Organochlorine compounds and trace elements in fish tissue and streambed sediment in the Mobile River Basin, Alabama, Mississippi, and Georgia, 1998

Humbert Zappia

doi:10.3133/wri024160

Home/Archive/USGS

USGS · wri024160

Organochlorine compounds and trace elements in fish tissue and streambed sediment in the Mobile River Basin, Alabama, Mississippi, and Georgia, 1998

Humbert Zappia

View original source ↗Export metadata ↓

Abstract

During the summer of 1998, as part of the National Water-Quality Assessment Program, a survey was conducted to determine which organochlorine compounds and trace elements occur in fish tissues and streambed sediments in the Mobile River Basin, which includes parts of Alabama, Mississippi, Georgia, and Tennessee. The data collected were compared to guidelines related to wildlife, land use, and to 1991 and 1994 National Water-Quality Assessment Program Study-Unit data.Twenty-one sites were sampled in subbasins of the Mobile River Basin. The subbasins ranged in size from about 9 to 22,000 square miles and were dominated by either a single land use or a combination of land uses. The major land-use categories were urban, agriculture, and forest.Organochlorine compounds were widespread spatially in the Mobile River Basin. At least one organochlorine compound was reported at the majority of sampling sites (84 percent) and in a majority of whole-fish (80 percent) and streambed-sediment (52 percent) samples. Multiple organochlorine compounds were reported at 75 percent of the sites where fish tissues were collected and were reported at many of the streambed-sediment sampling sites (45 percent). The majority of concentrations reported, however, were less than 5 micrograms per kilogram in fish-tissue samples and less than 1 microgram per kilogram in streambed-sediment samples.The majority of trace elements analyzed in fish-liver tissue (86 percent) and streambed-sediment (98 percent) samples were reported during this study. Multiple trace elements were reported in all samples and at all sites.Based on comparisons of concentrations of organochlorine compounds and trace elements in fish-tissue and streambed-sediment samples in relation to National Academy of Science and National Academy of Engineering and Canadian tissue guidelines, probable-effects concentrations, and mean probable-effects concentration quotients for streambed sediment, the potential exists for adverse effects to wildlife at 15 (72 percent) of the sites sampled. The potential for adverse effects at these sites is because of the presence of residues or breakdown products related to polychlorinated biphenyls (PCB?s), chlordane, dichlorodiphenyltrichloroethane (DDT), chromium, lead, and zinc.The majority of compounds reported (65 percent) were chlordane, DDT, and PCB?s, or their breakdown products. Concentrations of chlordane and heptachlor epoxide in whole-fish tissue were positively correlated to the amount of urban land use in a basin. Total DDT concentrations in whole-fish tissues were positively correlated to agriculture.The relation of trace elements to land use is not as clear as the relation of organochlorine compounds to land use. This lack of clarity may be due to the possibility of geologic sources of trace elements in the Mobile River Basin and to the ubiquitous nature of many of these trace elements. However, there may be a correlation between the amount of urban land use and concentrations of antimony, cadmium, lead, and zinc in streambed-sediment samples from the Mobile River Basin.Fewer organochlorine compounds and trace elements were reported in samples from the Mobile River Basin than in samples collected during the 1991 and 1994 National Water-Quality Assessment Program studies. Of the organochlorine compounds analyzed nationally, 57 percent were reported in whole-fish tissue samples collected locally and 41 percent were reported in streambed-sediment samples collected locally, whereas 96 percent and 86 percent, respectively, were reported nationally. Of trace elements analyzed nationally, 86 percent were reported in fish-liver tissue locally and 95 percent were reported in streambed-sediment samples locally, whereas 95 percent and 98 percent, respectively, were reported nationally.In general, concentrations of organochlorine compounds and trace elements and the frequency with which they were reported in the Mobile River Basin are similar to or less than t

Explore related subjects

Water-Resources Investigations Report Report

Source-reported bounding extent: 30.126124364224605° to 35.10193405724606° latitude; -89.32983398437499° to -83.34228515624999° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Humbert Zappia. 2002. Organochlorine compounds and trace elements in fish tissue and streambed sediment in the Mobile River Basin, Alabama, Mississippi, and Georgia, 1998. https://doi.org/10.3133/wri024160

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Hydrogeology of the Tully Valley and characterization of mudboil activity, Onondaga County, New York

Mudboil activity in the Tully Valley, in central New York, is causing turbidity in nearby Onondaga Creek, where it has caused a bridge to collapse; it also has threatened or damaged other structures and has caused extensive land subsidence. Mudboil activity was intermittent from its first reported appearance in the 1890's until the 1970's, when the rates of mudboil discharge and land subsidence began to increase. Historically, the water discharged from mudboils was reported as fresh, but chemical analyses in the late 1970's indicated an increase in specific conductance and chloride concentration. Mudboil discharge is driven by artesian pressure in unconsolidated sediments that are confined by a 60-foot layer of silt and red clay. This process, once begun, has been self-propagating. Artesian pressures are about 20 feet above land surface over most of the valley floor but exceed 30 feet above land surface along Onondaga Creek where Rattlesnake Gulf and Rainbow Creek enter the Tully Valley. The source of artesian pressure is recharge from the Tully (Valley Heads) Moraine at the south end of the valley, and the alluvial fans of Rattlesnake Gulf and Rainbow Creek. The mudboils are found within a 300-foot-wide by 1,500-foot-long corridor along Onondaga Creek just upstream from the two alluvial fans, and in a 5-acre subsided area just west of that corridor. Remediation efforts have entailed (1) diversion of flow from the tributary that feeds the subsided area, (2) installation of depressurizing wells at several locations, and (3) construction of a dam and settling impoundment to detain mudboil sediment that would normally discharge to Onondaga Creek. These efforts have been partly successful, but further work is needed to slow the mudboil activity, which is expected to persist in both areas. Mudboil activity is normally greatest during the early spring and late fall, when artesian pressures increase in response to seasonal ground-water recharge. Suspended-sediment concentrations at the out-flow of the subsidence area ranged from 31,210 mg/L (milligrams per liter) in October 1991 to 17 mg/L after remediation efforts in the summer of 1993. Yearly average suspended-sediment loads to Onondaga Creek from the subsidence area for water years 1992, 1993, 1994, and 1995 were 29.8, 9.75, 1.41, and 1.80 tons per day, respectively. Sediment discharged from the mudboils initially was 30 to 60 percent clay and 80 to 100 percent silt-sized or smaller sediment, and the sand fraction never exceeded 20 percent. After the remediation projects, 50 to 80 percent was clay, and nearly all sediment was silt size or smaller. Analyses of water from upstream and downstream of the subsidence area, as well as from mudboil vents within that area, indicate that the source of water for some mudboils is a confined freshwater aquifer, whereas for others it is an underlying, brackish-water aquifer. Water from the freshwater aquifer has specific conductance values ranging from about 400 ( μS /cm (microsiemens per centimeter at 25° Celsius) to almost 900 ( μS /cm, dissolved chloride concentrations range from 37 to 430 mg/L, and dissolved-solids concentrations range from 215 to 463 mg/L. Specific conductance of water from the brackish-water aquifer ranges from 17,000 to 28,000 ( μS /cm, chloride concentrations range from 2,000 to 7,100 mg/L, and dissolved-solids concentrations range from 4,200 to 12,800 mg/L. The largest landslide in New York State in the last 75 years occurred at the foot of Bare Mountain, 1 mile downstream from the mudboil area, in April 1993 and was the fourth in a series of slides that have occurred at the base of this hill. Slope instability was reported as early as May 1990. After the slide, intermittent mudboil-like activity was observed at several springs within the backscarp of the slide; water from these springs ranged from fresh to brackish. The chemical similarity between water from some springs in the backscarp area and water in the lower (brackish) aquifer beneath the mudboil area may indicate a hydraulic connection between this aquifer and the surficial deposits. Hydrologic changes in the valley during the last 100 years have been attributed to salt-solution mining in the upstream (southern) end of the valley. The removal of nearly 150 feet of salt from four evaporite beds in the Syracuse Shale of the Salina Group has caused the collapse of bedrock and unconsolidated deposits in and near the brine field, 3 miles south of the mudboil area. These collapses have created a hydraulic connection among bedding plane aquifers in the bedrock and increased the hydraulic connection with unconsolidated aquifers. The ground-water flow system after brine field closure in 1988 may have reached a new semiequilibrium, but mudboil activity will likely continue because artesian pressures remain. Whether mudboils were present before salt solution-mining began is unknown.

New York↗

USGS2018

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

Ground water historically has been the sole source of water supply for the Town of Yucca Valley in the Warren subbasin of the Morongo ground-water basin, California. An imbalance between ground-water recharge and pumpage caused ground-water levels in the subbasin to decline by as much as 300 feet from the late 1940s through 1994. In response, the local water district, Hi-Desert Water District, instituted an artificial recharge program in February 1995 using imported surface water to replenish the ground water. The artificial recharge program resulted in water-level recoveries of as much as 250 feet in the vicinity of the recharge ponds between February 1995 and December 2001; however, nitrate concentrations in some wells also increased from a background concentration of 10 milligrams per liter to more than the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) of 44 milligrams per liter (10 milligrams per liter as nitrogen). The objectives of this study were to: (1) evaluate the sources of the high-nitrate concentrations that occurred after the start of the artificial-recharge program, (2) develop a ground-water flow and solute-transport model to better understand the source and transport of nitrates in the aquifer system, and (3) utilize the calibrated models to evaluate the possible effect of a proposed conjunctive-use project. These objectives were accomplished by collecting water-level and water-quality data for the subbasin and assessing changes that have occurred since artificial recharge began. Collected data were used to calibrate the ground-water flow and solute-transport models. Data collected for this study indicate that the areal extent of the water-bearing deposits is much smaller (about 5.5 square miles versus 19 square miles) than that of the subbasin. These water-bearing deposits are referred to in this report as the Warren ground-water basin. Faults separate the ground-water basin into five hydrogeologic units: the west, the midwest, the mideast, the east and the northeast hydrogeologic units. Water-quality analyses indicate that septage from septic tanks is the primary source of the high-nitrate concentrations measured in the Warren ground-water basin. Water-quality and stable-isotope data, collected after the start of the artificial recharge program, indicate that mixing occurs between imported water and native ground water, with the highest recorded nitrate concentrations in the midwest and the mideast hydrogeologic units. In general, the timing of the increase in measured nitrate concentrations in the midwest hydrogeologic unit is directly related to the distance of the monitoring well from a recharge site, indicating that the increase in nitrate concentrations is related to the artificial recharge program. Nitrate-to-chloride and nitrogen-isotope data indicate that septage is the source of the measured increase in nitrate concentrations in the midwest and the mideast hydrogeologic units. Samples from four wells in the Warren ground-water basin were analyzed for caffeine and selected human pharmaceutical products; these analyses suggest that septage is reaching the water table. There are two possible conceptual models that explain how high-nitrate septage reaches the water table: (1) the continued downward migration of septage through the unsaturated zone to the water table and (2) rising water levels, a result of the artificial recharge program, entraining septage in the unsaturated zone. The observations that nitrate concentrations increase in ground-water samples from wells soon after the start of the artificial recharge program in 1995 and that the largest increase in nitrate concentrations occur in the midwest and mideast hydrogeologic units where the largest increase in water levels occur indicate the validity of the second conceptual model (rising water levels). The potential nitrate concentration resulting from a water-level rise in the midwest and mideast hydrogeologic units was estimated using a simple mixing-cell model. The estimated value is within the range of concentrations measured in samples from wells, further indicating the validity of the second conceptual model. A ground-water flow model and a solute-transport model were developed for the Warren ground-water basin for the period 1956-2001. MODFLOW-96 was used for the ground-water flow model and MOC3D was used for the solute-transport model. The model cell size is about 500 feet by 500 feet and the models were discretized vertically into three layers. The models were calibrated using a trial-and-error approach using water-level and nitrate-concentration data collected between 1956-2001. In order to better match the measured data, low fault hydraulic characteristic values were required, thereby compartmentalizing the ground-water basin. In addition, it was necessary to parameterize the specific yield distribution for the top model layer where unconfined ground-water conditions occur into three homogeneous zones. Separate sets of specific- yield values were needed to simulate the drawdown and subsequent water-level recovery. In addition, the calibrated natural recharge was about 83 acre-feet per year. The entrainment of unsaturated-zone septage was simulated as recharge having an associated nitrate concentration. The volume of recharge was a function of the measured water-level rise between 1994-98 and the moisture content of the unsaturated zone. The nitrate concentration of the recharge water was a weighted function of the assumed nitrate concentration in the infiltrating water associated with the overlying land use. The simulated hydraulic head and nitrate concentration results were in good agreement with the measured data indicating that the mechanism for the increase in nitrate concentrations was rising water levels entraining high-nitrate septage in the unsaturated-zone. The calibrated models were used to simulate the possible effects of a planned conjunctive-use project in the western part of the ground-water basin. The simulated project included the addition of a new recharge pond and a new extraction well. In addition, recharge at two existing recharge ponds was increased and three existing production wells were pumped, treated in a nitrate-removal facility, and used for water supply. The simulated hydraulic heads increased in the west, the mideast, and parts of the east hydrogeologic units; however, the simulated hydraulic heads decreased in the midwest and northeast hydrogeologic units. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter (10 milligrams per liter as nitrogen) in parts of the west as a result of the increase in simulated hydraulic head. The simulated nitrate concentrations decreased in part of the midwest hydrogeologic unit as a result of the artificial recharge and pumping from the nitrate-removal wells. The simulated nitrate concentrations increased to above the MCL of 44 milligrams per liter in part of the mideast and parts of the east hydrogeologic units beneath commercial land-use areas.

California↗

USGS2016

Clear-water abutment and contraction scour in the Coastal Plain and Piedmont Provinces of South Carolina, 1996-99

The U.S. Geological Survey, in cooperation with the South Carolina Department of Transportation, collected observations of clear-water aburment and contraction scour at 146 bridges in the Coastal Plain and Piedmont of South Carolina. Scour depths ranged from 0 to 23.6 feet. Theoretical scour depths were computed at each bridge and compared with observed scour. This comparison showed that theoretical scour depths, in general, exceeded the observed scour depths and often were excessive. A comparison of field data with dimensionless relations for laboratory data showed that the range of dimensionless variables used in laboratory investigations was outside of the range for field data in South Carolina, suggesting laboratory relations may not be applicable to field conditions in South Carolina. Variables determined to be important in developing scour within laboratory studies were investigated to understand their influence within the South Carolina field data, and many of these variables appeared to be insignificant under field conditions found in South Carolina. The strongest explanatory variables were embankment length, geometric-contraction ratio, approach velocity, and soil cohesion. Envelope curves developed with the field data are useful tools for assessing reasonable ranges of scour depth in South Carolina. These tools are simple to apply and are an improvement over the current methods for predicting theoretical scour. Data from this study have been compiled into a database that includes photographs, figures, observed scour depths, theoretical scour depths, limited basin characteristics, limited soil data, and theoretical hydraulic data. The database can be used to compare studied sites with unstudied sites to assess the potential for scour at the unstudied sites. In addition, the database can be used to assess the performance of various theoretical methods for predicting clear-water abutment and contraction scour.

South Carolina↗