Search USGS⌕ Search

SEARCH · Search USGS

Results for “Chemistry and Water”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10Linked to original sources
USGS2005

Bottled water, spas, and early years of water chemistry

Although hot springs have been used and enjoyed for thousands of years, it was not until the late 1700s that they changed the course of world civilization by being the motivation for development of the science of chemistry. The pioneers of chemistry such as Priestley, Cavendish, Lavoisier, and Henry were working to identify and generate gases, in part, to determine their role in carbonated beverages. In the 18th century, spas in America were developed to follow the traditional activities of popular European spas. However, they were to become a dominant political and economic force in American history on three major points: (1) By far the most important was to provide a place for the leaders of individual colonies to meet and discuss the need for separation from England and the necessity for the Revolutionary War; (2) the westward expansion of the United States was facilitated by the presence of hot springs in many locations that provided the economic justification for railroads and settlement; and (3) the desire for the preservation of hot springs led to the establishment of the National Park Service. Although mineral springs have maintained their therapeutic credibility in many parts of the world, they have not done so in the United States. We suggest that the American decline was prompted by: (1) the establishment of The Johns Hopkins School of Medicine in 1893; (2) enactment of the Pure Food and Drug Act of 1907; and (3) the remarkable achievement of providing safe water supplies for American cities by the end of the 1920s. The current expanding market for bottled water is based in part on bottled water being an alternative beverage Ito alcohol and sweetened drinks and the inconsistent palatability and perceived health hazards of some tap waters.

Groundwater↗
USGS2002

Weathering reactions and hyporheic exchange controls on stream water chemistry in a glacial meltwater stream in the McMurdo Dry Valleys

In the McMurdo Dry Valleys, Antarctica, dilute glacial meltwater flows down well‐established streambeds to closed basin lakes during the austral summer. During the 6–12 week flow season, a hyporheic zone develops in the saturated sediment adjacent to the streams. Longer Dry Valley streams have higher concentrations of major ions than shorter streams. The longitudinal increases in Si and K suggest that primary weathering contributes to the downstream solute increase. The hypothesis that weathering reactions in the hyporheic zone control stream chemistry was tested by modeling the downstream increase in solute concentration in von Guerard Stream in Taylor Valley. The average rates of solute supplied from these sources over the 5.2 km length of the stream were 6.1 × 10 −9 mol Si L −1 m −1 and 3.7 × 10 −9 mol K L −1 m −1 , yielding annual dissolved Si loads of 0.02–1.30 mol Si m −2 of watershed land surface. Silicate minerals in streambed sediment were analyzed to determine the representative surface area of minerals in the hyporheic zone subject to primary weathering. Two strategies were evaluated to compute sediment surface area normalized weathering rates. The first applies a best linear fit to synoptic data in order to calculate a constant downstream solute concentration gradient, dC / dx (constant weathering rate contribution, CRC method); the second uses a transient storage model to simulate dC / dx , representing both hyporheic exchange and chemical weathering (hydrologic exchange, HE method). Geometric surface area normalized dissolution rates of the silicate minerals in the stream ranged from 0.6 × 10 −12 mol Si m −2 s −1 to 4.5 × 10 −12 mol Si m −2 s −1 and 0.4 × 10 −12 mol K m −2 s −1 to 1.9 × 10 −12 mol K m −2 s −1 . These values are an order of magnitude lower than geometric surface area normalized weathering rates determined in laboratory studies and are an order of magnitude greater than geometric surface area normalized weathering rates determined in a warmer, wetter setting in temperate basins, despite the cold temperatures, lack of precipitation and lack of organic material. These results suggest that the continuous saturation and rapid flushing of the sediment due to hyporheic exchange facilitates weathering in Dry Valley streams.

Water Resources Research↗
USGS2021

A reactive transport approach to modeling cave seepage water chemistry I: Carbon isotope transformations

The majority of Critical Zone research has emphasized silicate lithologies, which are typified by relatively slow rates of reactivity and incongruent weathering. However, the relatively simpler weathering of carbonate-dominated lithology can result in secondary mineral deposits, such as speleothems, which provide a long-term archive for Critical Zone processes. In particular, carbon isotopic variability in speleothems has the potential to provide records of changes in vegetation, soil respiration, carbon stabilization in deep soils, and/or chemical weathering in the host rock. Despite this opportunity to reconstruct many Critical Zone processes, multiple influences can also make interpretion of these speleothem carbon isotope records challenging. The integration of observational data and simulations specific to karst systems offers an interpretive framework for these unique time-averaged records accumulated through the evolution of carbonate landscapes. Here, we present a forward and process-based reactive transport simulation based on a multi-year monitoring study of Blue Spring Cave in central Tennessee, USA. The simulations describe the fluid-driven weathering of limestone including explicit tracking of dissolved calcium, stable carbon, and radiocarbon isotope ratios based on reaction rates calibrated through laboratory batch reaction data. We find that calcium concentrations and radiocarbon isotope ratios are strongly influenced by the combination of fluid flow rate and soil CO 2 content, and require rapid gas phase communication between the overlying soil boundary condition and interior karst to sustain both elevated limestone weathering rates and relatively modern radiocarbon signatures. Stable carbon isotopes are largely dictated by temperature-dependent equilibrium fractionation among contemporaneous species. These simulations are extended to a wide range of parameter space to demonstrate the environmental factors that these isotope proxies record.

Geochimica et Cosmochimica Acta↗
USGS2007

Aquatic Communities and Selected Water Chemistry in St. Vrain Creek near the City of Longmont, Colorado, Wastewater-Treatment Plant, 2005 and 2006

In 2005, the U.S. Geological Survey and the City of Longmont, Colo., began a study to document chemical characteristics of St. Vrain Creek that had previously been unavailable either due to high cost of analysis or lack of analytical capability. Stream samples were collected at seven sites on St. Vrain Creek during the spring of 2005 and 2006 for analysis of wastewater compounds. A Lagrangian-sampling design was followed during each sampling event, and time-of-travel studies were conducted just prior to each sampling event to determine appropriate sampling times for the synoptic. In addition, semipermeable membrane devices, passive samplers that concentrate hydrophobic organic chemicals, were installed at six sites during the spring of 2005 and 2006 for approximately 4 weeks. After retrieval, contaminant residues concentrated in the semipermeable membrane devices were recovered and used in a toxicity assay that provided a screen for aryl hydrocarbon receptor type compounds, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls, dioxins, and furans. In addition, the U.S. Geological Survey summarized information on macroinvertebrate and fish communities known from St. Vrain Creek dating back to the early 1900s in order to assess their utility in evaluating wastewater-treatment plant upgrades and habitat improvement projects. Unfortunately, because of inconsistencies in data collection these data cannot be used as intended; however, they are useful for understanding to some degree gross patterns in fish species distribution, but less so for macroinvertebrates.

Data Series↗
USGS2005

Geologic and hydrogeologic framework of the Espanola basin -- Proceedings of the 4th annual Espanola Basin Workshop, Santa Fe, New Mexico, March 1-3, 2005

This report presents abstracts of technical studies that pertain to the hydrogeologic framework of the This report presents abstracts of technical studies that pertain to the hydrogeologic framework of the Española basin, a major subbasin of the Cenozoic Rio Grande rift. Sediments and interbedded volcanic rocks that fill the Española basin comprise an aquifer system that is an important source of water for many residents of the basin, including people in the cities of Santa Fe, Española, and Los Alamos as well as Native Americans in eleven Pueblos. The abstracts describe results of technical studies that were presented either as poster exhibits or oral presentations at the forth-annual Española basin workshop, held March 1-2 of 2005 in Santa Fe, New Mexico. The principal goal of this workshop was to share information about ongoing studies. The Española basin workshop was hosted by the Española basin technical advisory group (EBTAG) and sponsored by the U.S. Geological Survey, the New Mexico Bureau of Geology and Mineral Resources, and both the Water Research Technical Assistance Office and the Groundwater Protection Program of Los Alamos National Laboratory. Abstracts in this report have been grouped into six information themes: Basic Water Data, Water Quality and Water Chemistry, Water Balance and Stream/Aquifer Interaction, Data Integration and Hydrologic Model Testing, Three-Dimensional Hydrogeological Architecture, and Geologic Framework. Taken together, the abstracts in this report provide a view of the current status of hydrogeologic research within the Española basin. , a major subbasin of the Cenozoic Rio Grande rift. Sediments and interbedded volcanic rocks that fill the Española basin comprise an aquifer system that is an important source of water for many residents of the basin, including people in the cities of Santa Fe, Española, and Los Alamos as well as Native Americans in eleven Pueblos. The abstracts describe results of technical studies that were presented either as poster exhibits or oral presentations at the forth-annual Española basin workshop, held March 1-2 of 2005 in Santa Fe, New Mexico. The principal goal of this workshop was to share information about ongoing studies. The Española basin workshop was hosted by the Española basin technical advisory group (EBTAG) and sponsored by the U.S. Geological Survey, the New Mexico Bureau of Geology and Mineral Resources, and both the Water Research Technical Assistance Office and the Groundwater Protection Program of Los Alamos National Laboratory. Abstracts in this report have been grouped into six information themes: Basic Water Data, Water Quality and Water Chemistry, Water Balance and Stream/Aquifer Interaction, Data Integration and Hydrologic Model Testing, Three-Dimensional Hydrogeological Architecture, and Geologic Framework. Taken together, the abstracts in this report provide a view of the current status of hydrogeologic research within the Española basin.

New Mexico↗