Search USGSSearch

SEARCH · Search USGS

Results for “Health Physics”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10Linked to original sources

Status and understanding of groundwater quality in the Santa Clara River Valley, 2007-California GAMA Priority Basin Project

Groundwater quality in the approximately 460-square-mile Santa Clara River Valley study unit was investigated from April through June 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. The Santa Clara River Valley study unit contains eight groundwater basins located in Ventura and Los Angeles Counties and is within the Transverse and Selected Peninsular Ranges hydrogeologic province. The Santa Clara River Valley study unit was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected in 2007 by the USGS from 42 wells on a spatially distributed grid, and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined as that part of the aquifer system corresponding to the perforation intervals of wells listed in the CDPH database for the Santa Clara River Valley study unit. The quality of groundwater in the primary aquifer system may differ from that in shallow or deep water-bearing zones; for example, shallow groundwater may be more vulnerable to surficial contamination. Eleven additional wells were sampled by the USGS to improve understanding of factors affecting water quality.The status assessment of the quality of the groundwater used data from samples analyzed for anthropogenic constituents, such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of untreated groundwater resources in the primary aquifers of the Santa Clara River Valley study unit, not the quality of treated drinking water delivered to consumers. Relative-concentrations (sample concentration divided by health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (greater than 1.0); moderate (greater than 0.1 and less than or equal to 1.0); and low (less than or equal to 0.1). For inorganic constituents, relative-concentrations were classified as high (greater than 1.0); moderate (greater than 0.5 and less than or equal to 1.0); and low (less than or equal to 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the areal percentage of the primary aquifer system with relative-concentrations greater than 1.0. Moderate and low aquifer-scale proportions are defined as the areal percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches, grid-based and spatially weighted, were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the Santa Clara River Valley study unit (within 90 percent confidence intervals). The status assessment showed that inorganic constituents were more prevalent and relative-concentrations were higher than for organic constituents. For inorganic constituents with human-health benchmarks, relative-concentrations (of one or more constituents) were high in 21 percent of the primary aquifer system areally, moderate in 30 percent, and low or not detected in 49 percent. Inorganic constituents with human-health benchmarks with high aquifer-scale proportions were nitrate (15 percent of the primary aquifer system), gross alpha radioactivity (14 percent), vanadium (3.4 percent), boron (3.2 percent), and arsenic (2.3 percent). For inorganic constituents with aesthetic benchmarks, relative-concentrations (of one or more constituents) were high in 54 percent of the primary aquifer system, moderate in 41 percent, and low or not detected in 4 percent. The inorganic constituents with aesthetic benchmarks with high aquifer-scale proportions were total dissolved solids (35 percent), sulfate (22 percent), manganese (38 percent), and iron (22 percent). In contrast, the results of the status assessment for organic constituents with human-health benchmarks showed that relative-concentrations were high in 0 percent (not detected above benchmarks) of the primary aquifer system, moderate in 2.4 percent, and low or not detected in 97 percent. Relative-concentrations of the special interest constituent, perchlorate, were moderate in 12 percent of the primary aquifer system and low or not detected in 88 percent. Relative-concentrations of two VOCs-carbon tetrachloride and trichloroethene (TCE)-were moderate in 2.4 percent of the primary aquifer system. One VOC-chloroform (water disinfection byproduct)-was detected in more than 10 percent of the primary aquifer system but at low relative-concentrations. Of the 88 VOCs and gasoline oxygenates analyzed, 71 were not detected. Pesticides were low or not detected in 100 percent of the primary aquifer system. Of the 118 pesticides and pesticide degradates analyzed, 13 were detected and 5 of those had human-health benchmarks. Two of these five pesticides-simazine and atrazine-were detected in more than 10 percent of the primary aquifer system. The second component of this study, the understanding assessment, was to identify the natural and human factors that affect groundwater quality on the basis of the evaluation of land use, physical characteristics of the wells, and geochemical conditions of the aquifer. Results from these analyses are used to explain the occurrence and distribution of selected constituents in the primary aquifer system of the Santa Clara River Valley study unit. The understanding assessment indicated that water quality varied spatially primarily in relation to depth, groundwater age, reduction-oxidation conditions, pH, and location in the regional groundwater flow system. High and moderate relative-concentrations of nitrate and low relative-concentrations of pesticides were correlated with shallow depths to top-of-perforation, and with high dissolved oxygen. Groundwater of modern and mixed ages had higher nitrate than pre-modern-age groundwater. Decreases in concentrations of total dissolved solids (TDS) and sulfate were correlated with increases in pH. This relationship probably indicates relations of these constituents with increasing depth across most of the Santa Clara River Valley study unit. Previous studies have indicated multiple sources of high concentrations of TDS and sulfate and multiple geochemical processes affecting these constituents in the Santa Clara River Valley study unit. Manganese and iron concentrations were highest in pre-modern-age groundwater at depth and in the downgradient area of the Santa Clara River Valley study unit (closest to the coastline), indicating the prevalence of reducing groundwater conditions in these aquifer zones.

Scientific Investigations Report

Vision for a worldwide fluvial-sediment information network

The nations of the world suffer both from the deleterious effects of some natural and human-altered fluxes of fluvial sediment and a lack of consistent and reliable information on the temporal and spatial occurrence of fluvial sediments. Decades ago, this difficulty was unavoidable due to a lack of understanding of the magnitude and scope of environmental influences exerted by fluvial sediment coupled with a dearth of tools for monitoring and studying the data. Such is no longer the case. Fluvial sediment has a broad influence on the environment and humanity. Data needs that were once limited primarily to reservoir and channel maintenance now include issues associated with public water supply; contaminated sediment management; productivity of agricultural lands; stream restoration and watershed health; in-stream biotic stability; post-wildfire channel morphology; dam decommissioning, rehabilitation, or removal; and legal requirements for sediment management (Gray and Glysson, 2005). The adverse effects of poorly managed or unmanaged sediment movement related to these and other issues are well-known qualitatively, and in some cases quantitatively. For example, physical, chemical, and biological damages attributable to fluvial sediment in North America alone are now estimated to range between $20 billion and $50 billion annually (Pimental and others, 1995; Osterkamp and others, 1998; 2004). Capabilities for monitoring, analyzing, storing, and sharing fluvial-sediment data have been developed and, in many cases, are sufficiently mature for consideration for global utilization. Hence, there is not only a strong and expanding need for a global effort to gauge and understand fluvial-sediment characteristics and processes better, but the knowledge and tools to achieve these ends are largely available and ready for their applicability to be evaluated. Given the increasing importance of erosion and sediment processes for water-resources management, an International Sedimentation Initiative (ISI, 2007a), under the United Nations Educational, Scientific, and Cultural Organization’s International Hydrologic Programme (IHP, 2007) was adopted in 2004. The ISI, the focus of which is on sustainable water-resources management on the global scale, features six major activities and projects, which are listed as part of the section entitled, “Relation of the WoFSIN concept to the thrusts of the International Sedimentation Initiative,” that precedes the “Conclusions” section of this paper. Based on the need for more, and more consistent and reliable fluvial-sediment information and on the existence of the ISI and other international and national sediment programs, we envision the need for a Worldwide Fluvial Sediment-Information Network (WoFSIN) with a focus on data acquisition, storage, and dissemination globally. Envisioned components of a WoFSIN, administered largely via the Internet and relying mostly on the benefits derived from existing resources and programs, follow that summary. The goal of the WoFSIN is to maximize the availability and usefulness of the world’s historical and current fluvial-sediment and ancillary data through collaboration with existing programs so as to require few additional resources in the long-term. Thus, the WoFSIN concept was developed recognizing that informed resource management is predicated on the availability of adequate and reliable information. The WoFSIN is described in the ensuing sections in stand-alone fashion, followed by a section that describes the complementary aspects of the WoFSIN and the International Sediment Initiative. Thus, our first objective is to describe the fundamental components of a WoFSIN. Our second objective is to identify overlap or gaps between the WoFSIN and ISI concepts that might be useful in refining the ISI’s ability to meet its global mission to develop decision support for sediment management at the global scale more fully, cost-effectively, and (or) with enhanced quality.

Conference Paper

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin — Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

As part of a national analysis of the effects of land use on ground-water quality for the National Water-Quality Assessment Program, the U.S. Geological Survey sampled wells along a flow system in surficial glacial aquifers in the northwestern part of the Twin Cities metropolitan area during 1997 and 1998. In addition, a reconnaissance steady-state ground-water model was developed to estimate flowpaths and dates of ground-water recharge using a particle-tracking routine. Sediment samples collected during drilling had high horizontal hydraulic conductivities (ranging from about 3.1 to about 190 feet per day, based on sediment-size analysis of well cuttings), small organic carbon concentrations (ranging from less than 0.2 to 160 grams per kilogram), and pH values that were mostly alkaline (ranging from 4.9 to 8.2). Water samples were analyzed for physical properties, major ions, iron, manganese, nutrients, organic carbon, radon, pesticides, volatile organic compounds (VOCs), chlorofluorocarbons, tritium, and isotopes of nitrogen, hydrogen, and oxygen. Most of the water samples had small dissolved-oxygen concentrations (less than 1 milligram per liter). Calcium, magnesium, sodium, bicarbonate, sulfate, and chloride were the primary dissolved constituents in water samples. Nitrite plus nitrate as nitrogen (nitrate) concentrations were less than the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level of 10 mg/L. Nitrogen isotope ratios indicated that the sources of nitrate primarily were soils, animal waste, or denitrification that increased nitrogen isotope ratios in nitrate. Small concentrations of pesticides were detected in the shallow parts of the aquifer. The herbicide prometon was the most frequently detected pesticide. Herbicides applied to control grasses and weeds in corn (atrazine, simazine, and metolachlor) also were frequently detected in water samples. All pesticide and VOCs detected were below USEPA Maximum Contaminant Levels or Health Advisory Limits. Chlorofluorocarbon compounds and tritium concentrations were used to estimate dates of recharge of ground-water samples. In general, shallower ground-water samples were more recently recharged although most water sampled from the aquifer was recharged after 1955. Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Minnesota

Eutrophication saturates surface elevation change potential in tidal mangrove forests

Coastal mangrove forests are at risk of being submerged due to sea-level rise (SLR). However, mangroves have persisted with changing sea levels due to a variety of biotic and physical feedback mechanisms that allow them to gain and maintain relative soil surface elevation. Therefore, mangrove’s resilience to SLR is dependent upon their ability to build soil elevation at a rate that tracks with SLR, or well-enough to migrate inland. Anthropogenic disturbances, such as altered hydrology and eutrophication, can degrade mangrove forest health and compromise this land building process, placing mangroves at greater risk. Much of Florida’s mangroves are adjacent to highly urbanized areas that produce nutrient-loaded runoff. This study assesses how experimental nutrient inputs in the eutrophic Caloosahatchee Estuary influence the soil surface elevation change (SEC) in two distinct mangrove zones. Annual rates of SEC were reduced by phosphorus additions and differed by mangrove zone, ranging from 0.67 ± 0.59 to 2.13 ± 0.61 and 4.21 ± 0.58 to 6.39 ± 0.59 mm year −1 in the fringe and basin zone, respectively. This suggests that eutrophication can reduce the maximum potential SEC response to SLR and that a mangrove forest’s vulnerability to SLR is not uniform throughout forest but can differ by mangrove zone.

Estuaries and Coasts

Shallow groundwater quality in the Village of Patchogue, Suffolk County, New York

The onsite disposal of wastewater within the Patchogue River Basin-a riverine estuary that discharges into Great South Bay, Suffolk County, Long Island, N.Y. -has adversely affected water quality and aquatic habitats within both the tidal and non-tidal portions of the river. In response to increased development within the approximately 14 square mile basin, the Village of Patchogue has expanded efforts to manage and protect the local groundwater resources, which sustain freshwater base flow and aquatic habitats. Water-quality samples from 10 shallow wells within the Village were collected in March 2009, before the start of seasonal fertilizer application, to document the effects of onsite wastewater disposal on groundwater discharging into the Patchogue River. Each sample was analyzed for physical properties (pH, dissolved oxygen, specific conductance, and temperature), nutrients, organic carbon, major ions, and trace elements. Water samples from eight wells were analyzed for stable isotopes of nitrogen. The nitrate concentration in one well was 40 milligrams per liter (mg/L), which exceeded the U.S. Environmental Protection Agency (USEPA) and New York State Department of Health (NYSDOH) maximum contamination level in drinking water of 10 mg/L. Sodium concentrations at nine wells exceeded the USEPA Drinking Water Advisory Taste Threshold of 60 mg/L. Dissolved iron concentrations at three wells exceeded the NYSDOH and USEPA Secondary Drinking Water Standard of 300 micrograms per liter (?g/L). Nitrogen isotope signatures (d15N) were determined and compared with those reported from previous studies in Nassau and Suffolk Counties to identify possible sources of the nitrate. Local variations in measured ammonia, nitrate, total nitrogen, phosphorus, and organic carbon concentrations and d15N signatures indicate that nitrate enters the surficial aquifer from several sources (fertilizer, septic waste, and animal waste) and reflects biogeochemical processes such as denitrification.

Scientific Investigations Report

Statistical analysis of lake levels and field study of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015: Chapter A of Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

Water levels declined from 2003 to 2011 in many lakes in Ramsey and Washington Counties in the northeast Twin Cities Metropolitan Area, Minnesota; however, water levels in other northeast Twin Cities Metropolitan Area lakes increased during the same period. Groundwater and surface-water exchanges can be important in determining lake levels where these exchanges are an important component of the water budget of a lake. An understanding of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area has been limited by the lack of hydrologic data. The U.S. Geological Survey, in cooperation with the Metropolitan Council and Minnesota Department of Health, completed a field and statistical study assessing lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes. This report documents the analysis of collected hydrologic, water-quality, and geophysical data; and existing hydrologic and geologic data to (1) assess the effect of physical setting and climate on lake-level fluctuations of selected lakes, (2) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (3) estimate general ages for waters extracted from the wells, and (4) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Statistical analyses of lake levels during short-term (2002–10) and long-term (1925–2014) periods were completed to help understand lake-level changes across the northeast Twin Cities Metropolitan Area. Comparison of 2002–10 lake levels to several landscape and geologic characteristics explained variability in lake-level changes for 96 northeast Twin Cities Metropolitan Area lakes. Application of several statistical methods determined that (1) closed-basin lakes (without an active outlet) had larger lake-level declines than flow-through lakes with an outlet; (2) closed-basin lake-level changes reflected groundwater-level changes in the Quaternary, Prairie du Chien, and Jordan aquifers; (3) the installation of outlet-control structures, such as culverts and weirs, resulted in smaller multiyear lake-level changes than lakes without outlet-control structures; (4) water levels in lakes primarily overlying Superior Lobe deposits were significantly more variable than lakes primarily overlying Des Moines Lobe deposits; (5) lake-level declines were larger with increasing mean lake-level elevation; and (6) the frequency of some of these characteristics varies by landscape position. Flow-through lakes and lakes with outlet-control structures were more common in watersheds with more than 50 percent urban development compared to watersheds with less than 50 percent urban development. A comparison of two 35-year periods during 1925–2014 revealed that variability of annual mean lake levels in flow-through lakes increased when annual precipitation totals were more variable, whereas variability of annual mean lake levels in closed-basin lakes had the opposite pattern, being more variable when annual precipitation totals were less variable. Oxygen-18/oxygen-16 and hydrogen-2/hydrogen-1 ratios for water samples from 40 wells indicated the well water was a mixture of surface water and groundwater in 31 wells, whereas ratios from water sampled from 9 other wells indicated that water from these wells receive no surface-water contribution. Of the 31 wells with a mixture of surface water and groundwater, 11 were downgradient from White Bear Lake, likely receiving water from deeper parts of the lake. Age dating of water samples from wells indicated that the age of water in the Prairie du Chien and Jordan aquifers can vary widely across the northeast Twin Cities Metropolitan Area. Estimated ages of recharge for 9 of the 40 wells sampled for chlorofluorocarbon concentrations ranged widely from the early 1940s to mid-1970s. The wide range in estimated ages of recharge may have resulted from the wide range in the open-interval lengths and depths for the wells. Results from stable isotope analyses of water samples, lake-sediment coring, continuous seismic-reflection profiling, and water-level and flow monitoring indicated that there is groundwater inflow from nearshore sites and lake-water outflow from deep-water sites in White Bear Lake. Continuous seismic-reflection profiling indicated that deep sections of White Bear, Pleasant, Turtle, and Big Marine Lakes have few trapped gases and little organic material, which indicates where groundwater and lake-water exchanges are more likely. Water-level differences between White Bear Lake and piezometer and seepage measurements in deep waters of the lake indicate that groundwater and lake-water exchange is happening in deep waters, predominantly downgradient from the lake and into the lake sediment. Seepage fluxes measured in the nearshore sites of White Bear Lake generally were higher than seepage fluxes measured in the deep-water sites, which indicates that groundwater-inflow rates at most of the nearshore sites are higher than lake-water outflow from the deep-water sites.

Minnesota

Microbiological Water Quality in Relation to Water-Contact Recreation, Cuyahoga River, Cuyahoga Valley National Park, Ohio, 2000 and 2002

The microbiological water quality of a 23-mile segment of the Cuyahoga River within the Cuyahoga Valley National Park was examined in this study. This segment of the river receives discharges of contaminated water from stormwater, combined-sewer overflows, and incompletely disinfected wastewater. Frequent exceedances of Ohio microbiological water-quality standards result in a health risk to the public who use the river for water-contact recreation. Water samples were collected during the recreational season of May through October at four sites on the Cuyahoga River in 2000, at three sites on the river in 2002, and from the effluent of the Akron Water Pollution Control Station (WPCS) both years. The samples were collected over a similar range in streamflow in 2000 and 2002. Samples were analyzed for physical and chemical constituents, as well as the following microbiological indicators and pathogenic organisms: Escherichia coli (E. coli), Salmonella, F-specific and somatic coliphage, enterovirus, infectious enterovirus, hepatitis A virus, Clostridium perfringens (C. perfringens), Cryptosporidium, and Giardia. The relations of the microorganisms to each other and to selected water-quality measures were examined. All microorganisms analyzed for, except Cryptosporidium, were detected at least once at each sampling site. Concentrations of E. coli exceeded the Ohio primary-contact recreational standard (298 colonies per 100 milliliters) in approximately 87 percent of the river samples and generally were higher in the river samples than in the effluent samples. C. perfringens concentrations were positively and significantly correlated with E. coli concentrations in the river samples and generally were higher in the effluent samples than in the river samples. Several of the river samples that met the Ohio E. coli secondary-contact recreational standard (576 colonies per 100 milliliters) had detections of enterovirus, infectious enterovirus, hepatitis A virus, and Salmonella, indicating that there are still risks even when the E. coli standard is not exceeded. River samples in which the secondary-contact recreational standard for E. coli was exceeded showed a higher percentage of the co-occurrence of pathogenic organisms than samples that met the standard. This indicates that in this study area, E. coli is a useful indicator of human health risk. Detections of hepatitis A virus tended to be associated with higher median concentrations of somatic coliphage, F-specific coliphage, and infectious enterovirus. In addition, geometric mean C. perfringens concentrations tended to be higher in samples where hepatitis A virus was present than in samples where hepatitis A virus was absent. Hepatitis A virus was not detected in samples collected upstream from the Akron WPCS; all downstream detections had coincident detections in the Akron WPCS effluent, suggesting that Akron WPCS was a principal source of hepatitis A virus at the downstream sites. Geometric mean concentrations of E. coli were calculated on the basis of analytical results from at least five samples collected at each river site during May, July, and September of 2000. In each case, the Ohio geometric-mean primary-contact recreational standard of 126 col/100 mL was exceeded. E. coli concentrations were significantly correlated with streamflow and increased with streamflow at sites upstream and downstream from the Akron WPCS. This indicates that E. coli loads from sources upstream from the Akron WPCS have the potential to appreciably influence the frequency of attainment of recreational water-quality standards at downstream locations.

Water-Resources Investigations Report

Linear regression model documentation and updates for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River, Kansas, July 2012 through September 2019

The Kansas River provides drinking water to about 800,000 people in northeastern Kansas. Water-treatment facilities that use the Kansas River as a water-supply source use chemical and physical processes during water treatment to remove contaminants before public distribution. Advanced notification of changing water-quality conditions near water-supply intakes allows water-treatment facilities to proactively adjust treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, and Johnson County WaterOne, collected water-quality data at the Kansas River at Wamego (USGS site 06887500; hereafter referred to as the “Wamego site”) and De Soto (USGS site 06892350; hereafter referred to as the “De Soto site”) monitoring sites to update previously published regression models relating continuous water-quality sensor measurements, streamflow, and seasonal components to discretely sampled water-quality constituent concentrations or densities. Linear regression analysis was used to update and develop models for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and fecal indicator bacteria at the Wamego and De Soto monitoring sites using data collected during July 2012 through September 2019. The water-quality information documented in this report can be used as guidance for water-treatment processes and to characterize changes in water-quality conditions in the Kansas River over time that would not be otherwise possible.

Kansas

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in and near Walker River Indian Reservation, Nevada 1994-95

A study was begun in 1994 to determine whether the quality of irrigation drainage from the Walker River Indian Reservation, Nevada, has caused or has potential to cause harmful effects on human health or on fish and wildlife, or may adversely affect the suitability of the Walker River for other beneficial uses. Samples of water, bottom sediment, and biota were collected during June-August 1994 (during a drought year) from sites upstream from and on the Walker River Indian Reservation for analyses of trace elements. Other analyses included physical characteristics, major dissolved constituents, selected species of water-soluble nitrogen and phosphorus, and selected pesticides in bottom sediment. Water samples were collected again from four sites on the Reservation in August 1995 (during a wetterthan- average year) to provide data for comparing extreme climatic conditions. Water samples collected from the Walker River Indian Reservation in 1994 equaled or exceeded the Nevada water-quality standard or level of concern for at least one of the following: water temperature, pH, dissolved solids, unionized ammonia, phosphate, arsenic, boron, chromium, lead, and molybdenum; in 1995, only a single sample from one site exceeded a Nevada water-quality standard for molybdenum. Levels of concern for trace elements in bottom sediment collected in 1994 were equaled or exceeded for arsenic, iron, manganese, and zinc. Concentrations of organochiorine pesticide residues in bottom sediment were below analytical reporting limits. Levels of concern for trace-elements in samples of biota were equaled or exceeded for arsenic, boron, copper, and mercury. Results of toxicity testing indicate that only water samples from Walker Lake caused a toxic response in test bacteria. Arsenic and boron concentrations in water, bottom sediment, and biological tissue exceeded levels of concern throughout the Walker River Basin, but most commonly in the lower Walker River Basin. Mercury also was elevated in several biological samples collected throughout the Basin, although concentrations in water and bottom sediment were below analytical reporting limits. Sources of arsenic, boron, and mercury in the Basin are uncertain, but ambient levels reported for a variety of sample matrices collected from western Nevada generally exceed ranges cited as natural background levels. Because these potentially toxic constituents exceeded concern levels in areas that do not directly receive irrigation drainage, concentrations measured in samples collected for this study may not necessarily be attributable to agricultural activities. Diversion of river water for irrigation may have greater effects on beneficial uses of water and on fish and wildlife than does drainage from agricultural areas on the Reservation. In 1994, agricultural water consumption precluded dilution of ground-water seepage to the river channel. This resulted in concentrations of potentially toxic solutes that exceeded levels of concern. Diversion of irrigation water also may have facilitated leaching of potentially toxic solutes from irrigated soil on the Reservation, but during this study all water applied for irrigation on the Reservation was either consumed by evapotranspiration or infiltrated to recharge shallow ground water. No irrigation drainage was found on the Reservation during this study. However, because 1994 samples of ground-water seepage to the Walker River channel exceeded at least six Nevada waterquality standards, water-quality problems may result should ground-water levels rise enough to cause ground-water discharge to the agricultural drain on the Reservation. Nevertheless, the potential for adverse effects from irrigation drainage on the Reservation is believed to be small because surface-water rights for the Walker River Indian Reservation amount to only 2 percent of total surface- water rights in the entire Walker River Basin.

California, Nevada

Modeling functional flows in California rivers

Environmental flows are critical to the recovery and conservation of freshwater ecosystems worldwide. However, estimating desired ranges of environmental flows across large, diverse landscapes is challenging. To advance protections of environmental flows for streams in California, USA, we developed a statewide modeling approach focused on functional components of the natural flow regime. Functional flow components in California streams—fall pulse flows, wet season peak flows and base flows, the spring flow recession, and dry season baseflows—support essential physical and ecological processes in riverine ecosystems. These functional flow components can be represented by functional flow metrics (FFMs) and quantified by their magnitude, timing, frequency, duration, and rate-of-change from daily streamflow records. After quantifying FFMs at reference-quality streamflow gages in California, we used machine-learning methods to estimate their natural range of values for all stream reaches in the state based on physical watershed characteristics and climatic factors. We found that the models performed well in predicting FFMs in streams across a diversity of landscape and climate contexts, according to several model performance criteria. Using the predicted FFM values, we established initial estimates of ecological flows that are expected to support critical functions and are broadly protective of ecosystem health. Modeling functional flows statewide offers a pathway for increasing the pace and scale of environmental flow protections in California and beyond.

California

Characterization of water quality, biology, and habitat of the Pearl River and selected tributaries contiguous to and within Tribal lands of the Pearl River Community of the Mississippi Band of Choctaw Indians, 2017–18

The U.S. Geological Survey, in cooperation with the Mississippi Band of Choctaw Indians (MBCI), conducted a baseline assessment of the physical, chemical, and biological quality of selected streams and rivers within and contiguous to the Pearl River Community (PRC) in 2017 and 2018. The MBCI is a federally recognized tribe with territories in Mississippi and Tennessee. MBCI Tribal government and communities have sovereign authority over their natural resources and are responsible for protecting the quality of waters within the Tribal lands from sources of pollution and restoring impaired waters. The quality of these surface waters has a profound effect upon the health and welfare of MBCI Tribal members. Data generated from this study may be used with other relevant water-quality data for comparison and development of Tribal water-quality standards. The PRC territory is drained by the Pearl River and associated tributaries. Water-quality and biological samples were collected and habitat surveys were conducted at sites on the mainstem of the Pearl River and major tributaries of the Pearl River—Wolf Creek, Beasha Creek, Jones Creek, and Kentawka Creek. The selected stream sites represent a range of land use/land cover and potential sources of alteration and contamination from within their respective drainage areas. In particular, Wolf Creek watershed has the highest relative percentage of developed land. Ambient physicochemical properties, major ions, nutrients, and organic wastewater compounds (OWCs) were analyzed quarterly from surface-water samples from October 2017 through August 2018. Physicochemical properties were also measured in June 2018 over a continuous 48-hour period. Trace elements and polycyclic aromatic hydrocarbons were analyzed from streambed sediments in August 2018. Biological samples included the collection of periphyton algae (August 2018), benthic macroinvertebrate (March 2017 and March 2018), and fish communities (April 2018). Physical stream habitat characteristics were assessed using qualitative (March 2017 and March 2018) and quantitative surveys (August 2018). While not directly applicable, the State of Mississippi Water Quality Standards were used as reference to evaluate Tribal water quality. Physicochemical water-quality constituents—water temperature, specific conductance (SC), pH, and dissolved oxygen (DO)—were generally within natural ranges among sites and samples, with a few exceptions that exceeded existing Mississippi water-quality standards. pH and DO periodically were below the minimum State standards at some sampled sites. Specific conductance was also relatively high at both Wolf Creek sites but did not exceed the existing maximum standard for recreational waters. The surface water among stream sites was predominantly calcium bicarbonate type, with a shift toward sodium-bicarbonate water type at the downstream Wolf Creek (Wolf DS) site. Major ion concentrations were generally highest at the Wolf Creek sites. Nutrient concentrations were also often highest at Wolf DS, but total nitrogen and total phosphorus periodically exceeded recommended State and Federal nutrient criteria thresholds among most sampled sites. Twenty-nine OWCs, including 10 known or suspected endocrine disruptors, were detected among sites. Concentrations of OWCs were relatively low, and only 19 percent of all detections were above the reporting level. Concentrations of copper and nickel in streambed sediments were detected above consensus-based threshold-effect concentrations (TECs) at one site each, and arsenic and chromium exceeded TECs at most sites. Concentrations of all polycyclic aromatic hydrocarbons in streambed sediments were low and well below TECs at all sites. The periphyton, macroinvertebrate, and fish communities at most sampled sites appear typical of central Mississippi streams; however, the diversity, composition, and abundance of taxa sampled from Wolf DS were particularly distinctive compared to other sampled stream sites. Periphyton taxa richness was low at both Wolf Creek sites, and both sites had greater abundances of diatom taxa, which are indicative of high nutrient concentrations, than of soft-algae taxa. Similarly, Wolf DS had relatively low macroinvertebrate diversity, the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa, a high abundance of Tubificid taxa, and the lowest overall Mississippi-Benthic Index of Stream Quality score. Fish species richness was also relatively low at Wolf DS compared to some other sampled sites. Habitat characteristics also appeared to be generally typical of most central Mississippi streams. Qualitative habitat assessment scores were at or above the regional least disturbed streams for Wolf DS, the upstream Wolf Creek (Wolf US) site, and Jones Creek. Habitat scores among the remaining sites indicate fair conditions. Quantitative and qualitative habitat characteristics indicate relatively lower habitat quality at the two Beasha Creek sites.

Mississippi

Occurrence, distribution and transport of pesticides into the Salton Sea Basin, California, 2001-2002

The Salton Sea is a hypersaline lake located in southeastern California. Concerns over the ecological impacts of sediment quality and potential human exposure to dust emissions from exposed lakebed sediments resulting from anticipated shrinking of shoreline led to a study of pesticide distribution and transport within the Salton Sea Basin, California, in 2001-2002. Three sampling stations-upriver, river mouth, and offshore-were established along each of the three major rivers that discharge into the Salton Sea. Large-volume water samples were collected for analysis of pesticides in water and suspended sediments at the nine sampling stations. Samples of the bottom sediment were also collected at each site for pesticide analysis. Sampling occurred in October 2001, March-April 2002, and October 2002, coinciding with the regional fall and spring peaks in pesticide use in the heavily agricultural watershed. Fourteen current-use pesticides were detected in water and the majority of dissolved concentrations ranged from the limits of detection to 151 ng/l. Diazinon, EPTC and malathion were detected at much higher concentrations (940-3,830 ng/l) at the New and Alamo River upriver and near-shore stations. Concentrations of carbaryl, dacthal, diazinon, and EPTC were higher in the two fall sampling periods, whereas concentrations of atrazine, carbofuran, and trifluralin were higher during the spring, which matched seasonal use patterns of these pesticides. Current-use pesticides were also detected on suspended and bed sediments in concentrations ranging from detection limits to 106 ng/g. Chlorpyrifos, dacthal, EPTC, trifluralin, and DDE were the most frequently detected pesticides on sediments from all three rivers. The number of detections and concentrations of suspended sediment-associated pesticides were often similar for the river upriver and near-shore sites, consistent with downstream transport of pesticides via suspended sediment. While detectable suspended sediment pesticide concentrations were more sporadic than detected aqueous concentrations, seasonal trends were similar to those for dissolved concentrations. Generally, the pesticides detected on suspended sediments were the same as those on the bed sediments, and concentrations were similar, especially at the Alamo River upriver site. With a few exceptions, pesticides were not detected in suspended or bed sediments from the off-shore sites. The partitioning of pesticides between water and sediment was not predictable from solely the physical-chemical properties of individual pesticide compounds, but appear to be a complicated function of the quantity of pesticide applied in the watershed, residence time of sediments in the water, and compound solubility and hydrophobicity. Sediment concentrations of most pesticides were found to be 100-1,000 times lower than the low-effects levels determined in human health risk assessment studies. However, maximum concentrations of chlorpyrifos on suspended sediments were approximately half the low-effects level, suggesting the need for further sediment characterization of lake sediments proximate to riverine inputs. ?? 2008 Springer Science+Business Media B.V.

Hydrobiologia

Global volcanic hazards and risk

An estimated 800 million people live within 100 km of an active volcano in 86 countries and additional overseas territories worldwide [see Chapter 4 and Appendix B]1. Volcanoes are compelling evidence that the Earth is a dynamic planet characterised by endless change and renewal. Humans have always found volcanic activity fascinating and have often chosen to live close to volcanoes, which commonly provide favourable environments for life. Volcanoes bring many benefits to society: eruptions fertilise soils; elevated topography provides good sites for infrastructure (e.g. telecommunications on elevated ground); water resources are commonly plentiful; volcano tourism can be lucrative; and volcanoes can acquire spiritual, aesthetic or religious significance. Some volcanoes are also associated with geothermal resources, making them a target for exploration and a potential energy resource. Much of the time volcanoes are not a threat because they erupt very infrequently or because communities have become resilient to frequently erupting volcanoes. However, there is an everpresent danger of a long-dormant volcano re-awakening or of volcanoes producing anomalously large or unexpected eruptions. Volcanic eruptions can cause loss of life and livelihoods in exposed communities, damage or disrupt critical infrastructure and add stress to already fragile environments. Their impacts can be both short-term, e.g. physical damage, and long-term, e.g. sustained or permanent displacement of populations. The risk from volcanic eruptions and their attendant hazards is often underestimated beyond areas within the immediate proximity of a volcano. For example, volcanic ash hazards can have effects hundreds of kilometres away from the vent and have an adverse impact on human and animal health, infrastructure, transport, agriculture and horticulture, the environment and economies. The products of volcanism and their impacts can extend beyond country borders, to be regional and even global in scale. Although known historical loss of life from volcanic eruptions (since 1600 AD about 280,000 fatalities are recorded, Auker et al. (2013)) is modest compared to other major natural hazards, volcanic eruptions can be catastrophic for exposed communities. In 1985 the town of Armero in Colombia was buried by lahars (volcanic mudflows) with more than 21,000 fatalities due to relatively small explosive eruptions at the summit of Nevado del Ruiz volcano that partially melted a glacier (Voight, 1990).

Book chapter

Occurrence of radium-224, radium-226 and radium-228 in water from the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands, southwestern and south-central New Jersey

This investigation is the first regionally focused study of the presence of natural radioactivity in water from the Vincentown and Wenonah-Mount Laurel aquifers, Englishtown aquifer system, and the Hornerstown and Red Bank Sands. Geologic materials composing the Vincentown and Wenonah-Mount Laurel aquifers and the Hornerstown and Red Bank Sands previously have been reported to contain radioactive (uranium-enriched) phosphatic strata, which is common in deposits from some moderate-depth coastal marine environments. The decay of uranium and thorium gives rise to natural radioactivity and numerous radioactive progeny, including isotopes of radium. Naturally occurring radioactive isotopes, especially those of radium, are of concern because radium is a known human carcinogen and ingestion (especially in water used for drinking) can present appreciable health risks. A regional network in southwestern and south-central New Jersey of 39 wells completed in the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands was sampled for determination of gross alpha-particle activity; concentrations of radium radionuclides, major ions, and selected trace elements; and physical properties. Concentrations of radium-224, radium-226, and radium-228 were determined for water from 28 of the 39 wells, whereas gross alpha-particle activity was determined for all 39. The alpha spectroscopic technique was used to determine concentrations of radium-224, which ranged from less than 0.5 to 2.7 pCi/L with a median concentration of less than 0.5pCi/L, and of radium-226, which ranged from less than 0.5 to 3.2 pCi/L with a median concentration of less than 0.5 pCi/L. The beta-counting technique was used to determine concentrations of radium-228. The concentration of radium-228 ranged from less than 0.5 to 4.3 pCi/L with a median of less than 0.5. Radium-228, when quantifiable, had the greatest concentration of the three radium radioisotopes in 9 of the 12 samples (75 percent). The concentration of radium-224 exceeded that of radium-226 in five of the six (83 percent) samples when both were quantifiable. The radium concentration distribution differed by aquifer, with the highest Ra-228 concentrations present in the Englishtown aquifer system and the highest Ra-226 concentrations present in the Wenonah-Mount Laurel aquifer. Radium-224 generally contributed a considerable amount of gross alpha-particle activity to water produced from all the sampled aquifers, but was not the dominant radionuclide as it is in water from the Kirkwood-Cohansey aquifer system, nor were concentrations greater than 1 pCi/L of radium-224 widespread. Gross alpha-particle activity was found to exceed the U.S Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 15 pCi/L in one sample (16 pCi/L) from the Vincentown aquifer. A greater part of the gross alpha-particle activity in water from the Wenonah-Mount Laurel aquifer resulted from the decay of Ra-226 than did the gross alpha-particle activity in the other sampled aquifers; this relation is consistent with the concentration distribution of the Ra-226 itself. Concentrations of radium-224 correlate strongly with those of both radium-226 and radium-228 (Spearman correlation coefficients, r, +0.86 and +0.66, respectively). The greatest concentrations of radium-224, radium-226, and radium-228 were present in the most acidic ground water. All radium-224, radium-226, and radium-228 concentrations greater than 2.5 pCi/L were present in ground-water samples with a pH less than 5.0. The presence of combined radium-226 and radium-228 concentrations greater than 5 pCi/L in samples from the Vincentown and Wenonah-Mount Laurel aquifers and the Englishtown aquifer system was not nearly as common as in samples from the Kirkwood-Cohansey aquifer system, likely because of the slightly higher pH of water from these aquifers relative to that of Kirkwood-Cohansey aqu

New Jersey

Assessment of hydrogeologic terrains, well-construction characteristics, groundwater hydraulics, and water-quality and microbial data for determination of surface-water-influenced groundwater supplies in West Virginia

In January 2014, a storage tank leaked, spilling a large quantity of 4-methylcyclohexane methanol into the Elk River in West Virginia and contaminating the water supply for more than 300,000 people. In response, the West Virginia Legislature passed Senate Bill 373, which requires the West Virginia Department of Health and Human Resources (WVDHHR) to assess the susceptibility and vulnerability of public surface-water-influenced groundwater supply sources (SWIGS) and surface-water intakes statewide. In response to this mandate for reassessing SWIGS statewide, the U.S. Geological Survey (USGS), in cooperation with the WVDHHR, Bureau of Public Health, Office of Environmental Health Services, compiled available data and summarized the results of previous groundwater studies to provide the WVDHHR with data that could be used as part of the process for assessing and determining SWIGS. Existing geologic, hydrologic, well-construction, water-quality, and other related data and information from previous U.S. Geological Survey (USGS) hydrogeologic studies and the USGS National Water Information System (NWIS) database, in conjunction with data from the West Virginia Bureau for Public Health (WVBPH) Department of Health and Human Resources (WVDHHR) and the West Virginia Department of Environmental Protection database and files, were collected, compiled, and analyzed to help the WVDHHR to better assess public groundwater supply wells that may meet the definition of a surface-water-influenced- groundwater supply (SWIGS). In this study, measures of intrinsic susceptibility, which are characterized by the physical properties that affect the ease with which water moves through the unsaturated zone and, subsequently, into the saturated zone within an aquifer, showed that karst limestone aquifers are the aquifers most intrinsically susceptible to contamination within the State of West Virginia. Karst limestone aquifers are present within Cambrian- and Ordovician-age formations within West Virginia’s eastern panhandle and in Mississippian-age limestones within the Greenbrier River valley. Solution development within these limestone aquifers allows rapid recharge and flow of groundwater within the aquifer, both of which allow surface contaminants to easily enter the aquifer and travel long distances in a short period of time. Alluvial aquifers bordering the Ohio River in western West Virginia are also potentially highly susceptible to contamination because these alluvial aquifers can receive significant recharge from the adjacent Ohio River. Any potential contaminants that may be present in the river have the potential to enter the aquifer and contaminate wells completed within the sand and gravel alluvial sediments within which the wells are completed. These same alluvial sediments, however, help to retard the movement of bacteria and other potentially pathogenic organisms, such as Cryptosporidia and Giardia lamblia , into the aquifer. As a result, samples from alluvial aquifers bordering the Ohio River and elsewhere within the State do not commonly test positive for indicator bacteria, such as total coliform, fecal coliform, or Escherichia coli ( E. coli ). The alluvial sediments do not, however, provide assimilative capacity with respect to water soluble compounds such as nitrate and certain volatile and semi-volatile organic compounds. Therefore, the Ohio River alluvial aquifers are highly susceptible to organic compounds present in the river or on the land surface near a well. These aquifers are also susceptible to nitrate contamination from fertilizers, pesticides, and manure, which are commonly used on the fertile agricultural soils present on terraces along the Ohio River. Abandoned-coal-mine aquifers, which are typically used as a source of groundwater in southern West Virginia, are moderately susceptible to contamination. The vast network of voids from mine entries provide vast storage for groundwater in abandoned mine aquifers, and fracturing of overburden strata, which is common in areas of past or current mining, can allow rapid infiltration of contaminants to the aquifer. Where streams cross over below-drainage underground coal mines, there is an increased potential for contamination of coal-mine aquifers. As a result, above-drainage underground coal mines, those mines that are present at an elevation above local tributary drainage, are probably less susceptible to contamination than are below-drainage underground coal mines. Public groundwater supplies in abandoned coal mines need to be evaluated on a case-by-case basis to assess the potential for recharge of contaminated surface water to enter below-drainage underground coal-mine aquifers and to assess potential hydraulic conductivity to nearby surface-water bodies, such as lakes, ponds, rivers, or streams. Fractured-rock aquifers compose an additional major type of aquifer within the State of West Virginia. Owing to their low permeability and their typically small groundwater capture areas, fractured-rock aquifers within the State of West Virginia typically have low susceptibility to contamination. However, there are exceptions, and wells completed in fractured-rock aquifers that are in close proximity to streams may be adversely affected by induced recharge from the stream. Where such systems are present, frequent bacterial testing of the source water can be used to ascertain the potential for microbial contamination of the aquifer. Intrinsic susceptibility alone does not fully predict whether or not a well is vulnerable to contamination, only that the hydrogeologic terrain is suitable for rapid transport of pathogenic organisms or chemical compounds to and within the aquifer. However, contaminants may or may not be present in the recharge water to an individual well or well field. Therefore, an assessment of potential contaminant sources, such as nearby gas wells, landfills, underground storage tanks, above ground storage tanks, major transportation corridors, surface or underground coal mines, and flood plains, is needed to assess vulnerability. The assessments need to be conducted on a case-by-case basis or, as has been done in this study, by collecting and compiling the number of potential contaminant sources that may be present in the source-water-protection area for an individual public groundwater supply source. Groundwater public-supply systems in areas of high intrinsic susceptibility and with a large number of potential contaminant sources within the recharge or source-water-protection area of individual wells or well fields are potentially vulnerable to contamination and probably warrant further evaluation as potential SWIGS. However, measures can be taken to educate the local population and initiate safety protocols and protective strategies to appropriately manage contaminant sources to prevent release of contaminants to the aquifer, therefore, reducing vulnerability of these systems to contamination. However, each public groundwater supply source needs to be assessed on an individual basis. Data presented in this report can be used to categorize and prioritize wells and springs that have a high potential for intrinsic susceptibility or vulnerability to contamination.

West Virginia

Linear regression model documentation for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River above Topeka Weir at Topeka, Kansas, November 2018 through June 2021

The Kansas River and its associated alluvial aquifer provide drinking water to more than 950,000 people in northeastern Kansas. Water suppliers that rely on the Kansas River as a water-supply source use physical and chemical processes to treat and remove contaminants before public distribution. An early-notification system of changing water-quality conditions allows water suppliers to proactively make decisions that affect water treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, began collecting water-quality data at the Kansas River above Topeka Weir at Topeka, Kansas (USGS site 06888990, hereafter referred to as the “Topeka site”), during November 2018 to develop linear regression models that relate continuous in situ water-quality sensor measurements to discretely sampled water-quality constituent concentrations or densities. The addition of the Topeka site expanded an existing water-quality monitoring network, which included the upstream Kansas River at Wamego, Kans., and downstream Kansas River at De Soto, Kans., sites. Linear regression analysis was used to develop models that compute real-time concentrations or densities for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and Escherichia coli at the Topeka site using data collected during November 2018 through June 2021. Water-quality constituent concentrations or densities computed from the models documented in this report are available at the USGS National Real-Time Water-Quality website (https://nrtwq.usgs.gov), are useful to the public for cultural and recreational purposes, and can be used to guide water-treatment processes, compare conditions with Federal and State water-quality criteria, and characterize changes in Kansas River water-quality conditions through time.

Kansas

Global observational needs and resources for marine biodiversity

The diversity of life in the sea is critical to the health of ocean ecosystems that support living resources and therefore essential to the economic, nutritional, recreational, and health needs of billions of people. Yet there is evidence that the biodiversity of many marine habitats is being altered in response to a changing climate and human activity. Understanding this change, and forecasting where changes are likely to occur, requires monitoring of organism diversity, distribution, abundance, and health. It requires a minimum of measurements including productivity and ecosystem function, species composition, allelic diversity, and genetic expression. These observations need to be complemented with metrics of environmental change and socio-economic drivers. However, existing global ocean observing infrastructure and programs often do not explicitly consider observations of marine biodiversity and associated processes. Much effort has focused on physical, chemical and some biogeochemical measurements. Broad partnerships, shared approaches, and best practices are now being organized to implement an integrated observing system that serves information to resource managers and decision-makers, scientists and educators, from local to global scales. This integrated observing system of ocean life is now possible due to recent developments among satellite, airborne, and in situ sensors in conjunction with increases in information system capability and capacity, along with an improved understanding of marine processes represented in new physical, biogeochemical, and biological models.

Frontiers in Marine Science

Water quality monitoring protocol for wadeable streams and rivers in the Northern Great Plains Network

Preserving the national parks unimpaired for the enjoyment of future generations is a fundamental purpose of the National Park Service (NPS). To address growing concerns regarding the overall physical, chemical, and biological elements and processes of park ecosystems, the NPS implemented science-based management through “Vital Signs” monitoring in 270 national parks (NPS 2007). The Northern Great Plains Network (NGPN) is among the 32 National Park Service Networks participating in this monitoring effort. The NGPN will develop protocols over the next several years to determine the overall health or condition of resources within 13 parks located in Nebraska, North Dakota, South Dakota, and Wyoming. The NGPN identified water resources as a Vital Sign to monitor because water quality and quantity are important aspects of ecological processes that operate across multiple temporal and spatial scales. In the semi-arid region of the Northern Great Plains, surface-water resources within the NGPN are ecologically important. The 13 parks within the NGPN are diverse and vary greatly in size, visitation, and water resources. For example, the measured surface area of the Badlands National Park is about 243,000 acres, which represents nearly one-half of the combined acreage of all 13 NGPN park units; however, water resources within the park are scarce and the majority of streams are intermittent. The Badlands National Park annually hosts nearly 860,000 visitors. Mount Rushmore National Memorial also has limited water resources but hosts nearly 3 million visitors per year within its 1,278 acres. The Missouri National Recreational River contains the greatest portion of waterbodies within the NGPN, consisting of 139 rivers and streams within an areal extent of about 69,000 acres. Although water resources and acreage of the NGPN parks are varied, unifying factors among the parks include the relatively low population density within the Great Plains area and the strong emphasis on agrarian land use throughout the region. To address the diverse water quality concerns, NGPN received input from park staff and conducted pilot studies in 2009 and 2010. These factors, in combination with the NGPN budget allocations, resulted in development of the NGPN’s water quality monitoring protocol. This protocol will provide a context to aid park resource managers in their day-to-day decisions and allow the assessment of the status (current conditions) and trends (directional changes across time) of streams/rivers within selected NGPN parks. Data collected from integrating water resource monitoring, in combination with the inventory of additional Vital Signs, can be used to assess resources and to aid in sound managerial decisions by the NGPN parks. As recommended by Oakley et al. (2003), this protocol provides a narrative and the rationale for selection of streams and rivers within the NGPN that will be measured for water quality, including dissolved oxygen, pH, specific conductivity, and temperature. Standard operating procedures (SOPs) that detail the steps to collect, manage, and disseminate the NGPN water quality data are in an accompanying document. The sampling design documented in this protocol may be updated as monitoring information is collected and interpreted, and as refinement of methodologies develop through time. In addition, evaluation of data and refinement of the program may necessitate potential changes of program objectives. Changes to the NGPN water quality protocols and SOPs will be carefully documented in a revision history log.

Colorado, Montana, Nebraska, North Dakota, South D