Search Search USGS | Search USGS

USGS2026

Controls on natural hydrogen generation during serpentinization of mantle rocks

Mantle rocks undergoing serpentinization can generate significant amounts of natural hydrogen, yet the rates and controlling processes remain poorly understood. Here, we constrain the possible hydrogen generation rates in two distinct mantle rock types, the fertile lherzolites of the Western Pyrenees and the depleted harzburgites of Northern California, to relatively low rates of ~0.1 to ~0.5 tonnes H₂ yr⁻¹ km⁻³ of reactive rock. When integrated over the full reactive volumes, this corresponds to total production rates of ~300 to ~600 tonnes H₂ yr⁻¹. By combining three-dimensional geophysical inversion with numerical modelling of fluid-rock processes, we show that hydrogen generation rates are mainly limited by H₂ saturation in the fluid and reaction kinetics. Under these constraints, hydrogen generation in mantle-derived serpentinization systems proceeds slowly, making rapid large-scale replenishment unlikely and suggesting that large, economically relevant accumulations, would require timescales of thousands to tens of thousands of years to develop.

northern California, western Pyrenees↗

USGS2024

Application of non-stationary shear-wave velocity randomization approach to predict 1D seismic site response and its variability at two downhole array recordings

Accounting for uncertainties in seismic site response is crucial to improving the performance of one-dimensional (1D) ground response analyses (GRAs) at downhole array recording sites. In addition to site effects, uncertainties in 1D-GRAs can also be contributed from the seismic source and/or path. Though often representing not more than one percent of the distance (path) from the source, site conditions are known to have an enormous influence on ground shaking. In this study, we focus on the site shear-wave velocity ( V S ) structure, which is the main ingredient for estimating the variability of site response. As such, V S can manifest aleatory uncertainties related to the effects of small-scale spatial heterogeneities within the near surface, thus V S can substantially modify ground shaking during earthquakes. We apply a novel V S randomization approach to propagate the small-scale heterogeneities of V S to estimate seismic site response within a non-stationary probabilistic framework. The randomization approach generates samples of V S profiles that are used to perform several 1D-GRAs and obtain an averaged site response and related variability. The proposed method is implemented on data recorded at two downhole array sites with different subsurface soil conditions: a soft soil site on Treasure Island (California, United States of America) and a rock outcrop site in Cadarache (South-East France). We show that synthetic surface-to-borehole transfer functions from 1D-GRAs provide an acceptable fit to the empirical transfer functions from low-motion earthquake records and succeed in reproducing most of the site-specific seismic response variability. The remaining mismatch between transfer functions is likely due to insufficient precision on the seismic bedrock and the impedance contrast. The variability in site response is discussed with emphasis on the role of V S small-scale heterogeneities, attenuation, and input motion incidence angle in ground motion variability for the site and soil conditions at both locations.

California↗