PCB source assessment in the lower Clinton River, Clinton River Area of Concern, Mount Clemens, Michigan

Barbara C. Scudder Eikenberry; Hayley T. Olds; Owen M. Stefaniak; David A. Alvarez

doi:10.3133/sir20235030

Home/Archive/USGS

USGS · sir20235030

PCB source assessment in the lower Clinton River, Clinton River Area of Concern, Mount Clemens, Michigan

Barbara C. Scudder Eikenberry·Hayley T. Olds·Owen M. Stefaniak·David A. Alvarez

View original source ↗Read source document ↗Export metadata ↓

Abstract

Polychlorinated biphenyls (PCBs), some of the earliest “forever chemicals,” were used for decades in the United States before 1979 when PCB manufacturing was banned. High PCB concentrations were found recently in the lower Clinton River in the Great Lakes drainage. To determine the possible existence, location, and significance of a current source of PCBs, the U.S. Geological Survey (USGS) deployed passive water samplers (SPMDs, semipermeable membrane devices) in the river at 15 sites for 1 month in 2019 near outfalls of interest and other locations. USGS also deployed passive stream sediment samplers at a subset of four sites during the same period and collected bank sediment samples at a subset of four sites. Sediment from nearby catch basins was also collected. Samples were assayed for 209 individual PCB congeners, and patterns in total and individual congeners were evaluated; ancillary sediment data included grain size, total organic carbon, and moisture. U.S. Army Corps of Engineers (USACE) data for total PCBs and 209 PCB congeners in surficial sediment samples collected in 2019 were also evaluated. In general, total PCBs were highest in streambed sediment, followed by catch basin sediment, bank sediment, and then water as estimated from SPMDs. Total PCBs in sediment were low in all catch basins but one (sample CB19–02) that drains from an historical landfill area to one of two adjacent outfalls of interest: the outfall for a nearby wastewater treatment plant and adjacent outfall MTC–R–060, where the highest total PCBs in USGS stream sediment samples were found (site 14, sample 14STRM; 1,260,000 picograms per gram). Also, the SPMD at site 14 was the only water sample with more “light” (three or fewer chlorine atoms) than “heavy” (four or more chlorine atoms) PCB congeners, and the passive sediment sample had the highest proportion of light PCBs in USGS sediment samples. Light PCB congeners degrade more quickly than heavy PCB congeners and results may indicate that one or more current sources of PCBs are contributing to total PCBs in sediment at four river sites. Of 209 possible PCB congeners assayed, 117 congeners were detected in water samples; 155 and 154 congeners were detected in USGS and USACE sediment samples, respectively. PCBs 28, 73, 31, and 18 (highest to lowest) contributed most toward total PCBs in water samples overall; PCBs 20/28, 31, 52, and 44/47/65 contributed most toward total PCBs for sediment in USGS stream samples overall and USACE samples overall; these rankings were also true for catch basins overall except for PCB–31. After omitting coeluting congeners to allow further comparison, 5 key PCB congeners are in the top 20 congeners across all assay groups: 17, 31, 52, 95, and 118. The importance of these congeners in multiple assays aligns with their importance as components of certain Aroclors. Sediment from the high PCB catch basin (sample CB19–02) had a different pattern of top congeners than the other catch basins, and multivariate analyses indicated a high degree of similarity in its overall congener pattern with that of the highest PCB sediment sample (sample 14STRM) collected by the outfalls for the catch basin and the wastewater treatment plant. Similarities in overall congener patterns across sample media as determined by multivariate analyses confirmed some site linkages and the possibility of more than one source of PCBs to the reach. Furthermore, equilibrium partitioning calculations indicated that water concentrations as estimated by SPMDs were high enough to result in the PCB concentrations measured in USGS passive sediment samples but not USACE surficial sediment samples when normalized by organic carbon. However, the SPMDs and passive sediment samples reflect only one month of contribution to the river and higher concentrations would be expected to result with years of PCB accumulation. PCBs contributed to the river water by outfalls could eventually partition to sediment in the reach. Thus, the river could have a current source or sources of PCBs, perhaps one or more outfalls near four sites. Additional investigation is needed to better define the relative significance of each outfall and areas in nearby drainage systems that may be contributing PCBs to outfalls and the river.

Explore related subjects

Scientific Investigations Report Report

Source-reported bounding extent: 42.596° to 42.602° latitude; -82.87419476806319° to -82.86189203439089° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Barbara C. Scudder Eikenberry, Hayley T. Olds, Owen M. Stefaniak, David A. Alvarez. 2023-07-20. PCB source assessment in the lower Clinton River, Clinton River Area of Concern, Mount Clemens, Michigan. https://doi.org/10.3133/sir20235030

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Monitoring recreation on federally managed lands and waters—Aspects of visitor use

Federally managed public lands and waters receive around 1 billion recreational visits each year. Data on these visitors can aid in guiding policy decisions, managing resources effectively, and communicating the economic contributions of lands and waters. This report explores the methods used by agencies to collect data on aspects of recreational visitor use to Federal lands and waters (apart from visitation numbers, which are the focus of a companion publication). Aspects of recreational visitor use include visitor demographics, recreational activity participation, visitor satisfaction, visitor attitudes and experiences, trip characteristics, and economic contributions. We review practices used to understand aspects of visitor use across seven Federal agencies, revealing similarities such as the use of visitor intercept surveys and coverage of similar topic areas, and differences in how survey programs are operationalized and how specific questions on visitor surveys are worded. We also evaluate emerging technologies, such as geolocated social media and mobile device location data, for their potential to aid in understanding aspects of visitor use. This report concludes with potential opportunities to enhance data collection and coordination, ensuring cost-effective data collection and informed decision making.

Scientific Investigations Report↗

USGS2026

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio↗

USGS2026

Continuous monitoring and temporal variability of fluorescence of dissolved organic matter in karst groundwater of the Edwards aquifer, south-central Texas, 2019–24

Widespread urbanization on the Edwards aquifer recharge zone in south-central Texas has prompted the development of new approaches and tools for evaluating the current and future status of water quality in the San Antonio and Barton Springs segments of the Edwards aquifer. The U.S. Geological Survey, in cooperation with the San Antonio Water System and the City of Austin, applied continuous monitoring of fluorescence of dissolved organic matter (fDOM) to characterize the sources and transport of dissolved organic matter and associated constituents in the Edwards aquifer. Continuous fDOM time-series data were adjusted using empirically derived temperature, turbidity, and inner-filter-effect correction factors prior to analysis and interpretation. Fully corrected fDOM time-series data from the study sites were evaluated for short- and long-term temporal variability in fDOM in the context of the hydrologic and climatic conditions that occurred during the 5-year study period to understand vulnerability of the aquifer to potential contaminants in recharge. Study results indicate that fDOM is an effective proxy for dissolved organic carbon that, in turn, is indicative of the influx of recent surface water and associated contaminants, and thus, aquifer vulnerability to those contaminants. Although other continuously monitored water-quality parameters provide insights into changes in water quality in response to varying hydrologic conditions, the quantitative relation between fDOM and dissolved organic carbon directly indicates the timing and magnitude of pulses of organic constituents derived from the land surface, whereas other water-quality parameters do not.

Texas↗