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At least 181 records · Page 10Linked to original sources
USGS2015

Development of an assessment tool for agricultural best management practice Implementation in the Great Lakes Restoration Initiative priority watersheds—Alger Creek, tributary to Saginaw River, Michigan

The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Michigan↗
USGS2022

Water-quality trends in the Delaware River Basin calculated using multisource data and two methods for trend periods ending in 2018

Many organizations in the Delaware River Basin (DRB) monitor surface-water quality for regulatory, scientific, and decision-making purposes. In support of these purposes, over 260,000 water-quality records provided by 8 different organizations were compiled, screened, and used to generate water-quality trends in the DRB. These trends, for periods of record that end in 2018, were generated for 124 sites and up to 16 constituents using 2 trend methods: the Seasonal Kendall Test and the Weighted Regressions on Time, Discharge, and Season model. Seasonal Kendall Tests were performed on all water-quality records to detect monotonic trends in concentration over the period of record and for as many as four additional trend periods (1978–2018, 1998–2018, 2003–18, and 2008–18). The Weighted Regressions on Time, Discharge, and Season model was applied to water-quality records that passed more stringent screening criteria and was used to detect monontonic and nonmonotonic trends, account for variations in streamflow, and estimate annual concentrations. These two trend methods produced different trend directions less than 1 percent of the time, illustrating general agreement between the methods despite the different approaches and data input requirements. Overall, the changes in concentration for salinity constituents (specific conductance and total dissolved solids), chloride, and sodium were increases; those increases were some of the largest changes observed in the basin, and they occurred at faster rates over time. Total dissolved solids concentration trends at 4 of the 60 sites increased from below to above the level of concern threshold (a secondary drinking water threshold) over the period of record, indicating potentially meaningful degradation in water quality. Nutrient constituent (ammonia, nitrate, orthophosphate, total nitrogen, and total phosphorus) concentrations tended to decrease over the period of record, although fewer sites had significant trends and the changes in concentration were smaller compared to the salinity constituents. Total nitrogen and total phosphorus were the only nutrient constituents to have decreasing concentration trends that crossed from above to below the level of concern threshold, U.S. Environmental Protection Agency (EPA) ecoregional nutrient criteria, (EPA, undated c). This finding indicates water-quality improvement at sites with these trends (nine sites with total nitrogen trends and one site with a total phosphorus trend), although many sites were still in exceedance of the level of concern. Trends for total suspended solids and some major ions (calcium, magnesium, potassium) were largely nonsignificant or variable between sites, with no prevalent patterns across the DRB; however, sulfate concentrations decreased at most sites. Cumulative land-surface change within each watershed had a strong positive relation with changes in water-quality concentrations for the salinity constituents and most major ions, but not for the other constituents, indicating that land-surface changes are related to the sources and transport of these constituents. Investigating long-term trends (a decade or longer) in water quality can help the DRB water management community quantify the success of management practices and identify potential threats to water availability.

Delaware, New Jersey, New York, Pennsylvania↗
USGS1985

Quality of storm-water runoff, Mililani Town, Oahu, Hawaii, 1980-84

Storm water runoff and rainfall data were collected at two urban sites in Mililani Town, Oahu, Hawaii between September 1980 and August 1984. The data included results from analyses of 300 samples of storm water runoff. Turbidity, suspended solids, Kjeldahl nitrogen, and phosphorus concentrations exceeded the State of Hawaii Department of Health 's streamwater standards in more than 50% of the samples. Mercury, lead, and fecal coliform bacteria levels exceeded the U.S. EPA 's recommended criteria for either freshwater aquatic life or shellfish harvesting waters in more than half the samples. Other constituents exceeding State or federal standards in at least one sample included pH, cadmium, nitrate plus nitrite, iron, alkalinity, manganese, chromium, copper, zinc, and the pesticides heptachlor , lindane, and melathion. Runoff correlated well with rainfall in both basins. Antecedent rainfall conditions and rainfall intensity had little effect on the quality of runoff. No statistically significant relationships were found between quantity of runoff and concentration of water quality constituents. A ' first flush ' effect was observed for chemical oxygen demand, suspended solids, lead, nitrate plus nitrite, fecal coliform bacteria, dissolved solids, and mercury. There were significant (alpha = 0.05) differences between the two basins for values of discharge, turbidity, specific conductance, chemical oxygen demand, suspended solids, nitrate plus nitrite, phosphorus, lead, dissolved solids, and mercury. The larger basin had higher median and maximum values, and wider ranges of values. (Author 's abstract)

Water-Resources Investigations Report↗
USGS1986

Organic compounds in ground water near a sanitary landfill in the Town of Brookhaven, Long Island, New York

Landfill leachate and groundwater near the Brookhaven landfill site were analyzed for volatile, acid-extractable, and base/neutral-extractable organic compounds classified by EPA as ' priority pollutants, ' and for dissolved organic carbon (DOC) and inorganic constituents. Thirteen priority pollutants were detected, including benzene, chlorobenzene, ethyl benzene, and naphthalene. The most commonly detected priority pollutant, benzene, was found in the landfill leachate and in five groundwater samples. The concentration of ethyl benzene was the highest of all organic compounds detected--55 micrograms/L (ug/L) in the leachate. Three samples downgradient from the site contained detectable levels of priority pollutants; two of these from wells 2000 ft downgradient from the site, contained trace amounts of chloroform, and the other, from a well 500 ft downgradient, contained four priority pollutants in concentrations totaling less than 20 ug/L. DOC concentrations ranged from 410 mg/L in the leachate to 0.8 mg/L, which is considered background level for groundwater upgradient of the landfill site. Samples from downgradient wells contained less than 8 mg/L DOC except at two wells 500 ft from the site, which contained 21 and 16 mg/L. (Author 's abstract)

Water-Resources Investigations Report↗
USGS2017

Design and methods of the Midwest Stream Quality Assessment (MSQA), 2013

During 2013, the U.S. Geological Survey (USGS) National Water-Quality Assessment Project (NAWQA), in collaboration with the USGS Columbia Environmental Research Center, the U.S. Environmental Protection Agency (EPA) National Rivers and Streams Assessment (NRSA), and the EPA Office of Pesticide Programs assessed stream quality across the Midwestern United States. This Midwest Stream Quality Assessment (MSQA) simultaneously characterized watershed and stream-reach water-quality stressors along with instream biological conditions, to better understand regional stressor-effects relations. The MSQA design focused on effects from the widespread agriculture in the region and urban development because of their importance as ecological stressors of particular concern to Midwest region resource managers. A combined random stratified selection and a targeted selection based on land-use data were used to identify and select sites representing gradients in agricultural intensity across the region. During a 14-week period from May through August 2013, 100 sites were selected and sampled 12 times for contaminants, nutrients, and sediment. This 14-week water-quality “index” period culminated with an ecological survey of habitat, periphyton, benthic macroinvertebrates, and fish at all sites. Sediment was collected during the ecological survey for analysis of sediment chemistry and toxicity testing. Of the 100 sites, 50 were selected for the MSQA random stratified group from 154 NRSA sites planned for the region, and the other 50 MSQA sites were selected as targeted sites to more evenly cover agricultural and urban stressor gradients in the study area. Of the 50 targeted sites, 12 were in urbanized watersheds and 21 represented “good” biological conditions or “least disturbed” conditions. The remaining 17 targeted sites were selected to improve coverage of the agricultural intensity gradient or because of historical data collection to provide temporal context for the study. This report provides a detailed description of the MSQA study components, including surveys of ecological conditions, routine water sampling, deployment of passive polar organic compound integrative samplers, and stream sediment sampling at all sites. Component studies that were completed to provide finer scale temporal data or more extensive analysis at selected sites, included continuous water-quality monitoring, daily pesticide sampling, laboratory and in-stream water toxicity testing efforts, and deployment of passive suspended-sediment samplers.

Illinois, Indiana, Iowa, Kansas, Kentucky, Michiga↗
USGS1986

Direction of ground-water flow and ground-water quality near a landfill in Falmouth, Massachusetts

A landfill in Falmouth, Massachusetts, is upgradient of a pond used for municipal water supply, but analysis of groundwater flow directions and groundwater quality indicates that leachate from the landfill does not threaten the municipal water supply. A network of water table observation wells was established, and water table altitudes were measured in these wells on several dates in 1981. Water quality analyses and specific conductance measurements were made on water samples from several wells in the vicinity of the landfill between October 1980 and April 1983. A water table altitude contour map of the area between the landfill and Long Pond for April 16-17, 1981, indicates that the direction of groundwater flow is primarily southwest from the landfill to Buzzards Bay. A similar map for September 2, 1981--a time at which the water table was unusually low--indicates the possibility of groundwater discharge to Long Pond from the landfill site. Groundwater quality beneath the landfill exceeded U.S. EPA water quality criteria for domestic water supply for manganese and total dissolved solids. Concentrations as high as 52 mg/L of nitrogen as ammonia and 4,500 micrograms/L (ug/L) of manganese were found. Concentrations of ammonia, manganese, calcium, potassium, and alkalinity exceeded local background levels by more than a factor of 100; specific-conductance levels and concentrations of hardness, barium, chloride, sodium, magnesium, iron, and strontium exceeded local background levels by more than a factor of 10; and cadmium concentrations exceeded local background levels by more than a factor of 5. Water quality analyses and field specific conductance measurements indicate the presence of a volume of leachate extending south-southwest from the landfill. Average chloride concentrations of landfill leachate, precipitation on the surface of Long Pond, and recharge from the remainder of the recharge area were 180, 3, and 9 mg/L, respectively. No significant degradation of the quality of water in Long Pond is expected as a result of leachate from this landfill. (Author 's abstract)

Water-Resources Investigations Report↗
USGS2018

Describing the distribution and productivity of biota along a nearshore to offshore gradient

The Lake Michigan Lakewide Action and Management Plan (LAMP) proposed adding nutrients (phosphorus) to its “pollutant of concern” list in 2002, given that excessive nutrients were causing impairments in nearshore waters. Since that time, scientists have highlighted the “shunting” of nutrients to the nearshore (Hecky et al. 2004), owing to the ability of invasive dreissenid mussels to capture some portion of allochthonous phosphorus that enters the lake through tributaries. These changes are believed to increase productivity in the nearshore, reflected in increased benthic and pelagic primary production and nuisance Cladophora (Auer et al. 2010). Whether increases in primary productivity lead to concomitant increases for secondary (by zooplankton) and tertiary (by fish) production remains largely untested. Hence, understanding the distribution and abundance of nutrients and biota (e.g., zooplankton, fish) across a nearshore to offshore gradient was identified as a Cooperative Science and Monitoring Initiative (CSMI) priority in 2015. Increased understanding of the Lake Michigan nearshore will also facilitate the development of a Nearshore Strategy by the LAMP, which is called for in the 2012 Great Lakes Water Quality Agreement. Working collaboratively with Environmental Protection Agency (EPA) and National Oceanic and Atmospheric Administration (NOAA), United States Geological Survey (USGS) described the distribution of nutrients and biota across nearshore to offshore transects in 2015 (see Appendix 1). At each transect, we sampled the food web at three sites with differing bottom depths: 18 m, 46 m, and 91-110 m. We purposefully chose transects near tributaries of varying total phosphorus (TP) input (see Figure 1, Dolan and Chapra 2012): three transects that were not associated with any large tributary where total phosphorus would be loaded (Waukegan IL, Frankfort MI, Sturgeon Bay WI), three transects adjacent to tributaries presumed to be relatively low loaders of TP (Pere Marquette MI, Root WI, Muskegon MI), and three transects adjacent to tributaries presumed to be relatively high loaders of TP (St. Joseph MI, Kalamazoo MI, Manitowoc WI). USGS estimated chlorophyll concentrations, zooplankton, Mysis , larval fish, and juvenile and adult fish seasonally (April/May, July, October/November) at eight of these transects (all but Muskegon).

Illinois, Michigan, Wisconsin↗
USGS1986

Effect of urban stormwater runoff on ground water beneath recharge basins on Long Island, New York

Urban stormwater runoff was monitored during 1980-82 to investigate the source, type, quantity, and fate of contaminants routed to the more than 3,000 recharge basins on Long Island and to determine whether this runoff might be a significant source of contamination to the groundwater reservoir. Forty-six storms were monitored at five recharge basins in representative land use areas (strip commercial, shopping-mall parking lot, major highway, low-density residential, and medium-density residential). Runoff:precipitation ratios indicate that all storm runoff is derived from precipitation on impervious surfaces in the drainage area, except during storms of high intensity or long duration, when additional runoff can be derived from precipitation on permeable surfaces. Lead was present in highway runoff in concentrations up to 3300 micrograms/L, and chloride was found in parking lot runoff concentrations up to 1,100 mg/L during winter, when salt is used for deicing. In the five composite stormwater samples and nine groundwater grab samples that were analyzed for 113 EPA-designated ' priority pollutants, ' four constituents were detected in concentrations exceeding New York State guidelines of 50 micrograms/L for an individual organic compound in drinking water: p-chloro-m-cresol (79 micrograms/L); 2 ,4-dimethylphenol (96 micrograms/L); 4-nitrophenol (58 micrograms/L); and methylene chloride (230 micrograms/L in either groundwater or stormwater at the highway basin). One stormwater sample and two groundwater samples exceeded New York State guidelines for total organic compounds in drinking water (100 micrograms/L). The presence of these constituents is attributed to contamination from point sources rather than to the quality of runoff from urban areas. The median number of indicator bacteria in stormwater ranged from 0.1 to 10 billion MPN/100 ml. Fecal coliforms and fecal streptococci increased by 1 to 2 orders of magnitude during the warm season. The use of recharge basins to dispose of storm runoff does not appear to have significant adverse effects on groundwater quality in terms of the chemical and microbiological stormwater constituents studied. (Author 's abstract)

Water-Resources Investigations Report↗
USGS1988

Effects of highway runoff on streamflow and water quality in the Sevenmile Creek basin, a rural area in the Piedmont Province of North Carolina, July 1981 to July 1982

An evaluation of water-quality data from streams that receive stormwater runoff from a segment of Interstate Highway 85 in North Carolina indicated increased levels of many constituents compared to levels in nearby undeveloped basins. Additional data collected from a network of dry and wet atmospheric deposition collectors, lysimeter samples, soil surveys, wind measurements, and road sweepings helped define the general sources and migration of chemical substances near the highway. The eight study basins, located in a rural area in the Piedmont of North Carolina, had a combined area of 17.5 square miles and drained a 4.8-mile-long segment of the interstate. The average traffic flow along this section was 25,000 vehicles per day. During storm runoff, streamflow in basins traversed by the highway rose and fell more rapidly than that in the undeveloped basins. This more rapid response is due to the impervious, paved area of the basins and the manmade drainage systems designed to rapidly move water off the highway. Alkalinity, specific conductance, and concentrations of calcium, sodium, and chloride were greater at the highway stations than in the undeveloped basins as a result of highway salting for control of ice. Specific conductance and concentrations of dissolved and total nitrogen peaked at the beginning of each storm event. The data indicated that, for the study basins, highway runoff had little or no effect on suspended sediment, water temperature, dissolved oxygen, and pH. However, the pH at all stations decreased during stormflow because the rainfall drained off by the streams had pH values less than 5.7. High metals concentrations were found in the soils within 100 feet of the highway and in the soil water infiltrating the soil zone. Chromium, copper, nickel, and zinc concentrations in the streams near the highway generally were above the maximum levels recommended by the U.S. Environmental Protection Agency (EPA) for the protection of aquatic life. Lead and cadmium concentrations frequently exceeded the maximum levels recommended by the EPA for drinking water. The highway is a source of contaminants to surrounding areas. Particulate and metal loads in dustfall and chemical-constituent concentrations in soils decrease exponentially with distance from the highway. The highest concentrations of contaminants were found on the downwind side. Increased concentrations of metals (cadmium, chromium, iron, lead, nickel, and zinc) in rainfall were observed in samples collected near the highway and in samples collected approximately one-half mile away. Material loading due to dustfall was greater than loading due to rainfall. Loading due to saltated particles, those heavier particles bounced along the highway surface, was higher than loading due to dustfall. Saltation loads were greatest during the winter months because of highway deicing and sanding, which supplied an estimated two-thirds of the saltated materials. The remaining one-third of the saltated load came primarily from the deposition of particles from vehicles. Some of the greatest constituent concentrations were measured in the soil water sampled from the lysimeters located adjacent to the highway.

North Carolina↗
USGS2002

Results of test drilling in the Basalt aquifer near Fallon, Nevada

Drilling of two test holes into the Fallon basalt aquifer commenced August 14, 2001. The basalt aquifer is located beneath the Carson Desert, near Fallon, Nevada, and is the sole source of drinking water for the City of Fallon, the Naval Air Station (NAS) Fallon, and the Fallon Paiute-Shoshone Tribe. Basalt comprising the aquifer is exposed at Rattlesnake Hill, an eroded volcanic cone, about 1 mile northeast of Fallon, and the remainder is buried beneath sediments deposited by the Carson River and ancient Lake Lahontan to depths of 600 feet near its edges (fig. 1). The basalt-aquifer system is a mushroom-shaped body of highly permeable volcanic rock. Viewed from above, the lateral extent of the basalt body is oval-shaped, about 4-miles wide and 10-miles long (fig. 1). Drilling was part of a cooperative study between the U.S. Geological Survey (USGS), the Bureau of Reclamation, and NAS Fallon. The study was started because of concern about the continued viability of the basalt-aquifer system as a source of municipal water supply. Increased pumping from about 1,700 acre-feet per year (acre-ft/yr) in the 1970?s to over 3,000 acre-ft/yr in the late 1990?s has caused water levels in the basalt to decline as much as 12 feet (fig. 2). During this same time period, water pumped from the aquifer at NAS Fallon and the City of Fallon wells showed that concentrations of dissolved chloride increased, although chloride concentrations were well within the U.S. Environmental Protection Agency?s (EPA) drinking-water standards; at this rate of increase, it would take decades to exceed the present standard (Maurer and Welch, 2001, p. 46). Concentrations of arsenic in the aquifer are about 0.1 milligrams per liter (mg/L), exceeding the drinking-water standard of 0.01 mg/L, but show no apparent change over time (Maurer and Welch, 2001, p. 10 and 48; U. S. Environmental Protection Agency, 2001). Increasing concentrations of chloride may be caused by increased pumping, that induces inflow of more saline water from aquifers surrounding or underlying the basalt, or from greater depths within the basalt itself. Prior to the drilling on August 14, 2001, few wells penetrated the basalt more than 70 feet below its upper surface (Maurer and Welch, 2001, p. 34). This prevented monitoring changes in water quality deeper in the aquifer that might be moving upward with continued pumping. Purposes of drilling were to fully penetrate the basalt, determine its hydrogeological character, the distribution of water quality in the basalt and in the underlying sedimentary aquifer, install monitoring wells.

Fact Sheet↗
USGS2017

Effects of changes in pumping on regional groundwater-flow paths, 2005 and 2010, and areas contributing recharge to discharging wells, 1990–2010, in the vicinity of North Penn Area 7 Superfund site, Montgomery County, Pennsylvania

A previously developed regional groundwater flow model was used to simulate the effects of changes in pumping rates on groundwater-flow paths and extent of recharge discharging to wells for a contaminated fractured bedrock aquifer in southeastern Pennsylvania. Groundwater in the vicinity of the North Penn Area 7 Superfund site, Montgomery County, Pennsylvania, was found to be contaminated with organic compounds, such as trichloroethylene (TCE), in 1979. At the time contamination was discovered, groundwater from the underlying fractured bedrock (shale) aquifer was the main source of supply for public drinking water and industrial use. As part of technical support to the U.S. Environmental Protection Agency (EPA) during the Remedial Investigation of the North Penn Area 7 Superfund site from 2000 to 2005, the U.S. Geological Survey (USGS) developed a model of regional groundwater flow to describe changes in groundwater flow and contaminant directions as a result of changes in pumping. Subsequently, large decreases in TCE concentrations (as much as 400 micrograms per liter) were measured in groundwater samples collected by the EPA from selected wells in 2010 compared to 2005‒06 concentrations. To provide insight on the fate of potentially contaminated groundwater during the period of generally decreasing pumping rates from 1990 to 2010, steady-state simulations were run using the previously developed groundwater-flow model for two conditions prior to extensive remediation, 1990 and 2000, two conditions subsequent to some remediation 2005 and 2010, and a No Pumping case, representing pre-development or cessation of pumping conditions. The model was used to (1) quantify the amount of recharge, including potentially contaminated recharge from sources near the land surface, that discharged to wells or streams and (2) delineate the areas contributing recharge that discharged to wells or streams for the five conditions. In all simulations, groundwater divides differed from surface-water divides, partly because of differences in stream elevations and because of geologic structure and pumping. In the 1990 and 2000 simulations, all recharge in and near the vicinity of North Penn Area 7 discharged to wells, but in the 2005 and 2010 simulations some recharge in this area discharged to streams, indicating possible discharge of contaminated groundwater from North Penn Area 7 sources to streams. As the amount of groundwater withdrawals by wells has declined since 1990, the area contributing recharge to wells in the vicinity of North Penn Area 7 has decreased. To determine the effect of changes in pumping on flow paths and possible flow-path-related contributions to the observed changes in spatial distribution of contaminants in groundwater from 2005 to 2010, the USGS conducted simulations using the previously developed regional groundwater-flow model using reported pumping and estimated recharge rates for 2005 and 2010. Flow paths from recharge at known contaminant source areas to discharge locations at wells or streams were simulated under steady-state conditions for the two periods. Simulated groundwater-flow paths shifted only slightly from 2005 to 2010 as a result of changes in pumping rates. These slight changes in groundwater-flow paths from known sources of contamination are not coincident with the spatial distribution of observed changes in TCE concentrations from 2005 to 2010, indicating that the decreases of TCE concentrations may be a result of other processes, such as source removal or degradation. Results of the simulations and the absence of increases in TCE-degradation-product concentrations indicate that the decreases of TCE concentrations observed in 2010 may be at least partly related to contaminant-source removal by soil excavation completed in 2005, although additional data would be needed to confirm this preliminary explanation.

Pennsylvania↗
USGS2019

Groundwater quality and nutrient trends near Marsing, southwestern Idaho, 2018

The U.S. Geological Survey, in cooperation with the Idaho Department of Environmental Quality, sampled groundwater from 15 wells during spring 2018 near the city of Marsing in rural northwestern Owyhee County, southwestern Idaho. Samples were analyzed for field parameters, nutrients, trace elements, major inorganics, and dissolved gas, including methane. To examine trends in individual wells and in the region, ammonia and nitrate results from the spring 2018 sampling were compared with data collected from 1996 to 2015 by the Idaho Department of Environmental Quality and the Idaho State Department of Agriculture. Fourteen of the 15 samples collected in 2018 contained arsenic (0.13–33.8 micrograms per liter [μg/L]), with 7 arsenic concentrations greater than the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) of 10 μg/L. Iron (465–4,180 μg/L), manganese (54–693 μg/L), sulfate (300–624 milligrams per liter [mg/L]), and total dissolved solids (511–1,350 mg/L) were detected at concentrations greater than EPA secondary maximum contaminant levels (SMCL) in water-quality samples from 6, 10, 4, and 14 of the 15 wells, respectively. Fourteen of the 15 samples contained ammonia concentrations from 0.12 to 7.34 milligrams per liter (mg/L). Six samples contained nitrate concentrations from 0.08 to 24.6 mg/L, with one sample greater than the EPA MCL of 10 mg/L for drinking water. The presence of both ammonia and nitrate in four samples indicated multiple nutrient and groundwater sources and varying redox states. Ammonia concentrations tended to increase downgradient throughout the study area. Nutrient trend analysis identified water-quality samples from 2 of the 15 wells with increasing nitrate concentrations from 1999–2018 and 2005–2018. The well with increasing nitrate concentrations from 2005–2018 showed a decreasing trend in ammonia concentrations during the same time period. Groundwater-quality samples from the 13 remaining wells showed no temporal trends. A Regional Kendall test, which evaluates trends at numerous wells across the study area to determine if a consistent trend exists for the area, was done to analyze 539 ammonia concentrations from 91 wells over 20 years (1999–2018) and 591 nitrate concentrations from 107 wells over 23 years (1996–2018). The Regional Kendall Test for ammonia had a tau correlation coefficient of -0.073 with a p-value of 0.072, and nitrate had a tau correlation coefficient of -0.041 with a p-value of 0.198, both indicating no statistically significant trends.

Idaho↗
USGS2009

Land-cover change in the Lower Mississippi Valley, 1973-2000

The Land Cover Trends is a research project focused on understanding the rates, trends, causes, and consequences of contemporary United States land-use and land-cover change. The project is coordinated by the Geographic Analysis and Monitoring Program of the U.S. Geological Survey (USGS) in conjunction with the U.S. Environmental Protection Agency (EPA) and the National Aeronautics and Space Administration (NASA). Using the EPA Level III ecoregions as the geographic framework, scientists process geospatial data collected between 1973 and 2000 were processed to characterize ecosystem responses to land-use changes. The 27-year study period was divided into four temporal periods: 1973 to1980, 1980 to 1986, 1986 to 1992, 1992 to 2000 and overall from 1973 to 2000. General land-cover classes for these periods were interpreted from Landsat Multispectral Scanner, Thematic Mapper, and Enhanced Thematic Mapper Plus imagery to categorize and evaluate land-cover change using a modified Anderson Land Use Land Cover Classification System (Anderson and others, 1976) for image interpretation. The rates of land-cover change were estimated using a stratified, random sampling of 10-kilometer (km) by 10-km blocks allocated within each ecoregion. For each sample block, satellite images were used to interpret land-cover change. The sample block data then were incorporated into statistical analyses to generate an overall change matrix for the ecoregion. These change statistics are applicable for different levels of scale, including total change for the individual sample blocks and change estimates for the entire ecoregion.

Open-File Report↗
USGS2021

Occurrence and distribution of PFAS in sampled source water of public drinking-water supplies in the surficial aquifer in Delaware, 2018; PFAS and groundwater age-dating results

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (1) describe the occurrence and distribution of PFAS, and (2) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Delaware Coastal Plain between 2000 and 2008 and between 2008 and 2018. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November 2018. Groundwater collected from the wells was analyzed for the occurrence and distribution of 18 per- and polyfluorinated alkyl substances (PFAS) as well as groundwater age. Descriptive statistical analyses were performed to assess PFAS analytical results within the well network and the combined perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) concentrations were compared to the U.S. Environmental Protection Agency’s (EPA) health advisory level (HAL) for informational purposes only and not for evidence of compliance or noncompliance with Federal regulations. The EPA’s HAL is a health-based reference level for public drinking water as supplied to customers and is not applied to source (raw) water. Groundwater-age data were compared for sites sampled in 2000, 2008, and 2018 to document any changes. All samples were analyzed for 18 PFAS using EPA Method 537 (modified). Forty-four percent of the analyzed PFAS were detected in the study well network. Sixteen of the sampled wells have one or more PFAS detections, and as many as eight different PFAS were found in a single sample. Wells with a higher number of PFAS detected (five or more) were in New Castle and Sussex Counties. The PFAS most frequently detected were PFOA, with 47 percent detection; perfluorohexanoic acid (PFHxA), with 33 percent detection; and PFOS and perfluorohexane sulfonate (PFHxS), with 27 percent detection each. PFAS concentrations were below 1,000 parts per trillion (ppt). Two wells exceeded the EPA’s lifetime-drinking water health advisory level of 70 ppt for combined concentrations of PFOA and PFOS. The average age of groundwater entering the screens of the supply wells sampled in 2018 ranged from 8.2 to 45.8 years, with a median groundwater age of 25.7 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Groundwater age and PFAS concentrations were negatively correlated in the Columbia aquifer. Data from the 23 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2018 was generally 5 years older than the average groundwater age from samples collected in 2008. The same pattern was found during cycle two (2008) of this study, where the 2008 groundwater age was on average 7 years older than the samples collected in 2000. The distribution of groundwater sample ages among the 17 trend wells and during the three study cycles (2000, 2008, and 2018) indicates that sample-age medians were statistically different from zero; well-water sample-age data show a slight increase in groundwater sample age.

Delaware↗
USGS2014

Best practices for continuous monitoring of temperature and flow in wadeable streams

The United States Environmental Protection Agency (U.S. EPA) is working with its regional offices, states, tribes, river basin commissions and other entities to establish Regional Monitoring Networks (RMNs) for freshwater wadeable streams. To the extent possible, uninterrupted, biological, temperature and hydrologic data will be collected on an ongoing basis at RMN sites, which are primarily located on smaller, minimally disturbed forested streams. The primary purpose of this document is to provide guidance on how to collect accurate, year-round temperature and hydrologic data at ungaged wadeable stream sites. It addresses questions related to equipment needs, sensor configuration, sensor placement, installation techniques, data retrieval, and data processing. This guidance is intended to increase comparability of continuous temperature and hydrologic data collection at RMN sites and to ensure that the data are of sufficient quality to be used in future analyses. It also addresses challenges posed by year-round deployments. These data will be used for detecting temporal trends; providing information that will allow for a better understanding of relationships between biological, thermal, and hydrologic data; predicting and analyzing climate change impacts and quantifying natural variability.

Report↗
USGS2020

Groundwater withdrawals and regional flow paths at and near Willow Grove and Warminster, Pennsylvania—Data compilation and preliminary simulations for conditions in 1999, 2010, 2013, 2016, and 2017

In 2014, groundwater samples from residential and public supply wells in the vicinity of two former U.S. Navy bases at Willow Grove and Warminster, and an active Air National Guard Station at Horsham, Bucks and Montgomery Counties, Pennsylvania, were found to have concentrations of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), which are per- and polyfluoroalkyl substances (PFAS), above U.S. Environmental Protection Agency (EPA) provisional health advisory (HA) levels for drinking water. Five supply wells near the bases were shut down because of PFAS contamination. In 2016, after EPA established a Lifetime HA for PFAS in drinking water that is lower than the provisional HA in place in 2014, at least 13 additional supply wells near the bases were shut down because of PFAS contamination. At the request of the U.S. Navy, and in consultation with other Federal and State agencies and local stakeholders, the U.S. Geological Survey used historical and recent data on well withdrawals, recharge rates, aquifer properties, groundwater levels, and stream base flow to evaluate regional groundwater-flow paths from identified areas of PFAS groundwater contamination or potential PFAS sources at the bases. Groundwater withdrawals near the bases from public supply and other large wells decreased substantially from the 1990s to 2017, increasing the proportion of groundwater recharge that discharged to local streams. A preliminary groundwater-flow model, calibrated using 1,009 groundwater levels and 17 stream base flow estimates, simulated regional flow paths from the bases and showed that recharge at the bases discharged to withdrawal wells and local streams, generally within a mile or two of the bases. Supply and remediation wells at the bases captured some of the recharge on base areas of possible PFAS contamination, whereas other base recharge was simulated to flow to nearby public supply wells and streams, depending on water use and aquifer recharge conditions between 1999 and 2017. The locations of many residential wells near the bases that were identified by the Navy and Air National Guard as having elevated PFAS concentrations were generally consistent with the simulated flow paths from possible sources at the bases. However, there are some areas of observed PFAS contamination where no flow paths from base sources were simulated. Additionally, no data were available on PFAS concentrations in groundwater in some areas of simulated flow paths from base sources. Data and models used for this study are provided in this report and in digital data releases to support further investigations and model revisions.

Pennsylvania↗
USGS1988

Map showing radon potential of rocks and soils in Fairfax County, Virginia

Since 1984, indoor radon has gained national attention as a significant health hazard in the United States. Radon is a colorless, odorless, radioactive gas derived from uranium by radioactive decay. The U.S. Environmental Protection Agency (EPA) now projects that 5,000 to 20,000 lung-cancer deaths per year may be attributed to the long-term exposure to indoor radon and its radioactive decay products. Indoor radon has been previously recognized as a health hazard associated with uranium-bearing mill tailings or building materials, but it was not until December 1984 that some natural soils and rocks were found to be sources of indoor radon at levels comparable to those in uranium mines. It is now suspected that elevated indoor radon levels are far more widespread than initially though. The EPA considers 4 picoCuries of radon per liter of air (pCi/L) as the level (in a year-round measurement) at which actions ought to be taken to lower the concentration of indoor radon. All soils and rocks contain measurable amounts of uranium, which generate measurable amounts of radon. Certain soils and rocks, however, have a greater potential to cause indoor radon problems than others because (1) they have a higher uranium content and thus can generate higher levels of radon in soil gas (gas that occupies the pores of the soil), and (2) the permeability of the sol or rack is sufficiently high that radon-bearing soil gas can flow freely and move indoors through the foundation of the structure. This study was designed to demonstrate the correlation between the geologic environment and indoor radon levels and to demonstrate a method of assessment that could be used by other informed workers in areas of their interest. A parallel study by Gundersen and others (1988) of the radon potential of rocks and soils in Montgomery County, Md., used somewhat different methods of assessment because the data available for and assessment of Montgomery County differed.

Virginia↗
USGS2007

Geological assessment of cores from the Great Bay National Wildlife Refuge, New Hampshire

Geological sources of metals (especially arsenic and zinc) in aquifer bedrock were evaluated for their potential to contribute elevated values of metals to ground and surface waters in and around Rockingham County, New Hampshire. Ayotte and others (1999, 2003) had proposed that arsenic concentrations in ground water flowing through bedrock aquifers in eastern New England were elevated as a result of interaction with rocks. Specifically in southeastern New Hampshire, Montgomery and others (2003) established that nearly one-fifth of private bedrock wells had arsenic concentrations that exceed the U.S. Environmental Protection Agency (EPA) maximum contamination level for public water supplies. Two wells drilled in coastal New Hampshire were sited to intersect metasedimentary and metavolcanic rocks in the Great Bay National Wildlife Refuge. Bulk chemistry, mineralogy, and mineral chemistry data were obtained on representative samples of cores extracted from the two boreholes in the Kittery and Eliot Formations. The results of this study have established that the primary geologic source of arsenic in ground waters sampled from the two well sites was iron-sulfide minerals, predominantly arsenic-bearing pyrite and lesser amounts of base-metal-sulfide and sulfosalt minerals that contain appreciable arsenic, including arsenopyrite, tetrahedrite, and cobaltite. Secondary minerals containing arsenic are apparently limited to iron-oxyhydroxide minerals. The geologic source of zinc was sphalerite, typically cadmium-bearing, which occurs with pyrite in core samples. Zinc also occurred as a secondary mineral in carbonate form. Oxidation of sulfides leading to the liberation of acid, iron, arsenic, zinc, and other metals was most prevalent in open fractures and vuggy zones in core intervals containing zones of high transmissivity in the two units. The presence of significant calcite and lesser amounts of other acid-neutralizing carbonate and silicate minerals, acting as a natural buffer to reduce acidity, forced precipitation of iron-oxyhydroxide minerals and the removal of trace elements, including arsenic and lead, from ground waters in the refuge. Zinc may have remained in solution to a greater extent because of complexing with carbonate and its solubility in near-neutral ground and surface waters. The regional link between anomalously high arsenic contents in ground water and a bedrock source as established by Ayotte and others (1999, 2003) and Montgomery and others (2003) was confirmed by the presence of some arsenic-bearing minerals in rocks of the Kittery and Eliot Formations. The relatively low amounts of arsenic and metals in wells in the Great Bay National Wildlife Refuge as reported by Ayotte and others (U.S. Geological Survey Water Resources Data, 2005) were likely controlled by local geochemical environments in partially filled fractures, fissures, and permeable zones within the bedrock formations. Carbonate and silicate gangue minerals that line fractures, fissures, and permeable zones likely limited the movement of arsenic from bedrock to ground water. Sources other than the two geologic formations might have been required to account for anomalously high arsenic contents measured in private bedrock aquifer wells of Rockingham County.

New Hampshire↗