is unsuitable for many industrial uses unless treated.

Water Supply Paper↗

Geology and ground-water resources of Washington County, Colorado

Washington County, in northeastern Colorado, has an area of 2,520 square miles. The eastern two-thirds of the county, part of the High Plains physiographic section, is relatively flat and has been moderately altered by the deposition of loess and dune sand, and by stream erosion. The western one-third is a part of the South Platte River basin and has been deeply dissected by tributary streams. The soils and climate of the county are generally suited for agriculture, which is the principal industry. The rocks that crop out in the county influence the availability of ground water. The Pierre Shale, of Late Cretaceous age, underlies the entire area and ranges in thickness from 2,000 to 4,500 feet. This dense shale is a barrier to the downward movement of water and yields little or no water to wells. The Chadron Formation, of Oligocene age, overlies the Pierre Shale in the northern and central parts of the area. The thickness of the formation ranges from a few feet to about 300 feet. Small to moderate quantities of water are available from the scattered sand lenses and from the highly fractured zones of the siltstone. The Ogallala Formation, of Pliocene age, overlies the Chadron Formation and in Washington County forms the High Plains section of the Great Plains province. The thickness of the Ogallala Formation ranges from 0 to about 400 feet, and the yield from wells ranges from a few gallons per hour to about 1,500 gpm. Peorian loess, of Pleistocene age, and dune sand, of Pleistocene to Recent age, mantle a large pan of the county and range in thickness from a few inches to about 120 feet Although the loess and dune sand yield little water to wells, they absorb much of the precipitation and conduct the water to underlying formations. Alluvium, of Pleistocene and Recent age, occupies most of the major stream valleys in thicknesses of a few feet to about 250 feet. The yield of wells tapping the alluvium ranges from a few gallons per minute to about 3,000 gpm, according to the thickness of saturated material. Development of ground water for irrigation has been generally restricted to the South Platte, Arikaree, and Beaver valleys. There were 134 irrigation wells, 3 industrial wells, and 10 municipal wells in the county in 1959. The annual ground-water pumpage from Washington County is estimated to be 18,000 acre-ft; about 10,000 acre-ft is from the High Plains ground-water province. Although some ground water enters the county as underflow, most of the recharge to ground-water reservoirs is from precipitation on the land surface. Recharge to the Ogallala Formation in the county is assumed to be approximately equal to the natural discharge from the county by underflow because ground-water withdrawals are from storage, and no other significant amount of natural discharge is apparent. Undertow in the Ogallala was calculated to be 83,000 acre-ft per year and the rate of recharge from precipitation to be about 0.95 inch per year. Neither recharge nor discharge was calculated for that part of the county in the South Platte River basin. All ground water in Washington County has a high proportion of carbonate and is classed as hard to very hard. The sodium-adsorption-ratio for all samples analyzed was below the limit recommended for irrigation water. All the water from the Ogallala Formation and most of the water from the Chadron Formation is suitable for domestic use. Some water from the alluvial deposits overlying the Pierre Shale was exceptionally high in calcium, magnesium, and sodium sulfates. Ground water has been heavily developed for irrigation in the South Platte valley and in some parts of the Beaver and Arikaree valleys. Some additional areas, however, could be developed in the latter two valleys. Large quantities of ground water in the Ogallala Formation are available for future development. The quantity of water in storage in the High Plains ground-water province in Washington County is about 6.5 million acre-f

Water Supply Paper↗

Water resources of Jackson and Independence Counties, Arkansas

The present (1965) water use in Jackson and Independence Counties is about 55.6 million gallons per day, and quantities sufficient for any foreseeable use are available. Supplies for the large-scale uses--municipal, industrial, and irrigation--can best be obtained from wells in the Coastal Plain and from streams in the highlands. Wells in the Coastal Plain will yield 1,000-2,000 gallons of water per minute when screened at depths from 100 to 150 feet in alluvial sand and gravel of Quaternary age. The water will require treatment for the removal of iron and the reduction of hardness to be suitable for municipal and industrial uses. Wells in the highlands generally yield less than 50 gallons per minute of water that is of good quality, though hard. The dependable flow of .the White River at Newport is about 4.2 billion gallons per day. The dependable 'base flows of the small streams tributary to the White River in the Salem Plateau and Springfield Plateau sections range from 0.25 to 5 million gallons per day, and the dependable flow of Polk Bayou at Batesville is about 21 million gallons per day. These streams can be utilized for water supply with little or no artificial storage required. Streams in the Boston Mountains section and in the Arkansas Valley section recede to very low flow or to no flow during extended dry periods, but dependable, supplies can be obtained from these streams 'by construction of storage facilities Water from all the highland streams is af excellent chemical quality except that it generally is hard.

Arkansas↗

Hydrogeology and groundwater quality of Highlands County, Florida

Groundwater is the main source of water supply in Highlands County, Florida. As the demand for water in the county increases, additional information about local groundwater resources is needed to manage and develop the water supply effectively. To address the need for additional data, a study was conducted to evaluate the hydrogeology and groundwater quality of Highlands County. Total groundwater use in Highlands County has increased steadily since 1965. Total groundwater withdrawals increased from about 37 million gallons per day in 1965 to about 107 million gallons per day in 2005. Much of this increase in water use is related to agricultural activities, especially citrus cultivation, which increased more than 300 percent from 1965 to 2005. Highlands County is underlain by three principal hydrogeologic units. The uppermost water-bearing unit is the surficial aquifer, which is underlain by the intermediate aquifer system/intermediate confining unit. The lowermost hydrogeologic unit is the Floridan aquifer system, which consists of the Upper Floridan aquifer, as many as three middle confining units, and the Lower Floridan aquifer. The surficial aquifer consists primarily of fine-to-medium grained quartz sand with varying amounts of clay and silt. The aquifer system is unconfined and underlies the entire county. The thickness of the surficial aquifer is highly variable, ranging from less than 50 to more than 300 feet. Groundwater in the surficial aquifer is recharged primarily by precipitation, but also by septic tanks, irrigation from wells, seepage from lakes and streams, and the lateral groundwater inflow from adjacent areas. The intermediate aquifer system/intermediate confining unit acts as a confining layer (except where breached by sinkholes) that restricts the vertical movement of water between the surficial aquifer and the underlying Upper Floridan aquifer. The sediments have varying degrees of permeability and consist of permeable limestone, dolostone, or sand, or relatively impermeable layers of clay, clayey sand, or clayey carbonates. The thickness of the intermediate aquifer system/ intermediate confining unit ranges from about 200 feet in northwestern Highlands County to more than 600 feet in the southwestern part. Although the intermediate aquifer system is present in the county, it is unclear where the aquifer system grades into a confining unit in the eastern part of the county. Up to two water-bearing units are present in the intermediate aquifer system within the county. The lateral continuity and water-bearing potential of the various aquifers within the intermediate aquifer system are highly variable. The Floridan aquifer system is composed of a thick sequence of limestone and dolostone of Upper Paleocene to Oligocene age. The top of the aquifer system ranges from less than 200 feet below NGVD 29 in extreme northwestern Highlands County to more than 600 feet below NGVD 29 in the southwestern part. The principal source of groundwater supply in the county is the Upper Floridan aquifer. As of 2005, about 89 percent of the groundwater withdrawn from the county was obtained from this aquifer, mostly for agricultural irrigation and public supply. Over most of Highlands County, the Upper Floridan aquifer generally contains freshwater, and the Lower Floridan aquifer contains more mineralized water. The potentiometric surface of the Upper Floridan aquifer is constantly fluctuating, mainly in response to seasonal variations in rainfall and groundwater withdrawals. The potentiometric surface of the Upper Floridan aquifer in May 2007, which represents the hydrologic conditions near the end of the dry season when water levels generally are near their lowest, ranged from about 79 feet above NGVD 29 in northwestern Highlands County to about 40 feet above NGVD 29 in the southeastern part of the county. The potentiometric surface of the Upper Floridan aquifer in September 2007 was about 3 to 10 feet high

Scientific Investigations Report↗

Water-table contours, directions of ground-water movement, and measurements of inflow to American Falls Reservoir, southeastern Idaho, April 1984

In 1978 the U.S. Geological Survey began a 5-year study of the High Plains regional aquifer system to provide hydrologic information for evaluating the effects of long-term development of the aquifer and to develop a capability for predicting aquifer response to alternative changes in ground-water management. By use of a digital model, this report presents a quantitative description of the High Plains aquifer in Oklahoma. The High Plains aquifer consists predominantly of the Tertiary Ogallala Formation and overlying Quaternary alluvium and terrace deposits which are hydraulically connected to the High Plains aquifer. Much of the aquifer is underlain by formations of Permian through Cretaceous age, which generally have very small hydraulic conductivities. In some areas parts of underlying Triassic, Jurassic, or Cretaceous rocks are hydraulically connected with the aquifer. The High Plains aquifer is a water-table aquifer in which water moves generally to the east-southeast. Before the beginning of extensive irrigation of the 1960's, the aquifer was essentially in dynamic equilibrium with recharge from precipitation balanced by natural discharge from the aquifer. Ground-water discharge appeared in streams leaving the area or was returned to the atmosphere through evapotranspiration. Accurate records of irrigation pumpage are not available from the High Plains. In order to estimate irrigation pumpage, published records of crop distribution were used and a consumptive use was assigned to each principal irrigated crop. This method gave an estimated irrigation demand. Pumpage was taken as a percentage of the total irrigation demand. Irrigation has decreased ground-water discharge from the High Plains aquifer. Ground-water discharge was estimated as approximately 118 cubic feet per second in 1980. A finite-difference digital model was used to simulate flow in the High Plains aquifer. The recharge was adjusted so that 1980 ground-water discharge was 118 cubic feet per second, the estimated ground-water discharge for 1980. Recharge in the eastern half of the modeled area was 0.45 inch per year; one-half this value was used in the western half of the modeled area. Hydraulic conductivity was divided into three zones: 19.3 feet per day in the eastern zone; 16.2 feet per day in the central zone; and 8.28 feet per day in the western zone. A specific yield of 14.7 percent was used in the model. Using all these parameters, the model was calibrated so that the mean difference between predevelopment modeled and measured head was -0.044 foot. Following the calibration procedure, the model was used to predict the volumes of water in storage and distribution of saturated thickness in 1993 and 2020 using the 1980 pumping rates. The calculated quantity of water in storage in the aquifer in 1941 (predevelopment) was approximately 135.2 million acre-feet; in 1980, approximately 121.9 million acre-feet; in 1993 approximately 112.7 million acre-feet; and in 2020, approximately 96.2 million acre-feet. The High Plains aquifer in Oklahoma will continue to be an important source of water past the year 2000. As withdrawals continue from the aquifer at the present rate, the water table will continue to decline and when the water table drops below the streambed in any part of the area, ground-water discharge to streams will cease in that area. Based on the calculated volumes of water in storage, the volume of water remaining in storage as compared to the predevelopment volume is as follows: 90 percent in 1980, 83 percent in 1993, and 71 percent in 2020.

Idaho↗

Ecosystem-specific growth responses to climate pattern by a temperate freshwater fish

Somatic growth patterns among animal populations are maintained through complex processes that vary among ecosystems. Changes in growth patterns may be concomitant with changes in climate; however, understanding how growth will manifest among ecosystems is limited. Information embedded within fish hard-parts (i.e., otoliths, spines, vertebrae) can account for variation in growth patterns resulting from changing climate conditions. Channel catfish Ictalurus punctatus is a freshwater fish species widely distributed across North America with limited information regarding climate influences on growth and differences in climate-growth relations among ecological systems. We assessed growth (total length) response to changing climate conditions for channel catfish among three waterbody types—pit lakes, irrigation and power-generation reservoirs, and flood-control reservoirs in Nebraska, USA. We used linear mixed-effect models and an information theoretic approach to assess the relative strengths among competing hypotheses. The most supported linear mixed-effect model of channel catfish growth was a function of fish age and an interaction between waterbody type and growing-degree-day (GDD). A positive trend existed in GDD from 1990 through 2008 whereby the predicted increase in GDD among waterbody types ranged from 182 GDD to 189 GDD. The predicted change in channel catfish growth resulting from increased GDD ranged from 1% to 39% among waterbody types. Channel catfish population rate functions, thus, may not respond similarly to climate conditions across ecosystem types. Changes in climate variables may contribute to system-specific responses in population dynamics for channel catfish as well as other similar freshwater species. The establishment of relations between climate and growth variables for a freshwater generalist with a plastic diet and broad temperature tolerance serves as an indication of the breadth of responses possible for freshwater fishes under global changes in climate conditions.

Nebraska↗

Saltwater in shallow aquifers in east-central and northeastern Louisiana and southeastern Arkansas

The chemistry of water from irrigation and monitor wells in east-central Louisiana indicates the presence of saltwater in the Mississippi River alluvial aquifer and the uppermost part of the Jasper aquifer system. The salinity of this groundwater makes it unsuitable for use in irrigation of salt-sensitive crops. The geochemistry of bromide (Br) and chloride (Cl) ions and strontium (Sr) isotopes indicated that this saltwater could have originated from the mixing of freshwater with briny water originating from the Carrizo-Wilcox aquifer at altitudes from 5,800 to 6,800 feet below sea level. However, in the absence of data on the concentrations of Br and Cl ions and the values of (87)Sr/(86)Sr in water from the Catahoula, Cockfield, and Sparta aquifers within the study area, no conclusive statement can be made on the origin of saltwater in the alluvial aquifer and the uppermost part of the Jasper aquifer system. Analyses of water from irrigation wells in northeastern Louisiana and southeastern Arkansas indicated the presence of saltwater in the Mississippi River alluvial aquifer. Saltwater probably moves from southern Chicot County, Arkansas, into northeastern Louisiana by flowing to the southwest along a fluvial channel eroded into the Cockfield Formation. Saltwater in the Mississippi River alluvial aquifer in northeastern Louisiana and southeastern Arkansas can be hazardous to salt-sensitive crops, such as rice, when used for irrigation. The geochemistry of Br and Cl ions indicated that saltwater in the Mississippi River alluvial aquifer of southern Chicot County in southeastern Arkansas has two geochemically distinct sources. One source, which has Br/Cl ratios less than that of modern seawater, could be derived from saltwater present in aquifers of Tertiary age; this saltwater could enter the alluvial aquifer by upward flow from below as part of the natural regional groundwater flow pattern. The other source, which has Br/Cl ratios greater than that of modern sea- water, could be derived, in part, from briny water present in the Smackover Formation at altitudes from 5,500 to 6,500 feet below sea level. This briny water could enter the alluvial aquifer by upward migration along a fault that penetrates from near land surface into the Smackover Formation.

Open-File Report↗

Recharge, movement, and discharge in the Edwards Limestone Reservoir, Texas

The Edwards limestone of Lower Cretaceous age is the principal water‐bearing formation in a belt 5 to 25 miles wide that extends from Austin southwest to San Antonio and thence west through Uvalde and Del Rio to Comstock, a distance of about 250 miles (see Fig. 1). Throughout this belt it supplies water to wells for stock, industrial, irrigation, and municipal use and to a series of fault‐springs, some of which are among the largest in the United States. These springs have played an important part in the economic and cultural development of Texas. In 1718 the Spaniards stationed a department of light infantry near the springs at San Antonio and soon after established missions and constructed elaborate systems of canals for irrigating considerable areas. After the winning of Texas' independence large numbers of settlers moved into the area. This influx was greatly accelerated following the admission of Texas to the Federal Union and towns were soon established near all of the major springs. However, it was not until about 1880 that the rapid development of the Edwards limestone aquifer by wells was begun.

Texas↗

Geologic Map of the Edwards Aquifer In Northern Medina and Northeastern Uvalde Counties, South-central Texas

The southern segment of the Edwards aquifer in south-central Texas is one of the most productive subsurface reservoirs of potable water in the world, providing water of excellent quality to more than a million people in the San Antonio region, where the Environmental Protection Agency (EPA) has declared it to be a sole-source aquifer (van der Leeden and others, 1990). Depending on the depositional province within which the associated carbonate rocks originated (Maclay and Small, 1984), the Edwards aquifer is composed of several geologic formations (primarily limestone and dolostone) of Early Cretaceous age. Most water pumped from the Edwards aquifer comes form the Person and Kainer Formations, which were deposited over the San Marcos Platform. The principal source of ground water in study area is the Devils River Formation, which was deposited in the Devils River trend. The Devils River Formation provides large quantities of irrigation water to fertile bottomland areas of Medina and Uvalde Counties, where the success of farming and ranching activities has long depended upon water from the Edwards aquifer. The study area includes all of the Edwards aquifer recharge zone between the Sabinal River (on the west) and the Medina River (on the east) plus an updip fringe of the confined zone in east-central Uvalde and central Medina Counties. Over about ninety percent of the study area--within the Devils River trend--the Edwards aquifer is composed of the Georgetown Formation plus the underlying Devils River Formation. Over the remaining area--over the southwestern margin of the San Marcos platform--the Edwards aquifer consists of the Georgetown Formation plus the underlying Edwards Group (Rose, 1972), which comprises the Kainer and Person Formations.

Open-File Report↗