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USGS2010

Water-quality, water-level, and discharge data associated with the Mississippi embayment agricultural chemical-transport study, 2006-2008

In 2006, the Agricultural Chemicals: Sources, Transport and Fate study team (Agricultural Chemicals Team, ACT) of the U.S. Geological Survey National Water-Quality Assessment Program began a study in northwestern Mississippi to evaluate the influence of surface-water recharge on the occurrence of agriculturally related nutrients and pesticides in the Mississippi River Valley alluvial aquifer. The ACT study was composed in the Bogue Phalia Basin, an indicator watershed within the National Water-Quality Assessment Program Mississippi Embayment Study Unit and utilized several small, subbasins within the Bogue Phalia to evaluate surface and groundwater interaction and chemical transport in the Basin. Data collected as part of this ACT study include water-quality data from routine and incident-driven water samples evaluated for major ions, nutrients, organic carbon, physical properties, and commonly used pesticides in the area; discharge, gage height and water-level data for surface-water sites, the shallow alluvial aquifer, and hyporheic zone; additionally, agricultural data and detailed management activities were reported by land managers for farms within two subbasins of the Bogue Phalia Basin—Tommie Bayou at Pace, MS, and an unnamed tributary to Clear Creek near Napanee, MS.

Mississippi↗

USGS2000

A reconnaissance study of the effect of irrigated agriculture on water quality in the Ogallala Formation, Central High Plains Aquifer

In 1998, the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program began a regional study of water quality in the High Plains aquifer. The High Plains aquifer underlies an area of about 174,000 square miles in parts of eight States. Because of its large size, the High Plains aquifer has been divided into three regions: the Southern High Plains, Central High Plains, and Northern High Plains. Although an assessment of water quality in each of the three regions is planned, the initial focus will be the Central High Plains aquifer. Anyone who has flown over the Central High Plains in the summer and has seen the large green circles associated with center pivot sprinklers knows that irrigated agriculture is a widespread land use. Pesticides and fertilizers applied on those irrigated fields will not degrade ground-water quality if they remain in or above the root zone. However, if those chemicals move downward through the unsaturated zone to the water table, they may degrade the quality of the ground water. Water is the principal agent for transporting chemicals from land surface to the water table, and in the semiarid Central High Plains, irrigation often represents the most abundant source of water during the growing season. One objective of NAWQA's High Plains Regional Ground-Water study is to evaluate the effect of irrigated agriculture on the quality of recently recharged water in the Ogallala Formation of the Central High Plains aquifer. The Ogallala Formation is the principal geologic unit in the Central High Plains aquifer, and it consists of poorly sorted clay, silt, sand, and gravel that generally is unconsolidated (Gutentag and others, 1984). Approximately 23 percent of the cropland overlying the Ogallala Formation is irrigated (U.S. Department of Agriculture, 1999). The NAWQA Program generally defines recently recharged ground water to be water recharged in the last 50 years. The water table in the Ogallala Formation is separated from overlying land-use practices by as much as 400 feet of unsaturated sediments. Consequently, one may hypothesize that recently recharged water is not present in the formation. The U.S. Geological Survey conducted a reconnaissance study in 1999 to establish (a) if recently recharged water was present in the Ogallala Formation underlying irrigated cropland and (b) if agricultural land-use practices affect water quality. Results from the reconnaissance study will be used to determine whether a full-scale land-use study is warranted.

Fact Sheet↗

USGS1995

Are streams in agricultural and urban areas contaminated by pesticides?

To answer this question, a study of pesticides in streams in a small agricultural area and a small urban area in Colorado was conducted in 1993 by the U.S. Geological Survey (USGS) as part of the National Water-Quality Assessment (NAWQA) program. The results indicate that pesticides are present in streams, and both agricultural and urban areas are probable sources of the contamination. In the agricultural area, 30 pesticides were detected and in the urban area, 26 pesticides were detected at least once during the thirteen month study. In the agricultural area, the herbicides alachlor (two samples) and cyanazine (four samples) and the insecticide diazinon (one sample) were the only pesticides that exceeded the U.S. Environmental Protection Agency's maximum contaminant levels (MCLs) or health advisory levels (HALs) for drinking water. No pesticides exceeded MCLs or HALs in the urban area.

Fact Sheet↗

USGS2015

Development of an assessment tool for agricultural best management practice implementation in the Great Lakes Restoration Initiative priority watersheds—Upper East River, tributary to Green Bay, Wisconsin

Introduction The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Wisconsin↗

USGS2015

Development of an assessment tool for agricultural best management practice implementation in the Great Lakes restoration initiative priority watersheds—Eagle Creek, tributary to Maumee River, Ohio

Ohio↗

USGS2015

Development of an assessment tool for agricultural best management practice Implementation in the Great Lakes Restoration Initiative priority watersheds—Alger Creek, tributary to Saginaw River, Michigan

The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Michigan↗

USGS2002

Hydrologic conditions and quality of rainfall and storm runoff in agricultural and rangeland areas in San Patricio County, Texas, 2000-2001

During 2000–2001, rainfall and runoff were monitored in one mixed agricultural watershed and two rangeland watersheds in San Patricio County, located in the Coastal Bend area of South Texas. During this period, five rainfall samples were collected and analyzed for selected nutrients. Ten runoff samples from nine runoff events were collected at the three watershed monitoring stations. Runoff samples were analyzed for selected nutrients, major ions, trace elements, pesticides, and bacteria. Study area rainfall during 2000 and 2001 was 33.27 and 28.20 inches, respectively, less than the long-term average annual of 36.31 inches. Total runoff from the study area watersheds during 2000–2001 was 2.46 inches; the regional average is about 2 inches per year. Rainfall and runoff during the study period was typical of historical patterns, with periods of below average rainfall interspersed with extreme events. Three individual storm events accounted for about 29 percent of the total rainfall and 86 percent of the total runoff during 2000– 2001. Runoff concentrations of nutrients, major ions, and trace elements generally were larger in the mixed agricultural watershed than runoff concentrations in the rangeland watersheds. Pesticides were detected in two of eight runoff samples. Three pesticides (atrazine, deethylatrazine, and trifluralin) were detected in very small concentrations; only deethylatrazine was detected in a concentration greater than the laboratory minimum reporting level. Bacteria in agricultural and rangeland runoff is a potential water-quality concern as all fecal coliform and E. coli densities in the runoff samples exceeded Texas Surface Water Quality Standards for receiving waters. However, runoff and relatively large bacteria densities represent very brief and infrequent conditions, and the effect on downstream water is not known. Rainfall deposition is a major source of nitrogen delivered to the study area. Rainfall nitrogen (mostly ammonia and nitrate) exceeded the runoff yield. The average annual rainfall deposition of total nitrogen on the study area watersheds was 1.3 pounds per acre. In contrast, an average annual yield of 0.57 and 0.21 pound per acre of total nitrogen in runoff exited the mixed agricultural watershed and the rangeland watersheds, respectively.

Texas↗

USGS2009

Analytical Results for Agricultural Soils Samples from a Monitoring Program Near Deer Trail, Colorado (USA)

Since late 1993, Metro Wastewater Reclamation District of Denver (Metro District, MWRD), a large wastewater treatment plant in Denver, Colorado, has applied Grade I, Class B biosolids to about 52,000 acres of nonirrigated farmland and rangeland near Deer Trail, Colorado, USA. In cooperation with the Metro District in 1993, the U.S. Geological Survey (USGS) began monitoring groundwater at part of this site. In 1999, the USGS began a more comprehensive monitoring study of the entire site to address stakeholder concerns about the potential chemical effects of biosolids applications to water, soil, and vegetation. This more comprehensive monitoring program has recently been extended through 2010. Monitoring components of the more comprehensive study include biosolids collected at the wastewater treatment plant, soil, crops, dust, alluvial and bedrock groundwater, and stream bed sediment. Soils for this study were defined as the plow zone of the dry land agricultural fields - the top twelve inches of the soil column. This report presents analytical results for the soil samples collected at the Metro District farm land near Deer Trail, Colorado, during three separate sampling events during 1999, 2000, and 2002. Soil samples taken in 1999 were to be a representation of the original baseline of the agricultural soils prior to any biosolids application. The soil samples taken in 2000 represent the soils after one application of biosolids to the middle field at each site and those taken in 2002 represent the soils after two applications. There have been no biosolids applied to any of the four control fields. The next soil sampling is scheduled for the spring of 2010. Priority parameters for biosolids identified by the stakeholders and also regulated by Colorado when used as an agricultural soil amendment include the total concentrations of nine trace elements (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), plutonium isotopes, and gross alpha and beta activity (Colorado Department of Public Health and Environment, Hazardous Materials and Waste Management Division, 1997; Colorado Department of Public Health and Environment,1998; U.S. Environmental Protection Agency, 1993). Since these were the identified priority parameters for the biosolids, the soils have the same set of priority parameters. Although the composite soils' priority analytes have been reported earlier to Metro District, the remaining elemental datasets for both the composite soils samples and selected fields' individual subsamples' data are presented here for the first time. More information about the other monitoring components is presented elsewhere in the literature (http://co.water.usgs.gov/projects/CO406/CO406.html). In general, the objective of each component of the study was to determine whether concentrations of priority parameters (1) were higher than regulatory limits, (2) were increasing with time, and(or) (3) were significantly higher in biosolids-applied areas than in a similar farmed area where biosolids were not applied. The method chosen for sampling the soils proved to be an efficient and reliable representation of the average composition of each field. This was shown by analyzing individual subsamples, averaging the resulting values, and then comparing the values to the composited samples' values. The soil chemistry shows distinct differences between the two sites, most likely due to the different underlying parent material. Biosolids data were used to compile an inorganic-chemical biosolids signature that can be contrasted with the geochemical signature of the agricultural soils for this site. The biosolids signature and an understanding of the geology and hydrology of the site can be used to separate biosolids effects from natural geochemical effects. Elements of particular interest for a biosolids signature after application in the soils include bismuth, copper, silver, mercury, and phosphorus. This signat

Open-File Report↗

USGS2016

Agricultural irrigated land-use inventory for the counties in the Suwannee River Water Management District in Florida, 2015

A detailed inventory of irrigated crop acreage is not available at the level of resolution needed to accurately estimate agricultural water use or to project future water demands in many Florida counties. A detailed digital map and summary of irrigated acreage during the 2015 growing season was developed for 13 of the 15 counties that compose the Suwannee River Water Management District. The irrigated areas were delineated using land-use data, orthoimagery, and information obtained from the water management district consumptive water-use permits that were then field verified between May and November of 2015. Selected attribute data were collected for the irrigated areas, including crop type, primary water source, and type of irrigation system. Results indicate that an estimated 113,134 acres were either irrigated or had potential for irrigation in all or part of the 13 counties within the Suwannee River Water Management District during 2015. This estimate includes 108,870 acres of field-verified, irrigated crops and 4,264 acres of irrigated land observed as (1) idle (with an irrigation system visible but no crop present at the time of the field-verification visit), (2) acres that could not be verified during field visits, or (3) acres that were located on publicly owned research lands. Of the total field-verified crops, 83,721 acres were field crops; 20,962 acres were vegetable crops (sometimes referred to as row crops); 3,089 acres were in tree nurseries, ornamentals, and sod production; and 1,098 acres were fruit crops. Specific irrigated crops included 32,468 acres of corn (primarily for silage); 28,170 acres of peanuts; and 10,331 acres of hay. About 40 percent of the vegetable acreage (8,340 acres) was double cropped (planted with both a spring and a fall crop on the same field). Beans, carrots, and watermelons were the most commonly grown vegetable crops in these 13 counties in 2015. Sprinkler irrigation systems including center pivots, portable or traveling guns, and permanent or solid overhead fixtures accounted for nearly 91 percent (102,874 acres) of the total irrigated acreage in the Suwannee River Water Management District, whereas microirrigation systems including drip irrigation accounted for 9 percent (10,260 acres) of the irrigated acreage. A total of 1,466 center pivots were observed during field verification in 2015 and accounted for 93,093 irrigated acres (which represents 82 percent of the total irrigated acreage). Most center pivots were in use at the time of the field verification, although about 3 percent appeared idle. No flood irrigation systems were observed during field verification in 2015. Overall, groundwater was used to irrigate nearly all of the field-verified acreage (99.8 percent). Dairy wastewater effluent was used on many fields during 2015; however, a quantitative estimate of acreage using effluent could not be determined. Irrigated cropland totaled 26,927 acres in Suwannee County; 16,511 acres in Madison County; 14,862 acres in Hamilton County; and 14,155 acres in Gilchrist County; these four counties accounted for nearly two-thirds (64 percent) of the acres irrigated within the Suwannee River Water Management District during 2015. Corn (primarily for silage) and peanuts were the primary irrigated crops, accounting for 48, 70, and 71 percent, respectively, of the total irrigated acreage in Suwannee, Madison, and Gilchrist Counties; vegetables accounted for 52 percent of the total irrigated acres in Hamilton County. Other counties with substantial irrigated acreage included Levy (10,122 acres), Alachua (9,547 acres), and Lafayette (8,110 acres); these three counties, combined with Suwannee, Madison, Hamilton, and Gilchrist Counties, accounted for 88 percent of the irrigated acreage in the Suwannee River Water Management District. The irrigated acreage that was field verified in 2015 for the 13 counties in the Suwannee River Water Management District (113,134 acres) is about 6 percent higher than the estimated acreage published by the U.S. Department of Agriculture (107,217 acres) for 2012; however, this 2012 value represents acreage for the entire portion of all 13 counties, not just the Suwannee River Water Management District portion. Differences between the 2015 field-verified acreage totals and those published by the U.S. Department of Agriculture for 2012 may occur because (1) irrigated acreage for some specific crops increased or decreased substantially during the 3-year interval due to commodity prices or economic changes, (2) calculated field-verified irrigated acreage may be an overestimate because irrigation was assumed if an irrigation system was present and therefore the acreage was counted as irrigated, when in fact that may not have been the case as some farmers may not have used their irrigation systems during this growing period even if they had a crop in the field, or (3) the amount of irrigated acreages published by the U.S. Department of Agriculture for selected crops may be underestimated in some cases.

Florida↗

USGS2022

Mapping areas of groundwater susceptible to transient contamination events from rapid infiltration into shallow fractured-rock aquifers in agricultural regions of the conterminous United States

Current time-invariant groundwater vulnerability assessments may not capture intermittent contamination events in landscape areas that experience rapid infiltration following precipitation or snowmelt. Occurrences of rapid infiltration and intermittent degradation of groundwater quality are frequently reported in fractured-rock aquifers. This investigation identifies landscape areas underlain by fractured rock within the conterminous United States (CONUS) that may be susceptible to rapid infiltration and where groundwater is a principal source of water supply to the population. Our analysis shows that approximately 27 percent of the CONUS, corresponding to a population of approximately 150 million people, is both underlain by fractured rock and denoted as an area of significant groundwater use. The results of this survey identified shallow fractured-rock aquifers underlying glacial sediments in the upper Midwest and northeastern United States as areas that may be subject to rapid infiltration events. Additionally, aquifers associated with the early Mesozoic basins located in the northeastern and mid-Atlantic United States and bands of carbonate aquifers in the southeastern United States show high susceptibility to rapid infiltration. Index values used in this investigation indicate isolated areas in the western half of the United States also show high susceptibility to rapid infiltration. The isolated areas in Oklahoma, Texas, Arkansas, and southwestern Missouri correspond to karst regions of carbonate aquifers. The isolated areas showing high susceptibility to rapid infiltration and contamination from agricultural sources are locations where more detailed investigations of transient contamination events are warranted. This survey also addresses the potential for contaminant longevity in fractured-rock aquifers stemming from intermittent contamination events. Contaminants that can dissolve into the groundwater following infiltration may be introduced into fractures, and the dissolved constituents can diffuse from fractures into the porosity of the adjacent rock matrix. These constituents can then diffuse back into permeable fractures and adversely affect groundwater quality at downgradient locations over an extended time frame. Rock types with larger matrix porosities have the capacity to retain and then release larger quantities of dissolved constituents, resulting in longer residence times for dissolved groundwater contaminants. The magnitude of the dissolved contaminant concentration infiltrating to the water table will also dictate whether the contaminant concentration in the groundwater exceeds limits for human consumption over the duration of a contamination event. In general, sedimentary- and carbonate-rock aquifers have larger matrix porosities in comparison to igneous- and metamorphic-rock aquifers, and thus, they are more susceptible to longer contaminant residence times. Aquifers composed of sedimentary or carbonate rock constitute approximately 51 percent of the CONUS, and 19 percent of the CONUS is associated with sedimentary- or carbonate-rock aquifers that are of significance for groundwater use. Depending on the contaminants of concern and the concentration of the contaminants introduced into the groundwater from infiltrating water, it would be beneficial for investigations of susceptibility to rapid infiltration to also consider the potential for contaminant longevity. This investigation identifies areas of rapid infiltration into fractured rock using index values applied to the attributes (1) depth to the water table, (2) depth to bedrock, and (3) percentage of sand in soil, where larger index values indicate a greater susceptibility to rapid infiltration. These attributes are selected as the most likely factors that affect rapid infiltration to the water table. The combination of depth to water table and depth to bedrock highlight those aquifer settings that are characterized as shallow fractured-rock aquifers, where the water table may reside either in the bedrock or in overlying unconsolidated geologic materials. In addition, we consider the percentage of agricultural use as a land-use attribute when formulating an index of susceptibility to rapid infiltration and contamination. Agricultural areas are well recognized as nonpoint sources of contaminants that can affect groundwater quality because of seasonal amendments applied to the land surface. Rural agricultural areas are also characterized by septic tanks and leach fields for onsite treatment of wastewater, which may also be a source of contamination that may be introduced into the groundwater following precipitation or snowmelt events.

Conterminous United States↗

USGS1989

Effects of controlled agricultural practices on water quality in the Minnesota sand-plain aquifer

Recent studies of Minnesota's sand plains indicate that ground-water chemistry is related to agricultural practices. Surficial sand-plain aquifers cover 8,000,000 acres of Minnesota and are a major source of water for domestic use, irrigation, and some municipal systems. The sand-plain aquifers consist of sand and gravel deposits that are from 20 to greater than 100 feet thick and are covered by a thin sandy loam that generally is less than 2 feet thick. Sand-plain aquifers are recharged by the downward percolation of precipitation through the soil root zone and the unsaturated zone in the sand to the water table. The water table is the upper surface of the zone of saturation and forms the top of the sand-plain aquifer. Sand-plain aquifers are susceptible to contamination by agricultural chemicals (fertilizers and pesticides), if downward-percolating recharge water contains these chemicals. The concentrations of nitrate, pesticides, and some other chemical constituents fluctuate seasonally and differ with depth below the water table (Anderson, 1989). Despite the availability of water-quality data for about 260 wells that were collected during previous studies in three U.S. Geological Survey (USGS) project areas in Minnesota, it is not known how concentrations of agricultural chemicals in ground water relate to the rate and timing of fertilizer and pesticide application or to the tillage practices used. Field-scale research is needed to determine the effects of different farming practices on the concentrations of nitrate, pesticides, and other agricultural chemicals in ground water in the unsaturated and saturated zones.

Minnesota↗

USGS1993

Effects of recharge on the transport of agricultural chemicals at the Princeton, Minn. Management Systems Evaluation Area (MSEA), 1991-92

Rates of water movement through the unsaturated zone greatly affect the amount and concentrations of agricultural chemicals that may reach the water table. For example, recharge can flush to the water table chemicals that have accumulated In the unsaturated zone during dry periods. A better understanding of how topography influences recharge and the movement of agricultural chemicals is needed. In 1991, the U.S. Geological Survey (USGS), with funding from the USGS Toxic Substances Hydrology Program, began studying the movement of water and agricultural chemicals to the water table at the Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. Instruments were installed to measure the movement of moisture through the soil beneath a corn field. Samples of the recharge water were analyzed for concentrations of agricultural chemicals and tracers. Field recharge and tracer tests were simulated In the laboratory.

Minnesota↗

USGS1995

Similar agricultural areas, different ground-water quality, Red River of the North Basin, 1993-95

The U.S. Geological Survey has studied the ground-water quality within two areas of the Red River of the North Basin in southeastern North Dakota and west-central Minnesota. Although both areas are underlain by sandy surficial aquifers over which intensive irrigated agriculture dominates the land use, their ground-water quality differs. Ground water from the eastern study area has significantly higher concentrations of nitrate and agricultural herbicides than does ground water from the western area. Major differences in rainfall and minor differences in soils, depth to ground water, and agricultural practices between these two areas can account for the differences measured in ground-water quality. These same factors may indicate changes in ground-water quality from agricultural land uses in other surficial aquifers in the Red River of the North Basin.

Minnesota, North Dakota, South Dakota↗

USGS1996

Nutrient, sediment, and pesticide data collected at four small agricultural basins in the Beaver Creek watershed, West Tennessee, 1990-1995

In 1989, the U.S. Geological Survey began a cooperative study with the Tennessee Department of Agriculture to assess the impact of agricultural activities on water quality in the Beaver Creek watershed in West Tennessee. Quantification of the transport of nutrients, sediment, and pesticides from agricultural fields was one of the objectives of the study. This report presents nutrient, sediment, and pesticide data collected during selected storm events from 1990 through 1995 at four relatively small, agricultural basins (28 to 422 acres) in the Beaver Creek watershed. Approximately 3,000 water samples (500 to 1,000 at each site) were analyzed for nitrogen and phosphorus species. Total nitrogen (N) concentrations ranged from 0.2 to 41.2 milligrams per liter (mg/L). Median concentrations for samples from each site ranged from 2.0 to 2.7 mg/L for total nitrogen, 1.2 to 1.9 mg/L for organic nitrogen, 0.05 to 0.14 mg/L for ammonia (measured as N), and 0.2 to 0.8 mg/L for nitrate plus nitrite (measured as N). Total phosphorus (P) concentrations ranged from 0.03 to 16.0 mg/L. Median concentrations for samples from each site ranged from 0.80 to 1.2 mg/L for total phosphorus and 0.15 to 0.72 for orthophosphate (measured as P). Approximately 6,000 water samples (1,300 to 1,800 at each site) were analyzed for suspended sediment. Suspended-sediment concentrations ranged from 8.0 to 98,353 mg/L. Concentrations exceeded 1,000 mg/L in 33 percent of the samples collected and exceeded 10,000 mg/L in 6 percent of the samples. Median concentrations ranged from 347 to 713 mg/L at the four sites. Several herbicides and insecticides were detected in water samples. Maximum concentrations detected were 37 micrograms per liter for metolachlor, 3.2 for trifluralin, 150 for fluometuron, and 430 for aldicarb. Aldicarb metabolites were also detected in several samples. The maximum aldicarb sulfoxide and aldicarb sulfone concentrations detected were 68.4 and 14.3 micrograms per liter, respectively.

Tennessee↗

USGS2006

Hydrology and water quality in the Green River and surrounding agricultural areas near Green River in Emery and Grand Counties, Utah, 2004-05

Water from the Colorado River and its tributaries is used for municipal and industrial purposes by about 27 million people and irrigates nearly 4 million acres of land in the Western United States. Water users in the Upper Colorado River Basin consume water from the Colorado River and its tributaries, reducing the amount of water in the river. In addition, application of water to agricultural land within the basin in excess of crop needs can increase the transport of dissolved solids to the river. As a result, dissolved-solids concentrations in the Colorado River have increased, affecting downstream water users. During 2004-05, the U.S. Geological Survey, in cooperation with the Natural Resources Conservation Service, investigated the occurrence and distribution of dissolved solids in water from the agricultural areas near Green River, Utah, and in the adjacent reach of the Green River, a principle tributary of the Colorado River. The flow-weighted concentration of dissolved solids diverted from the Green River for irrigation during 2004 and 2005 was 357 milligrams per liter and the mean concentration of water collected from seeps and drains where water was returning to the river during low-flow conditions was 4,170 milligrams per liter. The dissolved-solids concentration in water from the shallow part of the ground-water system ranged from 687 to 55,900 milligrams per liter. Measurable amounts of dissolved solids discharging to the Green River are present almost exclusively along the river banks or near the mouths of dry washes that bisect the agricultural areas. The median dissolved-solids load in discharge from the 17 drains and seeps visited during the study was 0.35 ton per day. Seasonal estimates of the dissolved-solids load discharging from the study area ranged from 2,800 tons in the winter to 6,400 tons in the spring. The estimate of dissolved solids discharging from the study area annually is 15,700 tons. Water samples collected from selected sites within the Green River agricultural areas were analyzed for naturally occurring isotopes of strontium and boron, which can be useful for differentiating dissolved-solids sources. Substantial variations in the delta strontium-87 and delta boron-11 values among the sites were measured. Canal and river samples had relatively low concentrations of strontium and the most positive (heavier) isotopic ratios, while drains and seeps had a wide range of strontium concentrations and isotopic ratios that generally were less positive (lighter). Further study of the variation in strontium and boron concentrations and isotope ratios may provide a means to distinguish end members and discern processes affecting dissolved solids within the Green River study area; however, the results from isotope data collected during this study are inconclusive. Flow and seepage losses were estimated for the three main canals in the study area for May 2 to October 4 in any given year. This period coincides with the frost-free period in the Green River area. Estimated diversion from the Green River into the Thayn, East Side, and Green River Canals is 6,600, 6,070, and 19,900 acre-feet, respectively. The estimated seepage loss to ground water from the Thayn, East Side, and Green River Canals during the same period is 1,550, 1,460, and 4,710 acre-feet, respectively.

Utah↗

USGS2009

Biological-Community Composition in Small Streams and its Relations to Habitat, Nutrients, and Land Use in Agriculturally Dominated Landscapes in Indiana and Ohio, 2004, and Implications for Assessing Nutrient Conditions in Midwest Streams

The objective of this study was to relate algal-, invertebrate-, and fish-community composition to habitat, nutrients, and land-use variables in small streams in agriculturally dominated landscapes of the Midwest in Indiana and Ohio. Thirty sample locations were selected from a single ecoregion; all were small wadable streams within agriculturally dominated landscapes with similar substrate and canopy. Biological and nutrient samples were collected during stable flow conditions in August 2004. Canonical correspondence analysis was used to determine which variables most influenced each community. Total phosphorus concentrations significantly influenced the depositional-targeted habitat algal-diatom community and the richest-targeted habitat invertebrate community. Multivariate statistical analysis showed that habitat variables were more influential to the richest-targeted habitat algal-diatom and fish communities than nutrient concentrations. Although the nutrient concentrations measured during this study indicate that most streams were not eutrophic, the biological communities were dominated by eutrophic species, suggesting streams sampled were eutrophic. Consequently, it was concluded that biological relations to nutrients in agriculturally dominated landscapes are complex and habitat variables should be included in biological assessments of nutrient conditions in agriculturally dominated landscapes.

Scientific Investigations Report↗

USGS2009

Water-Quality and Biological Characteristics and Responses to Agricultural Land Retirement in Three Streams of the Minnesota River Basin, Water Years 2006-08

Water-quality and biological characteristics in three streams in the Minnesota River Basin were assessed using data collected during water years 2006-08. The responses of nutrient concentrations, suspended-sediment concentrations, and biological characteristics to agricultural land retirement also were assessed. In general, total nitrogen, suspended-sediment, and chlorophyll-a concentrations, and fish resource quality improved with increasing land retirement. The Chetomba Creek, West Fork Beaver Creek, and South Branch Rush River subbasins, which range in size from about 200 to 400 square kilometers, have similar geologic and hydrologic settings but differ with respect to the amount, type, and location of retired agricultural land. Total nitrogen concentrations were largest, with a mean of 15.0 milligrams per liter (mg/L), in water samples from the South Branch Rush River, a subbasin with little to no agricultural land retirement; total nitrogen concentrations were smaller in samples from Chetomba Creek (mean of 10.6 mg/L) and West Fork Beaver Creek (mean of 7.9 mg/L), which are subbasins with more riparian or upland land retirement at the basin scale. Total phosphorus concentrations were not related directly to differing land-retirement percentages with mean concentrations at primary data-collection sites of 0.259 mg/L in the West Fork Beaver Creek subbasin, 0.164 mg/L in the Chetomba Creek subbasin, and 0.180 mg/L in the South Branch Rush River subbasin. Temporal variation in water quality was characterized using data from in-stream water-quality monitors and storm-sediment data. Fish data indicate better resource quality for the West Fork Beaver Creek subbasin than for other subbasins likely due to a combination of factors, including habitat quality, food resources, and dissolved oxygen characteristics. Index of biotic integrity (IBI) scores increased as local land-retirement percentages (within 50 and 100 meters of the streams) increased. Data and analysis from this study can be used to evaluate the success of agricultural management practices and land-retirement programs for improving stream quality.

Scientific Investigations Report↗

USGS2015

Surface-water quality in agricultural watersheds of the North Carolina Coastal Plain associated with concentrated animal feeding operations

The effects of concentrated animal feeding operations (CAFOs) on water quality were investigated at 54 agricultural stream sites throughout the North Carolina Coastal Plain during 2012 and 2013. Three general watershed land-use types were examined during the study, including 18 background watersheds with no active CAFOs (BK sites), 18 watersheds with one or more active swine CAFOs but no poultry CAFOs (SW sites), and 18 watersheds with at least one active swine CAFO and one active dry-litter poultry CAFO (SP sites). The watershed drainage areas for these 54 stream sites ranged from 1.2 to 17.5 square miles. Conventional fertilizers used for crop production are the primary source of nutrients at the BK sites. Animal-waste manures represent an additional source of nutrients at the SW and SP study sites. Land cover, soil drainage, and CAFO attributes were compiled for each watershed. Water-quality field measurements were made and samples were collected at the 54 primary sites during 6 bimonthly sampling periods from June 2012 to April 2013. An additional 23 secondary sites were sampled once during April 2013 to provide supplemental data at stream locations directly adjacent or in close proximity to swine CAFOs and (or) background agricultural areas within 9 of the primary watersheds. The watershed drainage areas for the 23 secondary sites ranged from 0.2 to 8.9 square miles. Water temperature, specific conductance, dissolved-oxygen concentration, and pH were measured directly in the streams. Water samples were analyzed for major ions, nutrients, and stable isotopes, including delta hydrogen-2 (δ 2 H) and delta oxygen-18 (δ 18 O) of water and delta nitrogen-15 (δ 15 N) and δ 18 O of dissolved nitrate plus nitrite. Most of the water-quality properties and constituents varied significantly among the six sampling periods, changing both seasonally and in response to hydrologic conditions. The differences noted among the sampling periods indicate that the interactions between seasonal climatic differences, streamflow conditions, and instream biotic and abiotic processes are complex and their integrated effects can have varying degrees of influence on individual nutrients. Water-quality differences were noted for the SW and SP land-use groups relative to the BK group. Median values of specific conductance, several major ions (magnesium, sodium, potassium, and chloride), and nitrogen fractions (ammonia plus organic nitrogen, ammonia, nitrate plus nitrite, total nitrogen, and δ 15 N of nitrate plus nitrite) were higher for the SW and SP groups compared to the BK group. No significant differences in water temperature, dissolved oxygen, calcium, total organic nitrogen, orthophosphate, total phosphorus, or δ 18 O of nitrate plus nitrite were noted among the land-use groups. When compared on the basis of land-use type, there was an overall measurable effect of CAFO waste manures on stream water quality for the SW and SP watershed groups. Some individual sites within the SW and SP groups showed no measurable CAFO effects on water quality despite having CAFOs present upstream. An evaluation of sodium plus potassium concentrations coupled with δ 15 N values of nitrate plus nitrite proved valuable for distinguishing which SW and SP sites had a water-quality signature indicative of CAFO waste manures. Sites with CAFO manure effects were characterized by higher sodium plus potassium concentrations (commonly between 11 and 33 milligrams per liter) and δ 15 N values of nitrate plus nitrite (commonly between 11 and 26 parts per thousand) relative to sites reflecting background agricultural conditions, which commonly had sodium plus potassium concentrations between 6 and 14 milligrams per liter and δ 15 N values of nitrate plus nitrite between 6 and 15 parts per thousand. On the basis of the results of this study, land applications of waste manure at swine CAFOs influenced ion and nutrient chemistry in many of the North Carolina Coastal Plain streams that were studied. A classification tree model was developed to examine relations of watershed environmental attributes among the study sites with and without CAFO manure effects. Model results indicated that variations in swine barn density, percentage of wetlands, and total acres available for applying swine-waste manures had an important influence on those watersheds where CAFO effects on water quality were either evident or mitigated. Measurable effects of CAFO waste manures on stream water quality were most evident in those SW and SP watersheds having lower percentages of wetlands combined with higher swine barn densities and (or) higher total acres available for applying waste manure at the swine CAFOs. Stream water quality was similar to background agricultural conditions in SW and SP watersheds with lower swine barn densities coupled with higher percentages of wetlands or lower acres available for swine manure applications. The model provides a useful tool for exploring and identifying similar, unmonitored watersheds in the North Carolina Coastal Plain with potential CAFO manure influences on water quality that might warrant further examination.

North Carolina↗